Phenolic, E.g., Hydroquinone, Etc. Patents (Class 522/69)
  • Patent number: 11732135
    Abstract: A photocurable silicone composition is disclosed. The composition comprises 4,5,6,7-tetrachloro-3?,6?-dihydroxy-2?,4?,5?,7?-tetraiodospiro[2-benzofuran-3,9?-xanthen]-1-one as a photochromic pigment. The photochromic pigment is present in an amount of from about 0.001 to about 0.05 mass % of a total amount of the composition. The composition can indicate a cure point thereof by disappearance of color.
    Type: Grant
    Filed: November 25, 2020
    Date of Patent: August 22, 2023
    Assignee: DOW SILICONES CORPORATION
    Inventors: Gyuyoung Lee, Juyoung Yook
  • Patent number: 9823401
    Abstract: A cured-film formation composition that includes: (A) one or more compounds having a photo-aligning group and hydroxy group, etc.; (B) a polymer having at least one substituent from the group of a hydroxy group, carboxy group, amino group, and alkoxysilyl group, and the like; and (C) a cross-linking agent. Component (A) contains a compound having a group of Formula [1] below as the photo-aligning group: where A1 and A2 are independently a hydrogen atom or methyl group; and A3 is a hydroxy group. A cured-film is formed from the cured-film formation composition, and orientation material is formed by use of photo-alignment technique. A retardation material is obtained by applying a polymerizable liquid crystal on the orientation material and curing it.
    Type: Grant
    Filed: June 15, 2016
    Date of Patent: November 21, 2017
    Assignee: NISSAN CHEMICAL INDUSTRIES, LTD.
    Inventors: Kohei Goto, Shojiro Yukawa, Masato Moriuchi, Tadashi Hatanaka
  • Patent number: 9529132
    Abstract: A cured-film formation composition to form a cured film having excellent liquid-crystal alignment properties, orientation material, and retardation material by use of the orientation material. A cured-film formation composition includes: (A) one or more compounds having a photo-aligning group and hydroxy group, etc.; (B) a polymer having at least one substituent from the group of a hydroxy group, carboxy group, amino group, and alkoxysilyl group, and the like; and (C) a cross-linking agent, the component (A) contains at least a compound having a group of Formula [1] below as the photo-aligning group: (in the Formula, A1 and A2 are independently a hydrogen atom or methyl group; and A3 is a hydroxy group, etc.). A cured-film is formed from the cured-film formation composition, and orientation material is formed by use of photo-alignment technique. A retardation material is obtained by applying a polymerizable liquid crystal on the orientation material and curing it.
    Type: Grant
    Filed: March 6, 2014
    Date of Patent: December 27, 2016
    Assignee: NISSAN CHEMICAL INDUSTRIES, LTD.
    Inventors: Kohei Goto, Shojiro Yukawa, Masato Moriuchi, Tadashi Hatanaka
  • Publication number: 20150099127
    Abstract: Disclosed herein is an adhesive composition for polarizing plates having increased adhesion by preventing curing inhibition due to moisture. The present invention provides an adhesive composition for polarizing plates, comprising: (A) a radical polymerizable monomer; (B) a cationic polymerizable monomer; (C) an unsaturated dicarboxylic acid anhydride; and (D) an initiator.
    Type: Application
    Filed: February 14, 2013
    Publication date: April 9, 2015
    Inventors: Hirosh Ogawa, Tatsuhiro Suwa
  • Publication number: 20140187663
    Abstract: A telechelic macromer is disclosed having (meth)acrylic end-groups and a core. The macromer defined by Formula 1 comprises a core Y (Formulas 2 to 9) that is linked to (meth)acrylic groups by urethane, ester or anhydride bonds and has iodine value ranging from 5 to 75. The method involves a chemical reaction carried out in solvent, ranging 6-24 hours, wherein the precursor of a core (Formulas 2 and 3) reacts in two stages with compounds forming urethane bonds, or wherein the precursor of a core (Formulas 4 to 8) reacts in one stage with compounds forming ester bonds, or wherein the precursor of a core defined by Formula 9 reacts in one stage with compounds forming anhydride bonds. The urethane, ester and anhydride moieties comprise groups capable of free radical polymerization isolating the final product by evaporation. The composition disclosed provides the macromer, a photoinitiator and possibly a reactive diluent.
    Type: Application
    Filed: December 27, 2012
    Publication date: July 3, 2014
    Applicant: ZACHODNIOPOMORSKI UNIWERSYTET TECHNOLOGICZNY W SZCZECINIE
    Inventors: Miroslawa EL FRAY, Jedrzej Skrobot
  • Publication number: 20130248110
    Abstract: A sealing composition and a method of manufacturing a display panel using the sealing composition are disclosed. The sealing composition includes about 10% by weight to about 80% by weight of a denatured epoxy resin having a methacrylate group, about 5% by weight to about 40% by weight of a photo-curing acrylate monomer, about 1% by weight to about 10% by weight of a heat-curing agent, about 1% by weight to about 10% by weight of a photo-polymerization initiator, about 5% by weight to about 50% by weight of a filler, about 1% by weight to about 10% by weight of a flexibility improving agent and about 0.001% by weight to about 8% by weight of an additive.
    Type: Application
    Filed: February 7, 2013
    Publication date: September 26, 2013
    Applicant: Samsung Display Co., Ltd.
    Inventors: Ki-Beom LEE, Hyang-Shik Kong, Hyun-Seok Kim, Sung Hee Lee, Seung-Jun Lee, Jae-Hyuk Chang, Gug-Rae Jo
  • Publication number: 20130123381
    Abstract: The invention includes a new photopolymerizable resin system for dental restorative materials. The resin system utilizes a thiol-ene component as the reactive diluent in dimethacrylate systems. The ternary resin system comprises a thiol monomer, an ene monomer and a dimethacrylate monomer. The system of the invention has enhanced overall functional group conversion, improved polymer mechanical properties, and reduced shrinkage stress of the ternary system when compared to either traditional dimethacrylate or thiol-ene resin systems.
    Type: Application
    Filed: January 7, 2013
    Publication date: May 16, 2013
    Applicant: The Regents of the University of Colorado, a body Corporate
    Inventor: The Regents of the University of Colorado, a body Corporate
  • Publication number: 20130071658
    Abstract: The present invention aims to provide an adhesive composition having high adhesive strength, as well as being easily detachable and having excellent heat resistance, an adhesive tape comprising the adhesive composition, a method for treating a semiconductor wafer using the adhesive tape, and a method for producing a TSV wafer. The present invention relates to an adhesive composition comprising: an adhesive component; and a tetrazole compound represented by the following formula (1), formula (2), or formula (3), or its salt: wherein R1 and R2 each may be hydrogen, a hydroxy group, an amino group, or a C1-C7 alkyl group, alkylene group, phenyl group, or mercapto group; and the C1-C7 alkyl group, alkylene group, phenyl group, and mercapto group may be substituted.
    Type: Application
    Filed: March 17, 2011
    Publication date: March 21, 2013
    Applicant: Sekisui Chemical Co., Ltd.
    Inventors: Shigeru Nomura, Daihei Sugita, Toru Tonegawa
  • Publication number: 20120283350
    Abstract: The invention aims to provide a resin composition having favorable stain resistance and storage stability even in the form of a one-pack coating material. Provided is a resin composition for a coating material, including: (I) a synthetic resin emulsion; (II) a silicon compound represented by the formula (1): (R1O)4-aSiR2a??(1) wherein R1s are the same or different and each represent an alkyl group having 1-10 carbon atoms, an aryl group having 6-10 carbon atoms, or an aralkyl group having 7-10 carbon atoms; R2s are the same or different and each represent an alkyl group having 1-10 carbon atoms, an aryl group having 6-10 carbon atoms, or an aralkyl group having 7-10 carbon atoms; and a represents an integer from 0 to 2; and/or a partial hydrolysis condensation product thereof and/or a modified product thereof; and (III) a photosensitizer.
    Type: Application
    Filed: November 10, 2010
    Publication date: November 8, 2012
    Applicant: KANEKA CORPORATION
    Inventors: Takahiro Saito, Shinji Kagitani, Youichi Matsuo
  • Publication number: 20120225012
    Abstract: The composition for hard tissue repair of the present invention is characterized by comprising 5 to 98.95 parts by weight of a monomer (A), 1 to 75 parts by weight of a (meth)acrylate polymer (B) and 0.05 to 20 parts by weight of a polymerization initiator composition (C) containing an organoboron compound (c1), with the proviso that the total amount of the components (A), (B) and (C) is 100 parts by weight. The composition undergoes small-scale heat generation during curing and can ensure a sufficient working time.
    Type: Application
    Filed: November 18, 2010
    Publication date: September 6, 2012
    Applicant: MITSUI CHEMICALS, INC.
    Inventors: Noriaki Asada, Shinya Aoki, Hiroshi Naruse, Shoichi Miyakoshi, Masami Arata
  • Publication number: 20120205043
    Abstract: Provided is an adhesive (meth)acrylic resin composition being high in adhesiveness and capable of affording an adhered body which can be used at high temperatures of 250° C. or higher, and possessing low outgassing property and heat resistance. A (meth)acrylic resin composition including (A) a polyfunctional (meth)acrylate, and (B) a photopolymerization initiator that exhibits a mass loss on heating of 15% by mass or less when increasing temperature from 30° C. to 250° C. at a temperature increase rate of 10° C./min. under nitrogen flow, wherein the glass transition temperature of a cured body obtained from the composition is 250° C. or higher.
    Type: Application
    Filed: October 20, 2010
    Publication date: August 16, 2012
    Applicant: DENKI KAGAKU KOGYO KABUSHIKI KAISHA
    Inventors: Hiroyuki Kurimura, Isamu Ichikawa, Takayuki Nagumo, Takako Hoshino, Jun Watanabe
  • Publication number: 20120196949
    Abstract: The present invention relates to a fluorene-based resin polymer, and a photosensitive resin composition including the same, and the fluorene-based resin polymer according to the exemplary embodiment of the present invention has a high molecular weight, a low acid value, and excellent developing property, adhesive property and stability.
    Type: Application
    Filed: January 27, 2012
    Publication date: August 2, 2012
    Applicant: LG CHEM, LTD.
    Inventors: Yoon Hee HEO, Kwang Han PARK, Han Soo KIM, Changho CHO, Sunhwa KIM, Won Jin CHUNG
  • Publication number: 20120083547
    Abstract: The present disclosure relates to a nail coating system comprising a basecoat, a color layer, and a topcoat. The system of the present disclosure may be applied to natural and/or pre-existing artificial nail coatings. The present disclosure relates generally to compositions for natural and artificial nail coatings, and particularly, but not by way of limitation, to polymerizable compositions and color layers polymerized therefrom. The disclosure further relates to methods of making a polymerized color layer.
    Type: Application
    Filed: November 23, 2011
    Publication date: April 5, 2012
    Applicant: Creative Nail Disign, Inc.
    Inventors: Thong H. VU, Diane Marie Larsen, Chad Conger
  • Publication number: 20120021383
    Abstract: A radically curable polyurethane composite for dental restorations, including provisional restorations, includes polyurethane dimethacrylate prepolymers that have at least one flexible unit within a polyurethane dimethacrylate backbone, and one or more dimethacrylate monomers. Composite materials made with polyurethane dimethacrylate prepolymers of the invention exhibit superior and optimal properties of flexural strength and deflection-at-break relative to conventional dental resin composites. Composite materials of the invention also provide improved melt-resistance in response to the heat of grinding or finishing, thereby improving the fit of restorations made from the composite and preserving the finishing instruments. Methods of treating a tooth using the radically curable polyurethane composite and methods of making the polyurethane dimethacrylate prepolymers with flexible units is also provided. A kit including the radically curable polyurethane composite is also described.
    Type: Application
    Filed: July 23, 2010
    Publication date: January 26, 2012
    Applicant: PULPDENT CORPORATION
    Inventors: Sunny Skaria, Kenneth Berk
  • Publication number: 20100197821
    Abstract: Disclosed is an adhesive composition including a compound having a multi-functional urethane (meth)acrylate group and an adhesive film prepared by using it. The adhesive composition includes compounds represented by Chemical Formulae 1 to 3. The compound represented by Chemical Formulae 1 to 3 includes an urethane (meth)acrylate group represented by the Chemical Formula 1-1 or 1-2.
    Type: Application
    Filed: August 11, 2009
    Publication date: August 5, 2010
    Applicant: SAMSUNG ELECTRONICS CO., LTD.
    Inventors: Chul Ho JEONG, Yi Yeol LYU, Sun Jin SONG
  • Publication number: 20100069521
    Abstract: The invention relates to a method of increasing the storage stability and preventing yellowing under the action of UV-light, of a UV-curable composition comprising a1) at least one oligomer, co-oligomer, polymer or copolymer or a mixture thereof having at least one ethylenically unsaturated bond; or a2) a mixture of at least one ethylenically unsaturated monomer with at least one oligomer, co-oligomer, polymer or copolymer having at least one ethylenically unsaturated bond; and one or more ?-hydroxycycloalkylphenyl ketone or bisacylphosphine oxide photoinitiators, which method comprises adding b) at least one stable sterically hindered nitroxyl free-radical or at least one compound of the benzofuran-2-one type or a mixture of the two compounds.
    Type: Application
    Filed: November 18, 2009
    Publication date: March 18, 2010
    Inventors: TUNJA JUNG, Andreas Valet
  • Publication number: 20080305707
    Abstract: [Problems] To provide a radiation curable resin having an extremely low possibility of contaminating liquid crystals, and a liquid crystal sealing material using such a photopolymerization initiator. [Means for Solving Problems] A liquid crystal sealing material characterized by comprising (a) a radiation curable resin represented by the general formula (1) below, (b) a photopolymerization initiator and (c) a filler having an average particle diameter of not more than 3 ?m.
    Type: Application
    Filed: October 12, 2005
    Publication date: December 11, 2008
    Applicant: NIPPON KAYAKU KABUSHIKI KAISHA
    Inventors: Masahiro Imaizumi, Yasumasa Akatuka, Naoyuki Ochi, Eiichi Nishihara, Masaru Kudou, Toyohumi Asano, Naoki Toneda, Masahiro Hirano
  • Patent number: 7462658
    Abstract: Curable compositions are provided which contain a curable component and particular m-hydroxybenzene derivatives, wherein such derivatives function as aging inhibitors. Such curable compositions are useful as coating agents and adhesives having improved aging resistance.
    Type: Grant
    Filed: April 6, 2007
    Date of Patent: December 9, 2008
    Assignee: Henkel AG & Co. KGaA
    Inventors: Olaf Lammerschop, Steve Doering, Michael Kux, Andreas Ferencz, Stefan Kreiling
  • Patent number: 7460878
    Abstract: In the mobile terminal, the reception quality estimating unit measures a reception quality, and at least one of the data buffer monitoring unit and the transmission power monitoring unit measures a data transmission capability. Based on the measured reception quality and data transmission capability, the terminal determines a transmission mode to be used, and reports it to the base station. The base station determines the transmission mode to be practically used in accordance with the reported transmission mode, and notifies it to the mobile terminal. The base station transmits data according to the determined transmission mode, and the mobile terminal receives data according to the notified transmission mode. Thereby, the radio communication system determines the transmission mode in consideration for not only the reception quality, but also the deficiency in the data transmission capability of the terminal.
    Type: Grant
    Filed: September 1, 2004
    Date of Patent: December 2, 2008
    Assignee: Sony Ericsson Mobile Communications Japan, Inc.
    Inventor: Katsutoshi Itoh
  • Publication number: 20080258345
    Abstract: The present invention relates to liquid radiation-curing compositions having flexible and elastic material properties in the cured state, consisting of the following components: a) from 5.0 to 99.0% by weight of a di- or polyfunctional polyether (meth)-acrylate compound having a molecular weight of more than 1000 g/mol; b) from 1.00 to 90.0% by weight of a mono-, di- or polyfunctional radiation-curing (meth)acrylate compound having a molecular weight of less than 1000 g/mol as a reactive component or reactive thinner or cross-linking agent for the formation of polymer networks; c) from 0.05 to 10.0% by weight of a free-radical forming photoinitiator; d) from 0.001 to 5.0% by weight of further components; with the proviso that the sum of components a) to d) amounts to 100% by weight.
    Type: Application
    Filed: July 15, 2005
    Publication date: October 23, 2008
    Inventors: Arthur Thomas Bens, Hermann Seitz, Carsten Tille
  • Publication number: 20080214691
    Abstract: A process for preparing binders containing allophanate groups which contain, at the oxygen atom of the allophanate group that is bonded via two single bonds, organic radicals with activated groups capable of participating in a polymerization reaction with ethylenically unsaturated compounds on exposure to actinic radiation; the process includes reacting A) one or more compounds containing uretdione groups with B) one or more OH-functional compounds which contain groups capable of participating in a polymerization reaction with ethylenically unsaturated compounds on exposure to actinic radiation, and C) optionally further NCO-reactive compounds, and D) in the presence of one or more compounds containing phenoxide groups, as catalysts. The binders can be used in preparing coatings, coating materials, coating compositions, adhesives, printing inks, casting resins, dental compounds, sizes, photoresists, stereolithography systems, resins for composite materials and sealants.
    Type: Application
    Filed: February 22, 2008
    Publication date: September 4, 2008
    Inventors: Christophe Detrembleur, Jan Weikard, Dorota Greszta-Franz, Frank Richter, Wolfgang Fischer, Jorg Schmitz, Holger Mundstock
  • Publication number: 20080051483
    Abstract: The present invention relates to a photosensitive resin composition, and more particularly, to a photosensitive resin composition for forming an over coating layer of a color filter. The photosensitive resin composition according to the present invention includes a UV absorber. The photosensitive resin composition according to the present invention adjusts line width and height of a pattern without difficulty, forms a linear pattern, provides good transmittance and is adequate to form the over coating layer of the color filter.
    Type: Application
    Filed: August 24, 2007
    Publication date: February 28, 2008
    Applicant: DONGJIN SEMICHEM Co., Ltd.
    Inventors: Hyun-il CHO, Taeg-sung JUNG, Hee-jung JUNG, Chan-seok PARK
  • Patent number: 7244548
    Abstract: A photopolymerizing composition and a photopolymerizing recording medium manufactured using the composition, wherein the photopolymerizing composition contains: 1.0-99.0% by weight of at least one kind of polymerizable compound; 0.05-0.5% by weight of at least one kind of photosensitizer selected from among photochromic compounds that change color by incoherent UV light irradiation; 0.2-6.0% by weight of a coinitiator that is activated by visible light in the presence of a photoinduced form of the photochromic compound transformed by incoherent UV light to photopolymerize the polymerizable compound; 0-97.5% by weight of a polymer binding agent; 0-6.0% by weight of a plasticizer; and 0-3.0% by weight of a non-polymerizing solvent. The photopolymerizing recording medium has a high angular diffraction selectivity and thus can be effectively used to manufacture a 3D holographic optical memory with ultra high information storage capacity.
    Type: Grant
    Filed: November 22, 2004
    Date of Patent: July 17, 2007
    Assignees: Samsung Electronics Co., Ltd., Photochemistry Center of Russian Academy of Sciences
    Inventors: Valery Aleksandrovich Barachevsky, Svetlana Ivanovna Peredereeva, Dmitry Valerevich Nesterenko, Aleksandr Vladimirovich Lyubimov, Viktor Kamilievich Salahutdinov, Mikhail Mikhailovich Krayushkin, Nataliya Timofeovna Sokolyuk, Andrei Leanovich Mikaelyan
  • Patent number: 6590011
    Abstract: An epoxy-amine composition includes an epoxy resin, an amine curative and a latent catalyst. The latent catalyst does not cause the instant acceleration of the reaction between epoxides and amines. In the presence of radiation, the latent catalyst generates an active catalyst that accelerates/initiates the cure process of the epoxy-amine composition.
    Type: Grant
    Filed: April 30, 2001
    Date of Patent: July 8, 2003
    Assignee: Polymeright, Inc.
    Inventors: Leonid Rappoport, Alex Vainer, Aleksander Yam
  • Patent number: 6451869
    Abstract: Cyclopentadienylplatinum (IV) compounds having C7-20 aromatic radical substitution on the cyclopentadienyl ring have been found to impart enhanced cure speed and shelf-life stability to irradiation-curable silicone mixtures.
    Type: Grant
    Filed: September 13, 2000
    Date of Patent: September 17, 2002
    Assignee: General Electric Company
    Inventor: Matthew David Butts
  • Patent number: 6020396
    Abstract: Improved bone cement compositions and method of fixing a prosthetic implant to a bone using said improved bone cement compositions. More particularly, bone cement compositions having enhanced fatigue strength and consequently an increased projected service life when placed in a patient to fix a prosthetic implant securely in place. Specifically, bone cement compositions comprising a conventional poly[(methyl methacrylate)-styrene] copolymer based bone cement consisting of a liquid component and a dry powder component, and poly(butyl methacrylate) powder wherein at least a trace but no more than 5 wt % of the dry powder component is replaced by an equal mass of the poly(butyl methacrylate) powder.
    Type: Grant
    Filed: March 13, 1998
    Date of Patent: February 1, 2000
    Assignee: The Penn State Research Foundation
    Inventor: Christopher R. Jacobs
  • Patent number: 5712322
    Abstract: A composition of matter useful in the production of photoinitiator compositions, said compositions of matter comprising 100 parts by weight of camphorquinone and from 1 to 50 parts by weight of an anthraquinone compound having in the 2-position a substituent of the formula:--X--COR.sup.1 (1)wherein R.sup.1 represents an optionally substituted hydrocarbyl radical and X represents ##STR1## wherein R.sup.2 represents hydrogen or an optionally substituted hydrocarbyl radical.
    Type: Grant
    Filed: October 6, 1995
    Date of Patent: January 27, 1998
    Assignee: Zeneca Limited
    Inventors: Pushpito Kumar Ghosh, Iain Andrew Weddell, John Edward Yates
  • Patent number: 5710193
    Abstract: Colorants, polymeric binder resins, photoinitiators, photosensitizers, color-change agents, anti-halation agents, stabilizers, and other active hydrogen-containing components of radiation sensitive compositions for lithographic printing plate production and the like are reacted with a polyethylenically unsaturated monoisocyanate compound of the formula ##STR1## wherein Y is the residue of a monohydroxyl compound of formula YOH and Y contains at least two ethylenically unsaturated double bonds. In this way the components are bonded to the image on exposure.
    Type: Grant
    Filed: May 21, 1996
    Date of Patent: January 20, 1998
    Assignee: DuPont (UK) Limited
    Inventors: John Robert Wade, Michael John Pratt, Jianrong Ren
  • Patent number: 5459173
    Abstract: Stable thiol-ene compositions are provided which comprise a polythiol, a polyene and a stabilizer system comprising an alkenyl substituted phenolic compound having a formula: ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 are independently selected from the group consisting of H, OR, a C.sub.1 -C.sub.8 alkyl, substituted alkyl, alkenyl or substituted alkenyl, a C.sub.6 -C.sub.20 aryl or substituted aryl, or a cyano group; R.sup.4 is H, R, OR, halogen, COR, COOR, or SR; R.sup.5 is OH, OR, OCOR, OCOOR, OCONHR, or OTMS; R is a C.sub.1 -C.sub.6 alkyl, a cycloalkyl, or a C.sub.6 -C.sub.20 caryl or substituted aryl; x and y are 1, 2, or 3; z is 0, 1, or 2; and x+y+z=2, 3, or 4; or a formula: ##STR2## where x, y, z, w, R.sup.1 R.sup.2 R.sup.3, R.sup.4 and R.sup.5 are defined as above, except that x+y+z=2-6, and R.sup.6 is CH.sub.2, C(CH.sub.3).sub.2, O, S, or SO.sub.
    Type: Grant
    Filed: June 22, 1993
    Date of Patent: October 17, 1995
    Assignee: Loctite Corporation
    Inventors: David M. Glaser, Anthony F. Jacobine, Paul J. Grabek
  • Patent number: 5340847
    Abstract: A composition useful as a liquid gasket, having high working efficiency and high initial pressure resistance, is provided. The composition, characterized by being curable by ultraviolet light and by moisture, includes (a) a polysiloxane containing, on at least one molecular end, at least one group selected from the group consisting of (meth)acryl, glycidyl, propenyloxysilyl and thiol; (b) a polyorganosiloxane having silanol groups at both molecular ends; (c) a polyorganosiloxane having, on at least one molecular end, a hydrolyzable group; (d) a photopolymerization catalyst; and (e) a condensation catalyst.
    Type: Grant
    Filed: July 23, 1993
    Date of Patent: August 23, 1994
    Assignee: Three Bond Co., Ltd.
    Inventors: Yasuo Hanazuka, Ikuzo Usami, Kazuyuki Chiba, Noriko Mizutani
  • Patent number: 5234791
    Abstract: A radiation-curable composition which comprises a compound that forms an acid under the action of high-energy radiation and an acid-hardening substance, wherein the compound forming an acid contains aromatically linked chlorine or bromine and has a pK.sub.a value below 12. The composition and the recording material prepared therefrom display increased sensitivity, improved resolution and a high etch resistance after development.
    Type: Grant
    Filed: June 21, 1989
    Date of Patent: August 10, 1993
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Ralph Dammel, Karl-Friedrich Doessel, Juergen Lingnau, Juergen Theis
  • Patent number: 5153323
    Abstract: Radiation-sensitive organo-halogen compounds having a photo-labile halomethyl-1,2,5-triazine moiety and at least one photoinitator moiety within one molecule. The compounds of this invention are good photoinitiators, and compositions containing them can be used in printing, duplicating, copying, and other imaging systems. The compounds of this invention eliminate the need for a combination of photoinitiators in a photocurable or photopolymerizable composition.
    Type: Grant
    Filed: March 28, 1991
    Date of Patent: October 6, 1992
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Mitchell A. Rossman, James A. Bonham
  • Patent number: 4916169
    Abstract: A process for the addition of compounds containing silicon-bonded hydrogen to compounds containing aliphatic unsaturation and compositions suitable for said process. The process is activated by visible radiation and is conducted in the presence of a platinum complex having one cyclopentadienyl group that is eta-bonded to the platinum atom and three aliphatic groups that are sigma-bonded to the platinum atom and a sensitizer that is capable of absorbing visible light and is capable of transferring energy to said platinum complex such that the hydrosilation reaction is initiated upon exposure to visible light. The invention also provides for use in the aforementioned process.
    Type: Grant
    Filed: September 9, 1988
    Date of Patent: April 10, 1990
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Larry D. Boardman, Joel D. Oxman
  • Patent number: 4777213
    Abstract: Promoters for a crosslinking reaction involved in the curing of a system comprising crosslinkable polymers are bound to polymeric microparticles having a diameter of about 0.01 to 6 microns prepared by polymerizing a mixture of ethylenically unsaturated monomers. The microparticles carrying the crosslinking reaction promoter may be incorporated to coating compositions, printing inks, sealants, adhesives and other polymeric products in place of conventional crosslinking reaction promoters.
    Type: Grant
    Filed: March 2, 1987
    Date of Patent: October 11, 1988
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Kazunori Kanda, Shinichi Ishikura, Keizou Ishii, Akio Kashihara
  • Patent number: 4746514
    Abstract: Homogeneous hydrogels comprise a water-soluble sugar, derivative or mixture thereof, radiation cross-linked with at least one ethylenically unsaturated compound. A preferred combination is sucrose or glucose cross-linked with acrylic acid. The hydrogels may contain additives e.g. plasticizers such as glycerol. The hydrogels are strong and expand to a large extent e.g. 30.times. on water absorption. They are particularly suitable for use in medical dressings, preferably bonded to a supporting film which may be a semi-permeable membrane allowing control of water loss. A method for preparing such a hydrogel and dressing is also described.
    Type: Grant
    Filed: September 11, 1985
    Date of Patent: May 24, 1988
    Assignee: The Secretary of State for Defence in Her Britannic Majesty's Government of the United Kingdom of Great Britain and Northern Ireland
    Inventor: Kevin J. Warne
  • Patent number: 4631247
    Abstract: Disclosed are shelf life improvers for photoresist compositions containing organic halides as the photoinitiator that comprise an acetylene compound having the general formula RC.tbd.CR' where R and R' are each independently phenyl, hydrogen, benzyl, vinyl, lower alkyl substituted vinyl, phenyl substituted vinyl, lower alkoxy methyl and phenoxymethyl.
    Type: Grant
    Filed: August 9, 1985
    Date of Patent: December 23, 1986
    Assignee: Hercules Incorporated
    Inventor: Frank P. Tise