Process Of Treating Scrap Or Waste Product Containing Solid Organic Polymer To Recover A Solid Polymer Therefrom Patents (Class 521/40)
  • Patent number: 8138233
    Abstract: In one embodiment, the invention relates to a two step process in which a 1,4-butane diol component reacts with a polyethylene terephthalate component under conditions that depolymerize the polyethylene terephthalate component into a molten mixture and the molten mixture is placed under subatmospheric conditions that produce the modified polybutylene terephthalate random copolymers. In another embodiment, the invention relates to a three step process in which a diol component selected from the group consisting of ethylene glycol, propylene glycol, and combinations thereof reacts with a polyethylene terephthalate component under conditions sufficient to depolymerize the polyethylene terephthalate component into a first molten mixture; and where the first molten mixture is combined with 1,4-butane diol under conditions that create a second molten mixture that is subsequently placed under subatmospheric conditions that produce the modified polybutylene terephthalate random copolymers.
    Type: Grant
    Filed: February 4, 2011
    Date of Patent: March 20, 2012
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Parminder Agarwal, Kristen Cohoon-Brister, Sandeep Dhawan, Robert Russell Gallucci, Ganesh Kannan, Kenneth Frederick Miller, Dhaval Shah
  • Publication number: 20120052255
    Abstract: A method of recycling plastic e-waste material and products made from recycled e-waste involves one or more separate streams of different plastic waste which are reduced to small granular form, blended together or separately or used separately before insertion into a compounder which reduces the small sized plastic particles to a semi-molten emulsion. The emulsion is placed in a press and molded to a final product shape. The final product is finished and inspected. The products from the recycled plastic e-waste can be used as substrates on road signs.
    Type: Application
    Filed: May 17, 2011
    Publication date: March 1, 2012
    Applicant: IMAGE MICROSYSTEM, INC.
    Inventors: Alex Abadi, Michael Terry McMullen, JR., Dan Michael Adams, Robert Gallagher
  • Patent number: 8119699
    Abstract: A method of recycling a laminate shaped product, including the steps of: breaking a shaped product having a laminate structure including at least one layer of aliphatic polyester resin in addition to a principal resin layer, storing resultant broken pieces in a moisturizing environment to adjust a moisture content of the aliphatic polyester resin (layer) to at least 0.5 wt. %, and then washing the broken pieces with alkaline water to remove the aliphatic polyester resin layer, thereby recovering the principal resin. As a result, it becomes possible to shorten an induction period in the alkaline water washing step that is a principal process step, thereby rationalizing the entire process.
    Type: Grant
    Filed: November 11, 2004
    Date of Patent: February 21, 2012
    Assignee: Kureha Corporation
    Inventors: Kazuyuki Yamane, Ryo Kato, Akiko Wakamatsu
  • Patent number: 8110609
    Abstract: The invention relates to a composition comprising a modified, random copolyetherester containing a modified, random polytrimethylene terephthalate copolymer block that is derived from a polyethylene terephthalate component selected from the group consisting of polyethylene terephthalate and polyethylene terephthalate copolymers and combinations thereof; and contains at least one residue derived from the polyethylene terephthalate component; and a polyalkylene oxide copolymer block that contains polyalkylene oxide and at least one residue derived from the polyethylene terephthalate component.
    Type: Grant
    Filed: August 9, 2010
    Date of Patent: February 7, 2012
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Michael Determan, Ganesh Kannan, Kenneth Frederick Miller, Dhaval Shah
  • Patent number: 8106103
    Abstract: A method for reformulating reclaimed, contaminated mixed waste plastics into useful articles wherein a plurality of batches of the mixed waste plastics are preprocessed to produce substantially homogeneous mixtures of a desired particle size range that are characterized according to their respective apparent densities, and are thereafter blended to produce a mixed plastic feed material having a color predetermined to be desirable for reprocessing into at least one of such useful articles.
    Type: Grant
    Filed: July 21, 2008
    Date of Patent: January 31, 2012
    Assignee: Advanced Environmental Recycling Technologies, Inc.
    Inventors: Joe G. Brooks, Christopher Lynn Becker
  • Patent number: 8106104
    Abstract: A method for reformulating reclaimed, contaminated mixed waste plastics into useful articles wherein a plurality of batches of the mixed waste plastics are preprocessed to produce substantially homogeneous mixtures of a desired particle size range that are characterized according to their respective apparent densities, and are thereafter blended to produce a mixed plastic feed material having a plastic content predetermined to be desirable for reprocessing into at least one of such useful articles.
    Type: Grant
    Filed: July 21, 2008
    Date of Patent: January 31, 2012
    Assignee: Advanced Environmental Recycling Technologies, Inc.
    Inventors: Joe G. Brooks, Christopher Lynn Becker
  • Patent number: 8101100
    Abstract: A method for reformulating reclaimed, contaminated mixed waste plastics into useful articles wherein a plurality of batches of the mixed waste plastics are preprocessed to produce substantially homogeneous mixtures of a desired particle size range that are characterized according to their respective apparent densities, and are thereafter blended to produce a mixed plastic feed material having a target density predetermined to be desirable for reprocessing into at least one of such useful articles.
    Type: Grant
    Filed: July 21, 2008
    Date of Patent: January 24, 2012
    Assignee: Advanced Environmental Recycling Technologies, Inc.
    Inventors: Joe G. Brooks, Christopher Lynn Becker
  • Publication number: 20120007284
    Abstract: A composite formulation consisting of agglomerated industrial/residential sewer sludge and recycled high density polyethylene (HDPE) and/or polypropylene (PP) materials. The recycled plastic materials act as a binder for the pozzolan industrial/residential sewer sludge. The composite formulation can be produced in a batching process wherein the sieved dried sewer sludge and the recycled plastic in appropriate small cut pieces is fed into a large plastic extruder, heated and extruded into specific structures. The formulation can also be compounded using a compression mold wherein sieved dry sewer sludge are added to heated chopped recycled plastics and heat mixed to produce pellets or directed into a compression mold to create a structural member of predetermined shape.
    Type: Application
    Filed: July 12, 2010
    Publication date: January 12, 2012
    Inventors: Darrel S. Nelson, James M. Oliver
  • Patent number: 8088834
    Abstract: The invention relates to a process for making modified polybutylene terephththalate random copolymers from a polyethylene terephthalate component. The invention relates to a three step process in which a diol component selected from the group consisting of ethylene glycol, propylene glycol, and combinations thereof reacts with a polyethylene terephthalate component under conditions sufficient to depolymerize the polyethylene terephthalate component into a first molten mixture; and where the first molten mixture is combined with 1,4-butanediol under conditions that create a second molten mixture that is subsequently placed under subatmospheric conditions that produce the modified polybutylene terephthalate random copolymers. The invention also relates to compositions made from the process.
    Type: Grant
    Filed: September 2, 2010
    Date of Patent: January 3, 2012
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Parminder Agarwal, Kristen Cohoon, Sandeep Kumar Dhawan, Robert Russell Galucci, Ganesh Kannan, Sr., Kenneth Frederick Miller, Deepak Ramaraju, Gomatam Raghavan Ravi, Dhaval Shah
  • Patent number: 8080191
    Abstract: A polymer blend has a base and blend components. The base and blend components could be a branched slow crystallizing PET and a faster crystallizing PET, respectively. The ratio of base and blend components result in a block copolymer, the melt processing time and branching or chain extender levels can be can be tailored to impart the polymer blend with sufficient melt strength and crystallization rates, such that it is slow enough during the blow molding process to produce a clear article and yet fast enough during the subsequent PET recycling process making it suitable for extrusion processes as well as for recycling. The combination of materials can be used to form monolayer or multilayer articles.
    Type: Grant
    Filed: October 19, 2007
    Date of Patent: December 20, 2011
    Assignee: PepsiCo, Inc.
    Inventors: Clarence Sequeira, Said Farha
  • Publication number: 20110306688
    Abstract: Embodiments of the present disclosure include methods of removing face fibers from a fibrous substrate, systems of removing face fibers from a fibrous substrate, and the like.
    Type: Application
    Filed: July 16, 2009
    Publication date: December 15, 2011
    Applicant: INVISTA NORTH AMERICA S.A.R.L.
    Inventors: Nirmal K. Agarwal, Preston Thomas Compton
  • Patent number: 8071656
    Abstract: The present invention provides energetically and economically efficient methods for separating polyamide polymer(s) from commingled materials. The methods generally involve precipitating a polyamide polymer dissolved in a solvent (e.g., formic acid) using dimethyl ether (DME) as an antisolvent. The methods comprise dissolving the polyamide polymer in a solvent that (i) selectively dissolves the polyamide polymer relative to the other materials and (ii) has a higher solubility for DME relative to the polyamide polymer; and then contacting the mixture of the solvent with the dissolved polyamide polymer with DME, thereby precipitating the polyamide polymer.
    Type: Grant
    Filed: March 3, 2009
    Date of Patent: December 6, 2011
    Assignee: DynaSep LLC
    Inventors: Brian J. Waibel, Hans Schonemann, Val Krukonis, David J. Lawrence, Joseph N. Caulfield
  • Publication number: 20110294909
    Abstract: The invention relates to a process for manufacturing composite material which contains fiber based and polymer based material, wherein the manufacture includes a preliminary treatment process to form a raw stock mixture. According to the invention, the preliminary treatment process includes a hot-cold mixing device which comprises at least a heating stage, and that raw stock, which contains lignin-free material, and a coupling agent are fed to the mixing device to form the raw stock mixture, and adhesion between fiber based and polymer based substances of the raw stock is ameliorated by the coupling agent.
    Type: Application
    Filed: January 29, 2010
    Publication date: December 1, 2011
    Applicant: UMP-Kymmene Corporation
    Inventors: Liisa Lehtinen, Piia Peltola, Risto Laaksonen
  • Patent number: 8066785
    Abstract: The present invention provides a process which utilizes biodiesel and other high boiling esters containing short alkyl groups to produce liquid fuels from waste material. The waste material is added to a solvent having a predetermined cycle starting solvent volume. An energy source is introduced into the solvent for a predetermined time at a predetermined temperature and pressure to form a non-grindable product. The energy source is removed and the product is cooled to a predetermined temperature to produce the fuel. The invention also encompasses the fuel formed by the process described.
    Type: Grant
    Filed: October 31, 2010
    Date of Patent: November 29, 2011
    Assignee: Recarbon Corp.
    Inventors: Howard Gonchar, Roman Bielski, Donald Keiper, Ken Battle
  • Publication number: 20110288188
    Abstract: A method of processing waste carpet or matting material to separate constituent materials thereof, includes optionally drying the material and then cooling the material to a temperature at which at least one constituent material therein is embrittled. A mechanical force is applied to the cooled material causing the embrittled constituent material to break into fragments. Optionally, the material from the previous step is dried. The material is then separated to separate the fragments of constituent material from other constituent material. The carpet material can be initially shredded into coarse pieces. The procedure may be repeated optionally with different temperatures to selectively embrittle and fragment different components and facilitate their separation.
    Type: Application
    Filed: November 6, 2009
    Publication date: November 24, 2011
    Inventor: Ian Walters
  • Patent number: 8048934
    Abstract: A composition for acrylic artificial stone, the composition including a (meth)acrylic monomer and an inorganic material. At least one of the (meth)acrylic monomer and the inorganic material may be contained in a component generated by decomposing a polymeric (meth)acrylic resin.
    Type: Grant
    Filed: October 8, 2008
    Date of Patent: November 1, 2011
    Assignee: Cheil Industries, Inc.
    Inventors: Myeong Cheon Jeon, Hyeong Gyu Ahn, Jong Gap Kim, Hae Mun Jung, Seung Hwa Jeong, Bang Jun Park
  • Patent number: 8044107
    Abstract: A method of producing an embedded recycled container sheet includes: (a) providing a plurality of empty recycled plastic containers; (b) flattening the plurality of empty recycled plastic containers to reduce their width by at least 80%; (c) providing a base substrate of plastic; (d) placing the plurality of flattened, empty recycled plastic containers on the base substrate; and, (e) applying a molten top layer of plastic on the plurality of flattened, empty recycled plastic containers and on the base substrate, and cooling the molten top layer, so as to embed the plurality of empty recycled plastic containers between the top layer and the base substrate. A method of producing product from the resulting sheet involves creating the product using a processing step selected from the group consisting of molding, casting, cutting, machining, and combinations of these.
    Type: Grant
    Filed: June 22, 2009
    Date of Patent: October 25, 2011
    Assignee: Bgreen Innovations Inc
    Inventor: Kenneth P. Glynn
  • Publication number: 20110257279
    Abstract: The invention is directed to a method for recycling an organic-matrix composite material. The organic-matrix composite material comprises a first component comprising at least one organic matrix polymer and at least one solid second component being compatible with said first component and being structurally different from said first component, wherein said at least one organic polymer has thermosetting properties at room temperature and wherein said polymer comprises thermally reversible cross-links The method of the invention comprises -heating the organic-matrix composite material to a temperature at which at least part of the thermally reversible cross-links cleave and at which temperature the first component as a viscosity of at most 500 Pa·s, as measured by oscillatory measurements on an Anton Paar MCR 301 rheometer using parallel plate geometry; and -separating the at least part of said first component from said second component.
    Type: Application
    Filed: October 13, 2009
    Publication date: October 20, 2011
    Applicant: Nederlandse Organisatie voor toegepast-natuurwete- nschappelijk onnderzoek TNO
    Inventors: Maria Elizabeth Louise Wouters, Rudolf Hartmut Fischer
  • Patent number: 8030364
    Abstract: The present invention relates to a preparing method of polyols, polyurethane and polyurethane foams using the same. Polyester, polyamide and polyurethane are depolymerized with the polymeric fatty acid mono(polyhydroxyl alcohol)ide composition and additionally reacted with the polybasic acid, polyol and amine to prepare acid value of 05-˜1 mgKOH/g, hydroxyl value of 10˜500 mgKOH/g, and amine value of 1˜50 mgKOH/g in polyol. This is to transform the double bond of the unsaturated fatty acid from the component of the oils and fats into a conjugated double bond to induce the Diels-Alder reaction, and with the improvement of the reactivity to form a stable combination in the chemical structure to prevent the separate leaching appearance of fat and fatty oil from the final product. In particular, by recycling waste edible oil and waste synthetic resin that can be employed as industrially useful material, the invention provides environment advantages.
    Type: Grant
    Filed: October 10, 2005
    Date of Patent: October 4, 2011
    Inventors: Do Gyun Kim, Hyosung Kim
  • Patent number: 8017662
    Abstract: A process for producing a synthetic fiber composition with reclaimed post consumer carpet yarn, wherein face yarn is shaved from post consumer carpet using a shaving device to provide shaved face yarn, the shaved face yarn is reduced in size, contaminants are removed using mechanical screeners, the shave face yarn is melt filtered, and then fiber spun.
    Type: Grant
    Filed: May 29, 2008
    Date of Patent: September 13, 2011
    Assignee: Universal Fibers, Inc.
    Inventors: George Taylor Hoover, Jr., Milton Keith Roark, Brendan Francis McSheehy, Jr., Matthew Benjamin Studholme
  • Patent number: 8013028
    Abstract: An embedded recycled container sheet binder includes a front cover and a back cover, the front cover and the back cover being connected to one another for opening and closing, at least one of the front cover and the back cover being, at least in part, a plurality of flattened recycled containers embedded in a plastic base, and each of the plurality of flattened recycled containers being visibly recognizable. The plurality of flattened recycled containers is preferably embedded between a base substrate of plastic and a top layer of plastic. The base substrate is a recycled plastic base substrate selected from the group consisting of clear plastic, opaque plastic, colored plastic and combinations thereof. In some preferred embodiments, the embedded recycled container sheet binder the top layer is a recycled plastic selected from the group consisting of clear plastic, opaque plastic and combinations thereof.
    Type: Grant
    Filed: August 31, 2009
    Date of Patent: September 6, 2011
    Assignee: B Green Innovations, Inc.
    Inventor: Kenneth P. Glynn
  • Patent number: 8013027
    Abstract: A basket is made from embedded recycled container sheet. The basket includes: a side wall and a bottom, the side wall and the bottom being connected to one another in the shape of a basket with an open top, the side wall being, at least in part, a plurality of flattened recycled containers embedded therein, and each of the plurality of flattened recycled containers being visibly recognizable. In some embodiments, the basket also includes a hanging mechanism attached to at least one of the side wall and the bottom. The side wall has a footprint that may be circular, conical, oval, square, rectangular, polygonal or irregular.
    Type: Grant
    Filed: August 31, 2009
    Date of Patent: September 6, 2011
    Assignee: B Green Innovations, Inc.
    Inventor: Kenneth P. Glynn
  • Publication number: 20110207837
    Abstract: A method for re-mobilizing superabsorbent polymer particles which have previously been immobilized by a solidified thermoplastic composition comprising at least 30 weight-% of a thermoplastic polymer. The superabsorbent polymer particles are separated from the solidified thermoplastic composition by using a supercritical fluid comprising carbon dioxide, propane, or mixtures thereof. Separation may be further improved by the use of one or more co-solvents.
    Type: Application
    Filed: February 25, 2011
    Publication date: August 25, 2011
    Applicant: The Procter & Gamble Company
    Inventors: Carsten Luckert, Marion Michnacs, Carsten Zetzl
  • Publication number: 20110207838
    Abstract: Disclosed is a thermoplastic resin composition including a) 50 to 92 weight percent of a recycled thermoplastic, wherein said recycled thermoplastic includes at least 60 weight percent of a recycled polyamide selected from the group consisting of polyamide 66, polyamide 6, and copolymers having repeat units of polyamide 66 and polyamide 6; and 8 to 30 weight percent of polymer toughener, wherein said polymer toughener comprises at least one acid polymer toughener(s) wherein said polymer toughener has an averaged calculated acid number of about 10 to about 90 mg KOH/g before blending into said thermoplastic composition.
    Type: Application
    Filed: February 21, 2011
    Publication date: August 25, 2011
    Applicant: E.I. DU PONT DE NEMOURS AND COMPANY
    Inventor: Avelino F. Lima
  • Publication number: 20110208146
    Abstract: The present invention relates to absorbent cores comprising recycled superabsorbent polymer particles which have previously been immobilized by a solidified thermoplastic composition. The superabsorbent polymer particles can be separated from the solidified thermoplastic composition by using a supercritical fluid such as carbon dioxide, propane or mixtures thereof.
    Type: Application
    Filed: February 25, 2011
    Publication date: August 25, 2011
    Applicant: The Procter & Gamble Company
    Inventors: Marion Michnacs, Carsten Luckert, Carsten Zetzl
  • Patent number: 7999012
    Abstract: Disclosed is a system to mechanically destroy printer toner cartridges and reclaim their constituent materials under a water shielded environment while providing a safer and more environmentally friendly recycling system. The present invention is an economical system that provides greater protection from possible fire or explosion and releases less irritating or possibly harmful airborne contamination than the currently available systems.
    Type: Grant
    Filed: October 20, 2008
    Date of Patent: August 16, 2011
    Inventors: Lacee Lamphere, Brian Ibarra, Donald Laffler, James Hardin
  • Patent number: 7993550
    Abstract: A method of recycling spent filter media is disclosed. The method can include providing a cloth, the cloth being spent polymer-base filter media, removing foreign solid particles from the cloth, washing the cloth, drying the cloth and processing the dried cloth to produce polymer-base particles that can be used to produce a component. The processing of the dried cloth can include densifying and/or granulating the dried cloth. In addition, the spent cloth can have been used as metal working filtration media and the foreign solid particles removed from the cloth using a brush. In some instances, the cloth is washed using a dry cleaning process and the granulating or densifying of the cloth produces particles that can be used in an injection molding machine.
    Type: Grant
    Filed: October 24, 2008
    Date of Patent: August 9, 2011
    Inventors: Dan Chrzanowski, Brandon Chrzanowski
  • Publication number: 20110184077
    Abstract: The present invention is a method for decomposing a polymer material by chemically decomposing a polymer material containing a first monomer and a second monomer in a mixture of the polymer material with the first monomer or a derivative of the first monomer to produce a chemical raw material. A relationship between a proportion of number of molecules of the second monomer to number of molecules of the first monomer in a reaction system for decomposing the polymer material and the molecular weight of the chemical raw material produced in the reaction system is acquired in advance (S101). Subsequently, an addition mount of the derivative of the first monomer to be added to the polymer material is determined based on the above relationship (S102). The first monomer in the addition amount determined is then mixed with the polymer material (S103).
    Type: Application
    Filed: September 9, 2009
    Publication date: July 28, 2011
    Applicant: SUMITOMO BAKELITE CO., LTD
    Inventors: Junya Goto, Masaki Ishikawa, Tamotsu Orihara, Taichi Koide
  • Patent number: 7985778
    Abstract: Synthetic resin containing ester bond is subjected to hydrolysis treatment to reclaim raw material component before polymerization. Method for decomposing and reclaiming synthetic resin having ester bond in composition structure thereof, by conducting hydrolysis treatment and then separation collection treatment. In the hydrolysis treatment, article containing synthetic resin to be decomposed and reclaimed is exposed to water vapor atmosphere filled under saturation water vapor pressure at treatment temperature at or below melting point of the synthetic resin. The synthetic resin in article to be treated is hydrolyzed by water vapor generated at the treatment temperature, to generate decomposition product before polymerizing to the synthetic resin containing an ester bond. The separation collection treatment is treatment in which the decomposition product generated by the hydrolysis treatment is separated into liquid component and solid component to be collected individually.
    Type: Grant
    Filed: March 6, 2007
    Date of Patent: July 26, 2011
    Inventor: Koichi Nakamura
  • Patent number: 7981941
    Abstract: A method for reprocessing used PET bottles having the step of shredding the bottles to form plastic flakes, sorting the plastic flakes according to at least one criterion into at least two partial quantities, and performing an individual processing treatment including a decontamination treatment. The device permits performing the method whereby it is possible to separate the plastic flakes produced from the threaded part of a PET bottle, these flakes being more difficult to purify, from the lighter plastic flakes from the wall of the bottle, which have a thin wall and are easier to purify, and treating them further in separate reprocessing steps.
    Type: Grant
    Filed: February 4, 2011
    Date of Patent: July 19, 2011
    Assignee: Krones AG
    Inventors: Thomas Friedlaender, Maren Hofferbert, Timm Kirchhoff
  • Patent number: 7981940
    Abstract: Provided is a method of treating a sealing compound, in order to recover from the inside of a pneumatic tire the sealing compound that was used for repairing a puncture, the sealing compound including an aqueous solution having at least rubber latex dispersed therein, the method comprising: solid-liquid separating, by injecting a treating agent into the inside of a pneumatic tire into which the sealing compound was injected, the treating agent comprising at least one of a salt that is a reaction compound of an acid and a base and/or a water-soluble organic solvent, mixing the treating agent with the sealing compound inside the pneumatic tire, and aggregating and solidifying the rubber latex in the sealing compound.
    Type: Grant
    Filed: May 26, 2005
    Date of Patent: July 19, 2011
    Assignee: Bridgestone Corporation
    Inventors: Shinichi Iwasaki, Rieko Iwasaki, legal representative, Ryuji Izumoto, Daisuke Sugio
  • Patent number: 7973092
    Abstract: A method for reprocessing used PET bottles having the steps of shredding the bottles to form plastic flakes, sorting the plastic flakes according to at least one criterion into at least two partial quantities, and performing an individual processing treatment including a decontamination treatment. The device permits performing the method whereby it is possible to separate the plastic flakes produced from the threaded part of a PET bottle, these flakes being more difficult to purify, from the lighter plastic flakes from the wall of the bottle, which have a thin wall and are easier to purify, and treating them further in separate reprocessing steps.
    Type: Grant
    Filed: October 9, 2004
    Date of Patent: July 5, 2011
    Assignee: Krones AG
    Inventors: Thomas Friedlaender, Maren Hofferbert, Timm Kirchhoff
  • Patent number: 7968022
    Abstract: A method for reformulating reclaimed, contaminated mixed waste plastics into useful articles wherein a plurality of batches of the mixed waste plastics are preprocessed to produce substantially homogeneous mixtures of a desired particle size range that are characterized according to their respective apparent densities, and are thereafter blended to produce a mixed plastic feed material having a rheology predetermined to be desirable for reprocessing into at least one of such useful articles.
    Type: Grant
    Filed: July 21, 2008
    Date of Patent: June 28, 2011
    Assignee: Advanced Environmental Recycling Technologies, Inc.
    Inventors: Joe G. Brooks, Christopher Lynn Becker
  • Patent number: 7964675
    Abstract: A thermoplastic composition comprising recovered poly(arylene ether), less than or equal to 0.1 weight percent based on the total weight of the thermoplastic composition of a second recovered thermoplastic that gives off greater than or equal to 10 percent by mass of volatiles at a processing temperature for the thermoplastic composition; 0.025 to 4.0 weight percent, based on the total weight of the thermoplastic composition, of a third recovered thermoplastic selected from the group consisting of polyolefin, acrylonitrile-butadiene-styrene, polycarbonate, polycarbonate/acrylonitrile-butadiene-styrene blend, polymethyl methacrylate, polyamide, polyester, polycarbonate/polyester blend and combinations of two or more of the foregoing third recovered thermoplastics, wherein combinations of two or more of the foregoing third recovered thermoplastics are present in an amount of less than or equal to 10 weight percent, based on the total weight of the thermoplastic composition; and an optional virgin thermoplastic.
    Type: Grant
    Filed: January 10, 2005
    Date of Patent: June 21, 2011
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Allen Wai-Yee Ko, Michael L. Todt
  • Patent number: 7959890
    Abstract: The invention relates to recycled rubber produced by a process comprising the steps of: a) shredding cleaned rubber tires into shreds less than 2? long; b) pyrolyzing the shreds in a reaction chamber of a thermal processor in a first anaerobic environment to produce a char; c) drawing off volatile organics from the reaction chamber; c) removing the char from the reaction chamber; d) cooling the char in a second anaerobic environment; e) removing metal and textile components from the char to obtain pyrolytic carbon black; f) milling and sizing the pyrolytic carbon black so obtained into particles of 325 mesh size or smaller; and, g) utilizing the pyrolytic carbon black from the previous step in a polymerization process that produces said recycled rubber. It also relates to the high quality pyrolytic carbon black recovered from this process.
    Type: Grant
    Filed: February 1, 2010
    Date of Patent: June 14, 2011
    Assignee: RIPP Resource Recovery Corporation
    Inventors: Andrew D. E. MacIntosh, Vincent W. Y. Wong
  • Patent number: 7947749
    Abstract: A system to recycle plastics, which enables a supply of recycled plastics having a stable quality required for the recycled products. A system to recycle a used plastic material as a resin material including (a) means to sort used plastic materials for the purpose of recycling said used plastic materials, (b) means to crush and melt said used plastic material after it has been sorted, (c) reviving means to regain a desired property, and (d) means to measure a physical property of a reclaimed plastic after it has been revived and to indicate said measured physical property for quality assurance.
    Type: Grant
    Filed: November 5, 2008
    Date of Patent: May 24, 2011
    Assignee: Sony Corporation
    Inventors: Daisuke Hasegawa, Yasuhito Inagaki, Haruo Watanabe, Masahiro Sawaguchi
  • Patent number: 7943676
    Abstract: A method of recycling waste plastic foam materials firstly is to smash a waste material including polyurethane foam into fine particles so as to obtain a first starting material. The first starting material is then crisped and followingly milled into powder so as to obtain a second starting material. The second starting material is then placed into a mixer to mix with a first foaming reaction solution including polyol, catalyst and additives injected into the mixer so as to form a semi-treated foaming material. And then, the semi-treated foaming material is mixed with a second foaming reaction solution including diisocyanate injected into the mixer so as to obtain a completed-treated foaming material. Lastly, the completed-treated foaming material is poured into a mold and then water vapor is uniformly introduced into the mold so as to induce the completed-treated foaming material to proceed foaming reaction.
    Type: Grant
    Filed: February 7, 2008
    Date of Patent: May 17, 2011
    Inventor: Kun-Huang Chang
  • Publication number: 20110105632
    Abstract: Methods and systems for processing waste materials and for manufacturing composite materials are disclosed herein. According to some embodiments, the heterogeneous waste includes a plastic component and a non-plastic component, and the non-plastic component includes a plurality of pieces of waste. The heterogeneous waste is heated to melt at least a portion of said plastic component and reducing a volume of said heterogeneous waste, and then mixed (e.g. by rotating a mixing chamber or by stirring) until at least some said pieces are each encapsulated by the melted plastic component. Upon cooling, the mixture optionally sets into a composite material. The presently disclosed invention does not require pre-sorting of the heterogeneous waste and is operative to process “as is” waste. Optionally, the waste is pre-sorted.
    Type: Application
    Filed: October 28, 2010
    Publication date: May 5, 2011
    Inventors: Amit Azulay, Yuval I. Tamir
  • Patent number: 7935736
    Abstract: The invention relates to a method for recycling polyesters or polyester mixtures from polyester-containing waste, in which the polyester or the polyester mixture is dissolved in a solvent and subsequently free-flowing particles are precipitated herefrom with a precipitant. The precipitant is thereby chosen such that subsequent separation of precipitant and solvent is made possible in a simple manner.
    Type: Grant
    Filed: April 13, 2005
    Date of Patent: May 3, 2011
    Assignee: Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V.
    Inventors: Andreas Mäurer, Udo Knauf, Gerd Wolz, Michael Frankl, Otto Beck
  • Patent number: 7935783
    Abstract: A method and apparatus for processing polystyrene. The method includes the steps: using at least one scrapped surface heat exchanger (160) to heat a solution of polystyrene dissolved in an organic solvent to provide a heated solution of polystyrene dissolved in the organic solvent, and separating the dissolved polystyrene from the organic solvent. The apparatus includes: a holding tank at least partly filled with a solution of polystyrene dissolved in an organic solvent, at least one scrapped surface heat exchanger (160), and a separator.
    Type: Grant
    Filed: January 23, 2010
    Date of Patent: May 3, 2011
    Inventor: Joseph Douglas Sanders
  • Patent number: 7935737
    Abstract: Compositions of matter including articles derived from (a) from 5 to 99.99 wt % of a modified polybutylene terephthalate random copolymer that (1) is derived from polyethylene terephthalate and (2) contains a at least one residue derived from polyethylene terephthalate selected from the group consisting of antimony, germanium, diethylene glycol groups, isophthalic acid groups, cis isomer of cyclohexane dimethanol, trans isomer of cyclohexane dimethanol, sodium benzoate, alkali salts, napthalane dicarboxylic acids, 1,3-propane diols, cobalt, cobalt-containing compounds, and combinations thereof, and (b) from 0.01 to 95 wt. % of a member selected from the group consisting of (1) fillers, (2) a carboxy reactive component, (3) polyethyelene terephthalate, (4) a component including a polycarbonate and an impact modifier. The articles may be derived from various conversion processes, e.g., injection molding processes, extrusion processes, thermoforming processes, melt-blown process.
    Type: Grant
    Filed: January 29, 2007
    Date of Patent: May 3, 2011
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Vikram Gopal, Ganesh Kannan, Kenneth Frederick Miller, Dhaval Shah
  • Publication number: 20110083361
    Abstract: A method for processing paint overspray from an emulsion chemistry process which includes collecting the paint overspray in an aqueous medium, subjecting the paint overspray to a chemical treatment to form an aqueous suspension or emulsion of paint overspray solids having a first solids content and processing the aqueous suspension or emulsion of paint overspray solids to form: i) a light phase that has a second solids content that is lower than the first solids content; and ii) a heavy phase that has a third solids content that is higher than the first solids content. The light phase is recycled back into the process together with dispersion chemistry contained therein and the heavy phase can be used as a coating composition or as a combustible fuel or fuel additive.
    Type: Application
    Filed: October 14, 2010
    Publication date: April 14, 2011
    Applicant: Abednego Enviornmental Services, LLC
    Inventors: Paul Sikora, Christopher Hubb, Joe McCarty
  • Publication number: 20110071230
    Abstract: Methods of reclaiming plastic from plastic medical waste containers containing medical waste and manufacturing recycled medical devices are described. Recycled medical devices made from plastic medical waste containers containing medical waste are also described.
    Type: Application
    Filed: September 18, 2009
    Publication date: March 24, 2011
    Applicant: Becton, Dickinson and Company
    Inventor: Richard Ji
  • Patent number: 7910688
    Abstract: A process is described for recycling superabsorbent polymer fines into a process that includes treating the superabsorbent polymer fines with caustic and a polymerization step for making the superabsorbent polymer gel. The process requires treating the superabsorbent polymer fines with a caustic, followed by mixture with polymerizable monomer solution, and polymerizing the mixture of the superabsorbent polymer fines and monomer to form the aqueous fluid absorbent polymer. In the process, the fines are incorporated into the new polymer gel and become indistinguishable there from. The gel may then be comminuted into a particulate dried and then separated into a portion having a desired minimum particle size in a fines portion having less than the desired size. The particulate may then be coated with a surface crosslinking agent and surface additives and heated for surface conversion.
    Type: Grant
    Filed: October 22, 2008
    Date of Patent: March 22, 2011
    Assignee: Evonik Stockhausen Inc.
    Inventors: Gonglu Tian, Scott J. Smith, Janet Pate-Linton
  • Patent number: 7902262
    Abstract: The present invention relates to the recycling of waste electrical and electronic equipment (WEEE). Preferably, the present invention relates to the substantial recycling of all material forming the WEEE, thus providing substantially zero landfill. In yet another form, the invention relates to an additive and/or method of providing an additive. In still another form, the invention relates to recycling ink, toner, and/or PU foam from imaging consumables, forming part of the WEEE. In another form, the invention relates to the recycling of plastic materials containing flame retardants, including the recycling of plastics materials, such as plastics materials containing brominated flame retardants generally based on styrenics (e.g. PS, HIPS, ABS, PPO/PS, PPE/PS, ABS/PC) and polyamides (Nylon 6, nylon 6,6, nylon 12) and other engineering plastics such as polyacetal, polycarbonate, PET, PBT, liquid crystal polymers.
    Type: Grant
    Filed: June 15, 2005
    Date of Patent: March 8, 2011
    Assignee: Close the Loop Technologies Pty Ltd.
    Inventors: William Terence Armstrong, Stephen Michael Morriss, Glen Wilkie, John Scheirs
  • Patent number: 7902264
    Abstract: A composition comprising a polytrimethylene terephthalate random copolymer that (1) is derived from polyethylene terephthalate component selected from the group consisting of polyethylene terephthalate and polyethylene terephthalate copolymers and (2) contains at least one residue derived from the polyethylene terephthalate component. Methods for making such copolymers and articles made from such copolymers.
    Type: Grant
    Filed: December 27, 2006
    Date of Patent: March 8, 2011
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Michael Determan, Dhaval Shah
  • Patent number: 7902263
    Abstract: The invention relates to a process for making modified polybutylene terephthalate random copolymers from a polyethylene terephthalate component. In one embodiment, the invention relates to a two step process in which a 1,4-butane diol component reacts with a polyethylene terephthalate component under conditions that depolymerize the polyethylene terephthalate component into a molten mixture and the molten mixture is placed under subatmospheric conditions that produce the modified polybutylene terephthalate random copolymers.
    Type: Grant
    Filed: January 24, 2007
    Date of Patent: March 8, 2011
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Parminder Agarwal, Kristen Cohoon, Sandeep Dhawan, Robert Russell Gallucci, Ganesh Kannan, Kenneth Frederick Miller, Dhaval Shah
  • Patent number: 7897651
    Abstract: A method for rapidly depolymerizing a polyester and an unsaturated polyester by irradiating the polyester with microwaves in the presence of an alkylene glycol in which a titanium oxide fine powder having a bulk density of not more than 0.3 g/cm3 has been dispersed. Another embodiment comprises irradiating a polyester or an unsaturated polyester with microwaves in the presence of a monohydric alcohol or polyhydric alcohol containing an alkali metal and/or an alkaline earth metal. As a result, raw materials of a polyester, an unsaturated polyester or a polyurethane, such as an alkylene glycol and an unsaturated dibasic acid, can be recovered efficiently.
    Type: Grant
    Filed: September 29, 2006
    Date of Patent: March 1, 2011
    Inventor: Kazutoshi Ikenaga
  • Publication number: 20110046248
    Abstract: In a method and equipment for conditioning low-metal scrap high in plastics, which contains at least partially scrap high in plastics from shredder processes, especially of scrap vehicles, the method includes: splitting up ferromagnetic components from the scrap that is high in plastics; separating a first raw sand fraction from the scrap high in plastics that has been reduced in metals; reducing in size the fraction high in plastics that remains after the isolation of the first raw sand fraction; separating a second raw sand fraction after reducing in size the remaining fraction high in plastics; and splitting up the remaining fraction, that is high in plastics, into a light fraction and a heavy fraction. The equipment has the appropriate device for carrying out the individual method steps.
    Type: Application
    Filed: March 18, 2008
    Publication date: February 24, 2011
    Inventors: Bram den Dunnen, Michael Knust, Heiner Guschall
  • Patent number: 7893122
    Abstract: The present invention relates to a process for chemical recycling of PET waste that comprises, among other stages, a saponification reaction stage, wherein PET waste particles are reacted with stoichiometric or excessive amounts of a strong base metal in an alcoholic reaction media, the reaction being brought to the boiling temperature of the alcoholic reaction media, preferably at atmospheric pressure, thereby obtaining as reaction products a salt of terephthalic acid with the base metal and ethylene glycol, the latter being incorporated to the alcoholic reaction media. From this reaction it is possible to afford ethylene glycol, terephthalic acid and salts thereof, which are products with a high commercial value.
    Type: Grant
    Filed: January 27, 2004
    Date of Patent: February 22, 2011
    Inventors: Arturo Guadalupe Fregoso-Infante, Roxana Vega-Rangel, Maricruz Figueroa-Gomez-Crespo