With Step Of Spraying Or Centrifuging Patents (Class 523/342)
  • Patent number: 5462978
    Abstract: Polymers I comprising from 15 to 80% by weight of monomers of the general formula I ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are each C.sub.1 -C.sub.3 -alkyl, R.sup.4 is C.sub.1 -C.sub.5 -alkyl and X is O or NH, and from 20 to 85% by weight of other monomers capable of undergoing free radical copolymerization are used as assistants in the spray drying of aqueous dispersions of polymers II which differ from the polymers I.
    Type: Grant
    Filed: June 6, 1994
    Date of Patent: October 31, 1995
    Assignee: BASF Aktiengesellschaft
    Inventors: Erich Penzel, Gernot Franzmann, Maximilian Angel, Joachim Pakusch, Bernhard Schuler
  • Patent number: 5455342
    Abstract: A method and apparatus for the modification of the physical properties of polymers through pressure processing techniques. The apparatus is comprised of a piston device which acts on the polymer substrate charged within the confines of a compression chamber. The piston delivers an abrupt pressure change to the substrate for the purpose of effecting the desired modification of physical properties including altered thermal, viscosity, solubility, turbidity and hardness profiles. Predictable characteristics may be imparted to the substrate through variation of pressure duration and intensity as well as the number of piston strokes applied. Modification of the physical properties of starch and gum arabic, in particular, is disclosed.
    Type: Grant
    Filed: September 10, 1993
    Date of Patent: October 3, 1995
    Inventor: Bruce K. Redding, Jr.
  • Patent number: 5399597
    Abstract: The present invention provides a new and improved method of producing coating materials comprising the steps of providing a first organic material which is solid at room temperature, providing a second organic material which is solid at room temperature and which is substantially different in chemical composition from the first organic material, providing a source of supercritical fluid, providing a first container having a mechanical agitator, providing a second container, introducing the first and second organic materials and the supercritical fluid into the first container and mechanically agitating such materials and the supercritical fluid, and discharging the contents of the first container into the second container so as to collect substantially all of the first and second organic materials in the second vessel, the second container being maintained at a lower pressure than the first container.
    Type: Grant
    Filed: April 29, 1994
    Date of Patent: March 21, 1995
    Assignee: Ferro Corporation
    Inventors: Frederick S. Mandel, Charles D. Green, Anthony S. Scheibelhoffer
  • Patent number: 5395436
    Abstract: A waterborne wiping stain for wood is provided with an excellent combination of sprayability, lubricity, sag resistance, and holdout by employing a combination of thickeners including hectorite clay, cellulosic thickener, and an associative thickener.
    Type: Grant
    Filed: January 28, 1994
    Date of Patent: March 7, 1995
    Assignee: PPG Industries, Inc.
    Inventor: David Setzke
  • Patent number: 5216121
    Abstract: The invention includes a process for facilitating the handling of tacky polymers (specifically amorphous polypropylene and amorphous ethylene propylene copolymers) during their polymerization comprising:a. preparing a mixture of a tacky polymeric material and a carrying phase for said polymeric material at a temperature and pressure sufficient to maintain said carrying phase as a liquid;b. flashing said mixture to a flash pressure low enough to effect vaporization of said carrying phase, as well as autorefrigeration of said polymeric material to its non-tacky, easy-handling temperature range; andc. separating the thus autorefrigerated polymeric product from its carrying phase wherein said carrying phase will dissolve sufficient polymer to form a liquid mixture.The invention also includes an apparatus for carrying out this process.
    Type: Grant
    Filed: November 13, 1990
    Date of Patent: June 1, 1993
    Inventors: Giuseppe Zanella, deceased, Roberto Zanella, Heir, Zanella, Heir, Vittorio, Marco Zanella, heir, Giuseppe R. Palmese
  • Patent number: 5207954
    Abstract: Thermosettable, coreactable particulate powdereded compositions having particles comprising at least a first copolymer of an olefinically unsaturated monomer having at least one functional group and at least a second copolymer of an olefinically unsaturated monomer having at least one functional group which is reactive with the at least one functional group of the at least first copolymer are disclosed. Methods for making and using these compositions are also disclosed.
    Type: Grant
    Filed: June 22, 1992
    Date of Patent: May 4, 1993
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventors: Jeffrey M. Lewis, Kenneth L. Hoy, Michael J. Greene
  • Patent number: 5166227
    Abstract: High amounts of silicon dioxide are readily incorporated into an emulsion polymerized elastomer by mixing an aqueous dispersion of silicon dioxide with a latex of the emulsion polymer and subsequently spray drying the mixture. Free flowing, fine-size (e.g., less than 500 micrometers) particles are produced with generally complete incorporation of silicon dioxide. The presence of the silicon dioxide permits rubbers with low gel and/or low Mooney viscosity to be spray dried whereas previously this could not be accomplished. Compared to conventional means of adding a silica to a bale rubber, the above powdered masterbatch gives shorter mixing times with lower power consumption with improved physical properties, such as tensile strength.
    Type: Grant
    Filed: November 29, 1990
    Date of Patent: November 24, 1992
    Assignee: Zeon Chemicals USA, Inc.
    Inventors: Charles C. Raines, Philip H. Starmer
  • Patent number: 5049594
    Abstract: There is disclosed a process for preparing an organic polymer composition which includes an inorganic filler, which comprises: (i) treating an inorganic filler by adding to a particulate white inorganic material a natural or synthetic latex composition which comprises a suspension of polymer particles in water wherein the latex solids are selected from the group consisting of acrylic copolymers and vinyl acetate copolymers, and dewatering and drying the resultant mixture, the amount of the natural or synthetic latex composition added being such as to provide from 1% to 10% by weight of latex solids based on the weight of dry inorganic material; and (ii) combining the treated inorganic filler with an organic polymer. Also disclosed is an organic polymeric composition comprising an organic polymer and an inorganic filler.
    Type: Grant
    Filed: January 17, 1990
    Date of Patent: September 17, 1991
    Assignee: ECC International Limited
    Inventor: David G. Jeffs
  • Patent number: 5028482
    Abstract: A process for preparing an inorganic filler comprises admixing a particulate inorganic material with a natural or synthetic latex composition and an aqueous suspension of fine carbon black, and dewatering and drying the resultant mixture, the amount of the natural or synthetic latex composition added being such as to provide a coating on the inorganic mineral of from 1% to 10% by weight of latex solids based on the weight of dry inorganic material.
    Type: Grant
    Filed: September 6, 1989
    Date of Patent: July 2, 1991
    Assignee: ECC International Limited
    Inventor: David G. Jeffs
  • Patent number: 5017630
    Abstract: High amounts of silicon dioxide are readily incorporated into an emulsion polymerized elastomer by mixing an aqueous dispersion of silicon dioxide with a latex of the emulsion polymer and subsequently spray drying the mixture. Free flowing, fine-size (e.g., less than 500 micrometers) particles are produced with generally complete incorporation of silicon dioxide. The presence of the silicon dioxide permits rubbers with low gel and/or low Mooney viscosity to be spray dried whereas previously this could not be accomplished. Compared to conventional means of adding a silica to a bale rubber, the above powdered masterbatch gives shorter mixing times with lower power consumption with improved physical properties, such as tensile strength.
    Type: Grant
    Filed: August 17, 1989
    Date of Patent: May 21, 1991
    Assignee: Zeon Chemicals USA, Inc.
    Inventors: Charles C. Raines, Philip H. Starmer
  • Patent number: 5017631
    Abstract: Powders of an emulsion polymer having reduced fines and exhibiting low dusting are made by spray drying an emulsion of a polymer having a Vicat softening temperature above 60.degree. C., said emulsion containing an external plasticizer having a boiling point of at least 150.degree. C.
    Type: Grant
    Filed: December 26, 1989
    Date of Patent: May 21, 1991
    Assignee: Rohm GmbH
    Inventors: Hubert Rauch, Peter J. Arndt, Wolfgang Klesse, Wilhelm Krall, Klaus Frank
  • Patent number: 4892910
    Abstract: Polymer powders comprising aggregated polymer particles, said powders having a low content of fines and being suitable as processing aids in the manufacture of polyvinyl chloride, are made by spray drying an aqueous dispersion (latex) of two emulsion polymers, one of which has a dynamic glass transition temperature above 90.degree. C. and the other of which has a dynamic glass transition below 105.degree. C., the latter being at least 10 K. degrees below the former.
    Type: Grant
    Filed: July 13, 1988
    Date of Patent: January 9, 1990
    Assignee: GmbH Rohm
    Inventors: Wolfgang Klesse, Hubert Rauch, Peter J. Arndt, Norbert Suetterlin
  • Patent number: 4892932
    Abstract: The formation of interfering polymer deposits in spary drying apparatus during the spray drying of aqueous dispersions or solutions of polymers in a stream of warm air is avoided if water is atomized together with the dispersion or solution.
    Type: Grant
    Filed: February 24, 1989
    Date of Patent: January 9, 1990
    Assignee: Rohm GmbH
    Inventors: Hubert Rauch, Peter J. Arndt
  • Patent number: 4816558
    Abstract: A method for obtaining redispersible powders of a copolymer having a dynamic glass transition temperature, T.sub.max, below 150.degree. C., by spray drying an aqueous dispersion thereof having a minimum film forming temperature, MFT, using an inlet temperature T.sub.i and an outlet temperature T.sub.o such that MFT<T.sub.i <T.sub.max and MFT<T.sub.o <65.degree. C.
    Type: Grant
    Filed: July 27, 1987
    Date of Patent: March 28, 1989
    Assignee: Rohm GmbH
    Inventors: Hubert Rauch, Wolfgang Klesse, Klaus Lehmann, Theodor Mager
  • Patent number: 4800103
    Abstract: A process for preparing an inorganic filler comprising treating a particulate inorganic material with a natural or synthetic latex composition and dewatering and drying the resultant mixture. The surface-treated inorganic filler can be used with advantage in a polymeric resin composition.
    Type: Grant
    Filed: August 29, 1986
    Date of Patent: January 24, 1989
    Assignee: ECC International Limited
    Inventor: David G. Jeffs
  • Patent number: 4774271
    Abstract: The invention relates to a process for the recovery of thermoplastic polymers from aqueous dispersions by spray-drying after treatment with carboxylic acid of formula I ##STR1## wherein X is a single bond, --CH.sub.2 -- or --C.sub.2 H.sub.
    Type: Grant
    Filed: February 9, 1987
    Date of Patent: September 27, 1988
    Assignee: Bayer Aktiengesellschaft
    Inventors: Christian Lindner, Pol Bamelis, Jurgen Hinz, Dieter Wittmann, Otto Koch, Burkhard Braun
  • Patent number: 4547428
    Abstract: A terpolymer comprising repeating units derived from an olefin, a diester of an addition polymerizable unsaturated dicarboxylic acid, and a solubilizing monomer which promotes compatibility between the terpolymer and a vinyl halide polymer. A granular form of the processing aid and a method for its preparation are also disclosed.
    Type: Grant
    Filed: March 21, 1983
    Date of Patent: October 15, 1985
    Assignee: Monsanto Company
    Inventors: Vladimir Bekker, Wayne J. Buchheim, William Vanderlinde, Donald S. T. Wang
  • Patent number: 4433076
    Abstract: What are disclosed are methods for making a suspension suitable for use as a coating agent for medicaments by suspending a powder of certain vinyl copolymers in an aqueous solution or suspension of a plasticizer therefor, methods for converting such a suspension of copolymer in plasticizer into a film-forming solution or other extensively homogeneous phase, such suspensions and the film-forming conversion products thereof, and methods for coating medicaments with such suspensions and film-forming conversion products.
    Type: Grant
    Filed: December 8, 1981
    Date of Patent: February 21, 1984
    Assignee: Rohm GmbH
    Inventors: Kurt H. Bauer, Hermann Osterwald, Klaus Lehmann, Dieter Dreher
  • Patent number: 4379871
    Abstract: There is disclosed a process for the production of a pigment-synthetic resin concentrate containing an organic solvent soluble polymer and carbon black having quicker distributability in organic media such as lacquer binding media, printing inks, etc., such concentrates being especially suitable for the production of molded parts, castings, films and/or synthetic fibers, the process comprising continuously homogenizing in a mixer powdery pigment and powdery synthetic resin jointly with an organic solvent in a given case also containing plasticizer, stabilizer and/or dispersing acid, dispersing the pigment in the mixture, removing the solvent from the dispersion, comminuting the resulting pigment-synthetic resin concentrated and grinding the product.
    Type: Grant
    Filed: December 30, 1977
    Date of Patent: April 12, 1983
    Assignee: Deutsche Gold- und Silber-Scheideanstalt Vormals Roessler
    Inventors: Peter Werle, Hans Graf, Erwin Walter