Aryl Group Patents (Class 524/125)
  • Patent number: 10800915
    Abstract: A polycarbonate composition includes the following components in parts by weight: a. 30 to 87 parts of a PC resin; b. 8 to 50 parts of a rubber-modified graft polymer; c. 5 to 25 parts of a fire retardant; and d. 0 to 10 parts of other aids; wherein a sum of parts by weight of the four components a, b, c, and d is 100. Phenols which are added in a polycarbonate composition formula, based on a total weight of the polycarbonate composition does not exceed 100 ppm. A K value of a component I of the PC resin is adjusted between 300000 and 500000 and the K value of a component II is adjusted to be less than 300000.
    Type: Grant
    Filed: May 27, 2016
    Date of Patent: October 13, 2020
    Assignee: KINGFA SCI. & TECH. CO., LTD.
    Inventors: Zhengyu Tian, Donghai Sun, Yin Cen, Wei Tong, Xiang Xie, Xianwen Liu
  • Patent number: 10717931
    Abstract: Embodiments described herein are directed to oligomeric phosphonates and polyphosphonates that have non-reactive end groups, methods for making such oligomeric phosphonates and polyphosphonates, and compositions containing such oligomeric phosphonates and polyphosphonates. The oligomeric phosphonates and polyphosphonates of such embodiments may be incorporated into engineering polymeric into which they are mixed to make polymer compositions having good flame retardancy and mechanical properties.
    Type: Grant
    Filed: January 5, 2018
    Date of Patent: July 21, 2020
    Assignee: FRX POLYMERS, INC.
    Inventors: Jan-Pleun Lens, Lawino Kagumba
  • Patent number: 9670362
    Abstract: The present invention relates to a thermoset resin composition, and a prepreg and a laminate for a printed circuit board manufactured therefrom. The thermoset resin composition comprises the following components: a phosphorus-containing polyphenyl ether resin having low molecular weight, an epoxy resin, a cyanate resin and an accelerator. The prepreg manufactured using the resin composition comprises a base material and the thermoset resin composition adhered to the base material by impregnation and drying. The laminate for a printed circuit board manufactured using the resin composition comprises a plurality of laminated prepregs, a metal foil covering one or two faces of the laminated prepregs by pressing, with each prepreg comprising a base material and the thermoset resin composition adhered to the base material by impregnation and drying.
    Type: Grant
    Filed: December 29, 2011
    Date of Patent: June 6, 2017
    Assignee: SHENGYI TECHNOLOGY CO., LTD.
    Inventors: Yundong Meng, Kehong Fang
  • Patent number: 9527998
    Abstract: Flame retardant compositions that include a thermoplastic polyurethane, a metal hydrate flame retardant and a phosphorus-based flame retardant are provided. The compositions are characterized by good flame retardant properties, as well as high insulation resistance.
    Type: Grant
    Filed: October 28, 2009
    Date of Patent: December 27, 2016
    Assignee: DOW GLOBAL TECHNOLOGIES LLC
    Inventors: Lan Lu, Given Jing Chen, Xiaowei Wilson Yan, Bin Li, Weiming Wayne Ma
  • Patent number: 9318240
    Abstract: Halogen-free, flame retardant compositions comprising in weight percent based on the weight of the composition: A. 20 to 60% TPU/Si-g-EVA polymer blend in which the Si-g-EVA is crosslinked, B. 1 to 25% organic phosphate ester, C. 30 to 60% metal hydrate, and D. 0.1 to 10% epoxidized novolac. Optionally, the compositions further comprise in weight percent based on the weight of the composition, one or more of: E. 0.01 to 0.5% anti-dripping agent, F. 0.1 to 2% additive; and G. 0.1 to 5% filler.
    Type: Grant
    Filed: May 24, 2010
    Date of Patent: April 19, 2016
    Assignee: Dow Global Technologies LLC
    Inventors: Wilson Xiao Wei Yan, Given Jing Chen, Lotus Hua Huang, David Hong Fei Guo
  • Publication number: 20150141556
    Abstract: Certain phosphonic acid salts heated at temperatures over 200° C. generate thermally stable, highly efficient flame retardant materials well suited for use as flame retardant additives in polymers. Various methods for preparing flame retardant materials from more than one phosphonic acid salts are provided, wherein each method can generate different flame retardant materials from the same mixture of starting phosphonic acids. The flame retardants of the invention can be used as the sole flame retardant in a composition or in combination with other flame retardants, synergists or adjuvants.
    Type: Application
    Filed: January 8, 2015
    Publication date: May 21, 2015
    Inventors: Zachary Stockdale, Mark V. Hanson, Larry D. Timberlake, Subramaniam Narayan, William R. Fielding
  • Publication number: 20140371359
    Abstract: A recycled resin composition includes polystyrene collected from wasted home electric appliances in an amount of from 51 to 84% by weight, unused polystyrene in an amount of from 11 to 39% by weight, an impact modifier in an amount of from 2 to 4% by weight, and a phosphorous flame retardant in an amount of from 6 to 19% by weight.
    Type: Application
    Filed: June 6, 2014
    Publication date: December 18, 2014
    Applicant: RICOH COMPANY, LTD.
    Inventors: Yasushi Akiba, Tadakatsu Harada
  • Patent number: 8901216
    Abstract: The present invention relates to impact-modified polyester/polycarbonate compositions containing: A) 41 to 80 parts by weight, in each case relative to the sum of the parts by weight of components A+B+C+D, of aromatic polycarbonate, B) 5 to 40 parts by weight, in each case relative to the sum of the parts by weight of components A+B+C+D, of polyester with a content of isophthalic acid building blocks, C) 1 to 15 parts by weight, in each case relative to the sum of the parts by weight of components A+B+C+D, of rubber-modified graft polymer, D) 0 to 25 parts by weight, in each case relative to the sum of the parts by weight of components A+B+C+D, of a flame retardant, E) 0 to 20 parts by weight, in each case relative to the sum of the parts by weight of components A+B+C+D=100, of vinyl (co)polymer, F) 0 to 50 parts by weight, in each case relative to the sum of the parts by weight of components A+B+C+D=100, of additives, wherein all the stated parts by weights in the present application are normalized such that
    Type: Grant
    Filed: August 22, 2011
    Date of Patent: December 2, 2014
    Assignee: Bayer MaterialScience AG
    Inventors: Achim Feldermann, Eckhard Wenz
  • Patent number: 8865342
    Abstract: Provided a polycarbonate resin composition excellent in flame resistance, impact resistance, and color fastness. A polycarbonate resin composition containing, per 100 parts by mass of polycarbonate resin (A), 0.001 to 30 parts by mass of flame retardant (B), 0.001 to 1 part by mass of fluoropolymer (C), and 0.5 to 10 parts by mass of graft copolymer (D) obtainable by graft-copolymerizing a diene-based rubber with a (meth)acrylate ester compound, the graft copolymer (D) having (i) a sulfur content of 100 to 1500 ppm, and (ii) an average particle size of 70 to 240 nm.
    Type: Grant
    Filed: November 15, 2011
    Date of Patent: October 21, 2014
    Assignee: Mitsubishi Engineering-Plastics Corporation
    Inventors: Toshiki Monden, Yutaka Shiraishi
  • Publication number: 20140308505
    Abstract: The invention relates to the use of polyphosphonates, copoly(phosphonate ester)s, copoly(phosphonate carbonate)s, and their respective oligomers, as flame retardant additives for polyamide fibers to impart fire resistance while maintaining or improving processing characteristics for melt spun fibers and fabrics, thereof.
    Type: Application
    Filed: April 3, 2014
    Publication date: October 16, 2014
    Inventor: Thomas Edward SCHMITT
  • Publication number: 20140299907
    Abstract: Polymer compositions are described that are well suited for producing reflectors for light-emitting devices, such as light-emitting diodes. In one embodiment, the polymer composition contains a polymer resin and a stabilizer comprising a phosphonate compound and/or a phosphate compound and optionally a white pigment. The polymer resin may comprise, for instance, a poly(1,4-cyclohexanedimethanol terephthalate). The phosphate stabilizer has been found to significantly improve the stability of the polymer composition without interfering with the ability of the composition to bond to other polymer materials, such as silicone resins. Silicone resins, for instance, are typically used as an encapsulant for light-emitting diode assemblies.
    Type: Application
    Filed: April 5, 2012
    Publication date: October 9, 2014
    Applicant: Ticona LLC
    Inventor: Bing Lu
  • Publication number: 20130126217
    Abstract: Disclosed is an epoxy resin composition comprising: (A) a polymerized compound including, as structural components, phosphaphenanthrene and at least one constituent selected from a structural unit of a phenolic novolak polymer and a structural unit of a phenolic novolak polymer in which a hydrogen atom of a phenolic hydroxyl group is substituted by phosphaphenanthrene; (B) an epoxy resin having two or more epoxy groups in a molecule; and (C) a curing agent that cures the epoxy resin.
    Type: Application
    Filed: April 19, 2011
    Publication date: May 23, 2013
    Applicant: PANASONIC CORPORATION
    Inventors: Mao Yamaguchi, Tetsuya Arisawa, Syunji Araki, Keiko Kashihara, Takashi Sagara, Lin Lin
  • Patent number: 8258221
    Abstract: A polylactic acid-based resin composition includes (A) a polylactic acid-based resin; (B) a flame retardant compound; and (C) an ammonium compound of organic acid.
    Type: Grant
    Filed: August 9, 2010
    Date of Patent: September 4, 2012
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Kenji Yao, Masaya Ikuno, Masayuki Okoshi
  • Publication number: 20120053271
    Abstract: The present invention relates to impact-modified polyester/polycarbonate compositions containing: A) 41 to 80 parts by weight, in each case relative to the sum of the parts by weight of components A+B+C+D, of aromatic polycarbonate, B) 5 to 40 parts by weight, in each case relative to the sum of the parts by weight of components A+B+C+D, of polyester with a content of isophthalic acid building blocks, C) 1 to 15 parts by weight, in each case relative to the sum of the parts by weight of components A+B+C+D, of rubber-modified graft polymer, D) 0 to 25 parts by weight, in each case relative to the sum of the parts by weight of components A+B+C+D, of a flame retardant, E) 0 to 20 parts by weight, in each case relative to the sum of the parts by weight of components A+B+C+D=100, of vinyl (co)polymer, F) 0 to 50 parts by weight, in each case relative to the sum of the parts by weight of components A+B+C+D=100, of additives, wherein all the stated parts by weights in the present application are normalised such that
    Type: Application
    Filed: August 22, 2011
    Publication date: March 1, 2012
    Applicant: BAYER MATERIALSCIENCE AG
    Inventors: Achim FELDERMANN, Eckhard WENZ
  • Publication number: 20100298475
    Abstract: The present invention relates to flame resistance additives for organic polymers, and in particular polyphosphonate-type flame resistance additives in a polycarbonate or a polyester carbonate and/or in blends of polycarbonate or a polyester carbonate with an acrylonitrile, butadiene, and styrene terpolymer. The aromatic polyphosphonate compounds of the present invention are represented by the structure, wherein a and b are each from 0 to 6, with a+b being from 2 to 6, each R is independently hydrogen, unsubstituted or inertly substituted alkyl having up to 6 carbon atoms, —NO2, —NR12, —C?N, —OR1, —C(O)OR1, or —C(O)NR12 (wherein R1 is hydrocarbyl or hydrogen), each R2 is independently hydrogen, alkyl or inertly substituted alkyl, each R3 is a covalent bond or a divalent linking group, and each R4 is independently an alkyl, aryl, inertly substituted alkyl or inertly substituted aryl group.
    Type: Application
    Filed: January 8, 2009
    Publication date: November 25, 2010
    Inventors: David R. Wilson, Ravi B. Shankar, Ashwin R. Bharadwaj, Bruce A. King
  • Patent number: 7799848
    Abstract: A thermoplastic molding composition characterized by its flame retardance and impact strength is disclosed. The composition contains (A) linear aromatic (co)polycarbonate, (B) a graft (co)polymer having core-shell morphology, the shell containing polymerized alkyl(meth)acrylate and the core containing interpenetrated and inseparable polyorganosiloxane and poly(meth)alkyl acrylate components, (C) a phosphorous-containing flame retardant compound, (D) fluorinated polyolefin and (E) a boron compound, and optionally SAN. The composition is further characterized in that it contains no polyalkylene terephthalate.
    Type: Grant
    Filed: February 6, 2008
    Date of Patent: September 21, 2010
    Assignee: Bayer Materialscience LLC
    Inventor: Marina Rogunova
  • Publication number: 20100233405
    Abstract: Disclosed are stabilized blends of polyester and polyamide. The polymer blends are stabilized with A) a combination of stabilizers a) acetaldehyde scavengers and b) stabilizers selected from phenolic antioxidants, organic phosphorus stabilizers and lactone stabilizers or B) a combination of c) lactone stabilizers and d) stabilizers selected from phenolic antioxidants and organic phosphorus stabilizers. The present blends exhibit reduced color formation, a high level of whiteness/brightness and acceptably low haze formation upon heat treatment. The blends are useful to make bottles, containers and films for drinks, food and cosmetics and the like. The polyester is in particular polyethylene terephthalate, PET, and the polyamide is in particular polyamide-MXD6. Heat treatment is for example melt extrusion or solid state polymerization, SSP.
    Type: Application
    Filed: March 11, 2010
    Publication date: September 16, 2010
    Applicant: CIBA CORPORATION
    Inventors: Stephen M. Andrews, Paul A. Odorisio, Yijun Ye
  • Publication number: 20100168293
    Abstract: Disclosed herein is a thermoplastic composition comprising: a polycarbonate; an impact modifier; a polycarbonate-polysiloxane copolymer; a poly(arylene ether)-polysiloxane copolymer; and an organophosphate in an amount of 2 to 20 weight percent based on the combined weight of polycarbonate, impact modifier, polycarbonate-polysiloxane copolymer, and poly(arylene ether)-polysiloxane copolymer, wherein the composition has a notched Izod impact strength of greater than or equal to 4 kilojoules per square meter (kJ/m2) as determined according to ISO 180/A, a melt viscosity rate of less than or equal to 130 Pascal seconds (Pa·s) as determined according to ISO11443 at 1500 s?1 and 280° C., and a UL94 rating of V1 or better at 0.8 millimeter thickness.
    Type: Application
    Filed: December 29, 2008
    Publication date: July 1, 2010
    Inventors: Vitthal Abaso Sawant, Srinivas Siripurapu, Raja Krishnamurthy, Sandeep Tyagi
  • Publication number: 20080269383
    Abstract: Organic polymer compositions can be made flame-retardant by addition of selected organic phosphate and other components, such as known flame-retardants or conventional additives for further improvements, e.g. in name retardancy or light stability.
    Type: Application
    Filed: May 18, 2005
    Publication date: October 30, 2008
    Applicant: CIBA SPECIALTY CEMICALS HOLDING INC.
    Inventors: Jean-Roch Pauquet, Grant Leslie, Natacha Berthelon, Daniel Muller
  • Patent number: 7319116
    Abstract: A flame resistant thermoplastic molding composition having improved mechanical properties is disclosed. The composition contains polycarbonate, a graft polymer and a phosphorus compounds of formula (I): and a mixture of fluorinated polyolefins with polyalkyl (meth)acrylates.
    Type: Grant
    Filed: July 31, 2003
    Date of Patent: January 15, 2008
    Assignee: Bayer MaterialScience AG
    Inventors: Thomas Eckel, Andreas Seidel, Juan Gonzalez-Blanco, Dieter Wittmann
  • Patent number: 7273900
    Abstract: There are provided a resin composition comprising a crosslinking component with a weight average molecular weight of 1,000 or less having a plurality of styrene groups and represented by the following formula: wherein R is a hydrocarbon skeleton, each of R1s is a hydrogen atom or a hydrocarbon group, each of R2, R3 and R4 is a hydrogen atom or an alkyl group, m is an integer of 1 to 4, and n is an integer of 2 or more, at least one high-molecular weight compound, an inorganic filler, and at least one treating agent for said inorganic filler; its cured product; and a prepreg, a laminate sheet having a conductor layer, and a multilayer printed wiring board obtained by processing the conductor layer of the laminate sheet into wiring.
    Type: Grant
    Filed: September 8, 2004
    Date of Patent: September 25, 2007
    Assignee: Hitachi Chemical Company, Ltd.
    Inventors: Satoru Amou, Morimichi Umino, Akira Nagai, Yoshihiro Nakamura, Nobuyuki Minami
  • Patent number: 7186767
    Abstract: A thermoplastic molding compositions having improved stress cracking resistance is disclosed. The composition contains A) 40 to 99.5 parts by weight of at least one branched resin selected from a first group consisting of aromatic polycarbonate and polyestercarbonate and B) 0.5 to 60 parts by weight of graft polymer containing a grafting shell and a grafting base, said grafting base being other than polybutadiene rubber. The structure of the branched resin contains at least one residue of a branching agent selected from among tri-functional phenolic monomer and tetra-functional phenolic monomer.
    Type: Grant
    Filed: December 1, 2003
    Date of Patent: March 6, 2007
    Assignee: Bayer Aktiengesellschaft
    Inventors: Andreas Seidel, Thomas Eckel, Holger Warth
  • Patent number: 7067567
    Abstract: A thermoplastic molding composition having improved flammability rating and mechanical properties is disclosed. The composition contains aromatic polycarbonate having a weight-average molecular weight Mw?25,000 g/mol., polyalkylene terephthalate, graft (co)polymer characterized in that its grafted phase includes structural units derived from acrylate monomers, an oligomeric organic phosphoric acid ester, and an optional fluorinated polyolefin. In a preferred embodiment the graft (co)polymer is characterized in its core-shell morphology.
    Type: Grant
    Filed: July 25, 2003
    Date of Patent: June 27, 2006
    Assignee: Bayer Aktiengesellschaft
    Inventors: Andreas Seidel, Thomas Eckel
  • Patent number: 7056973
    Abstract: A high flow polyphenylene ether resin composition comprises a blend of at least two polyphenylene ether resins, a first resin having an intrinsic viscosity of at least 0.3 dl/g, and a second resin having an intrinsic viscosity of less than 0.17 dl/g and preferably having a particle size of at least about 100 ?m. Fiber reinforced and flame retarded compositions exhibit high HDT values.
    Type: Grant
    Filed: April 9, 2003
    Date of Patent: June 6, 2006
    Assignee: General Electric
    Inventor: Nirajkumar Patel
  • Patent number: 6949596
    Abstract: A flame resistant anti-electrostatic polycarbonate composition that is chlorine- and bromine-free is disclosed. Good melt flowability and low tendency to juicing, coupled with its good mechanical and thermal properties make the composition especially suitable for injection molding. The composition finds use in the production of a variety of molded articles.
    Type: Grant
    Filed: May 21, 2001
    Date of Patent: September 27, 2005
    Assignee: Bayer Aktiengesellschaft
    Inventors: Andreas Seidel, Thomas Eckel, Michael Zobel, Dieter Wittmann, Manfred Dietrich
  • Patent number: 6828365
    Abstract: Flame-retardant polyester monofilaments formed by extrusion from a mixture consisting essentially of 5 to 20 weight percent melamine cyanurate and 3 to 10 weight percent organopolyphosphonate with the balance being either poly(ethylene terephthalate) or poly(ethylene naphthalate).
    Type: Grant
    Filed: June 25, 2002
    Date of Patent: December 7, 2004
    Assignee: T&N Technology Limited
    Inventor: Lee Hamilton Martin
  • Patent number: 6638997
    Abstract: Hindered amines substituted on the N-atom with an —O—E—OH moiety are particularly effective in stabilizing polyolefin and automotive coating compositions against the deleterious effects of oxidative, thermal and actinic radiation where the presence of the OH group on the compounds adds important properties not attainable by the use of normal —O—E moieties.
    Type: Grant
    Filed: September 27, 2001
    Date of Patent: October 28, 2003
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: James P. Galbo, Gerald A. Capocci, Nancy N. Cliff, Robert E. Detlefsen, Michael P. DiFazio, Ramanathan Ravichandran, Peter Solera
  • Patent number: 6596794
    Abstract: Thermoplastic moulding compositions based on polycarbonate and/or polyester-carbonate comprising graft polymer prepared by means of bulk, solution or bulk-suspension polymerization processes and phosphorus compounds of the general formula (I)
    Type: Grant
    Filed: May 16, 2001
    Date of Patent: July 22, 2003
    Assignee: Bayer Aktiengesellschaft
    Inventors: Thomas Eckel, Michael Zobel, Bernd Keller, Dieter Wittmann
  • Patent number: 6593404
    Abstract: The present invention relates to flame-retardant thermoplastic resin compositions. More particularly, the present invention relates to the thermoplastic resin compositions which comprise a polycarbonate, a styrene containing graft copolymer, a styrene containing copolymer, a mixture of alkyl substituted, preferably t-butyl substituted, monophosphate esters, a phosphate ester compound, and a fluorinated polyolefin, whose stress cracking resistance and flame retardancy are improved.
    Type: Grant
    Filed: September 29, 2000
    Date of Patent: July 15, 2003
    Assignee: Cheil Industries, Inc.
    Inventors: Jun Hyuk Shin, Sam Joo Yang, Young Kil Chang
  • Patent number: 6590015
    Abstract: The invention relates to flame-resistant poly-carbonate/ABS molding compounds which are considerably improved in their mechanical properties and thermal stability by an addition of polyalkylene terephthalate and an oligomeric phosphate.
    Type: Grant
    Filed: January 3, 1995
    Date of Patent: July 8, 2003
    Assignee: Bayer Aktiengesellschaft
    Inventors: Thomas Eckel, Dieter Wittmann, Horst Beicher
  • Patent number: 6586507
    Abstract: Hindered amines substituted on the N-atom with an —O—E—OH moiety are particularly effective in stabilizing polyolefin and automotive coating compositions against the deleterious effects of oxidative, thermal and actinic radiation where the presence of the OH group on the compounds adds important properties not attainable by the use of normal —O—E moieties.
    Type: Grant
    Filed: October 3, 2001
    Date of Patent: July 1, 2003
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: James Peter Galbo, Gerald A. Capocci, Nancy N. Cliff, Robert E. Detlefsen, Michael P. DiFazio, Ramanathan Ravichandran, Peter Solera, Christophe Bulliard
  • Patent number: 6583257
    Abstract: The invention relates to thermoplastic copolycarbonate compositions and moulded parts containing the latter having improved stress cracking resistance and thermal stability.
    Type: Grant
    Filed: September 24, 2001
    Date of Patent: June 24, 2003
    Assignee: Bayer Aktiengesellschaft
    Inventors: Holger Warth, Thomas Eckel, Dieter Wittmann, Silke Kratschmer
  • Patent number: 6576700
    Abstract: A high flow polyphenylene ether resin composition with improved HDT values and flame retardance comprising a blend of at least two polyphenylene ether resins, a first resin having an intrinsic viscosity of at least 0.3 dl/g, and a second resin having an intrinsic viscosity of less than 0.25 dl/g and preferably having a particle size of at least about 100 &mgr;m. The composition preferably contains less than 30 wt % of the low viscosity polyphenylene ether based on the weight of the total composition. Fiber reinforced and flame retarded compositions also exhibit high HDT values.
    Type: Grant
    Filed: April 12, 2000
    Date of Patent: June 10, 2003
    Assignee: General Electric Company
    Inventor: Nirajkumar Patel
  • Patent number: 6528561
    Abstract: The present invention relates to polycarbonate-ABS moulding compositions provided with phosphonate amines, which moulding compositions exhibit excellent flame protection and very good processing properties, such as improved flow properties, improved modulus of elasticity and reduced formation of a coating on the tool, the graft polymer being prepared by means of mass, solution or mass-suspension polymerization processes.
    Type: Grant
    Filed: February 27, 2002
    Date of Patent: March 4, 2003
    Assignee: Bayer Aktiengesellschaft
    Inventors: Michael Zobel, Thomas Eckel, Torsten Derr, Dieter Wittmann
  • Patent number: 6410621
    Abstract: A flame-retardant molded component comprises a matrix-forming polymer material. The component also comprises 5 to 20 wt % of melamine cyanurate and 3 to 10 wt % of a polyphosphonate.
    Type: Grant
    Filed: October 22, 1998
    Date of Patent: June 25, 2002
    Assignee: T&N Technology Limited
    Inventor: Lee Hamilton Martin
  • Patent number: 6268418
    Abstract: Thermoplastic moulding compounds containing A) 30 to 99 parts by wt. of polyalkyleneterephthalate B) 0 to 50 parts by wt. of polycarbonate C) 0 to 30 parts by wt. of a graft polymer D) 0.1 to 20 parts by wt. of an oligomeric phosphorus compound of the formula (Ia)  or 0.1 to 20 parts by weight of a mixture of an oligomeric phosphorus compound of the formula (Ia) and a phosphorus compound of the formula (Ib)  where the amount of phosphorus compound of the formula (Ib) in the mixture of phosphorus compounds is 1 to 50% by weight (relative to 100% by weight of phosphorus compound of the formula (Ia) and (Ib), E1) 1 to 60 parts by wt. of mineral filler and E2) 0 to 30 parts by wt. of fillers and reinforcing materials which differ from E1).
    Type: Grant
    Filed: July 29, 1996
    Date of Patent: July 31, 2001
    Assignee: Bayer AG
    Inventors: Herbert Magerstedt, Georg Heger, Karsten-Josef Idel, Friedemann Paul
  • Patent number: 6184278
    Abstract: The present invention relates to organic polymer compositions, containing liquid ester compositions as plastisizers, said compositions comprising mixtures of esters derived from (a) diethylene glycol and triethylene glycol and (b) benzoic or toluic acid, wherein the freezing point of the ester mixture is below the freezing points of the constituent esters when the relative concentrations of the constituent esters are within specified limits.
    Type: Grant
    Filed: December 7, 1998
    Date of Patent: February 6, 2001
    Assignee: Velsicol Chemical Corporation
    Inventors: William David Arendt, Thomas Joseph Bohnert, Mark Stephen Holt
  • Patent number: 6127465
    Abstract: Disclosed is a polycarbonate resin composition comprising an aromatic polycarbonate (PC), a high-impact polystyrene resin (HIPS) and a non-halogen phosphate, and also talc and/or polytetrafluoroethylene (PTFE). Optionally, the composition may contain a core/shell-type, grafted, rubber-like elastic material. The composition has good flame retardancy and has good physical properties such as stiffness, impact resistance, outward appearance and flowability.
    Type: Grant
    Filed: September 4, 1997
    Date of Patent: October 3, 2000
    Assignee: Idemitsu Petrochemical Co., Ltd.
    Inventor: Akio Nodera
  • Patent number: 6071992
    Abstract: The present invention relates to a flame-retardant thermoplastic resin composition comprising the following components (A) to (D):(A) 50 to 80 parts by weight of an aromatic polycarbonate resin;(B) 5 to 40 parts by weight of a rubber-reinforced thermoplastic resin prepared by graft-polymerizing monomer components comprising an aromatic vinyl monomer, a vinylcyanide monomer and optionally other copolymerizable vinyl-based monomers, with a rubber polymer, the amount of said vinylcyanide monomer used being not less than 0.5% by weight and less than 5% by weight based on the total weight of said monomer components;(C) 5 to 30 parts by weight of phosphate represented by the formula (I): ##STR1## wherein R.sup.1 to R.sup.3 are the same or different and are independently an alkyl group having 1 to 10 carbon atoms or an aryl group having 6 to 20 carbon atoms; and n is 0 or 1,the total amount of the (A), (B) and (C) components being 100 parts by weight; and(D) 0.
    Type: Grant
    Filed: January 22, 1999
    Date of Patent: June 6, 2000
    Assignee: Techno Polymer Co., Ltd.
    Inventors: Koji Okada, Yutaka Maeda, Ryoichi Motoshige, Masahiko Noro
  • Patent number: 6028129
    Abstract: The invention relates to a process for increasing the molecular weight of polycondensates and at the same time stabilizing them, essentially without crosslinking, which comprises heating a polyamide, a polyester, a polycarbonate or a copolymer or blend of these polymers with addition of at least one diepoxide comprising terminal epoxide groups and as a further structural element a tetramethylpiperidine radical located centrally between the epoxide groups to a temperature which is above the melting point of the polymer in the case of crystalline polycondensates or above the glass point in the case of amorphous polycondensates. The invention additionally relates to mixtures comprising the corresponding diepoxides, to their use, and to polycondensates prepared from them.
    Type: Grant
    Filed: January 20, 1999
    Date of Patent: February 22, 2000
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Rudolf Pfaendner, Alfred Steinmann, Heinz Herbst, Kurt Hoffmann
  • Patent number: 5883165
    Abstract: A description is given of a process for the production of polyolefin hollow articles, which comprises charging the polyolefin with a stabilizer combination, comprising (A) at least one compound from the group of the organic phosphites or phosphonites, and (B) at least one compound from the group of the 3-arylbenzofuranones, filling this mixture into a mold, heating this mold in an oven to above 280.degree. C., such that the stabilised polyolefin fuses, rotating the mold around at least 2 axes, the plastic spreading to the walls, and cooling the mold while still rotating, opening it and taking the resultant hollow article out.
    Type: Grant
    Filed: October 27, 1997
    Date of Patent: March 16, 1999
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Christoph Krohnke, Urs Leo Stadler
  • Patent number: 5852086
    Abstract: An antigel agent composed of four types of antioxidants that allows polyamides to be blended with acrylonitrile/butadiene polymers with minimum generation of gels and yields a blend which can be extruded or sheeted to give a uniformed shaped product, for example, sheets and molded articles and is essentially free of plugging the screens of extruder used to extrude hose tube or sheet.
    Type: Grant
    Filed: September 30, 1996
    Date of Patent: December 22, 1998
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: James Walter Horvath, Faith Michelle Howard
  • Patent number: 5837760
    Abstract: Self-extinguishing thermoplastic polyurethanes contain, as flameproofing agents, one or more organic phosphates and/or one or more organic phosphonates, preferably as a mixture together with melamine derivatives.
    Type: Grant
    Filed: July 21, 1997
    Date of Patent: November 17, 1998
    Assignee: Elastogran GmbH
    Inventors: Christa Hackl, Friedhelm Lehrich, Gerhard Bittner
  • Patent number: 5750602
    Abstract: The invention relates to flameproofed polycarbonate/ABS blends which are resistant to stress cracking, wherein the polycarbonates are wholly or partly modified by halobutyl rubber blocks.
    Type: Grant
    Filed: October 9, 1996
    Date of Patent: May 12, 1998
    Assignee: Bayer AG
    Inventors: Burkhard Kohler, Jurgen Kirsch, Richard Weider, Dieter Wittmann, Horst Beicher
  • Patent number: 5703150
    Abstract: Phosphonite and phosphonate compounds ##STR1## wherein X.sup.1, X.sup.2, X.sup.3 and X.sup.4 are each independently a group of the formula ##STR2## wherein R is a hydrogen atom or a methyl group, p is 0 or 1, q is independently 0 or 1 with regard to each repeat unit, and m is an integer of 2 to 10, a stabilizer for organic materials comprising said compound and a stabilized organic material comprising said compound. The compound of the present invention is less volatile at high temperatures. The use of the compound of the present invention as a stabilizer for organic materials affords an extremely useful organic material which is superior in heat stability and free of degradation caused by oxidation. The compound of the present invention has excellent compatibility with the above-mentioned organic materials and hardly migrate from the organic materials.
    Type: Grant
    Filed: December 27, 1995
    Date of Patent: December 30, 1997
    Assignee: Yoshitomi Pharmaceutical Industries, Ltd.
    Inventors: Tetsuji Ike, Takeshi Inoue, Yoshihiro Ozaki
  • Patent number: 5684071
    Abstract: An additive having an improved dispersibility or adhesion property to thermoplastic resins and useful for imparting an excellent flame resistance and other properties thereto without deteriorating properties that the thermoplastic resins originally possess, such as mechanical, electrical and thermal properties and molding processability, which comprises a nitrogen-containing heterocyclic compound or its salt surface-treated with 0.1 to 50% by weight of a compound having at least two functional groups such as epoxy resin, acid anhydride or the like; and a flame retardant polyester resin composition comprising (A) a thermoplastic polyester, (B) a nitrogen-containing heterocyclic compound or its salt, (C) a compound having at least two functional groups and optionally (D) a phosphorus based flame retarder, which may be prepared by adding the component (B) previously surface-treated with the component (C) or separately adding the components (B) and (C) to the polyester (A).
    Type: Grant
    Filed: June 27, 1996
    Date of Patent: November 4, 1997
    Assignee: Kanegafuchi Kagaku Kogyo Kabushiki Kaisha
    Inventors: Kenji Mogami, Masaaki Nakamura, Tadashi Koyama, Tomomi Nakashima, Akiyoshi Somemiya
  • Patent number: 5665801
    Abstract: The synthesis of a high-molecular weight phosphorus-containing polyester flame retardant is disclosed. A metal complex is selected as the catalyst to catalyze the addition reaction of phosphorus compounds and unsaturated dicarboxylic acids in the presence of saturated dicarboxylic acids and diols at a relatively lower temperture in one single reactor to form phosphorus-containing diacids, followed by esterification and polymerization to complete the process.
    Type: Grant
    Filed: June 20, 1995
    Date of Patent: September 9, 1997
    Assignee: Industrial Technology Research Institute
    Inventors: Shinn-Jen Chang, Yuung-Ching Sheen, Rong-Shuh Chang, Tsai-Wie Tseng, Jen-Lien Lin
  • Patent number: 5476888
    Abstract: The diposphines have the formula (I) ##STR1## wherein: R.sup.2, R.sup.3 and R.sup.4 independently from each other represent a hydrocarbyl group which is substituted with one or more radicals selected from the group consisting of halogen, alkyl and alkoxy, andA is --C(O)--, --S(O).sub.2 --, --S(O)-- or certain divalent organic groups.The diphosphines are useful for stabilizing thermoplastic polymers, such as polycarbonates, against thermal discoloration.
    Type: Grant
    Filed: September 2, 1994
    Date of Patent: December 19, 1995
    Assignee: The Dow Chemical Company
    Inventors: Jurgen Eiffler, Gunter A. Juptner, David P. Flores
  • Patent number: 5356964
    Abstract: A polyolefin composition comprising a polyolefin, and the following components:(A) a phenolic compound such as 1,3,5-tris(3,5-di-t-butyl-4-hydroxybenzyl) isocyanurate;(B) an acrylate compound represented by the formula (I): ##STR1## wherein R.sup.1 is an alkyl of 1 to 5 carbon atoms, R.sup.2 is an alkyl of 1 to 8 carbon atoms, R.sup.3 is hydrogen or an alkyl of 1 to 8 carbon atoms, and R.sup.4 is hydrogen or methyl;(C) an organic phosphorous compound such as bis(2,6-di-t-butyl-4-methylphenyl) pentaerythritol diphosphite; and(D) a hindered piperidine compound such as poly[{6-(1,1,3,3-tetramethylbutyl)imino-1,3,5-triazin-2,4-diyl}{(2,2,6,6-t etramethyl-4-piperidyl)imino}hexamethylene{(2,2,6,6-tetramethyl-4-piperidyl )imino}]. This composition is stable against thermal processing, thermal oxidation, light oxidation and discoloration, and it is especially useful for fibers and films.
    Type: Grant
    Filed: December 10, 1992
    Date of Patent: October 18, 1994
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Tamaki Ishii, Shinichi Yachigo, Fumitoshi Kojima, Kanako Ida
  • Patent number: RE36188
    Abstract: The invention relates to a polymer mixture which comprises an aromatic polycarbonate, a styrene-containing copolymer and/or a styrene-containing graft polymer and a flame-retardant. It has been found that the use of a certain type of flame-retardants, namely oligomeric phosphates leads to a polymer mixture having improved properties. In particular to a polymer mixture having a good combination of flame retardancy, non-juicing characteristics of the flame retardant, good plastifying effect and good heat resistance.
    Type: Grant
    Filed: September 3, 1997
    Date of Patent: April 6, 1999
    Assignee: General Electric Company
    Inventors: Johannes C. Gosens, Charles F. Pratt, Herman B. Savenije, Christianus A. A. Claesen