Abstract: Various embodiments disclosed relate to silane-based tackifiers for treatment of subterranean formations. In various embodiments, the present invention provides a method of treating a subterranean formation. The method includes placing in the subterranean formation a tackifier having the structure: or a salt thereof, wherein the variables are as defined herein.

Abstract: Curable adhesive compositions comprising a silane coupling agent; a polymer, the polymer having a reactive silicon end group; a catalyst operable to facilitate the curing of the polymer; and, a diluent and wherein the polymer comprises about 0.1% to about 30% by weight of the curable adhesive composition. The curable adhesive compositions may further comprise a dehydrating agent comprising a component selected from the group consisting of: vinyl trimethoxysilane, vinyl alkoxysilane, inorganic zeolites, and organic zeolites.

Abstract: Curable adhesive compositions comprising a silane coupling agent; a polymer, the polymer having a reactive silicon end group; a catalyst operable to facilitate the curing of the polymer; and, a diluent and wherein the polymer comprises about 0.1% to about 30% by weight of the curable adhesive composition. The curable adhesive compositions may further comprise a dehydrating agent comprising a component selected from the group consisting of: vinyl trimethoxysilane, vinyl alkoxysilane, inorganic zeolites, and organic zeolites.

Abstract: Method of treating a subterranean formation comprising providing a consolidation fluid, introducing the resin consolidation fluid into a subterranean formation comprising unconsolidated particulates; and, curing the resin to at least partially consolidate the unconsolidated particulates. The consolidation fluid comprises a resin in emulsified form with an aqueous external phase and an organic internal phase wherein the emulsified resin does not comprise a hardening agent and an aqueous base fluid that further comprises a hardening agent. The consolidation fluid may further comprise an emulsifying agent.

Abstract: The invention discloses a method of creating a polymerized composition in a well bore: providing a polymerizable composition made of a polymerization initiator and a monomer polymerizable by frontal polymerization; introducing the polymerizable composition into the wellbore; exposing the polymerizable composition to a trigger to activate the frontal polymerization; and creating the polymerized composition.

Abstract: A method of servicing a wellbore comprising placing a sealant composition comprising solid latex into the wellbore.

Abstract: Compositions comprising (1) a refractory and/or a binder, and (2) bis-cyclopentadienyl iron cyclopentadienyl manganese tricarbonyl, derivatives thereof, and mixtures thereof.

Abstract: A gravel packing system, method and slurry. The system comprises a blending device to prepare a slurry comprising a carrier fluid suspending first, second and third particulates, wherein the carrier fluid comprises a brine and less than about 2.4 g/L (20 lb per 1000 gallons) of a viscosifier, and wherein the sum of the mass of the particulates is greater than about 2.4 kg/L (20 pounds per gallon), wherein the first average particle volume is between 27 and 3375 times larger than the second average particle volume, which in turn is between 27 and 3375 times larger than the third average particle volume. The system can also include tubing to position a screen in the wellbore and a slurry pump to circulate the slurry from the blending device in the wellbore in any order such that the particulates are deposited in the screen annulus to form a gravel pack.

Abstract: A method of stabilising a blasthole prior to detonation which comprises the step of coating the inner wall of the blasthole with a stabilising composition. In one embodiment, the invention comprises coating the blast hole by means of a movable spraying application. The invention further relates to the use of a silicate-containing resin but is also suitable for use with a thermoset resin system. The method can be used to apply the stabilising composition to both dry and wet blastholes.

Abstract: The invention discloses a method of controlling fluid loss from a subterranean formation of a well bore. In a first aspect, the method is done by providing a treatment fluid made of an aqueous fluid and a hydrophobic polymer; and introducing the treatment fluid into the wellbore. In a second aspect, the method is done by providing a treatment fluid made of water and a water soluble polymer; providing in the treatment fluid a fluid loss additive having a hydrophobic polymer; using the treatment fluid in a well bore of a subterranean formation; allowing the treatment fluid to establish a permeable filter cake with the water soluble polymer in at least a portion of the well bore; and allowing hydrophobic polymer to enter into the filter cake to reduce permeability of the filter cake.

Abstract: A method is disclosed where introducing into a wellbore a degradable material stabilized in a non-aqueous based fluid.

Abstract: A process for the preparation of a binder comprising a heterocondensate of (i) a hydrolysable silicon compound having at least one nonhydrolysable organic radical without polymerizable group and (ii) a metal and/or boron compound. The process comprises hydrolyzing (i) with water, adding (ii) to the resultant reaction mixture after the water in the reaction mixture is substantially consumed, and, optionally, adding an organic binder component to the heterocondensate and/or a precursor thereof.

Abstract: A gravel packing system, method and slurry. The system comprises a blending device to prepare a slurry comprising a carrier fluid suspending first, second and third particulates, wherein the carrier fluid comprises a brine and less than about 2.4 g/L (20 lb per 1000 gallons) of a viscosifier, and wherein the sum of the mass of the particulates is greater than about 2.4 kg/L (20 pounds per gallon), wherein the first average particle volume is between 27 and 3375 times larger than the second average particle volume, which in turn is between 27 and 3375 times larger than the third average particle volume. The system can also include tubing to position a screen in the wellbore and a slurry pump to circulate the slurry from the blending device in the wellbore in any order such that the particulates are deposited in the screen annulus to form a gravel pack.

Abstract: A method includes providing a wellbore treatment fluid having a divalent brine and an amount of polymer and lowering a pH value of the treatment fluid. The method further includes retaining the treatment fluid at the lower pH value until the polymer achieves a primary hydration value. The method further includes adding a cross-linking agent and a cross-linking delay agent to the treatment fluid. The cross-linking agent includes zirconium and/or titanium, and the cross-linking delay agent is a polyol. The method further includes performing a wellbore treatment with the treatment fluid.

Abstract: The invention relates to a copolymer including betaininc units and hydrophobic and/or amphiphile units. The invention also relates to a method for preparing a copolymer including betaininc units and hydrophobic and/or amphiphile units, by controlled micellar polymerisation. The invention further relates to the uses of the copolymer. The copolymer is particularly used for increasing the viscosity of saline aqueous compositions.

Abstract: Disclosed herein are free flowing coated particles and low temperature methods of making same. Each particle has a curable coating disposed upon a substrate. The substrate is a particulate substrate including an inorganic material, a particulate substrate including an organic material, a composite substantially homogeneous formed particle including a first portion of an at least partly cured binder and filler particles, or a hybrid particle having an inorganic particle as a core and a composite coating including at least partially cured resin and filler. The curable coating includes a continuous phase including a curable liquid resin and reactive powder particles embedded or adhered to the continuous phase. The reactive powder particles typically include one or more of a resole phenolic-formaldehyde resin, a novolak phenolic-formaldehyde resin, a polyester resin, an acrylic polymer resin, a urethane resin or an epoxy resin.

Abstract: The invention provides a method for treating a subterranean formation penetrated by a wellbore. The method comprises the steps of: (a) introducing a composition through the wellbore into the subterranean formation, wherein the composition comprises: (i) a solvent consisting essentially of an aqueous dissolvable solvent comprising any solvent that is at least 25% by weight soluble in water, wherein the solvent is from about 90% to about 99.9% by weight of the composition; and (ii) a curable resin, wherein the curable resin is from about 0.01% to about 10% by weight of the composition; wherein the curable resin and the solvent are mutually selected such that, for the ratio of the curable resin to the solvent, the curable resin is soluble in the solvent; and (b) installing a mechanical sand control device into the wellbore either before or after introducing the composition into the wellbore.

Abstract: Methods and compositions relating to delayed tackifying compositions that comprise an aqueous tackifying agent and a delayed acid-releasing activator that may be used to stabilize particulates and reduce particulate migration within a subterranean formation.

Abstract: Methods of controlling particulate migration in a portion of a subterranean formation comprising placing a pre-flush fluid into the portion of the subterranean formation; and then, placing a low-viscosity adhesive substance diluted with an aqueous dissolvable solvent into the portion of the subterranean formation; wherein the portion of a subterranean formation being treated has a regain permeability of at least about 70%. Methods of creating a stabilized region around a portion of a subterranean formation around a well bore having a screen or liner in place in that portion of the subterranean formation comprising placing a pre-flush fluid into the portion of the subterranean formation; and then, placing a low-viscosity adhesive substance diluted with an aqueous dissolvable solvent into that portion of the subterranean formation; wherein the portion of a subterranean formation being treated has regain permeability of at least about 70%.

Abstract: The present invention involves methods of preparing coated particulates and using such coated particulates in subterranean applications such as production enhancement and sand control. One embodiment of the present invention provides a method of preparing coated particulates comprising the steps of coating particulates with a resin or a tackifying agent to create pre-coated particulates; and, covering the pre-coated particulates with a partitioning agent to create coated particulates.

Abstract: A liner is the product of reaction of (a) a hydrophilic prepolymer bearing isocyanate groups; and (b) a water-borne polymer dispersion, the polymer bearing groups that are reactive to isocyanate groups; wherein the dispersion has a sufficiently high solids content, and the polymer has a sufficiently high modulus and glass transition or crystalline melting temperature, that the product of reaction exhibits a 24-hour Tensile Strength of at least about 2.5 MPa.

Abstract: Disclosed herein is a particle comprising a particulate substrate; and a thermoplastic elastomer present on or in the substrate as an amount sufficient to improve the dust suppression of the particle above that which would occur if the thermoplastic elastomer was absent. Disclosed herein is a particle comprising a particulate substrate; and a thermoplastic elastomer, wherein the particle has a compressive strength retention of greater than about 50% as measured by a UCS test and a turbidity of about 10 to 200 NTU after a one hour ball mill test.

Abstract: Improved methods and compositions for consolidating proppant in subterranean fractures are provided. In certain embodiments, the hardenable resin compositions may be especially suited for consolidating proppant in subterranean fractures having temperatures above about 200° F. Improved methods include providing proppant particles coated with a hardenable resin composition mixed with a gelled liquid fracturing fluid, and introducing the fracturing fluid into a subterranean zone. The fracturing fluid may form one or more fractures in the subterranean zone and deposit the proppant particles coated with the resin composition therein. Thereafter, the hardenable resin composition on the proppant particles is allowed to harden by heat and to consolidate the proppant particles into degradation resistant permeable packs. The hardenable resin composition may include a liquid bisphenol A-epichlorohydrin resin, a 4,4?-diaminodiphenyl sulfone hardening agent, a solvent, a silane coupling agent, and a surfactant.

Abstract: Coated particle substrates having a coating of resin and/or water soluble polymers and soluble, fibrous material are provided for use in subterranean formations. The coated particle substrate particles are typically proppants used to prop open subterranean hydrocarbon formations during recovery processes, such as after a hydraulic fracture, and provide both improved settling characteristics and improved hydrocarbon flow characteristics due to the conductive channels formed by the soluble fibers downhole. Methods of making the coated particles are also described.

Abstract: Storable water-silica suspensions and methods of cementing well bores are provided. The storable water-silica suspensions are basically comprised of water, silica and an effective amount of a suspending agent selected from the group consisting of colloidal materials, clays and gel forming polymers.

Abstract: Method of treating a portion of a subterranean formation comprising: placing a pre-pad fluid into a portion of a subterranean formation wherein the pre-pad fluid comprises a low-viscosity aqueous tackifying composition that comprises an aqueous tackifier compound and an aqueous fluid; placing a fracturing fluid into the portion of the subterranean formation at a pressure sufficient to create or extend at least one fracture therein; and, activating the aqueous tackifier compound with an activator so as to consolidate the unconsolidated particulates.

Abstract: The present invention relates to aqueous based tackifier fluids and their use in stabilizing particulates in propped fractures. Some embodiments of the present invention provide methods of creating a proppant pack in a subterranean formation, comprising introducing an aqueous servicing fluid comprising proppant particulates, wherein at least some of the proppant particulates are at least partially coated with an aqueous tackifier compound, into a subterranean fracture; and, activating the aqueous tackifier compound so as to form a proppant pack. Other embodiments provide methods of stabilizing a proppant pack comprising introducing an aqueous tackifier compound to at least a portion of an existing proppant pack; and, activating the aqueous tackifier compound so as to stabilize the proppant pack. Other embodiments provide servicing fluids comprising proppant particulates and an aqueous fluid wherein at least some of the proppant particulates are at least partially coated with an aqueous tackifier compound.

Abstract: The present invention relates to enhancing fluid flow from subterranean formations. More particularly, this invention relates to providing improved proppant matrixes within fractures in a subterranean formation. An example of the methods of increasing the conductivity of a fracture in a subterranean formation comprises the steps of providing a fracturing treatment fluid comprising a proppant composition, the proppant composition comprising proppant particulates and a degradable material capable of undergoing an irreversible degradation downhole; introducing the proppant composition to the fracture; and allowing the proppant composition to form a proppant matrix having voids in the fracture.

Abstract: Improved methods and compositions for consolidating proppant in fractures formed in subterranean zones are provided. An improvement of this invention comprises using proppant particles having a coating of hardenable resin including a gel breaker. The gel breaker facilitates removal of gelled carrier fluid from the surface of the proppant particles.

Abstract: The present invention relates to improved methods for completing well bores along producing zones and, more particularly, to methods for strengthening near well bore subterranean formations. Some embodiments of the present invention provide a method of strengthening the near well bore region of a subterranean formation comprising the steps of isolating a zone of interest along a well bore; either hydrajetting a slot in the zone of interest or acidizing the zone of interest to create wormholes; filling the slot or wormholes with a consolidation material wherein the viscosity of the consolidation material is sufficient to enable the consolidation material to penetrate a distance into the formation; and, allowing the consolidation material to substantially cure.

Abstract: A liner is the product of reaction of (a) a hydrophilic prepolymer bearing isocyanate groups; and (b) a water-borne polymer dispersion, the polymer bearing groups that are reactive to isocyanate groups; wherein the dispersion has a sufficiently high solids content, and the polymer has a sufficiently high modulus and glass transition or crystalline melting temperature, that the product of reaction exhibits a 24-hour Tensile Strength of at least about 2.5 MPa.

Abstract: The present invention relates to increasing the permeability of a subterranean formation by forming a resinous mass having conductive channels through which fluids can be produced in the formation. Some embodiments of the present invention provide methods of creating a permeable resinous mass comprising the steps of selecting an interval along a well bore; providing a resin slurry comprising an acid curable resin, filler, and degradable material; placing the resin slurry into the selected interval; and, activating the acid curable resin using an activator wherein the activation causes the acid curable resin to substantially cure, the degradable material to substantially degrade, and forms the permeable resinous mass.

Abstract: The present invention provides methods of reducing the production of both water and particulates from subterranean formations; the methods are particularly useful in conjunction with subterranean formations surrounding wellbores and fractures. The methods comprise the steps of applying to a subterranean formation a pre-flush fluid, applying aqueous surfactant fluid, applying a low-viscosity consolidating fluid, and applying an after-flush fluid.

Abstract: The present invention described a resin composition comprising from about 5% to about 30% phenol, from about 40% to about 70% phenol formaldehyde, from about 10% to about 40% furfuryl alcohol, from about 0.1% to about 3% of a silane coupling agent, and from about 1% to about 15% of a surfactant and methods of using of that resin in consolidating subterranean formation fines.

Abstract: The present invention provides methods of reducing the production of both water and particulates from subterranean formations; the methods are particularly useful in conjunction with subterranean formations surrounding wellbores and fractures. The methods comprise the steps of applying to a subterranean formation a pre-flush fluid, applying aqueous surfactant fluid, applying a low-viscosity consolidating fluid, and applying an after-flush fluid.

Abstract: Improved methods and compositions for consolidating proppant in subterranean fractures are provided. In accordance with the methods of the invention, proppant particles coated with a hardenable bisphenol A-epichlorohydrin resin composition are mixed with a gelled liquid fracturing fluid and the fracturing fluid is pumped into a subterranean zone. The fracturing fluid forms one or more fractures in the subterranean zone and deposits the proppant particles coated with the resin composition therein. Thereafter, the hardenable resin composition on the proppant particles is allowed to harden by heat and consolidate the proppant particles into degradation resistant permeable packs. The hardenable bisphenol A-epichlorohydrin resin compositions of the invention are storable for long periods of time before use.

Abstract: Methods of reducing or preventing particulate flow-back in subterranean zones are provided. In accordance with the methods, a treating fluid having a mixture of reticulated foam fragments and particulate solids suspended therein is provided. The treating fluid is introduced into a subterranean zone and the mixture of the reticulated foam fragments and the particulate solids are deposited in the subterranean zone whereby the reticulated foam fragments retard or prevent the flow-back of the particulate solids and the transport of formation fines from the subterranean zone upon the flowing-back of fluid from the zone.

Abstract: The present invention provides methods of stabilizing subterranean formations and methods of reducing the production of particulates from subterranean formations, which are useful in conjunction with subterranean formations surrounding wellbores and fractures. The methods comprise the steps of applying to a subterranean formation a combination aqueous liquid and surfactant preflush solution, an integrated consolidation fluid and an afterflush fluid and then waiting a chosen period of time.

Abstract: The present invention relates to a cement slurry set in a wellbore. The slurry comprises cement, at least one mineral filler, water and a determined amount of at least one hydrophobically modified acrylamide or acrylate derivative. The present invention also relates to an additive specific to a cement slurry and acting as a filtrate reducer and as a rheological control agent, the additive comprising mainly a hydrophobically modified acrylamide or acrylate derivative.

Abstract: Improved methods of forming fractures containing resilient proppant particle packs which prevent the production of sand and fines with produced fluids and prevent proppant flow-back in a subterranean zone penetrated by a well bore are provided. As the fractures are formed, a liquid hardenable resin component is mixed with a liquid hardening agent component and a liquid rubber component to form a hardenable resin composition. The hardenable resin composition is coated onto dry proppant particles which are suspended in the fracturing fluid and placed in the fractures. The hardenable resin composition on the resin composition coated proppant particles is allowed to harden and consolidate the proppant particles into high strength resilient permeable packs.

Abstract: Methods of consolidating formations or forming chemical casing or both while drilling are provided. One method of the invention comprises drilling a well bore with a drilling fluid comprised of water, a polymeric cationic catalyst which is adsorbed on weak zones or formations formed of unconsolidated clays, shale, sand stone and the like, a water soluble or dispersible polymer which is cross-linked by a thermoset resin and causes the resin to be hard and tough when cured, a particulate curable solid thermoset resin, a water soluble thermoset resin, and a delayed dispersible acid catalyst for curing the solid and water soluble resins. The drilling fluid forms a filter cake on the walls of the well bore that cures and consolidates the unconsolidated weak zones and formations penetrated by the well bore so that sloughing is prevented and forms a hard and tough cross-linked chemical casing on the walls of the well bore.

Abstract: Methods of consolidating formations or forming chemical casing or both while drilling are provided. One method of the invention comprises drilling a well bore with a drilling fluid comprised of water, a polymeric cationic catalyst which is adsorbed on weak zones or formations formed of unconsolidated clays, shale, sand stone and the like, a water soluble or dispersible polymer which is cross-linked by a thermoset resin and causes the resin to be hard and tough when cured, a particulate curable solid thermoset resin, a water soluble thermoset resin, and a delayed dispersible acid catalyst for curing the solid and water soluble resins. The drilling fluid forms a filter cake on the walls of the well bore that cures and consolidates the unconsolidated weak zones and formations penetrated by the well bore so that sloughing is prevented and forms a hard and tough cross-linked chemical casing on the walls of the well bore.

Abstract: The use is described of polysulfide-free preparations comprising, based on solids content, from 40 to 99.5% by weight of at least one water-dispersible copolymer and from 0.5 to 10% by weight of at least one alkoxylated ionic or nonionic emulsifier, as additives for construction materials based on loam or clay. The building materials based on loam or clay and comprising the preparation are described, as are the use of the construction materials and a process for treating construction materials with the preparation.

Abstract: Composite particles made of a binder and filler material are provided for use in subterranean formations. The filler is finely divided mineral and optional fiber. The particles are proppants useful to prop open subterranean formation fractures. The particles are also useful for water filtration and artificial turf for sports fields. Methods of making the composite particles are also disclosed.

Abstract: Methods of forming permeable sand screens in long, open hole well bores within fluid producing zones are provided by the present invention. The methods basically comprise the steps of placing a perforated pipe in the open hole well bore, providing a hardenable composition which after being placed in a desired location cures into a hard mass, placing said hardenable composition in said well bore adjacent to said fluid producing zone within the interior of the perforated pipe therein, between the perforated pipe and the walls of the open hole well bore and within voids or fractures in the producing zone, causing the hardenable composition to cure into a hard permeable mass and drilling the hard permeable mass out of the interior of the perforated pipe.

Abstract: Compositions and method for resisting soil erosion. The compositions comprise either an aqueous mixture of a polymer mixed with an organic material or, alternatively, a polymer and organic material that can be mixed in water. The polymer preferably comprises polyacrylamide having anionic functional groups and the organic base comprises either cellulose, mulch and/or seed and mulch. The methods of the present invention comprise providing or forming an aqueous mixture of the compositions of the present invention and applying them to an area of land sought to be provided with soil erosion resistance.

Abstract: A method is provided for incorporating a foaming agent into mixtures of particulates and then forming a foam within the mixture to increase the flowability of the particulates. A method is also provided for excavating solid particulates, incorporating a foaming agent into mixtures of solid particulates, and then forming a foam within the mixture to increase the flowability of the particulates. The particulates can be transported through pipelines or boreholes. Examples of particulates include, but are not limited to, mine tailings, ores, sand, coal, soils, clays, silts, aggregates, and mixtures thereof.

Abstract: A water-soluble branched polyhydroxyetheramine, wherein the branched polyhydroxyetheramine is prepared by reacting an amine having two reactive hydrogen atoms with a diepoxide to form a polyhydroxyetheramine and then reacting the polyhydroxyetheramine with an N-alkylating agent, an aqueous composition comprising the branched polyhydroxyetheramine and use of the branched polyhydroxyetheramine to modify the permeability to water of a subterranean formation are disclosed.

Abstract: Fracturing fluid compositions and methods for their preparation and use are disclosed. The compositions are useful in the oil and gas drilling operations, as well as in gravel packing operations, water blocking, temporary plugging for purposes of wellbore isolation and/or fluid loss control, and other uses. The compositions comprise a liquid, a polymer soluble in the liquid, having a degree of substitution of ionic groups of about 0.01 to about 0.1; and a crosslinking agent capable of increasing the viscosity of the fracturing fluid by crosslinking the polymer in liquid.

Abstract: Coated particles made of particulate substrates having a coating of resin and fibrous material are provided for use in subterranean formations. The coated substrate particles are proppants useful to prop open subterranean formation fractures. The coated substrate particles are also useful for sand control, that is, acting as a filter or screen to prevent backwards flow of sand, other proppants or subterranean formation particles. Methods of making the coated particles are also disclosed.