With Non -c=x Containing Reactant Patents (Class 521/173)
  • Patent number: 11827737
    Abstract: A novel thermoplastic polyurethane composition is disclosed which comprise the reaction product of a polyisocyanate component, a polyol component, wherein the polyol component comprises a polyester comprising the reaction product of triethylene glycol and/or tetraethylene glycol with a diacid having 6 carbon atoms or fewer, and, optionally, a chain extender component.
    Type: Grant
    Filed: November 7, 2018
    Date of Patent: November 28, 2023
    Assignee: Lubrizol Advanced Materials, Inc.
    Inventors: Julius Farkas, Charles P. Jacobs
  • Patent number: 11813763
    Abstract: A razor blade including a blade body, an expanded coating structure arranged on a surface of the blade body so as to cover the blade body at least partially, the expanded coating structure including one or more expanded polymer microspheres, at least one of the one or more expanded polymer microspheres including a gas encapsulated within a hollow thermoplastic polymer shell.
    Type: Grant
    Filed: November 19, 2020
    Date of Patent: November 14, 2023
    Assignee: BIC VIOLEX SINGLE MEMBER S.A.
    Inventors: George Kanakaris, Christos Ampatis
  • Patent number: 11787897
    Abstract: Described herein is a method for producing a PU foam insole, including the following steps of: (1) pouring the raw materials used to form a PU foam into a mould, reacting to obtain a PU sheet, where the height of the mould cavity is from about 1.0 to about 1.6 times of the total thickness of two finished insoles; (2) splitting the PU sheet into two halves in the horizontal direction to obtain two pieces of PU insole material, where one surface of the material has open pores, and the other surface of the material has a skin; and (3) attaching a piece of fabric onto the surface having open pores of the material obtained in step (2). Also described herein is a PU foam insole produced by the method.
    Type: Grant
    Filed: December 4, 2018
    Date of Patent: October 17, 2023
    Assignee: BASF SE
    Inventors: Zhen Peng Liang, Yun Bang Zhong
  • Patent number: 11708515
    Abstract: The invention relates to an adhesive dual-component composition based on polyurethane, comprising an —NCO component and an —OH component such that: the —NCO component is a composition comprising: A) at least one polyurethane prepolymer comprising at least two NCO terminal groups obtained by the polyaddition reaction of at least one dissymmetric diisocyanate monomer and at least one diol, and B) at least one triisocyanate selected from isocyanurates, biurets, diisocyanate and triol adducts, and the mixtures thereof; the —OH component is a composition comprising at least one polyol; at least one of the polyols or diols is selected from polyether polyols (or polyether diols); at least one of the polyols or diols is selected from polyester polyols (or polyester diols); and the weight ratio of the quantity of polyether polyol(s) to the quantity of polyester polyol(s), defined as r4, ranges from 0.6 to 2.2.
    Type: Grant
    Filed: July 7, 2017
    Date of Patent: July 25, 2023
    Assignee: BOSTIK SA
    Inventors: Francis Pardal, Guillaume Michaud, Aurélien Wiegand, David Penet
  • Patent number: 11292867
    Abstract: A polyurethane foam material having the following properties: Compression hardness at 10% (according to ISO 3386/1) higher than 60 kPa and lower than 120 kPa; Free rise density in the range 40-80 kg/m3 (according to ISO 845); Flexural modulus (according to ISO 1209-2) in range 0.95-2 MPa.
    Type: Grant
    Filed: August 22, 2017
    Date of Patent: April 5, 2022
    Assignee: HUNTSMAN INTERNATIONAL LLC
    Inventors: Raf Elen, Luc Van Essche
  • Patent number: 9023908
    Abstract: The present invention relates to a method for adsorbing and/or absorbing oil, by bringing oil into contact with a polyurethane sponge with excellent mechanical properties.
    Type: Grant
    Filed: May 24, 2011
    Date of Patent: May 5, 2015
    Assignee: BASF SE
    Inventors: Nils Mohmeyer, Ralf Fritz, Bernd Bruchmann, Anna Cristadoro, Marcus Leberfinger, Antje van der Net
  • Patent number: 8980422
    Abstract: A polyurethane/polyisocyanurate foam is obtainable from the reaction of A) a polyol component comprising A1) an aromatic polyester polyol, A2) a polyether polyol started on a carbohydrate polyol and A3) a polyether polyol started on ethylene glycol, wherein the total hydroxyl number of the polyol component A) is from ?150 mg KOH/g to ?300 mg KOH/g; with B) a polyisocyanate component, wherein the equivalent ratio of NCO groups to the sum of the hydrogen atoms reactive towards NCO groups is from ?110:100 to ?200:100. This foam has improved adhesion properties to facings and is suitable for the production of composite elements without requiring the use of an additional adhesion promoter.
    Type: Grant
    Filed: November 9, 2010
    Date of Patent: March 17, 2015
    Assignee: Bayer MaterialScience AG
    Inventors: Rolf Roers, Torsten Heinemann, Maria Dolors Mateu
  • Patent number: 8940803
    Abstract: The present invention relates to a rigid polyurethane foam which can be obtained by mixing (a) isocyanates, (b) compounds having groups which are reactive toward isocyanates, (c) blowing agents comprising water, (d) catalysts and optionally (e) further additives to form a reaction mixture, applying the reaction mixture to a reinforcing material and curing the reaction mixture, where the isocyanates (a) have a viscosity of not more than 500 mPas at 25° C. and the compounds (b) having groups which are reactive toward isocyanates comprise a polyetherol (b1) having a functionality of 4 or more and a viscosity at 25° C. of 10 000 mPas or less, a polyetherol (b2) having a functionality of 3.5 or less and a viscosity at 25° C. of 600 mPas or less, a polyesterol (b3) having a viscosity at 25° C. of 2000 mPas or less, chain extenders (b4) comprising at least 30% secondary OH groups and optionally a crosslinker (b5).
    Type: Grant
    Filed: December 3, 2009
    Date of Patent: January 27, 2015
    Assignee: BASF SE
    Inventors: Marco Balbo Block, Cheul Hyeon Hwang
  • Publication number: 20150025164
    Abstract: The present invention relates to polyurethane rigid foams formulations. More particularly, the present invention relates to polyurethane rigid foams formulations, prepared from aromatic polyester polyols, which show improved compressive strength. The formulations include an isocyanate reacting mixture, at least one polymeric diphenylmethane diisocyanate, having a functionality of at least 2.7, and at least one blowing agent; such that the stoichiometric index of the polyisocyanate to the isocyanate reacting mixture is 1.0-1.8.
    Type: Application
    Filed: August 24, 2012
    Publication date: January 22, 2015
    Applicant: Dow Global Technologies LLC
    Inventors: Paolo Golini, Maurizio Guandalini
  • Publication number: 20140370267
    Abstract: The present invention relates to a polyurethane/polyisocyanurate foam with improved dimensional stability. It relates further to the use thereof in the production of metal composite elements, to metal composite elements produced therewith, and to a method for producing metal composite elements.
    Type: Application
    Filed: January 30, 2013
    Publication date: December 18, 2014
    Applicant: Bayer Intellectual Property GmbH
    Inventors: Rolf Roers, Torsten Hagen, Rene Abels, Inge Tinnefeld, Walter Schindler
  • Patent number: 8901189
    Abstract: A foam article, for use in a seat such as a seat cushion, includes an open cell, polyurethane foam material that includes a plant oil-based polyol material content greater than five percent and is produced from the reaction of a base polyol formulation blend including at least a portion of a plant oil-based polyol, a copolymer polyol including at least a portion of a plant oil-based polyol, water, a cross-linking agent, a catalyst, cell opener and a surfactant that are reacted with an isocyanate material for producing the seat cushion having performance specifications that are equivalent or better than the performance characteristics for a traditional petroleum oil-based polyol material seat cushion.
    Type: Grant
    Filed: October 30, 2007
    Date of Patent: December 2, 2014
    Assignee: Johnsons Controls Technology Company
    Inventors: Patricia J. McClarren, Ryoko Yamasaki, James T. McEvoy, Terry M. McRoberts, William W. Li
  • Patent number: 8895636
    Abstract: Rigid polyurethane foams or rigid polyisocyanurate foams with low brittleness are produced by the reaction of polyisocyanate polyetherester polyols based on aromatic dicarboxylic acids obtained by esterification of a dicarboxylic acid composition containing aromatic dicarboxylic acids and aliphatic dicarboxylic acids, fatty acids, aliphatic or cycloaliphatic diols having 2 to 18 carbon atoms or alkoxylates thereof, and a polyether polyol having a functionality of not less than 2.
    Type: Grant
    Filed: December 31, 2012
    Date of Patent: November 25, 2014
    Assignee: BASF SE
    Inventor: Gunnar Kampf
  • Patent number: 8865782
    Abstract: A fire-resistant polyurethane foam is provided. A hydroxyl-containing inorganic fire retardant is premixed with a polyisocyanate and a polyol, respectively, to form two premixtures. Then, the two premixtures are mixed for reaction to form a fire-resistant polyurethane foam. Preferably, a combination of different particle sizes of the fire retardant is employed to maximize the amount of the fire retardant and increase the fire resistance of the foam.
    Type: Grant
    Filed: November 6, 2013
    Date of Patent: October 21, 2014
    Assignee: Industrial Technology Research Institute
    Inventors: Po-Ju Chen, Sung-Jeng Jong, Ren-Kuen Chang, Chin-Shang Hsu, Jer-Young Chen, Yih-Her Chang, Chei Kao
  • Patent number: 8865785
    Abstract: A polishing pad capable of maintaining a high level of dimensional stability upon moisture absorption or water absorption and providing high polishing rate includes a polishing layer of a polyurethane foam having fine cells, wherein the polyurethane foam includes a cured product of a reaction of (1) an isocyanate-terminated prepolymer (A) that includes an isocyanate monomer, a high molecular weight polyol (a), and a low molecular weight polyol, (2) an isocyanate-terminated prepolymer (B) that includes a polymerized diisocyanate and a polyethylene glycol with a number average molecular weight of 200 to 1,000, and (3) a chain extender.
    Type: Grant
    Filed: March 13, 2008
    Date of Patent: October 21, 2014
    Assignee: Toyo Tire & Rubber Co., Ltd.
    Inventor: Yoshiyuki Nakai
  • Patent number: 8846776
    Abstract: Composite materials and methods for their preparation are described herein. The composite materials include a polyurethane made from the reaction of an isocyanate and a mixture of polyols, and coal ash (e.g., fly ash). The mixture of polyols comprises at least two polyols including a high hydroxyl number polyol having a hydroxyl number greater than 250 and comprising from about 1% to about 25% by weight of the total polyol content used to form the polyurethane, and a low hydroxyl number polyol having a hydroxyl number of 250 or lower. The coal ash is present in amounts from about 40% to about 90% by weight of the composite material. Also described is a method of preparing a composite material, including mixing an isocyanate, a mixture of at least two polyols, coal ash (e.g., fly ash), and a catalyst.
    Type: Grant
    Filed: August 12, 2010
    Date of Patent: September 30, 2014
    Assignee: Boral IP Holdings LLC
    Inventors: Ronald M. Herrington, Kengqing Jian
  • Publication number: 20140242313
    Abstract: A cavity between inner and outer walls of an open-box-shaped mould is filled with a polyurethane reaction mixture, containing an isocyanate and an emulsion of an isocyanate-reactive composition with three polyols and a blowing agent, which is cured to a polyurethane containing polymer. The inner and outer wall are a fixed distance from one another and each wall comprises a bottom and sides. The mixture is fed through an inlet in the bottom of the outer wall. Before filling the cavity, the mould is turned downwards so that the mixture foams upwards, filling the cavity. The three polyols are polyether polyol obtained by adding an epoxy to carbohydrates or difunctional or higher-functional alcohols; polyether polyol obtained by adding an epoxy to an aromatic amine; and polyester polyether polyol obtained by adding an epoxy to the esterification product of an aromatic dicarboxylic acid derivative and a difunctional or higher-functional alcohol.
    Type: Application
    Filed: February 20, 2014
    Publication date: August 28, 2014
    Applicant: BAYER MATERIALSCIENCE AG
    Inventors: Stephanie VOGEL, Reinhard ALBERS, Michael LOOF, Frank OTTO
  • Publication number: 20140213679
    Abstract: The invention relates to stable emulsions for the production of foams based on isocyanates, comprising at least three polyols A1a, A1b and A1c and at least one physical blowing agent T, wherein A1a is a polyether polyol, obtained by the addition of epoxies to starter compounds selected from carbohydrates and difunctional or higher-functional alcohols, A1b is a polyether polyol started on an aromatic amine and A1c is a polyester polyether polyol, obtained by the addition of epoxies to the esterification product of an aromatic dicarboxylic acid derivative and a difunctional or higher-functional alcohol. The invention further relates to a method for producing foams by reactions of such emulsions with isocyanates and to the foams obtainable in this way and their use for insulating purposes.
    Type: Application
    Filed: August 22, 2012
    Publication date: July 31, 2014
    Applicant: Bayer Intellectual Property GmbH
    Inventors: Reinhard Albers, Torsten Heinemann, Stephanie Vogel, Thomas Heidelmann, Frank Otto
  • Patent number: 8791168
    Abstract: A viscoelastic polyurethane foam is the reaction product of at least one natural oil derived polyol and at least one aromatic compound having an average of more than one isocyanate group. A viscoelastic polyurethane foam has an air flow of at least about 0.5 l/s, wherein the foam is formed in the substantial absence of copolymer polyol and has not (yet) been mechanically reticulated and is preferably prepared using at least one natural oil derived polyol, more preferably in an amount of at least about 20 weight percent of the polyols used. A process of preparing a viscoelastic foam, comprises steps of (A) forming a reaction mixture including at least one polyol, at least one polyisocyanate, water, at least one catalyst wherein a the polyol comprises at least one natural oil derived polyol; and (B) subjecting the reaction mixture to conditions sufficient to result in the reaction mixture to expand and cure to form a viscoelastic polyurethane foam.
    Type: Grant
    Filed: September 7, 2007
    Date of Patent: July 29, 2014
    Assignees: Dow Global Technologies, Dow Brasil Sudeste Industrial Ltda
    Inventors: David A. Babb, Bernard E. Obi, Robert E. O'Neill, Alvaro Pauperio-Neto
  • Publication number: 20140206786
    Abstract: Described is a method for using a trialkyl phosphate as a smoke suppressant in a polyurethane foam. The trialkyl phosphate having at least one alkyl group with two carbon atoms is included in the polyurethane foam, which has an absence of halogenated flame retardants.
    Type: Application
    Filed: September 29, 2011
    Publication date: July 24, 2014
    Applicant: DOW GLOBAL TECHNOLOGIES LLC
    Inventors: JianPing Xu, Yudong Qi, Luca Lotti, Xiang Y. Tai
  • Publication number: 20140179812
    Abstract: A rigid polyurethane foam includes the reaction product of an isocyanate and an isocyanate reactive component in the presence of a blowing agent. The isocyanate reactive component includes an aromatic polyester polyol, a rigid polyol, and an aliphatic polyester polyol. The rigid polyurethane foam has a tensile adhesion of greater than 35 kPa (5 psi) when disposed on a metal substrate or a polyester, polyurethane, or epoxy coated metal substrate, each having a substrate temperature of greater than 41° C. (105° F.), and tested in accordance with ASTM D1623-09. A method of forming a composite article comprising a substrate and the rigid polyurethane foam includes the steps of combining the isocyanate reactive component and the isocyanate in the presence of the blowing agent to form a reaction mixture and applying the reaction mixture to the substrate having a substrate temperature of greater than 41° C. (105° F.) to form the composite article.
    Type: Application
    Filed: December 20, 2013
    Publication date: June 26, 2014
    Applicant: BASF SE
    Inventor: Michael L. JACKSON
  • Publication number: 20140162006
    Abstract: The invention relates to a method for producing a water-blown polyurethane/polyisocyanurate rigid foam material that can be sprayed, by reacting a mixture comprising an aromatic polyester polyol, a first, comparatively short-chain aliphatic polyether polyol, a second, comparatively long-chain aliphatic polyether polyol, an isocyanate component, a blowing agent having water at least as a main component, and a catalyst component. The invention further relates to a rigid foam produced according to the method according to the invention, a composite material composed of said rigid foam and a pipe, and to the use of such a composite material for transporting liquid or gaseous media.
    Type: Application
    Filed: July 16, 2012
    Publication date: June 12, 2014
    Applicant: Bayer Intellectual Property GmbH
    Inventors: Reinhard Albers, Patrick Klasen, Horst-Heinrich Schneider, Stephanie Vogel
  • Patent number: 8735460
    Abstract: The invention relates to a foamed isocyanate-based polymer derived from a reaction mixture comprising an isocyanate, an active hydrogen-containing compound, a blowing agent and a highly branched polysaccharide which is derivatized with at least two esters of different length. Further the invention relates to a mix and a process for the production of isocyanate-based polymer. The mix for the production of a foamed isocyanate-based polymer comprises a mixture of the derivatized polysaccharide of the invention and an active hydrogen-containing compound. The process for producing a foamed isocyanate-based polymer comprises the steps of: contacting an isocyanate, an active hydrogen-containing compound, the derivatized highly branched polysaccharide of the invention and a blowing agent to form a reaction mixture and expanding the reaction mixture to produce the foamed isocyanate-based polymer.
    Type: Grant
    Filed: January 9, 2009
    Date of Patent: May 27, 2014
    Assignee: Dupont Nutrition Bioscience APS
    Inventors: Kenneth Knoblock, Charles Nichols, James O'Connor
  • Patent number: 8686058
    Abstract: Embodiments of the present invention disclose viscoelastic foams having a renewable natural resource contents of between about 1 and about 25 wt % of the foam. The foams may have a ratio of elastic modulus (E?) at 20° C. to 25% compression force deflection (CFD) of 25 to 125.
    Type: Grant
    Filed: July 15, 2009
    Date of Patent: April 1, 2014
    Assignee: Dow Global Technologies LLC
    Inventors: Bernard E. Obi, Alan K. Schrock, Rogelio R. Gamboa, Asjad Shafi
  • Patent number: 8686057
    Abstract: Polyurethane polymers are made from a reaction mixture that contains a polyisocyanate, a hydroxylmethyl-containing fatty acid or ester, and another polyol, polyamine or aminoalcohol. The carboxylic acid or ester group on the hydroxymethyl-containing fatty acid or ester are capable of engaging in a variety of reactions with the polyisocyanate and/or amine or hydroxyl groups present in the reaction mixture. This allows for good quality, high molecular weight polymers to be produced even though the hydroxymethyl-containing fatty acid or ester tends to be a low functionality material.
    Type: Grant
    Filed: October 24, 2005
    Date of Patent: April 1, 2014
    Assignee: Dow Global Technologies LLC
    Inventors: Hanno R. Van der Wal, Camiel F. Bartelink
  • Patent number: 8673991
    Abstract: The two-part curable polyurethane foam resin composition uses little or no petroleum-derived raw materials but a plant-derived raw material so that the biomass ratio can be improved, the load on the environment can be reduced, and excellent physical characteristics can be exhibited. The two-part curable polyurethane foam resin composition includes a main agent that contains an isocyanate-terminated urethane prepolymer (A) and a curing agent that contains an isocyanate-reactive compound (B), water (C), and a catalyst (D), in which a polyol component used in (A) and (B) uses a castor oil polyol (b1) having 1.5 to 2.3 functional groups on average and a polyol (b2) prepared by addition polymerization of lactone to polytetramethylene glycol and/or polytetramethylene glycol (b3), the ratio (b1)/(b2) and/or (b3)=15/85 to 60/40 on a mass basis, and a content of the castor oil polyol (b1) is 10 to 45% by mass.
    Type: Grant
    Filed: March 22, 2011
    Date of Patent: March 18, 2014
    Assignee: DIC Corporation
    Inventors: Tomoaki Shinchi, Hiroshi Suzaki
  • Patent number: 8642670
    Abstract: The present invention relates to an open-cell polyurethane foam comprising polyester and polyether structures and having a density of 70 to 300 g/L, 1 to 20 cells/cm, a rebound intensity greater than 30%, an elongation at break of greater than 200%, a tear propagation resistance of greater than 1.2 N/mm and a tensile strength of greater than 200 kPa. The present invention further relates to a process for producing inventive open-cell polyurethane sponges and to the use thereof as a pipe cleaning sponge.
    Type: Grant
    Filed: March 13, 2009
    Date of Patent: February 4, 2014
    Assignee: BASF SE
    Inventors: Nils Mohmeyer, Ralf Fritz, Annika Habicht, Daniela Tepe, Frank Prissok, Michael Harms, Bernd Bruchmann, Daniel Schoenfelder, Daniel Freidank, Andreas Emge, Andrea Eisenhardt
  • Patent number: 8637584
    Abstract: An isocyanate reactive composition for making a polyurethane foam includes a tertiary amine urethane catalyst comprising a di(C1-C4)alkyl fatty alkyl amine and a polyester polyol. The use of one or more of fatty alkyl tertiary amine serves to reduce hydrolysis of the polyester polyol in the isocyanate reactive composition.
    Type: Grant
    Filed: May 25, 2007
    Date of Patent: January 28, 2014
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Gary Dale Andrew, Juan Jesus Burdeniuc, Goran Zarkov
  • Patent number: 8604093
    Abstract: A fire-resistant polyurethane foam is provided. A hydroxyl-containing inorganic fire retardant is premixed with a polyisocyanate and a polyol, respectively, to form two premixtures. Then, the two premixtures are mixed for reaction to form a fire-resistant polyurethane foam. Preferably, a combination of different particle sizes of the fire retardant is employed to maximize the amount of the fire retardant and increase the fire resistance of the foam.
    Type: Grant
    Filed: October 8, 2010
    Date of Patent: December 10, 2013
    Assignee: Industrial Technology Research Institute
    Inventors: Po-Ju Chen, Sung-Jeng Jong, Ren-Kuen Chang, Chin-Shang Hsu, Jer-Young Chen, Yih-Her Chang, Chei Kao
  • Patent number: 8598297
    Abstract: Prepolymers are prepared by a reaction of a polyisocyanate and a hydroxylmethyl containing polyester polyol derived from a fatty acid. The prepolymers can be prepared having isocyanate, hydroxyl, or a variety of other reactive functional groups. The prepolymers are useful in making polyurethanes and other polymers, or a crosslinking agents.
    Type: Grant
    Filed: October 24, 2005
    Date of Patent: December 3, 2013
    Assignee: Dow Global Technologies LLC
    Inventors: Erdem Bedri, Debkumar Bhattacharjee, John N. Argyropoulos
  • Publication number: 20130310477
    Abstract: The present invention is a polyol composition (A) for the production of polyurethane resins which comprises a compound (a1) having a vinyl-polymerizable functional group represented by general formula (I) and a strength improver (a2) represented by general formula (II). In general formula (I), R is hydrogen, C1-15 alkyl, or C6-21 aryl. In general formula (II), R1 is a residue derived from an active-hydrogen-containing compound by removing one active hydrogen atom; Y is a residue derived from an at least divalent aromatic polycarboxylic acid (f) by removing the carboxyl groups; a is an integer satisfying the relationship: 1?a?(the number of substituents on the aromatic ring?1); Z is a residue derived from an at least m-valent active-hydrogen-containing compound by removing the m active hydrogen atoms; and m is an integer of 1 to 10.
    Type: Application
    Filed: August 22, 2011
    Publication date: November 21, 2013
    Applicant: SANYO CHEMICAL INDUSTRIES, LTD.
    Inventors: Katsuya Uchida, Koji Kabu, Kei Sasaki, Tomohisa Hirano
  • Patent number: 8575226
    Abstract: A building material composite that includes a building substrate at least partially lined with a urethane material. The urethane material of the present invention is typically the reaction product of an A-side that includes an isocyanate and a B-side that typically includes: a blown vegetable oil, a cross-linking agent, and a catalyst; a blown vegetable oil and a multifunctional alcohol; or an esterified polyol and a catalyst where the esterified polyol is typically the reaction product of a first polyol and a blown vegetable oil.
    Type: Grant
    Filed: January 25, 2005
    Date of Patent: November 5, 2013
    Assignee: Rhino Linings Corporation
    Inventors: Thomas M. Kurth, Richard A. Kurth, Robert B. Turner, Les P. Kreifels
  • Publication number: 20130261204
    Abstract: A premix composition includes polyether polyol and a blowing agent, wherein the polyether polyol is a copolymer of propylene oxide and trimethylolpropane, a copolymer of propylene oxide, ethylene oxide and trimethylolpropane, a copolymer of propylene oxide, ethylene oxide and glycerol, or combinations thereof. A foaming composition which is obtained by mixing the premix composition with diisocyanate.
    Type: Application
    Filed: March 29, 2012
    Publication date: October 3, 2013
    Inventor: Chien-Chang CHEN
  • Publication number: 20130261205
    Abstract: The present invention relates to a process for the preparation of polyricinoleic acid ester polyols having primary hydroxyl end groups. It furthermore relates to polyricinoleic acid ester polyols obtainable according to the invention and polyurethane polymers prepared using these polyols. The process comprises the steps: a) polycondensation of ricinoleic acid until a hydroxyl number of >0 mg of KOH/g to <60 mg of KOH/g is reached; and b) reaction of the product obtained in step a) or of a secondary product of the product obtained in step a) comprising carboxyl groups with an epoxide of the general formula (I), wherein R1 represents hydrogen, an alkyl radical or an aryl radical, with the proviso that >80% by weight to <100% by weight, based on the total amount of the epoxide (I) employed, is ethylene oxide and the reaction is carried out in the presence of an amine as the catalyst.
    Type: Application
    Filed: November 18, 2011
    Publication date: October 3, 2013
    Applicant: Bater Intellectual Property GmbH
    Inventors: Hartmut Nefzger, Jörg Hofmann, Erika Bauer, Bert Klesczewski, Klaus Lorenz
  • Publication number: 20130251980
    Abstract: Embodiments of the invention provide for polyurethane or polyisocyanurate foam formulations. The formulations include a formulated polyol, a polyisocyanate, and a blowing agent such that the stoichiometric index of the polyisocyanate to the formulated polyol is above 250. The formulated polyol includes (i) from about 20 to about 60 percent by weight of an aromatic polyester polyol, (ii) from about 10 to about 30 percent by weight of a Novolac-type polyether polyol, and (iii) from about 5 to about 40 percent by weight of a polyether polyol including a sucrose- or sorbitol-initiated polyol. Components (i), (ii), and (iii) are selected so that the formulated polyol as a whole has an average functionality of at least about 2.4.
    Type: Application
    Filed: December 15, 2011
    Publication date: September 26, 2013
    Applicant: DOW GLOBAL TECHNOLOGIES LLC
    Inventors: Luigi Pellacani, Paolo Golini, Peter Keller
  • Publication number: 20130237624
    Abstract: The present invention relates to a method for producing flexible polyurethane foams, wherein a polyol component which comprises polyricinoleic acid esters is used as starting substance. The flexible polyurethane foams according to the invention have a bulk density according to DIN EN ISO 3386-1-98 in the range of ?10 kg/m3 to ?150 kg/m3, preferably ?20 kg/m3 to ?70 kg/m3, and in general their compressive strength according to DIN EN ISO 3386-1-98 is in the range of ?0.5 kPa to ?20 kPa (at 40% deformation and 4th cycle). The polyricinoleic acid esters are obtainable by the reaction of ricinoleic acid with an alcohol component which comprises mono- and/or polyhydric alcohols with a molecular mass of ?32 g/mol to ?400 g/mol, the reaction being carried out at least in part in the presence of a catalyst.
    Type: Application
    Filed: November 18, 2011
    Publication date: September 12, 2013
    Applicant: BAYER INTELLECTUAL PROPERTY GMBH
    Inventors: Bert Klesczewski, Gundolf Jacobs, Sven Meyer-Ahrens, Hartmut Nefzger
  • Patent number: 8530533
    Abstract: The present invention relates to a rigid polyurethane foam comprising reinforcing materials which can be obtained by mixing (a) isocyanates which have a viscosity at 25° C. of less than 500 mPas with (b) compounds having groups which are reactive toward isocyanates, (c) blowing agents comprising water, (d) catalysts and, if appropriate, (e) further additives to form a reaction mixture and applying the reaction mixture to a reinforcing material, wherein the compounds (b) having groups which are reactive toward isocyanates comprise a polyetherol (b1) having a functionality of 4 or more and a viscosity at 25° C. of 10 000 mPas or less and a polyetherol (b2) having a functionality of 3 or less and a viscosity at 25° C. of 500 mPas or less. The present invention further relates to a process for producing such rigid polyurethane foams and the use of the rigid polyurethane foams for the insulation of liquefied natural gas tanks.
    Type: Grant
    Filed: January 2, 2008
    Date of Patent: September 10, 2013
    Assignee: BASF SE
    Inventors: Pit Lehmann, Katrin Thane, Cheul Hyeon Hwang
  • Publication number: 20130197115
    Abstract: The present invention relates to a process for producing rigid polyurethane foams by reaction of a) at least one organic polyisocyanate with b) at least one polyol component in the presence of a blowing agent mixture comprising water and halogenated alkenes, wherein the amount of water is at least 1.40 mol/kg of polyol component b) and the amount of halogenated alkene is at most 2.00 mol/kg of polyol component b), and also to the use of such a blowing agent mixture for producing corresponding rigid polyurethane foams and for increasing the adherence and reducing the thermal conductivity of corresponding rigid polyurethane foams. The present invention further relates to a rigid polyurethane foam obtainable by the process of the present invention.
    Type: Application
    Filed: July 30, 2012
    Publication date: August 1, 2013
    Applicant: BASF SE
    Inventors: Christiane GIESKER, Markus Schuette, Patrick Lax, Jörg Krogmann
  • Publication number: 20130190419
    Abstract: Rigid polyurethane foams or rigid polyisocyanurate foams with low brittleness are produced by the reaction of polyisocyanate polyetherester polyols based on aromatic dicarboxylic acids obtained by esterification of a dicarboxylic acid composition containing aromatic dicarboxylic acids and aliphatic dicarboxylic acids, fatty acids, aliphatic or cycloaliphatic diols having 2 to 18 carbon atoms or alkoxylates thereof, and a polyether polyol having a functionality of not less than 2.
    Type: Application
    Filed: December 31, 2012
    Publication date: July 25, 2013
    Inventor: Gunnar KAMPF
  • Publication number: 20130184369
    Abstract: The present invention relates to a process for preparing rigid polyurethane foams or rigid polyisocyanurate foams by using certain polyetherester polyols B) based on aromatic dicarboxylic acids, optionally further polyester polyols C), which differ from those of component B), and polyether polyols D), wherein the mass ratio of total components B) and optionally C) to component D) is less than 1.6. The present invention also relates to the rigid foams thus obtainable and to their use for producing sandwich elements having rigid or flexible outer layers. The present invention further relates to the underlying polyol components.
    Type: Application
    Filed: January 14, 2013
    Publication date: July 18, 2013
    Inventor: Gunnar KAMPF
  • Patent number: 8476328
    Abstract: A method for manufacturing a polishing pad that has high level of optical detection accuracy and is prevented from causing slurry leak from between the polishing region and the light-transmitting region includes preparing a cell-dispersed urethane composition by a mechanical foaming method; placing a light-transmitting region at a predetermined position on a face material or a belt conveyor, continuously discharging the cell-dispersed urethane composition onto part of the face material or the belt conveyor where the light-transmitting region is not placed; placing another face material or belt conveyor on the discharged cell-dispersed urethane composition; curing the cell-dispersed urethane composition to form a polishing region including a polyurethane foam, so that a polishing sheet is prepared; applying a coating composition containing an aliphatic and/or alicyclic polyisocyanate to one side of the polishing sheet and curing the coating composition to form water-impermeable film; and cutting the polishing
    Type: Grant
    Filed: February 26, 2009
    Date of Patent: July 2, 2013
    Assignee: Toyo Tire & Rubber Co., Ltd
    Inventors: Junji Hirose, Takeshi Fukuda
  • Patent number: 8476329
    Abstract: A bioresin composition is used to form a rigid polyurethane article that includes a first and a second biopolyol and is substantially free of aprotic solvents that chemically decompose in the presence of water. The first biopolyol includes a natural oil component. The second biopolyol includes the reaction product of a natural carbohydrate and an alkylene oxide. The rigid polyurethane foam article includes the reaction product of the bioresin composition and an isocyanate which are reacted in the presence of a chemical blowing agent.
    Type: Grant
    Filed: June 9, 2010
    Date of Patent: July 2, 2013
    Assignee: BASF SE
    Inventors: Christopher M. Tanguay, Patrick J. Watters, John P. Erickson, Eric W. Banks
  • Publication number: 20130102697
    Abstract: The two-part curable polyurethane foam resin composition uses little or no petroleum-derived raw materials but a plant-derived raw material so that the biomass ratio can be improved, the load on the environment can be reduced, and excellent physical characteristics can be exhibited. The two-part curable polyurethane foam resin composition includes a main agent that contains an isocyanate-terminated urethane prepolymer (A) and a curing agent that contains an isocyanate-reactive compound (B), water (C), and a catalyst (D), in which a polyol component used in (A) and (B) uses a castor oil polyol (b1) having 1.5 to 2.3 functional groups on average and a polyol (b2) prepared by addition polymerization of lactone to polytetramethylene glycol and/or polytetramethylene glycol (b3), the ratio (b1)/(b2) and/or (b3)=15/85 to 60/40 on a mass basis, and a content of the castor oil polyol (b1) is 10 to 45% by mass.
    Type: Application
    Filed: March 22, 2011
    Publication date: April 25, 2013
    Applicant: DIC CORPORATION
    Inventors: Tomoaki Shinchi, Hiroshi Suzaki
  • Patent number: 8426482
    Abstract: Invention relates to a process for producing viscoelastic flexible polyurethane foams by reacting a) polyisocyanates with b) compounds having at least two hydrogen atoms which are reactive toward isocyanate groups, wherein as b) a mixture of bi) from 25 to 70% by weight of a hydroxyl-comprising natural oil or fat or a reaction product of a hydroxyl-comprising natural oil or fat with alkylene oxides, bii) from 3 to 30% by weight of at least one polyether having a hydroxyl number of from 100 to 800 mg KOH/g and a functionality of 3-5 selected from the group consisting of polyether prepared by addition of alkylene oxides onto an amine, biii) 20-50% by weight of at least one polyether alcohol having a hydroxyl number of from 10 to 80 mg KOH/g and a functionality of 2-5, where the proportion of ethylene oxide is 5-25% by weight, based on the weight of the polyether alcohol, and at least part of the ethylene oxide is added on at the end of the polyether chain, biv) >0-8% by weight of at least one polyether alcoh
    Type: Grant
    Filed: October 19, 2009
    Date of Patent: April 23, 2013
    Assignee: BASF SE
    Inventors: Ansgar Frericks, Heinz-Dieter Lutter, Edmund Stadler, Heinz-Juergen Schroeder, Kirsten Simon, Andre Meyer, Franck Pomeris
  • Patent number: 8399532
    Abstract: Embodiments of the disclosure include aromatic polyol compositions, resin blend compositions, and spray foam compositions.
    Type: Grant
    Filed: May 18, 2010
    Date of Patent: March 19, 2013
    Assignee: Invista North America S.A R.L.
    Inventor: David K. Mulkey
  • Patent number: 8318821
    Abstract: Provided is a process for producing a rigid foamed synthetic resin, wherein, as a blowing agent, a hydrocarbon compound and water are used, and a rigid foamed synthetic resin provided with dimensional stability, heat insulating properties, and possibly reduced weight can be obtained. The process involves reacting a polyol (P) with a polyisocyanate (I) in the presence of a blowing agent, a foam stabilizer and a catalyst, wherein the blowing agent has at least a C2-8 hydrocarbon compound and water; the polyol (P) has a specific polyesterpolyol (A), a specific polyetherpolyol (B), and a polymer-dispersed polyol (Z) having fine polymer particles (M) dispersed; and the isocyanate index of the polyol (P) and the polyisocyanate (I) is over 200 and at most 400.
    Type: Grant
    Filed: October 29, 2010
    Date of Patent: November 27, 2012
    Assignee: Asahi Glass Company, Limited
    Inventors: Yuko Hayashi, Hiroshi Wada
  • Patent number: 8318826
    Abstract: Polyether polyols are initiated with orthocyclohexanediamines such as 1,2-diaminocyclohexane. The polyols are useful in making rigid polyurethane foams, especially foams for pour-in-place applications, where they give a good combination of low k-factor and short demold times.
    Type: Grant
    Filed: January 30, 2008
    Date of Patent: November 27, 2012
    Assignee: Dow Global Technologies LLC
    Inventors: Timothy A. Morley, Francois M. Casati, Adrian J. Birch, David A. Babb, Charles A. Martin, II
  • Patent number: 8318822
    Abstract: It is an object of the invention to provide a vibration damping and sound absorbing material containing a plant-derived polyol which material largely contributes a decrease of environmental load and has excellent vibration damping and sound absorbing properties, and it is another object of the invention to provide a production process of the material. Specifically, disclosed is a vibration damping and sound absorbing material which is suitably used for cars. A vibration damping and sound absorbing material comprises a polyurethane foam which comprises, as raw materials, a polyol and/or a polymer-dispersed polyol in which polymer fine particles obtainable by polymerizing an unsaturated bond-containing compound are dispersed in a polyol, and water, a catalyst and a polyisocyanate, wherein the polyol comprises (A) a plant-derived polyol produced using a raw material obtainable by a plant.
    Type: Grant
    Filed: April 21, 2008
    Date of Patent: November 27, 2012
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Kazuto Usaka, Kouichi Sano, Hiroyuki Utsumi
  • Patent number: 8318827
    Abstract: The invention described herein relates to an essentially closed-cell two-component polyurethane foam containing an pesticide, which upon curing provides a barrier to insect infestation.
    Type: Grant
    Filed: March 27, 2009
    Date of Patent: November 27, 2012
    Assignee: Fomo Products, Inc.
    Inventor: Anthony J. Taylor
  • Patent number: 8293808
    Abstract: A flexible polyurethane foam prepared by reacting, in the presence of a blowing agent, a polyisocyanate with an active hydrogen-containing composition that includes a modified vegetable oil-based polyol. The foams exhibit good load-bearing properties, relatively high sag factors, and/or good color retention upon exposure to light.
    Type: Grant
    Filed: June 25, 2004
    Date of Patent: October 23, 2012
    Assignee: Cargill, Incorporated
    Inventors: Ron Herrington, Jeffrey Malsam
  • Patent number: 8288448
    Abstract: The polishing pad is suitable for planarizing at least one of semiconductor, optical and magnetic substrates. The polishing pad includes a cast polyurethane polymeric material formed with an isocyanate-terminated reaction product formed from a prepolymer reaction of a prepolymer polyol and a polyfunctional isocyanate. The isocyanate-terminated reaction product has 4.5 to 8.7 weight percent unreacted NCO; and the isocyanate-terminated reaction product is cured with a curative agent selected from the group comprising curative polyamines, curative polyols, curative alcoholamines and mixtures thereof. The polishing pad contains at least 0.1 volume percent filler or porosity.
    Type: Grant
    Filed: June 4, 2008
    Date of Patent: October 16, 2012
    Assignee: Rohm and Haas Electronic Materials CMP Holdings, Inc.
    Inventor: Mary Jo Kulp