Abstract: Provided herein are core-shell microcapsules useful for compartmentalizing biological molecules in solution. Also provided are processes for manufacturing core-shell microcapsules and methods for using core-shell microcapsules to compartmentalize and optionally process biological entities and molecules.

Abstract: Disclosed is an ink composition for photo-curable ink jet printing, comprising (A) at least one selected from the group consisting of hexanediol acrylate, 3-methyl-1,5-pentanediol diacrylate, dipropylene glycol diacrylate, and hydroxy pivalic acid neopentyl glycol diacrylate, (B) at least one of vinyl amide monomer and acryloyl amine monomer, (C) an acrylated amine compound having two photopolymerizable functional groups and two amino groups in a molecule, (D) a monofunctional monomer (excluding vinyl amide monomer which is the (B) component), and a photopolymerization initiator, wherein a content of the (A) component is 40 to 70% by mass, wherein a content of the (B) component is 5 to 30% by mass, wherein a content of the (C) component is 0.1 to 15% by mass, and wherein a viscosity is 200 mPa·s or less.

Abstract: Methods for fabricating orthodontic appliances are provided. In some embodiments, a method includes providing a polymerizable composition including a first polymerizable component and a second polymerizable component. The polymerizable composition can be characterized by an initial ratio of the first polymerizable component to the second polymerizable component. The method can include fabricating a portion of the orthodontic appliance from the polymerizable composition by forming a first region of the orthodontic appliance by exposing the polymerizable composition to radiation, the first region including a first ratio of the first polymerizable component to the second polymerizable component. The method can also include forming a second region of the orthodontic appliance, the second region including a second ratio of the first polymerizable component to the second polymerizable component. The initial ratio, the first ratio, and the second ratio can be different.

Abstract: Photoresponsive materials for use with a volumetric additive manufacturing system are described herein. Some embodiments of photoresponsive materials described herein include at least one constituent selected from the group consisting of (i) a thiol-containing siloxane prepolymer, (ii) a vinyl-containing siloxane prepolymer, (iii) a reinforcing filler, (iv) a photoinitiator (v) a polymerization inhibitor. Various methods of using the same photoresponsive materials in additive manufacturing processes, such as volumetric additive manufacturing, are also described.

Abstract: Described herein are eye implants that can include a pressure-responsive material that can be capable of changing color in response to pressure exerted on it. Also described here are methods of implanting and using the eye implants described herein to monitor intraocular pressure in a subject. The pressure-responsive material can be used to diagnose and monitor human or animal subjects.

Abstract: An ink jet process includes an ejection step, in which a radiation-curable ink jet composition is ejected from an ink jet head to a recording medium, and a curing step, in which the ejected ink jet composition is irradiated with radiation to give a cured coating of the ink jet composition. The ink jet composition contains at least one polymerizable compound, at least one photopolymerization initiator, and C.I. Pigment Red 57:1. The C.I. Pigment Red 57:1 constitutes 4.0% by mass or more of the total amount of the ink jet composition, and the cured coating has a maximum thickness of 5 ?m or less.

Abstract: Disclosed is an ink composition having excellent storage stability and capable of printing printed material having excellent metal tone. This active energy ray curable ink composition includes at least a scaly metal pigment, a polymerizable compound, and a photopolymerization initiator. The scaly metal pigment has a 50% volume average diameter of at least 0.05 ?m and less than 0.5 ?m, an average thickness of at least 5.0 nm and less than 50.0 nm, and a non-reactive solvent content of 0.01%-5.00% by mass.

Abstract: An ink jet recording apparatus includes an ink composition, an ink encasement in which the ink composition is encased, a recording head that ejects the ink composition, and a carriage configured to move the recording head back and forth. The carriage carries the ink encasement, with the ink encasement integrated with the carriage. The ink encasement has an ink fill port that opens and shuts as a port through which the ink composition is loaded. The ink composition contains a disperse colorant, with the volume-average particle diameter of the disperse colorant being 110.0 nm or more and 200.0 nm or less, and also contains at least one organic solvent with an SP of 9 or more, with the percentage thereof being 10.0% by mass or more.

Abstract: Energy curable composition including partially acrylated polyols, and one or more monofunctional or multifunctional free-radically polymerizable ethylenically unsaturated monomer and/or oligomers.

Abstract: Compositions for and methods of digitally printing an ink image onto a woven textile material are provided. A base application is applied to the surface of a woven textile material, especially one comprising synthetic resin fibers prior to application of an ink image layer. The base application comprises an acrylic latex material that is formulated to be printed on with a digital ink while still wet, thereby eliminating the need for an intermediate drying cycle in between base application deposit and printing of the ink image.

Abstract: Compositions for and methods of digitally printing an ink image onto a woven textile material are provided. A base application is applied to the surface of a woven textile material, especially one comprising synthetic resin fibers prior to application of an ink image layer. The base application comprises an acrylic latex material that is formulated to be printed on with a digital ink while still wet, thereby eliminating the need for an intermediate drying cycle in between base application deposit and printing of the ink image.

Abstract: Compositions for and methods of digitally printing an ink image onto a woven textile material are provided. A base application is applied to the surface of a woven textile material, especially one comprising synthetic resin fibers prior to application of an ink image layer. The base application comprises an acrylic latex material that is formulated to be printed on with a digital ink while still wet, thereby eliminating the need for an intermediate drying cycle in between base application deposit and printing of the ink image.

Abstract: A color sampling display product is provided that includes a radiation-curable water-based coating composition applied to a substrate, and shows mechanical integrity and aesthetic appeal.

Abstract: There is provided an ultraviolet-curable aqueous ink containing: a continuous phase containing water; and a dispersed phase dispersed in the continuous phase, wherein the dispersed phase contains a water-insoluble ultraviolet polymerizable compound, and a water-insoluble ultraviolet polymerization initiator having an absorption at a wavelength range of 375 nm or more and 450 nm or less.

Abstract: A graphics display system is provided in which a graphics layer is printed upon a transparent substrate. An adhesive is generally applied over the graphics layer so that the graphics display system may be permanently affixed to a support. The graphics layer may be digitally printed upon the substrate using one or more UV-curable inks formulated to provide excellent adhesion to the substrate and resistance to degradation by the adhesive. The inks are capable of curing by UV radiation emitted from an LED array as opposed to conventional mercury vapor lamps.

Abstract: A phase change ink composition is provided comprising a UV-curable component, a crystalline component, and an amorphous component, wherein the addition of a UV-curable component imparts improved robustness over the ink that contains only crystalline and amorphous materials.

Abstract: New ester derivatives of hyaluronic acid with hydroxy-cinnamic acid, their rheological and anti-radical properties are used as protective agents in dermatology.

Abstract: A photocurable resin composition for three-dimensional photofabrication operations, including stereolithography, comprising (A) a cationically polymerizable compound having two or more bisphenol structures and one or more hydroxyl groups, (B) a cationically polymerizable compound other than the component (A), (C) a cationic photoinitiator, (D) a radically polymerizable compound, (E) a radical photoinitiator, and (F) multilayer polymer particles having a core and a shell layer, the shell layer containing functional group-modified rubber polymer particles having at least one reactive functional group.

Abstract: This invention relates to a printing ink and in particular to an ink for ink-jet printing which is cured by irradiation. The ink comprises at least one radiation-curable monomer; at least one passive thermoplastic resin; at least one radical photoinitiator; and at least one colouring agent; wherein the ink has a viscosity of less than 100 mPas at 25° C., and wherein the at least one passive resin is present at 2 to 15 wt % based on the total weight of the ink and has a molecular weight of 1,500 to 70,000.

Abstract: Disclosed is a curable coating agent composition which exhibits excellent wear resistance and weather resistance when applied as a coating agent to plastic or other substrates to be used outdoors. The curable coating agent composition comprises 95 to 65 parts by mass of a component (A) comprising an urethane adduct compound having weather resistance, 5 to 35 parts by mass of a component (B) comprising a specific organosilicon compound, 0.1 to 10 parts by mass of a component (C) which is a radical polymerization initiator, 1 to 12 parts by mass of a component (D) which is an ultraviolet ray absorber, and 10 to 1,000 parts by mass of a component (E) which is an organic solvent, with respect to 100 parts by mass of the components (A) and (B) in total.

Abstract: The invention provides an aqueous liquid composition containing a water-soluble monomer, a photopolymerization initiator and an aqueous medium and further containing a polymer emulsion, wherein the water-soluble monomer is a monomer that has two or more ethylenically unsaturated bonds and is curable with an active energy ray.

Abstract: A process for producing a molded printed material is provided that includes (A) a step of forming an image on a support by an inkjet method using an ink composition comprising a polymerizable monomer, a colorant, and a polymerization initiator, (B) a step of forming a surface coating layer on the image by an inkjet method using a liquid composition comprising a polymerizable monomer and a polymerization initiator and comprising substantially no colorant, (C) a step of curing the image by irradiation with actinic radiation, (D) a step of curing the surface coating layer by irradiation with actinic radiation so as to obtain a printed material having the image and the surface coating layer cured on the support, and (E) a step of molding the printed material. There is also provided a molded printed material obtained by the process for producing a molded printed material.

Abstract: The present invention relates to methods for making wear and oxidation resistant polymeric materials by high temperature melting. The invention also provides methods of making medical implants containing cross-linked antioxidant-containing tough and ductile polymers and materials used therewith also are provided.

Abstract: A method and a system for producing a change in a medium disposed in an artificial container. The method places in a vicinity of the medium at least one of a plasmonics agent and an energy modulation agent. The method applies an initiation energy through the artificial container to the medium. The initiation energy interacts with the plasmonics agent or the energy modulation agent to directly or indirectly produce the change in the medium. The system includes an initiation energy source configured to apply an initiation energy to the medium to activate the plasmonics agent or the energy modulation agent.

Abstract: The invention provides a process for manufacturing a polymeric material having a compositional gradient, comprising: forming a mixture comprising a first photopolymerizable polymer precursor and a second photopolymerizable precursor, and subjecting said mixture to an intensity gradient of electromagnetic radiation, wherein said first precursor has a greater reactivity ratio than said second precursor, and/or said first precursor is mono-functional and said second precursor is di-functional, and/or said first precursor is less inhibited by oxygen than said second precursor.

Abstract: A modified fluorocarbon resin composition and a modified molded product of fluorocarbon resin composition having an excellent abrasion resistivity and low friction property under high pressure, are provided. The modified fluorocarbon resin composition comprises a blend of fluorocarbon resin and aromatic engineering plastic, which is modified by irradiation of ionizing radiation.

Abstract: The present invention relates to methods for making oxidation resistant homogenized polymeric materials and medical implants that comprise polymeric materials, for example, ultra-high molecular weight polyethylene (UHMWPE). The invention also provides methods of making antioxidant-doped medical implants, for example, doping of medical devices containing cross-linked UHMWPE with vitamin E by diffusion and annealing the anti-oxidant doped UHMWPE in a super critical fluid, and materials used therein.

Abstract: An object to be attained by the present invention is to provide an active energy ray-curable composition that is capable of producing a cured coating film having high scratch resistance and excellent transparency. The present invention relates to an active energy ray-curable composition containing a reactive particle (A) obtained by reacting a silica fine particle (a-1) and a hydrolysable silane (a-2) having one or more (meth)acryloyloxy groups and one or more isocyanurate ring structures in a molecule. The present invention also provides the active energy ray-curable composition according to the above, containing a photopolymerization initiator (B).

Abstract: The active ray-curable inkjet ink comprises a gelling agent, photopolymerizable compounds and a photoinitiator, and reversibly transitions into a sol-gel phase according to the temperature. Therein: (1) a (meth)acrylate compound having a molecular weight of 300-1,500 and having 3-14 (—CH2—CH2—O—) structural units within a molecule is included as the first photopolymerizable compound at a proportion of 30-70 mass % relative to the total mass of the ink; (2) a (meth)acrylate compound having a molecular weight of 300-1,500 and a C log P value of 4.0-7.0 is included as the second photopolymerizable compound at a proportion of 10-40 mass % relative to the total mass of the ink; and (3) the gelling agent has a total of at least 12 carbon atoms, and has a straight or branched alkyl chain including at least three carbon atoms.

Abstract: An ink composition includes: (Component a) a polymerizable compound having an ethylenically unsaturated double bond; (Component b) a polymerization initiator; (Component c) water; and (Component d) a polyhydric alcohol having an alkyleneoxy chain, wherein the (Component a) polymerizable compound includes a monofunctional polymerizable monomer having a (meth)acrylamide structure, and a content of the monofunctional polymerizable monomer is 5% by mass or more with respect to a total content of the (Component a) polymerizable compound.

Abstract: An active ray curable composition, including: a photobase generator; a polymerizable compound; and an acid, wherein the photobase generator is a salt of a carboxylic acid and a basic compound, wherein a ratio by mole of a carboxyl group of the carboxylic acid:a basic functional group of the basic compound is 1:1, and wherein the acid is an acid that loses a function thereof as acid by light or heat.

Abstract: A radiation curable solid ink composition comprising at least one curable wax that is curable by free radical polymerization; at least one monomer, oligomer, or prepolymer; at least one non-curable wax; at least one free-radical photoinitiator or photoinitiating moiety; and a colorant; wherein the components form a curable ink composition that is a solid at a first temperature of from about 20 to about 25° C.; and wherein the components form a liquid composition at a second temperature of greater than about 40° C.

Abstract: The present invention provides an energy ray-curable ink composition excellent in the continuous discharge property, and excellent in curability and adherability. The present invention relates to an energy ray-curable ink composition which contains a coloring agent, contains only a monofunctional monomer having an acrylic equivalent of 300 or less, and having one ethylenic double bond in one molecule, and a polyfunctional monomer having an acrylic equivalent of 150 or less, and having two or more ethylenic double bonds in one molecule as a polymerizable compound, contains an ?-aminoalkylphenone compound and a thioxanthone compound as a photopolymerization initiator, and contains a silicone compound having a polydimethylsiloxane structure as a surface conditioner.

Abstract: Disclosed are a positive photosensitive resin composition that includes (A) an alkali soluble resin; (B) a dissolution controlling agent including the compound represented by Chemical Formula 6; (C) a photosensitive diazoquinone compound; (D) a silane compound; and (E) a solvent, and a photosensitive resin film prepared by using the same.

Abstract: The present invention relates to a novel fluorinated compound, a composition comprising the same, and a method for manufacturing a film by using the same, and more particularly a novel compound having a structure in which one or more fluorine and acrylate-based functional groups are substituted in a silane core, a composition comprising the compound and photoinitiator, and a method for manufacturing a film by using the same. If the composition comprising the compound according to the present invention is used, it is possible to manufacture a film in which a refractive index is low, reflectivity is reduced, and transmissivity is increased.

Abstract: A glass printing ink and glass printing lacquer are prepared, which contain at least one photoinitiator, at least one resin and at least one additional substance. The resin is an epoxy resin based on bisphenol A, diluted in a UV-curing monomer, or a resin with functional groups containing free functional amino, hydroxy, epoxy, acid, acid anhydride and/or acrylate groups, or a combination of the epoxy resin with the resin with functional groups. The at least one additional substance is a wax. The use of the glass printing ink and glass printing lacquer in printing a glass substrate and processes for the printing of a glass substrate are also described.

Abstract: Ink deposited on a substrate by an ink-jet arrangement to form a protective layer includes hardenable oligomer, hardenable monomer selected from a group including alkoxylated and/or poly-alkoxylated acrylic monomers comprising one or more di- or tri-acrylates, and a photoinitiator. The oligomer has a room temperature viscosity greater than 1 Pa·s. The oligomer to monomer weight ratio is between 1/6 and 1/25. The ink has a room temperature viscosity between 15 and 22 mPa·s and between 5 and 2 mPa·s at 60° C., and a room temperature surface tension between 15 and 28 mN/m. The photoinitiator is activated by a UV source having an appropriate wavelength and intensity.

Abstract: A flexographic printing ink for use in a flexographic printing process with wet on wet capability, comprising a polymer and a combination of liquids comprising radiation curable monomers and/or oligomers, diluents, colorants, additives, and photoinitiators, the components having the Hansen Solubility Parameters adjusted to generate an ink with a capability to form a gel having the required physical characteristics, and that is in a liquid form in the presence of a small quantity of non reactive solvent, or is brought to a liquid state during the printing process. The disclosure is also directed to a flexographic printing process with wet on wet capability based on controlled polymer or polymer segment precipitation that leads to gel formation of ink compounds by controlling the solubility parameter of the ink system.

Abstract: The invention relates to a two-component or multicomponent system for producing a dental material, to the use of the system for producing a dental material.

Abstract: The present invention provides: an ink composition which contains at least a polymerizable compound, a photopolymerization initiator and a coloring material, and is free from an aqueous solvent, wherein the polymerizable compound comprises at least a urethane oligomer; a two-pack curing ink composition set comprising an ink composition containing a coloring material and a reaction liquid containing a photopolymerization initiator and capable of forming an image with an ink composition obtained by mixing the ink composition and the reaction liquid, wherein the ink composition after mixing contains at least a polymerizable compound, a photopolymerization initiator and a coloring material, and is free from an aqueous solvent, wherein the polymerizable compound comprises a urethane oligomer.

Abstract: A lightfast green radiation curable ink including at least one curable monomer, at least one organic gellant, at least one photoinitiator and at least one colorant, where the colorant exhibits a reflectance on a substrate at a loading of from about 2 mg/inch2 to about 7 mg/inch2 that ranges from 50% to about 60% at a wavelength of 500 nm and that ranges from 0% to about 10% at a wavelength of about 600 nm which substantially matches Pantone green.

Abstract: A light-magenta radiation-curable gel ink including at least one curable monomer, at least one organic gellant, at least one photoinitiator, and a colorant. The colorant includes a magenta colorant, a hue-adjusting colorant that absorbs light having a wavelength of from about 400 to about 500 nm, and an optional shade-adjusting colorant that absorbs light having a wavelength of from about 600 to about 700 nm.

Abstract: Oxidation resistant crosslinked ultrahigh molecular weight polyethylene (UHMWPE) is described, wherein at least two different additives in the manufacture synergistically increase the oxidation resistance of crosslinked UHMWPE. This allows the manufacture of oxidation resistant crosslinked UHMWPE using lower levels of additives and/or lower levels of crosslinking irradiation or chemicals. The lower levels of additives and/or crosslinking produce crosslinked UHMWPE having desired physical properties not possible without the synergistic interaction of the additives. This crosslinked UHMWPE may be used in medical prostheses such as in bearing components having desired physical properties such as wear resistance and oxidation resistance not possible without the synergistic interaction of the additives.

Abstract: Release agents with increased affinity toward nano-imprint lithography template surfaces interact strongly with the template during separation of the template from the solidified resist in a nano-imprint lithography process. The strong interaction between the surfactant and the template surface reduces the amount of surfactant pulled off the template surface during separation of a patterned layer from the template in an imprint lithography cycle. Maintaining more surfactant associated with the surface of the template after the separation of the patterned layer from the template may reduce the amount of surfactant needed in a liquid resist to achieve suitable release of the solidified resist from the template during an imprint lithography process. Strong association of the release agent with the surface of the template facilitates the formation of ultra-thin residual layers and dense fine features in nano-imprint lithography.

Abstract: Embodiments in accordance with the present invention are directed to polymer compositions that are useful for forming temporary bonding layers that serve to releasably join a first substrate to a second substrate as well as methods of both forming such a temporary bond and methods of debonding such substrates. Some such polymer compositions encompass a casting solvent, a photoacid generator and optionally a sensitizer and/or an adhesion promoter.

Abstract: A method increases the toughness of a material obtained by curing a composition that includes at least one vinyl ester monomer. The method includes the incorporation into the composition of a sulfonated polyaromatic thermoplastic polymer, which is achieved by dissolving the vinyl ester monomer and the thermoplastic polymer in a reactive diluent in which they are both soluble. The resulting curable composition includes at least one vinyl ester monomer, and very high toughness materials can be made from it. A curable composition can include at least one vinyl ester monomer, a sulfonated polyaromatic thermoplastic polymer and a N-vinyl lactam. The compositions can be used in the aeronautical, space, railway, nautical, automotive industries, arms and other industries.

Abstract: Disclosed is a photosensitive resin composition for a color filter that includes (A) an organic salt-type sulfonate-containing dye; (B) a pigment; (C) an acrylic-based binder resin; (D) a photopolymerizable monomer; (E) a photopolymerization initiator; and (F) a solvent.

Abstract: Disclosed is a high energy ray-curable composition which is excellent in storage stability before curing and enables to form a cured coating film which is excellent in hardness, property of preventing adhesion of fats and oils, property of wiping off fats and oils, abrasion resistance, transparency, water repellency, adhesion, smoothness and uniformity. Specifically disclosed is a high energy ray-curable composition containing the following components (A)-(D). (A) 100 parts by weight of a polyfunctional acrylate (B) 1-30 parts by weight of an organoalkoxysilane having an aliphatic unsaturated bond (C) 1-100 parts by weight of colloidal silica (D) 0.2-20 parts by weight of a fluorine compound having an aliphatic unsaturated bond.

Abstract: A dental adhesive composition comprising (i) at least one non-acidic polymerizable monomer having at least one ethylenically unsaturated group, (ii) optionally one or more acidic compounds, (iii) at least one photoinitiator, (iv) at least one solvent, and (v) about 0-40% by weight of one or more fillers; wherein the weight ratio of non-acidic polymerizable monomers/acidic compounds in the adhesive composition is more than about 4.5; the viscosity of the adhesive composition is less than about 350 centipoise (cP) at 25° C.; and the adhesive composition excluding solvent and filler has an acid number of less than about 0.75 mmol NaOH/g. The dental adhesive composition is used with a dental primer composition, which may be provided together in a kit.

Abstract: The present invention relates to compositions of cyanoacrylate monomer, a method of improving the viscosity and the curing speed with a single additive and a process of providing sterilized cyanoacrylate adhesive compositions for application in the medical field.