Aryl Group Patents (Class 524/135)
  • Publication number: 20090232968
    Abstract: The present invention relates to thermosetting powder coating compositions comprising of at least one bismuth-containing inorganic pigment, at least one organic phosphorous stabilizer, at least one thermally polymerizable thermosetting powder coating resin and at least one crosslinker. The inventive thermosetting powder coating compositions are advantageously used where there is a need for heat resistant coatings and where only minor surface modifications during over bake conditions are acceptable. The invention also relates to the use of the inventive thermosetting powder coating compositions for the preparation of powdered paints and varnishes for the making of coatings and to coatings obtained therewith.
    Type: Application
    Filed: November 8, 2006
    Publication date: September 17, 2009
    Inventors: Thomas Gross, Conny Te Walvaart, Hub Bernsen, Jules Lahaye
  • Publication number: 20090137699
    Abstract: The present invention pertains to compositions comprising a polyester polyol, a polyether polyol, an acrylic polyol, a polycarbonate polyol, a polybutadiene polyol, a hydrogenated polybutadiene polyol, a functionalized polyether and/or a polyurethane susceptible to thermal degradation, and at least one antioxidant of formula (101) and/or (102) and optionally further antioxidants.
    Type: Application
    Filed: January 23, 2009
    Publication date: May 28, 2009
    Inventor: Dietmar Mader
  • Patent number: 7531585
    Abstract: It is an object of the present invention is to provide a polylactic acid resin composition in which a crystal nucleator appropriate for accelerating crystallization of polylactic acid rein is added. A polylactic acid resin composition comprising a polylactic acid resin, and a metal salt of a phosphorus compound of formula (I) wherein R1 and R2 may be the same or different and are hydrogen atom, C1-10alkyl or C2-10alkoxycarbonyl, or a polylactic acid resin composition comprising a polylactic acid resin, and a metal salt of a phosphorus compound of formula (II) wherein R3, R4, R5 and R6 may be the same or different and are hydrogen atom, C1-10alkyl or C2-10alkoxycarbonyl. The composition is excellent in heat resistance and forming processability.
    Type: Grant
    Filed: March 25, 2005
    Date of Patent: May 12, 2009
    Assignee: Nissan Chemical Industries, Ltd.
    Inventors: Masaaki Ozawa, Yoshie Kawamura, legal representative, Ryoko Kawamura, legal representative, Daichi Kawamura, legal representative, Mikio Kasai, Yasuo Kawamura
  • Patent number: 7494694
    Abstract: The invention relates to adhesive silicone elastomer compositions which can be crosslinked by polyaddition. The composition, crosslinkable by polyaddition (hydrosilylation), comprises: ?/ at least one polyorganosiloxane (POS) bearing ethylenic and/or acetylenic unsaturations [POS with ?Si-(unsaturated) units]; ?/ at least one polyorganosiloxane (POS) with ?Si—H units; ?/ a catalytic combination comprising ?.1 at least one metallic catalyst (preferably platinum based), ?.2 and at least one crosslinking inhibitor; ?/ a filler; ?/ at least one adhesion promoter; ?/ at least one POS resin; ?/ at least one thermal resistance agent; and ?/ optionally at least one other functional additive. Methods of making and using the subject composition are also described.
    Type: Grant
    Filed: November 25, 2003
    Date of Patent: February 24, 2009
    Assignee: Rhodia Chimie
    Inventors: Catherine George, Alain Pouchelon, Fabio Zanandrea, Sébastien Sterin
  • Publication number: 20090048373
    Abstract: Novel halogen-free flame-retardant thermoplastic molding compositions are described, and give laser-markable moldings with increased quality of marking. The molding compositions comprise at least one thermoplastic A) and at least one light-sensitive compound of salt type B1) which within the polymer matrix when exposed to laser light changes its color or leads to a change in the color of the polymer matrix, and/or at least one light-sensitive or light-sensitizing oxide B2) which within the polymer matrix when exposed to laser light changes its color or leads to a change in the color of the polymer matrix, and at least one halogen-free compound or mixture C) which has a positive effect on the flammability and fire performance of the molding composition, and if appropriate, other conventional additives D). The invention further relates to moldings produced from these laser-markable flame-retardant molding compositions, and also to laser-marked moldings produced therefrom.
    Type: Application
    Filed: October 15, 2005
    Publication date: February 19, 2009
    Inventors: Joachim Clauss, Hanno Huckstadt, Arnold Schneller, Klaus Kurz
  • Patent number: 7468408
    Abstract: Disclosed is a flame retarded styrene-based resin composition containing a brominated flame retardant and an additive capable of enhancing the flame retardancy of the shaped article of the composition even in a very small amount of addition. The composition comprises (A) a styrene-based resin, (B) 0.1 to 30 parts by weight per 100 parts by weight of the resin (A) of a brominated flame retardant having a bromine content greater than 50 wt %, and (C) 0.01 to 0.2 parts by weight per 100 parts by weight of the resin (A) of a metal phthalocyanine selected from iron, manganese, cobalt, nickel, platinum or paradium phthalocyanine.
    Type: Grant
    Filed: January 11, 2005
    Date of Patent: December 23, 2008
    Assignee: Dai-Ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Hideaki Onishi, Makoto Teramoto
  • Publication number: 20080241452
    Abstract: The present invention provides a halogen-free, flame retardant adhesive composition that exhibits excellent anti-migration properties, not only within single layer structures, but also within multilayer structures of much higher density such as copper-clad laminates. The flame retardant adhesive composition according to the present invention comprises: (A) a halogen-free epoxy resin, (B) a carboxyl group-containing acrylic resin and/or a carboxyl group-containing acrylonitrile-butadiene rubber, (C) a curing agent, (E) specific phosphinate and/or diphosphonate compounds, and (F) an ion scavenger and/or a heavy metal deactivator.
    Type: Application
    Filed: October 1, 2007
    Publication date: October 2, 2008
    Applicant: Shin-Etsu Chemical Co., Ltd.
    Inventors: Kazunori KONDO, Shigehiro Hoshida, Tadashi Amano
  • Patent number: 7411014
    Abstract: A composition comprising a phosphorus containing stabilizer and a polyetherimide sulfone resin having an amount of anhydride functional end groups in excess of the amount of amine functional end groups. The composition may optionally comprise a hindered phenol.
    Type: Grant
    Filed: June 9, 2005
    Date of Patent: August 12, 2008
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Robert R. Gallucci, Jon M. Malinoski
  • Patent number: 7273901
    Abstract: The invention relates to a novel flame retardant dispersion for thermoplastic and thermoset polymers, comprising, as component A, a phosphinic salt of the formula (I), and/or a diphosphinic salt of the formula (II), and/or polymers of these, where R1 and R2 are identical or different and are C1-C6-alkyl, linear or branched, and/or aryl; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, -alkylarylene, or -arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na and/or K; m is from 1 to 4; n is from 1 to 4; x is from 1 to 4, and, as component B, a nitrogen-containing synergist or a phosphorus/nitrogen flame retardant, and, as component C, a liquid compound.
    Type: Grant
    Filed: March 5, 2004
    Date of Patent: September 25, 2007
    Assignee: Clariant Produkte (Deutschland) GmbH
    Inventors: Martin Sicken, Susanne Knop, Sebastian Hoerold, Harald Bauer
  • Patent number: 7256228
    Abstract: A stabilized thermoplastic resin composition is disclosed which comprises structural units derived at least one substituted or unsubstituted polycarbonate, at least one substituted or unsubstituted polyester and a combination of at least two quenchers, wherein said quencher is selected from a group consisting of phosphorus compound, carboxylic acid, derivates of carboxylic acids, epoxy functional polymers and boron compound. Also disclosed is a stabilized thermoplastic resin composition comprising: structural units derived at least one substituted or unsubstituted polycarbonate, at least one substituted or unsubstituted polyester, an epoxy functional polymers and a combination of at least one quenchers, wherein said quencher is selected from a group consisting of phosphorus compounds, carboxylic acid compounds, polyols, and boron compounds. In addition the composition disclosed possess good optical properties, thermal properties and stability.
    Type: Grant
    Filed: March 31, 2004
    Date of Patent: August 14, 2007
    Assignee: General Electric Company
    Inventors: Parminder Agarwal, Peter H. Th. Vollenberg, Gabrie Hoogland, Vishvajit Chandrakant Juikar, Ganesh Kannan, Abbas-Alli Ghudubhai Shaikh, Sachin Ashok Shelukar
  • Patent number: 7208535
    Abstract: PHA pellet compositions are provided which are processible into blown and cast free-standing films. The Mw of the PHA in the pellets used to produce the films is at least 470,000, at least 435,000 if PHA thermal stabilizers of the invention are used. In order to achieve a stable, unsupported film having desirable elongational and tensile properties, the Mw of PHA in the film is greater than about 420,000.
    Type: Grant
    Filed: August 6, 2003
    Date of Patent: April 24, 2007
    Assignee: Metabolix, Inc.
    Inventors: Jawed Asrar, Jean R. Pierre
  • Patent number: 7087666
    Abstract: The invention relates to surface-modified phosphinic salts of the formula (I) and/or diphosphinic salts of the formula (II) and/or polymers of these, where R1 and R2 are identical or different and are C1–C6-alkyl, linear or branched, and/or aryl; R3 is C1–C10-alkylene, linear or branched, C6–C10-arylene, -alkylarylene, or -arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K, and/or a protonated nitrogen base; m is from 1 to 4; n is from 1 to 4; x is from 1 to 4, wherein the phosphinic salts and/or diphosphinic salts, or their polymers, have been encapsulated with a surface layer composed of a synthetic resin or a wax, and to a process for their preparation, and to their use as flame retardants for thermoplastic and thermoset polymers.
    Type: Grant
    Filed: September 5, 2003
    Date of Patent: August 8, 2006
    Assignee: Clariant GmbH
    Inventors: Sebastian Hoerold, Franz-Leo Heinrichs, Elisabeth Jung
  • Patent number: 7067569
    Abstract: The invention relates to a synergistic mixture comprising a) at least one compound selected from the group consisting of the phosphites of the formula (I) to (V), of the phosphonites of the formulae (VI) to (IX) and (XV), of the di/oligophosphonites of the formulae (X) and (XI) and of the phosphinites of the formulae (XII) to (XIV), and b) at least one compound selected from the group consisting of the phosphanes of the formula (XVI), the di/oligophosphanes of the formulae (XVII) and (XVIII), and of the cyclophosphanes of the formula (XIX), and also to a process for stabilizing polymers with respect to thermooxidative degradation by addition and incorporation of a synergistic mixture of this type.
    Type: Grant
    Filed: July 13, 2001
    Date of Patent: June 27, 2006
    Assignee: Clariant Finance (BVI) Limited
    Inventor: Peter Staniek
  • Patent number: 6964746
    Abstract: The invention relates to mixtures of phosphonite (component A) and/or an ester and/or salt of a long-chain fatty acid (component B), and/or a carboxylic ester, and/or carboxylic amide (component C), and also to their use in polyamides or in polyesters.
    Type: Grant
    Filed: June 12, 2003
    Date of Patent: November 15, 2005
    Assignee: Clariant GmbH
    Inventors: Elke Schlosser, Wolfgang Wanzke, Christian Lechner
  • Patent number: 6784233
    Abstract: The invention relates to thermoplastic molding compound that contain A) 1 to 97.85% by weight of at least one thermoplastic polyester, B) 1 to 97.85% by weight of at least one polycarbonate, C) 1 to 50% by weight of a rubber-elastic polymer, D) 0.1 to 5% by weight of a phosphorous stabilizer, E) 0.05 to 2% by weight of an organic acid, F) 0 to 60% by weight of further additives. The weight percentages of the components A) to F) add up to 100%.
    Type: Grant
    Filed: December 19, 2001
    Date of Patent: August 31, 2004
    Assignee: BASF Aktiengesellschaft
    Inventors: Martin Weber, Ingolf Hennig
  • Patent number: 6767941
    Abstract: A halogen-free, flame-retardant composition includes (1) organic phosphorus compound (A) and (1′) melamine or a compound derived from melamine (B); or (2) a melamine-phosphorus compound (AB). The composition also includes and olefin polymer and from 0.1-30 wt % based on the olefin polymer, of a compound containing acid, acid anhydride or epoxy groups. The flame-retardant composition may included in a polycondensate composition which incorporate the flame-retardant composition is substantially shortened.
    Type: Grant
    Filed: November 27, 2001
    Date of Patent: July 27, 2004
    Assignee: DSM IP Assets B.V.
    Inventors: Pieter A. Van Der Spek, Martinus L. M. Bos, William A. C. Roovers, Marnix Van Gurp, Henrica N. A. M. Menting
  • Patent number: 6759459
    Abstract: The present invention is drawn to colorless toner compositions for overcoating a print having an ink jet ink image printed thereon. The colorless toner can comprise: a toner resin and at least two additives independently selected from the group consisting of ultraviolet absorbers, free radical inhibitors, thermal stabilizers, and combinations thereof, wherein the ratio of toner resin to total additive is from 1:1 to 99:1 by weight. The colorless toner can also be comprised of a charge control agent and/or a low-melt wax.
    Type: Grant
    Filed: May 13, 2002
    Date of Patent: July 6, 2004
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: An-Chung Robert Lin, Michael H. Lee
  • Patent number: 6716899
    Abstract: Thermoplastic molding compositions comprise A) from 5 to 96% by weight of a polyester, B) from 1 to 30% by weight of a phosphinate of formula I and/or of a diphosphinate of formula II and/or polymers of these  where: R1 and R2 are linear or branched C1-C6-alkyl, phenyl or hydrogen, R3 is linear or branched C1-C10-alkylene, arylene, alkylarylene or arylalkylene, M is an alkaline-earth or alkali metal, Zn, Al, Fe or B, m is an integer from 1 to 3, n is an integer from 1 to 3, is 1 or 2 and C) from 1 to 30% by weight of at least one organic phosphorus-containing flame retardant, D) from 0 to 5% by weight of at least one ester or amide of saturated or unsaturated aliphatic carboxylic acids having from 10 to 40 carbon atoms with saturated aliphatic alcohols or amines having from 2 to 40 carbon atoms, and E) from 0 to 60% by weight of other additives, where the total of the percentages by weight of components A) to E) is 100%.
    Type: Grant
    Filed: November 2, 2000
    Date of Patent: April 6, 2004
    Assignee: BASF Aktiengesellschaft
    Inventors: Martin Klatt, Michael Nam, Herbert Fisch
  • Publication number: 20040051087
    Abstract: The invention relates to a fire-protection coating which forms an insulating layer and is based on substances which, in the event of a fire, form a foam layer and form carbon, on film-forming binders, on blowing agents, and on conventional auxiliaries and additives, which comprises a phosphinic salt of the formula (I) and/or a diphosphinic salt of the formula (II), and/or their polymers, 1
    Type: Application
    Filed: September 11, 2003
    Publication date: March 18, 2004
    Applicant: Clariant GmbH
    Inventors: Volker Thewes, Andrea Zurstrassen
  • Publication number: 20040051088
    Abstract: The invention relates to mixtures of phosphonite (component A) and/or an ester and/or salt of a long-chain fatty acid (component B), and/or a carboxylic ester, and/or carboxylic amide (component C), and also to their use in polyamides or in polyesters.
    Type: Application
    Filed: June 12, 2003
    Publication date: March 18, 2004
    Applicant: Clariant GmbH
    Inventors: Elke Schlosser, Wolfgang Wanzke, Christian Lechner
  • Patent number: 6646031
    Abstract: Transparent thermoplastic resin compositions include a polyetherimide resin, a polyester resin, sodium benzene phosphinate, and optionally 3,4-epoxy cyclohexylmethyl-3,4-epoxy cyclohexanecarboxylate and preferably comprising a first polyester resin and a second polyester resin and sodium benzene phosphinate, wherein from 50 to 100 mole percent of the structural units of the first polyester resin include an alicyclic hydrocarbon radical as the diol residue of the structural unit, and wherein less than 50 mole percent of the structural units of the second polyester include an alicyclic hydrocarbon radical as the diol residue of the structural unit, exhibit resistance to elevated temperature and improved impact properties.
    Type: Grant
    Filed: March 26, 2002
    Date of Patent: November 11, 2003
    Assignee: General Electric Company
    Inventors: Yimin Jin, Jun Liao
  • Patent number: 6547992
    Abstract: The invention relates to a flame retardant combination for thermoplastic polymers comprising, as component A, a phosphinate of the formula (I) and/or a diphosphinate of the formula (II) and/or polymers of these where R1 and R2 are identical or different and are C1-C6-alkyl, linear or branched, and/or aryl; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, -alkylarylene or -arylalkylene; M are calcium ions, aluminum ions and/or zinc ions; m is 2 or 3; n is 1 or 3; x is 1 or 2, and, as component B, a synthetic inorganic compound and/or a mineral product.
    Type: Grant
    Filed: January 29, 2000
    Date of Patent: April 15, 2003
    Assignee: Clariant GmbH
    Inventors: Elke Schlosser, Bernd Nass, Wolfgang Wanzke
  • Patent number: 6531525
    Abstract: An abherent composition which contains (A) a compound having C4-C20 perfluoro-alkyl or alkenyl group, (B) polytetrafluoroethylene having a number-average molecular weight of at most 500,000, and (C) at least one compound selected from the group consisting of a silicone oil, a silicone resin and a highly fluorinated compound having a boiling point of at least 100° C. except those included in the components (A) and (B), is disclosed. This composition prevents various articles from adhering to each other and is suitable as a mold release agent, an anti-blocking agent, a stripping agent for an electrical wire and the like.
    Type: Grant
    Filed: December 22, 1995
    Date of Patent: March 11, 2003
    Assignee: Daikin Industries, Ltd.
    Inventors: Masayuki Yamana, Tsukasa Aga
  • Patent number: 6521681
    Abstract: Organic materials which possess outstanding stability to oxidative, thermal or light-induced degradation comprise as stabilizers at least one compound of the benzofuran-2-one type and at least one compound of the sterically hindered amine type.
    Type: Grant
    Filed: June 23, 1997
    Date of Patent: February 18, 2003
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Jürg Zingg, Jean-Roch Pauquet, Christoph Kröhnke
  • Patent number: 6479572
    Abstract: Thermoplastic molding materials contain A) from 5 to 97.9% by weight of a polyphenylene ether B) from 1 to 93.9% by weight of a vinylaromatic polymer C) from 1 to 50% by weight of an elastomeric polymer D) from 0.1 to 10% by weight of a stabilizer mixture comprising d1) at least one sterically hindered phenol, d2) at least one phosphonite and d3) at least one alkyl aryl phosphite, E) from 0 to 70% by weight of a polyamide and F)from 0 to 60% by weight of further additives and processing assistants, the sum of the percentages by weight of components A) to F) being 100%.
    Type: Grant
    Filed: October 28, 1997
    Date of Patent: November 12, 2002
    Assignee: BASF Aktiengesellschaft
    Inventors: Martin Weber, Hans Joachim Reinhardt, Joachim Seibring
  • Patent number: 6403684
    Abstract: Transparent thermoplastic resin compositions include a polyetherimide resin, a polyester resin, sodium benzene phosphinate, and optionally 3,4-epoxy cyclohexylmethyl-3,4-epoxy cyclohexanecarboxylate and preferably comprising a first polyester resin and a second polyester resin and sodium benzene phosphinate, wherein from 50 to 100 mole percent of the structural units of the first polyester resin include an alicyclic hydrocarbon radical as the diol residue of the structural unit, and wherein less than 50 mole percent of the structural units of the second polyester include an alicyclic hydrocarbon radical as the diol residue of the structural unit, exhibit resistance to elevated temperature and improved impact properties.
    Type: Grant
    Filed: December 16, 1998
    Date of Patent: June 11, 2002
    Assignee: General Electric Company
    Inventors: Yimin Jin, Jun Liao
  • Patent number: 6399716
    Abstract: An aromatic group containing copolyester resin composition which has good biodegradability and physical properties, wherein; (i) 0.1 wt % to 30 wt % of an aliphatic prepolymers having number average molecular weight of from 300 to 30,000; (ii) one or a plurality of aromatic dicarboxylic acid (or an acid anhydride thereof which containing aromatic group in the molecule; (iii) one or a plurality of aliphatic (including cyclic type) dicarboxylic acid (or an acid anhydride thereof); and (iv) one or a plurality of aliphatic (including cyclic type) glycol, wherein the copolyester resin has number average molecular weight of from 30,000 to 90,000, weight average molecular weight of from 100,000 to 600,000, melting point of from 70° C. to 150° C., and melt index of from 0.1 to 50 g/10min. (190° C., 2,160 g), and the process for preparing and/or producing the same.
    Type: Grant
    Filed: December 13, 2000
    Date of Patent: June 4, 2002
    Assignee: IRE Chemical Ltd.
    Inventors: Hyun Soo Chung, Jae Wang Lee, Dong Hoon Kim, Do Youn Kim, Suok Woo Lee
  • Patent number: 6346562
    Abstract: The invention relates to cross-linkable mixtures and a method for the production and utilization thereof.
    Type: Grant
    Filed: October 23, 2000
    Date of Patent: February 12, 2002
    Assignee: General Electric Company
    Inventors: Rolf Haselhorst, Ralf Karch, Klaus Zimmermann
  • Patent number: 6255371
    Abstract: The invention relates to a novel flame retardant combination comprising, as component A, a phosphinate of the formula (I) and/or a diphosphinate of the formula (II) and/or polymers of these where R1 and R2 are identical or different and are C1-C6-alkyl, linear or branched, and/or aryl; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, -alkylarylene or -arylalkylene; M is calcium ions, magnesium ions, aluminum ions and/or zinc ions, preferably aluminium or zinc; m is 2 or 3; n is 1 or 3; x is 1 or 2; and comprising, as component B, condensation products of melamine and/or reaction products of melamine with phosphoric acid and/or reaction products of condensation products of melamine with phosphoric acid and/or comprising a mixture of these. The invention also relates to the use of the abovementioned flame retardant combination, especially in thermoplastic polymers.
    Type: Grant
    Filed: July 17, 2000
    Date of Patent: July 3, 2001
    Assignee: Clariant GmbH
    Inventors: Elke Schlosser, Bernd Nass, Wolfgang Wanzke
  • Patent number: 6207737
    Abstract: An aqueous sizing composition for glass fibers used to reinforce polyolefin polymers contains coupling agent, chemically modified polyolefin film forming material, and stabilizer.
    Type: Grant
    Filed: February 15, 1995
    Date of Patent: March 27, 2001
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Philip L. Schell, Laura A. Meesters, Rajgopal Subramanian
  • Patent number: 6103796
    Abstract: A homogeneous blended additive useful as a processing stabilizer for polymers which is a blend of Component (a), a defined phosphite or phosphonite; and Component (b) which is micronized zinc oxide. Component (b) is preferably in an amount of 5 to 10% based on the weight of component (a). This additive composition improves the resistance of phosphites and phosphonites against hydrolysis in the presence of moisture, by providing Component (b) as a hydrolysis stabilizer for Component (a).
    Type: Grant
    Filed: October 3, 1997
    Date of Patent: August 15, 2000
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Peter Staniek, Klaus Stoll, Rainer Wolf
  • Patent number: 5980777
    Abstract: A liquid crystalline resin which comprises at least one kind of liquid crystalline polymer selected from liquid crystalline polyester and liquid crystalline polyester amide, both forming an anisotropic molten phase, and an inorganic phosphorus compound, said liquid crystalline resin having an absorbance of 0.5 or less at 380 nm when measured over an optical path length of 10 mm in a 0.5 wt % solution in a 1:1 mixed solvent of pentafluorophenol and chloroform (by weight). It is useful as engineering plastics because of improved color, heat resistance, and hydrolytic resistance.
    Type: Grant
    Filed: December 24, 1997
    Date of Patent: November 9, 1999
    Assignee: Toray Industries, Inc.
    Inventors: Hideyuki Umetsu, Yoshiki Makabe, Toshihide Inoue
  • Patent number: 5929148
    Abstract: The present invention provides polyhexamethylene adipamide fibers significantly excellent in thermal yellowing resistance, and a process for producing the same. The improved polyhexamethylene adipamide fibers have adaptability to fibers for clothing which adaptability is comparable to that of poly-.epsilon.-capramide fibers and polyester fibers. The improved polyhexamethylene adipamide fibers can be obtained by either (1) melt spinning a polyhexamethylene adipamide simultaneously containing 2,4-bis(alkylthio)-6-(3,5 -dialkyl-4-hydroxyanilino)-1,3,5-triazine and a compound selected from the group consisting of phosphorous acid, hypophosphorous acid and derivatives of these acids, or (2) melt spinning the fibers having the sum of an amino end group concentration (?--NH.sub.2)!) and a carboxyl end group concentration (?--COOH!) of 70 to 200 meq/kg, satisfying the condition: ?--COOH!.ltoreq.60 meq/kg, and containing from 0.005 to 0.
    Type: Grant
    Filed: November 25, 1996
    Date of Patent: July 27, 1999
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Katsuya Shimizu, Hiroshi Tomiyama
  • Patent number: 5922471
    Abstract: Polypropylene random copolymer resins and metallized, heat sealable cast films produced from such resins include (1) a polypropylene-.alpha.-olefin random copolymer such as a propylene-butene-1 or propylene-ethylene random copolymer and (2) an additive package including a synthetic amorphous silica, a hindered phenolic antioxidant, a processing stabilizer and an acid acceptor. The compositions according to the invention are useful for the preparation of metallized, heat sealable packaging films suitable for protecting goods, particularly goods requiring a long shelf life such as foods or semiconductor products.
    Type: Grant
    Filed: March 4, 1996
    Date of Patent: July 13, 1999
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventor: Ananda M. Chatterjee
  • Patent number: 5852085
    Abstract: Disclosed are transparent blends of a polyetherimide, at least one resin selected from the group consisting of polycarbonate resins, poly(ester-carbonate) resins, and polyarylate resins, and an effective amount of a catalyst to provide transparency to the blends. In addition to being transparent, the blends have good ductility as well as high flexural and tensile properties. The yellowness index of the compositions can be improved with the addition of a phosphite.
    Type: Grant
    Filed: December 31, 1996
    Date of Patent: December 22, 1998
    Assignee: General Electric Company
    Inventors: Sterling Bruce Brown, Stephen Michael Copper, Brenda A. Giles
  • Patent number: 5780534
    Abstract: Polyesters such as polyethylene terephthalate or polybutylene terephthalate are provided with a flame-retardant finish by addition of calcium salts or aluminum salts of phosphinic or diphosphinic acids.
    Type: Grant
    Filed: January 8, 1997
    Date of Patent: July 14, 1998
    Assignee: Ticona GmbH
    Inventors: Hans-Jerg Kleiner, Winfried Budzinsky, Gunther Kirsch
  • Patent number: 5773556
    Abstract: Low-flammability polyamide molding materials are obtained by admixing calcium or aluminum phosphinates. These salts confer improved flame protection on polyamides compared with other metal salts.
    Type: Grant
    Filed: February 27, 1997
    Date of Patent: June 30, 1998
    Assignee: Ticona GmbH
    Inventors: Hans-Jerg Kleiner, Winfried Budzinsky, Gunther Kirsch
  • Patent number: 5514739
    Abstract: An improved synthetic resin composition is provided that consists essentially of 100 parts by weight of a resin component composed of 50 to 99 (preferably 50 to 90) parts by weight of a melt-processable polyester that does not form an anisotropic melt phase and 1 to 50 (preferably 10 to 50) parts by weight of a liquid crystal polyester that is capable of forming an anisotropic melt phase, to which has been added 0.01 to 0.5 part by weight of a phosphorus compound. The presence of the phosphorus compound has been found to facilitate the fibrillation of the liquid crystal polyester component during molding so as to form fibrils within the resulting molded article having an aspect ratio of 6 or more. The resulting molded article accordingly exhibits significantly enhanced mechanical properties.
    Type: Grant
    Filed: November 9, 1994
    Date of Patent: May 7, 1996
    Assignee: Polyplastics Co., Ltd.
    Inventors: Tomoyuki Aketa, Takayuki Ishikawa
  • Patent number: 5451626
    Abstract: This invention relates to a polyester composition comprisinga) a polyester having repeat units from terephthalic acid and 1,4-cyclohexane dimethanol, said polyester having an I.V. of 0.5-2.0 g/dL, andb) about 1-10% by weight of the total composition of an ether compound having the formulawherein R and R' having from about 1 to about 30 carbon atoms are univalent hydrocarbon radicals, A and A' having from about 6 to about 18 carbon atoms are aromatic radicals, and --X-- is a chemical bond or divalent coupling radical.
    Type: Grant
    Filed: June 29, 1993
    Date of Patent: September 19, 1995
    Assignee: Eastman Chemical Company
    Inventors: Jiro Kumaki, Kiyomi Okita, Hidetoshi Ohtawa
  • Patent number: 5391690
    Abstract: A process for producing a (co)polycarbonate or a (co)polyestercarbonate having a high molecular weight and excellent hue, heat stability and mechanical properties by reacting a dihydroxyl compound with a diester of carbonic acid and/or a diester of dicarbonic acid in the presence of a transesterification catalyst, wherein at least part of the reaction process is conducted in the presence of a specified organic phosphorus compound, or, in the presence of a specified organic phosphorus compound and a hindered phenol compound. A (co)polycarbonate or (co)polyester-carbonate composition having excellent hue, heat stability and mechanical properties, comprising a (co)polycarbonate and/or a (co)polyestercarbonate and, a specified organic phosphorus compound, or, a specified organic phosphorus compound and a hindered phenol compound.
    Type: Grant
    Filed: June 2, 1993
    Date of Patent: February 21, 1995
    Assignee: Daicel Chemical Industries,Ltd.
    Inventors: Tatsuya Kanno, Tsutomu Yamato, Yasuhiro Oshino, Yutaka Fukuda, Yoshihiro Iguchi, Takaaki Kuwana, Toshihiro Matsumoto
  • Patent number: 5387628
    Abstract: A process for producing a (co)polycarbonate or a (co)polyestercarbonate having a high molecular weight and excellent hue, heat stability and mechanical properties by reacting a dihydroxyl compound with a diester of carbonic acid and/or a diester of dicarbonic acid in the presence of a transesterification catalyst, wherein at least part of the reaction process is conducted in the presence of a specified organic phosphorus compound, or, in the presence of a specified organic phosphorus compound and a hindered phenol compound. A (co)polycarbonate or (co)polyester-carbonate composition having excellent hue, heat stability and mechanical properties, comprising a (co)polycarbonate and/or a (co)polyestercarbonate and, a specified organic phosphorus compound, or, a specified organic phosphorus compound and a hindered phenol compound.
    Type: Grant
    Filed: September 9, 1993
    Date of Patent: February 7, 1995
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Tatsuya Kanno, Tsutomu Yamato, Yasuhiro Oshino, Yutaka Fukuda, Yoshihiro Iguchi, Takaaki Kuwana, Toshihiro Matsumoto
  • Patent number: 5331032
    Abstract: An aromatic polyester shaped article, for example, a fiber, a film or a sheet, having excellent hydrophilic characteristics and a durable antistatic property, sweat-absorbing property and soil-releasing property, is prepared from an aromatic polyester composition comprising (a) 100 parts by weight of an aromatic polyester resin, (b) 0.2 to 30 parts by weight a water-insoluble polyoxyethylene type polyether represented by the formula (I): ##STR1## wherein Z is a residue of an organic compound having 1 to 6 active hydrogen atoms and a molecular weight of 300 or less, R.sup.1 is an unsubstituted or substituted alkylene group having at least 6 carbon atoms, R.sup.2 is H, a monovalent hydrocarbon group having 1 to 40 carbon atoms, or a monovalent acyl group having 2 to 40 carbon atoms, k is 1 to 6, l satisfies the relationship: k x l.gtoreq.70 and m is 1 or more, and having a number average molecular weight of 5000 to 16000, said R.sup.1, R.sup.
    Type: Grant
    Filed: July 30, 1993
    Date of Patent: July 19, 1994
    Assignees: Teijin Limited, Dai-ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Togi Suzuki, Shigeo Mori, Noboru Chujo
  • Patent number: 5298541
    Abstract: A process for the preparation of aryl phosphonites of the formula V ##STR1## wherein the radicals and n are defined in the disclosure. The invention further relates to a plastic molding composition, in particular a polyolefin molding composition containing aryl phosphonites of the formula V.
    Type: Grant
    Filed: February 20, 1992
    Date of Patent: March 29, 1994
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Manfred Bohshar, Hans-Jerg Kleiner, Gerhard Pfahler
  • Patent number: 5296521
    Abstract: The present invention relates to fast-crystallizing polyester compositions comprising: (a) a thermoplastic polyester resin; (b) a nucleating agent of the formula: ##STR1## wherein: R is an alkali or alkaline-earth metal; m is 1, 2 or 3; n takes an average value within the range of 1 to 5; said nucleating agent being optionally admixed with the compound of formula (I) wherein R is a hydrogen atom, linear alkyl radial or branched alkyl radical each having from 1 to 6 carbon atoms; with the proviso that at least 50% mole of said nucleating agent is in the salt form. This nucleating additive raises the crystallization temperature upon cooling (T.sub.cc) of the polyester so that crystallization occurs rapidly during molding.
    Type: Grant
    Filed: June 3, 1993
    Date of Patent: March 22, 1994
    Assignees: Istituto Guido Donegani S.P.A., Enichem Synthesis S.P.A.
    Inventors: John W. Gilmer, Gianluigi Landoni
  • Patent number: 5278279
    Abstract: A process for producing a (co)polycarbonate or a (co)polyestercarbonate having a high molecular weight and excellent hue, heat stability and mechanical properties by reacting a dihydroxyl compound with a diester of carbonic acid and/or a diester of dicarbonic acid in the presence of a transesterification catalyst, wherein at least part of the reaction process is conducted in the presence of a specified organic phosphorus compound, or, in the presence of a specified organic phosphorus compound and a hindered phenol compound. A (co)polycarbonate or (co)polyester-carbonate composition having excellent hue, heat stability and mechanical properties, comprising a (co)polycarbonate and/or a (co)polyestercarbonate and, a specified organic phosphorus compound, or, a specified organic phosphorus compound and a hindered phenol compound.
    Type: Grant
    Filed: August 31, 1992
    Date of Patent: January 11, 1994
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Tatsuya Kanno, Tsutomu Yamato, Yasuhiro Oshino, Yutaka Fukuda, Yoshihiro Iguchi, Takaaki Kuwana, Toshihiro Matsumoto
  • Patent number: 5276077
    Abstract: According to the present invention there are obtained improved ignition resistant carbonate polymer blends having unexpectedly better combinations of toughness, ignition resistance, processability and stability. In particular the blend comprises a major amount of carbonate polymer, a minor amount of a rubber-modified monovinylidene aromatic copolymer, and an optional rubbery core/shell graft copolymer impact modifier. As ignition resistance additives the blends contain a metal salt of an aromatic sulfur compound, a buffering aromatic sulfur compound, an organophosphorus compound, and a tetrafluoroethylene polymer.
    Type: Grant
    Filed: June 3, 1992
    Date of Patent: January 4, 1994
    Assignee: The Dow Chemical Company
    Inventors: Lisa M. Schwane, M. Robert Christy, Samuel A. Ogoe
  • Patent number: 5262460
    Abstract: An aromatic polyester shaped article, for example, a fiber, a film or a sheet, having excellent hydrophilic characteristics and a durable antistatic property, sweat-absorbing property and soil-releasing property, is prepared from an aromatic polyester composition comprising (a) 100 parts by weight of an aromatic polyester resin, (b) 0.2 to 30 parts by weight a water-insoluble polyoxyethylene type polyether represented by the formula (I):Z--[(CH.sub.2 CH.sub.2 O).sub.l -(R.sup.1 O).sub.m -R.sup.2 ]k (I)wherein Z is a residue of an organic compound having 1 to 6 active hydrogen atoms and a molecular weight of 300 or less, R.sup.1 is an unsubstituted or substituted alkylene group having at least 6 carbon atoms, R.sup.2 is H, a monovalent hydrocarbon group having 1 to 40 carbon atoms, or a monovalent acyl group having 2 to 40 carbon atoms, k is 1 to 6, l satisfies the relationship: k.times.l.gtoreq.70 and m is 1 or more, and having a number average molecular weight of 5000 to 16000, said R.sup.1, R.sup.
    Type: Grant
    Filed: March 21, 1991
    Date of Patent: November 16, 1993
    Assignees: Teijin Limited, Dai-Ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Togi Suzuki, Shigeo Mori, Noboru Chujo
  • Patent number: 5234979
    Abstract: The present invention relates to thermoplastic moulding compositions consisting of halogen-free polycarbonates, halogen-free polystyrene and/or halogen-free copolymers of styrene with acrylonitrile, halogen-free phosphorus compounds of the formula I ##STR1## and tetrafluoroethylene polymers, and, if appropriate, other known additives.
    Type: Grant
    Filed: January 25, 1988
    Date of Patent: August 10, 1993
    Inventors: Gert Todtemann, Klaus Reinking
  • Patent number: 5158992
    Abstract: Disclosed are olefin polymers in nonextruded, aspolymerized particle form having a regular, essentially symmetrical geometrical shape, which are stabilized by depositing on their surface a mixture which is either melted, or in which at least stabilizer (A) is in the liquid state, and which comprises the following stabilizers (percent by weight on the polymer):A) from 0.02% to 0.015% of one or more organic phosphites or phosphonites or mixtures thereof, which are liquid at room temperature or have melting point below 100.degree. C.;B) from 0.025% to 0.2% of one or more phenolic antioxidants with melting point from 45.degree. to 130.degree. C.; and, optionally, one or more of the following additional components:C) from 0.05% to 0.5% of one or more thioethers, or organic polysulfides or mixtures thereof;D) from 0.1% to 1.0% of one or more light stabilizers which are liquid at room temperature or have a melting point below 150.degree. C.
    Type: Grant
    Filed: July 30, 1990
    Date of Patent: October 27, 1992
    Assignee: HIMONT Incorporated
    Inventors: Giancarlo Caselli, Giuseppe Gorini
  • Patent number: 5145941
    Abstract: The invention is a polyester and a method for producing a polyester fiber which has a combination of flame resistance and low pilling properties. The method comprises forming a polyester fiber made from a blend of two polyester polymers, one polyester polymer containing an oxysilicon compound and the second polyester polymer containing pentaerythritol and a phosphinic acid in the amount between 0.5 and 20 mole percent of the terephthalate acid and monomer. In particular, the invention also comprises the enhanced fiber formed by the process, as well as the fabrics having a pilling of about 3 to less than 5 as measured in accordance with ASTM D-3512-82.
    Type: Grant
    Filed: November 22, 1991
    Date of Patent: September 8, 1992
    Assignee: Hoechst Celanese Corporation
    Inventors: Jerry T. Munday, Theodore D. Meiss