Chemical Reactant Is Ethylenically Unsaturated Patents (Class 522/114)
  • Patent number: 11154737
    Abstract: Described are flame retardant, porous plastic flame arrestors. The flame retardant, porous plastic flame arrestor is formed by irradiating a flame retardant polymer resin to achieve a fractional melt index, grinding the flame retardant polymer resin into a powder, and sintering the flame retardant polymer resin to form a porous structure. Irradiating the flame retardant polymer resin increases the resin's molecular weight and reduces the resin's melt index through crosslinking.
    Type: Grant
    Filed: December 7, 2015
    Date of Patent: October 26, 2021
    Assignee: M.A. INDUSTRIES, INC.
    Inventors: Michael W. Smith, Delores Sewell, Thomas Fleming
  • Patent number: 10974209
    Abstract: A polymerizable composition for forming an ion-exchange resin precursor, the polymerizable composition containing a monomer component and polyethylene particles in an amount of 50 to 120 parts by mass per 100 parts by mass of the monomer component, wherein the monomer component contains an aromatic monomer for introducing ion-exchange groups and a nitrogen-containing aliphatic monomer, the nitrogen-containing aliphatic monomer being present in an amount of 10 to 35% by mass in said monomer component. An ion-exchange membrane is produced by applying the polymerizable composition onto a polyolefin type filament base material and polymerizing the polymerizable composition to form an ion-exchange resin precursor and, thereafter, introducing ion-exchange groups into the precursor.
    Type: Grant
    Filed: August 30, 2017
    Date of Patent: April 13, 2021
    Assignee: ASTOM CORPORATION
    Inventors: Maki Kinoshita, Masayuki Kishino, Shunichiro Nakatsukasa, Kenji Fukuta
  • Patent number: 10563075
    Abstract: An actinic ray-curable-type inkjet ink composition for 3D printing includes an acrylate monomer A capable of forming a homopolymer having a glass transition temperature of from 25° C. to 120° C.; an acrylate monomer B capable of forming a homopolymer having a glass transition temperature of ?60° or higher and lower than 25° C.; a bifunctional acrylate oligomer C having a weight-average molecular weight of from 2,000 to 20,000; and an acylphosphine oxide compound, in which the mass content of bifunctional or higher-functional acrylate compounds is 15% by mass or less.
    Type: Grant
    Filed: May 19, 2017
    Date of Patent: February 18, 2020
    Assignee: FUJIFILM Corporation
    Inventor: Tsutomu Umebayashi
  • Patent number: 10457825
    Abstract: A UV curable inkjet ink composition includes a monofunctional urethane acrylate component consisting of 5-50% by weight of the ink composition, the monofunctional urethane acrylate component comprising either of a monomer and an oligomer; a monomer component consisting of 10-80% by weight of ink composition; a photoinitiator component consisting of 1-15% by weight of ink composition; and an oligomer component, consisting of no more than 20% by weight of the ink composition, in addition to the monofunctional urethane acrylate component if the monofunctional urethane acrylate component is an oligomer.
    Type: Grant
    Filed: August 16, 2016
    Date of Patent: October 29, 2019
    Assignee: ELECTRONICS FOR IMAGING, INC.
    Inventor: Lianhui Cong
  • Patent number: 10138387
    Abstract: An active energy ray image forming apparatus containing a head, a heating mechanism disposed inside the head, and a storing part configured to accommodate a non-polymerizable synthetic resin and a mono-functional monomer containing a single unsaturated ethylene double bond. An active energy ray image forming apparatus, containing a head, a heating mechanism disposed inside the head, and a storing part configured to accommodate a non-polymerizable synthetic resin and a mono-functional monomer containing a single unsaturated ethylene double bond, where the heating mechanism is heated to 60° C. when ink is discharged.
    Type: Grant
    Filed: June 6, 2017
    Date of Patent: November 27, 2018
    Assignee: Ricoh Company, Ltd.
    Inventors: Shizuka Kohzuki, Teruki Kusahara, Hiroki Nakane
  • Patent number: 10035328
    Abstract: The disclosure describes a curable composition comprising a) a solute (meth) acryloyl oligomer having a plurality of pendent, ethylenically unsaturated, free-radically polymerizable functional groups and nucleophilic, hydrophilic groups, a Mw of 5 k to 30 k. a Tg<20° C.; b) a solvent monomer component; and non-reactive oligomer an a photoinitiator. The curable composition may be used as an adhesive in optical applications.
    Type: Grant
    Filed: November 13, 2014
    Date of Patent: July 31, 2018
    Assignee: 3M Innovative Properties Company
    Inventors: Jason D. Clapper, Serkan Yurt, Christopher J. Campbell
  • Patent number: 9765167
    Abstract: A reverse-phase suspension polymerization process for the manufacture of polymer beads comprising forming aqueous monomer beads comprising an aqueous solution of water-soluble ethylenically unsaturated monomer or monomer blend and polymerizing the monomer or monomer blend to form polymer beads while suspended in a non-aqueous liquid, and recovering polymer beads, in which the process comprises, providing in a vessel (1) a volume (2) of non-aqueous liquid wherein the volume of non-aqueous liquid extends between at least one polymer bead discharge point (3) and at least one monomer feed point (4), feeding the aqueous monomer or monomer blend through orifices (5) into, or onto, the non-aqueous liquid to form aqueous monomer beads, allowing the aqueous monomer beads to flow towards the polymer bead discharge point subjecting the aqueous monomer beads to polymerization conditions to initiate polymerization to form polymerizing beads, wherein the polymerizing beads have formed polymer beads when they reach the poly
    Type: Grant
    Filed: July 29, 2014
    Date of Patent: September 19, 2017
    Assignee: BASF SE
    Inventors: Robert Haschick, Aleksandra Jelicic, John Scott Barratt, Pascal Hesse, Oliver Soetje, Gabriela Eugenia Fonseca Zepeda, Shankara Narayanan Keelapandal Ramamoorthy, Bjoern Langlotz
  • Patent number: 9399695
    Abstract: The present invention relates to pressure-sensitive adhesive compositions which contain (A) hydroxyl group and alkylene oxide group containing acrylic copolymer and (B) a multifunctional isocyanate-based hardener, and form interpenetrating network structures when hardened, and polarizers and liquid crystal displays comprising the same. The pressure-sensitive adhesive compositions of the present invention exhibit superior durability, reliability, and workability and effectively prevent light leakage under high temperature and/or high humidity conditions. Particularly, the present invention provides pressure-sensitive adhesive compositions capable of significantly suppressing light leakage even in large size display devices, and polarizers and liquid crystal displays comprising the same.
    Type: Grant
    Filed: January 6, 2009
    Date of Patent: July 26, 2016
    Assignee: LG Chem, Ltd.
    Inventors: No Ma Kim, In Ho Hwang, Jeong Min Ha, Sung Soo Yoon, Sung Su Kim, Sang Jo Bae
  • Patent number: 9034938
    Abstract: A description is given of a photoreactive polymer preparable by radical polymerization using at least one photoreactive monomer, where the photoreactive monomer has at least one radically polymerizable C—C double bond, at least one hydrophilic group selected from an ethylene glycol group and polyethylene glycol groups having at least 2 ethylene glycol units, and at least one photoreactive group, the photoreactive group being a photoenolizable carbonyl group.
    Type: Grant
    Filed: September 9, 2013
    Date of Patent: May 19, 2015
    Assignee: BASF SE
    Inventors: Dieter Urban, Ulrike Licht, Theo Smit, Christopher Barner-Kowollik, Guillaume Delaittre, Elena Frick
  • Patent number: 8952078
    Abstract: This invention relates to a printing ink and in particular to an ink for ink-jet printing which is cured by irradiation. The ink comprises at least one radiation-curable monomer; at least one passive thermoplastic resin; at least one radical photoinitiator; and at least one colouring agent; wherein the ink has a viscosity of less than 100 mPas at 25° C., and wherein the at least one passive resin is present at 2 to 15 wt % based on the total weight of the ink and has a molecular weight of 1,500 to 70,000.
    Type: Grant
    Filed: July 4, 2007
    Date of Patent: February 10, 2015
    Assignee: Sericol Limited
    Inventor: Nigel Paul Gould
  • Patent number: 8933146
    Abstract: The present invention describes the preparation of an aqueous polyurethane dispersion which is cured by radiation, and its use as binder.
    Type: Grant
    Filed: August 6, 2008
    Date of Patent: January 13, 2015
    Assignee: Bayer MaterialScience AG
    Inventors: Stefan Sommer, Richard Kopp, Harald Blum, Christoph Irle, Jan Weikard, Erhard Luehmann
  • Patent number: 8921445
    Abstract: Curable adhesive compositions are provided that exhibit a high refractive index.
    Type: Grant
    Filed: April 12, 2010
    Date of Patent: December 30, 2014
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Yassin Turshani, Omar Mohamed Buazza
  • Patent number: 8901198
    Abstract: Disclosed herein are solventborne liquid UV-curable coating compositions comprising: a radiation curable compound comprising an acrylate-terminated compound having greater than two unsaturated sites, wherein the acrylate-terminated compound comprises a reaction product of reactants comprising: an adduct of a polyisocyanate, wherein the adduct of a polyisocyanate comprises a reaction product of reactants comprising a polyisocyanate comprising greater than two isocyanate groups and a compound having groups reactive with the isocyanate groups of the polyisocyanate; and an active hydrogen-containing acrylate; and a photoinitiator composition that includes a first photoinitiator composition for providing surface cure and a second photoinitiator composition for providing through cure of the resultant coating layer. Also disclosed are related multi-component composite coatings, coated substrates, and methods for coating a substrate.
    Type: Grant
    Filed: November 5, 2010
    Date of Patent: December 2, 2014
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Charles M. Kania, Kenneth T. Phelps, Kurt A. Humbert, Todd M. Roper, Jiping Shao, David C. Martin
  • Patent number: 8859633
    Abstract: Provided are a temporal fixation method in processing of optical members and a resin composition suitable therefore, which uses a composition which is characterized by containing the following (A3), (B3) and (D3), wherein (A3) is a urethane(meth)acrylate; (B3) is one or more (meth)acrylic acid derivative monomers selected from the group consisting of n-(meth)acryloyloxyalkyl hexahydrophthalimides, carboxyl group-containing (meth)acrylates and (meth)acrylic acid derivative monomers represented by the formula (C3): Z—O—(R2O)p—R1??Formula (C3): wherein Z represents a (meth)acryloyl group, R1 represents a phenyl group or a phenyl group having an alkyl group with 1 to 3 carbon atoms, R2 represents —C2H4—, —C3H6—, —CH2CH(CH3)—, —CH2CH(OH)CH2—, —C4H8— or —C6H12—, and p represents an integer of from 1 to 10; and D(3) is a photopolymerization initiator, along with methods for temporarily fixing a member.
    Type: Grant
    Filed: July 7, 2011
    Date of Patent: October 14, 2014
    Assignee: Denki Kagaku Kogyo Kabushiki Kaisha
    Inventors: Kazuhiro Oshima, Tomoyuki Kanai, Kunio Iriuchijima
  • Patent number: 8859636
    Abstract: An ink composition includes: (Component a) a polymerizable compound having an ethylenically unsaturated double bond; (Component b) a polymerization initiator; (Component c) water; and (Component d) a polyhydric alcohol having an alkyleneoxy chain, wherein the (Component a) polymerizable compound includes a monofunctional polymerizable monomer having a (meth)acrylamide structure, and a content of the monofunctional polymerizable monomer is 5% by mass or more with respect to a total content of the (Component a) polymerizable compound.
    Type: Grant
    Filed: November 18, 2011
    Date of Patent: October 14, 2014
    Assignee: FUJIFILM Corporation
    Inventors: Toshihiro Kamada, Takahiro Kato
  • Patent number: 8859634
    Abstract: This invention relates to a photo-curing or electron beam-curing adherent resin composition being excellent in the adhesiveness to various adherends such as metal oxide, metal, resin and so on, and more particularly to an adherent resin composition of a photo-curing or electron beam-curing type comprising a difunctional urethane (metha)acrylate oligomer (A) and a monomer component (B), characterized in that the urethane (metha)acrylate oligomer includes a urethane prepolymer portion composed of a polyol and a polyisocyanate wherein repetitive number of urethane prepolymer portion (n) is 10-30, and the monomer component (B) is a cyclic monomer having a (metha)acryloyl group.
    Type: Grant
    Filed: December 9, 2008
    Date of Patent: October 14, 2014
    Assignee: BRIDGESTONE Corporation
    Inventors: Junji Sakata, Hajime Kitano, Hiroyuki Kanesugi
  • Patent number: 8835675
    Abstract: The present invention is directed to compounds and adhesives finding special utility in dental applications. Compounds of formulae: are of special interest, wherein: R represents a polymerizable group of the structure ?wherein R1 represents a hydrogen atom or methyl group; A represents an oxygen atom or a sulfur atom; Xqs represent independently an oxygen atom or a sulfur atom; Yqs represent independently hydrogen atom; Zqs may independently represent D-R2 where D represents a single carbon atom and R2 represents phenyl; p is an integer from 1 to 10; and q is an integer from 1 to p.
    Type: Grant
    Filed: December 4, 2007
    Date of Patent: September 16, 2014
    Assignee: Kabushiki Kaisha Shofu
    Inventors: Kunio Ikemura, Yoshiyuki Jogetsu, So Ito
  • Publication number: 20140256840
    Abstract: A structure having a carbon nanotube material having a plurality of carbon nanotubes and an electrically or thermally conductive material disposed on at least a portion of the carbon nanotubes, such electrically or thermally conductive material being chemically bonded to such portion of the carbon nanotubes.
    Type: Application
    Filed: February 27, 2014
    Publication date: September 11, 2014
    Applicant: Raytheon Company
    Inventors: James R. Chow, Kurt S. Ketola, Carl W. Townsend
  • Publication number: 20140242024
    Abstract: The present disclosure relates to a hydrogel composition and methods of using the same. The hydrogel composition may include precursors that react with each other upon contact as well as precursors that react upon contact with an initiator. In embodiments, the resulting hydrogels may have varying levels of crosslinking with both denser and less dense regions.
    Type: Application
    Filed: May 8, 2014
    Publication date: August 28, 2014
    Applicant: Covidien LP
    Inventors: Steven Bennett, Nathaniel Mast, Kevin Lavigne, Walter Skalla, Timothy Sargeant, Joshua Stopek
  • Patent number: 8809412
    Abstract: The present invention relates to the use of oligomeric siloxane components in radiation-curable formulations which in the cured state offer a particular degree of corrosion control for metallic substrates.
    Type: Grant
    Filed: June 4, 2008
    Date of Patent: August 19, 2014
    Assignee: Evonik Degussa GmbH
    Inventors: Emmanouil Spyrou, Rene Koschabek, Burkhard Standke
  • Patent number: 8796352
    Abstract: Provided is a material suitable for an optical element, which can be applied by inkjet, has an ultraviolet curable characteristic, and yields a cured product excellent in transparency and hardness and having a refractive index of more than 1.5. Specifically, an optical element excellent in transparency and hardness and having a refractive index of more than 1.5 is obtained by preparing a resin composition including at least: (A) 5 to 45 mass % of a vinyl group-containing copolymer obtained by copolymerization of a divinyl aromatic compound; (B) 55 to 94 mass % of a liquid photocurable polyfunctional (meth)acrylate having two or more (meth)acryloyl groups; (C) 0.97 to 20 mass % of a photopolymerization initiator; and (D) 0.03 to 1 mass % of a surfactant, and applying the resin composition onto a support substrate by inkjet, followed by photocuring.
    Type: Grant
    Filed: June 9, 2011
    Date of Patent: August 5, 2014
    Assignee: Nippon Steel & Sumikin Chemical Co., Ltd.
    Inventors: Koichi Fujishiro, Masanao Kawabe, Tohru Saito, Takahiro Yoshioka
  • Patent number: 8785517
    Abstract: A pre-adhesive composition is described comprising an acid- and epoxy-functional (meth)acryloyl copolymer, which when crosslinked using an ionic photoacid generator (PAG) provides a pressure-sensitive adhesive and pressure-sensitive adhesive articles having desirable properties.
    Type: Grant
    Filed: June 8, 2011
    Date of Patent: July 22, 2014
    Assignee: 3M Innovative Properties Company
    Inventors: Arlin L. Weikel, Larry R. Krepski, Jason D. Clapper, Wayne S. Mahoney, Babu N. Gaddam
  • Patent number: 8741980
    Abstract: A hardenable two part acrylic composition, a polymer component of the two part hardenable composition and a method of producing a polymer component of the two part composition are disclosed. The hardenable two part acrylic composition includes an acrylic polymer composition first part and an acrylic monomer composition second part. The acrylic polymer composition first part includes a first type of acrylic polymer particles wherein each first type of acrylic polymer particle is formed of a network of coalesced emulsion polymerized acrylic microparticles or is macroporous. The acrylic polymer composition may include emulsion polymerised acrylic polymer particles of particle size between 10 and 2000 nm and includes the use of acrylic polymer particles formed of a network of coalesced emulsion polymerized acrylic microparticles as a dough time reduction agent in a hardenable two part acrylic composition.
    Type: Grant
    Filed: August 13, 2009
    Date of Patent: June 3, 2014
    Assignee: Lucite International UK Limited
    Inventors: Michael Stephen Chisholm, David McDonald, Sera Saheb Abed-Ali
  • Patent number: 8729147
    Abstract: A flexographic printing ink for use in a flexographic printing process with wet on wet capability, comprising a polymer and a combination of liquids comprising radiation curable monomers and/or oligomers, diluents, colorants, additives, and photoinitiators, the components having the Hansen Solubility Parameters adjusted to generate an ink with a capability to form a gel having the required physical characteristics, and that is in a liquid form in the presence of a small quantity of non reactive solvent, or is brought to a liquid state during the printing process. The disclosure is also directed to a flexographic printing process with wet on wet capability based on controlled polymer or polymer segment precipitation that leads to gel formation of ink compounds by controlling the solubility parameter of the ink system.
    Type: Grant
    Filed: March 28, 2012
    Date of Patent: May 20, 2014
    Assignee: Technosolutions Assessoria Ltda
    Inventors: Valter Marques Baptista, Wilson Andrade Paduan
  • Patent number: 8722757
    Abstract: A fiber-based adsorbent and a related method of manufacture are provided. The fiber-based adsorbent includes polymer fibers with grafted side chains and an increased surface area per unit weight over known fibers to increase the adsorption of dissolved metals, for example uranium, from aqueous solutions. The polymer fibers include a circular morphology in some embodiments, having a mean diameter of less than 15 microns, optionally less than about 1 micron. In other embodiments, the polymer fibers include a non-circular morphology, optionally defining multiple gear-shaped, winged-shaped or lobe-shaped projections along the length of the polymer fibers. A method for forming the fiber-based adsorbents includes irradiating high surface area polymer fibers, grafting with polymerizable reactive monomers, reacting the grafted fibers with hydroxylamine, and conditioning with an alkaline solution.
    Type: Grant
    Filed: July 19, 2012
    Date of Patent: May 13, 2014
    Assignee: UT-Battelle, LLC
    Inventors: Christopher J. Janke, Sheng Dai, Yatsandra Oyola
  • Patent number: 8716361
    Abstract: Provided is a curable fluorine-containing resin produced by causing a reaction between a polymer (P) and a compound (C); the polymer (P) being prepared by copolymerization in which essential monomer components are a compound (A) having a poly(perfluoroalkylene ether) chain and styryl groups at both ends of the poly(perfluoroalkylene ether) chain and a polymerizable unsaturated monomer (B) having at least one functional group (b) selected from the group consisting of a hydroxy group, an isocyanate group, an epoxy group, a carboxyl group, an acid anhydride group, and a carboxylic acid halide group; the compound (C) having a polymerizable unsaturated group and at least one functional group (c) that has reactivity with the functional group (b) and is selected from the group consisting of a hydroxy group, an isocyanate group, an epoxy group, a carboxyl group, an acid anhydride group, and a carboxylic acid halide group.
    Type: Grant
    Filed: March 22, 2011
    Date of Patent: May 6, 2014
    Assignee: DIC Corporation
    Inventors: Takashi Mihara, Hideya Suzuki
  • Patent number: 8673994
    Abstract: The present invention provides: an ink composition which contains at least a polymerizable compound, a photopolymerization initiator and a coloring material, and is free from an aqueous solvent, wherein the polymerizable compound comprises at least a urethane oligomer; a two-pack curing ink composition set comprising an ink composition containing a coloring material and a reaction liquid containing a photopolymerization initiator and capable of forming an image with an ink composition obtained by mixing the ink composition and the reaction liquid, wherein the ink composition after mixing contains at least a polymerizable compound, a photopolymerization initiator and a coloring material, and is free from an aqueous solvent, wherein the polymerizable compound comprises a urethane oligomer.
    Type: Grant
    Filed: August 3, 2011
    Date of Patent: March 18, 2014
    Assignee: Seiko Epson Corporation
    Inventors: Keitaro Nakano, Takashi Oyanagi
  • Patent number: 8642673
    Abstract: The present invention relates to the use of alkoxysilane components in the presence of acid-generating photoinitiators in radiation-curable, free-radically crosslinkable formulations which in the cured state offer a particular degree of corrosion control for metallic substrates.
    Type: Grant
    Filed: February 5, 2009
    Date of Patent: February 4, 2014
    Assignee: Evonik Degussa GmbH
    Inventor: Emmanouil Spyrou
  • Patent number: 8637587
    Abstract: Release agents with increased affinity toward nano-imprint lithography template surfaces interact strongly with the template during separation of the template from the solidified resist in a nano-imprint lithography process. The strong interaction between the surfactant and the template surface reduces the amount of surfactant pulled off the template surface during separation of a patterned layer from the template in an imprint lithography cycle. Maintaining more surfactant associated with the surface of the template after the separation of the patterned layer from the template may reduce the amount of surfactant needed in a liquid resist to achieve suitable release of the solidified resist from the template during an imprint lithography process. Strong association of the release agent with the surface of the template facilitates the formation of ultra-thin residual layers and dense fine features in nano-imprint lithography.
    Type: Grant
    Filed: September 7, 2011
    Date of Patent: January 28, 2014
    Assignee: Molecular Imprints, Inc.
    Inventors: Frank Y. Xu, Weijun Liu
  • Patent number: 8632952
    Abstract: Provided are a photosensitive resin composition which is soluble in an alkaline aqueous solution and which has a good propagation loss in a visible light wavelength region, a photosensitive resin cured matter, a photosensitive resin film, a photosensitive resin film cured matter and an optical waveguide obtained by using the same. Provided are, to be specific, a photosensitive resin composition comprising (A) a vinyl polymer having at least one chain-polymerizable functional group in a molecule, (B) a polymerizable compound and (C) a polymerization initiator, wherein the component (C) is at least one selected from the group consisting of 2-[2-oxo-2-phenylacetoxyethoxy]ethyl oxyphenylacetate, 2-(2-hydroxyethoxy)ethyl oxyphenylacetate and oligo{2-hyroxy-2-methyl-1-[4-(1-methylvinyl)phenyl]}propanone, a photosensitive resin cured matter, a photosensitive resin film, a photosensitive resin film cured matter and an optical waveguide obtained by using the same.
    Type: Grant
    Filed: November 17, 2008
    Date of Patent: January 21, 2014
    Assignee: Hitachi Chemical Company, Ltd.
    Inventors: Kouji Suzumura, Tatsuya Makino, Atsushi Takahashi
  • Patent number: 8609742
    Abstract: Disclosed is a high energy ray-curable composition which is excellent in storage stability before curing and enables to form a cured coating film which is excellent in hardness, property of preventing adhesion of fats and oils, property of wiping off fats and oils, abrasion resistance, transparency, water repellency, adhesion, smoothness and uniformity. Specifically disclosed is a high energy ray-curable composition containing the following components (A)-(D). (A) 100 parts by weight of a polyfunctional acrylate (B) 1-30 parts by weight of an organoalkoxysilane having an aliphatic unsaturated bond (C) 1-100 parts by weight of colloidal silica (D) 0.2-20 parts by weight of a fluorine compound having an aliphatic unsaturated bond.
    Type: Grant
    Filed: February 28, 2007
    Date of Patent: December 17, 2013
    Assignees: Daikin Industries, Ltd., Dow Corning Corporation
    Inventors: Mari Wakita, Motoshi Sasaki, Peter Cheshire Hupfield, Yasuo Itami, Kaori Ozawa, Masahiko Maeda
  • Patent number: 8604095
    Abstract: A radiation-curable ink composition contains (A) aminoacrylate at 1 mass % to 10 mass %, inclusive, (B) phenoxyethyl acrylate at 20 mass % to 50 mass %, inclusive, and (C) tetraethylene glycol diacrylate at 1 mass % to 20 mass %, inclusive, in its reaction component, as well as (E) bis(2,4,6-trimethylbenzoyl)-phenylphosphine oxide at 3 parts by mass to 8 parts by mass, inclusive, (F) 2,4,6-trimethylbenzoyl-diphenyl-phosphine oxide at 3 parts by mass to 5 parts by mass, inclusive, in 100 parts by mass of the reaction component, and (G) diethylthioxanthone at 1 part by mass to 3 parts by mass, inclusive, in 100 parts by mass of the reaction component.
    Type: Grant
    Filed: December 28, 2010
    Date of Patent: December 10, 2013
    Assignee: Seiko Epson Corporation
    Inventors: Taketoshi Kagose, Toshiyuki Miyabayashi, Satoru Miura, Toru Saito, Hiroki Nakane, Jun Ito, Hiroyuki Kajimoto, Chigusa Sato, Hiroaki Kida
  • Patent number: 8604251
    Abstract: The invention pertains to novel oligofunctional photoinitiators of the formula (1) or (1A). R1 and R2 are methyl or together are —(CH2)5—; and n is 2 or 3, and the solvent in (1A) is water or an organic solvent; and their use in photopolymerizable compositions, in particular inks.
    Type: Grant
    Filed: March 19, 2010
    Date of Patent: December 10, 2013
    Assignee: BASF SE
    Inventors: Ulrich Berens, Jean-Luc Birbaum, Katia Studer
  • Patent number: 8598250
    Abstract: The present invention relates to a photocurable acrylic viscoelastic material composition including: an acrylic monomer mixture containing an alkyl (meth)acrylate as a main monomer component and a polar group-containing vinyl monomer, or a partial polymerization product thereof; a (meth)acrylate compound having at least one isocyanate group within the molecule thereof; and a photopolymerization initiator. The photocurable acrylic viscoelastic material composition of the present invention has, by virtue of the above-described construction, excellent pot life and excellent storage stability, despite containing an isocyanate compound having at least one isocyanate group within the molecule thereof, and further can form an acrylic viscoelastic material excellent in the holding power at high temperatures through photocuring. Also, the acrylic viscoelastic material and acrylic viscoelastic material layer tape or sheet of the present invention is excellent in the holding power at high temperatures.
    Type: Grant
    Filed: January 22, 2009
    Date of Patent: December 3, 2013
    Assignee: Nitto Denko Corporation
    Inventors: Akira Hirao, Kunio Nagasaki, Kazuhisa Maeda
  • Patent number: 8574822
    Abstract: A nanoimprint resist includes a hyperbranched polyurethane oligomer, a perfluoropolyether, a methylmethacrylate, a diluent solvent, and a photo initiator. The hyperbranched polyurethane oligomer can be polymerized by a copolymerization of trimellitic anhydride, ethylene mercaptan, and epoxy acrylic acid. The hyperbranched polyurethane oligomer can also be polymerized by a ring-opening copolymerization epoxy acrylic acid and ethylene glycol.
    Type: Grant
    Filed: May 24, 2012
    Date of Patent: November 5, 2013
    Assignees: Tsinghua University, Hon Hai Precision Industry Co., Ltd.
    Inventors: Zhen-Dong Zhu, Qun-Qing Li, Li-Hui Zhang, Mo Chen
  • Patent number: 8568883
    Abstract: The present invention relates to superabsorbent polymer particles with improved surface cross-linking and improved hydrophilicity and their use in absorbent articles. Superabsorbent polymer particles of the invention consist of cross-linked poly(meth)acrylic acid and salts thereof. The polymer chains comprised by the superabsorbent polymer particles are cross-linked to each other through direct covalent bonds and comprise alcoholic hydroxyl groups. Moreover, the invention relates to a method for surface cross-linking superabsorbent polymer particles using vacuum UV irradiation.
    Type: Grant
    Filed: December 8, 2005
    Date of Patent: October 29, 2013
    Assignee: Then Procter & Gamble Company
    Inventors: Andreas Flohr, Torsten Lindner
  • Patent number: 8557890
    Abstract: The present invention provides a coating composition and a coating film that comprises a binder containing a UV-curable functional group, a compound containing a fluorine UV-curable functional group, a photoinitiator; and nano-sized particles. The coating film according to the present invention has excellent abrasion resistance and contamination resistance such as fingerprint trace removability and scribbling resistance.
    Type: Grant
    Filed: November 28, 2008
    Date of Patent: October 15, 2013
    Assignee: LG Chem, Ltd.
    Inventors: Yeong-Rae Chang, Joon-Koo Kang, Kyung-Ki Hong, Eun-Sang Yoo, Sung-Su Kim, Ju-Young Kim, Soon-Hwa Jung, Young-Jun Hong
  • Patent number: 8557031
    Abstract: This invention relates to methods for chemically grafting and attaching ceragenin molecules to polymer substrates; methods for synthesizing ceragenin-containing copolymers; methods for making ceragenin-modified water treatment membranes and spacers; and methods of treating contaminated water using ceragenin-modified treatment membranes and spacers. Ceragenins are synthetically produced antimicrobial peptide mimics that display broad-spectrum bactericidal activity. Alkene-functionalized ceragenins (e.g., acrylamide-functionalized ceragenins) can be attached to polyamide reverse osmosis membranes using amine-linking, amide-linking, UV-grafting, or silane-coating methods. In addition, silane-functionalized ceragenins can be directly attached to polymer surfaces that have free hydroxyls.
    Type: Grant
    Filed: January 7, 2011
    Date of Patent: October 15, 2013
    Assignee: Sandia Corporation
    Inventors: Michael Hibbs, Susan J. Altman, Howland D. T. Jones, Paul B. Savage
  • Patent number: 8552084
    Abstract: A process for preparing a pressure sensitive adhesive using a modified planetary roller extruder is described. The process in accordance with one aspect of the invention is a continuous process that includes introducing primary raw materials comprising a non-thermoplastic elastomer into a planetary roller extruder, introducing a heat-activatable crosslinker into the planetary roller extruder for mixing with the primary raw materials, and compounding the primary raw materials and the heat activatable crosslinker to form an adhesive composition while maintaining the temperature of the adhesive composition between about 25° C. and about 100° C. The non-thermoplastic elastomer is masticated during compounding and at least some of the heat-activatable crosslinker remains generally unactivated and is available for later activation.
    Type: Grant
    Filed: December 27, 2011
    Date of Patent: October 8, 2013
    Assignee: Intertape Polymer Corp.
    Inventors: John Kinch Tynan, Jr., Richard Walter St. Coeur, David Michael Kovach, Thomas Lombardo
  • Patent number: 8552083
    Abstract: The present invention relates to a radiation-curable composition having a refractive index less than 1.40 comprising (1) a curable perfluoropolyether oligomer having a structural formula selected from the group consisting of: and wherein R represents a hydrogen atom or a methyl group, wherein A represents a straight chained or branched alkylene group, wherein m represents an integer from 1 to 4, wherein the integers represented by m within individual —((CF2)m—O)n— repeat units can be the same or different, and wherein n represents an integer from 1 to 20; (2) a diluent; (3) a photo-initiator; and (4) an adhesion promoter; wherein the radiation-curable composition is free of compounds containing —CF3 groups.
    Type: Grant
    Filed: June 29, 2011
    Date of Patent: October 8, 2013
    Assignee: Ovation Polymer Technology and Engineered Materials, Inc.
    Inventors: Prasad Taranekar, Austin L. Schuman, Asis Banerjie
  • Patent number: 8546461
    Abstract: The present invention relates to a method for producing water-absorbing polymer particles by radiation-inducing polymerization on a continuously revolving belt, electromagnetic radiation having a wavelength of greater than 400 nm being shielded.
    Type: Grant
    Filed: November 24, 2008
    Date of Patent: October 1, 2013
    Assignee: BASF SE
    Inventors: Matthias Weismantel, Rüdiger Funk, Leigh R. Blair, Kevin D. Heitzhaus
  • Patent number: 8529681
    Abstract: This invention relates to methods for chemically grafting and attaching ceragenin molecules to polymer substrates; methods for synthesizing ceragenin-containing copolymers; methods for making ceragenin-modified water treatment membranes and spacers; and methods of treating contaminated water using ceragenin-modified treatment membranes and spacers. Ceragenins are synthetically produced antimicrobial peptide mimics that display broad-spectrum bactericidal activity. Alkene-functionalized ceragenins (e.g., acrylamide-functionalized ceragenins) can be attached to polyamide reverse osmosis membranes using amine-linking, amide-linking, UV-grafting, or silane-coating methods. In addition, silane-functionalized ceragenins can be directly attached to polymer surfaces that have free hydroxyls.
    Type: Grant
    Filed: January 7, 2011
    Date of Patent: September 10, 2013
    Assignee: Sandia Corporation
    Inventors: Michael Hibbs, Susan J. Altman, Howland D. T. Jones, Paul B. Savage
  • Patent number: 8530583
    Abstract: A composition for film formation which can form a film suitable for use as an interlayer dielectric in a semiconductor device, etc. and having an appropriate even thickness and can give a film having excellent characteristics including permittivity and Young's modulus; and a dielectric film obtained from the film-forming composition. The composition contains a compound (X) having a functional group which is partly eliminated by heating, irradiation with light, irradiation with radiation, or a combination thereof to generate volatile matter and yield an unsaturated group in the remaining part of the functional group.
    Type: Grant
    Filed: November 10, 2009
    Date of Patent: September 10, 2013
    Assignee: FUJIFILM Corporation
    Inventors: Kenji Wada, Katsuyuki Watanabe, Keiji Yamamoto
  • Patent number: 8519408
    Abstract: Disclosed is a method of producing a thin film transistor substrate having high light sensitivity, heat-resistance, impact resistance, and a photosensitive composition used by the same, the method including forming data wires on an insulating substrate, forming an organic insulating film on the data wires by applying a photosensitive composition comprising a terpolymer, where the terpolymer is derived from monomers of an unsaturated carboxylic acid, an unsaturated carboxylic acid anhydride, or a mixture thereof, an unsaturated epoxy group-containing compound, and an olefinic compound.
    Type: Grant
    Filed: August 30, 2012
    Date of Patent: August 27, 2013
    Assignee: Samsung Display Co., Ltd.
    Inventors: Hoon Kang, Jae-sung Kim, Yang-ho Jung, Hi-kuk Lee
  • Patent number: 8513332
    Abstract: Disclosed is a color filter ink composition that includes an acrylic-based copolymer resin including repeating units represented by a particular chemical formula, a polymerizable monomer, a pigment, and a solvent. According to the present invention, the color filter ink composition can have excellent ejection properties and ejection stability by using a new acrylic-based copolymer resin as a binder resin, and also can have excellent storage stability, so that it can be used for a long period. In addition, a pattern formed using the color filter ink composition can have improved heat resistance, chemical resistance, and film strength.
    Type: Grant
    Filed: April 16, 2010
    Date of Patent: August 20, 2013
    Assignee: Cheil Industries Inc.
    Inventors: Jong-Seung Park, In-Jae Lee, Jin-Ki Hong, Seung-Joo Shin, Sung-Woong Kim, Tae-Woon Cha
  • Patent number: 8507584
    Abstract: Disclosed is a phase change ink comprising a colorant, an initiator, and a phase change ink carrier, said carrier comprising at least one radically curable monomer compound and a compound of the formula wherein R1 and R1? are the same, and wherein R1 and R1? are each an aromatic group; and wherein R2 and R2? and R3 each, independently of the others, are alkylene groups, arylene groups, arylalkylene groups, or alkylarylene groups; or wherein, in embodiments, R1 and R1? can be the same or different, and wherein R1 and R1? each, independently of the other is an alkyl group having a least one ethylenic unsaturation, an arylalkyl group having at least one ethylenic unsaturation, an alkylaryl group having at least one ethylenic unsaturation, or an aromatic group, provided that at least one of R1 and R1? is an aromatic group; and provided that neither of R1 or R1? is a photoinitiator group. Also disclosed herein is a method of printing with the phase change ink.
    Type: Grant
    Filed: April 22, 2010
    Date of Patent: August 13, 2013
    Assignee: Xerox Corporation
    Inventors: Naveen Chopra, Michelle N. Chretien, Barkev Keoshkerian, Jennifer L. Belelie, Peter G. Odell
  • Patent number: 8507726
    Abstract: Photoinitiators mixture comprising (i) at least one compound selected from the group consisting of alpha-hydroxy ketones, monoacylphosphine oxides, bisacylphosphine oxides, ketosulfones, benzil ketals, benzoin ether, phenylglyoxylates, borates and titanocenes; and (ii) at least one compound of the formula (I) or (I?) R1, R?1, R2 and R2? R?9 independently of each other for example are hydrogen or C1-C12alkyl R7, R8, R9, R?8 and R?9 independently of each other for example are hydrogen, C1-C12alkyl which optionally is substituted or phenyl which optionally is substituted, exhibit excellent photoinitiating properties.
    Type: Grant
    Filed: October 23, 2009
    Date of Patent: August 13, 2013
    Assignee: BASF SE
    Inventors: Katia Studer, Sébastien Villeneuve, Akira Matsumoto, Hisatoshi Kura, Jan Sültemeyer
  • Patent number: 8507725
    Abstract: Compounds of the formula I or (I?), wherein R1 and R?1 for example are hydrogen, C3-C8cycloalkyl or C1-C12alkyl, R2 and R2? for example are hydrogen; unsubstituted C1-C20alkyl or substituted C1-C20alkyl; and R8 and R9 for example are hydrogen, C1-C12alkyl which optionally is substituted, or phenyl which optionally is substituted; exhibit an unexpectedly good performance in photopolymerization reactions.
    Type: Grant
    Filed: May 27, 2009
    Date of Patent: August 13, 2013
    Assignee: BASF SE
    Inventors: Akira Matsumoto, Hisatoshi Kura
  • Patent number: 8501391
    Abstract: The present invention provides a photosensitive resin composition comprising 100 parts by mass of a polyurethane prepolymer having an ethylenically unsaturated group, 10 to 150 parts by mass of an ethylenically unsaturated compound, and 0.01 to 10 parts by mass of a photopolymerization initiator, wherein the ethylenically unsaturated compound comprises 0.1 to 10 parts by mass of a polyfunctional ethylenically unsaturated compound having 6 or more (meth)acryloyl groups in a molecule thereof with respect to 100 parts by mass of the polyurethane prepolymer.
    Type: Grant
    Filed: June 18, 2008
    Date of Patent: August 6, 2013
    Assignee: Asahi Kasei E-Materials Corporation
    Inventors: Masahiro Yoshida, Shusaku Tabata
  • Patent number: 8492452
    Abstract: A polymerizable photoinitiator is represented by Formula (I): wherein R1, R2 and R3 are independently selected from the group consisting of a hydrogen, an optionally substituted alkyl group and an optionally substituted aryl group or R1 and R3 represent the necessary atoms to form a five to eight membered ring; p, w, y and z are all integers with y representing a value 1 to 6; p representing the sum of w and z; p representing a value of 1 to 6; w=1 to (p?z) and z=0 to (p?w); L represents an optionally substituted (p+y)-valent linking group comprising 1 to 14 carbon atoms; A represents a radically polymerizable group selected from the group consisting of an acrylate group, a methacrylate group, a styrene group, an acryl amide group, a methacryl amide group, a maleate group, a fumarate group, an itaconate group, a vinyl ether group, an allyl ether group, an allyl ester group and a vinyl ester group; and X represents a photoinitiating moiety including at least one group capable of initiating a free radical p
    Type: Grant
    Filed: December 1, 2009
    Date of Patent: July 23, 2013
    Assignee: Agfa Graphics NV
    Inventors: Johan Loccufier, Luc Van Maele, Jaymes Van Luppen, Roland Claes