Glass Dnrm Patents (Class 523/527)
  • Patent number: 4496688
    Abstract: Unsaturated polyester or polyesteramide compositions containing an unsaturated polyester/polyesteramide or mixture thereof, an ethylenically unsaturated monomer, and a dicyclopentadiene ester of an unsaturated polycarboxylic acid are prepared and used to cure resin compositions. The resin compositions have improved resistance to heat aging, reduced shrinkage upon curing, and improved corrosion resistance with excellent mechanical properties.
    Type: Grant
    Filed: March 21, 1983
    Date of Patent: January 29, 1985
    Assignee: The Dow Chemical Company
    Inventor: Robert E. Hefner, Jr.
  • Patent number: 4489184
    Abstract: This invention discloses a creep resistant thermoset molding composition which is of particular value as a material from which wheels can be made. The creep resistant molding composition of this invention is comprised of a mixture of a vinyl ester resin and a dicyclopentadiene polyester resin.
    Type: Grant
    Filed: September 26, 1983
    Date of Patent: December 18, 1984
    Inventor: James A. Woelfel
  • Patent number: 4487863
    Abstract: Amino substituted acrylamide monomer is utilized as a coupling agent for reinforcing fibers and polyester base resin matrix in the production of thermosetting resin systems to enhance the bonding characteristics of the resin with the fiber while improving the flexural strength of the final composite structure.
    Type: Grant
    Filed: November 22, 1982
    Date of Patent: December 11, 1984
    Assignee: Great Lakes Carbon Corporation
    Inventor: John C. Goan
  • Patent number: 4483949
    Abstract: Thermoplastic compositions comprising, in intimate admixture, polyethylene terephthalate, a rubber-free copolymer of or a rubber-modified graft copolymer of a vinyl aromatic compound and an .alpha.,.beta.-unsaturated cyclic anhydride, a fibrous modifier, and a nucleating agent are disclosed. These compositions display desirable properties, particularly elevated heat deflection temperatures and good surface appearance.Also disclosed is a process for producing articles by injection molding the compositions at a hold pressure of about 5,000 to about 10,000 psi.
    Type: Grant
    Filed: August 22, 1983
    Date of Patent: November 20, 1984
    Assignee: Ethyl Corporation
    Inventors: John Semen, Jesse D. Jones, Edwin D. Hornbaker
  • Patent number: 4483963
    Abstract: Storage stable, polyester based compositions well adapted for hardening into molded shaped articles exhibiting virtually no shrinkage, are comprised of (i) an unsaturated polyester, (ii) a polymerizable, ethylenically unsaturated monomer copolymerizable therewith, (iii) an oligoester of the formula: ##STR1## and (iv) a condensate of such oligoester (I) with an unsaturated polyester.
    Type: Grant
    Filed: June 22, 1983
    Date of Patent: November 20, 1984
    Assignee: Chloe Chimie
    Inventor: Jacques Meyer
  • Patent number: 4476274
    Abstract: High molecular weight thermoplastic polyesters and polyester blends having unexpected improved impact strength by incorporating therein linear low density polyethylene and glass fibers.
    Type: Grant
    Filed: January 3, 1983
    Date of Patent: October 9, 1984
    Assignee: General Electric Company
    Inventor: Nan-I Liu
  • Patent number: 4465808
    Abstract: A thermosetting molding composition containing unsaturated polyester and carboxy-containing rubber exhibit improved surface gloss of molded articles when the composition further contains an unsaturated ester/potassium salt of phosphoric acid, such as potassium oleyl phosphate.
    Type: Grant
    Filed: June 24, 1983
    Date of Patent: August 14, 1984
    Assignee: Phillips Petroleum Company
    Inventor: James S. Dix
  • Patent number: 4443580
    Abstract: The corrosion resistance of dicyclopentadiene (DCPD) modified unsaturated polyester or DCPD modified unsaturated polyesteramide resins can be improved by replacing a part of the styrene used as a reactant diluent in the resin with materials, such as divinylbenzene.
    Type: Grant
    Filed: August 25, 1982
    Date of Patent: April 17, 1984
    Assignee: The Dow Chemical Company
    Inventor: Robert E. Hefner, Jr.
  • Patent number: 4435530
    Abstract: Heat resistant resin compositions are prepared containing unsaturated polyester resins or polyesteramide resins terminated with a norbornene type group, an ethylenically unsaturated group, and a dicyclopentadiene ester of an unsaturated polycarboxylic acid.
    Type: Grant
    Filed: October 22, 1982
    Date of Patent: March 6, 1984
    Assignee: The Dow Chemical Company
    Inventor: Robert E. Hefner, Jr.
  • Patent number: 4417011
    Abstract: A resin composition for bonding of foundry sand, said composition comprising as a resin component a crystalline unsaturated polyester being solid and substantially tack-free at room temperature and having an acid value of 15 to 100, said unsaturated polyester being prepared by polymerizing (A) a dicarboxylic acid component containing 10 to 50 mole % of terephthalic acid, an alkyl terephthalate, isophthalic acid or an alkyl isophthalate and 50 to 90 mole % of fumaric acid and (B) a glycol component containing at least 90 mole % of ethylene glycol, trimethylene glycol, neopentyl glycol, hydrogenated bisphenol A or 2,2-d-(4-hydroxypropoxyphenyl)propane.
    Type: Grant
    Filed: April 1, 1983
    Date of Patent: November 22, 1983
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Koue Ohkawa, Shin Fujii, Takashi Seino
  • Patent number: 4413072
    Abstract: Unsaturated polyester resins containing--as additive--polyesterurethanes having free carboxyl groups and/or terminal radically polymerizable double bonds are good starting materials for manufacturing moulded articles with outstanding properties, particularly with an excellent impact strength.
    Type: Grant
    Filed: June 9, 1981
    Date of Patent: November 1, 1983
    Assignee: Bayer Aktiengesellschaft
    Inventors: Bernhard Hess, Hansjochen Schulz-Walz, Hannes von Harpe, Bernd Peltzer, Ludwig Bottenbruch
  • Patent number: 4409344
    Abstract: A low shrink unsaturated polyester based upon propylene glycol terephthalate reacted with a dibasic acid or anhydrides thereof and glycols and mixing the polyester with a filler, fibrous reinforcing agent and catalyst.
    Type: Grant
    Filed: June 23, 1981
    Date of Patent: October 11, 1983
    Assignee: Cargill Incorporated
    Inventors: Thomas J. Moulson, John E. Greenzweig
  • Patent number: 4396676
    Abstract: Cocoa amine acetate and a polyamide condensate, in combination as a lubricant in a glass size, result in glass strands exhibiting less fuzz than does glass sized with a size containing either of the two components, individually.
    Type: Grant
    Filed: August 30, 1982
    Date of Patent: August 2, 1983
    Assignee: Owens-Corning Fiberglas Corporation
    Inventors: Robert C. Brannon, Leonard J. Adzima, Timothy W. Ramey
  • Patent number: 4383091
    Abstract: Curable polymeric products are the reaction product of a polymer containing secondary hydroxyl groups and an aliphatic unsaturated isocyanate.
    Type: Grant
    Filed: July 1, 1982
    Date of Patent: May 10, 1983
    Assignee: The Dow Chemical Company
    Inventor: Bruce L. Burton
  • Patent number: 4378402
    Abstract: A composition for producing surface layers on wood or other substrates is formed from diatomite, expanded perlite, chopped glass fibers and a thermosettable resin mixed in specified amounts to provide a flowable mixture. When applied to the substrate as a layer about 1 to 2 cms. thick and the resin component has cured, a tough, impact-resistant, watertight surface is created on the substrate. The new compositions and surfacing methods are particuarly useful for refinishing the hulls of wooden boats.
    Type: Grant
    Filed: November 5, 1981
    Date of Patent: March 29, 1983
    Inventor: Charles Below
  • Patent number: 4374215
    Abstract: The addition of a select group of crosslinkable vinyl monomers to low shrinking polyester molding compositions containing unsaturated polyesters results in moldings with improved surface characteristics.
    Type: Grant
    Filed: October 16, 1980
    Date of Patent: February 15, 1983
    Assignee: Union Carbide Corporation
    Inventor: Kenneth E. Atkins
  • Patent number: 4370428
    Abstract: Polyester and hardener compositions have incorporated therein pigments of Toluidine Red Y and Parachlor R to enable the user to determine when mixing is uniform and when the cure has been completed.
    Type: Grant
    Filed: October 17, 1980
    Date of Patent: January 25, 1983
    Inventor: Carlos R. Danville
  • Patent number: 4367315
    Abstract: An improved fire retardant polyester polymer system and composition comprising an interpolymer of a reaction product of hexachlorocyclopentadiene, a polyhydric alcohol, a carboxylic acid containing aliphatic carbon-to-carbon unsaturation, a styrene-type monomer, maleic acid or anhydride and a copolymerizable brominated neopentylacrylate comonomer.
    Type: Grant
    Filed: January 29, 1981
    Date of Patent: January 4, 1983
    Assignee: Occidental Chemical Corporation
    Inventors: Paul Zwaenepoel, Guido Strzelbicki, Daniel J. Scharf, George M. Wagner
  • Patent number: 4363889
    Abstract: Disclosed is an anti-corrosive coating composition comprising (a) 100 parts by weight of an unsaturated polyester resin, (b) 10 to 100 parts by weight of a glass flake having an average thickness of 0.5 to 5 microns and an average particle size of 100 to 400 microns, or 10 to 70 parts by weight of said glass flake and 10 to 150 parts of scaly metal pigment, (c) 0.1 to 1.0 part by weight of a ketone peroxide and (d) 0.5 to 2.0 parts by weight of a hydroperoxide and/or a peroxy ester. Also disclosed is a process for forming anti-corrosive coatings, which comprises spray-coating the above anti-corrosive coating composition to a thickness of 300 to 1500 microns by using a spray gun having a spray tip diameter of 0.5 to 3 mm.
    Type: Grant
    Filed: October 28, 1980
    Date of Patent: December 14, 1982
    Assignee: Dai Nippon Toryo Co., Ltd.
    Inventors: Minoru Hoshino, Tosio Shinohara, Hiroyuki Tanabe, Tooru Taki, Shunsuke Nakayama
  • Patent number: 4352897
    Abstract: A resin molded stator comprising a stator core and coils as major constituents at least parts of which are molded into one piece by a molding material, said molding material comprising (a) a low-shrink unsaturated polyester resin, (b) a filler having a particle size of 44 .mu. or less, and (c) a fibrous material having a length of 3 mm or less, in proportions of 15 to 40% by weight of the component (a) and 60 to 85% by weight of a total of the components (b) and (c), and a weight ratio of the component (b) to the component (c) being 3/1 to 30/1, is excellent in crack resistance, moisture resistance and insulating properties.
    Type: Grant
    Filed: December 14, 1979
    Date of Patent: October 5, 1982
    Assignee: Hitachi, Ltd.
    Inventors: Masatsugu Ogata, Hirokazu Takasaki, Masanori Nemoto, Toshikazu Narahara, Kenichi Hironaka, Tetuo Ishikawa
  • Patent number: 4338242
    Abstract: Curable polymeric products are the reaction product of a polymer containing secondary hydroxyl groups and an aliphatic unsaturated isocyanate.
    Type: Grant
    Filed: September 19, 1980
    Date of Patent: July 6, 1982
    Assignee: The Dow Chemical Company
    Inventor: Bruce L. Burton
  • Patent number: 4338231
    Abstract: An asphalt-modified polyester composition comprising an asphalt which has first been reacted with a polycarboxylic acid or anhydride and a polyalcohol; the modified asphalt is then reacted with a polyester and a vinyl aromatic monomer to produce a molding composition which is ideally suited for combination with a glass fiber reinforcement in the molding of rigid bodies reinforced with, for example, glass fibers.
    Type: Grant
    Filed: October 27, 1980
    Date of Patent: July 6, 1982
    Assignee: Owens-Corning Fiberglas Corporation
    Inventors: Alfred Marzocchi, Charles E. Bolen, Edward R. Harrington, Michael G. Roberts
  • Patent number: 4327145
    Abstract: A process for producing an easily handleable sheet molding compound which comprises impregnating glass fibers with a resin composition comprising (A) an unsaturated polyester having a hydroxyl value of 20 to 55 and an acid value of 5 to 20 with a hydroxyl value/acid value ratio of from 1.7 to 10, (B) a polymerizable monomer and (C) a polyisocyanate compound having not more than 20 carbon atoms excepting the carbon atoms of the isocyanate groups and selected from the group consisting of diisocyanates and polymethylenepolyphenyl isocyanates, the proportions of the unsaturated polyester (A) and the polyisocyanate compound (C) being such that the mole ratio of the hydroxyl groups of the unsaturated polyester (A) to the isocyanate groups of the polyisocyanate compound (C) is from 0.7 to 1.
    Type: Grant
    Filed: August 6, 1980
    Date of Patent: April 27, 1982
    Assignee: Dainippon Inc. & Chemicals, Inc.
    Inventors: Tomomasa Mitani, Yoshimi Ogasawara, Shunichi Hiraishi
  • Patent number: 4322333
    Abstract: A thermoplastic molding composition having improved impact strength is provided, the composition comprising a thermoplastic resin selected from (i)a poly(1,4-butylene terephthalate)in combination with a poly(ethylene terephthalate)resin, mineral-filled, or (ii) a poly(1,4-butylene terephthalate) co-aromatic/aliphatic polyester, reinforced and/or mineral-filled, and a minor, effective amount of a copolymer of ethylene and vinyl acetate or a terpolymer of ethylene, vinyl acetate and methacrylic and/or acrylic acid.
    Type: Grant
    Filed: November 5, 1979
    Date of Patent: March 30, 1982
    Assignee: General Electric Company
    Inventors: John E. Kochanowski, Allen D. Wambach