With Removal Of A Phase Patents (Class 523/339)
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Patent number: 10516184Abstract: The present invention provides a device for removing gas trap in a spare battery cell generated in a formation process during a process of manufacturing the battery cell, wherein the device is a gas trap removing device for manufacturing a battery cell, including: a battery cell receiving unit into which the spare battery cell is received; and a vibration applying unit for applying vibration to the battery cell receiving unit, in a state where the spare battery cell is received into the battery cell receiving unit.Type: GrantFiled: May 19, 2016Date of Patent: December 24, 2019Assignee: LG Chem, Ltd.Inventor: Sungju Cho
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Patent number: 9966508Abstract: The addition of a chain transfer agent (CTA) or a reversible-addition fragmentation chain transfer agent (RAFT CTA) such as (2-(dodecyl-thiocarbonothioylthio)-2-methylpropionic acid) during the formation of quantum dot polymer films yields films characterized by high and stable quantum yields.Type: GrantFiled: March 4, 2015Date of Patent: May 8, 2018Assignee: Nanoco Technologies Ltd.Inventors: Cong-Duan Vo, Imad Naasani
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Patent number: 9108851Abstract: The present invention relates to a highly conductive carbon nanotube having bundle moieties with ultra low apparent density less than 0.01 g/cc. More specifically, this invention relates to a highly conductive carbon nanotube prepared by following preparation steps of i) preparing the sphere shape of metal catalyst by spray pyrolysis of catalytic metal precursor solution including low molecular weight polymer, ii) synthesizing carbon nanotube using carbon source and obtained metal catalyst according to thermal chemical vapor deposition method; and iii) obtaining a highly conductive carbon nanotube having bundle moieties with ultra-low bulk apparent density.Type: GrantFiled: February 12, 2013Date of Patent: August 18, 2015Assignee: KOREA KUMHO PETROCHEMICAL CO., LTD.Inventors: Dong Hwan Kim, Wan Sung Lee, Woo Ram Jung, Youngchan Jang
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Publication number: 20150025174Abstract: A process includes dissolving a polyester resin in an organic solvent to form a solution, the polyester resin has a latex-destabilizing cation, removing substantially all of the latex-destabilizing cation, neutralizing the solution of the polyester resin, adding a sufficient amount of water to the neutralized solution form an emulsion, and removing a portion of the organic solvent from the emulsion to form a latex of the polyester resin.Type: ApplicationFiled: July 18, 2013Publication date: January 22, 2015Inventors: Yulin Wang, Karen Moffat, John L. Pawlak, Kevin F. Marcell, Steven M. Malachowski
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Publication number: 20140370438Abstract: A phase inversion emulsification process includes dissolving a polyester resin in a mixture comprising (1) an organic solvent, (2) a first portion of a total amount of neutralizing agent, and (3) a first portion of water, neutralizing the dissolved polyester resin with a second portion of neutralizing agent, the second portion of neutralizing agent including the remaining amount of the total amount neutralizing agent, forming an emulsion by adding a second portion of water after the neutralizing step, and removing a portion of the organic solvent from the emulsion to provide a latex.Type: ApplicationFiled: June 17, 2013Publication date: December 18, 2014Inventors: Shigang Steven Qiu, Chieh-Min Cheng, Amy Grillo, Yulin Wang, Rashid Mahmood, David Kurceba
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Patent number: 8841406Abstract: Crosslinked polyimide-poly(alkylene oxide) copolymers capable of holding large volumes of liquid while maintaining good dimensional stability. Copolymers are derived at ambient temperatures from amine endcapped amic-acid oligomers subsequently imidized in solution at increased temperatures, followed by reaction with trifunctional compounds in the presence of various additives. Films of these copolymers hold over four times their weight at room temperature of liquids such as ionic liquids (RTIL) and/or carbonate solvents. These rod-coil polyimide copolymers are used to prepare polymeric electrolytes by adding to the copolymers various amounts of compounds such as ionic liquids (RTIL), lithium trifluoromethane-sulfonimide (LiTFSi) or other lithium salts, and alumina.Type: GrantFiled: December 22, 2008Date of Patent: September 23, 2014Assignee: The United States of America as Represented by the Administrator of National Aeronautics and Space AdministrationInventors: Maryann B. Meador, Dean M. Tigelaar
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Publication number: 20140142216Abstract: Methods herein include mixing at least one polyester resin with at least one solvent to form a resin mixture, adding water to cause phase inversion and form a polyester latex, adding at least one buffering agent to the phase inverted mixture to stabilize the phase inverted mixture, and subsequent to the buffering agent addition, substantially removing the at least one solvent from the phase inverted mixture.Type: ApplicationFiled: January 28, 2014Publication date: May 22, 2014Applicant: XEROX CORPORATIONInventors: Zhen LAI, Chieh-Min CHENG
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Patent number: 8329783Abstract: The present invention is toner particle that includes a continuous phase of binder polymer and a second phase of hydrocolloid. The particle has a porosity of at least 10 percent.Type: GrantFiled: December 7, 2010Date of Patent: December 11, 2012Assignee: Eastman Kodak CompanyInventors: Mridula Nair, Xiqiang Yang, Tamara K. Jones, Jason Morgan
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Patent number: 8222318Abstract: The present invention relates to (1) a process for producing a water dispersion for ink-jet printing containing colorant-containing polymer particles which includes a step I of obtaining a dispersion of colorant-containing polymer particles; a step II of obtaining a water dispersion of the colorant-containing polymer particles from the dispersion obtained in the step I; a step III of mixing the water dispersion obtained in the step II with an organic solvent (B) to suitably control a relative dielectric constant of a mixed solvent in the resultant dispersion, thereby precipitating the colorant-containing polymer particles; and a step IV of separating precipitates obtained in the step III from the dispersion and re-dispersing the precipitates in a water-based solvent; (2) a water-based ink for ink-jet printing which is excellent in ejection stability and optical density; (3) a process for purifying a water dispersion for ink-jet printing; and (4) a process for producing a dispersion containing groups of fine pType: GrantFiled: December 13, 2007Date of Patent: July 17, 2012Assignee: Kao CorporationInventors: Ryuma Mizushima, Nobuyuki Takizawa
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Patent number: 8178597Abstract: An aqueous inkjet recording ink including pigment particles coated with a water-insoluble resin, water, and a water-soluble organic solvent including at least one hydroxy group, wherein the water-insoluble resin has a salt-forming group and a structural unit which is derived from a methacrylate and has an aromatic ring linked via a linking group to an atom in the main chain of the water-insoluble resin, and the water-insoluble resin satisfies the condition that when the water-insoluble resin, an organic solvent, one equivalent of a neutralizing agent with respect to the salt-forming group, and water are mixed with a total content of the water-insoluble resin and the organic solvent being 35% by mass relative to the total mass of the mixture, an emulsion is formed without precipitation of the water-insoluble resin, and after the emulsion is allowed to stand for three hours, a transparent single phase is formed, or two separate phases are formed and at least an aqueous phase of the two phases is transparent.Type: GrantFiled: February 6, 2009Date of Patent: May 15, 2012Assignee: FUJIFILM CorporationInventors: Misato Sasada, Takafumi Hosokawa
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Patent number: 8110616Abstract: An aqueous inkjet recording ink including at least a resin (A), a pigment (B) dispersed with the resin (A), a resin emulsion (C), and an aqueous liquid medium (D), wherein the resin (A) includes hydrophobic structural units (a) and hydrophilic structural units (b), the hydrophobic structural units (a) include a hydrophobic structural unit (a1) in an amount of 40% by mass or more of the resin (A), the hydrophobic structural unit (a1) having an aromatic ring indirectly linked to an atom for forming the main chain of the resin (A), and a hydrophobic structural unit (a2) in an amount of 15% by mass or more of the resin (A), the hydrophobic structural unit (a2) being derived from a C1 to C4 alkyl acrylate or methacrylate, the hydrophilic structural units (b) include a structural unit (b1) derived from an acrylic acid or a methacrylic acid, and the content of the hydrophilic structural units (b) is 15% by mass or less in the resin (A).Type: GrantFiled: February 9, 2009Date of Patent: February 7, 2012Assignee: Fujifilm CorporationInventors: Misato Sasada, Takafumi Hosokawa, Takahiro Kato
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Patent number: 8030376Abstract: Disclosed herein are processes for dispersing a plurality of unaggregated particles, such as nanoparticles and microparticles, in a viscous medium. The dispersions can be used for making a variety of useful materials, such as carbon nanotube composites.Type: GrantFiled: July 12, 2007Date of Patent: October 4, 2011Assignee: MinusNine Technologies, Inc.Inventor: David W. Kurz
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Patent number: 7888410Abstract: The present invention is a method for the preparation of porous particles that includes dissolving a polymer material in a first organic solvent and adding a second organic solvent and nonionic organic polymer particles to form an organic phase. The organic phase is dispersed in an aqueous phase that includes a particulate stabilizer to form a dispersion and the dispersion is homogenized. The first and second organic solvents are evaporated and the product is recovered.Type: GrantFiled: April 24, 2007Date of Patent: February 15, 2011Assignee: Eastman Kodak CompanyInventors: Mridula Nair, Xiqiang Yang, Tamara K. Jones, James G. Popowych
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Patent number: 7867555Abstract: A method for coloring powders using a stable colorant dispersion is provided. The method includes mixing a base powder and a stable colorant dispersion. A colored powder composition baying a core particle and a partial shell about the core particle is provided.Type: GrantFiled: February 13, 2004Date of Patent: January 11, 2011Assignee: Valspar Sourcing Inc.Inventors: William G. O'Dell, Steven D. Johnson, Larry B. Brandenburger
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Patent number: 7745514Abstract: Disclosed are tinted, abrasion resistant coating compositions comprising polymer-enclosed color-imparting particles. Also disclosed are methods for making such a composition and substrates at least partially coated with a hard coat deposited from such a composition.Type: GrantFiled: December 7, 2006Date of Patent: June 29, 2010Assignee: PPG Industries Ohio, Inc.Inventors: Shan Cheng, Dennis L. Faler, W. David Polk
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Publication number: 20100152326Abstract: Disclosed herein are processes for dispersing a plurality of unaggregated particles, such as nanoparticles and microparticles, in a viscous medium. The dispersions can be used for making a variety of useful materials, such as carbon nanotube composites.Type: ApplicationFiled: July 12, 2007Publication date: June 17, 2010Applicant: MinusNine Technologies, Inc.Inventor: David W. Kurz
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Patent number: 7169528Abstract: A process for the preparation of colored polymeric toner particles includes: forming an organic phase by dissolving an organic polymer and, optionally, one or more additives in a water-immiscible organic solvent; forming a dispersion by combining the organic phase with an aqueous phase comprising a particulate stabilizer, a colorant, and, optionally, a promoter, with the proviso that when the colorant is carbon black, it is an acidic carbon black having a pH less than 7; homogenizing the dispersion to form droplets containing the organic solvent, organic polymer, and colorant; removing the organic solvent from the droplets to form colored polymeric toner particles; and separating and drying the toner particles.Type: GrantFiled: April 30, 2004Date of Patent: January 30, 2007Assignee: Eastman Kodak CompanyInventors: Hichang Yoon, Bret Martin Johnston, Dinesh Tyagi, Michael Thomas Regan
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Patent number: 6881820Abstract: This invention is a series of rod-coil block polyimide copolymers that are easy to fabricate into mechanically resilient films with acceptable ionic or protonic conductivity at a variety of temperatures. The copolymers consist of short-rigid polyimide rod segments alternating with polyether coil segments. The rods and coil segments can be linear, branched or mixtures of linear and branched segments. The highly incompatible rods and coil segments phase separate, providing nanoscale channels for ion conduction. The polyimide segments provide dimensional and mechanical stability and can be functionalized in a number of ways to provide specialized functions for a given application. These rod-coil black polyimide copolymers are particularly useful in the preparation of ion conductive membranes for use in the manufacture of fuel cells and lithium based polymer batteries.Type: GrantFiled: May 13, 2002Date of Patent: April 19, 2005Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space AdministrationInventors: Mary Ann B. Meador, James D. Kinder
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Publication number: 20040087713Abstract: A water based coating composition prepared by dispersing a heat-curable coating composition into water in the presence of a suspension stabilizer comprising a block copolymer to obtain a water dispersion, followed by optionally removing an organic solvent from the water dispersion to obtain a water based coating composition having a mean particle size of 0.Type: ApplicationFiled: April 3, 2003Publication date: May 6, 2004Inventors: Takeshi Fujii, Takashi Okubo, Hiroshi Igarashi, Takato Adachi, Tetsuo Ogawa
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Patent number: 6727341Abstract: A stable and high-solids aqueous dispersion of blocked isocyanates, containing auxiliary solvent, is prepared by (1) preparing a solution of a polyisocyanate mixture of from 20-70% by weight of a blocked, hydrophilically modified polyisocyanate (A) and from 30-80% by weight of a blocked, hydrophobic polyisocyanate (B) in an auxiliary solvent (G) and (2) adding water to this solution, with intensive mixing, in an amount which is such as to give a two-phase system comprising a disperse polyisocyanate phase and a continuous, aqueous phase containing auxiliary solvent. In a preferred embodiment of the invention dispersions are prepared which are virtually free from auxiliary solvent, by first adding a portion of water to the solution (1), substantially removing the auxiliary solvent with intensive mixing and then adding a second portion of water with intensive mixing to the mixture comprising the polyisocyanates (A) and (B) and the first portion of water.Type: GrantFiled: October 19, 2001Date of Patent: April 27, 2004Assignee: Degussa AGInventors: Hartwig Lange, Klaus Janischewski, Dirk Reichel
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Patent number: 6677400Abstract: An aqueous polyurethane resin dispersions containing i) a polyol component with a molecular weight above 300 daltons, containing a polyether diol initiated on an aromatic diol, ii) a polyol component with a molecular weight of 62 to 299 daltons, iii) a monofunctional isocyanate-reactive compound with an ethylene oxide content of at least 50 wt. % and a molecular weight of at least 400 daltons, iv) a polyisocyanate v) an aliphatic polyamine with a molecular weight of 60 to 300 daltons or hydrazine, and vi) a hydrophilic aliphatic diamine, a process for making the dispersion and substrates primed with the dispersion.Type: GrantFiled: August 5, 2002Date of Patent: January 13, 2004Assignee: Bayer AktiengesellschaftInventors: Thomas MĂĽnzmay, Uwe Klippert, Frank Kobor, Claus Kobusch, Gerald Kurek
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Patent number: 6566432Abstract: Disclosed is a coloring resin composition comprising a dispersing agent, a pigment and a thermoplastic resin, in which the dispersing agent is expressed by the following Formula 1 and the thermoplastic resin is metallocene polyolefin: CnH2n+1(OCH2CH2)mOH Formula 1 wherein n is an integer of 26 to 50, and m is an integer of 4 to 100. The composition is useful in coloring molded articles of thermoplastic resin. Colored resin molded articles using the composition are also disclosed.Type: GrantFiled: June 15, 2001Date of Patent: May 20, 2003Assignee: Toyo Ink Mfg. Co., Ltd.Inventors: Masayasu Kawamura, Masashi Koide
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Publication number: 20030087176Abstract: A process for preparing polymeric toner particles comprises dissolving a binder polymer in an organic solvent to form an organic phase, which is dispersed in an aqueous phase comprising a promoter and a particulate stabilizer to form a first dispersion. This first dispersion is homogenized to form a limited coalescence dispersion, to which is added poly(adipic acid-co-N-methylaminethanol), resulting in formation of a mixture comprising toner particle droplets. The organic solvent is removed from the mixture, and the resulting non-spherical toner particles are collected.Type: ApplicationFiled: July 2, 2002Publication date: May 8, 2003Inventors: Matthew C. Ezenyilimba, Hichang Yoon, John C. Wilson
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Patent number: 6416921Abstract: A process for forming non-spherical toner particles by limited coalescence comprises: forming an organic phase comprising a polymeric material, a pigment, a quaternary ammonium tetraphenylborate salt, a phosphonium salt polymer formed by condensation of at least one dicarboxylic acid or dicarboxylic ester monomer with at least one diol monomer, at least one of the acid or ester monomers including a triarylphosphonium salt group, and a water-immiscible liquid; dispersing the organic phase in an aqueous phase containing a solid colloidal stabilizer; forming a suspension of small droplets of the organic phase in the aqueous phase by high shear agitation; removing the water-immiscible liquid from the small droplets, thereby forming a suspension of small solid particles in the aqueous phase; and separating and drying the solid particles, which are toner particles having a non-spherical shape.Type: GrantFiled: March 22, 2001Date of Patent: July 9, 2002Assignee: Heidelberg Digital L.L.C.Inventors: John C. Wilson, Matthew C. Ezenyilimba, Gretchen S. McGrath
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Patent number: 6359035Abstract: This adhesive for electroless plating can be produced without causing dust explosion and is excellent as an interlaminar resin insulating layer and is obtained by mixing an organic solvent dispersion of cured particles of heat resistant resin soluble or decomposable in an acid or an oxidizing agent with an uncured resin. The dispersion of the cured particles of the heat resistant resin in the organic solvent is obtained by dispersing cured particles formed in the production of heat resistant resin cured particles into the organic solvent without drying, and the uncured resin is a resin becoming hardly soluble in an acid or an oxidizing agent through curing treatment and capable of forming a heat resistant cured resin.Type: GrantFiled: April 13, 2000Date of Patent: March 19, 2002Assignees: Ibiden Co., Ltd., Sanyo Chemical Industries, Ltd.Inventors: Yoshitaka Ono, Taki Adachi
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Patent number: 6348521Abstract: A stable and high-solids aqueous dispersion of blocked isocyanates, containing auxiliary solvent, is prepared by (1) preparing a solution of a polyisocyanate mixture of from 20-70% by weight of a blocked, hydrophilically modified polyisocyanate (A) and from 30-80% by weight of a blocked, hydrophobic polyisocyanate (B) in an auxiliary solvent (G) and (2) adding water to this solution, with intensive mixing, in an amount which is such as to give a two-phase system comprising a disperse polyisocyanate phase and a continuous, aqueous phase containing auxiliary solvent. In a preferred embodiment of the invention dispersions are prepared which are virtually free from auxiliary solvent, by first adding a portion of water to the solution (1), substantially removing the auxiliary solvent with intensive mixing and then adding a second portion of water with intensive mixing to the mixture comprising the polyisocyanates (A) and (B) and the first portion of water.Type: GrantFiled: May 10, 2000Date of Patent: February 19, 2002Assignee: Degussa-Huels AktiengesellschaftInventors: Hartwig Lange, Klaus Janischewski, Dirk Reichel
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Patent number: 6100325Abstract: Dispersions, obtained starting from a system formed by a (per)fluorinated polymer in polar solvent, comprising at least:0.1-30% by weight of a polytetrafluoroethylene or of tetrafluoroethylene copolymers with other ethylenically unsaturated, totally or partially fluorinated, monomers;50-99% by weight of fluorinated liquid;0.01-5% by weight of surfactant selected from carboxylic acids with PFPE chain and nonionic surfactants having a perfluoroalkylic or perfluoropolyether chain with a oxyalkylenic repeating unit number lower than or equal to 6;polar solvent (water and/or alcohol) complement to 100; weight ratio lower than that of the initial system containing the (per)fluoropolymer used to prepare the dispersion.Type: GrantFiled: July 30, 1998Date of Patent: August 8, 2000Assignee: Ausimont S.p.A.Inventors: Alba Chittofrati, Paolo Lazzari, Daria Lenti
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Patent number: 6034156Abstract: The presently claimed process for the production of a solid pigment/resin dispersion comprises the steps of mixing together a particulate pigment, a solid resin carrier, a water-immiscible organic solvent in which the carrier is at least partially soluble, water, and, optionally, a water miscible solvent until the mixture separates into an aqueous phase and a coherent phase comprising resin, pigment and organic solvent; separating water from the coherent phase; and continuing to mix the coherent phase while removing the organic solvent under the action of heat and/or reduced pressure until a dry particulate material comprising a pigment and resin is formed.Type: GrantFiled: November 24, 1997Date of Patent: March 7, 2000Assignee: Coates Brothers PLCInventor: Philip Edward Thorne
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Patent number: 5908896Abstract: Organic aerogel microspheres which can be used in capacitors, batteries, thermal insulation, adsorption/filtration media, and chromatographic packings, having diameters ranging from about 1 micron to about 3 mm. The microspheres can be pyrolyzed to form carbon aerogel microspheres. This method involves stirring the aqueous organic phase in mineral oil at elevated temperature until the dispersed organic phase polymerizes and forms nonsticky gel spheres. The size of the microspheres depends on the collision rate of the liquid droplets and the reaction rate of the monomers from which the aqueous solution is formed. The collision rate is governed by the volume ratio of the aqueous solution to the mineral oil and the shear rate, while the reaction rate is governed by the chemical formulation and the curing temperature.Type: GrantFiled: January 16, 1996Date of Patent: June 1, 1999Assignee: The Regents of the University of CaliforniaInventors: Steven T. Mayer, Fung-Ming Kong, Richard W. Pekala, James L. Kaschmitter
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Patent number: 5872164Abstract: A process is provided for preparing a resin composition for coloring which comprises the steps of a phase replacement and dehydration of a pigment (a); water (b); a thermoplastic resin (c), an aqueous dispersion or solution of a thermoplastic resin (d) or an aqueous compound (e) in a twin screw extruder. Also, there is provided a resin composition for coloring prepared by such a process. It is possible to efficiently manufacture a resin composition for coloring (master batch) which has excellent pigment dispersibility and which is capable of uniform coloring without causing color unevenness.Type: GrantFiled: September 19, 1997Date of Patent: February 16, 1999Assignee: Toyo Ink Manufacturing Co., Ltd.Inventors: Masashi Koide, Yasuaki Machida, Junichi Suzuki
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Patent number: 5869542Abstract: Processes for spray drying water-soluble and water-swellable vinyl-addition polymer-containing dispersions, emulsions and microemulsions to obtain substantially dry water-soluble or water-swellable polymer particles, compositions of substantially dry water-soluble or water-swellable polymer particles, methods of agglomerating spray-dried polymer particles, and methods of using spray-dried polymer particles and agglomerates in water-treating, mining, paper, food processing, soil conditioning, solution thickening, biotechnological, and oil recovery applications are disclosed.Type: GrantFiled: June 21, 1996Date of Patent: February 9, 1999Assignee: Cytec Technology Corp.Inventors: William Bloor Davies, John Edward Healy
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Patent number: 5795926Abstract: A process is described for the preparation of finely divided polymer powders by polymerizing water-soluble monomers in the aqueous phase of a water-in-oil emulsion in the presence of water-in-oil emulsifiers and polymerization initiators, removing the water from the resultant water-in-oil polymer suspension by azeotropic distillation, and isolating the suspended, finely divided polymer powder, either the polymerization of the water-soluble monomers being carried out in the presence of from 0.1 to 10% by weight, based on the monomers employed in the polymerization, of protective colloids, or the protective colloids being added to the water-in-oil polymer suspension after the polymerization is complete. The polymerization is preferably carried out in the presence of surfactant. The finely divided pulverulent polymers are used as flocculants or thickeners for aqueous systems.Type: GrantFiled: November 21, 1991Date of Patent: August 18, 1998Assignee: BASF AktiengesellschaftInventors: Manfred Niessner, Norbert Grund, Wilfried Heide, Heinrich Hartmann
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Patent number: 5731368Abstract: Aqueous dispersions of vinyl polymers are disclosed. The polymers are copolymers of a vinyl halide, a vinyl ester, e.g., vinyl acetate, and a poly(alkylene glycol)-based macromonomer, e.g., poly(ethylene glycol)-maleic anhydride. Also disclosed are processes for the preparation of the aqueous dispersions which comprise forming the copolymer by solution polymerization, converting the dissolved polymer into an aqueous dispersion and removing the solvent from the aqueous dispersion.Type: GrantFiled: September 1, 1995Date of Patent: March 24, 1998Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventors: James Preston Stanley, Eric Jay Nagel, Richard Jude Burns, Walter Paul Mayer, Steven Nicholas Semerak
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Patent number: 5650255Abstract: An in situ chemical process for the preparation of toner comprised of(i) the provision of a latex, which latex is comprised of polymeric resin particles, an ionic surfactant and a nonionic surfactant;(ii) providing a pigment dispersion, which dispersion is comprised of a pigment solution, a counterionic surfactant with a charge polarity of opposite sign to that of said ionic surfactant, and optionally a charge control agent;(iii) mixing said pigment dispersion with said latex with a stirrer equipped with an impeller, stirring at speeds of from about 100 to about 900 rpm for a period of from about 10 minutes to about 150 minutes;(iv) heating the above resulting blend of latex and pigment mixture to a temperature below about the glass transition temperature (Tg) of the resin to form electrostatically bound toner size aggregates;(v) adding further aqueous ionic surfactant or stabilizer in the range amount of from about 0.Type: GrantFiled: September 3, 1996Date of Patent: July 22, 1997Assignee: Xerox CorporationInventors: T. Hwee Ng, Arthur Helbrecht, Raj D. Patel, Grazyna E. Kmiecik-Lawrynowicz, David Kurceba, Francisco E. Torres, David J. Sanders
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Patent number: 5645968Abstract: A process for the preparation of toner comprising(i) preparing, or providing a cationic emulsion resin latex comprised of a resin derived from at least one olefinic nonpolar monomer, a cationic olefinic monomer, a cationic free radical initiator, and optionally a chain transfer agent in an aqueous mixture comprised of a nonionic surfactant and a cationic surfactant, and which mixture is heated at a temperature of from about 60.degree. C. to about 95.degree. C.Type: GrantFiled: October 7, 1996Date of Patent: July 8, 1997Assignee: Xerox CorporationInventors: Guerino G. Sacripante, Maureen M. Kedian, Raj D. Patel, Walter Mychajlowskij, Beng S. Ong
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Patent number: 5629367Abstract: A method of making pigment concentrate particles having pigment uniformly dispersed in a polymer and exhibiting a controlled morphology and narrow particle size distribution. The method involves dispersing pigment particles in a pigment dispersant liquid to form a first dispersion phase; blending the first dispersion phase with a binder to produce a second dispersion phase; mixing the second dispersion phase under sufficient shear to produce a suspension of small dispersion phase droplets in an immiscible suspending liquid; allowing the small dispersion phase droplets in the suspension to coalesce to a larger size at which substantially no further coalescence can occur; mixing the suspension of coalesced droplets with an extracting liquid to remove the pigment dispersant liquid from the coalesced droplets; and isolating the resulting pigment concentrate particles.Type: GrantFiled: January 31, 1995Date of Patent: May 13, 1997Assignee: Eastman Kodak CompanyInventors: Kevin D. Lofftus, Alexandra D. Bermel
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Patent number: 5627004Abstract: A process for the preparation of negatively charged toner comprising:(i) preparing a pigment dispersion, which dispersion is comprised of a pigment, an ionic surfactant, and optionally a charge control agent;(ii) shearing said pigment dispersion with a latex or emulsion blend comprised of a resin of styrene-vinylidene chloride-acrylic acid, styrene-vinyl chloride-acrylic acid, styrene-chloroprene-acrylic acid, styrene-butylacrylate-vinylidene chloride-acrylic acid, styrene-butylacrylate-vinyl chloride-acrylic acid, styrene-butadiene-vinylidene chloride-acrylic acid, or styrene-isoprene-vinylidene chloride-acrylic acid, a counterionic surfactant with a charge polarity of opposite sign to that of said ionic surfactant and a nonionic surfactant;(iii) heating the above sheared blend below about the glass transition temperature (Tg) of the resin to form electrostatically bound toner size aggregates with a narrow particle size distribution; and(iv) heating said bound aggregates above about the Tg of the resin.Type: GrantFiled: September 27, 1996Date of Patent: May 6, 1997Assignee: Xerox CorporationInventor: Bernard Grushkin
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Patent number: 5624996Abstract: Disclosed is a dispersion of fine particles of modified polyethylene, which comprises a hydrocarbon organic solvent and fine particles of an ethylene polymer or ethylene polymer composition dispersed in the solvent, wherein the ethylene polymer or ethylene polymer composition has an acid value of 0.3 to 75 mg-KOH/g as a whole and a crystallinity of at least 45% as determined by the X-ray diffractometry and has an average dispersed particle size of 0.3 to 20 .mu.m and a concentration of 15 to 60% by weight.Type: GrantFiled: May 31, 1995Date of Patent: April 29, 1997Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Akio Morinaga, Takeo Kigami, Kunihiko Yorihiro, Toshihiko Okada
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Patent number: 5620826Abstract: A method is provided for producing dry toner particles comprising the steps of:(i) dissolving at least one organic polymer (toner resin) in a solvent therefor to form a solution, said solvent being immiscible with water,(ii) dispersing said solution in an aqueous phase to form a dispersion of small droplets,(iii) removing the solvent by evaporation from the dispersed droplets and(iv) separating solid polymeric particles from the water of the aqueous phase, characterized in that:I. the dispersion of said small droplets is stabilized by the presence in the aqueous phase of a dissolved water-soluble (co)polymer, comprising both hydrophobic and hydrophilic moieties and thatII. after evaporation of said solvent said water-soluble (co)polymer is washed away.Type: GrantFiled: December 12, 1995Date of Patent: April 15, 1997Assignee: Agfa-Gevaert, N.V.Inventors: Serge Tavernier, Frank Ruttens, Bart Van Hove, Gustaaf Piron, Theophiel Stuer
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Patent number: 5508341Abstract: Organic aerogel microspheres which can be used in capacitors, batteries, thermal insulation, adsorption/filtration media, and chromatographic packings, having diameters ranging from about 1 micron to about 3 mm. The microspheres can be pyrolyzed to form carbon aerogel microspheres. This method involves stirring the aqueous organic phase in mineral oil at elevated temperature until the dispersed organic phase polymerizes and forms nonsticky gel spheres. The size of the microspheres depends on the collision rate of the liquid droplets and the reaction rate of the monomers from which the aqueous solution is formed. The collision rate is governed by the volume ratio of the aqueous solution to the mineral oil and the shear rate, while the reaction rate is governed by the chemical formulation and the curing temperature.Type: GrantFiled: July 8, 1993Date of Patent: April 16, 1996Assignee: Regents of the University of CaliforniaInventors: Steven T. Mayer, Fung-Ming Kong, Richard W. Pekala, James L. Kaschmitter
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Patent number: 5504129Abstract: The specification discloses an aqueous dispersion for coatings consisting essentially of water and a water dispersible component, wherein the water dispersible component is provided by reacting maleic anhydride with a rosin ester to provide a maleated rosin ester, adding wax and preferably also an ethylene vinyl acetate copolymer to the maleated rosin ester, and adding a tertiary amino alcohol to the mixture to yield the water dispersible component as a reaction product thereof. When used in a coating formulation for paper, clay and/or latex may be added to the formulation. In one preferred embodiment, the dispersion is applied as a coating to paper to enhance toner adhesion to the surface of the paper while also providing a relatively low friction surface.Type: GrantFiled: December 8, 1993Date of Patent: April 2, 1996Assignees: International Paper Company, Arizona Chemical CompanyInventors: Gary F. Dandreaux, John T. Geoghegan, Long S. Wang, Lori S. Slovik, John H. Hung
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Patent number: 5482812Abstract: A process for the preparation of toner compositions or toner particles comprising:(i) providing an aqueous pigment dispersion comprised of a pigment, an ionic surfactant, and optionally a charge control agent;(ii) providing a wax dispersion comprised of wax, a dispersant comprised of nonionic surfactant, ionic surfactant or mixtures thereof;(iii) shearing a mixture of the wax dispersion and the pigment dispersion with a latex or emulsion blend comprised of resin, a counterionic surfactant with a charge polarity of opposite sign to that of said ionic surfactant and a nonionic surfactant;(iv) heating the above sheared blend below about the glass transition temperature (Tg) of the resin to form electrostatically bound toner size aggregates with a narrow particle size distribution;(v) adding additional ionic surfactant to the aggregated suspension of (iv) to ensure that no, or minimal additional particle growth of the electrostatically bound toner size aggregates occurs on further increasing the temperature to coType: GrantFiled: November 23, 1994Date of Patent: January 9, 1996Assignee: Xerox CorporationInventors: Michael A. Hopper, Raj D. Patel, Grazyna E. Kmiecik-Lawrynowicz, Stephan V. Drappel, Paul J. Gerroir
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Patent number: 5480921Abstract: The use of falling-film evaporation and a concentration means such as centrifugal separation to dehydrate and concentrate a water-in-oil polymer emulsion or suspension is disclosed. In a preferred embodiment, a water-in-oil polymer composition containing less than about 25% active polymer solids is dehydrated in falling-film evaporator to produce an evaporator concentrate containing less than about 5.0% water. The evaporator concentrate then flows to a separation device such as a centrifuge, wherein oil is removed to produce a composition that is substantially a polymer and emulsifying surfactant-in-oil composition containing in excess of about 60 weight % polymer solids. The centrifuge raffinate may optionally be treated in a second separation means to capture additional polymer solids, with optional recycle of the oil-rich raffinate. The concentrated polymer composition is preferably stabilized with a steric stabilizer to produce a free flowing liquid product.Type: GrantFiled: September 1, 1994Date of Patent: January 2, 1996Assignee: Calgon CorporationInventors: Wood E. Hunter, Kevin W. Frederick, Randy J. Loeffler
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Patent number: 5476744Abstract: A toner for developing electrostatic latent images obtained by passing a toner composition-dispersed phase comprising at least a thermoplastic resin dissolved/dispersed in organic solvents through a microporous body to form an emulsion in an aqueous solution which is to form a continuous phase, and then removing the organic solvents from the emulsion.Type: GrantFiled: June 15, 1994Date of Patent: December 19, 1995Assignee: Minolta Camera Kabushiki KaishaInventor: Masahiro Anno
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Patent number: 5408005Abstract: A process for preparing a rubber modified thermoplastic resin, in which a latex in aqueous emulsion is prepared in the presence of an ionic surfactant; a vinyl monomer insoluble or substantially insoluble in water is added, and the particles of the latex are transferred to the monomer to form an organic phase using a transfer agent of opposite charge to the surfactant; and a polymerization of the organic phase is performed.Type: GrantFiled: June 21, 1993Date of Patent: April 18, 1995Assignee: NorsolorInventors: Philippe Heim, Gerard Riess
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Patent number: 5391456Abstract: A process for the preparation of toner compositions comprising:(i) forming a dispersion of resin in an aqueous ionic surfactant solution;(ii) preparing pigment dispersions in water of three different pigments each of a dissimilar color, each dispersion being comprised of a pigment dispersed in water and which preparation utilizes nonionic dispersants, and optionally an ionic surfactant;(iii) blending the prepared resin dispersed as a latex with two, or optionally three of the different color pigment dispersions of step (ii);(iv) adding an aqueous solution of counterionic surfactant as a coagulant to the formed resin-pigment blends, while continuously subjecting the mixture to high shear, to induce a homogeneous gel of the flocculated resin-pigments blend;(v) heating the above sheared gel at temperatures between about 20.degree. C. and about 5.degree. C.Type: GrantFiled: February 28, 1994Date of Patent: February 21, 1995Assignee: Xerox CorporationInventors: Raj D. Patel, Grazyna E. Kmiecik-Lawrynowicz, Michael A. Hopper, Melvin D. Croucher
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Patent number: 5380771Abstract: Acrylic polymer aqueous dispersions and a method of making such dispersions are described.Type: GrantFiled: June 22, 1992Date of Patent: January 10, 1995Assignee: Cargill IncorporatedInventor: Joseph L. Nothnagel
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Patent number: 5370964Abstract: A process for the preparation of toner comprising:(i) preparing a pigment dispersion in water, which dispersion is comprised of pigment, an ionic surfactant, and an optional charge control agent;(ii) shearing the pigment dispersion with a polymeric latex comprised of resin, a counterionic surfactant with a charge polarity of opposite sign to that of said ionic surfactant, and which latex contains a nonionic surfactant thereby forming a homogeneous or a uniform blend;(iii) heating the above sheared homogeneous blend below about the glass transition temperature (Tg) of the resin to form electrostatically bound toner size aggregates;(iv) reshearing the above electrostatically bound toner aggregates (iii) to fragment or break down said toner aggregates of (iii) into smaller average diameter particle size;(v) heating the resulting formed sheared homogeneous blend (iv) comprised of resin, pigment particles, and the ionic, counterionic and nonionic surfactants in water below about the glass transition temperature (TType: GrantFiled: November 29, 1993Date of Patent: December 6, 1994Assignee: Xerox CorporationInventors: Raj D. Patel, Grazyna E. Kmiecik-Lawrynowicz, Michael A. Hopper, Melvin D. Croucher, T. Hwee Ng, William J. Dale
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Patent number: 5366841Abstract: A process for the preparation of toner compositions comprising:(i) preparing a pigment dispersion in water, which dispersion is comprised of a pigment, an ionic surfactant and optionally a charge control agent;(ii) shearing the pigment dispersion with a latex blend comprised of resin particles, a counterionic surfactant with a charge polarity of opposite sign to that of said ionic surfactant and a nonionic surfactant thereby causing a flocculation or heterocoagulation of the formed particles of pigment, resin and charge control agent to form a uniform dispersion of solids in the water, and surfactant;(iii) heating the above sheared blend at a critical temperature region about equal to or above the glass transition temperature (Tg) of the resin, while continuously stirring, to form electrostatically bounded toner size aggregates with a narrow particle size distribution and wherein said critical temperature is from about 0.degree. C. to about 10.degree. C.Type: GrantFiled: September 30, 1993Date of Patent: November 22, 1994Assignee: Xerox CorporationInventors: Raj D. Patel, Grazyna E. Kmiecik-Lawrynowicz, Michael A. Hopper, Melvin D. Croucher
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Patent number: 5364729Abstract: A process for the preparation of toner compositions comprising:(i) preparing a pigment dispersion, which dispersion is comprised of a pigment, an ionic surfactant, and optionally a charge control agent;(ii) shearing said pigment dispersion with a latex or emulsion blend comprised of resin, a counterionic surfactant with a charge polarity of opposite sign to that of said ionic surfactant and a nonionic surfactant;(iii) heating the above sheared blend below about the glass transition temperature (Tg) of the resin, to form electrostatically bound toner size aggregates with a narrow particle size distribution; and(iv) heating said bound aggregates above about the Tg of the resin.Type: GrantFiled: June 25, 1993Date of Patent: November 15, 1994Assignee: Xerox CorporationInventors: Grazyna E. Kmiecik-Lawrynowicz, Raj D. Patel, Michael A. Hopper