Phosphorus Bonded Directly To Only Two Chalcogen Atoms And Having At Least One P-c Linkage, E.g., Phosphinate, Phosphonite, Etc. Patents (Class 524/126)
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Patent number: 7196135Abstract: A stabilizer composition is described and comprises a 3-arylacrylate, a polymeric compound with molecular weight at least 2000, bearing, on a polymeric framework, side groups having amine functions, where all of the substituents in the ?-position to the amine nitrogen atom are other than hydrogen, and comprises a sterically hindered phenol. The stabilizer composition is particularly suitable for stabilizing thermoplastic polyurethane with respect to light, oxygen, and heat.Type: GrantFiled: December 13, 2002Date of Patent: March 27, 2007Assignee: BASF AktiengesellschaftInventors: Thomas Heidenfelder, Manfred Appel
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Patent number: 7186767Abstract: A thermoplastic molding compositions having improved stress cracking resistance is disclosed. The composition contains A) 40 to 99.5 parts by weight of at least one branched resin selected from a first group consisting of aromatic polycarbonate and polyestercarbonate and B) 0.5 to 60 parts by weight of graft polymer containing a grafting shell and a grafting base, said grafting base being other than polybutadiene rubber. The structure of the branched resin contains at least one residue of a branching agent selected from among tri-functional phenolic monomer and tetra-functional phenolic monomer.Type: GrantFiled: December 1, 2003Date of Patent: March 6, 2007Assignee: Bayer AktiengesellschaftInventors: Andreas Seidel, Thomas Eckel, Holger Warth
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Patent number: 7169838Abstract: The invention relates to thermoplastic moulding materials containing A) between 20 and 97 wt. % of a thermoplastic polyester; B) between 1 and 40 wt. % of a phosphinic acid salt and/or a diphosphinic acid salt and/or the polymers thereof, constituent B) having an average particle size (value d50) which is smaller than 10 ?m; C) between 1 and 30 wt. % of a nitrogenated flameproofing agent; D) between 0 and 5 wt. % of at least one ester or amide of saturated or unsaturated aliphatic carboxylic acids having between 10 and 40 C atoms and aliphatic saturated alcohols or amines having between 2 and 40 C atoms; and E) between 0 and 60 wt. % of other additives. The total weight percent of constituents A) to E) amounts to 100%.Type: GrantFiled: July 26, 2002Date of Patent: January 30, 2007Assignee: BASF AktiengesellschaftInventors: Jochen Engelmann, Detlev Wartig
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Patent number: 7148276Abstract: The invention relates to a flame retardant combination comprising, as component A, a phosphinate of the formula (I) and/or a diphosphinate of the formula (II) and/or polymers of these where R1 and R2 are identical or different and are C1–C6-alkyl, linear or branched, and/or aryl; R3 is C1–C10-alkylene, linear or branched, C6–C10-arylene, -alkylarylene or -arylalkylene; M is calcium ions, magnesium ions, aluminum ions and/or zinc ions, m is 2 or 3; n is 1 or 3; x is 1 or 2; and comprising a component B1, B2 and/or B3 wherein B1 is a salt of 1,3,5-triazine compound with polyphosphoric acid, and wherein B2 is a melamine polymetaphosphate, and wherein B3 is a composite salt of polyphosphoric acid with melamine, melam and/or melem.Type: GrantFiled: September 5, 2003Date of Patent: December 12, 2006Assignee: Clariant GmbHInventors: Harald Bauer, Sebastian Hoerold, Werner Krause, Martin Sicken
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Patent number: 7144527Abstract: The invention relates to a flame retardant combination comprising, as component A, a phosphinate of the formula (I) and/or a diphosphinate of the formula (II) and/or polymers of these where R1 and R2 are identical or different and are C1–C6-alkyl, linear or branched, and/or aryl; R3 is C1–C10-alkylene, linear or branched, C6–C10-arylene, -alkylarylene or -arylalkylene; M is calcium ions, magnesium ions, aluminum ions and/or zinc ions, m is 2 or 3; n is 1 or 3; x is 1 or 2; and comprising a component B1, B2 and/or B3 wherein B1 is a salt of 1,3,5-triazine compound with polyphosphoric acid, and wherein B2 is a melamine polymetaphosphate, and wherein B3 is a composite salt of polyphosphoric acid with melamine, melam and/or melem.Type: GrantFiled: September 11, 2003Date of Patent: December 5, 2006Assignee: Clariant GmbHInventors: Volker Thewes, Andrea Zurstrassen
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Patent number: 7138010Abstract: The invention is a pigment comprising titanium dioxide and an amino phosphoryl compound. The pigment of the invention imparts improved physical qualities, such as improved lacing resistance and dispersion, when incorporated into polymers.Type: GrantFiled: December 12, 2005Date of Patent: November 21, 2006Assignee: Millennium Inorganic Chemicals, Inc.Inventors: Modasser El-Shoubary, M. Kamal Akhtar
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Patent number: 7122588Abstract: The object of the present invention is to provide a golf ball having a paint film which is excellent in the adhesion, the durability and the coloring-resistance. The golf ball of the present invention comprises a paint film formed on the surface of a golf ball body, wherein the paint film contains 0.05 to 5 parts by mass of a phosphorus stabilizer with respect to 100 parts by mass of a resin component.Type: GrantFiled: March 4, 2004Date of Patent: October 17, 2006Assignee: Sri Sports LimitedInventors: Koichi Fujisawa, Kazuhiko Isogawa
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Patent number: 7084196Abstract: Polymeric substrates, for example polyolefins such as polypropylene, can be made flame retardant by the incorporation therein of a synergistic mixture of (i.) at least one compound selected from the group consisting of nitroxyl stabilizers, hydroxylamine stabilizers, nitrone stabilizers, substituted hydroxylamine stabilizers, amine oxide stabilizers, benzofuranone stabilizers phosphite and phosphonite stabilizers, quinone methide stabilizers and monoacrylate esters of 2,2?-alkylidenebisphenol stabilizers and (ii.) at least one compound selected from the group consisting of brominated flame retardants, phosphorus containing flame retardants and inorganic flame retardants such as ammonium polyphosphate or decabromodiphenyl oxide; wherein the amount of organic or inorganic flame retardant of component (ii.) required to achieve an acceptable level of flame retardancy is significantly reduced compared to that needed when component (i.) is not present.Type: GrantFiled: March 12, 2002Date of Patent: August 1, 2006Assignee: Ciba Specialty Chemicals CorporationInventors: Malisa V. Troutman, Ramanathan Ravichandran, Rangarajan Srinivsan, Roswell Easton King, Douglas Wayn Horsey
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Patent number: 7022397Abstract: There is provided a membrane switch film comprising polyethylene 2, 6-naphthalenedicarboxylate as the major component and having excellent handling properties and durability, and particularly a film which is suitable for a membrane switch to be used in automobile interior devices which are potentially exposed to high temperature. The film is a membrane switch film having a refractive index in the range of 1.770–1.790 on both surfaces in either or both the film processing direction and the widthwise direction and an absolute value of no greater than 0.015 for the difference between the refractive indexes of both surfaces.Type: GrantFiled: September 4, 2003Date of Patent: April 4, 2006Assignee: Teijin DuPont Films Japan LimitedInventors: Koji Furuya, Makoto Handa
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Patent number: 7001944Abstract: A mineral-filled, impact-resistant thermoplastic molding composition is disclosed. The composition contains at least one resin selected from the group consisting of polycarbonate and polyester carbonate B) impact resistance modifier, and C) wollastonite having carbon content greater than 0.1% relative to the weight of the wollastonite as determined by elemental analysis. Exhibiting high modulus of elasticity and a good toughness, in particular also at low temperatures, the composition is suitable for car body external applications.Type: GrantFiled: October 22, 2002Date of Patent: February 21, 2006Assignee: Bayer AktiengesellschaftInventors: Marc Vathauer, Andreas Seidel, Detlev Joachimi, Dieter Wittmann
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Patent number: 6995200Abstract: The present invention relates to a stabilizer composition comprising a) at least one sterically hindered phenol, b) at least one phosphorus-containing secondary antioxidant, and c) at least one Leucine compound, wherein the weight ratio of component (a) to component (b) to component (c) is from 1:5:3 to 1:0,5:0,1 for the stabilization of polyolefine-based thermoplastic polymers against degradation, crosslinking and/or discoloration due to the exposure to heat and/or light, especially in the presence of oxygen.Type: GrantFiled: February 20, 2002Date of Patent: February 7, 2006Assignee: Clariant Finance (BVI) LimitedInventor: Christoph Kröhnke
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Patent number: 6992124Abstract: The present invention relates to a synergistic additives mixture for producing calendered polyolefin articles, comprising A) at least one component from the group of peroxide-destroying phosphorus or sulfur compounds, B) at least one component from the group of phenolic antioxidants, C) at least one component from the group of sterically hindered amines, and D) if desired, further additives. Using this additive mixture prevents sticking to the hot roll surfaces and reduces the degradation of the polymer.Type: GrantFiled: February 3, 1999Date of Patent: January 31, 2006Assignee: Clariant GmbHInventors: Christian Wick, Gerhard Pfahler, Alexander Lichtblau
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Patent number: 6964746Abstract: The invention relates to mixtures of phosphonite (component A) and/or an ester and/or salt of a long-chain fatty acid (component B), and/or a carboxylic ester, and/or carboxylic amide (component C), and also to their use in polyamides or in polyesters.Type: GrantFiled: June 12, 2003Date of Patent: November 15, 2005Assignee: Clariant GmbHInventors: Elke Schlosser, Wolfgang Wanzke, Christian Lechner
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Patent number: 6958374Abstract: The present invention relates to semiaromatic semi-crystalline thermoplastic polyamide moulding materials having improved processing behavior, increased flowability, improved surface quality and improved mechanical properties, in particular, in conditioned state, the matrix of the polyamide moulding materials according to the present invention comprising at least 3 components: a semi-crystalline copolyamide (A) having the composition 66/6I/6T, a PA prepolymer (B) having the composition 6T/6I/66 or 6T/6I/6 and an amorphous copolyamide (C) having the composition 6I/6T.Type: GrantFiled: November 15, 2001Date of Patent: October 25, 2005Assignee: EMS-Chemie AGInventors: Friedrich Severin Bühler, Alwin Hermann Schwitzer
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Patent number: 6956072Abstract: To provide a resin composition, in which a liquid crystal polymer is made into fiber in a molded article to exhibit an extremely high reinforcing effect which has not been available yet, and from which a molded article having an excellent mechanical strength can be manufactured in a stable manner. That is, a thermoplastic resin composition, wherein 100 parts by weight in total consisting of 99-50 parts by weight of a thermoplastic polyester resin (A) not forming an anisotropic molten phase and 1-50 parts by weight of a liquid crystal polymer (B) capable of forming an anisotropic molten phase is blended with 0.001-2.Type: GrantFiled: July 12, 2000Date of Patent: October 18, 2005Assignee: Polyplastics Co., Ltd.Inventors: Keiichi Kanaka, Toshio Shiwaku, Mineo Ohtake
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Patent number: 6914090Abstract: An impact resistant, flame-resistant thermoplastic molding composition suitable for making thin-wall housing parts is disclosed. The composition contains A) 50 to 90 parts by weight of at least one a member selected from the group consisting of polycarbonate and polyester carbonate, B) 5 to 20 parts by weight of rubber-modified vinyl (co)polymer C) 2 to 15 parts by weight of at least one low-volatility, halogen-free flameproofing agent, D) 0.1 to 6 parts by weight of a silicate mineral, and optional E) fluorinated polyolefin, and F) conventional polymer additive wherein the total sum of the parts by weight of the components A) to F) is 100, and wherein the rubber content of the composition referred to the weight of the composition is 2 to 6 wt.-%.Type: GrantFiled: October 22, 2002Date of Patent: July 5, 2005Assignee: Bayer AktiengesellschaftInventors: Andreas Seidel, Thomas Eckel, Dieter Wittmann
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Patent number: 6872764Abstract: Certain essentially phenol antioxidant-free stabilizer systems that comprise either a binary hindered amine/hydroxylamine or nitrone or amine oxide or benzofuranone system or a ternary hindered amine/hydroxylamine or nitrone or amine oxide or benzofuranone/organic phosphite or phosphonite system are especially effective towards protecting polyolefins against the deleterious effects of gamma irradiation. Polyolefin articles such as medical packaging, hospital garments, draperies, woven and non-woven fiber products, surgery utensils, blow-molded I.V. bottles, hypodermic syringes, needle shields, laboratory ware such as trays, funnels, Petri dishes and filters, and hygiene related articles may be sterilized with gamma irradiation and are stabilized according to the present invention.Type: GrantFiled: February 24, 2003Date of Patent: March 29, 2005Assignee: Ciba Specialty Chemicals CorporationInventor: Roswell E. King, III
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Patent number: 6818293Abstract: Disclosed are fibers and films prepared from polyesters of a dicarboxylic acid, preferably terephthalic acid, and a diol selected from 1,3-cyclohexanedimethanol, 1,4-cyclohexanedimethanol, or 1,3-propanediol. The fibers and films contain a multifunctional epoxide additive and, optionally, an antioxidant, and show an increased dry heat stability when exposed to elevated temperatures in the presence of air while preserving excellent hydrolytic stability. Also disclosed is a process for stabilizing polyester fibers by melt blending a polyester and epoxide additive and melt spinning. The fibers and films are particularly useful in applications requiring elevated temperatures.Type: GrantFiled: April 24, 2003Date of Patent: November 16, 2004Assignee: Eastman Chemical CompanyInventors: Gerald Timothy Keep, William Alston Haile, Mark Elliott Tincher
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Patent number: 6784233Abstract: The invention relates to thermoplastic molding compound that contain A) 1 to 97.85% by weight of at least one thermoplastic polyester, B) 1 to 97.85% by weight of at least one polycarbonate, C) 1 to 50% by weight of a rubber-elastic polymer, D) 0.1 to 5% by weight of a phosphorous stabilizer, E) 0.05 to 2% by weight of an organic acid, F) 0 to 60% by weight of further additives. The weight percentages of the components A) to F) add up to 100%.Type: GrantFiled: December 19, 2001Date of Patent: August 31, 2004Assignee: BASF AktiengesellschaftInventors: Martin Weber, Ingolf Hennig
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Patent number: 6767941Abstract: A halogen-free, flame-retardant composition includes (1) organic phosphorus compound (A) and (1′) melamine or a compound derived from melamine (B); or (2) a melamine-phosphorus compound (AB). The composition also includes and olefin polymer and from 0.1-30 wt % based on the olefin polymer, of a compound containing acid, acid anhydride or epoxy groups. The flame-retardant composition may included in a polycondensate composition which incorporate the flame-retardant composition is substantially shortened.Type: GrantFiled: November 27, 2001Date of Patent: July 27, 2004Assignee: DSM IP Assets B.V.Inventors: Pieter A. Van Der Spek, Martinus L. M. Bos, William A. C. Roovers, Marnix Van Gurp, Henrica N. A. M. Menting
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Patent number: 6716899Abstract: Thermoplastic molding compositions comprise A) from 5 to 96% by weight of a polyester, B) from 1 to 30% by weight of a phosphinate of formula I and/or of a diphosphinate of formula II and/or polymers of these where: R1 and R2 are linear or branched C1-C6-alkyl, phenyl or hydrogen, R3 is linear or branched C1-C10-alkylene, arylene, alkylarylene or arylalkylene, M is an alkaline-earth or alkali metal, Zn, Al, Fe or B, m is an integer from 1 to 3, n is an integer from 1 to 3, is 1 or 2 and C) from 1 to 30% by weight of at least one organic phosphorus-containing flame retardant, D) from 0 to 5% by weight of at least one ester or amide of saturated or unsaturated aliphatic carboxylic acids having from 10 to 40 carbon atoms with saturated aliphatic alcohols or amines having from 2 to 40 carbon atoms, and E) from 0 to 60% by weight of other additives, where the total of the percentages by weight of components A) to E) is 100%.Type: GrantFiled: November 2, 2000Date of Patent: April 6, 2004Assignee: BASF AktiengesellschaftInventors: Martin Klatt, Michael Nam, Herbert Fisch
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Patent number: 6710161Abstract: A polymer composition is provided including copolymer particles bearing phosphorus acid groups dispersed in an aqueous medium, wherein the polymer composition is substantially-free of water soluble phosphorus acid compounds. Also provided is a monomer composition containing at least one phosphorus acid monomer and a method of preparing the polymer composition from the monomer composition. The monomer composition is substantially-free of inorganic phosphorus acid compounds. A method is provided for applying the polymer composition to a substrate. The polymer composition is useful as a coating composition to prepare coatings for metal substrates, which have improved solvent resistance.Type: GrantFiled: December 17, 2002Date of Patent: March 23, 2004Assignee: Rohm and Haas CompanyInventors: James Keith Bardman, Ward Thomas Brown, Gary Robert Larson, William Joseph Rosano
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Publication number: 20040051087Abstract: The invention relates to a fire-protection coating which forms an insulating layer and is based on substances which, in the event of a fire, form a foam layer and form carbon, on film-forming binders, on blowing agents, and on conventional auxiliaries and additives, which comprises a phosphinic salt of the formula (I) and/or a diphosphinic salt of the formula (II), and/or their polymers, 1Type: ApplicationFiled: September 11, 2003Publication date: March 18, 2004Applicant: Clariant GmbHInventors: Volker Thewes, Andrea Zurstrassen
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Publication number: 20040051088Abstract: The invention relates to mixtures of phosphonite (component A) and/or an ester and/or salt of a long-chain fatty acid (component B), and/or a carboxylic ester, and/or carboxylic amide (component C), and also to their use in polyamides or in polyesters.Type: ApplicationFiled: June 12, 2003Publication date: March 18, 2004Applicant: Clariant GmbHInventors: Elke Schlosser, Wolfgang Wanzke, Christian Lechner
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Patent number: 6686401Abstract: Liquid composition polymerizable, by means of radicalic polymerization, into organic glass, comprising the product obtained from the transesterification of a mixture of diallyl carbonate (A) and a phthalic ester (B), with one or more polyols (C), linear or branced, containing from two to eight carbon atoms in the molecule.Type: GrantFiled: May 16, 2002Date of Patent: February 3, 2004Assignee: Great Lakes Chemical (Europe) GmbHInventors: Fiorenzo Renzi, Andrea Bendandi, Roberto Forestieri
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Patent number: 6664317Abstract: Certain essentially phenol antioxidant-free stabilizer systems that comprise either a binary hindered amine/hydroxylamine or nitrone or amine oxide or benzofuranone system or a ternary hindered amine/hydroxylamine or nitrone or amine oxide or benzofuranone/organic phosphite or phosphonite system are especially effective towards protecting polyolefins against the deleterious effects of gamma irradiation. Polyolefin articles such as medical packaging, hospital garments, draperies, woven and non-woven fiber products, surgery utensils, blow-molded I.V. bottles, hypodermic syringes, needle shields, laboratory ware such as trays, funnels, Petri dishes and filters, and hygiene related articles may be sterilized with gamma irradiation and are stabilized according to the present invention.Type: GrantFiled: February 14, 2001Date of Patent: December 16, 2003Assignee: Ciba Specialty Chemicals CorporationInventor: Roswell E. King, III
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Patent number: 6646031Abstract: Transparent thermoplastic resin compositions include a polyetherimide resin, a polyester resin, sodium benzene phosphinate, and optionally 3,4-epoxy cyclohexylmethyl-3,4-epoxy cyclohexanecarboxylate and preferably comprising a first polyester resin and a second polyester resin and sodium benzene phosphinate, wherein from 50 to 100 mole percent of the structural units of the first polyester resin include an alicyclic hydrocarbon radical as the diol residue of the structural unit, and wherein less than 50 mole percent of the structural units of the second polyester include an alicyclic hydrocarbon radical as the diol residue of the structural unit, exhibit resistance to elevated temperature and improved impact properties.Type: GrantFiled: March 26, 2002Date of Patent: November 11, 2003Assignee: General Electric CompanyInventors: Yimin Jin, Jun Liao
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Patent number: 6635340Abstract: The present application relates to a white, biaxially oriented, flame-retardant polyester film with at least one base layer which comprises, based on the weight of the base layer, from 2 to 60% by weight of a cycloolefin copolymer (COC), where the glass transition temperature of the COC is within the range from 70 to 270° C. The film also comprises from 0.5 to 30% by weight of flame retardant, based on the weight of the layer comprising the flame retardant. The film of the invention is suitable for packing foods or other consumable items which are sensitive to light and/or to air, or for use in industry, e.g. in the production of hot-stamping foils or as a label film, or for image-recording papers, printed sheets or magnetic recording cards.Type: GrantFiled: February 12, 2001Date of Patent: October 21, 2003Assignee: Mitsubishi Polyester Film GmbHInventors: Herbert Peiffer, Klaus Oberlaender, Gottfried Hilkert, Ursula Murschall
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Patent number: 6635698Abstract: A transparent/translucent flame redardant composition comprises a uniform blend of a miscible resin blend of a polycarbonate resin and a cycloaliphatic polyester resin wherein the composition has at least a 80% pass rate in 10 test specimen in the Norme Francaise NF-P-92-505 flammability test of L'Association Francaise de Normalisation using test specimens with weight between about 1.0 to about 6.0 kilograms per square meter.Type: GrantFiled: December 22, 2000Date of Patent: October 21, 2003Assignee: General Electric CompanyInventors: Johannes Martinus D. Goossens, Walter C. M. van der Heijden, Gabrie Hoogland, Johannes Jacobus M. de Moor, Hendrik Verhoogt
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Publication number: 20030193110Abstract: An article of manufacture comprises an ultrahigh molecular weight polyethylene (UHMWPE) mixed with a processing oil and a lubricant selected from the group consisting of fatty acid esters, ethoxylated fatty acid esters, glycol esters, PEG esters, glycerol esters, ethoxylated esters, sorbitol esters, ethoxylated sorbitol esters, aromatic ethoxylates, alcohol ethoxylates, mercaptan ethoxylates, modified ethoxylates, amide surfactants, phosphate esters, phosphonate esters, phosphite esters, alkyl sulfates, fatty acid ethers, alkyl ether sulfates, alkylaryl ether sulfates, sulfonates, naphthalene sulfonates, sulfosuccinates, sulfonated esters, sulfonated amides, alkyl ether carboxylates, alkylaryl ether carboxylates, quaternary amines, amino quaternary amines, ethoxylated amines, imidazoline derivatives, betaines, sultaines, aminopropionate, catechol derivatives, saturated fatty acids, unsaturated fatty acids, and combinations thereof. The method for making those articles is also disclosed.Type: ApplicationFiled: April 12, 2002Publication date: October 16, 2003Inventors: Joseph G. Yaritz, J. Kevin Whear
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Patent number: 6612351Abstract: A pneumatic rubber tire is provided having inner and outer air retention quasi envelopes which individually substantially envelop the tire air chamber and which are comprised of a first inner quasi envelope as an integral innerliner and a second outer quasi envelope as a combination of sidewalls and tread. Such pneumatic tire is of a relatively conventional open toroidal shape. The innerliner and the sidewall-tread combination are termed as being quasi envelopes in a sense that a rigid rim, onto which the tire is to be mounted and inflated, is used to complete the closure of the tire's air chamber envelope.Type: GrantFiled: February 5, 2001Date of Patent: September 2, 2003Assignee: The Goodyear Tire & Rubber CompanyInventor: David John Zanzig
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Patent number: 6599963Abstract: Hindered amine compounds containing a group of the formula where G1 and G2 are independently alkyl of 1 to 4 carbon atoms or are together pentamethylene, Z1 and Z2 are each methyl, or Z1 and Z2 together form a linking moiety which may additionally be substituted by an ester, ether, amide, amino, carboxy or urethane group, and E is alkoxy, cycloalkoxy, aralkoxy, aryloxy, —O—CO—OZ3, —O—Si(Z4)3, —O—PO(OZ5)2 or —O—CH2—OZ6 where Z3, Z4, Z5 and Z6 are selected from the group consisting of hydrogen, an aliphatic, araliphatic and aromatic moiety, when added to a wide variety of polymeric substrates, particularly polyolefins and styrenic polymers, surprisingly bestow flame retardant properties to such compositions.Type: GrantFiled: August 1, 2001Date of Patent: July 29, 2003Assignee: Ciba Specialty Chemicals CorporationInventors: Douglas Wayne Horsey, Stephen Mark Andrews, Leonard Harris Davis, Darrell David Dyas, Jr., Robert Leo Gray, Anunay Gupta, Bruce Vincent Hein, Joseph Stephen Puglisi, Ramanathan Ravichandran, Paul Shields, Rangarajan Srinivasan
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Patent number: 6590015Abstract: The invention relates to flame-resistant poly-carbonate/ABS molding compounds which are considerably improved in their mechanical properties and thermal stability by an addition of polyalkylene terephthalate and an oligomeric phosphate.Type: GrantFiled: January 3, 1995Date of Patent: July 8, 2003Assignee: Bayer AktiengesellschaftInventors: Thomas Eckel, Dieter Wittmann, Horst Beicher
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Publication number: 20030119954Abstract: A crosslinkable composition is provided including copolymer particles having phosphorus acid groups dispersed in an aqueous medium, and polycarbodiimide, wherein the crosslinkable composition is substantially free of water soluble phosphorus acid compounds. Also provided is a process for forming the crosslinkable composition and a method for crosslinking the crosslinkable composition. The crosslinkable composition is useful as a coating composition to prepare coatings for various substrates including metal, wood, glass, paper, and leather.Type: ApplicationFiled: December 12, 2002Publication date: June 26, 2003Inventor: Ward Thomas Brown
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Patent number: 6583204Abstract: Thermoplastic moulding composition comprising at least 2 components chosen from the group consisting of aromatic poly(ester)carbonates, graft polymers of one or more vinyl monomers on one or more graft bases having a glass transition temperature of <10° C., thermoplastic vinyl (co)polymer and polyalkylene terephthalate and 0.5 to 20 parts by wt. phosphorus compound of the general formula (I).Type: GrantFiled: May 16, 2001Date of Patent: June 24, 2003Assignee: Bayer AktiengesellschaftInventors: Thomas Eckel, Dieter Wittmann, Jörn Stölting, Michael Zobel
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Patent number: 6569928Abstract: A fire retardant thermoplastic polyester comprising a phosphorus containing additive and a high charring polymer containing benzene rings in its main polymer backbone and that has a softening point of no less than about 120° C. exhibits improved fire resistance and no plate out of fire retardant additive during aging.Type: GrantFiled: January 4, 2002Date of Patent: May 27, 2003Assignee: Akzo Nobel N.V.Inventors: Sergei V. Levchik, Danielle A. Bright, Gerald R. Alessio
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Patent number: 6555605Abstract: Additive composition for polymer compounds containing magnesium hydroxide, calcium carbonate at least a phosphorus compound and at least a nitrogen compound, capable of conferring flame-retardant properties to the polymer compounds to which it is added, maintaining the mechanical properties of said compound within limits acceptable for the use of the end product.Type: GrantFiled: September 22, 1997Date of Patent: April 29, 2003Assignee: Pirelli Cavi E Sistemi S.p.A.Inventor: Flavio Casiraghi
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Patent number: 6541547Abstract: Polyolefin mouldings which have excellent stability on permanent contact with extracting media comprise, as stabilizers, a selected mixture comprising an organic phosphite or phosphonite and a specially selected group of sterically hindered phenols or a certain group of sterically hindered amines. In addition, a selected three-component mixture comprising a phosphite or phosphonite, a phenolic antioxidant and a certain group of sterically hindered amines is particularly suitable as stabilizer for polyolefin moldings which are in permanent contact with extracting media.Type: GrantFiled: September 9, 1996Date of Patent: April 1, 2003Assignee: Ciba Specialty Chemicals CorporationInventors: Thomas Schmutz, Erich Kramer, Hans Zweifel, Bruno Rotzinger
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Patent number: 6531530Abstract: The present invention provides a flame retardant resin composition having excellent impact resistance, heat resistance, dimensional stability, and flame retardance. That is, it provides a flame retardant resin composition made up of: 100 parts by weight of a thermoplastic resin (A) containing: 80 to 10% by weight of (A-1) at least one of an aromatic polyester resin and a polyamide resin, 17 to 85% by weight of at least one of a rubber-containing copolymer of a vinyl cyanide and an aromatic vinyl (A-2) and a copolymer of a vinyl cyanide and an aromatic vinyl (A-3) and 3 to 40% by weight of (A-4) at least one of a polyphenylene ether resin and a polyphenylene sulfide resin, 1 to 60 parts by weight of a non-halogen, organic or inorganic flame retardant (B) and 100 parts by weight or less of a filler (C).Type: GrantFiled: December 21, 2000Date of Patent: March 11, 2003Assignee: Daicel Chemical Industries, Ltd.Inventor: Takayuki Asano
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Patent number: 6528560Abstract: Polyamide mixtures (blends) or alloys having improved transparency, chemical resistance and slight natural color, as well as a process improving the melting capacity and homogeneity of blends of polyamide according to formula (I) and partly crystalline polymers according to formula (II). Transparent polyamide blends are obtained which exhibit improved properties with respect to transparency, color, and chemical resistance, in particular stress cracking resistance against isopropanol, without resulting losses in the mechanical properties. At the same time it was possible to distinctly raise the throughput during extrusion while maintaining optimum transparency.Type: GrantFiled: February 28, 2001Date of Patent: March 4, 2003Assignee: EMS-Chemie AGInventor: Friedrich Severin Bühler
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Patent number: 6521681Abstract: Organic materials which possess outstanding stability to oxidative, thermal or light-induced degradation comprise as stabilizers at least one compound of the benzofuran-2-one type and at least one compound of the sterically hindered amine type.Type: GrantFiled: June 23, 1997Date of Patent: February 18, 2003Assignee: Ciba Specialty Chemicals CorporationInventors: Jürg Zingg, Jean-Roch Pauquet, Christoph Kröhnke
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Patent number: 6503969Abstract: Thermoplastic molding compositions comprise A) from 5 to 96% by weight of a polyester, B) from 1 to 30% by weight of a nitrogen compound, excluding melamine cyanurate, C) from 0.1 to 30% by weight of a phosphinate of formula I or of a diphosphinate of formula II or of polymers of these or mixtures of these as defined in the specification D) from 0 to 5% by weight of at least one ester or amide of saturated or unsaturated aliphatic carboxylic acids having from 10 to 40 carbon atoms with saturated aliphatic alcohols or amines having from 2 to 40 carbon atoms, and E) from 0 to 60% by weight of other additives, where the total of the percentages by weight of components A) to E) is 100%.Type: GrantFiled: November 2, 2000Date of Patent: January 7, 2003Assignee: BASF AktiengesellschaftInventors: Martin Klatt, Bernd Leutner, Michael Nam, Herbert Fisch
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Patent number: 6492444Abstract: Flame retardant organic phosphorus-phosphorus oxyacid compounds are produced by mixing and reacting a phosphorus halide, phosphorus oxyacid and an organic compound. This organic phosphorus-phosphorus oxyacid compound may be reacted with a basic compound to produce a flame retardant salt of organic phosphorus-phosphorus oxyacid. The organic phosphorus-phosphorus oxyacid and/or it's salt may be mixed with or applied on a flammable organic material to make it less flammable. A flame retardant composition may be produced by mixing or reacting the organic phosphorus-phosphorus oxyacid or it's salt with carbonization auxiliaries, carbonization accelerators, comb-like polymer and a filler. This composition may be mixed in or applied on a flammable organic material to make it less flammable.Type: GrantFiled: November 27, 2000Date of Patent: December 10, 2002Inventor: David H. Blount
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Patent number: 6479572Abstract: Thermoplastic molding materials contain A) from 5 to 97.9% by weight of a polyphenylene ether B) from 1 to 93.9% by weight of a vinylaromatic polymer C) from 1 to 50% by weight of an elastomeric polymer D) from 0.1 to 10% by weight of a stabilizer mixture comprising d1) at least one sterically hindered phenol, d2) at least one phosphonite and d3) at least one alkyl aryl phosphite, E) from 0 to 70% by weight of a polyamide and F)from 0 to 60% by weight of further additives and processing assistants, the sum of the percentages by weight of components A) to F) being 100%.Type: GrantFiled: October 28, 1997Date of Patent: November 12, 2002Assignee: BASF AktiengesellschaftInventors: Martin Weber, Hans Joachim Reinhardt, Joachim Seibring
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Patent number: 6451888Abstract: A phosphite stabilizer composition is provided which exhibits enhanced hydrolytic stability. The stabilizer composition preferably contains from 10 to 90 percent by weight of a phosphorous compound selected from phosphites and phosphonites, and preferably contains from 10 to 90 percent by weight of a hindered phenolic isocyanate. The stabilizer composition exhibits enhanced hydrolytic stability, and is preferably in the form of powders or flakes. The stabilizer composition is useful as an additive to polymeric resins as an antioxidant stabilizer.Type: GrantFiled: June 1, 1994Date of Patent: September 17, 2002Assignee: General Electric CompanyInventor: James A. Mahood
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Patent number: 6420462Abstract: A new process is described for the preparation of a compound of the formula I wherein R1, R2, R3 and R4, independently of each other, are C1-C8alkyl or C1-C5hydroxyalkyl, or R1 and R2 together with the carbon atom they are attached to are C5-C12cycloalkyl or R3 and R4 together with the carbon atom they are attached to are C5-C12cycloalkyl; R5, R6, R7, R8 and R9, independently of each other, are H, C1-C8alkyl, C2-C8alkenyl, C5-C12aryl, C1-C4haloalkyl, an electron withdrawing group, or C1-C12aryl which is substituted by a residue selected from C1-C4alkyl, C1-C4alkoxy, halogen; and R7 and R8 together may also form a chemical bond; and R is an organic linking group containing 2-500 carbon atoms and forming, together with the carbon atoms it is directly connected to and the nitrogen atom, a substituted, 5-, 6 or 7-membered cyclic ring structure; characterized in that a compound of the formula II is oxidized.Type: GrantFiled: June 15, 2000Date of Patent: July 16, 2002Assignee: Ciba Specialty Chemicals CorporationInventors: Alessandro Zedda, Gianluca Ferri, Massimiliano Sala
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Patent number: 6420463Abstract: Hindered amines substituted on the N-atom with an -O-E-OH moiety are particularly effective in stabilizing polyolefin and automotive coating compositions against the deleterious effects of oxidative, thermal and actinic radiation where the presence of the OH group on the compounds adds important properties not attainable by the use of normal -O-E moieties.Type: GrantFiled: February 21, 2001Date of Patent: July 16, 2002Assignee: Ciba Specialty Chemicals Corp.Inventors: James P. Galbo, Gerald A. Capocci, Nancy N. Cliff, Robert E. Detlefsen, Michael P. DiFazio, Ramanathan Ravichandran, Peter Solera
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Patent number: 6420461Abstract: The present invention relates to novel compounds of the formula (III) in which the substituents are as defined in the description, to a process for their preparation and to mixtures with other compounds. The compounds of the formula (III) are suitable for stabilizing organic material against the effect of light and heat.Type: GrantFiled: November 12, 1999Date of Patent: July 16, 2002Assignee: Clariant GmbHInventors: Thomas Stährfeldt, Mathias Mehrer, Matthias Zäh, Gerhard Pfahler
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Patent number: 6420465Abstract: The present invention relates to a process for preparing phosphoric acid esters, in particular monomeric bisaryl diphosphates, or bridged phosphates.Type: GrantFiled: December 4, 2000Date of Patent: July 16, 2002Assignee: Bayer AktiengesellschaftInventors: Nikolaus Janke, Reinhard Pech, Andreas Chrisochoou, Dieter Heinz, Werner Bäcker, Kaspar Hallenberger
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Patent number: 6417256Abstract: A thermoplastic molding composition containing 1 to 99 parts by weight of aromatic polycarbonate or polyester carbonate and 1 to 99 parts by weight of at least one graft polymer prepared by solution polymerization is disclosed. The graft polymer is characterized in having rubber content of 20 to 50 wt. % and in that the average particle size of its rubber phase is 80 to 600 nm. The composition, which optionally contains additives, flameproofing agents and reinforcing agents, is characterized by its improved mechanical properties.Type: GrantFiled: March 22, 2000Date of Patent: July 9, 2002Assignee: Bayer AktiengesellschaftInventors: Thomas Eckel, Dieter Wittmann, Ralph Ostarek, Richard Weider, Gisbert Michels