Abstract: Polyaddition products containing urethane groups are produced by reacting an isocyanate group containing distillation residue with a compound having a molecular weight less than 600 containing at least two alcoholic hydroxyl groups. The distillation residue is obtained in the commercial production of tolylene diisocyanate. The distillation residue and hydroxyl compound are reacted in amounts such that the NCO/OH equivalent ratio is less than 1.5:1. The polyaddition reaction is carried out at a temperature in the range of 50.degree. to 220.degree. C. The reaction is carried out in a reaction screw extruder preferably having self-cleaning screw geometry. The polyaddition products are useful as molding compositions, reactive fillers and starting materials in the production of flame-resistant polyurethane plastics.

Abstract: A mixing head suitable for mixing two or more liquids is provided. During the mixing process, the liquids are first contacted in a zone of small dimensions in which turbulent mixing occurs and are then discharged into a zone of larger dimensions in which laminar flow is established. The two zones are so designed that there is a single piston operating in both zones and discharging the mixed product. The mixing head can be used to mix a polyol and a polyisocyanate during the formation of polyurethanes.

Abstract: A method and apparatus for forming a chemical composition from two liquid components selected for cross-linking reaction with each other and a product of the method are disclosed, the method including the steps of selecting the components for interaction to form a solid chemical composition product, the components being intimately mixed with an inert blowing agent to avoid altering chemical characteristics of the chemical composition product and to vary density of the product, the mixture being conducted to an application zone through an expansion chamber having internal dimensions selected for achieving substantially complete expansion of the mixture to a substantially relaxed condition as it passes from the expansion chamber. In one embodiment, means are provided for spraying the product onto the application zone. In another embodiment, delay means are provided for causing increased viscosity of the components. Mesh material forms an integral portion of one preferred product.

Abstract: Described is a process for preparing extruded functional fluid and solid-containing thermoplastic foamed particles using chemical blowing agents or direct gas extrusion processes, uses of such foamed particles and articles produced from said foamed particles. The process described involves the use of a single screw or double screw extruder wherein the resin particles are added upstream from the functional fluid or solid which, in turn, is added to the extruder upstream from the point of addition of the liquid or gaseous blowing agent.

Abstract: Polyurethane foams which may be rendered flame resistant by the addition of flame retardants are produced by reaction between a carbohydrate, a polyisocyanate and water in the presence of a suitable surfactant and polyurethane forming catalyst.

Abstract: When producing molded foam parts from liquid reaction components, the charge of gas in the initial components has a significant effect on the foam structure and quality of the molded part. This invention provides a process and apparatus for introducing a gas into at least one of the liquid reaction components prior to mixing said components for reaction. The component which is to be charged with gas is circulated from a feed tank through a recycle circuit to a compression zone which is maintained at a higher pressure than that of the feed tank. Said gas is admixed with said component at the point of initiation of the compression zone and the higher pressure is relieved through a throttle element prior to returning the gas-charged component to the feed tank. A finely divided stable gas dispersion which can be mixed with other components for reaction is obtained.

Abstract: In a process for producing a thermoplastic resin foam which comprises continuously heat-foaming a foamable thermoplastic resin sheet containing a heat-decomposable organic blowing agent with a heated gas, the improvement wherein a gas containing sublimation products generated by the heat-foaming of the foamable sheet is burned to decompose the sublimation products and obtain a treated gas having a substantially reduced content of the sublimation products, and the treated gas is then used as the heated gas for the heat-foaming of the foamable sheet; and a apparatus for producing a thermoplastic resin foam by continuously heat-foaming a foamable thermoplastic resin sheet, said apparatus comprising a heat-foaming chamber having an inlet portion for feeding the foamable thermoplastic resin sheet, an outlet portion for discharging the foamed sheet, a discharge port for a gas containing sublimation products generated by the heat-foaming of said foamable sheet, and a supply port for a heated gas, said discharge port

Abstract: A mixing head for two or more reactive components especially anionically polymerizing caprolactam comprises a piston formed with recess means which, at the end turn toward the outlet of the mixing chamber, intercept respective streams of the components which are normally trained upon one another and thus prevent mixing just before the piston blocks the ports through which these streams are directed into the mixing chamber.

Abstract: A method for the production of fire retardant foam such as flexible polyurethane foam. The method includes the mixing of urea with one or more of the foam producing reactants prior to combining or at the time of combining such reactants to produce the foam material. In one embodiment, the urea is pre-mixed with the polyol reactant in a slurry apparatus. In another embodiment, urea is injected into a mixing head at the time of mixing the foam producing reactants. The urea component may be employed in amounts of about 30 to 45% by weight of the total foam mass composition.

Abstract: Process for obtaining cellular materials, based on unsaturated polyester in optionally containing reinforcing and/or inert fillers, having a density between 0.2 and 1.0 kg/l by moulding under pressure a liquid foam of said resins, characterized by the fact that the liquid foam based on unsaturated polyester resins containing conventional additives, optionally containing an inert and/or reinforcing charge of mineral or organic fibers having a length which is less than 5 mm, preferably less than 3 mm and more preferably less than 1.5 mm, obtained by mechanical introduction of a gas and/or by means of a chemical and/or physical foaming agent, is firstly introduced into an open half-mould optionally containing a further fiber reinforcement, by casting an amount higher than the free volume of the mould, and subsequently said foam is cross-linked.

Abstract: The invention relates to a method and a device for producing a reaction mixture from flowable foam-forming or solid-forming components (preferably polyurethane forming components) which are conveyed continuously and are mixed together or are circulated. The quantity to be conveyed is preselected. The injection pressure is preselected and the circulatory pressure is measured for each component. The predetermined quantity and pressure to be conveyed as well as the measured value are preferably fed into a control computer during the circulation and the mixing process and are compared with actual values. Cavities are filled out with the reaction mixture produced and, in particular, molded articles are produced in molds.

Abstract: Disclosed is a method for forming pre-froth plastics foam which comprises the steps of mixing the plastics components with a volatile liquid under pressure, causing the mixture to flow to a point of use, and maintaining a series of controlled pressure drops by means of present automatic valves or by passive means such as orifice plates. Typical foams are polyurethane and phenolic.

Abstract: Pressure vessels are disclosed for containing a foamable mixture of liquid and a blowing agent for incrementally or continuously dispensing a foam of constant foam-volume ratio. Liquid compositions having coating or polymeric solids are capable of being foamed and dispensed with the apparatus. The method and apparatus are especially advantageous in dispensing foamed coatings, paints or adhesives with superior control.

Abstract: The invention is a method of making a molded reaction injection molded elastomer which will release from its mold without the presence of externally applied mold release agents. The reaction injection molded (RIM) elastomer is made by injecting exactly two streams via a RIM machine into a mold cavity of the desired configuration, a formulation comprising in the first stream amine terminated polyethers of greater than 1,500 molecular weight, an amine terminated chain extender and an internal mold release agent, and in the second stream an aromatic polyisocyanate. The resulting RIM elastomer may be removed from the mold easily. RIM elastomers are useful, for example, for automobile body parts.

Abstract: A deformable and durable polyurethane foam molding is made from the reaction product of a polyether polyol component and a polyisocyanate component. The polyether polyol component is a polyether having at least two hydroxyl groups, a molecular weight of from 400 to 10,000 and at least 10 wt. % hydroxyl groups which are primary hydroxyl groups. The polyisocyanate component is a mixture of from 60-90 wt. % 4,4'-diphenyl methane diisocyanate and from 3-30 wt. % 2,4'-diphenyl methane diisocyanate. Such reaction mixture is prepared in each of at least two mixing heads. The index of reaction mixture is different from that in the other mixing head. The mixture is then introduced into associated zones of a mold cavity where the mixture is allowed to foam. The molding is subsequently removed from the mold cavity. These polyurethane foam moldings are particularly useful in making seat cushions.

Abstract: In reaction injection molding facilities of the recirculation type, a closed loop system controls the addition of a gas to a mixture of liquid and gas. The system takes a sample volume of the liquid and forces a plunger into the sample volume. The distance travelled by the plunger between two preset pressures of the sample is measured and compared to a reference distance to get a control signal that is used to operate a valve that controls gas admission to the mixture.

Abstract: Methods of sealing particular areas, including subterranean well formations, are provided wherein the methods utilize an isocyanate polymer suitable as a sealing agent having a controllable gelation time in the presence of water without formation of excess foam by using one or more typical di- or polyisocyanates with one or more alcoholic or acidic compounds and a particular catalyst namely, triethylene-diamine, Groups 3 and 4 metal-organic compounds or mixtures thereof. A particularly useful catalyst is tributyl titanate.

Abstract: The present invention provides a method of utilizing polyurethane foam for insulation purposes in existing walls and other areas without expanding the existing structure. Conventional polyurethane foam post-expands, causing pressures as high as 6 p.s.i., which results in swelling and expanding of existing wall structures. The process of the present invention places the polyurethane foam into its final position in a totally pre-expanded form, making it possible to insulate homes, office buildings, and any other existing structure with foam having a density as low as 0.5 lb. per cu. ft. with no distortion of even the weakest type of structure.

Abstract: A continuous process for the production of flame-resistant foamed plastics material by condensation of aqueous aminoplast precondensates with diisocyanates or polyisocyanates, wherein, in a first mixing stage, the isocyanate is mixed with 4 to 14% by weight of catalyst, the catalyst being an organic amine and/or an organic metal compound, at temperatures of 40.degree. to 130.degree. C., with a residence time of 1 to 8 seconds, and directly thereafter, in a second mixing stage, the aminoplast precondensate and, simultaneously but separately from the aminoplast, an acid curing catalyst are introduced, after which the foamable mixture thereby produced is discharged continuously.

Abstract: The invention disclosed herein is concerned with a process for mixing a plurality of viscous rapidly reacting, fluid materials and an apparatus with which to perform this process. In this process the fluid materials are initially introduced into a mixing chamber and mixed with a gas, preferably in such a way that an angular momentum is imparted to the mixture. The mixture is then fed into a static mixer which has a short residence time spectrum. The apparatus comprises a cylindrical mixing chamber with a gas inlet and at least one nongaseous fluid material inlet arranged to direct flow tangentially to the interior surface of the mixing chamber. Other inlets may be provided downstream of these initial inlets but before a static mixer with which said mixing chamber communicates. An outlet is provided downstream of said static mixer which preferably has intersecting baffle plates, a low pressure loss and a short residence time spectrum.

Abstract: Here is described the manufacture of a cured urea/formaldehyde resin foam having a shrinkage on drying of less than 20% by volume, by a method which includes the step of producing a homogeneous wet foam from an aqueous resin solution and an aqueous solution of a hardener for the resin, the freshly made wet foam having a total reactive resin solids content of at least 35% by weight. Apparatus for producing the cured resin foam includes a foaming column having upstream and downstream regions constituted by different inert materials.

Abstract: The invention is directed to a method and device for the discontinuous production of block foam. The device has a mixing unit provided with component feed lines and a stirrer. The device is vertically movable on a bridgelike framework. The mixing unit has a bottomless cylindrical shell which serves as a mixing container. The bottomless cylindrical shell can be arranged on a head plate and can be placed on the bottom of a mold placed beneath it. On the bottom of the mold is a flexible elastic layer on top of which is arranged a plastic film.

Abstract: A process for the preparation of a dimensionally stable one-component polyurethane foam from a storage-stable mixture, under pressure, of a prepolymer based on polyols and containing isocyanate groups and an organic blowing agent, with or without additives, by releasing the pressure and allowing the mixture to react with the atmosphere and cure, wherein the foamable mixture, which contains from 0.1 to 15% by weight, based on the weight of the prepolymer containing isocyanate groups, of a blowing agent is introduced into the inner container of a two-compartment pressure pack, which pack contains a pressure medium in the outer container, and is discharged, when required, through a dispensing device.

Abstract: The invention is directed to a device for the discontinuous production of block foam comprising a mixing unit, a means for moving the unit approximately vertically into and/or out of a mold with the unit having reaction component feed lines, a stirring means, and a mixing container having a plate with feed openings for the reaction components characterized in that(A) a distributing device is arranged below the feed opening for one of the components and(B) the mixing container comprises a bottomless cylindrical shell, the lower rim of which can be placed on the bottom of the mold.

Abstract: A process for the manufacture of dimensionally stable polyurethane foams by releasing, and curing by interaction with the atmosphere, a mixture, which is under pressure, of prepolymers, containing isocyanate groups, and blowing agents, with or without assistants and additives, wherein the prepolymers, containing isocyanate groups, are obtained by reaction of organic polyisocyanates with difunctional to octafunctional polyester-polyols and/or polyether-polyols, containing chemically bonded tertiary amino groups in the polymer chain, or, preferably, with mixtures of such polyester-polyols and/or polyether-polyols and nitrogen-free polyester-polyols and/or polyether-polyols.

Abstract: The instant invention broadly relates to a process and apparatus for filling a cavity with a reactive mixture. More particularly, the invention relates to a process for filling cavities, particularly mold cavities, with a reactive, flowable mixture which preferably forms foam, wherein at least two reaction components are brought into a mixing zone, where they are mixed and then brought into the cavity, the improvement wherein at the beginning of the filling process, during a limited time interval, the reaction mixture is fed into the cavity under low flow velocity until the mixture has reached a certain level in the cavity, and subsequently the remaining mixture to be injected, is fed in under increased flow velocity.

Abstract: A foam material, such as a polyurethane foam, is formed by mixing a polymer forming material with a blowing agent and two catalysts, one catalyst being provided to catalyze polymer formation and the other catalyst being provided to catalyze blowing. An auxiliary blowing agent in the form of a vaporizable substance, such as methylene chloride, is also incorporated. In one embodiment, the mixed components are maintained in a reaction vessel prior to application of same to a surface on which the foam is allowed to expand. In a further embodiment, in the case where the foam is polyurethane foam and the vaporizable substance is methylene chloride, the mixed components are maintained in a reaction vessel prior to application of same to a surface on which the foam is allowed to expand and the methylene chloride is used in an amount in excess of 12% of the weight of the polyurethane-forming material.

Abstract: A system and method is disclosed for continuously producing and dispensing foam material including storage containers with respective delivery lines for delivering, via separate motor driven pumps, a foaming agent solution and curable synthetic resinous material to a mixing gun. An air compressor supplies compressed air which is first heated and then directed to the mixing gun wherein the components are mixed in the proper proportions to produce and dispense foam to the point of placement. The system includes an electric motor which conjointly drives the separate pumps which supply the constituent materials to the mixing gun under predetermined constant pressures and continuous flow conditions so as to produce a homogeneous and continuous foam product of desired density generally free of streaks and inconsistencies.

Abstract: In a process for the production of a plastic organopolysiloxane molding composition which can be stored under pressure and with exclusion of moisture, and which, on release of the pressure and under the action of water or atmospheric moisture, is converted into an elastomeric, fine-pored foam molding or foam coating, which comprises forming a mixture of an .alpha.,.omega.-dihydroxypolydiorganopolysiloxane with a silicon-containing crosslinking agent, introducing the mixture into the inner container of a two-container pack which consists of a rigid outer container and a flexible inner container located within the outer container and provided with a dispensing valve which extends to the exterior, and placing the mixture under pressure.

Abstract: A method of after-foaming a mixture containing a foam and a resin solution. The foam component is brought into contact with the resin solution by means of a suction action. The after-foaming is produced due to said suction action and by superfluous air present.

Abstract: The present invention relates to a method for producing foam plastics and a device for effecting same. The method resides in foaming with continuous and proportioned injection of all components successively in two stages, mixing water, resin and a foaming agent under pressure with compressed air to obtain homogenized foam with a foam coefficient of 15 to 20, with subsequent injection thereinto of a curing catalyst together with compressed air. The device for carrying out the proposed method comprises proportioners the inlets whereof are connected to tanks each being intended for a respective component, as well as curing and foaming chambers communicating through two closely adjacent coaxially arranged pipes forming an annulus, the outer pipe being provided with diametrically oposite connections for letting into the annulus the catalyst and compressed air.

Abstract: In a preferred embodiment, minute bubbles of a suitable gas are rapidly entrained in a liquid chemical constituent of a reaction injection molding system (e.g., polyurethane) to reduce the viscosity of the constituent and the density of parts molded therefrom. A small portion of the constituent is continuously withdrawn from and returned to a main holding tank via a recirculation line wherein minute gas bubbles are dispersed from a microporous stone into the flowing portion of the constituent. The recirculating and gas entraining processes are continued until a predetermined quantity of the gas is dispersed in the molding constituent.

Abstract: This invention relates to methods and apparatus for successively dispensing predetermined quantities of urea formaldehyde foamed resin mixture having as constituents a resin component and a hardener component in which a prefoamed one of said components and the other component are independently fed under pressure to a mixing chamber where they are mixed and from which, they are dispensed, any residue of the urea formaldehyde foamed resin mixture left in the mixing chamber after said predetermined quantity has been dispensed therefrom being swept and removed prior to the mixing chamber being supplied with the next batch of said components.The present invention is particularly useful for filling pre-cast cavity building blocks with insulating foamed material.

Abstract: The instant invention relates to a process and apparatus for the preparation of a reaction mixture for the production of foam materials from at least two components, wherein one of the components, before it is mixed with the remaining components to form the reaction mixture, is passed through a constriction at a predetermined flowrate. The constriction produces a zone of reduced pressure and a gas is fed into the reduced pressure zone.

Abstract: Polyester foam is formed by simultaneously cross-linking an unsaturated polyester resin and generating carbon dioxide as a blowing agent. The foam-forming components are divided into two equal volume parts which are metered together to effect the simultaneous reactions and form the foam. Apparatus is described for effecting the foam-forming method.

Abstract: Stable foams of reaction resins and/or condensation resins can be obtained by adding a blowing agent which is gaseous under normal conditions to the resin under pressure, the gas liquid interface being enlarged while dispensing with moving equipment, allowing the mixture to expand and to cure.

Abstract: The invention relates to a frothing method for mixing a liquid propellant having a low boiling point with further components for the production of foamed material, more particularly polyurethane. The invention also relates to an apparatus for carrying out the method with a mixing head for high pressure mixing of the main components in a mixing chamber. The foam production is carried out in two stages involving a first chamber for receiving and premixing reactive polymeric components, and a second chamber intersected by the first into which the mix components are advanced while the frothing propellant is injected at the intersection. The frothed reactive polymeric mix is then discharged from the second chamber into a suitable mold for forming the finished polymerized product.

Abstract: A mixing head for a reaction injection molding machine, which incorporates several beneficial features, comprises a body having a bore, which defines a mixing chamber, and a plurality of nozzle orifices opening into the mixing chamber for conducting reactive polymeric components thereto. A plunger is mounted for reciprocal movement in the mixing chamber to control flow of the reactive components through the nozzle orifices to form a homogeneous polymer mix, e.g. a polyurethane or polyisocyanurate mix, in the chamber, and serves also to eject the resulting mix from the chamber. The plunger is controlled by an actuator piston and is linked thereto by a universal coupling that minimizes plunger binding in the mixing chamber due to misalignment between the plunger and actuator.

Abstract: The instant invention relates to an improved process for the production of cold-hardening polyurethane foams through the reaction of modified polyisocyanates with compounds having at least two active hydrogen atoms in the presence of blowing agents. The improved process is characterized by the fact that the modified polyisocyanate is prepared in a preliminary stage immediately before foaming.