With Aldehyde Or Aldehyde Derivative Reactant, Condensate Or Solid Polymer Thereof Patents (Class 522/94)
  • Patent number: 9120265
    Abstract: A nanoimprint lithography method includes the following steps. First, a first sacrifice layer, a second sacrifice layer and a nanoimprint resist are formed on a substrate. The nanoimprint resist includes a hyperbranched polyurethane oligomer, a perfluoropolyether; a methylmethacrylate, and a diluent solvent. Second, a master stamp with a first nanopattern formed by a number of projecting portions and gaps is provided, and the first nanopattern is pressed into the nanoimprint resist to form a second nanopattern in the nanoimprint resist. Third, the second nanopattern is transferred to the substrate.
    Type: Grant
    Filed: November 28, 2012
    Date of Patent: September 1, 2015
    Assignees: Tsinghua University, HON HAI PRECISION INDUSTRY CO., LTD.
    Inventors: Zhen-Dong Zhu, Qun-Qing Li, Li-Hui Zhang, Mo Chen
  • Patent number: 8431673
    Abstract: The present invention relates to composition comprising at least one compound obtained from the reaction of at least one compound (i) having a refractive index nD20 of at least 1.50 comprising at least one isocyanate-reactable functional group —XH, wherein each of X is, independently, O or NR, at least one polyisocyanate (ii), and, optionally, at least one compound (iii) comprising at least one isocyanate-reactable functional group —YH and at least one curable functional group Q, wherein each of Y is, independently, O, NR or S, and its use for making high refractive index coatings and films.
    Type: Grant
    Filed: November 7, 2008
    Date of Patent: April 30, 2013
    Assignee: Cytec Surface Specialties S.A.
    Inventors: Zhikai Jeffrey Wang, Christopher Wayne Miller, Marcus Lee Hutchins, James C. Matayabas, Jr.
  • Patent number: 7199166
    Abstract: Radiation-curable resins containing a carbonyl-hydrogenated ketone-aldehyde and/or a ring-hydrogenated phenyl-aldehyde resins, and a process for preparing them.
    Type: Grant
    Filed: August 17, 2004
    Date of Patent: April 3, 2007
    Assignee: Degussa AG
    Inventors: Patrick Gloeckner, Lutz Mindach, Peter Denkinger
  • Patent number: 6916854
    Abstract: The invention relates to a compound containing at least one unsaturated, radically or cationically polymerizable group and at least one carbamate terminal group or urea terminal group.
    Type: Grant
    Filed: March 20, 2002
    Date of Patent: July 12, 2005
    Assignee: BASF Aktiengesellschaft
    Inventors: Reinhold Schwalm, Uwe Meisenburg
  • Patent number: 6730733
    Abstract: Aqueous polymer composition suitable for coating which comprises the following components dispersed in water: (1) a combination of an acrylic polymer(s) A and an acrylic polymer(s) B where polymer(s) A has a Tg of not more than 30° C. and polymer(s) B has a Tg of at least 35° C., more preferably at least 45° C., which is at least 25° C. higher than the Tg of polymer(s) A, and wherein one or both of polymers A and B bear crosslinker functional groups capable of imparting ambient-temperature crosslinkability to component (1) in a coating formed from the composition via the formation of non-radically-formed covalent bonds; and (2) a self-dispersible, ionically stabilised polymer having olefinically unsaturated bond functionality capable of imparting radiation-curability (preferably uv-radiation curability) thereto in a coating formed from the composition.
    Type: Grant
    Filed: August 28, 2002
    Date of Patent: May 4, 2004
    Assignee: Avecia Limited
    Inventors: Gerardus Cornelis Overbeek, Pablo Steenwinkel, Ronald Tennebroek, Tijs Nabuurs
  • Patent number: 6190834
    Abstract: The present invention provides a photosensitive resin composition capable of forming an insulating film, which is superior in both a roughening property and an adhesiveness, and a via-hole, which is highly reliable in connection, and a multilayer printed circuit board. The present invention provides a photosensitive resin composition containing a first resin, which is an epoxy resin, and a second resin having a N-substituted carbamic acid ester atomic group and a radical polymeric unsaturated bond in its side chain. The second resin is desirably an oligomer having a repeating unit expressed by the following general formula (chem. 1) or (chem. 3) by 3-10 units. Where, X is H or CH3, Y and Z is H or an alkyl group of carbon number 1-4, n is 0 or 1, a part of R1 is an atomic group expressed by the following general formula (chem. 2), the residual R1 is a hydroxyl group, and R2 is an alkylene group of carbon number 1-4.
    Type: Grant
    Filed: May 6, 1998
    Date of Patent: February 20, 2001
    Assignees: Hitachi, Ltd., Hitachi Chemical Company, Ltd.
    Inventors: Masatoshi Narahara, Mineo Kawamoto, Tokihito Suwa, Masao Suzuki, Satoru Amou, Akio Takahashi, Hiroyuki Fukai, Mitsuo Yokota, Shiro Kobayashi, Masashi Miyazaki
  • Patent number: 6187893
    Abstract: Two-component polyurethane systems composed of an at least bifunctional polyisocyanate component and a polyol component have a polyol component which comprises at least one hydroxyl-containing cyclic acetal and/or ketal.
    Type: Grant
    Filed: October 6, 1998
    Date of Patent: February 13, 2001
    Assignee: BASF Aktiengesellschaft
    Inventors: Bernd Bruchmann, Heinz-Dieter Lutter, Hans Renz, Dietrich Scherzer, Günter Mohrhardt
  • Patent number: 5976000
    Abstract: A hard polishing pad with a porous surface for use in chemical-mechanical planarization of semiconductor wafers. The polishing pad has a body with a planarizing surface upon which a slurry may be deposited, and a plurality of particles are suspended in the body. The body is made from a continuous phase matrix material, and the particles are made from a substantially incompressible material that is soluble in the slurry. As a wafer is planarized, the particles at the planarizing surface of the polishing pad dissolve in the slurry and create pores in the pad. Also, because the particles are substantially incompressible, they reinforce the pad to provide a hard, substantially incompressible pad.
    Type: Grant
    Filed: January 13, 1999
    Date of Patent: November 2, 1999
    Assignee: Micron Technology, Inc.
    Inventor: Guy F. Hudson
  • Patent number: 5688633
    Abstract: A photosensitive resin composition includes a urethane oligomer prepared from a hydroxy-functionalized acrylate and/or methacrylate, at least one diol, and 2,4-toluene diisocyanate and 2,6-toluene diisocyanate in a 65:35 weight ratio. The resin composition additionally contains a monomer having at least one acrylate or methacrylate group, and a photoreactive initiator. The photosensitive resin composition may be cured to provide a soft photopolymer printing plate, particularly well suited for printing on corrugated bard.
    Type: Grant
    Filed: September 6, 1996
    Date of Patent: November 18, 1997
    Assignee: MacDermid Imaging Technology, Inc.
    Inventor: Douglas R. Leach
  • Patent number: 5451616
    Abstract: A liquid composition which on exposure to actinic radiation polymerizes to form a heat-curable solid film adhesive, said composition comprising (A) a heat-curable phenol-aldehyde resol resin, (B) a photopolymerizable polyurethane or polyester having, on average, more than one polymerizable acrylic group per molecule, or a mixture of said polyurethane and said polyester, (C) a photopolymerization initiator for (B) and (D) a polyvinylacetal.
    Type: Grant
    Filed: August 2, 1994
    Date of Patent: September 19, 1995
    Assignee: Ciba-Geigy Corporation
    Inventors: Margaret R. Haddon, Terence J. Smith, Stuart Mansfield
  • Patent number: 5449704
    Abstract: A liquid composition which on exposure to actinic radiation polymerises to form a heat-curable solid film adhesive, said composition comprising (A) a heat-curable phenol-aldehyde resol resin, (B) a photopolymerisable resin having, on average, more than one polymerisable acrylic group per molecule, (C) a photopolymerisation initiator for (B) and (D) an aminotriazine-formaldehyde resin.
    Type: Grant
    Filed: December 14, 1993
    Date of Patent: September 12, 1995
    Assignee: Ciba-Geigy Corporation
    Inventors: Stuart J. Thompson, Stuart Mansfield
  • Patent number: 5318998
    Abstract: An adhesive composition comprising a first liquid containing (A) an acrylic compound selected from the group consisting of (meth)acrylic acids and esters thereof, and (B) a polymerization initiator selected from the group consisting of peroxy esters and hydroperoxides, and a second liquid containing (C) a condensation product of an amine and an aldehyde, and (D) a copper salt, wherein an acid phosphate compound of the following formula (I): ##STR1## wherein R is an alkyl group, an alkoxyalkyl group or a CH.sub.2 .dbd.CR.sub.1 --CO(OR.sub.2).sub.m -- group, wherein R.sub.1 is H or CH.sub.3, R.sub.2 is --C.sub.2 H.sub.4 --, --C.sub.3 H.sub.6 --, ##STR2## --C.sub.4 H.sub.8 --, --C.sub.6 H.sub.12 -- or ##STR3## and m is an integer of from 1 to 10; and n is 1 or 2, is contained in the first liquid or in both the first and second liquids.
    Type: Grant
    Filed: September 10, 1990
    Date of Patent: June 7, 1994
    Assignee: Denki Kagaku Kogyo Kabushiki Kaisha
    Inventors: Kohichi Taguchi, Hiroshi Suto
  • Patent number: 5153102
    Abstract: An alkaline-solution-developable liquid image-producing composition useful as a permanent protective layer for printed circuit boards is disclosed comprising at least: (1) an acrylic copolymer with hyroxy group, carboxyl group and branched unsaturated carbon double bond. Its number average molecular weight is 3,000 to 10,000 and its acid value is at least 30 mg KOH/g; (2) a photo reactive monomer with hydroxy group, the number of the unsaturated carbon double bond functional groups should be not less than 2; (3) a melamine compound; and (4) a free radical photo initiator.
    Type: Grant
    Filed: August 10, 1990
    Date of Patent: October 6, 1992
    Assignee: Industrial Technology Research Institute
    Inventors: Rong-Jer Lee, Chein-Dhau Lee, Wen-Shin Shen, Dhei-Jhai Lin
  • Patent number: 5015709
    Abstract: The invention provides a radiation-curable liquid resin for use as a secondary coating of lightwave guides which is a reaction product of (meth)acrylic acid or -acid chloride or isocyanatoalkyl-(meth)acrylate with a 1:2 addition compound of a diepoxide with a mean molecular weight.ltoreq.1000 and a short-chain .alpha.,.omega. -diol with a mean molecular weight.ltoreq.700 or with a 1:2 addition compound of a diepoxide with a mean molecular weight.ltoreq.400 and a monovalent aliphatic alcohol with a mean molecular weight.ltoreq.200, where the diepoxide is an aliphatic-aromatic or aromatic diglycidylether, an aliphatic or cycloaliphatic diepoxide or a silicon-organodiepoxide, and where the short-chain .alpha.,.omega. -diol is an .alpha..omega. -hydroxy-terminated polyoxyalkylene, an .alpha.,.omega. -hydroxy-terminated polyester, an .alpha.,.omega. -hydroxy-terminated polybutadiene, an .alpha.,.omega. -hydroxyterminated organo-functional polysiloxane or an .alpha.,.omega. -alkanediol with a mean molecular weight.
    Type: Grant
    Filed: December 19, 1988
    Date of Patent: May 14, 1991
    Assignee: Siemens Aktiengesellschaft
    Inventors: Siegfried Birkle, Hans-Dieter Feucht, Rainer Kamps, Eva Rissel
  • Patent number: 4971892
    Abstract: A high speed visible light sensitive photopolymerizable composition useful for printing plates comprising(a) at least one free radically polymerizable monomer having at least one ethylenically unsaturated group,(b) an ethylenically unsaturated free radically polymerizable oligomer having carboxyl groups substituted thereon,(c) a visible light sensitizing initiator system for free radical polymerization comprising an initiator selected from diaryl iodonium salts, halogenated triazines, and triaryl iodonium salts which are photoinitiating electron acceptor compounds having a reduction potential in the range 0.0 to -1.5 eV, spectrally sensititzed with at least one merocyanine sensitizer containing a constrained alkylamino group, preferably a julolidinyl group.
    Type: Grant
    Filed: October 26, 1989
    Date of Patent: November 20, 1990
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Mohammad Z. Ali, Stanley C. Busman
  • Patent number: 4843111
    Abstract: Disclosed herein are novel diesters of (meth)acrylic acid represented by the following formula: ##STR1## wherein the mean values of m and n are respectively 0 to 5, preferably 0 to 3, the mean value of m+n is 1 to 10, preferably 1 to 6, and R represents H or CH.sub.3.Also, disclosed herein are resin compositions comprising said diester(s) of (meth)acrylic acid, polyurethane (meth)acrylate(s), monoethylenically unsaturated monomer(s) and initiator(s) of photopolymerization as an optional component.
    Type: Grant
    Filed: January 21, 1987
    Date of Patent: June 27, 1989
    Assignee: Nippon Kayaku Kabushiki Kaisha
    Inventors: Minoru Yokoshima, Tetsuo Ohkubo, Hideaki Hattori, Masayuki Kiyomoto
  • Patent number: 4710445
    Abstract: Photopolymerizable compositions containing thermally-softenable, developer resistive polymeric binders are particularly useful in image transfer systems and processes.
    Type: Grant
    Filed: April 22, 1986
    Date of Patent: December 1, 1987
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: James F. Sanders
  • Patent number: 4659788
    Abstract: A radiation curable adhesive composition comprising a liquid oligomer, a chain transfer agent, and an N-methyl compound can give a surface protective film which is slightly influenced in adhesive strength with the lapse of time, and excellent in weather resistance and heat resistance.
    Type: Grant
    Filed: April 1, 1985
    Date of Patent: April 21, 1987
    Assignee: Hitachi Chemical Co., Ltd.
    Inventors: Tomohisa Ohta, Akihiko Dobashi, Hisashige Kanbara, Yasuyuki Seki
  • Patent number: 4634602
    Abstract: Compositions of the invention comprise a radiation sensitive compound having ethylenic unsaturation and at least one moiety selected from the group consisting of a urea moiety, a urethane moiety and mixtures thereof, a radiation insensitive compound having a number average molecular weight of at least about 400 comprising at least about 40 percent, by weight, based on the weight of the radiation insensitive compound, of aromatic ring moieties and having a hydroxyl equivalent weight of between about 200 and 1500 and a crosslinking agent reactive with the hydroxyl groups present in said radiation insensitive compound, said crosslinking agent being selected from the group consisting of an aminoplast resin, a blocked isocyanate and mixtures thereof. The composition is capable of being cured using heat and either ultraviolet light or ionizing radiation. A process for applying and curing the composition of the invention on a substrate is also disclosed.
    Type: Grant
    Filed: January 2, 1986
    Date of Patent: January 6, 1987
    Assignee: PPG Industries, Inc.
    Inventors: Robert J. Sirkoch, Kenneth W. Niederst
  • Patent number: 4576975
    Abstract: Michler's ketone analogs and salts thereof, which are photosensitizers in water-soluble photoinitiator systems used to induce polymerization in free-radically-curable, ethylenically-unsaturated materials, are disclosed. The Michler's ketone analogs have the formula: ##STR1## wherein each R is an alkyl group of 1 to 8 carbon atoms,R.sup.1 is an alkylene group having 1 to 8 carbon atoms,Z is R.sup.1 COOH or R.sup.1 H, andn is an integer having a value of 1 or 2.The photoinitiator systems are useful in imaging systems, and additionally contain a free radical initiator compound selected from iodonium salts, biimidazoles, trialkylphosphites, alkyl peroxides, benzyl halides, alkyl nitrates, and the benzophenones other than (a).
    Type: Grant
    Filed: December 18, 1984
    Date of Patent: March 18, 1986
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Laurence W. Reilly, Jr.