Latex, Dispersion, Or Emulsion Contains Two Or More Solid Polymers Patents (Class 521/70)
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Patent number: 5356683Abstract: An expandable aqueous coating composition includes a polymeric binder including latex particles wherein the latex particles include a copolymer having a glass transition temperature of about -20.degree. C. to about +60.degree. C. and a weight average molecular weight of about 20,000 to about 500,000 and including expandable particles having a liquid blowing agent contained within a thermoplastic shell.Type: GrantFiled: October 28, 1993Date of Patent: October 18, 1994Assignee: Rohm and Haas CompanyInventors: Scott L. Egolf, Reginald T. Smart
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Patent number: 5124363Abstract: A method of treating hazardous material or other substrate with an aqueous air foam, comprising the steps of (1) preparing an aqueous solution or dispersion comprising (a) water-soluble polyhydroxy polymer having a plurality of hydrogen-bondable 1,2- and/or 1,3-diol structures capable of complexation with the borate anion, B(OH).sub.4.sup.Type: GrantFiled: March 26, 1991Date of Patent: June 23, 1992Assignee: Minnesota Mining and Manufacturing CompanyInventor: Richard M. Stern
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Patent number: 5106881Abstract: A water base pigment ink composition for use in marking pens which contain an absorbent ink reservoir and a pen tip connected thereto, the ink composition comprising:(a) water in amounts of not less than 50% by weight;(b) an aqueous emulsion of hollow resin particles in amounts of 0.5-40% by weight as solids;(c) a white pigement in amounts of 1-40% by weight; and(d) a water-solubilized .alpha.-methylstyrene/styrene/acrylic acid copolymer which has a weight average molecular weight of 1000-10000 and a distribution of molecular weight of 0.5-3.3, but which contains substantially no components having a weight average molecular weight of not more than 500, in amounts of 0.1-30% by weight, based on the ink compositions, respectively.The ink composition may contain chromatic or achromatic (other than white) pigments in amounts of 0.1-30% by weight based on the ink composition.Type: GrantFiled: March 11, 1991Date of Patent: April 21, 1992Assignee: Sakura Color Products Corp.Inventors: Hiroshi Inoue, Wataru Yokono, Yasuji Okuda
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Patent number: 5093374Abstract: Expandable molding compositions having high heat distortion resistance and containing from 80 to 99% by weight of a styrene polymer, 1 to 20% by weight of poly-1,4-phenylene sulfide, from 1 to 10% by weight of a C.sub.3 -C.sub.6 -hydrocarbon as blowing agent and, if desired, customary additives, are obtained by suspension polymerization of a solution of the polyphenylene sulfide in styrene.Type: GrantFiled: June 28, 1990Date of Patent: March 3, 1992Assignee: BASF AktiengesellschaftInventors: Klaus Hahn, Uwe Guhr, Hans Hintz, Dietmar Wittenberg
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Patent number: 5059629Abstract: A biocidal foam product comprising a foam having incorporated therein a water insoluble thermoplastic copolymer consisting of an alpha olefin and an alpha, beta-ethylenically unsaturated carboxylic acid, said copolymer having at least one biocidal agent ionically bonded to said copolymer.Type: GrantFiled: March 25, 1991Date of Patent: October 22, 1991Assignee: The Dow Chemical CompanyInventors: Robert T. Patton, Walter L. Vaughn, Thomas J. McKeand, Jr.
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Patent number: 5026735Abstract: A method of treating hazardous material or other substrate with an aqueous air foam, comprising the steps of (1) preparing an aqueous solution or dispersion comprising (a) water-soluble polyhydroxy polymer having a plurality of hydrogen-bondable 1,2- and/or 1,3-diol structures capable of complexation with the borate anion, B(OH).sub.4.sup.Type: GrantFiled: June 12, 1990Date of Patent: June 25, 1991Assignee: Minnesota Mining and Manufacturing CompanyInventor: Richard M. Stern
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Patent number: 5011864Abstract: A water absorbent latex polymer foam produced by the process of combining a foamed latex polymer product with both a water absorbent polymer and chitin and drying that blend to form a foamable latex polymer containing both water absorbent polymer and chitin. The latex foams produced by this process are of great use, for example, with wound or surgical dressings.Type: GrantFiled: June 4, 1990Date of Patent: April 30, 1991Assignee: Hoechst Celanese Corp.Inventors: Steven F. Nielsen, Dai W. Kim
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Patent number: 5004760Abstract: A biocidal foam product comprising a foam having incorporated therein a water insoluble thermoplastic copolymer consisting of an alpha olefin and an alpha, beta-ethylenically unsaturated carboxylic acid, said copolymer having at least one cationic biocidal agent ionically bonded to said copolymer.Type: GrantFiled: February 16, 1990Date of Patent: April 2, 1991Assignee: The Dow Chemical CompanyInventors: Robert T. Patton, Walter L. Vaughn, Thomas J. McKeand, Jr.
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Patent number: 4990541Abstract: A water absorbent latex polymer foam produced by the process of combining a foamed latex polymer product with a water absorbent polymer and drying that blend to form a foamable latex polymer containing a water absorbent polymer is disclosed in this invention. The latex foams produced by this process are of great use, for example, within diapers, sanitary napkins, packaging materials, and the like. In particular, the use of water absorbent polymers with particle size less than about 30 microns has been shown to produce particularly effective absorbent latex foams.Type: GrantFiled: November 9, 1989Date of Patent: February 5, 1991Assignee: Hoechst Celanese Corp.Inventors: Steven F. Nielsen, Dai W. Kim
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Patent number: 4990545Abstract: A thermoplastic or thermoset article, a porous sheet, a paint composition, and a synthetic leather which are characterized with a memory shape or a healable characteristics comprising a polyurethane resin obtained by reacting a polyisocyanate and aromatic and/or alicyclic polyol is disclosed. The polyurethane comprises at least 15% by weight in total of a ring component derived from the above polyol.The original (memorized) shape of the article or the porous sheet is reshaped into another desired form below 130.degree. C., and locked into below 40.degree. C. Those material can be reverted back to their original shape by heating above 40.degree. C. The memorized shape as an original shape of the thermoplastic article or the porous sheet can be changed by maintaining it in a desired shape at a temperature 130.degree..about.230.degree. C.When the paint or the synthetic leather is scratched or creased to its surface, they can be healed by heating above 40.degree. C.Type: GrantFiled: September 1, 1989Date of Patent: February 5, 1991Assignee: Sanyo Chemical Industries, Ltd.Inventors: Kouzi Hourai, Yoshio Kobayashi, Katsuhiko Ikegami
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Patent number: 4973670Abstract: The present invention provides for a process for preparing hollow polymer latexes by a one stage emulsion polymerization. The first step invloves introducing an effective amount of a first charge of a organic phase to an aqueous phase. The first charge of the organic phase comprises monomer which is vertually insoluble in the aqeuous phase and an inert-nonpolymerizable hydrocarbon. The polymer formed from polymerizing the monomer is virtually insoluble in the hydrocarbon, the hydrocarbon is virtually insoluble in the aqueous phase and the monomer is miscible with the hydrocarbon. The monomer is polymerized to produce a low molecular weight polymer such that the low molecular weight polymer will phase separate from the organic phase and conentrates at the surface of the introduced organic phase forming a low molecular weight polymer phase.Type: GrantFiled: November 22, 1989Date of Patent: November 27, 1990Assignee: The Dow Chemical CompanyInventors: Charles J. McDonald, Yohannes Chonde, William E. Cohrs, Dalton C. MacWilliams
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Patent number: 4888134Abstract: A conductive foam having a surface resistance of not more than 9.9.times.10.sup.10 ohms as measured by DIN 53,345 may be prepared by incorporating into the base compound at least about 5 parts by dry weight per 100 parts by weight of polymer of a dispersion of carbon black stabilized by a soap predominantly of the same type as that compatible with the process used to set the foam; and processing the compound in a conventional manner.Type: GrantFiled: July 19, 1988Date of Patent: December 19, 1989Assignee: BASF AktiengesellschaftInventors: Jean-Pierre Kleitz, Piere H. A. Mertzeisen
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Patent number: 4870112Abstract: A foamable, gelable and heat-vulcanizable composition for the manufacture of latex foam having, e.g., the following properties:(a) the indentation hardness must be sufficiently high;(b) the pore structure is to be uniformly fine for an adequate layer thickness,comprises a mixture of a rubber latex and a filler/rubber powder, a vulcanizing agent and conventional additives.The latex foams according to the invention are excellently suited as vibration damping materials, the mass to volume ratio and correspondingly the hardness being adjustable depending on the intended use to a high or low value.Type: GrantFiled: May 15, 1987Date of Patent: September 26, 1989Assignee: Huels AktiengesellschaftInventors: Herbert Knipp, Wolfgang Schulz
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Patent number: 4839222Abstract: An improved heat collapsible foam coating is provided for fiberglass insulation articles which is coated onto the fiberglass insulation, thereby providing the fiberglass insulation with good mechanical properties and other desirable properties such as low emission of volatiles, fire retardency, low potential smoke generation and low air friction.Type: GrantFiled: March 25, 1988Date of Patent: June 13, 1989Assignee: The Reynolds CompanyInventor: Surendra Jain
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Patent number: 4764363Abstract: Aqueous aerosol mousse compositions are disclosed which contain a water-dispersible silicone elastomer. The presence of the elastomer provides for clean wet hair feel along with good style retention.Type: GrantFiled: June 13, 1986Date of Patent: August 16, 1988Assignee: The Procter & Gamble CompanyInventor: Raymond E. Bolich, Jr.
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Patent number: 4537915Abstract: The resistance to internal charring of molded styrene-butadiene latex foam rubber when exposed to a lit cigarette is improved by incorporating from about 10 to 30 parts by dry weight, per hundred parts by dry weight of latex of a compound selected from the group consisting of an organic phosphate of the formula ##STR1## wherein R is a C.sub.6-12 alkyl radical or a phenyl radical, which is unsubstituted or substituted by a C.sub.1-4 alkyl radical, butyl benzyl phthalate, and a mixture thereof.Type: GrantFiled: May 9, 1983Date of Patent: August 27, 1985Assignee: Polysar International S.A.Inventors: Patrick Oberle, Michel Longuet, David Walker
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Patent number: 4506037Abstract: A process for producing a resin foam by using an aqueous medium, which comprises(a) treating a resin compound with said aqueous medium to cause the aqueous medium to adhere to and be held by the resin compound, said resin compound being composed of porous agglomerated particles resulting from partial melt-adhesion of thermoplastic resin particles coated with a fine hydrophilic solid powder which does not substantially melt at the melting temperature of the resin particles, said solid powder being embedded in the resin particles but partly exposed at their surfaces,(b) melt-kneading the resin compound treated with the aqueous medium under such an elevated pressure that evaporation of the aqueous medium is substantially inhibited, and(c) thereafter releasing the kneaded resin composition from the pressurized state to foam it; and a thermoplastic resin compound used for the aforesaid process.Type: GrantFiled: March 15, 1984Date of Patent: March 19, 1985Assignee: Chuo Kagaku Co., Ltd.Inventors: Shigemasa Suzuki, Toshiyuki Takai
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Patent number: 4501825Abstract: A novel tire sealant and inflator composition comprising a resin, a latex sealant, alkylene glycol, fibers, an alkanolamine, a foaming agent, and water. The composition is packaged in aerosol cans with a chlorofluorocarbon propellant/inflator and used to seal and inflate punctured tires. The composition is applied to the punctured tire through the valve stem, and acts to seal the puncture and inflate the tire sufficiently to support the weight of the car.Type: GrantFiled: June 28, 1984Date of Patent: February 26, 1985Assignee: Pennzoil CompanyInventors: Arpad M. Magyar, Gerald G. Smith
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Patent number: 4482648Abstract: A foamable ink composition which comprises a water-based printing ink, a foaming agent and a pseudoplastic additive. The ink, foaming agent and pseudoplastic additive are foamed with a compressed gas. The pseudoplastic additive aids in the mixing of the ink with the gas and enhances the stability of the foam. The foam is especially adapted for application to a gravure cylinder where it is doctored to convert the foam bubbles into thin discrete membranes spanning the gravure cells. These membranes then are transferred, either directly or indirectly to a moving web.Type: GrantFiled: September 17, 1982Date of Patent: November 13, 1984Assignee: Foamink Company, Inc.Inventor: Edward C. Norman
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Patent number: 4443562Abstract: A process for making a lightweight structural member or insulating coating uses an initial mixture of hydrated lime, a dispersible additive, rock wool and, optionally an aggregate. This mixture has added to it water, and the water/solids mixture is agitated at high speed to produce a castable slurry having 60-80 volume percent air bubbles. The mixing is desirably conducted in a mixer having a cylindrical chamber and using paddles which rotate about their own axis and wherein there is movement of the chamber wall relative thereto, and the blades desirably scrape the chamber wall during such relative rotation.Type: GrantFiled: July 19, 1982Date of Patent: April 17, 1984Inventor: Karl M. Mayer
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Patent number: 4431768Abstract: Aqueous acidic compositions which contain a combination of an organic polymer having a bound latent source of thiolate ions, such as isothiouronium groups and an organic polymer having bound cationic onium groups, such as sulfonium groups, or a polymer containing both kinds of groups can be cured in the wet state by raising the pH to above about 9 at a temperature from about 0.degree. C. to about 100.degree. C.Type: GrantFiled: May 4, 1982Date of Patent: February 14, 1984Assignee: The Dow Chemical CompanyInventors: Ritchie A. Wessling, Thomas C. Klingler
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Patent number: 4430447Abstract: When polyvinyl alcohol and vinyl acetate/ethylene copolymers are acetalized in an acid aqueous medium in the presence of a wetting agent, an open-pore solid foam is formed, if the reaction mixture contains gas bubbles. These gas bubbles are produced, in particular, by stirring in air. The molded articles obtained are porous, and the pores are uniformly distributed. The dried molded article absorbs many times its weight of water. It is employed as a sponge for household use and in industry.Type: GrantFiled: September 30, 1982Date of Patent: February 7, 1984Assignee: Hoechst AktiengesellschaftInventors: Gunther Pospich, Wolfgang Zimmermann
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Patent number: 4417016Abstract: An improved frothing aid composition for use in combination with sodium polyacrylate viscosity regulator which consists about 70 to 99% by weight of a surfactant and from about 1 to 30% by weight of a thickener comprising a copolymer of acrylic or methacrylic acid with at least one copolymerizable monomer selected from the group consisting of alkyl acrylates or methacrylates having up to 6 carbons in the alkyl, vinylidene aromatic monomers and aliphatic conjugated diene monomers of 4-10 carbon atoms.Type: GrantFiled: February 19, 1982Date of Patent: November 22, 1983Assignee: Para-Chem Southern, Inc.Inventors: Charles D. Cline, Thomas L. Mills
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Patent number: 4373033Abstract: The manufacture of foam rubber having improved set and deflection properties at low foam densities is provided.Type: GrantFiled: August 3, 1981Date of Patent: February 8, 1983Assignee: Clarex Manufacturing LimitedInventor: Ramesh K. Gupta
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Patent number: 4318998Abstract: Additive of the cellular plastic type, method for manufacturing the additive and use of the additive. The additive is intended to be mixed with a hardening or air-drying component, preferably, liquid paint. The additive of this invention is characterized in that a mixture of closed cellular plastic particles, disintegrated foamed urea formaldehyde resin and chopped fiberglass filaments or strands from part of the additive.Type: GrantFiled: February 18, 1981Date of Patent: March 9, 1982Assignee: Jan Berglund Produktions ABInventor: Jan-Olof V. Berglund
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Patent number: 4288559Abstract: The instant invention is directed to a process for the production of flame resistant foams by the impregnation of polyurethane foams with a dispersion consisting substantially of an aluminum hydroxide, a polyurethane latex, an alumino-silicate and surface active substances which results in foams having very desirable mechanical properties as well as excellent flame resistant properties.Type: GrantFiled: November 1, 1979Date of Patent: September 8, 1981Assignee: Bayer AktiengesellschaftInventors: Hans-Walter Illger, Manfred Dahm, Alberto C. Gonzalez-Dorner
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Patent number: 4240998Abstract: A process is disclosed herein for the production of a composite foamed material which comprises premixing expandable polystyrene beads and a binder and adding the premix to fragments of resilient, open-celled material. The materials are combined in the proportions of about 4-15% polystyrene beads, about 6-25% binder and about 60-90% open-celled material. The combined materials are compressed to a density of about 5-30 lbs per cubic foot, preferably 5-17 lbs per cubic foot, and steam is applied to the compressed materials to cure the binder and expand the polystyrene beads, producing the desired composite foamed material.Type: GrantFiled: April 5, 1979Date of Patent: December 23, 1980Inventors: Seymour Lichter, Frank P. Nold
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Patent number: 4241190Abstract: A process is disclosed herein for the production of a composite foamed material which comprises premixing expandable polystyrene beads and a binder and adding the premix to fragments of resilient, open-celled material. The materials are combined in the proportions of about 4-15% polystyrene beads, about 6-25% binder and about 60-90% open-celled material. The combined materials are compressed to a density of about 5-30 lbs per cubic foot preferably 5-17 lbs per cubic foot, and steam is applied to the compressed materials to cure the binder and expand the polystyrene beads, producing the desired composite foamed material.Type: GrantFiled: April 5, 1979Date of Patent: December 23, 1980Inventors: Seymour Lichter, Frank P. Nold
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Patent number: 4214053Abstract: The gel range of acid-acting delayed-action gelling agents, such as sodium silicofluoride, in latex spread foam compounds which are to be gelled by subjecting them to a preliminary heat treatment prior to drying is substantially broadened by including a water-soluble ammonium or amine sulfamate in the compound. At least 0.5 parts by weight of the sulfamate should be used per 100 parts by weight of dry solids in the starting uncompounded latex. It can be added to the latex at any time before or during the compounding step and it is preferably added with 0.5-1 part of a soap per part of sulfamate and also with sufficient ammonium hydroxide or other ammonia donor compound to maintain the pH of the compounded latex composition at 9.5 or higher.Type: GrantFiled: January 29, 1979Date of Patent: July 22, 1980Assignee: Polysar International, S.A.Inventor: David Porter
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Patent number: 4208485Abstract: An expansion agent comprising a foamable mixture of (a) 15-53 weight % of a foaming agent having 6 to 78 carbon atoms selected from the group of an ammonium salt, aliphatic amine salt and/or an alkali metal salt of an alkyl sulfate, hydroxyalkyl sulfate, alkyl ether sulfate and/or aryl alkyl ether sulfate; (b) 5-42 weight % of a dispersant having 22 to 260 carbon atoms selected from the group of an alkyl alkyleneoxy amine and/or its quaternary alkylsulfate, alkylhalide or alkylphosphate derivative; and (c) 5-40 weight % of a stabilizer having 8 to 68 carbon atoms selected from the group of a sodium and/or potassium salt of an alkyl sulfosuccinate; and the combination of said mixture with a synthetic resin, latex or natural rubber to provide a coating or finishing composition; the process of applying said composition to a substrate and the treated substrate product having incorporated the composition of the invention.Type: GrantFiled: March 16, 1979Date of Patent: June 17, 1980Assignee: GAF CorporationInventor: Roop C. Nahta