Preparing A Cellular Product By Decomposition Of A Solid Polymer; Or Process Of Forming A Composition Containing A Solid Polymer Which Decomposes So As To Subsequently Form A Cellular Polymer, Or Composition Therefrom Patents (Class 521/77)
  • Patent number: 4363883
    Abstract: High density structural ("blocking") materials composed of a polyimide filled with glass microballoons. Structural components such as panels which have integral edgings and/or other parts made of the high density materials.
    Type: Grant
    Filed: September 12, 1980
    Date of Patent: December 14, 1982
    Assignee: International Harvester Company
    Inventors: John Gagliani, Raymond Lee
  • Patent number: 4355120
    Abstract: Copolyimide foams derived from a diester of 3,3',4,4'-benzophenonetetracarboxylic acid, an aromatic diamine, and a heterocyclic diamine. A molar concentration of the heterocyclic diamine approaching but not exceeding 0.42 is employed. This results in a flexible foam with a homogeneous cellular structure and a reduced compression set loss.
    Type: Grant
    Filed: December 7, 1981
    Date of Patent: October 19, 1982
    Assignee: International Harvester Co.
    Inventors: John Gagliani, Raymond Lee, Usman A. K. Sorathia
  • Patent number: 4346182
    Abstract: Terpolyimides prepared from tetracarboxylic acid esters and combinations of heterocyclic, aromatic, and aliphatic diamines and artifacts composed of those terpolymers. Precursors, and methods of converting them to the corresponding terpolymers.
    Type: Grant
    Filed: April 14, 1981
    Date of Patent: August 24, 1982
    Assignee: International Harvester Company
    Inventors: John Gagliani, Raymond Lee
  • Patent number: 4319000
    Abstract: Closed cell polyimide foams. Methods of making such foams from precursors derived from a benzophenonetetracarboxylic acid diester and a mixture of diamines in which the precursor is molded to shape and cured, hydrated, and heated until a porous, closed cell structure develops.
    Type: Grant
    Filed: March 30, 1981
    Date of Patent: March 9, 1982
    Assignee: International Harvester Company
    Inventors: John Gagliani, John V. Long
  • Patent number: 4315077
    Abstract: Terpolyimides prepared from tetracarboxylic acid esters and combinations of heterocyclic, aromatic, and aliphatic diamines and artifacts composed of those terpolymers. Precursors, and methods of converting them to the corresponding terpolymers.
    Type: Grant
    Filed: May 27, 1981
    Date of Patent: February 9, 1982
    Assignee: International Harvester Company
    Inventors: John Gagliani, Raymond Lee
  • Patent number: 4315080
    Abstract: Terpolyimides prepared from tetracarboxylic acid esters and combinations of heterocyclic, aromatic, and aliphatic diamines and artifacts composed of those terpolymers. Precursors, and methods of converting them to the corresponding terpolymers.
    Type: Grant
    Filed: May 27, 1981
    Date of Patent: February 9, 1982
    Assignee: International Harvester Company
    Inventors: John Gagliani, Raymond Lee
  • Patent number: 4315076
    Abstract: Terpolyimides prepared from tetracarboxylic acid esters and combinations of heterocyclic, aromatic, and aliphatic diamines and artifacts composed of those terpolymers. Precursors, and methods of converting them to the corresponding terpolymers.
    Type: Grant
    Filed: April 14, 1981
    Date of Patent: February 9, 1982
    Assignee: International Harvester Company
    Inventors: John Gagliani, Raymond Lee
  • Patent number: 4314035
    Abstract: Foamable copolymers and copolymer mixtures comprising 35% to 98% by weight ethylene, 1% to 30% by weight vinyl alcohol, 1% to 30% by weight acrylic acid esters of secondary or tertiary alcohols, and 0 to 5% by weight vinyl ester are disclosed. All percentages are based upon the total weight of the copolymer or mixture. Methods of foaming such materials, foamed materials made therefrom, and methods of preparation thereof are also disclosed.
    Type: Grant
    Filed: August 20, 1980
    Date of Patent: February 2, 1982
    Assignee: Ruhrchemie Aktiengesellschaft
    Inventors: John-Victor Hobes, Wolfgang Payer
  • Patent number: 4296208
    Abstract: Methods of preparing polyimides and polyimide precursors from liquid resins containing tetracarboxylic acid esters and primary diamines which involve spray drying the resin.
    Type: Grant
    Filed: September 12, 1980
    Date of Patent: October 20, 1981
    Assignee: International Harvester Company
    Inventors: John Gagliani, Usman A. K. Sorathia
  • Patent number: 4273886
    Abstract: Polyimide foams derived from mixtures of aromatic diamines and partial esters of a benzophenonetetracarboxylic acid. The precursors are converted into polyimide foams by the application of heat; and the foams are then compressed, yielding dense, rigid, and structurally strong, intumescent materials.
    Type: Grant
    Filed: February 15, 1980
    Date of Patent: June 16, 1981
    Assignee: International Harvester Company
    Inventor: John Gagliani
  • Patent number: 4246358
    Abstract: Fire-resistant organic materials including foams, are made by heating at temperatures sufficient to cause polymerization and elimination of nitrogen and sulfur precursor aromatic polymers having sulfonamide linkages and aromatic compounds capable of forming said polymers, e.g. sulfamyl-type aminoaromatic compounds such as sulfanilamide, sulfaguanadine and the like. Preferred compounds are those providing para linkages in the sulfonamide polymer chain, those which are substantially free of oxidizing substituents, for example nitro groups, and those which are not fused-ring aromatic. Preferred foams are the high expansion foams, i.e. those having expansion ratios of at least about 3:1, more preferably at least about 8:1. The precursors of these fire-resistant organic materials can be incorporated into polymers such as polyvinylidene chloride, polyisocyanates, aminoplasts, and the like either physically by mixing or by chemical reaction to give improved fire-resistance.
    Type: Grant
    Filed: December 17, 1979
    Date of Patent: January 20, 1981
    Assignee: Monsanto Research Corporation
    Inventor: James A. Ellard
  • Patent number: 4246357
    Abstract: A foamable copolymer comprising 40 to 98 percent by weight units of ethylene, 1 to 30 weight percent units of vinyl alcohol, 1 to 30 weight percent units of acrylic acid ester of a secondary or tertiary alcohol, and up to 2 percent by weight of vinyl acetate units is described together with a process for the manufacture thereof. The same is useful in the formation of a foamed mass which is relatively highly cross-linked. The copolymer can be foamed to form a foam by heating the same at 250.degree. to 350.degree. C. for 5 to 60 minutes in the absence of oxygen.
    Type: Grant
    Filed: July 9, 1979
    Date of Patent: January 20, 1981
    Assignee: Ruhrchemie Aktiengesellschaft
    Inventors: John V. Hobes, Wolfgang Payer
  • Patent number: 4241193
    Abstract: Polyimide foams derived from mixtures of aromatic diamines and partial esters of a benzophenonetetracarboxylic acid. The precursors are converted into polyimide foams by the application of heat; and the foams are then compressed, yielding dense, rigid, and structurally strong, intumescent materials.
    Type: Grant
    Filed: August 21, 1978
    Date of Patent: December 23, 1980
    Assignee: International Harvester Company
    Inventor: John Gagliani
  • Patent number: 4241114
    Abstract: Polyimide foams derived from mixtures of aromatic diamines and partial esters of a benzophenonetetracarboxylic acid. The precursors are converted into polyimide foams by the application of heat; and the foams are then compressed, yielding dense, rigid, and structurally strong, intumescent materials.
    Type: Grant
    Filed: February 15, 1980
    Date of Patent: December 23, 1980
    Assignee: International Harvester Company
    Inventor: John Gagliani
  • Patent number: 4238572
    Abstract: The invention relates to a foamable polymeric polyblend of a matrix copolymer of alkenyl aromatic/alkenyl nitrile monomers having dispersed therein (1) a grafted diene rubber being grafted with said monomers and (2) an alkyl half ester of a styrene/maleic anhydride copolymer. The composition is foamed by the thermal decomposition of said half ester. The foamed polyblend has great utility as a structural foam with said composition providing fast molding cycles and fine cell structure. A method for foaming said polyblend is disclosed.
    Type: Grant
    Filed: November 16, 1979
    Date of Patent: December 9, 1980
    Assignee: Monsanto Company
    Inventor: Richard L. Hoffman
  • Patent number: 4230820
    Abstract: Organopolysiloxane foams are prepared by heating a mixture containing (A) a diorganopolysiloxane, (B) silicon dioxide having a surface area of at least 50 m.sup.2 /g, (C) a peroxide compound, (D) at least one organosilicon compound containing at least 2 weight percent of Si-bonded hydroxyl groups and (E) at least one organopolysiloxane having Si-bonded hydrogen, to a temperature between 280.degree. and 320.degree. C. at a pressure which does not exceed the pressure of the surrounding atmosphere.
    Type: Grant
    Filed: March 2, 1979
    Date of Patent: October 28, 1980
    Assignee: Wacker-Chemie GmbH
    Inventors: Adolph Maschberger, Peter August
  • Patent number: 4226949
    Abstract: Aromatic polyamide foams having a density of 0.025 to 0.7 g./cm..sup.3 are prepared by heating N-alkyl aromatic polyamides having at least one .beta. hydrogen atom on the alkyl groups, a plasticizer and an aromatic sulfonic acid catalyst at 250.degree. to 340.degree. C. for a length of time sufficient to remove substantially all of the N-alkyl groups.
    Type: Grant
    Filed: August 1, 1979
    Date of Patent: October 7, 1980
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Wesley Memeger, Jr.
  • Patent number: 4208486
    Abstract: Organic amides, solutions of polymers thereof, which polymers are subject to hydrolysis and degradation in the presence of amines, and polymers isolated therefrom are stabilized by the presence of aromatic sulfonic acid esters of aliphatic, arylaliphatic and alicyclic alcohols and polyols.
    Type: Grant
    Filed: December 8, 1978
    Date of Patent: June 17, 1980
    Assignee: Exxon Research & Engineering Co.
    Inventor: Tad L. Patton
  • Patent number: 4197370
    Abstract: Novel foamable compositions are disclosed which may comprise a polyphenylene oxide resin with or without an alkenyl aromatic resin; and a foaming agent which is a thermally unstable copolymer.
    Type: Grant
    Filed: December 27, 1976
    Date of Patent: April 8, 1980
    Assignee: General Electric Company
    Inventors: Daniel W. Fox, John C. Goossens
  • Patent number: 4179298
    Abstract: Flame retardant intumescent polyamides comprising repeating structural units of the formulas ##STR1## wherein X is independently chloro or bromo, and n and n' are each independently a positive integer are disclosed.
    Type: Grant
    Filed: January 18, 1978
    Date of Patent: December 18, 1979
    Assignee: The Dow Chemical Company
    Inventors: Linnea E. Nelson, Charles E. Reineke
  • Patent number: 4128513
    Abstract: A black sorbent thermoset foam which has been prepared by the pyrolysis of a composition comprising at least one aromatic nitrogen-containing compound having the general formula:X -- Ar -- Yin which Ar represents an aromatic nucleus on which X and Y are substituents directly attached to the nucleus, X represents a substituent having a negative Hammett sigma constant and attached to the aromatic nucleus by a nitrogen, oxygen or sulphur atom, and Y represents a substituent having a positive Hammett sigma constant and attached to the aromatic nucleus by a nitrogen atom, the substituents X and/or Y optionally forming part of a ring fused onto the aromatic nucleus, in an effective sorbtive substance for polar molecules and materials.
    Type: Grant
    Filed: May 13, 1974
    Date of Patent: December 5, 1978
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Louis A. Errede, Robert A. Sinclair