Preparing A Cellular Product By Spraying A Solid Polymer Containing Material Patents (Class 521/78)
  • Patent number: 4649162
    Abstract: The invention relates to a process for the preparation of cellular or noncellular plastics, preferably polyurethane coatings, by reacting at least two components with one another, preferably organic polyisocyanates and polyhydroxyl compounds, by feeding the components into a mixing zone separately, and mixing them together and then discharging the reaction mixture from the mixing zone, while adding air heated to a temperature of 100.degree. to 1200.degree. C. to the reaction mixture as it emerges from the mixing zone.
    Type: Grant
    Filed: January 23, 1986
    Date of Patent: March 10, 1987
    Assignee: BASF Aktiengesellschaft
    Inventors: Peter Roche, Mathaeus Rank
  • Patent number: 4631297
    Abstract: What is disclosed is a method for preparing antimicrobially effective foams using certain silanes as co-catalysts, co-surfactants and antimicrobial agents to give soft, resilient, fine-celled foams that are capable of reducing the number of, or eliminating, microorganisms in all types of media. Such foams themselves are not susceptible to attack by the microorganisms. An example is the use of (CH.sub.3 O).sub.3 Si(CH.sub.2).sub.3 N.sup..sym. (CH.sub.3).sub.2 C.sub.18 H.sub.37 Cl.sup.- in a flexible polyurethane foam formulation to give a fine-celled, soft, resilient foam which is antimicrobially effective over a long period of time.
    Type: Grant
    Filed: October 15, 1985
    Date of Patent: December 23, 1986
    Assignee: Dow Corning Corporation
    Inventors: David R. Battice, Michael G. Hales
  • Patent number: 4608398
    Abstract: Surface coating methods and compositions are disclosed which eliminate many of the disadvantages associated with known coating processes from pollution, equipment, materials, energy, labor and cost standpoints. According to techniques described, thermosetting liquid compositions containing film-forming solids are formulated, then conveyed in the foam state toward a surface, and upon foam disintegration, form a film of solids on the surface. The foamable thermosetting resin compositions contain a curable resin having a free hydroxyl or carboxyl group, a curing agent consisting of a lower (C.sub.1 -C.sub.4) alkoxylated amine for reaction with the resin hydroxyl or carboxyl group and a liquid blowing agent consisting of a C.sub.1 -C.sub.4 alkanol which is also a by-product of the thermosetting reaction.
    Type: Grant
    Filed: December 2, 1983
    Date of Patent: August 26, 1986
    Assignee: Nordson Corporation
    Inventors: Walter H. Cobbs, Jr., Robert G. Shong, William R. Rehman
  • Patent number: 4590218
    Abstract: A method and apparatus for forming a chemical composition from two liquid components selected for cross-linking reaction with each other and a product of the method are disclosed, the method including the steps of selecting the components for interaction to form a solid chemical composition product, the components being intimately mixed with an inert blowing agent to avoid altering chemical characteristics of the chemical composition product and to vary density of the product, the mixture being conducted to an application zone through an expansion chamber having internal dimensions selected for achieving substantially complete expansion of the mixture to a substantially relaxed condition as it passes from the expansion chamber. In one embodiment, means are provided for spraying the product onto the application zone. In another embodiment, delay means are provided for causing increased viscosity of the components. Mesh material forms an integral portion of one preferred product.
    Type: Grant
    Filed: June 19, 1985
    Date of Patent: May 20, 1986
    Assignee: The O'Brien Corporation
    Inventor: Richard T. Vass
  • Patent number: 4584324
    Abstract: A composition useful in producing an open-cell, elastomeric silicone foam combines a silicone oil-in-water emulsion, which forms an elastomer upon removal of the water, with an aerosol propellant. When the composition is discharged to atmospheric pressure, a froth is formed. Removing water from the froth yields an open-cell foam. The froth is stabilized by surfactants, thickeners, or froth stabilizers selected from fibers or lauryl alcohol.
    Type: Grant
    Filed: September 30, 1985
    Date of Patent: April 22, 1986
    Assignee: Dow Corning Corporation
    Inventors: Therese M. Bauman, Chi-Long Lee, James A. Rabe
  • Patent number: 4559369
    Abstract: A composition useful in producing an open-cell, elastomeric silicone foam combines a silicone oil-in-water emulsion, which forms an elastomer upon removal of the water, with an aerosol propellant. When the composition is discharged to atmospheric pressure, a froth is formed. Removing water from the froth yields an open-cell foam. The froth is stabilized by surfactants, thickeners, or froth stabilizers selected from fibers or lauryl alcohol.
    Type: Grant
    Filed: October 26, 1984
    Date of Patent: December 17, 1985
    Assignee: Dow Corning Corporation
    Inventors: Therese M. Bauman, Chi-long Lee, James A. Rabe
  • Patent number: 4547529
    Abstract: Polyorganosiloxane foams are obtained by blending, dispensing and curing two-part polyorganosiloxane compositions comprising a liquid hydroxyl endblocked polydimethylsiloxane, a liquid alkyl orthosilicate as the curing agent, a catalytically effective amount of a tin compound, a blowing agent and, as a foam stablilizer, a resinous organosiloxane copolymer comprising trimethylsiloxy units, SiO.sub.4/2 units and a specified class of fluorine-containing organosiloxane units.
    Type: Grant
    Filed: March 25, 1985
    Date of Patent: October 15, 1985
    Assignee: Dow Corning Corporation
    Inventors: Chi-Long Lee, James A. Rabe
  • Patent number: 4543366
    Abstract: Sprayable urethane resin compositions and a process for preparing the sprayable resin compositions particularly with reinforcing materials such as chopped fiberglass, which process comprises reacting generally equal volumes of A and B side mixtures in a sprayable reaction to form a fast reacting, fast curing urethane resin, the A side mixture comprising an MDI or an MDI prepolymer prepared by reacting an MDI with a triol and a B side mixture comprising an auto catalytic, aromatic amine polyol having a hydroxyl number ranging from about 300 to 600, a viscosity reducing amount of a tetraethylene glycol and a catalyst to affect the rapid reaction and cure of the A and B side mixtures on spraying, the process may optionally include the incorporation of reinforcing materials, such as glass fibers and optionally may include the use of blowing agents to provide a lower density reinforced cured product.
    Type: Grant
    Filed: October 15, 1984
    Date of Patent: September 24, 1985
    Assignee: Thermocell Development, Ltd.
    Inventor: Stuart B. Smith
  • Patent number: 4525487
    Abstract: A spray method for making cured polyester resin foam is provided using a liquid unsaturated polyester resin, a sulfonyl hydrazide, an effective amount of a promoter, an effective amountof a catalyst and 0.005-3 parts quaternary ammonium salt.
    Type: Grant
    Filed: August 11, 1983
    Date of Patent: June 25, 1985
    Assignee: Uniroyal, Inc.
    Inventors: James Ahnemiller, Warren J. Peascoe
  • Patent number: 4522954
    Abstract: A method for producing low density polyester foam includes heating the resin to a temperature in the range of from 80.degree. to 140.degree. F., combining the resin with a blowing agent such as a sulfonyl hydrazide, combining the resulting admixture with a catalyst, and depositing the catalyzed resin on a surface. The density of the resulting foam can be decreased by incorporating a flourinated hydrocarbon into the resin.
    Type: Grant
    Filed: March 14, 1984
    Date of Patent: June 11, 1985
    Inventor: Frank Ive
  • Patent number: 4518716
    Abstract: Polyorganosiloxane foams exhibiting a desirable combination of low density, an average cell size between 0.2 and 4 mm and a cell concentration of at least 4 per linear centimeter are obtained by dispensing and curing moisture curable organosiloxane compositions containing a dispersed liquid or gaseous blowing agent and, as a foam stabilizer, a resinous organosiloxane copolymer comprising trimethylsiloxy units, SiO.sub.4/2 units and fluorine-containing organosiloxane units. The polymer portion of the organosiloxane compositions can be a polydimethylsiloxane or a graft copolymer comprising at least 20 mole percent of dimethylsiloxane units in combination with organic units.
    Type: Grant
    Filed: October 26, 1984
    Date of Patent: May 21, 1985
    Assignee: Dow Corning Corporation
    Inventors: Chi-Long Lee, James A. Rabe
  • Patent number: 4504602
    Abstract: A composition comprising mineral wool and polyolefin fibers is adaptable for spraying onto a ceiling or wall or the like to form a textured acoustical coating.
    Type: Grant
    Filed: April 6, 1984
    Date of Patent: March 12, 1985
    Assignee: United States Gypsum Company
    Inventors: Daniel D. O'Connell, Thomas A. Broz
  • Patent number: 4501825
    Abstract: A novel tire sealant and inflator composition comprising a resin, a latex sealant, alkylene glycol, fibers, an alkanolamine, a foaming agent, and water. The composition is packaged in aerosol cans with a chlorofluorocarbon propellant/inflator and used to seal and inflate punctured tires. The composition is applied to the punctured tire through the valve stem, and acts to seal the puncture and inflate the tire sufficiently to support the weight of the car.
    Type: Grant
    Filed: June 28, 1984
    Date of Patent: February 26, 1985
    Assignee: Pennzoil Company
    Inventors: Arpad M. Magyar, Gerald G. Smith
  • Patent number: 4476159
    Abstract: Access to a space is impeded by generation of a sticky foam from a silicone polymer and a low boiling solvent such as a halogenated hydrocarbon. In a preferred aspect, the formulation is polydimethylsiloxane gel mixed with F502 Freon as a solvent and blowing agent, and pressurized with CO.sub.2 in a vessel to about 250 PSI, whereby when the vessel is opened, a sticky and solvent resistant foam is deployed. The foam is deployable, over a wide range of temperatures, adhering to wet surfaces as well as dry, is stable over long periods of time and does not propagate flame or lose adhesive properties during an externally supported burn.
    Type: Grant
    Filed: December 21, 1983
    Date of Patent: October 9, 1984
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventors: Judith W. Mead, Orelio J. Montoya, Peter B. Rand, Vernon O. Willan
  • Patent number: 4472230
    Abstract: Aqueous polyisocyanate emulsions are made by emulsifying 5 to 70 parts by weight (on a basis of 100 parts) of a polyisocyanate which has not been modified to render it hydrophilic and emulsifiable with 30 to 95 parts by weight (on a basis of 100 parts) aqueous paraffin dispersion containing 3 to 65 wt. % paraffin, and optionally known additives in the presence of water. The water is used in a quantity such that the emulsion has a solids content of from 6 to 90 wt. %. These emulsions are particularly useful as binders in the production of molded articles.
    Type: Grant
    Filed: January 3, 1983
    Date of Patent: September 18, 1984
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hanns I. Sachs, Peter Kasperek, Robert Peters
  • Patent number: 4425440
    Abstract: The invention provides a flame retardant thermally insulating material which comprises cellular polymer particles and fly ash bound into a coherent mass by a dried synthetic polymer latex binder, and a process for providing between at least two spaced-apart surfaces a flame retardant thermal insulation in the form of such a material. The process has particularly useful application in the field of roof insulation in sloping roofs having spaced-apart outer and inner layers.
    Type: Grant
    Filed: September 3, 1982
    Date of Patent: January 10, 1984
    Assignee: Shell Oil Company
    Inventors: Roel Bloembergen, Jan A. Verhave
  • Patent number: 4422877
    Abstract: Synthetic polymer-propellant compositions are provided that are capable of forming foamed structures having a temperature at least 30.degree. C. below ambient temperature and containing open and/or closed cells, which may optionally contain a material which is deposited in the pores and/or walls of the structure as the structure is formed, and comprising:(a) a film-forming synthetic polymer is an amount within the range from about 2% to about 30% by weight of the composition;(b) at least one liquefied propellant boiling below -10.degree.
    Type: Grant
    Filed: February 4, 1982
    Date of Patent: December 27, 1983
    Assignee: Restech Research Limited Partnership
    Inventors: J. George Spitzer, Lloyd I. Osipow
  • Patent number: 4423161
    Abstract: Pressure vessels are disclosed for containing a foamable mixture of liquid and a blowing agent for incrementally or continuously dispensing a foam of constant foam-volume ratio. Liquid compositions having coating or polymeric solids are capable of being foamed and dispensed with the apparatus. The method and apparatus are especially advantageous in dispensing foamed coatings, paints or adhesives with superior control.
    Type: Grant
    Filed: May 11, 1981
    Date of Patent: December 27, 1983
    Assignee: Nordson Corporation
    Inventors: Walter H. Cobbs, Jr., William R. Rehman
  • Patent number: 4381066
    Abstract: This invention concerns sprayable emulsions of a foamable polymer in water which are useful as aerosol caulking or insulating compositions.
    Type: Grant
    Filed: May 10, 1982
    Date of Patent: April 26, 1983
    Inventors: Edward H. Page, Frank Scotti
  • Patent number: 4379857
    Abstract: An insulating composition comprising in combination a liquid binder, a heat expanded polystyrene material in bead or granular form and a reinforcing pigment, said liquid binder comprising a 95.5 to 50:50 mixture, by weight of an acrylic or vinyl polymer emulsion and an alkali metal silicate, said expanded polystyrene being present in an amount ranging from 5 to 25 percent by weight of said composition.
    Type: Grant
    Filed: October 28, 1981
    Date of Patent: April 12, 1983
    Assignee: Cook Paint and Varnish Company
    Inventors: Douglas E. Hansen, Steven D. Johnson, Richard L. Motko
  • Patent number: 4350774
    Abstract: A composition suitable for preparing a stable cellular foam, aerosol containers containing the composition, and methods of using the foamed composition to caulk and insulate, where the composition includes an emulsion of one or more foamable polymers and dispersed in the emulsion a foam forming amount of a mixture of a volatile organic liquid compound selected from the group consisting of a volatile hydrocarbon, a volatile halogenated hydrocarbon and mixtures thereof, and nitrous oxide, wherein the weight ratio of the organic liquid compound to nitrous oxide is selected such that the foam is self leveling and the volume of the foam is not greater than six times the volume of the composition.
    Type: Grant
    Filed: September 4, 1981
    Date of Patent: September 21, 1982
    Inventors: Frank Scotti, Edward H. Page
  • Patent number: 4328319
    Abstract: A process is provided for preparing propellant compositions including a film-forming synthetic polymer that are capable of forming foamed structures containing open and/or closed cells, which may optionally contain a material which is deposited in the pores and/or walls of the structure as the structure is formed, which comprises coating the synthetic polymer in particulate form with an inert solid material insoluble in the propellant and in solutions of the synthetic resin the propellant at atmospheric temperature; and then adding the propellant and dissolving the synthetic polymer in the propellant.
    Type: Grant
    Filed: October 27, 1980
    Date of Patent: May 4, 1982
    Assignee: Restech Research Limited Partnership
    Inventors: Lloyd I. Osipow, J. George Spitzer
  • Patent number: 4229548
    Abstract: In a process for the production of a plastic organopolysiloxane molding composition which can be stored under pressure and with exclusion of moisture, and which, on release of the pressure and under the action of water or atmospheric moisture, is converted into an elastomeric, fine-pored foam molding or foam coating, which comprises forming a mixture of an .alpha.,.omega.-dihydroxypolydiorganopolysiloxane with a silicon-containing crosslinking agent, introducing the mixture into the inner container of a two-container pack which consists of a rigid outer container and a flexible inner container located within the outer container and provided with a dispensing valve which extends to the exterior, and placing the mixture under pressure.
    Type: Grant
    Filed: July 16, 1979
    Date of Patent: October 21, 1980
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hans Sattlegger, Hermann Schmidt, Karl Schnurrbusch
  • Patent number: 4140661
    Abstract: This invention relates to methods and apparatus for successively dispensing predetermined quantities of urea formaldehyde foamed resin mixture having as constituents a resin component and a hardener component in which a prefoamed one of said components and the other component are independently fed under pressure to a mixing chamber where they are mixed and from which, they are dispensed, any residue of the urea formaldehyde foamed resin mixture left in the mixing chamber after said predetermined quantity has been dispensed therefrom being swept and removed prior to the mixing chamber being supplied with the next batch of said components.The present invention is particularly useful for filling pre-cast cavity building blocks with insulating foamed material.
    Type: Grant
    Filed: December 13, 1976
    Date of Patent: February 20, 1979
    Assignee: Beaconet Engineering Company, Limited
    Inventors: Michael Connett, Peter Connett