Containing C-co-c(r)(oh) Wherein R Is Organic Patents (Class 522/42)
  • Patent number: 6011079
    Abstract: A radiation curable release coating composition comprising, by weight,(a) 10-90% of an acrylate-functional silicone resin,(b) 10-90% of a vinylether monomer as reactive diluent therein, and(c) a photoinitiator.
    Type: Grant
    Filed: October 9, 1997
    Date of Patent: January 4, 2000
    Assignee: ISP Investments Inc.
    Inventors: James A. Dougherty, John Mc Kittrick
  • Patent number: 6008269
    Abstract: [Problem] To provide ultraviolet hardening type ink compositions with a temperature-sensitive color change property, which has both the hardening property and the printing strength of UV ink and also has an excellent light resistance.[Solution] Ultraviolet hardening type ink compositions comprising microcapsules with a temperature-sensitive color change property and a photopolymerization initiator, wherein said microcapsules contain no ultraviolet absorber and have the mean diameter of 0.5-50 .mu.m whereas said photopolymerization initiator comprises at least one of the compounds selected from ace tophenone type compounds and benzophenone type compounds.
    Type: Grant
    Filed: November 18, 1997
    Date of Patent: December 28, 1999
    Assignee: Matsui Shikiso Chemical Co., Ltd.
    Inventors: Yosuke Kitagawa, Ryuichi Hoshikawa
  • Patent number: 6008268
    Abstract: A method of generating reactive species which includes exposing a photoreactor composition to radiation, in which the photoreactor composition comprises a wavelength-specific sensitizer associated with one or more reactive species-generating photoinitiators. Also described are methods of polymerizing unsaturated monomers and curing an unsaturated oligomer/monomer mixture.
    Type: Grant
    Filed: January 22, 1998
    Date of Patent: December 28, 1999
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Ronald Sinclair Nohr, John Gavin MacDonald
  • Patent number: 5998496
    Abstract: A compound of the general formula:A-L.sup.+ D.sup.-where A is a moiety which absorbs radiation and enters an excited state in which it accepts an electron; D.sup.- is a moiety which donates an electron to the excited state A and releases a free radical; and L.sup.+ is a cationic linking group which tethers electron acceptor moiety A to electron donor moiety D.sup.-. Cationic linking moiety L.sup.+ has the formula:-L'-G-where L' is a moiety which forms a stable radical with acceptor moiety A upon transfer of an electron from donor moiety D.sup.- to electron acceptor moiety A, and G is a moiety which forms a leaving group upon transfer of the electron from donor moiety D.sup.- to acceptor moiety A.
    Type: Grant
    Filed: August 19, 1996
    Date of Patent: December 7, 1999
    Assignee: Spectra Group Limited, Inc.
    Inventors: Salah A. Hassoon, Ananda M. Sarker, Douglas C. Neckers
  • Patent number: 5985447
    Abstract: A method of producing glass strands, the method comprising coating glass strands with a heat-polymerizable composition constituted by a solution with a solvent content of less than 5% by weight and a viscosity of less than 400 cP, the solution comprising a basic structure which can be polymerized or cross-linked thermally, the structure comprising at least 60% by weight of one or more components with molecular weights of less than 750, having at least one acrylic and/or methacrylic and/or vinyl ether and/or N-vinylamide and/or N-vinyllactam function, the proportion of polyfunctional components within these components being at least 45% by weight of these components, so as to produce glass strands coated with a non-polymerized, heat-polymerizable composition; the glass strands produced, as well as to composites produced from the strands.
    Type: Grant
    Filed: January 15, 1997
    Date of Patent: November 16, 1999
    Assignee: Vetrotex France
    Inventor: Patrick Moireau
  • Patent number: 5973021
    Abstract: Organosiloxane compositions that cure in the presence of ultraviolet radiation comprise a alkenyl-substituted fluorinated polyorganosiloxane, a mercaptoalkyl-substituted fluorinated polyorganosiloxane and a photoinitiator. The cured compositions are particularly useful as coating and encapsulants to protect electronic devices that are exposed to hydrocarbon fuels.
    Type: Grant
    Filed: December 17, 1997
    Date of Patent: October 26, 1999
    Assignee: Dow Corning Corporation
    Inventors: James Anderson Beck, Myron Timothy Maxson, Bernard VanWert
  • Patent number: 5948514
    Abstract: A photocurable and thermosetting resin composition developable with an aqueous alkali solution is disclosed. The composition comprises in combination: (A) a photosensitive prepolymer soluble in a dilute aqueous alkali solution obtained by esterifying an epoxy resin represented by the following general formula (1) with (meth)acrylic acid and further adding an acid anhydride thereto until an acid value reaches a level in the range of 60 to 120 mg KOH/g, (B) a diglycidyl ether type epoxy compound containing two epoxy groups in the molecular unit thereof, (C) a photopolymerization initiator, and (D) a diluent at such ratios of combination that said epoxy compound (B) accounts for a proportion in the range of 5 to 120 parts by weight and said photopolymerization initiator (C) for a proportion in the range of 0.1 to 30 parts by weight, based on 100 parts by weight of said photosensitive prepolymer (A): ##STR1## wherein X represents CH.sub.2, C(CH.sub.3).sub.2, or SO.sub.
    Type: Grant
    Filed: June 5, 1996
    Date of Patent: September 7, 1999
    Assignee: Taiyo Ink Manufacturing Co., Ltd.
    Inventors: Shigeru Komori, Kazuo Suda, Masao Arima, Miyako Juni
  • Patent number: 5945462
    Abstract: The present invention relates to an aqueous-based coating composition for forming strippable, protective coating for protecting surfaces, such as glass, metal, ceramic, plastic or other materials of construction. More specifically, the compositions and coatings formed therefrom of this invention are particularly useful in connection with protecting precision surfaces, such as optical lenses, including but not limited to ophthalmic lenses, telescopic lenses, microscopic lenses, and the like, which protection is desirably only of a temporary nature.
    Type: Grant
    Filed: October 2, 1997
    Date of Patent: August 31, 1999
    Assignee: Loctite Corporation
    Inventor: Peter A. Salamon
  • Patent number: 5942290
    Abstract: Molecular complex compounds comprising a mono-, bis- or trisacylphosphine oxide compound with an .alpha.-hydroxy ketone compound are suitable as photoinitiators for the photopolymerization of free-radically polymerizable compounds.
    Type: Grant
    Filed: August 21, 1997
    Date of Patent: August 24, 1999
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: David George Leppard, Thomas Lloyd James, Nils Hock, Manfred Kohler, Ronald Salathe
  • Patent number: 5942555
    Abstract: A photoactivatable reagent useful as a chain transfer reagent for providing a semitelechelic polymer having one or more terminal photoactivatable groups. The reagent provides one or more photoactivatable groups and one or more sulfhydryl (or other chain transfer) groups, the photoactivatable and chain transfer groups optionally being joined together by a spacer group. The reagent can be used to prepare a polymer by serving to initiate the polymerization of ethylenically unsaturated monomers. The reagent itself becomes an integral part of the resultant polymer, thereby providing the polymer with a terminal photoactivatable nature. The method provides a number of benefits, including the ability to provide homogeneous photoactivatable polymer compositions, e.g., in terms of the uniform location of the photogroup(s) on the terminal portion of each polymer molecule and the ability to build a desired nonpolar quality, and in turn improved surfactancy, into otherwise polar polymers.
    Type: Grant
    Filed: March 21, 1996
    Date of Patent: August 24, 1999
    Assignee: SurModics, Inc.
    Inventors: Melvin J. Swanson, Richard A. Amos, Dale G. Swan, Gary W. Opperman
  • Patent number: 5908873
    Abstract: A one-part, cured, radiation-curable liquid matrix composition for affixing coated and inked optical fibers in a ribbon configuration which is peelable from the coated and inked fibers without damage to the integrity of itself or the fibers is disclosed. The composition comprises an aliphatic urethane acrylate oligomer; a reactive monomer having one or more acrylate or methacrylate moieties; a release agent; and an optional photoinitiator. Also disclosed are an optical fiber ribbon array prepared therefrom; a process for removing such matrix composition from inked and coated fibers; a process for preparing such ribbon array; and a radiation-curable coating composition generally applicable for coating a substrate.
    Type: Grant
    Filed: December 20, 1995
    Date of Patent: June 1, 1999
    Assignee: Borden Chemicals, Inc.
    Inventor: Paul J. Shustack
  • Patent number: 5883147
    Abstract: A photopolymerizable adhesive consisting of Compound (1) which contains at least one (meth)acryloxy group as a polymerizing group in its molecule, and other structures constructed from the group(s) selected from the group consisting of alkyl group, alkyloxy group, polyalkoxy group, siloxanyl group and the substituted group thereof substituted by fluorine, hydroxy or alkoxy group; Compound (2) selected from (meth)acrylic acids, hydroxyalkyl (meth)acrylates, (meth)acryloxyalkyl succinic acids, trialkoxyvinyl silanes and .gamma.-(meth)acryloxyalkyl trialkoxy silanes; and Compound (3) selected from hydroxyacetophenones, acetophenones, glyoxy esters and camphorquinones, wherein said adhesive comprises 3 to 60 wt % of the compound (2), and 0.1 to 2 wt % of the Compound (3).
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: March 16, 1999
    Assignee: Japan Institute of Advanced Dentistry
    Inventors: Eiichi Masuhara, Shigeo Komiya, Takeyuki Sawamoto, Satoko Maeda
  • Patent number: 5882792
    Abstract: The present invention relates to a sizing composition for glass threads which comprises a solution of a viscosity of less than or equal to 400 cP containing less than 5% by weight of solvent and containing at least one base system which can be polymerized under the action of ultraviolet radiation or an electron beam, the said base system comprising at least one component that has a molecular mass of less than 750 and that has at least one reactive epoxy group and comprising at least 60% by weight of one or more components that have a molecular mass of less than 750 and that have at least one reactive group selected from the following groups: epoxy, hydroxy, vinyl ether, acrylic and methacrylic. The invention relates also to a process using this composition and to the threads coated with the said composition.
    Type: Grant
    Filed: October 10, 1996
    Date of Patent: March 16, 1999
    Assignee: Vetrotex France
    Inventor: Patrick Moireau
  • Patent number: 5858545
    Abstract: Free-radically polymerizable release coating compositions containing conductivity enhancers, which are capable of being electrosprayed onto a substrate. The compositions comprise (a) about 100 parts by weight of one or more free-radically polymerizable vinyl monomer(s), (b) from about 0.05 to about 250 parts by weight of one or more polydiorganosiloxane polymer(s) copolymerizable with the vinyl monomer(s), and (c) from about 0.10 to about 10 parts by weight, based on 100 parts by weight of (a) and (b), of one or more non-volatile conductivity enhancer(s), which are soluble in the monomer(s) and which do not interfere with polymerization, wherein the composition may be electrosprayed.The composition may further comprise from about 0.1 to about 5 parts by weight of one or more initiator(s) based on 100 parts by weight of monomer(s) and polydiorganosiloxane polymer(s).Another embodiment of the present invention further comprises at least 0.
    Type: Grant
    Filed: March 26, 1996
    Date of Patent: January 12, 1999
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Albert I. Everaerts, Mieczyslaw H. Mazurek, Albert E. Seaver
  • Patent number: 5849411
    Abstract: A polymer film, polymer-coated nonwoven web, and a polymer-coated fiber formed by a process wherein an admixture of unsaturated polymerizable material and a photoreactor composition are drawn into a film or coated onto a web or fiber. The photoreactor composition includes a photoinitiator associated with a wavelength-specific sensitizer. The film, web or fiber is subsequently irradiated with light to polymerize the admixture.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: December 15, 1998
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Ronald Sinclair Nohr, John Gavin MacDonald
  • Patent number: 5837746
    Abstract: Compounds of the formulaRG--A--INwherein IN is a photoinitiator basic structure A is a spacer group and RG is a functional reactive group can be employed as coreactive photoinitiators for photo-polymerization of systems containing ethylenically unsaturated compounds.
    Type: Grant
    Filed: June 23, 1997
    Date of Patent: November 17, 1998
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Manfred Kohler, Jorg Ohngemach, Eike Poetsch, Rudolf Eidenschink, Gerhard Greber, Dieter Dorsch, Jurgen Gehlhaus, Konrad Dorfner, Hans Ludwig Hirsch
  • Patent number: 5824716
    Abstract: This invention relates to dicyclopentyl-oxyethyl methacrylate acrylic copolymer latices forming photocurable coalesced films and prepared by adding a photoinitiator to the latex, and which are useful for preparing lacquers and paints, particularly for building facades.
    Type: Grant
    Filed: July 19, 1996
    Date of Patent: October 20, 1998
    Assignee: Elf Atochem S.A.
    Inventors: Xavier Coqueret, Pierre Rousseau, Christophe Verge
  • Patent number: 5821280
    Abstract: A process for producing a conductive composition for a biological electrode wherein casting or injection is preformed while maintaining the flowability of the feedstock solution to thereby enable the molding of the solid gel into a desired shape. A process for producing a conductive gel composition for a biological electrode having a function of electrically and physically connecting a living body to an electrode element and comprising at least the following components:(1) a radical-polymerizable unsaturated compound;(2) an acid reacting with NaOH or KOH to thereby give a reaction product which is a moisturizer serving as a plasticizer and having a function of supplementing and promoting the physiological humidifying function of the horny layer;(3) water;(4) NaOH and/or KOH;(5) a photopolymerization or light polymerization initiator; and(6) a crosslinking agent.
    Type: Grant
    Filed: July 26, 1996
    Date of Patent: October 13, 1998
    Assignee: Nihon Kohden Corporation
    Inventors: Shin Suda, Toru Kurata, Toshihiro Fukai, Kenichiro Maeda
  • Patent number: 5811199
    Abstract: A method of generating reactive species which includes exposing a photoreactor composition to radiation, in which the photoreactor composition comprises a wavelength-specific sensitizer associated with a reactive species-generating photoinitiator. Also described are methods of polymerizing unsaturated monomers and curing an unsaturated oligomer/monomer mixture.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: September 22, 1998
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: John Gavin MacDonald, Ronald Sinclair Nohr
  • Patent number: 5798015
    Abstract: A method of generating reactive species which includes exposing a photoreactor composition to radiation, in which the photoreactor composition comprises a wavelength-specific sensitizer associated with a reactive species-generating photoinitiator. Also described are methods of polymerizing unsaturated monomers and curing an unsaturated oligomer/monomer mixture.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: August 25, 1998
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Ronald Sinclair Nohr, John Gavin MacDonald
  • Patent number: 5773487
    Abstract: A sprayable coating composition is formulated using one or more acrylates and one or more photoinitiators which act to polymerize the composition when exposed to ultraviolet light. Because of the use of low molecular weight monomers or oligomers, the composition is essentially free of volatile organic solvents, and therefore evaporative emissions in curing are substantially eliminated.
    Type: Grant
    Filed: September 26, 1995
    Date of Patent: June 30, 1998
    Assignee: UV Coatings, Inc.
    Inventor: Andrew A. Sokol
  • Patent number: 5747550
    Abstract: A method of generating reactive species which includes exposing a photoreactor composition to radiation, in which the photoreactor composition comprises a wavelength-specific sensitizer associated with a reactive species-generating photoinitiator. Also described are methods of polymerizing unsaturated monomers and curing an unsaturated oligomer/monomer mixture.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: May 5, 1998
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Ronald Sinclair Nohr, John Gavin MacDonald
  • Patent number: 5744514
    Abstract: Coated optical fibers with radiation-curable coatings which include mercaptofunctional oligomers are disclosed. Specifically, the coatings may comprise the cured reaction products of mercapto-terminated urethane oligomers of number average molecular weight as determined by gel permeation chromatography (GPC) of at least about 3,000 daltons, particularly in combination with one or more (meth)acrylate-terminated urethane oligomers; monomer diluents; and optional silane adhesion promoter, photoinitiator and stabilizers. The coatings, when cured, exhibit a percent extractables content, as obtained by Soxhlet extraction, of no more than about 15%, and preferably of no more than about 8%, and a volatiles content, as obtained by thermogravimetric analysis, of less than about 7%, and preferably less than about 3%. Processes for preparing such coated optical fibers and the coatings per se are also disclosed.
    Type: Grant
    Filed: October 31, 1996
    Date of Patent: April 28, 1998
    Assignee: Borden Chemical, Inc.
    Inventor: Paul J. Shustack
  • Patent number: 5744512
    Abstract: Compounds of the formulaRG--A--INwhereinIN is a photoinitiator basic structureA is a spacer group andRG is a functional reactive group can be employed as coreactive photoinitiators for photopolymerization of systems containing ethylenically unsaturated compounds.
    Type: Grant
    Filed: March 20, 1996
    Date of Patent: April 28, 1998
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Manfred Kohler, Jorg Ohngemach, Eike Poetsch, Rudolf Eidenschink, Gerhard Greber, Dieter Dorsch, Jurgen Gehlhaus, Konrad Dorfner, Hans Ludwig Hirsch
  • Patent number: 5739175
    Abstract: A method of generating reactive species which includes exposing a photoreactor composition to radiation, in which the photoreactor composition comprises a wavelength-specific sensitizer associated with a reactive species-generating photoinitiator. Also described are methods of polymerizing unsaturated monomers and curing an unsaturated oligomer/monomer mixture.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: April 14, 1998
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Ronald Sinclair Nohr, John Gavin MacDonald
  • Patent number: 5728749
    Abstract: This photopolymerizable composition includes an grafted reactive telomer containing trifluoroethyl methacrylate units, a reactive diluent and a photopolymerization initiator. It gives hydrophobic transparent coatings.
    Type: Grant
    Filed: November 30, 1995
    Date of Patent: March 17, 1998
    Assignee: Elf Atochem S.A.
    Inventors: Didier Vanhoye, Elsa Ballot, Robert Legros, Olivier Loubet, Bernard Boutevin, Bruno Ameduri
  • Patent number: 5728747
    Abstract: A free radical polymerization process for the preparation of polymer comprising:a first heating and photoinitiating with ultraviolet light of a mixture comprised of a stable free radical agent, and at least one polymerizable monomer compound;optionally cooling said mixture;a second heating of said mixture at a temperature of from about 100.degree. C. to about 160.degree. C.;isolating the polymer product formed; andoptionally washing and drying said polymer.
    Type: Grant
    Filed: August 8, 1996
    Date of Patent: March 17, 1998
    Assignee: Xerox Corporation
    Inventors: Peter M. Kazmaier, Barkev Keoshkerian, Rafik O. Loutfy, Karen A. Moffat, Michael K. Georges, Gordon K. Hamer, Richard P. N. Veregin
  • Patent number: 5709955
    Abstract: An adhesive composition, a laminated structure, and a method of laminating a structure. The adhesive composition comprises an admixture of unsaturated polymerizable material and a photoreactor, the photoreactor comprising a wavelength-specific sensitizer covalently bonded to a reactive species-generating photoinitiator. Suitable wavelength-specific sensitizers have a molar extinction coefficient greater than about 5000 liters per mole per cm at an absorption maximum and resulting photoreactors have a quantum yield of greater than about 0.5 at an absorption maximum. Suitable photoreactors include 2-?p-(2-methyllactoyl)phenoxy!ethyl-1,3-dioxo-2-isoindolineacetate, 2-hydroxy-2-methyl-4'-?2-?p-(3-oxobutyl)phenoxy!ethoxy!propiophenone, 4-?p-?(4-benzoylcyclohexyl)oxy!phenyl!-2-butanone, and 1,3-dioxo-2-isoindolineacetic acid diester with 2-hydroxy-4'-(2-hydroxyethoxy)-2-methylpropiophenone.
    Type: Grant
    Filed: October 16, 1996
    Date of Patent: January 20, 1998
    Assignee: Kimberly-Clark Corporation
    Inventors: Ronald Sinclair Nohr, John Gavin MacDonald
  • Patent number: 5708047
    Abstract: A method for decorating a substrate with hot stamping foil comprising the steps of:a) applying an ink composition comprised of a cationically radiation cured cycloaliphatic epoxide to the substrate in a predetermined design, said ink being operable when cured to bond to the substrate,b) curing the ink on the substrate by exposing to the radiation by which it is curable, thereby bonding the ink composition to the substrate,c) pressing a sheet of hot stamping foil against the substrate with a die heated to a temperature sufficient to cause a portion of the hot stamping foil to adhere to the heated, cured ink design but not to the ink-free areas of the substrate, andd) removing the die, thereby leaving behind a portion of the foil adhered to the ink design.
    Type: Grant
    Filed: December 30, 1994
    Date of Patent: January 13, 1998
    Assignee: Revlon Consumer Products Corporation
    Inventors: Melvin Edwin Kamen, Bhupendra Patel
  • Patent number: 5703139
    Abstract: The present invention relates to a photo-curable resin composition which shows an excellent antistatic property and staining resistance by introducing aliphatic trifunctional urethane acrylate prepolymer therein and to a product coated with said resin composition. Specifically, the photo-curable resin composition according to the present invention are useful for coating a product made from metacrylate resin, vinylchloride resin, ABS resin or carbonate resin. The photo-curable resin composition according to the present invention can comprise reactive diluent, photoinitiator and additives in addition to said prepolymer.
    Type: Grant
    Filed: September 27, 1995
    Date of Patent: December 30, 1997
    Assignee: HANWHA Chemical Corporation
    Inventors: Sang-Keun Kim, Seoung-Ho Kim, Haeng-Woo Lee, Cheol-Kyu Choi, Jeong-Deuk Kim, Jin-Who Hong, Chang-Soo Kim, Kong-Hyun Whang
  • Patent number: 5686503
    Abstract: A method of generating reactive species which includes exposing a polymolecular photoreactor to radiation, in which the polymolecular photoreactor comprises a wavelength-specific sensitizer associated with a reactive species-generating photoinitiator. The sensitizer absorbs energy and transfers the absorbed energy to the photoinitiator which, in turn, generates reactive species. The wavelength-specific sensitizer is adapted to have an absorption wavelength band generally corresponding to an emission peak of the radiation. The radiation to which the polymolecular photoreactor is exposed generally will have a wavelength of from about 4 to about 1,000 nanometers. Thus, the radiation may be ultraviolet radiation, including near ultraviolet and far or vacuum ultraviolet radiation: visible radiation: and near infrared radiation. Desirably, the radiation will have a wavelength of from about 100 to about 900 nanometers.
    Type: Grant
    Filed: January 22, 1996
    Date of Patent: November 11, 1997
    Assignee: Kimberly-Clark Corporation
    Inventors: Ronald Sinclair Nohr, John Gavin MacDonald
  • Patent number: 5665477
    Abstract: A biocompatible hydrogel adhesive which is prepared from a precursor containing acrylic acid and an alcoholamine and is adhesive under both wet and dry conditions. The use of diisopropanolamine provides these unexpected and unique wet tack properties and permits adhesion to wet tissue. Additionally, the use of a polyol which contains hydroxyl groups, such as glycerine, and a diamine, such as 2-methylpentamethylenediamine, is found to provide a hydrogel having wet adhesive properties and longer shelf life. The hydrogel adhesive can be used as an attachment means in conjunction with a biomedical detection or monitoring means. The adhesive may be used to attach a sensor on the skin of an intrautero fetus and to monitor the well being of the fetus during labor and delivery. The hydrogel having wet adhesive properties permits the attachment of a sensor or sensors onto wet tissue. The biocompatible adhesive is used to attach a fetal probe securely to a fetus.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: September 9, 1997
    Assignee: Graphic Controls Corporation
    Inventors: William G. Meathrel, Mohammad Saleem, Shirley A. Binks
  • Patent number: 5663211
    Abstract: An ultraviolet curing resin for an optical disk according to the present invention which includes: a multiacrylate-functional monomer selected from the group consisting of multiacrylate-functional monomers and multimethacrylate-functional monomers and mixtures of the foregoing monomers; a difunctional monomer selected from the group consisting of diacrylate-functional monomers, dimethacrylate-functional monomers and mixtures of the foregoing monomers; a diluent; an adhesion promoter; and a photopolymerization initiator. The ultraviolet curing resin may also include a surface tension adjusting agent.
    Type: Grant
    Filed: May 13, 1996
    Date of Patent: September 2, 1997
    Assignee: Sony Chemicals Corporation
    Inventors: Hiraku Kominami, Harumi Saotome
  • Patent number: 5639846
    Abstract: Ultraviolet radiation-curable primary and secondary coating compositions for optical fibers are disclosed. The primary coatings comprise a hydrocarbon polyol-based reactively terminated aliphatic urethane oligomer; a hydrocarbon monomer terminated with at least one end group capable of reacting with the terminus of the oligomer; and an optional photoinitiator. The secondary coatings comprise a polyester and/or polyether-based aliphatic urethane reactively terminated oligomer; a hydrocarbonaceous viscosity-adjusting component capable of reacting with the reactive terminus of (I); and an optional photoinitiator. Also disclosed are optical fibers coated with the secondary coating alone or with the primary and secondary coatings of the invention.
    Type: Grant
    Filed: April 28, 1995
    Date of Patent: June 17, 1997
    Assignee: Borden, Inc.
    Inventor: Paul J. Shustack
  • Patent number: 5616629
    Abstract: A radiation-curable release composition is disclosed which comprises:(A) an organopolysiloxane represented by the formulaRSi(CH.sub.3).sub.2 --O--(Si(CH.sub.3).sub.2 O).sub.n (Si(CH.sub.3)(R)O).sub.m Si(CH.sub.3).sub.2 R (I)wherein in Formula (I), each R is --R.sup.1 --O(O)C--C(R.sup.2).dbd.CH.sub.2, --R.sup.1 --O--C(R.sup.2).dbd.CH.sub.2 or is derived from an organic molecule containing both ethylenic unsaturation and epoxide functionality; R.sup.1 is a hydrocarbylene group; each R.sup.2 is independently hydrogen or a methyl or ethyl group; m is a number from about 1 to about 15; and n is a number from about 50 to about 300; and(B) an organosiloxane copolymer represented by the formula(R.sub.3 SiO).sub.x (SiO.sub.4/2).sub.y (II)wherein in Formula (II), each R is independently a hydrocarbon group or a group represented by the formula--O(O)C--C(R*).dbd.CH.sub.2wherein R* is hydrogen or a methyl or ethyl group; x is a number from about 0.
    Type: Grant
    Filed: February 27, 1995
    Date of Patent: April 1, 1997
    Assignee: Avery Dennison Corporation
    Inventors: Thanh V. Nguyen, John Allen, Qun Yu
  • Patent number: 5596024
    Abstract: A sealing compound for use in production of a liquid crystal display unit, comprises isobornyl(meth)acrylate, epoxy acrylate, a photopolymerizable initiator, epoxy resin having one or more polymerizable groups in one molecule, a latent thermosetting agent obtained by pretreating imidazole compounds, adducts of imidazole compounds and carboxylate of imidazole compounds, and/or adducts of imidazole compounds and epoxy resin with isocyanate compounds. The sealing compound is applicable particularly for sealing liquid crystal in between substrates of the liquid crystal display unit, and can secure the electrode substrates without misregistration of the substrates and uneven separation of the substrates.
    Type: Grant
    Filed: April 18, 1995
    Date of Patent: January 21, 1997
    Assignee: Three Bond Co., Ltd.
    Inventors: Ken'ichi Horie, Hidefumi Miura, Eiichi Tomioka
  • Patent number: 5587403
    Abstract: Ultraviolet radiation-curable primary coating compositions for optical fibers are disclosed. The primary coatings comprise a polyether polyol-based reactively terminated aliphatic urethane oligomer; one or more diluent monomers terminated with at least one end group capable of reacting with the reactive terminus of the oligomer; an organofunctional silane adhesion promoter; and an optional photoinitiator. Also disclosed are optical fibers coated with the coatings of the invention, and processes for preparing same.
    Type: Grant
    Filed: January 17, 1996
    Date of Patent: December 24, 1996
    Assignee: Borden, Inc.
    Inventor: Paul J. Shustack
  • Patent number: 5539012
    Abstract: Resin compositions useful for filament winding applications comprising an epoxy component including at least one polyepoxide resin curable by heat, an olefinicially unsaturated monomer component including at least one polyolefinically unsaturated monomer curable by actinic radiation, a cyanate ester component including at least one cyanate ester compound having at least two cyanate functional groups per molecule, at least one organic peroxide, at least one photoinitiator, and a heat activated curing agent for epoxides. The compositions have a viscosity less than about 2000 centipoise (cps) and are capable of retaining this viscosity for at least about 6 months at about ambient temperature. The resins are capable of being immobilized by actinic radiation exposure and further heat cured without substantial resin drip. One or more organic peroxides are employed, selected from the group of organic peroxides having 10 hour decomposition half-lives at temperatures of from about 50.degree. C. to less than about 104.
    Type: Grant
    Filed: August 18, 1993
    Date of Patent: July 23, 1996
    Assignee: Loctite Corporation
    Inventors: Philip T. Klemarczyk, Yoshihisa Okamoto
  • Patent number: 5538791
    Abstract: Ultraviolet radiation-curable primary coating compositions for optical fibers are disclosed. The primary coatings comprise a polyether polyol-based reactively terminated aliphatic urethane oligomer; one or more diluent monomers terminated with at least one end group capable of reacting with the reactive terminus of the oligomer; an organofunctional silane adhesion promoter; and an optional photoinitiator. Also disclosed are optical fibers coated with the coatings of the invention, and processes for preparing same.
    Type: Grant
    Filed: May 31, 1995
    Date of Patent: July 23, 1996
    Assignee: Borden, Inc.
    Inventor: Paul J. Shustack
  • Patent number: 5534558
    Abstract: In a process for cladding an optical fiber, a photoinitiator monomer having both a photoinitiating group and an ethylenically unsaturated group is reacted with a fluorosubstituted monomer having an ethylenically unsaturated group, thereby preparing a copolymer having pendant photoinitiating groups. This copolymer is then mixed with a fluorosubstituted diacrylate, thereby forming a photopolymerizable composition, which is coated on to the optical fiber and exposed to ultraviolet light, thereby curing the photopolymerizable composition to produce a cladding on the optical fiber. Preferred claddings can have refractive indices below 1.35.
    Type: Grant
    Filed: June 2, 1995
    Date of Patent: July 9, 1996
    Assignee: Polaroid Corporation
    Inventor: Richard A. Minns
  • Patent number: 5532286
    Abstract: A photopolymerizable composition comprising a crosslinking agent, a UV sensitive photopolymerization initiator and a thioether compound having a vinyl ester or vinyl amide component; wherein the crosslinking agent and the thioether may be the same compound.
    Type: Grant
    Filed: March 16, 1995
    Date of Patent: July 2, 1996
    Assignee: Eastman Kodak Company
    Inventors: Elizabeth G. Burns, Susan A. Visser, Jeffrey F. Taylor
  • Patent number: 5527925
    Abstract: Compounds of formula I: ##STR1## are disclosed. The compounds are photoinitiators which can be functionalized by means of ethylenic groups or can be bonded to H-active substances, in order, for example, to modify surfaces by means of photopolymerizable substances. The compounds are especially useful in the manufacture of contact lenses.
    Type: Grant
    Filed: June 24, 1994
    Date of Patent: June 18, 1996
    Assignee: Ciba-Geigy Corporation
    Inventors: Peter Chabrecek, Dieter Lohmann
  • Patent number: 5527835
    Abstract: Ultraviolet radiation-curable primary coating compositions for optical fibers are disclosed. The primary coatings comprise a polyether polyol-based reactively terminated aliphatic urethane oligomer; one or more diluent monomers terminated with at least one end group capable of reacting with the reactive terminus of the oligomer; an organofunctional silane adhesion promoter; and an optional photoinitiator. Also disclosed are optical fibers coated with the coatings of the invention, and processes for preparing same.
    Type: Grant
    Filed: November 16, 1994
    Date of Patent: June 18, 1996
    Assignee: Borden, Inc.
    Inventor: Paul J. Shustack
  • Patent number: 5516509
    Abstract: A clear, photocurable coating composition to be applied over wet nail polish on a nail for binding with the wet nail polish upon exposure to ultraviolet light, consisting of: between 5% and 50% by weight of a film-forming polymer selected from the group consisting of:i) cellulose estersii) acrylic polymers,between 2% and 15% by weight of a photoinitiator selected from the group consisting of:i) benzophenoneii) alkylphenyl ketone, andiii) cyclohexylphenyl ketone;and between 40% and 85% by weight of a photoreactive monomer selected from the group consisting of methacrylic acid esters.
    Type: Grant
    Filed: October 17, 1994
    Date of Patent: May 14, 1996
    Assignee: International Beauty Design, Inc.
    Inventors: Debra Marr-Leisy, Naranbhai N. Patel
  • Patent number: 5492987
    Abstract: In a process for cladding an optical fiber, a photoinitiator monomer having both a photoinitiating group and an ethylenically unsaturated group is reacted with a fluorosubstituted monomer having an ethylenically unsaturated group, thereby preparing a copolymer having pendant photoinitiating groups. This copolymer is then mixed with a fluorosubstituted diacrylate, thereby forming a photopolymerizable composition, which is coated on to the optical fiber and exposed to ultraviolet light, thereby curing the photopolymerizable composition to produce a cladding on the optical fiber. Preferred claddings can have refractive indices below 1.35.
    Type: Grant
    Filed: June 2, 1995
    Date of Patent: February 20, 1996
    Assignee: Polaroid Corporation
    Inventor: Richard A. Minns
  • Patent number: 5492733
    Abstract: A gloss coating composition comprising radiation curable oligomers and monomers, and photosensitizers in a homogeneous mixture having a viscosity in the range of 4500 to 8000 cps; wherein the presence of the photosensitizers causes polymerization of the radiation curable oligomers and monomers when exposed to an ultraviolet light source. The coating composition is applied to at least one surface of a substrate and exposed to an ultraviolet light source resulting in curing of the composition onto the substrate surface without substantial penetration into the substrate surface forming a gloss coated substrate.
    Type: Grant
    Filed: September 20, 1993
    Date of Patent: February 20, 1996
    Assignee: International Paper Company
    Inventors: Guy D'Anna, Stephen H. Monroe, Peter J. Angelini, James A. Goettmann, John R. Boylan
  • Patent number: 5470892
    Abstract: A photopolymerizable resin is formed from between about 50% to 90% by weight of a polymerizable base component, between about 1% and 20% by weight of a cross-linker, between about 0.5% and 6% by weight of a photoinitiator, and between about 0.5% and 20% by weight of a viscosity control agent. Preferably the resin has a viscosity above 25 and below 130 centistokes at 68.degree. F. In a preferred embodiment, the resin includes between about 0.5% and 3.0% by weight of fumed silica or fine mesh silica as a viscosity control agent, and is cured under the combined influence of heat and actinic radiation to form a clear, hard, plastic optic having a refractive index of greater than or equal to 1.50 and a scratch resistance greater than or equal to 1.0 in a Bayer abrader and hazemeter. A method and apparatus for forming improved ophthalmic lenses is also included.
    Type: Grant
    Filed: May 1, 1992
    Date of Patent: November 28, 1995
    Assignee: Innotech, Inc.
    Inventors: Amitava Gupta, Ronald D. Blum
  • Patent number: 5453451
    Abstract: A sprayable coating composition is formulated using one or more acrylates and one or more photoinitiators which act to polymerize the composition when exposed to ultraviolet light. Because of the use of low molecular weight monomers or oligomers, the composition is essentially free of volatile organic solvents and therefore evaporative emissions in curing are substantially eliminated.
    Type: Grant
    Filed: March 29, 1993
    Date of Patent: September 26, 1995
    Inventor: Andrew A. Sokol
  • Patent number: 5416126
    Abstract: A composition which is cured upon exposure to ultraviolet light in the absence of solvent is disclosed. The liquid composition is prepared by combining a liquid maleate polyester and at least one of a vinyl compound and an allyl functional compound. A photoinitiator is then added to the polymerizable liquid composition. A substrate is impregnated with the polymerizable liquid composition and exposed to actinic energy of a sufficient dosage for a sufficient amount of time to polymerize the composition to a sufficient degree to impart useful properties to the substrate. The composition can be used as a binder for fiberglass insulation, in the manufacture of transparent or semi-transparent paper and to manufacture paper for use in photocopy machines.
    Type: Grant
    Filed: February 17, 1993
    Date of Patent: May 16, 1995
    Assignee: DSM N.V.
    Inventors: Edward J. Murphy, Edward P. Zahora, Sami A. Shama
  • Patent number: 5391587
    Abstract: Photoinitiators having a terminal fluoroalkyl moiety are useful for photopolymerizing and photocuring fluorinated as well as non-fluorinated monomers, especially fluorinated acrylic monomers.
    Type: Grant
    Filed: April 30, 1993
    Date of Patent: February 21, 1995
    Assignee: AlliedSignal Inc.
    Inventor: Chengjiu Wu