Carbohydrate Or Derivative Including Tannin Or Derivative Dnrm Patents (Class 523/509)
  • Patent number: 11441057
    Abstract: An Additive Package is provided to adjust the cure properties of a two-part bonding filler across a temperature range of from 4 and 44 degrees Celsius. A low temperature additive speeds a cure rate between 4 and 15 degrees Celsius and a high temperature additive slows down a cure rate between 25 and 44 degrees Celsius. The amount of Additive Package is varied to account for the desired cure properties. The Additive Package includes a first unsaturated polyester resins with an average degree of unsaturation of 70-100 percent based on total acid and anhydride monomer content. A process for repairing a vehicle body is provided using the Additive Package. A kit for accomplishing repairs in an after-market repair setting is also provided.
    Type: Grant
    Filed: January 17, 2020
    Date of Patent: September 13, 2022
    Assignee: ILLINOIS TOOL WORKS INC.
    Inventors: Helena Twardowska, Robert Mark Adams, David McKinney
  • Patent number: 10125287
    Abstract: Copolymers and latex paint compositions using such copolymers that are heat-age stable and provide good adhesion, block resistance, and hiding all while using lower amounts of titanium dioxide are described herein. In one aspect, the heat-age stable compositions include an acrylic, styrene acrylic, vinyl acrylic copolymer or blends thereof including, as additional polymerizable units, at least one polymerizable phosphate surfactant and at least one linear or branched hydrophobic monomer that are both polymerized into the acrylic, styrene acrylic, vinyl acrylic copolymer backbone.
    Type: Grant
    Filed: August 31, 2016
    Date of Patent: November 13, 2018
    Assignee: The Sherwin-Williams Company
    Inventors: Revathi R Tomko, Wanda J Smith, Kimberly A Koglin
  • Patent number: 9663608
    Abstract: A molding composition formulation includes a thermoset cross-linkable 12 to 45 micron polymeric resin. Hollow glass microspheroids are present from 2 to 12 total weight percent. An article formed from such a composition is further strengthened by the addition of a surface activating agent bonded to the surface of the glass microspheroids. Conventional particulate fillers when added to an inventive formulation provide enhanced performance when the filler particle has a size sufficiently small to insert within adjacent microspheroid interstitial voids. An unsaturated polyester resin so formed is particularly well suited for the formation of sheet molding compound formulations.
    Type: Grant
    Filed: May 28, 2014
    Date of Patent: May 30, 2017
    Assignee: Continental Structural Plastics, Inc.
    Inventors: Brian A. Beach, Probir K. Guha, Brad Haskell, Michael J. Siwajek
  • Patent number: 9657184
    Abstract: Copolymers and latex paint compositions using such copolymers that are heat-age stable and provide good adhesion, block resistance, and hiding all while using lower amounts of pigment are described herein. In one aspect, the heat-age stable compositions include an acrylic, styrene acrylic, vinyl acrylic copolymer or blends thereof including, as additional polymerizable units, at least one polymerizable phosphate surfactant and at least one linear or branched hydrophobic monomer that are both polymerized into the acrylic, styrene acrylic, vinyl acrylic copolymer backbone.
    Type: Grant
    Filed: August 31, 2016
    Date of Patent: May 23, 2017
    Assignee: The Sherwin-Williams Company
    Inventors: Revathi R Tomko, Wanda J Smith, Kimberly A. Koglin
  • Patent number: 9399707
    Abstract: A composite comprising a flame retardant, such as ATH and an expandable graphite is disclosed.
    Type: Grant
    Filed: March 15, 2013
    Date of Patent: July 26, 2016
    Assignee: J.M. Huber Corporation
    Inventors: Gary Charles Rex, Mark Anthony Herndon
  • Patent number: 9133060
    Abstract: The present invention provides a gypsum composition, a gypsum board and their preparation method and the use of DHA as an anti-sagging additive in a gypsum product. Said gypsum board comprises set gypsum prepared from the composition; while said composition comprises gypsum, and an anti-deformation additive, wherein the anti-deformation additive comprises at least one selected from a group consisting of dehydroascorbic acid, dehydroascorbate and semidehydroascorbic acid. The set gypsum prepared from the said composition shows better anti-sagging or deformation resisting property. The gypsum product of the present invention is hardly distorted and has stronger stability even in the condition of high humidity, thus improve the quality of the gypsum product to meet the demands of the customer.
    Type: Grant
    Filed: December 3, 2012
    Date of Patent: September 15, 2015
    Assignee: Saint-Gobain Placo
    Inventors: Xiaotong Gao, Dongxiao Shao, Huifen Li, Hao Song, Ke Zhang
  • Patent number: 9045644
    Abstract: Solid pigment preparations comprising as essential constituents (A) from 60% to 95% by weight of at least one pigment, (B) from 2.5% to 35% by weight of at least one water-soluble surface-active additive based on polyurethanes and (C) from 2.5% to 35% by weight of at least one nonionic water-soluble surface-active additive (C1) based on polyethers and/or of an anionic water-soluble additive other than additives (B) which is based on polymers of ethylenically unsaturated carboxylic acids (C2), and also production and use of the pigment preparations for coloration of macromolecular organic and inorganic materials and also of plastics.
    Type: Grant
    Filed: February 8, 2006
    Date of Patent: June 2, 2015
    Assignee: BASF Aktiengesellschaft
    Inventors: Hans-Ulrich Reisacher, Christian Krueger, Uwe Mauthe, Juan Antonio Gonzalez Gomez, Raimund Schmid
  • Patent number: 8124672
    Abstract: Disclosed are solid pigment preparations containing (A) 60 to 95 per weight of at least one pigment, (B) 5 to 40 percent by weight of at least one water-soluble anionic surface-active additive from the group of the homopolymers and copolymers of ethylenically unsaturated monocarboxylic acids and/or ethylenically unsaturated dicarboxylic acids which can additionally contain monopolymerized vinyl monomers having no acid function, the alkoxylation products of said homopolymers and copolymers, and the salts of said homopolymers and copolymers and the alkoxylation products thereof, and (C) 0 to 20 percent by weight of at least one nonionic surface-active polyether-based additive as essential components. Also disclosed are a method for the production thereof and methods for dyeing macromolecular organic and inorganic materials.
    Type: Grant
    Filed: November 11, 2003
    Date of Patent: February 28, 2012
    Assignee: BASF Aktiengesellschaft
    Inventors: Hansulrich Reisacher, Ingo Klopp, Stephan Hueffer, Matthias Klueglein
  • Patent number: 7256223
    Abstract: Polymeric materials and products, including sheet flooring materials prepared from the polymeric materials, and processes for preparing the polymeric materials, are disclosed. The polymeric materials include a polylactic acid-based polymer in combination with plasticizer and a compatibilizer, and optionally include a filler. The polymeric material can include between about 30 to about 50 percent by weight polyvinyl chloride, polyethylene glycol, polyglycolide, ethylene vinyl acetate, polycarbonate, polycaprolactone, polyhydroxyalkanoates, or polyolefins modified with polar groups, for example, ionomers. The plasticizer is typically an epoxidized vegetable oil or esterified and epoxidized vegetable oil and is typically present in an amount of between about 10 and about 50% by weight. In some embodiments, the compatibilizer is a polyolefin modified with one or more polar functional groups, and is typically present in an amount of between about 5 and about 10% by weight.
    Type: Grant
    Filed: January 10, 2005
    Date of Patent: August 14, 2007
    Assignee: Michigan State University, Board of Trustees
    Inventors: Amar K. Mohanty, Lawrence T. Drzal, Brian P. Rook, Manjusri Misra
  • Patent number: 6869985
    Abstract: Polymeric materials and products, including sheet flooring materials prepared from the polymeric materials, and processes for preparing the polymeric materials, are disclosed. The polymeric materials include a polylactic acid-based polymer in combination with plasticizer and a compatibilizer, and optionally include a filler. The polymeric material can include between about 30 to about 50 percent by weight polyvinyl chloride, polyethylene glycol, polyglycolide, ethylene vinyl acetate, polycarbonate, polycaprolactone, polyhydroxyalkanoates, or polyolefins modified with polar groups, for example, ionomers. The plasticizer is typically an epoxidized vegetable oil or esterified and epoxidized vegetable oil and is typically present in an amount of between about 10 and about 50% by weight. In some embodiments, the compatibilizer is a polyolefin modified with one or more polar functional groups, and is typically present in an amount of between about 5 and about 10% by weight.
    Type: Grant
    Filed: November 26, 2002
    Date of Patent: March 22, 2005
    Assignee: AWI Licensing Company
    Inventors: Amar Kumar Mohanty, Lawrence T. Drzal, Brian P. Rook, Manjusri Misra
  • Patent number: 6545068
    Abstract: A composition is provided which comprises a first component, a second component, and a compressible substance in which the first component comprises a peroxide, a liquid which comprises water, and a solid particulate; and the second component comprises a polymer, a crosslinking agent, and a solid particulate. The composition can further comprises a sugar. Also disclosed is a process that can be used for preventing a grouting composition from becoming limp. The process comprises combining a grouting composition with a compressible substance in which the composition comprises a first component and a second component as disclosed above.
    Type: Grant
    Filed: February 9, 2000
    Date of Patent: April 8, 2003
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Walter John Simmons, Domenic Joseph Barsotti, Phillip Edwin Gramlich
  • Patent number: 6541545
    Abstract: An composition is provided which comprises a first component and a second component in which the first component comprises a peroxide, a liquid which comprises water, a sugar, and a solid particulate; and the second component comprises a polymer, a crosslinking agent, and a solid particulate. Also disclosed are processes for reducing fluid loss in a grouting composition and for anchoring a reinforcing member in a hole using the composition disclosed above.
    Type: Grant
    Filed: March 19, 1999
    Date of Patent: April 1, 2003
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Walter John Simmons, Domenic Joseph Barsotti
  • Patent number: 5880181
    Abstract: The present invention relates to a gel comprising A) a solution of at least one organic peroxide essentially solubilized in a phlegmatizer, B) at least one cellulose ester as thickening agent essentially solubilized in solution A, and C) at least one thixotropic agent selected from hydrogenated castor oil and fumed silica. These gels offer the advantages of essentially no phase segregation during storage, essentially no formation of solid crystals during storage, and easy metering into thermoset resins because of their thixotropic behavior. Furthermore, these gels may be transparent, with the advantage that brightly colored gels may be prepared therefrom.
    Type: Grant
    Filed: June 6, 1996
    Date of Patent: March 9, 1999
    Assignee: Akzo Nobel NV
    Inventors: Reinder Torenbeek, Jacobus Johannes Antonius Eijmans
  • Patent number: 5767177
    Abstract: Thermosetting composition. According to the invention, it comprises approximately, by weight:33% to 43% of a thermosetting resin;5% to 15% cellulose fibers;15% to 21% mineral fillers;12.5% to 22.5% reinforcement fibers of high mechanical strength.
    Type: Grant
    Filed: April 1, 1996
    Date of Patent: June 16, 1998
    Assignee: Cytec Industry Incorporated
    Inventors: Pedro Omente, Lionel Landru
  • Patent number: 5500465
    Abstract: Compatibilized blends of a biodegradable hydrophobic polyester, unmodified starch or other similar polysaccharide containing less than 1% water by weight, other biodegradable polymers that may be hydrophobic, plasticizer, and other additives. The blends are produced in the absence of water. The preferred polyester polymer is poly(.epsilon.-caprolactone) and the preferred starch is from corn. A small amount of a unique stretching agent is incorporated to provide high elongations at break, especially in film forming compositions containing a significant amount of starch. The starch is a discontinuous phase that may be completely or partially plasticized and the polyester polymer is the continuous phase. The preferred polymers have unique film forming properties and are resistant to water and moisture.
    Type: Grant
    Filed: March 10, 1994
    Date of Patent: March 19, 1996
    Assignee: Board of Trustees operating Michigan State University
    Inventors: Mohan Krishnan, Ramani Narayan
  • Patent number: 5422387
    Abstract: Liquid impervious, biodegradable films are disclosed. In particular, the films comprise a blend of an interpenetrated network of destructurized starch with ethylene/acrylic acid copolymers or ethylene/vinyl alcohol copolymers, and an aliphatic polyester such as polycaprolactone. Diapers, sanitary napkins, pantiliners, and the like, containing backsheets prepared from the foregoing materials are also disclosed.
    Type: Grant
    Filed: October 18, 1993
    Date of Patent: June 6, 1995
    Assignee: The Proctor & Gamble Company
    Inventors: Douglas Toms, Andrew J. Wnuk
  • Patent number: 5417679
    Abstract: Liquid impervious, biodegradable films are disclosed. In particular, the films comprise a blend of an interpenetrated network of destructurized starch with ethylene/acrylic acid copolymers or ethylene/vinyl alcohol copolymers, and an aliphatic polyester such as polycaprolactone. Diapers, sanitary napkins, pantiliners, and the like, containing backsheets prepared from the foregoing materials are also disclosed.
    Type: Grant
    Filed: September 27, 1993
    Date of Patent: May 23, 1995
    Assignee: The Procter & Gamble Company
    Inventors: Douglas Toms, Andrew J. Wnuk
  • Patent number: 5354809
    Abstract: A curable molding material based on a dispersion of a finely divided ethylene polymer in an unsaturated polyester resin is prepared by a process in which a melt of the ethylene polymer is uniformly distributed in a melt of an unsaturated polyester in an extruder or stirred kettle.
    Type: Grant
    Filed: April 30, 1993
    Date of Patent: October 11, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Anton Hesse, Juergen Hofmann, Walter Heckmann, Volker Warzelhan
  • Patent number: 5231121
    Abstract: Molding compositions based on unsaturated polyester (UP) resins and containing natural fibers are prepared from which molded parts can be produced by hot pressing. The molded parts have a residual styrene content <0.1 wt. %. The UP resins are comprised of a customary UP and a mixture of styrene and di(meth)acrylic acid ester(s).
    Type: Grant
    Filed: January 29, 1992
    Date of Patent: July 27, 1993
    Assignee: Huls Aktiengesellschaft
    Inventors: Horst Kramer, Johannes Stawowy
  • Patent number: 4766163
    Abstract: Thermosetting resin composition comprising an unsaturated thermosetting polyester resin and a thermosetting organo-silicone compound which can react with the thermosetting polyester resin by cross-linking to establish chemical bonds between the thermosetting polyester resin and the thermosetting organo-silicone compound for forming a solid polyester/organo-silicone thermoset resin product with a network of cross-linked chemical bonds. The thermosetting organo-silicone compound preferably is a thermosetting organo-silicone elastomer; the composition preferably contains a low-profile or low-shrinkage additive; and the polyester resin preferably is associated with an unsaturated monomer for cross-linking therewith. The resin composition is useful for the production of "dough" moulding compounds, sheet moulding compounds, bulk moulding compounds, high strength moulding compounds, and thick moulding compounds.
    Type: Grant
    Filed: October 10, 1986
    Date of Patent: August 23, 1988
    Assignee: Bridges Corporation Pty Ltd
    Inventor: Kenneth R. Strudwick
  • Patent number: 4730012
    Abstract: A building material composition comprises a mixture of a styrenated unsaturated polyester with hydrated alumina at a ratio of one part by volume polyester to 0.5 to one part hydrated alumina. The mixture is cured by adding a methyl ethyl Ethyl ketone peroxide as a catalyst. Other ingredients, such as dry clean sand, perlite, and/or calcium carbonate may be added to the mixture prior to the addition of the catalyst. The resulting composition exhibits superior strength characteristics as a building material.
    Type: Grant
    Filed: September 4, 1986
    Date of Patent: March 8, 1988
    Inventors: Arthur J. Espeland, Theodore R. Stekhuizen
  • Patent number: 4539349
    Abstract: The present invention relates to novel unsaturated polyester compositions and to a process for the preparation thereof. The composition comprises an unsaturated polyester, a reactive solvent for the unsaturated polyester, and at least about 0.5% by weight of a carboxylated cellulose ester. The unsaturated polyester comprises the reaction product of a diacid component which comprises at least about 50% by weight of an ethylenically unsaturated dicarboxylic acid and a diol component. The process of the present invention comprises reacting a diacid component with a diol component so as to form an unsaturated polyester resin, dissolving the unsaturated polyester resin in a solvating quantity of a reactive solvent, the resulting solution further comprising at least about 0.5% by weight of a carboxylated cellulose ester, and curing the solution in the substantial absence of additional initiator so as to form a substantially clear, solid unsaturated polyester composition.
    Type: Grant
    Filed: April 30, 1984
    Date of Patent: September 3, 1985
    Assignee: Eastman Kodak Company
    Inventors: William W. Blount, William M. Robinette
  • Patent number: 4496674
    Abstract: The present invention relates to gasketing materials comprising a rubber binder, a pulverized rice hull filler and a polyester which preferably is crystallizable. The rice hull material acts as a reinforcing filler and, in combination with the rubber and polyester, provides gasketing materials which demonstrate the ability to conform to flange irregularities. As a result, the gaskets demonstrate remarkable sealing capabilities. When they comprise nitrile rubbers, they are also resistant to fuel absorption.
    Type: Grant
    Filed: November 17, 1983
    Date of Patent: January 29, 1985
    Assignee: Armstrong World Industries, Inc.
    Inventors: Wendell A. Ehrhart, Ronald S. Lenox, Moses Sparks, Jr.
  • Patent number: 4352897
    Abstract: A resin molded stator comprising a stator core and coils as major constituents at least parts of which are molded into one piece by a molding material, said molding material comprising (a) a low-shrink unsaturated polyester resin, (b) a filler having a particle size of 44 .mu. or less, and (c) a fibrous material having a length of 3 mm or less, in proportions of 15 to 40% by weight of the component (a) and 60 to 85% by weight of a total of the components (b) and (c), and a weight ratio of the component (b) to the component (c) being 3/1 to 30/1, is excellent in crack resistance, moisture resistance and insulating properties.
    Type: Grant
    Filed: December 14, 1979
    Date of Patent: October 5, 1982
    Assignee: Hitachi, Ltd.
    Inventors: Masatsugu Ogata, Hirokazu Takasaki, Masanori Nemoto, Toshikazu Narahara, Kenichi Hironaka, Tetuo Ishikawa