Extruding A Solid Polymer Containing Material To Form A Cellular Product Patents (Class 521/79)
  • Patent number: 6800669
    Abstract: A foam comprising a propylene copolymer material comprising at least 50 weight percent of units derived from propylene, based on the total propylene copolymer material, and units derived from ethylenically unsaturated comonomers and having a melt flow rate in the range of from 0.5 to 8 g/10 min, a melt strength of at least 5 cN, and a melt drawability of at least 20 mm/s, process for making a foam using such a propylene copolymer material, process for making a foam in the form of thermoplastic foam beads using such a propylene copolymer material, and an expandable composition comprising such a propylene copolymer material.
    Type: Grant
    Filed: December 12, 2001
    Date of Patent: October 5, 2004
    Assignee: Dow Global Technologies Inc.
    Inventors: Johan A. Thoen, Chuiwah A. Cheung, Bharat I. Chaudhary
  • Patent number: 6790870
    Abstract: A method of producing a foamed material comprises contacting a mixture comprising a first thermoplastic polymer and a second thermoplastic polymer with a blowing agent, wherein the first thermoplastic polymer has a higher percent crystallinity that the second thermoplastic polymer; and subjecting the mixture to conditions sufficient to create a thermodynamic instability in the blend foam the mixture, wherein the mixture comprising the first and second thermoplastic polymers has a percent crystallinity lower than the first thermoplastic polymer.
    Type: Grant
    Filed: March 1, 2000
    Date of Patent: September 14, 2004
    Assignees: North Carolina State University, The University of North Carolina at Chapel Hill
    Inventors: Joseph M. DeSimone, Saad A. Khan, Joseph R. Royer, Richard J. Spontak, Teri Anne Walker, Yvon J. Gay, Srinivas Siripurapu
  • Publication number: 20040176484
    Abstract: Thermoplastic polymer foams having sound deadening properties satisfactory for demanding applications are provided which have mechanical strength, which are economical to manufacture, and which are hydrolytically stable. Methods of preparing these foams are also provided. The foams are useful in sound management, cushion packaging, filtering, and fluid absorption and exhibit one or more of the following properties: 1) average cell size greater than about 2 mm; 2) substantially open-cell structure and 3) relatively large pores connecting the cells. In order that the foam be acoustically active, the foam should possess a substantially open-cell structure and a relatively low airflow resistivity. Foams with substantially open-cell structure and relatively low airflow resistivity are prepared by mechanically opening a foam having an average cell size greater than about 2 mm. In most cases, such mechanical opening creates relatively large pores connecting the cells.
    Type: Application
    Filed: March 9, 2004
    Publication date: September 9, 2004
    Inventor: Chung P. Park
  • Publication number: 20040167240
    Abstract: A macmocellular foam is described having improved cell size and Fire-test-response Characteristics, among other features, which is obtained by selecting a particle size less than 1 micron for the flame retardant adjuvant. The inventors found that the amount of fire retardant adjuvant can be increased for a given foam cell size or the foam cell size can be increased for a given amount of fire retardant adjuvant, allowing the production of foams having exceptionally large, well-formed, cells that have excellent Fire-test-response Characteristics. The benefits are especially noteworthy in relation to thermoplastic foams and inorganic flame retardation adjuvants, due to the unexpected reduction in the nucleation effect of the adjuvant. The foams are useful for improving the acoustic performance of products that are required to meet certain Fire-test-response Characteristics.
    Type: Application
    Filed: October 30, 2003
    Publication date: August 26, 2004
    Inventors: Sandrine Burgun, Jonathan Kammerer, Chung P Park, William G Stobby, Suresh Subramonian
  • Publication number: 20040167241
    Abstract: The present invention relates to an open-cell foam, and to a process for producing this open-cell foam by melting a thermoplastic, or a mixture comprising a thermo-plastic, giving a melt, mixing the melt with at least one blowing agent under pressure, and foaming the melt comprising the blowing agent via extrusion into the free atmosphere, the temperature of the melt during the foaming process being greater than the melt temperature at which a closed-cell foam is formed, and/or adding a pulverulent solid, and/or adding a foreign polymer. The present invention further relates to the use of the foam of the invention for sound deadening or for producing materials by sound deadening.
    Type: Application
    Filed: February 24, 2004
    Publication date: August 26, 2004
    Inventors: Dietrich Scherzer, Hanns-Jorg Krautschneider, Franz-Josef Dietzen
  • Publication number: 20040162358
    Abstract: A composition for a polyolefin resin foam, which comprises a polymer component comprising a polyolefin resin, and at least one of a rubber and a thermoplastic olefin elastomer, and powdery particles, wherein said composition has a melt tension of at least 20 cN when measured in a range between a first temperature at a melting point of said composition and a second temperature that is 20 degrees Celsius higher than said first temperature.
    Type: Application
    Filed: February 19, 2004
    Publication date: August 19, 2004
    Applicant: NITTO DENKO CORPORATION
    Inventors: Takayuki Yamamoto, Katsuhiko Tachibana, Tomohiro Taruno, Mitsuhiro Kanada
  • Patent number: 6773804
    Abstract: A process for making a protective and decorative surfacing film comprises extrusion coating a solventless polymeric material from an extruder die to form an optically clear first layer on a polyester carrier sheet traveling past the extruder die opening. The extrusion coated first layer is immediately cooled on the carrier sheet to harden it, followed by applying a pigmented second layer to the first layer. The composite paint coat is transferred to a reinforcing backing sheet, after which the carrier sheet is separated from the paint coat to expose the outer surface of the first layer as a high gloss surface with a high distinctness-of-image, providing a transparent protective outer coat for the pigmented second layer. The pigmented second layer can be solvent cast and dried or extruded and hardened as a separate coating on the first layer. The composite paint coat can be bonded to a coextruded size coat and semi-rigid plastic substrate panel to form a thermoformable laminate.
    Type: Grant
    Filed: July 3, 2001
    Date of Patent: August 10, 2004
    Assignee: Avery Dennison Corporation
    Inventors: Howard H. Enlow, John J. Markey, John E. Roys, Keith L. Truog, Frederick Young
  • Patent number: 6770683
    Abstract: A foam, comprising a blend of (a) from 0.1 to 4.9 weight percent ethylene/styrene interpolymer; and (b) from 95.1 to 99.9 weight percent polyethylene homopolymer or copolymer.
    Type: Grant
    Filed: February 22, 2002
    Date of Patent: August 3, 2004
    Assignee: Sealed Air Corporation (US)
    Inventors: Natarajan S. Ramesh, Thomas Greco
  • Publication number: 20040147625
    Abstract: A low-pressure CO2 tank or an air compressor with a refrigerated air dryer is attached to the vent zone of a standard twin-screw extruder. During extrusion, the gas is dissolved in the wood-plastic melt. The CO2 expands which foams the wood-plastic material.
    Type: Application
    Filed: March 18, 2004
    Publication date: July 29, 2004
    Inventors: David F. Dostal, Michael P. Wolcott
  • Patent number: 6767931
    Abstract: A foamable polymer composition is described which comprises: a1) a substantially random interpolymer produced from: i) one or more &agr;-olefin monomers; and ii) one or more vinyl or vinylidene aromatic monomers and/or one or more sterically hindered aliphatic or cycloaliphiatic vinyl or vinylidene monomers; and optionally iii) other polymerizable ethylenically unsaturated monomer(s); or a2) an interpolymer comprising polymerized units of ethylene and vinyl acetate; or a3) a combination of the polymers a1) and a2); and b) a polydiorganosiloxane having a viscosity of at least one million centistoke at 25° C.; and c) a foaming agent. The polydiorganosiloxane is useful for improving the abrasion resistance of foams comprising the substantially random interpolymer a1) and/or the ethylene/vinyl acetate interpolymer a2).
    Type: Grant
    Filed: January 9, 2003
    Date of Patent: July 27, 2004
    Assignee: Dow Global Technologies Inc.
    Inventors: Felipe Martinez, Antonio Batistini, Jerker B. L. Kjellqvist, Ronald Wevers
  • Patent number: 6765029
    Abstract: A method for dehydrating a porous cross-linked polymer conveniently to a low final water content is provided. A porous cross-linked polymer sheet is produced by a method which comprises causing a porous cross-linked polymer obtained by forming and polymerizing a water-in-oil type higher internal phase emulsion to be dehydrated by the use of non-woven fabric rolls furnished with an aspiration mechanism. Properly in this case, the porous cross-linked polymer is subjected to preliminary squeezing. In accordance with the present invention, a porous cross-linked polymer abounding in a water absorbing property to be dehydrated to a low final water content with a small number of rolls.
    Type: Grant
    Filed: June 13, 2002
    Date of Patent: July 20, 2004
    Assignees: Nippon Shokubai Co., Ltd., The Proctor & Gamble Company
    Inventors: Masazumi Sasabe, Katsuhiko Sakamoto, Kozo Nogi, Motohiro Arakawa
  • Publication number: 20040138320
    Abstract: A non-crosslinked polyolefin foam comprises a plastics component and a blowing agent. The plastics component comprises a first constituent and a second constituent. The first constituent is a Ziegler-Natta catalyzed linear low density polyolefin and the second constituent is a low density polyolefin in one embodiment. The Ziegler-Natta catalyzed linear low density polyolefin has a polydispersity of less than 10 and a melt flow index less than 10 g/10 minutes.
    Type: Application
    Filed: December 4, 2003
    Publication date: July 15, 2004
    Inventor: Leon Swennen
  • Patent number: 6762212
    Abstract: An extruded styrene resin foam obtained by extrusion-foaming of a styrene resin and excellent in environmental compatibility and excellent in flame retardant property and thermal insulating property, characterized in that it contains, as a blowing agent, 100 to 10% by weight of at least one of saturated hydrocarbons having 3 to 5 carbons and 0 to 90% by weight of other blowing agent, based on the total amount of the blowing agent, and contains (A) a halogenated flame retardant and (B) at least one compound selected from the group consisting of phosphorus type flame retardants containing nitrogen atom in a molecule, tetrazole compounds, cyanuric acid and derivatives thereof, isocyanuric acid and derivatives thereof, metal borates, and boron oxides.
    Type: Grant
    Filed: February 5, 2003
    Date of Patent: July 13, 2004
    Assignee: Kaneka Corporation
    Inventors: Youichi Oohara, Fuminobu Hirose, Takeshi Sato, Hiroshi Fujiwara, Toru Yoshida
  • Publication number: 20040132844
    Abstract: A method for producing an alkenyl aromatic polymer foam structure that comprises melting at least one alkenyl aromatic polymer resin. An effective amount of blowing agent mixture is dissolved in the at least one alkenyl aromatic polymer. The blowing agent mixture comprises at least one VOC blowing agent and acetone. The majority by mole percent of the VOC blowing agent is selected from n-butane, iso-butane, propane and combinations thereof. An extrudate is formed comprising the at least one alkenyl aromatic polymer resin, the at least one VOC blowing agent, and acetone. The extrudate comprises less than about 2.7 wt. % of the at least one VOC blowing agent. The extrudate is transferred to an expansion zone and permitted to expand to produce the foam structure. The foam structure has an extruded density less than about 7 lbs/ft3 and a basis weight of less than about 20 grams per 100 in2.
    Type: Application
    Filed: January 3, 2003
    Publication date: July 8, 2004
    Inventors: Gary A. Francis, Wen P. Wu
  • Patent number: 6759445
    Abstract: The present invention relates to form materials comprising polymeric material wherein the structure of the polymeric material contains elastic amorphous areas of nano-scale-size reinforced with self arranged crystalline domains of nano-crystals.
    Type: Grant
    Filed: March 27, 2002
    Date of Patent: July 6, 2004
    Assignee: The Procter & Gamble Company
    Inventors: Valery Alexandrovich Dyatlov, Bernhard Hanke, Bernhard Rieger, Judith Preuschen
  • Publication number: 20040127589
    Abstract: The invention provides open-cell microcellular polystyrene foams and a method for making the same. The method includes: adding a mixture comprising polystyrene and 8˜14 wt % of additive agent to a double screw extruder for blending; adding the blended mixture with a 2.0˜5.1 wt % of foaming agent to a single screw extruder for blending and foaming to obtain polystyrene foam. Average cell size of the polystyrene foam is equal to or less than 60 &mgr;m. Open cell content of the polystyrene foam is equal to or greater than 60%.
    Type: Application
    Filed: May 2, 2003
    Publication date: July 1, 2004
    Inventors: Mu-Li Chang, Pen-Chang Tseng, Chih-Chen Chang
  • Patent number: 6750264
    Abstract: Prepare a multimodal polymeric foam from a foamable composition containing a polymer, an absorbent clay, and a blowing agent composition containing water and carbon dioxide and that contains less than 0.2 parts by weight of bentonite based on 100 parts by weight of polymer.
    Type: Grant
    Filed: September 20, 2002
    Date of Patent: June 15, 2004
    Assignee: Dow Global Technologies Inc.
    Inventors: Chau Van Vo, Simon P. Lee, Kenji Matsue, Itsuki Nakatani
  • Publication number: 20040096744
    Abstract: Disclosed is a successively biaxially stretched film obtained by successive biaxial stretching method comprising extruding a melt of a &bgr;-crystal nucleating agent-containing polypropylene-based resin composition from a T-die, cooling the extruded resin on a chill roll, and stretching the resulting web sheet longitudinally and then transversely, wherein the longitudinally stretched sheet is made to have a degree of &bgr;-crystal orientation of less than 0.
    Type: Application
    Filed: August 21, 2003
    Publication date: May 20, 2004
    Inventors: Kiyoshi Sadamitsu, Naoki Ikeda, Manabu Hoki, Kenichiro Nagata, Koichi Ogino
  • Publication number: 20040092613
    Abstract: A method for the production of a biodegradable foamed product 7 from a base material and a blowing agent 1. The base materials are mixed with a blowing agent and any other required additives 1. The mixture 3, after extrusion 2, is placed in a microwave transparent mold 6 and processed in a microwave via distinct steps. The first step preheats the extrudate to a temperature just below the flash point 6. The second step 7 rapidly heats the extrudate beyond the flash point causing the extrudate to foam in the mold 7. By utilizing this method it is possible to produce shaped articles with uniform properties and with packaging properties such as compressibility, resilience and shock absorption.
    Type: Application
    Filed: February 3, 2003
    Publication date: May 13, 2004
    Inventors: John Gough Errington, Anya Jane Hornsey, Timothy James Chapman, Maria Louise Hastings, Philip James Quinn
  • Patent number: 6727291
    Abstract: A process prepares expandable propylene polymer beads by mixing propylene polymer melt with a volatile organic blowing agent and with a nucleating agent in an extruder, whereupon the extrusion and pelletization of the extruded takes place in a water bath under conditions of temperature and pressure at which practically no foaming of the pellets takes place.
    Type: Grant
    Filed: November 5, 2001
    Date of Patent: April 27, 2004
    Assignee: BASF Aktiengesellschaft
    Inventors: Christian Maletzko, Klaus Hahn, Isidor de Grave, Gerd Ehrmann, Franz-Josef Dietzen
  • Patent number: 6720362
    Abstract: Thermoplastic polymer foams having sound deadening properties satisfactory for demanding applications are provided which have mechanical strength, which are economical to manufacture, and which are hydrolytically stable. Methods of preparing these foams are also provided. The foams are useful in sound management, cushion packaging, filtering, and fluid absorption and exhibit one or more of the following properties: 1) average cell size greater than about 2 mm; 2) substantially open-cell structure and 3) relatively large pores connecting the cells. In order that the foam be acoustically active, the foam should possess a substiantially open-cell structure and a relatively low airflow resistivity. Foams with substantially open-cell structure and relatively low airflow resistivity are prepared by mechanically opening a foam having an average cell size greater than about 2 mm. In most cases, such mechanical opening creates relatively large pores connecting the cells.
    Type: Grant
    Filed: March 12, 2001
    Date of Patent: April 13, 2004
    Assignee: The Dow Chemical Company
    Inventor: Chung P. Park
  • Patent number: 6699421
    Abstract: Provided are a method for forming a foamed polypropylene resin sheet in which draw down and waving are not caused in heating the foamed sheet and in which inferior appearance such as partial thickness and wrinkles is not produced on the product, and a foamed formed article having an excellent shape obtained from the same. The method comprises a heating step for heating and softening the foamed polypropylene resin sheet and a forming step for bringing the heated foamed polypropylene resin sheet into contact with a forming mold to form it into a prescribed shape, wherein the foamed polypropylene resin sheet has an expansion ratio of 1.1 to 6 times, an open cell rate of 70% or less and a sheet thickness of 0.5 to 5 mm; and the foamed polypropylene resin sheet described above is heated in the heating step in the state that it is supported on a tabular sheet support.
    Type: Grant
    Filed: May 8, 2002
    Date of Patent: March 2, 2004
    Assignees: Chisso Corporation, Chisso Petrochemical Corporation
    Inventors: Ken Shimizu, Yuuichi Yamanaka, Hiroyuki Maehara
  • Patent number: 6696504
    Abstract: Production of extruded styrene resin foams which are excellent in environmental compatibility and retain highly efficient thermal insulation property and have appropriate strength properties is disclosed which is characterized by using as a blowing agent a blowing agent comprising mainly 40% by weight or more and 85% by weight or less, based on the whole amount of the blowing agent, of at least one ether selected from the group consisting of dimethyl ether, methyl ethyl ether and diethyl ether, and 15% by weight or more and 60% by weight or less, based on the whole amount of the blowing agent, of at least one saturated hydrocarbon selected from the group consisting of saturated hydrocarbons having 3 to 5 carbon atoms. The production is further characterized by providing a more desirable cell structure such as a specified shape of cells or the presence of larger and smaller cells.
    Type: Grant
    Filed: December 23, 1999
    Date of Patent: February 24, 2004
    Assignee: Kaneka Corporation
    Inventors: Takahiro Hayashi, Osamu Kobayashi, Jun Fukuzawa, Hiroshi Fujiwara
  • Publication number: 20040006149
    Abstract: A blowing agent blend for making polyolefin foams comprising isopentane and at least one co-blowing agent The co-blowing agent is either a physical co-blowing agent having a boiling point less than 28° C., or a chemical co-blowing agent, or combinations thereof The blowing agent blend comprises less than about 99 mol % isopentane.
    Type: Application
    Filed: July 2, 2002
    Publication date: January 8, 2004
    Inventors: Y. Paul Handa, Jiayan Gu
  • Publication number: 20030236313
    Abstract: Methods for making foamed elastomer gels are disclosed. Chemical foaming agents may be incorporated or gas may be injected into a molten gel and then using heating and cooling techniques and/or additives, gas bubbles are formed and preserved in the cooled and solidified elastomer gel.
    Type: Application
    Filed: February 11, 2003
    Publication date: December 25, 2003
    Applicant: EdiZONE, LC
    Inventor: Terry V. Pearce
  • Patent number: 6666998
    Abstract: A method for producing an at least partially open-celled foam foil on a basis of styrene polymers, nucleating agents, surfactants, physical foaming agents and, if required, further additives, such as foreign polymers and auxiliary materials, comprising a twin-screw extruder with identical parallel screws rotating in the same direction, wherein the twin-screw extruder has a length of at least 25 D (D=screw diameter), in particular 30 to 42 D, with a draw-in and plastification zone of a length of 10 to 15 D, and a mixing zone of a length of 3 to 6 D, and a following cooling zone.
    Type: Grant
    Filed: February 13, 2002
    Date of Patent: December 23, 2003
    Assignee: Reifenhäuser GmbH & Co. Maschinenfabrik
    Inventors: Ulrich Berghaus, Stephan Homer, Hubert Jansen
  • Patent number: 6667350
    Abstract: An insect resistant foam building material includes calcium borate incorporated therein in sufficient quantity to provide insect resistance. Calcium borate may be incorporated in expanded polystyrene or extruded polystyrene foam materials as part of the foam manufacturing process. The resulting insect resistant calcium borate infused foam material is non-toxic to humans and resistant to leaching out of the protective calcium borate compound from the foam material under high moisture conditions.
    Type: Grant
    Filed: October 17, 2002
    Date of Patent: December 23, 2003
    Assignee: Plymouth Foam, Incorporated
    Inventor: George G. Satula
  • Publication number: 20030229167
    Abstract: PTFE pellets with good bulk density, homogeneity, and flowability properties may be obtained by:
    Type: Application
    Filed: June 10, 2002
    Publication date: December 11, 2003
    Applicant: Asahi Glass Fluoropolymers USA, INC.
    Inventors: Pamela J. Baron, Gary Eckrote, Tonya James, Ronald Partridge, Timothy C. Duzick
  • Patent number: 6649666
    Abstract: The invention includes a process for providing a coupled propylene polymer foam. The invention also includes any composition comprising a product formed by the process of the invention and any article formed from such a composition.
    Type: Grant
    Filed: May 21, 2002
    Date of Patent: November 18, 2003
    Assignee: Dow Global Technologies Inc.
    Inventors: Michael D. Read, Kevin R. Hughes, Jin Zhao, Thomas J. Styranec, Eung Kyu Kim
  • Publication number: 20030212157
    Abstract: A method of preparing a porous fiber, the method including blending a natural polymer having a thermal stability with a synthetic polymer having a thermal stability, wherein the thermal stability of the natural polymer is different from the thermal stability of the synthetic polymer, and wherein the natural polymer and synthetic polymer from immiscible phases; extruding the blended polymers while heating at a predetermined heating rate to the fiber spinning temperature; spinning the fibers while maintaining the temperature; and heating the fibers at a heating rate that maintains the natural polymer in a fiber form and that removes the synthetic polymer, whereby a porous fiber is formed.
    Type: Application
    Filed: December 16, 2002
    Publication date: November 13, 2003
    Inventors: John F. Kadla, Richard D. Gilbert, Richard A. Venditti, Satoshi Kubo
  • Patent number: 6638985
    Abstract: A continuous method for making foams having uniform and/or small cell sizes and articles made with these foams are described. The method allows for adjusting or controlling cell size and cell size distribution by controlling temperature and/or blowing agent concentration. The foams feature small and/or uniform cell sizes and may be comprised of amorphous thermoplastic polymers, pressure sensitive adhesive compositions, and immiscible thermoplastic polymer compositions. A method for coextruding the foams is also described.
    Type: Grant
    Filed: November 27, 2001
    Date of Patent: October 28, 2003
    Assignee: 3M Innovative Properties Co.
    Inventors: Mark David Gehlsen, David Loren Vall, Craig Allen Perman, Bonnie Weiskopf Albrecht
  • Patent number: 6632382
    Abstract: The present invention generally relates to processes for preparing extruded foam products and more particularly to a process for producing such products wherein surface defects are minimized. There has been a movement to replace conventional halo-carbon blowing agents in favor of purportedly more environmentally safe halo-carbon free blowing agents such as carbon dioxide, nitrogen, argon, water, air, nitrogen, and helium. However, these halo-carbon free blowing agents, in particular carbon dioxide, have higher foaming rates and higher volatility leading to greater surface defects in the extruded foam. The present invention employs polyethylene wax to reduce or eliminate the occurrence of surface defects where halo-carbon free blowing agents are employed in an extruded foam manufacture process.
    Type: Grant
    Filed: February 29, 2000
    Date of Patent: October 14, 2003
    Assignee: Owens-Corning Fiberglas Technology, Inc.
    Inventors: Larry Michael Miller, Raymond Marshall Breindel, Mitchell Zane Weekley, Thomas Earl Cisar
  • Publication number: 20030191203
    Abstract: An extruded styrene resin foam obtained by extrusion-foaming of a styrene resin and excellent in environmental compatibility and excellent in flame retardant property and thermal insulating property, characterized in that it contains, as a blowing agent, 100 to 10% by weight of at least one of saturated hydrocarbons having 3 to 5 carbons and 0 to 90 % by weight of other blowing agent, based on the total amount of the blowing agent, and contains (A) a halogenated flame retardant and (B) at least one compound selected from the group consisting of phosphorus type flame retardants containing nitrogen atom in a molecule, tetrazole compounds, cyanuric acid and derivatives thereof, isocyanuric acid and derivatives thereof, metal borates, and boron oxides.
    Type: Application
    Filed: February 5, 2003
    Publication date: October 9, 2003
    Applicant: Kaneka Corporation
    Inventors: Youichi Oohara, Fuminobu Hirose, Takeshi Sato, Hiroshi Fujiwara, Toru Yoshida
  • Patent number: 6624208
    Abstract: Composition that can be used as a polymer blowing agent, comprising from 60 to 98% of HFC-134a and from 2 to 40% of cyclopentane; polymeric composition comprising it, and process for manufacturing an expanded polymer using it.
    Type: Grant
    Filed: February 1, 2002
    Date of Patent: September 23, 2003
    Assignee: Atofina
    Inventors: Arnaud Albouy, Gérard Guilpain, Richard McMaster Crooker
  • Patent number: 6613811
    Abstract: Microcellular thermoplastic elastomeric polymeric structures are provided. The articles have an average cell size of less than 100 &mgr;m and a compression set ranging from less than about 30% to less than about 5%, and a rebound value of at least 50%. The articles may be formed from a thermoplastic elastomeric olefin, preferably metallocene-catalyzed polyethylene. The density of the articles ranges from less than 0.5 gm/cm3 to less than 0.3 gm/cm3.
    Type: Grant
    Filed: November 8, 2000
    Date of Patent: September 2, 2003
    Assignee: Trexel, Inc.
    Inventors: Matthew Pallaver, Sung W. Cha
  • Patent number: 6610755
    Abstract: A thermoplastic foam comprises a styrenic polymer and a blowing agent consisting of 100% carbon dioxide. The thermoplastic foam has no visible corrugations and an average cell size of 0.20 mm to 0.35 mm.
    Type: Grant
    Filed: March 28, 2002
    Date of Patent: August 26, 2003
    Assignee: Dart Container Corporation
    Inventors: Wayne J. Myer, Blaine M. Kelley
  • Patent number: 6610754
    Abstract: Provided is a foamable composition adapted to form a cross-linked novolac-epoxy resin foam. The foamable composition is formulated from a composition comprising at least one novolac resin, at least one epoxy resin, and at least one blowing agent.
    Type: Grant
    Filed: October 7, 2002
    Date of Patent: August 26, 2003
    Assignee: American Foam Technologies, Inc.
    Inventor: Samuel L. Rader
  • Patent number: 6610757
    Abstract: An expandable vinyl chloride resin composition that the expansion ratio of a vinyl chloride resin can be greatly increased by the use of thermally decomposable inorganic blowing agents without the use of organic solvent blowing agents, and which comprises 100 parts by weight of a vinyl chloride resin, 0.5 to 30 parts by weight of, as a processing aid, a (meth)acrylic acid ester polymer having a specific viscosity of not less than 0.73 measured at 30° C. with respect to a solution of 0.1 g of the polymer dissolved in 100 ml of chloroform, and not less than 0.3 to less than 2 parts by weight of a thermally decomposable inorganic blowing agent such as sodium bicarbonate.
    Type: Grant
    Filed: October 31, 2001
    Date of Patent: August 26, 2003
    Assignee: Kaneka Corporation
    Inventors: Takenobu Sunagawa, Mitsutaka Sato, Noriko Sakashita, Mamoru Kadokura
  • Patent number: 6602923
    Abstract: Processes for producing alkenyl aromatic foams utilizing a cycloaliphatic gas as blowing agent, are described. Also disclosed are alkenyl aromatic foams produced by the process which exhibit increased thermal insulation properties.
    Type: Grant
    Filed: February 1, 2001
    Date of Patent: August 5, 2003
    Assignee: Reedy International Corporation
    Inventors: Walter R. Harfmann, Michael E. Reedy
  • Publication number: 20030144370
    Abstract: The combination of fluoropolymer processing aid with foam cell nucleating agent gives a combined processing aid that is far superior to either individually when used in the extrusion of melt processible polymers.
    Type: Application
    Filed: January 22, 2003
    Publication date: July 31, 2003
    Inventors: Charles W. Stewart, Stuart K. Randa, Savvas G. Hatzikiriakos, Evgueni E. Rozenbaoum, Marlin D. Buckmaster
  • Patent number: 6596783
    Abstract: The present invention provides a process for producing a foamed resin article, the process comprising: a step (the first step) of impregnating any one crystalline thermoplastic resin or resin composition containing, as an elementary ingredient, a crystalline thermoplastic resin selected from a certain group, under an elevated pressure which is not lower than the critical pressure of a substance with which the selected crystalline thermoplastic resin or resin composition is to be impregnated, with a fluid of the substance, and a step (the second step) of releasing the resin or resin composition impregnated with the substance from the foregoing pressurized condition in a period of less than 10 seconds.
    Type: Grant
    Filed: March 12, 2002
    Date of Patent: July 22, 2003
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Mitsunori Nodono, Ryuma Kuroda
  • Patent number: 6596784
    Abstract: A thermoplastic window covering article, and the method for making the same. The window covering article is formed of a closed cell foam of a thermoplastic strengthened with diatomaceous earth having less than about two percent moisture.
    Type: Grant
    Filed: July 19, 2002
    Date of Patent: July 22, 2003
    Assignee: Nien Made Enterprise Co., Ltd.
    Inventor: Gordon King
  • Patent number: 6593384
    Abstract: Systems and techniques for forming microcellular polymeric material, via injection molding, blow molding, continuous extrusion, or the like, at very low blowing agent levels, are described. The invention involves, in one aspect, the discovery of a region of very low blowing agent level where, surprisingly, microcellular material can be formed. Articles with particularly good surface properties are provided.
    Type: Grant
    Filed: December 7, 2000
    Date of Patent: July 15, 2003
    Assignee: Trexel, Inc.
    Inventors: Jere R. Anderson, Kelvin T. Okamoto, Kent G. Blizard
  • Patent number: 6593380
    Abstract: A continuous method for making foams having uniform and/or small cell sizes and articles made with these foams are described. The method allows for adjusting or controlling cell size and cell size distribution by controlling temperature and/or blowing agent concentration. The foams feature small and/or uniform cell sizes and may be comprised of amorphous thermoplastic polymers, pressure sensitive adhesive compositions, and immiscible thermoplastic polymer compositions. A method for coextruding the foams is also described.
    Type: Grant
    Filed: November 27, 2001
    Date of Patent: July 15, 2003
    Assignee: 3M Innovative Properties Company
    Inventors: Mark David Gehlsen, David Loren Vall, Craig Allen Perman, Bonnie Weiskopf Albrecht
  • Patent number: 6590004
    Abstract: The present invention is a foam composite wood replacement material and a method for its manufacture. One embodiment of the present invention is a cellulosic/polymer foamable composite material. The composite material may include at least one cellulosic filler in the amount of about 20% to about 60% by weight and a plastic material in the amount of about 40% to about 80% by weight. The plastic material may include stabilizer(s) in an amount of about 1 to about 10 parts per 100 parts of a polymer resin, lubricant(s) in an amount of about 1 to about 12 parts per 100 parts of the polymer resin, process aid(s) in an amount of about 2 to about 15 parts per 100 parts of the polymer resin, and blowing agent(s) in amount of about 0.25 to about 5 parts per 100 parts of the polymer resin. Examples of the polymer resin are polyvinyl chloride and polypropylene. The foamable composite may be used to make structural components such as siding units.
    Type: Grant
    Filed: December 31, 2001
    Date of Patent: July 8, 2003
    Assignee: Crane Plastics Company LLC
    Inventor: Burch E. Zehner
  • Patent number: 6586482
    Abstract: A continuous method for making foams having uniform and/or small cell sizes and articles made with these foams are described. The method allows for adjusting or controlling cell size and cell size distribution by controlling temperature and/or blowing agent concentration. The foams feature small and/or uniform cell sizes and may be comprised of amorphous thermoplastic polymers, pressure sensitive adhesive compositions, and immiscible thermoplastic polymer compositions. A method for coextruding the foams is also described.
    Type: Grant
    Filed: November 27, 2001
    Date of Patent: July 1, 2003
    Assignee: 3M Innovative Properties Company
    Inventors: Mark David Gehlsen, David Loren Vall, Craig Allen Perman, Bonnie Weiskopf Albrecht
  • Patent number: 6583189
    Abstract: A thermoplastic article, and the method for making the same. The article is formed of a closed cell foam thermoplastic or substantially solid thermoplastic strengthened with diatomaceous earth having less than about two percent moisture.
    Type: Grant
    Filed: July 19, 2002
    Date of Patent: June 24, 2003
    Assignee: Nien Made Enterprise Co., Ltd.
    Inventor: Gordon King
  • Patent number: 6583188
    Abstract: This invention describes grafted blend compositions, processes for their preparation and fabricated articles, especially foams therefrom. The blends exhibit enhanced melt strength, melt elongation greater than or equal to about 20 mm/s, increased upper service temperature, increased modulus, and increased hardness. The grafted blend compositions have little or no high shear viscosity increase over a corresponding polymer of the same chemical composition absent the coupling agent.
    Type: Grant
    Filed: March 4, 2002
    Date of Patent: June 24, 2003
    Assignee: The Dow Chemical Company
    Inventors: Bharat I. Chaudhary, Thoi H. Ho, Thomas Oswald, Jennifer DellaMea
  • Patent number: 6583193
    Abstract: An extruded, coalesced foam strand propylene polymer material that is either open-celled and useful for sound insulation applications or close celled and useful for thermal insulation applications. An apparatus suitable for preparing such foams with an expanded cross-section.
    Type: Grant
    Filed: March 9, 2001
    Date of Patent: June 24, 2003
    Assignee: Dow Global Technologies Inc.
    Inventors: Chung P. Park, Michel Brucker, Georges Eschenlauer, Michael E. Schaller, Jean-Francois Koenig
  • Patent number: 6583190
    Abstract: An extruded thin sheet foam is disclosed prepared from a polyolefin resin in which the blowing agent comprises a blend of from about 1 to 25% by weight of carbon dioxide and the balance of C3 to C4 VOCs. Thin foam sheets produced with the blowing agent age about twice as fast as foams prepared with VOCs, are remarkably stable, and can be produced at high throughputs.
    Type: Grant
    Filed: December 27, 2000
    Date of Patent: June 24, 2003
    Assignee: Sealed Air Corporation (U.S.)
    Inventors: Shau-Tarng Lee, Natarajan S. Ramesh, James Baker