Abstract: In a method for manufacturing articles in the form of a slab or block, the articles are obtained from an initial mix comprising aggregates and a binder. Synthetic aggregates and fillers have a hardness greater than or equal to 5 Mohs, and contain silicon dioxide substantially only in amorphous form, the silicon dioxide in crystalline form being present in quantities of less than 1% by weight.

Abstract: A process for the production of an article for the cladding of floors or walls, comprising the steps of, in a mold: a) optionally applying a gel coat layer, based on a first curing polymer resin, on the inside of the mold in order to obtain a coated mold, and b) introducing into the core of the mold or into the core of the coated mold from step a) a filling composition which is based on a second curing polymer resin supplemented with at least one mineral filler, wherein core contains at least 5% wt and at most 20% wt of curing polymer resin, relative to the dry amount of filling composition, and the filling composition contains only one single initiator in a concentration of 0.5% wt to 5.0% wt relative to the amount of curing polymer resin in the filling composition.

Abstract: Lead-free radiation shielding material and processes for producing and using the same are described. The radiation shielding comprising a heavy metal component, such as bismuth, and a polymer component while also being optically transparent. The bismuth can be bonded to the polymer component or can be embedded within the matrix of the polymer component without being bonded to the polymer. As well, the bismuth can be nanoparticles that are contained within the matrix of the polymer component without being bonded to the polymer. The bismuth provides a stable, environmentally benign alternative to lead, while blocking the radiation and also being optically transparent. Other embodiments are described.

Abstract: The present invention relates to a synthetic cement that comprises a low viscosity monofunctional monomer, a dicyclopentadienyl moiety having a pendant free radical reactive species, 1,3-butyleneglycol dimethacrylate, unsaturated styrenic block copolymer, and a peroxide curing agent. Additionally it may include weighting agents depending on the circumstances of the well, as is well known to those skilled in the art. Other additional components such as oil based mud, suspending agents, Portland cement, acrylates and methacrylates, retardant curing additives, and clays may optionally be incorporated into the synthetic cement. The synthetic cement is activated by heat, for example, and can be crafted to set within a certain time frame, for example in 4 hours, so that it pumpable for as long as need be, and then be set to seal the well in the manner desired.

Abstract: An anchoring adhesive includes effective amounts of an isocyanurate compound and a vinyl ester compound that react and cure to form a composition having high compressive strength, high tensile strength and low shrinkage. The anchoring adhesive can be used to firmly bond anchor pins to boreholes in concrete, steel, wood, and other substrates.

Abstract: Provided are a resin composition for general-purpose LED reflectors, which discolors little through thermal deterioration and is excellent in heat discoloration resistance, which can provide an LED lamp using it and having a long life, which is relatively inexpensive and has good storage stability, and which is excellent in handleability and workability, and an LED reflector and an LED luminaire using the resin composition.

Abstract: An adhesive, including: at least 100 weight parts of an unsaturated polyester resin suitable for air-drying, between 0 and 5 weight parts of hydrogenated castor oil, between 1 and 20 weight parts of nano powder, between 0 and 100 weight parts of a filler, and between 1 and 15 weight parts of an anti-shrinking agent.

Abstract: A tyre, the tread of which comprises a rubber composition comprising at least: a diene elastomer; from 100 to 150 phr of a reinforcing inorganic filler; a poly(alkylene ester) thermoplastic resin; a plasticizing system comprising: according to a content A of between 5 and 60 phr, a hydrocarbon resin exhibiting a Tg of greater than 20° C.; according to a content B of between 5 and 60 phr, a plasticizer which is liquid at 20° C., the Tg of which is less than ?20° C.; and it being understood that A+B is greater than 40 phr. The use of a poly(alkylene ester) resin, combined in particular with high contents of filler and plasticizers, makes it possible to improve the stiffness of the tread and thus the road behaviour of the tyre, without affecting the hysteresis and thus the rolling resistance.

Abstract: Adhesive composition usable in particular as an adhesion primer, based on a polyisocyanate compound and a polyester or vinyl ester resin comprising (in particular hydroxyl) functional groups which are reactive towards isocyanate groups of said polyisocyanate, the total number of said isocyanate groups being in excess relative to the total number of said functional groups of the polyester or vinyl ester resin. The polyisocyanate compound is preferably a diisocyanate, the resin is preferably an epoxy vinyl ester resin, in particular novolac- and/or bisphenol-based. Said composition is usable, as an adhesion primer, in combination with a secondary adhesion layer preferably based on a polyvinylpyridine/stirene/butadiene elastomer and a polyester or vinyl ester resin.

Abstract: The present disclosure provides a capsulated colorant including a colorant and a polymer resin coating the colorant, wherein the polymer resin is obtained by polymerization of a polymerizable composition including a basic monomer, a macromonomer and a polymerizable unsaturated monomer; a method of preparing the capsulated colorant; and an ink composition including the capsulated colorant.

Abstract: New gel coat composition, in particular new marine gel coat compositions, a process for their manufacture as well as their use to coat surfaces of articles exposed to light, water and solvents. The gel coats incorporate a precipitated silica having A BET surface of from 150 to 250 m2/g A SiO2 content of more than or equal to 98.5% by weight A Na2O content of less than or equal to 0.5% by weight.

Abstract: A hydrogel having a floatability where from 40% to 90% of a solution and/or suspension to be thickened are thickened starting from the surface of the liquid and the rest of the solution and/or suspension to be thickened is thickened starting from the bottom of the container, a process for preparing the hydrogel and also its use for absorbing blood and/or body fluids, especially in hygiene articles, or for thickening aqueous solutions and/or suspensions, especially for thickening medical wastes.

Abstract: Polymeric materials and products, including sheet flooring materials prepared from the polymeric materials, and processes for preparing the polymeric materials, are disclosed. The polymeric materials include a polylactic acid-based polymer in combination with plasticizer and a compatibilizer, and optionally include a filler. The polymeric material can include between about 30 to about 50 percent by weight polyvinyl chloride, polyethylene glycol, polyglycolide, ethylene vinyl acetate, polycarbonate, polycaprolactone, polyhydroxyalkanoates, or polyolefins modified with polar groups, for example, ionomers. The plasticizer is typically an epoxidized vegetable oil or esterified and epoxidized vegetable oil and is typically present in an amount of between about 10 and about 50% by weight. In some embodiments, the compatibilizer is a polyolefin modified with one or more polar functional groups, and is typically present in an amount of between about 5 and about 10% by weight.

Abstract: Polymeric materials and products, including sheet flooring materials prepared from the polymeric materials, and processes for preparing the polymeric materials, are disclosed. The polymeric materials include a polylactic acid-based polymer in combination with plasticizer and a compatibilizer, and optionally include a filler. The polymeric material can include between about 30 to about 50 percent by weight polyvinyl chloride, polyethylene glycol, polyglycolide, ethylene vinyl acetate, polycarbonate, polycaprolactone, polyhydroxyalkanoates, or polyolefins modified with polar groups, for example, ionomers. The plasticizer is typically an epoxidized vegetable oil or esterified and epoxidized vegetable oil and is typically present in an amount of between about 10 and about 50% by weight. In some embodiments, the compatibilizer is a polyolefin modified with one or more polar functional groups, and is typically present in an amount of between about 5 and about 10% by weight.

Abstract: Photocurable luminescent polymers are prepared from thermosetting unsaturated polyesters, suspending fillers, phosphorescent pigments and photocatalysts and utilized to make gel coated articles and molded, cast and fiberglass reinforced plastic (FRP) articles. The luminescent polymers show bright and long-lasting photoluminescent afterglow, strong thermostimulation of afterglow by heat and electroluminescent properties.

Abstract: A cross-linkable polyester resin composition for use with a reinforcing element for reinforcing rock and other structures, comprises: (a) from 10 to 45% of a cross-linkable unsaturated polyester resin, (b) from 40 to 90% of a filter and (c) from 1 to 15% of an ethylenically unsaturated monomer copolymerizable with the polyester, the percentages being by weight based on the total weight of (a), (b) and (c), the composition being solid but permitting insertion and rotation of a reinforcing element to cause mixing of the composition with a cross-linking catalyst to form a hard mass. Composition will cold cure when mixed with catalyst preferably the monomer has higher flash point than styrene. Advantage of the solid composition is that it does not need to be enclosed within frangible sheath as in the prior art.

Abstract: An organoclay composition for gelling unsaturated polyester resin/monomer systems comprising a mineral clay mixture which has been treated with an alkyl quaternary ammonium compound. The mineral clay mixture comprises two components: mineral clay (a) comprising greater than 50 wt. %, based on the weight of the mineral clay mixture, of a mineral clay selected from the group consisting of sepiolite, palygorskite and mixtures of sepiolite and palygorskite; and mineral clay (b) comprising less than 50 wt. %, based on the weight of the mineral clay mixture, of a smectite.

Abstract: A composition is provided which comprises a first component, a second component, and a compressible substance in which the first component comprises a peroxide, a liquid which comprises water, and a solid particulate; and the second component comprises a polymer, a crosslinking agent, and a solid particulate. The composition can further comprises a sugar. Also disclosed is a process that can be used for preventing a grouting composition from becoming limp. The process comprises combining a grouting composition with a compressible substance in which the composition comprises a first component and a second component as disclosed above.

Abstract: An organoclay composition for gelling unsaturated polyester resin/monomer systems comprising a mineral clay mixture which has been treated with an alkyl quaternary ammonium compound. The mineral clay mixture comprises two components; mineral clay (a) comprising greater than 50 wt. %, based on the weight of the mineral clay mixture, of a mineral clay selected from the group consisting of sepiolite, palygorskite and mixtures of sepiolite and palygorskite; and mineral clay (b) comprising less than 50 wt. %, based on the weight of the mineral clay mixture, of a smectite.

Abstract: This invention provides a particulate composite comprising a polyester resin, a plasticizer, and a plurality of cenospheres. The polyester resin and the plasticizer form a matrix wherein the cenospsheres are distributed nonhomogeneously in the matrix. The nonhomogenous distribution of cenospheres further comprises a continuously varying particle volume fraction along a single dimension.

Abstract: Provided are curable coating compositions comprised of any of a variety of film-forming polymers containing reactive functional groups, a curing agent containing functional groups which are reactive with the functional groups of the polymer, and an exfoliated silicate material derived from a layered silicate which has been exfoliated with a polymer which is compatible with both the film-forming polymer and the curing agent. The inclusion of the exfoliated silicate material enhances coating properties such as adhesion, appearance, crater resistance, and rheology control.

Abstract: The invention relates to a method for preparing a nanocomposite material based on a polymeric matrix and a layered double hydroxide, comprising the steps of: a) providing a layered double hydroxide which contains an amount of anions of at least 20%, based on the total number of anions of the layered double hydroxide, which anions are compatible and/or reactive with the polymeric matrix: b) mixing the layered double hydroxide with a monomeric material for forming the polymeric matrix, in an amount such that the polymeric matrix is present in the nanocomposite material in an amount of at least 50% by weight, based on the nanocomposite material; c) polymerizing the monomeric material to form the polymeric matrix. The invention further relates to a nanocomposite material obtainable by such method and to a shaped article manufactured from such nanocomposite material.

Abstract: The invention relates to a nanocomposite material based on a polymeric matrix and a layered double hydroxide, wherein the polymeric matrix is present in an amount of at least 50% by weight, based on the nanocomposite material, and wherein the layered double hydroxide contains an amount of anions of at least 20%, based on the total number of anions of the layered double hydroxide, which anions are compatible and/or reactive with the polymeric matrix, and wherein at least 5% of the above amount of anions contain a second charge-carrying group. The invention further relates to a method for preparing such a nanocomposite material and to a shaped article from such a nanocomposite material.

Abstract: A method for repairing, filling and fabricating including the steps of providing a resin containing fiberglass; providing a polyester body fill material; providing a fiber strand body filler; mixing the resin, polyester body fill material and fiber strand body filler at room temperature to form a first mixture; providing a liquid clear fiberglass resin hardener; mixing the liquid clear fiberglass resin hardener with the first mixture at room temperature to form a first composition; providing a cream body filler hardener; and mixing the cream body filler hardener with the first composition at room temperature to form a second composition, the second composition having a putty-like consistency.

Abstract: A resin concrete composition and its molded article are provided, the resin concrete, even with a reduced resin content, having an excellent flowability, which is an important property in a molding operation, and necessitating no shrinkage reduction agent, and the molded article having no cracks and being highly strong. The resin concrete composition comprises (A) a resin composition containing (a) an unsaturated polyester of an unsaturated acid, a di- and/or trialkylene glycol, and dicyclopentadiene and (b) a polymerizable unsaturated monomer, (B) an aggregate, and (C) a filler.

Abstract: Luminescent polymers are prepared from thermosetting unsaturated polyesters, suspending fillers and phosphorescent pigments and utilized to make gel coated articles and molded, cast and fiberglass reinforced plastic (FRP) articles. The luminescent polymers show bright and long-lasting photoluminescent afterglow, strong thermostimulation of afterglow by heat and electroluminescent properties. The preferred thermosetting unsaturated polyester resins are prepared by condensing mixtures of ethylenically unsaturated and aromatic dicarboxylic acids and anhydrides with dihydric alcohols and a polymerizable vinylidene monomer. Phthalic (orthophthalic) and isophthalic aromatic modified polyesters and their substituted derivatives are preferred, particularly those formed from maleate or fumarate unsaturated dicarboxylic acids and anhydrides and a glycol or mixtures of glycols. The preferred monomer is styrene.

Abstract: A substrate with an organic undercoat as bonding layer for a printing medium to be deposited subsequently on the substrate in a printing process is such that the organic undercoat contains fine grained constituents of organic and/or inorganic substances, whereby the surface of the inorganic constituents is treated or provided with a coating of organic substances. Suitable inorganic constituents are e.g. highly dispersed silica, the surface of which is treated with a resin or a polymer. Suitable compositions for the organic undercoat layer on the substrate are organic coatings based on many commercially available organic coating materials with an addition of e.g. 0.3 to 20 wt. % silica. By adding highly dispersed silica to the undercoat the adhesion between the undercoat and the printing medium can be greatly improved, also in the case of laser printing methods with small thermal energy.

Abstract: When small amounts of zeolite or titanosilicates are added to thermotropic liquid crystalline aromatic polyester, poly(ester-amide) or poly(ester-imide) compositions, the compositions become less flammable. In many cases addition of the zeolite or titanosilicates does not significantly affect other properties of the composition, which may be used as molding resins, for instance to make parts useful in the electrical, electronic or automotive industry.

Abstract: The present invention relates to a gel comprising A) a solution of at least one organic peroxide essentially solubilized in a phlegmatizer, B) at least one cellulose ester as thickening agent essentially solubilized in solution A, and C) at least one thixotropic agent selected from hydrogenated castor oil and fumed silica. These gels offer the advantages of essentially no phase segregation during storage, essentially no formation of solid crystals during storage, and easy metering into thermoset resins because of their thixotropic behavior. Furthermore, these gels may be transparent, with the advantage that brightly colored gels may be prepared therefrom.

Abstract: A coarse particle kaolin clay is provided having an average Stokes equivalent particle diameter of about 4.5-6.0 microns, a BET surface area of about 8-11 m.sup.2 /g, and preferably having a median Malvern particle size of about 9.0-10.5 microns as determined by laser light-scattering measurement and a high aspect ratio preferably of about 12-14 as determined by Sphericity Model calculations. The coarse particle kaolin clay provides low viscosity build, good reinforcement properties and excellent surface finish qualities as a filler in thermoset composite materials, such as polyester molding compounds, and also provides excellent pigmenting properties in paints and industrial coatings.

Abstract: This invention relates to a process of forming a polymeric nanocomposite comprising a continuous polymeric phase formed from a melt processible polymer having amelt processing temperature equal to or greater than about 220.degree. C. and platelet particles having an average thickness equal to or less than about 50 .ANG. and a maximum thickness of about 100 .ANG. having a secondary or primary ammonium cationic complex, a quaternary phosphonium cationic complex bonded to surface of said particles, the composite material formed by said process and an article formed from the composite material.

Abstract: A plugging compound for chemical fastening technology is based on a free-radically polymerizable resin and a free-radical initiator spatially separated therefrom. The plugging compound in question is a self-supporting and storage-stable material which can be inserted in that form directly into a drill-hole.

Abstract: This invention involves a method of optically whitening clay minerals to transform their natural yellow tint to increased whiteness. Generally, it has been found that clay materials having low cation exchange capability can be directly reacted with very small amounts of cationic dyes, the apparent whiteness of said clay minerals being substantially increased thereby.

Abstract: A molding composition comprises a) an unsaturated polyester resin, b) a copolymerizable olefinically unsaturated monomer, c) a pigment, d) fiber reinforcement and e) a poly(vinyl ether) polymer with a weight average molecular weight of at least 50,000 to control shrinkage and promote the uniform distribution of the pigment in the molding composition.

Abstract: This invention involves a method of optically whitening clay minerals to transform their natural yellow tint to increased whiteness. Generally, it has been found that clay materials having low cation exchange capability can be directly reacted with very small amounts of cationic dyes, the apparent whiteness of said clay minerals being substantially increased thereby.

Abstract: The invention relates to oxide particles which have a surface modification by covalently bonded organic groups which allow covalent bonding into polymer materials. These particles are particularly advantageous in their use as fillers or modifying agents in polymer materials, in particular polymer films.

Abstract: Filled, thermoplastic-modified thermosetting polyester resin formulations are provided as encapsulants for microelectronics devices. The polyester encapsulant formulations include either a low profile thermoplastic resin additive or a combination of polyethylene and a low shrink thermoplastic additive. In preferred embodiments the polyester encapsulant formulations are of low viscosity and can be utilized in various pressure molding protocols. The encapsulant matrix is characterized by a low coefficient of thermal expansion, very low shrinkage, low modulus, and good thermal conductivity. Microelectronics devices encapsulated with the polyester resin formulation exhibit good resistance to moisture related and stress-induced failure.

Abstract: The improved thermotropic LCP composition comprises 10-13 wt % of a thermotropic liquid crystal polymer resin and 90-87 wt % of zircon and is useful as an electrical insulator. The composition is a good electrical insulator, permits good heat conduction and experiences small thermal expansion, thus insuring high reliability. The composition may be injection molded to form an electrically insulated housing of a stator for electric machines or appliances that includes a coil and terminals thereof.

Abstract: An unsaturated polyester resin characterized by high performance electrical, physical and mechanical properties and useful in the electronic and microwave industries, and a process for preparing such a resin.

Abstract: The unsaturated polyester resin molding composition of the invention comprising an unsaturated polyester, a vinyl monomer, a stabilizer, a thermoplastic resin, an organic peroxide, a fluidity modifier, a thickening agent, a filler and a fibrous reinforcement material possesses curability at low temperatures of about 50.degree. to 120.degree. C., good fluidity and filling property on the occasion of molding at low pressures of about 0.1 to 20 kgf/cm.sup.2, and good storage stability at room temperature.

Abstract: Electrical insulators having a high tracking resistance are obtained from a highly filled polymerizable composition, by injection molding said composition within a short period of time as low as 5 minutes, said composition containing an amount of up to 96% by weight of an improved filler which comprises, based on the total composition, from about 40 to about 52% by weight of silica sand having a particle size such that no less than about 70% by weight of the particles are retained on a 60 mesh U.S. standard sieve and no more than about 30% by weight of the particles are retained on a 40 mesh U.S. standard sieve, an amount of from about 23 to about 36% by weight of silica sand having a particle size such that no less than about 80% by weight of the particles are retained on a 325 mesh U.S. standard sieve and no more than about 11% by weight of the particles are retained on a 200 mesh U.S.

Abstract: A resin composition including a modified acrylic unsaturated polyester resin composition comprising a maleic dicyclopentadienyl glycol polyester which is dissolved in a mixture of styrene monomer and methylmethacrylate monomer. The maleic dicyclopentadienyl glycol polyester is the reaction product of a glycol or mixture of glycols, an ethylenically unsaturated polycarboxylic acid moiety and dicyclopentadiene. The glycol utilized as a reactant preferably has a structure defined by: H--(OCHR--CH.sub.2).sub.n --OH wherein R is H or CH.sub.3 and n is 1-10. The concentration of unsaturated polyester is preferably about 40 weight percent to about 75 weight percent in the resin composition. The concentration of styrene monomer ranges from about 5 weight percent to about 40 weight percent, while the concentration of methylmethacrylate monomer ranges from about 5 weight percent to about 45 weight percent.

Abstract: An artificial marble formed by molding a material, in which said material comprises an unsaturated polyester, an unsaturated polymerizable monomer, and a filler. The unsaturated polyester consists essentially of an acid component and an alcohol component, wherein said alcohol component contains at least a glycol selected from a group consisting of 2-methylpropane-1,3-diol, 3-methylpentane-1,5-diol, 3-methyl-2-pentene-1,5-diol, 2-isopropylidene-1,3-propanediol, 2-isopropyl-1,3-propanediol, and 2-methylene-1,3-propanediol.

Abstract: An unsaturated polyester resin characterized by high performance electrical, physical and mechanical properties and useful in the electronic and microwave industries, and a process for preparing such a resin.

Abstract: A coating composition for use in a hydrophilic treatment comprising (A) an organic-inorganic composite reaction product prepared by a process which comprises reacting 100 parts by weight, as the solid content, of (i) a water-dispersible silica with 0.

Abstract: A curable adhesive composition is disclosed, comprising a polymerizable prepolymer, a reactive diluent, and a polymerization initiator, wherein said composition further comprises an inorganic filler and/or a (meth)acrylate having an isocyanurate ring.The adhesive composition of the invention is curable by the action of heat or light and is extremely useful as an adhesive for surface mounting devices.

Abstract: The invention relates to novel suppressants for unsaturated polyester styrenated resins resulting in lower emission of volatile compounds in the production of the polyester resins.

Abstract: A family of novel and unique synthetic alkali metal alumino-silicates (SAMS) are produced by the hydrothermal reaction between kaolin and alkali metal silicates. The integrated composition of the SAMS products is a unique entity having an overall composition ofxM.sub.2 O:Al.sub.2 O.sub.3 :ySiO.sub.2 :zH.sub.2 Owhere x is the number of moles of alkali metal oxide and is an integer from 0.01 to 2.0, M is the alkali metal, y is the number of moles of SiO.sub.2 in the unique SAMS compositions and is an integer greater than 2.0, and z is the number of moles of bound water and is an integer ranging from 1.0 to 5.0. The unique SAMS compositions are structured materials in which the structure can be controlled, and are therefore useful as functional fillers, as TiO.sub.2 extenders, as silica extenders or as reinforcing agents for paper, paint, rubber, plastics and specialty products.

Abstract: Stable, low-evaporation unsaturated polyester resins contain an ethylenically unsaturated polyester, styrene as comonomer, paraffins for preventing styrene evaporation and a pyrogenic silica with both hydrophilic and hydrophobic end groups.

Abstract: New shrinkage control agents, for unsaturated polyester resin systems, which are copolymers of vinyl versatate and vinyl acetate, i.e., poly(vinyl versatate-co-vinyl acetate). The shrink control agents are useful both with neat and filled unsaturated polyester resin systems. The shrink control agents are especially useful under conditions where the unsaturated polyester resin system is cured at or below ambient temperatures.