Abstract: A particulate material for powder bed fusion has specific particle size characteristics and includes a thermoplastic and a sulfonate salt having the structure (A), wherein Z is a phosphorus atom or a nitrogen atom; each occurrence of X is independently halogen or hydrogen provided that at least one X is halogen; b, d, and e are integers from zero to 12; c is 0 or 1 provided that when c is 1, d and e are not both zero; R11_13 are each independently C1-C12 hydrocarbyl; R14 is C1-C18 hydrocarbyl; and Y is selected from (B)—wherein R15 is hydrogen or C1-C12 hydrocarbyl. Also described is a method of powder bed fusion utilizing the particulate material.

Abstract: The invention relates to a composition, more particularly, to a two-component composition comprising component I comprising at least one methylene malonate monomer (A), at least one polymer (B) and at least one acidic stabilizer (C), and component comprising at least one alkali accelerator, to the preparation thereof, and to the use of the composition as a waterproofing coat in construction applications.

Abstract: A thermoplastic resin composition of the present invention comprises: approximately 100 parts by weight of a polycarbonate resin; approximately 0.01-2 parts by weight of a modified aromatic vinyl-based copolymer resin; approximately 0.01-1 parts by weight of a metal aliphatic sulfonate; and approximately 0.01-2 parts by weight of a fluorinated olefin-based resin, wherein the modified aromatic vinyl-based copolymer resin is a polymer of a monomer mixture comprising an aromatic vinyl-based monomer and glycidyl (meth)acrylate. The thermoplastic resin composition has excellent flame retardancy, transparency and the like.

Abstract: A flame-retardant polycarbonate-based resin composition, including: a polycarbonate-based resin satisfying requirements (1) and (2); and a flame retardant, wherein the flame retardant is in an amount of from 0.

Abstract: Provided is a polycarbonate-polyorganosiloxane copolymer including polycarbonate blocks (A-1) each formed of a specific repeating unit and polyorganosiloxane blocks (A-2) each containing a specific repeating unit, wherein the polycarbonate-polyorganosiloxane copolymer satisfies the following expression (F1a): 15?wM1??(F1a) wherein wM1 represents the average content of the polyorganosiloxane blocks (A-2) in polycarbonate-polyorganosiloxane copolymers each having a molecular weight determined by using a polycarbonate as a conversion reference of from 56,000 or more to 200,000 or less among polycarbonate-polyorganosiloxane copolymers obtained through the separation of the polycarbonate-polyorganosiloxane copolymer by gel permeation chromatography.

Abstract: Provided is a polycarbonate-polyorganosiloxane copolymer including polycarbonate blocks (A-1) each formed of a specific repeating unit and polyorganosiloxane blocks (A-2) each containing a specific repeating unit, wherein the polycarbonate-polyorganosiloxane copolymer satisfies the following expression (F1a): 15?wM1??(F1a) wherein wM1 represents the average content of the polyorganosiloxane blocks (A-2) in polycarbonate-polyorganosiloxane copolymers each having a molecular weight determined by using a polycarbonate as a conversion reference of from 56,000 or more to 200,000 or less among polycarbonate-polyorganosiloxane copolymers obtained through the separation of the polycarbonate-polyorganosiloxane copolymer by gel permeation chromatography.

Abstract: Polycarbonate blend compositions are disclosed. The compositions include at least one polycarbonate useful for high heat applications. The compositions include at least one poly(aliphatic ester)-polycarbonate. The compositions can include one or more additional polymers. The compositions can include one or more additives. The compositions can be used to prepare articles of manufacture.

Abstract: The present invention relates to compositions containing flame retardant polycarbonate, which are suitable for producing flame-resistant milk-white colored plates. The composition contains polycarbonate, 0.10 to 4.00 weight percent of an acrylate-based scattering additive, 0.50 to 5.00 weight percent of an aromatic-aliphatic polyester, and 0.50 to 8.00 weight percent of a phosphorus-based flame retardant.

Abstract: Described herein is a thermoplastic composition comprising a polycarbonate, a mineral filler, inorganic acid or acid salt, an anti-drip agent, and a flame retardant comprising a perfluoroalkyl sulfonate salt or a combination of an aromatic phosphate ester and a polycarbonate-siloxane block copolymer.

Abstract: A polycarbonate film having a thickness of 0.05 mm to 0.25 mm is formed from a thermoplastic composition that includes a first branched polycarbonate that has a peak melt viscosity of at least 7,000 poise when measured using a parallel plate melt rheology test at a heating rate of 10° C./min at a temperature of between 350° C. to 450° C., a second branched polycarbonate, and a perfluoroalkyl sulfonate salt.

Abstract: The present invention relates to flameproofed, UV-resistant polycarbonate moulding compositions having improved flame retardancy and a low incorporation of the UV absorber into the polymer chain and a resulting higher relative viscosity compared with the polycarbonates having increased incorporation of UV absorber, wherein the polycarbonate compositions comprise A) at least one polycarbonate having an average molecular weight Mw of from 18,000 to 40,000 g/mol, B) one or more reactive UV absorbers and C) at least one alkali metal or alkaline earth metal salt of a fluorinated organic acid, and C) has a content of free sulfate of less than 0.007 wt. % and a content of free fluoride of less than 0.017 wt.%, in each case based on the weight of C).

Abstract: The invention relates to (co)polycarbonate compositions and molding compositions which feature improved optical properties, good flowability, and high heat resistance.

Abstract: The present invention relates to glass fibre-reinforced polycarbonate compositions of high rigidity and improved thermal and rheological properties in combination with improved flameproofing properties and a significantly increased Vicat temperature. The present invention furthermore relates to the use of the compositions according to the invention for the production of thin-walled housing parts or switch boxes in the EE (electrical/electronics) and IT (information technology) sector.

Abstract: An aromatic polycarbonate resin composition includes per 100 mass parts of an aromatic polycarbonate resin (A) having an aromatic polycarbonate resin (a1) and an aromatic polycarbonate resin (a2) in a ratio when a total quantity of aromatic polycarbonate resins (a1) and (a2) is denoted as 100 mass percent, (a1):(a2)=99 mass percent to 50 mass percent:1 mass percent to 50 mass percent; 0.01 to 10 mass parts of microparticles (B) selected from the group consisting of polyorganosilsesquioxane microparticles and (meth)acrylic resin microparticles; and 0.005 mass part to 0.1 mass part of a flame retardant (C) in the form of organic sulfonic acid metal salt; wherein a molten resin quantity Q value flowing out of an orifice 1 mm in diameter×10 mm in length at a temperature of 280° C. at a load of 1.57×107 Pa.

Abstract: A pressure-sensitive adhesive composition, comprising: a (meth)acryl-based polymer (A); and an ionic compound (B) comprising an anion component and a cation component, wherein the (meth)acryl-based polymer (A) is a hydroxyl group-containing (meth)acryl-based polymer (A) containing a monomer unit derived from a hydroxyl group-containing monomer, and the anion component has an organic group and three or more carbon atoms. The anion component is preferably at least one of anion components represented by the following formula (1): (CnF2n+1SO2)2N???(1) ?wherein n is an integer of 3 to 10; the following formula (2): CF2(CmF2mSO2)2N???(2) ?wherein m is an integer of 2 to 10; and the following formula (3): ?O3S(CF2)lSO3???(3) ?wherein l is an integer of 3 to 10.

Abstract: The present invention relates to impact-modified glass fibre-reinforced polycarbonate compositions of high rigidity and improved thermal and rheological properties in combination with good flameproofing properties. The present invention furthermore relates to the use of the compositions according to the invention for the production of thin-walled housing parts or switch boxes in the EE sector.

Abstract: Provided a polycarbonate resin composition excellent in flame resistance, impact resistance, and color fastness. A polycarbonate resin composition containing, per 100 parts by mass of polycarbonate resin (A), 0.001 to 30 parts by mass of flame retardant (B), 0.001 to 1 part by mass of fluoropolymer (C), and 0.5 to 10 parts by mass of graft copolymer (D) obtainable by graft-copolymerizing a diene-based rubber with a (meth)acrylate ester compound, the graft copolymer (D) having (i) a sulfur content of 100 to 1500 ppm, and (ii) an average particle size of 70 to 240 nm.

Abstract: A thermoplastic resin composition having good balance among impact resistance, flame retardancy, heat resistance and flowability all of which are required for thin molded articles high-dimensionally. The flame retardant resin composition comprises 100 parts by weight of a resin component comprising (A) a polycarbonate resin and (B) a polycarbonate-polydiorganosiloxane copolymer resin obtained by copolymerizing a dihydric phenol with a hydroxyaryl-terminated polydiorganosiloxane, (C) 3 to 35 parts by weight of an organic phosphorus-based flame retardant or 0.005 to 5 parts by weight of an organic metal salt-based flame retardant, (D) 0.1 to 30 parts by weight of a silicate mineral and (E) 0.1 to 3 parts by weight of a dripping inhibitor, and, if necessary, (F) 3 to 45 parts by weight of a styrene resin wherein the polydiorganosiloxane content of the component (B) in the composition is 0.2 to 0.6 wt %.

Abstract: Polymeric blends having improved flame retardance properties and good ductility at low temperatures are disclosed. The blend is formed from (A) a photoactive additive that is a cross-linkable polycarbonate resin containing a photoactive group derived from a dihydroxybenzophenone; and (B) a polymer resin which is different from the photoactive additive. The additive can be a compound, oligomer, or polymer. When exposed to ultraviolet light, crosslinking will occur between the photoactive additive and the polymer resin, enhancing the chemical resistance and flame retardance while maintaining ductility.

Abstract: Photoactive additives, such as cross-linkable polycarbonate resins, are disclosed. The additive is formed from the reaction of a monohydroxybenzophenone, a dihydroxybenzophenone, a diol chain extender, and one or more linker moieties having functional groups that react with the phenolic groups on the other ingredients. If desired, a secondary linker moiety and/or an end-capping agent can be used. When added to a base polymeric resin, the photoactive additive permits crosslinking when exposed to ultraviolet light.

Abstract: A pressure-sensitive adhesive composition comprising (A) a (meth)acryl-based polymer, (B1) an ionic compound comprising a cation component and an anion component having an organic group of three or more carbon atoms, and (B2) an ionic compound comprising a cation component and an anion component having an organic group of two or less carbon atoms. The anion component having an organic group of three or more carbon atoms is preferably at least one of anion components represented by formula (1): (CnF2n+1SO2)2N???(1) in formula (1), n is an integer of 3 to 10, formula (2): CF2(CmF2mSO2)2N???(2) in formula (2), m is an integer of 2 to 10, formula (3): ?O3S(CF2)lSO3???(3) in formula (3), l is an integer of 3 to 10, and formula (4): (CpF2p+1SO2)N?(CqF2q+1SO2)??(4) in formula (4), p and q are each an integer of 2 to 10.

Abstract: Polycarbonate blend compositions are provided. In particular, polycarbonate blend compositions having a combination of a high heat polycarbonate, a polycarbonate polysiloxane copolymer, an anti-drip agent comprising a perfluorinated polyolefin, and a flame retardant additive.

Abstract: In a polycarbonate resin composition containing a polycarbonate resin and a polycarbosilane compound, the use of the polycarbosilane compound modifies the surface properties of the polycarbonate resin composition without adversely affecting the intrinsic characteristics of the polycarbonate resin, such as transparency, heat resistance, and mechanical properties, e.g., impact resistance. A polycarbonate resin composition containing 100 parts by mass of a polycarbonate resin, 0.001 to 1 part by mass of a metal salt compound, and 0.005 to 5 parts by mass of a polycarbosilane compound has significantly improved flame resistance and high transparency and causes markedly reduced outgassing and mold fouling, without losing impact resistance and heat resistance.

Abstract: An aromatic polycarbonate resin composition includes per 100 mass parts of an aromatic polycarbonate resin (A) having an aromatic polycarbonate resin (a1) and an aromatic polycarbonate resin (a2) in a ratio when a total quantity of aromatic polycarbonate resins (a1) and (a2) is denoted as 100 mass percent, (a1):(a2)=99 mass percent to 50 mass percent:1 mass percent to 50 mass percent; 0.01 to 10 mass parts of microparticles (B) selected from the group consisting of polyorganosilsesquioxane microparticles and (meth)acrylic resin microparticles; and 0.005 mass part to 0.1 mass part of a flame retardant (C) in the form of organic sulfonic acid metal salt; wherein a molten resin quantity Q value flowing out of an orifice 1 mm in diameter×10 mm in length at a temperature of 280° C. at a load of 1.57×107 Pa.

Abstract: In a polycarbonate resin composition containing a polycarbonate resin and a polycarbosilane compound, the use of the polycarbosilane compound modifies the surface properties of the polycarbonate resin composition without adversely affecting the intrinsic characteristics of the polycarbonate resin, such as transparency, heat resistance, and mechanical properties, e.g., impact resistance. A polycarbonate resin composition containing 100 parts by mass of a polycarbonate resin, 0.001 to 1 part by mass of a metal salt compound, and 0.005 to 5 parts by mass of a polycarbosilane compound has significantly improved flame resistance and high transparency and causes markedly reduced outgassing and mold fouling, without losing impact resistance and heat resistance.

Abstract: Disclosed herein are compositions including a cross-linked polycarbonate. The cross-linked polycarbonate may be derived from a polycarbonate having about 0.5 mol % to about 5 mol % endcap groups derived from a monohydroxybenzophenone. A plaque including the composition can achieve a UL94 5VA rating. Also disclosed herein are articles including the compositions, methods of using the compositions, and processes for preparing the compositions.

Abstract: Disclosed herein are compositions including a cross-linked polycarbonate. The cross-linked polycarbonate may be derived from a polycarbonate having about 0.5 mol % to about 5 mol % endcap groups derived from a monohydroxybenzophenone. A plaque including the composition can achieve a UL94 5VA rating. Also disclosed herein are articles including the compositions, methods of using the compositions, and processes for preparing the compositions.

Abstract: Five to eighty-five percent by weight of an aromatic polycarbonate resin (A component) having a weight-average molecular weight (polystyrene equivalent) of 27000 to 35000, 0.2 to 10 percent by weight of an impact strength improver (D component), 0.05 to 4 percent by weight of a core-shell-type styrene-based polymer flame retardant (E component) having a sulfonate group bonded to a particle surface layer portion, 5 to 20 percent by weight of an inorganic filler (F component), and 0.1 to 0.5 percent by weight of a polyfluoroolefin resin (G component) are mixed.

Abstract: A polycarbonate resin composition for light guides which has excellent light guiding properties and flame retardancy, a light guide and a surface light source body. The light guide is formed from a resin composition which comprises (A) 100 parts by weight of a polycarbonate resin (component A) and (B) 0.001 to 0.1 part by weight of a metal salt-based compound (component B).

Abstract: In a polycarbonate resin composition containing a polycarbonate resin and a polycarbosilane compound, the use of the polycarbosilane compound modifies the surface properties of the polycarbonate resin composition without adversely affecting the intrinsic characteristics of the polycarbonate resin, such as transparency, heat resistance, and mechanical properties, e.g., impact resistance. A polycarbonate resin composition containing 100 parts by mass of a polycarbonate resin, 0.001 to 1 part by mass of a metal salt compound, and 0.005 to 5 parts by mass of a polycarbosilane compound has significantly improved flame resistance and high transparency and causes markedly reduced outgassing and mold fouling, without losing impact resistance and heat resistance.

Abstract: A process comprising polymerizing in an aqueous medium at least one fluorinated olefin monomer other than vinylidene fluoride in the presence of a compound of formula (1): Rf(CH2CF2)m—(CH2)nSO3M??(1) wherein Rf is a C1 to C4 linear or branched perfluoroalkyl group, m is an integer of from 1 to 6, n is from 0 to 4, M is H, NH4, Li, Na or K, and a method of altering the surface behavior of a liquid comprising adding to the liquid the composition of a compound of formula (1).

Abstract: The invention relates to antistatic polymer compositions comprising a polymer substrate, a polyalkyleneethoxylate with a specific molecular weight and a salt. Further aspects are a process for preparing an antistatic polymer and the use of such a polyalkyleneethoxylate as antistatic agent in polymers, preferably together with a salt.

Abstract: In a polycarbonate resin composition containing a polycarbonate resin and a polycarbosilane compound, the use of the polycarbosilane compound modifies the surface properties of the polycarbonate resin composition without adversely affecting the intrinsic characteristics of the polycarbonate resin, such as transparency, heat resistance, and mechanical properties, e.g., impact resistance. A polycarbonate resin composition containing 100 parts by mass of a polycarbonate resin, 0.001 to 1 part by mass of a metal salt compound, and 0.005 to 5 parts by mass of a polycarbosilane compound has significantly improved flame resistance and high transparency and causes markedly reduced outgassing and mold fouling, without losing impact resistance and heat resistance.

Abstract: A polycarbonate resin composition includes about 100 parts by weight of a base resin including about 45 to about 86 parts by weight of a polycarbonate resin (A), about 10 to about 45 parts by weight of a polysiloxane-polycarbonate copolymer (B) and about 4 to about 10 parts by weight of an aromatic vinyl graft copolymer (C), about 0.03 to about 5 parts by weight of a sulfonate flame retardant (D) based on about 100 parts by weight of the base resin, and about 1 to about 10 parts by weight of a polycaprolactone polymer (E) based on about 100 parts by weight of the base resin.

Abstract: A flame-retardant thermoplastic molding composition is disclosed. The composition contains aromatic polycarbonate resin, about 0.01 to 0.15 wt.-% of a salt, wherein the salt is an alkali metal or alkaline earth metal salt of perfluoroalkane sulfonic acid, aromatic sulfimide, ar aromatic sulfonic add, and about 0.5 to 10 wt.-% of poly- and/or oligo-aryloxysiloxane (herein after referred as aryloxysiloxane) as flame-retardant synergist. The inventive composition is characterized in that its flammability rating is better than that of aromatic polycarbonate resin containing only inorganic salt of a derivative from aliphatic or aromatic sulfonic acid, sulphonamide or sulfonimide in accordance with UL-94 V standard, while mechanical and optical properties of the compositions are maintained.

Abstract: A glass fiber reinforced polycarbonate resin composition includes (A) a glass fiber reinforced polycarbonate, (B) a mixture of two kinds of organic silicone based compounds comprising (b1) a siloxane based compound and (b2) a silicone based resin, (C) a metal salt based flame retardant, and (D) a fluorinated polyolefin based resin and can have excellent flame retardancy and impact resistance.

Abstract: Some implementations provide a composite material that includes a first material and a second material. In some implementations, the composite material is a metamaterial. The first material includes a chiral polymer (e.g., crystalline chiral helical polymer, poly-?-benzyl-L-glutamate (PBLG), poly-L-lactic acid (PLA), polypeptide, and/or polyacetylene). The second material is within the chiral polymer. The first material and the second material are configured to provide an effective index of refraction value for the composite material of 1 or less. In some implementations, the effective index of refraction value for the composite material is negative. In some implementations, the effective index of refraction value for the composite material of 1 or less is at least in a wavelength of one of at least a visible spectrum, an infrared spectrum, a microwave spectrum, and/or an ultraviolet spectrum.

Abstract: Disclosed are oligomeric phosphonates including oligophosphonates, random or block co-oligo(phosphonate ester)s and co-oligo(phosphonate carbonate)s produced using a condensation process terminated with hydroxyl, epoxy, vinyl, vinyl ester, isopropenyl, isocyanate groups, and the like. These materials can be used as a reactive additive to other polymers, oligomers or monomer mixtures to impart flame resistance without diminishing melt processability which is important in the fabrication of polymers for many applications.

Abstract: Laser engravable films are disclosed. In one aspect, the laser engravable film of the present invention includes a monolayer film, preferably comprising polycarbonate, having a laser engraving additive and an antistatic composition mixed within the layer of polycarbonate. In another aspect, the laser engravable film of the present invention includes a first layer, preferably comprising polycarbonate, having an antistatic composition mixed within the first layer, and a second layer, preferably comprising polycarbonate, with laser engraving additives mixed within the second layer.

Abstract: In a polycarbonate resin composition containing a polycarbonate resin and a polycarbosilane compound, the use of the polycarbosilane compound modifies the surface properties of the polycarbonate resin composition without adversely affecting the intrinsic characteristics of the polycarbonate resin, such as transparency, heat resistance, and mechanical properties, e.g., impact resistance. A polycarbonate resin composition containing 100 parts by mass of a polycarbonate resin, 0.001 to 1 part by mass of a metal salt compound, and 0.005 to 5 parts by mass of a polycarbosilane compound has significantly improved flame resistance and high transparency and causes markedly reduced outgassing and mold fouling, without losing impact resistance and heat resistance.

Abstract: Disclosed herein is a composition comprising: a flame retardant comprising a sulfonate salt and three polycarbonates. The first polycarbonate has a branching level of greater than or equal to 2%, a weight average molecular weight of 20,000 g/mole to 55,000 g/mole and a peak melt viscosity of greater than or equal to 25,000 poise. The second polycarbonate has a glass transition temperature greater than or equal to 170° C. The third polycarbonate has a branching level of 0 to less than 2% and a molecular weight of 17,000 to 40,000g/mol. The composition has a heat distortion temperature greater than or equal to 145° C., ductility greater than or equal to 90% at 23° C., multi-axial impact greater than or equal to 50 Joules per meter (J/m) at 23° C., and a molded article of the composition has a UL 94 V0 rating at a thickness of 1.5 mm.

Abstract: A fluorine-containing compound exhibiting excellent surface tension-reducing ability despite the absence of perfluoroalkyl group having a chain length of 8 or more which had been the cause of the PFOS and PFOA problems and use of a fluorine material with low environmental load is provided. Also provided are a fluorine-containing surfactant and a composition thereof, an aqueous resin emulsion and a floor polish composition containing such surfactant. The fluorine-containing compound is represented by the following formula (1): Rf1—CpH2p—CH(OH)—CqH2q—NR—CrH2r—(O)n—SO3M (1) wherein Rf1 is a C1-6 perfluoroalkyl group, p, q, and r are independently an integer of 1 to 6, M is a cationic atom or atomic group, n is 0 or 1, R is hydrogen atom, a C1-12 alkyl group, or a group represented by the following formula (2): Rf2—CsH2s—CH(OH)—CtH2t—??(2) wherein Rf2 is a C1-6 perfluoroalkyl group, and s and t are independently an integer of 1 to 6.

Abstract: A polycarbonate containing composition comprising a peak melt viscosity of at least 8,000 poise when measured using a parallel plate melt rheology test at a heating rate of 10° C./min at a temperature of between about 350° C. to about 450° C., and wherein a molded article of the composition has a UL 94 VO rating at a thickness of 1.0 mm, 1.5 mm, 2.0 mm, or between 1.0 mm and 2.0 mm is disclosed.

Abstract: Compositions containing a polycarbonate and a linear and cyclic phenyl containing siloxanes are disclosed. Specifically, a composition comprising: (a) a branched polycarbonate resin, (b) a flame retardant, (c) at least one linear phenyl containing siloxane and at least one cyclic phenyl containing siloxane, and (d) a linear polycarbonate resin when said branched polycarbonate is less than 100% based upon weight percent of total polycarbonate in said composition, wherein the amounts of said branched and linear polycarbonate resins, said linear siloxanes and cyclic siloxanes, and flame retardant are in amounts effective to provide a molded article from said composition with a UL94 V0 p(FTP) value of 0.90 or greater at a thickness of between 1 mm and 2.5 mm or at 2.5 mm or at 1.5 mm or at 1 mm is disclosed.

Abstract: In an embodiment, a polycarbonate composition comprises: polycarbonate; 7 wt % to 20 wt % titanium dioxide, based upon a total weight of the polycarbonate composition; an optional flame retardant; and an optional UV stabilizer. A plaque formed from the polycarbonate composition has a reflectance of greater than or equal to 95%, as determined by reflectance measurements using a Gretag Macbeth Coloreye spectrophotometer (D65 light source, 10 degree observer, UV included) made at a wavelength of 680 nm. In an embodiment, a polycarbonate composition comprises: a polycarbonate; 7 to 20 wt % titanium dioxide; a flame retardant; and an optional UV stabilizer; wherein the polycarbonate composition has a maximum reflectance of greater than or equal to 95%. The melt volume rate as determined at 300° C. using a 1.2 kilogram weight, in accordance with ASTM D1238-04 is from 5 to 30 grams per 10 minutes.

Abstract: The present invention discloses a polycarbonate resin composition and molded article thereof with excellent flame resistance, no problem with clouding, and excellent haze properties and color tone values. The flame retardant polycarbonate resin composition wherein (B) a metal salt of an organic sulfonic acid and (C) a compound with inclusion capability are contained in (A) a polycarbonate resin, and a flame retardant for a polycarbonate resin comprising an inclusion compound in which (B) a metal salt of an organic sulfonic acid is enclosed by (C) a compound with inclusion capability.

Abstract: There is disclosed a polycarbonate and polysiloxane block copolymer includes 1 to 50 percent by mass of a siloxane portion derived from a polysiloxane block represented by the following formula (I) and 50 to 99 percent by mass of a carbonate portion derived from a polycarbonate block represented by the following formula (II). There can be provided a novel polycarbonate and polysiloxane block copolymer capable of readily imparting excellent flame retardance, and a flame retardant resin composition.

Abstract: In a polycarbonate resin composition containing a polycarbonate resin and a polycarbosilane compound, the use of the polycarbosilane compound modifies the surface properties of the polycarbonate resin composition without adversely affecting the intrinsic characteristics of the polycarbonate resin, such as transparency, heat resistance, and mechanical properties, e.g., impact resistance. A polycarbonate resin composition containing 100 parts by mass of a polycarbonate resin, 0.001 to 1 part by mass of a metal salt compound, and 0.005 to 5 parts by mass of a polycarbosilane compound has significantly improved flame resistance and high transparency and causes markedly reduced outgassing and mold fouling, without losing impact resistance and heat resistance.

Abstract: The present invention relates to flameproofed, UV-resistant polycarbonate moulding compositions having improved flame retardancy and a low incorporation of the UV absorber into the polymer chain and a resulting higher relative viscosity compared with the polycarbonates having increased incorporation of UV absorber, wherein the polycarbonate compositions comprise A) at least one polycarbonate having an average molecular weight Mw of from 18,000 to 40,000 g/mol, B) one or more reactive UV absorbers and C) at least one alkali metal or alkaline earth metal salt of a fluorinated organic acid, and C) has a content of free sulfate of less than 0.007 wt. % and a content of free fluoride of less than 0.017 wt. %, in each case based on the weight of C).

Abstract: In a polycarbonate resin composition containing a polycarbonate resin and a polycarbosilane compound, the use of the polycarbosilane compound modifies the surface properties of the polycarbonate resin composition without adversely affecting the intrinsic characteristics of the polycarbonate resin, such as transparency, heat resistance, and mechanical properties, e.g., impact resistance. A polycarbonate resin composition containing 100 parts by mass of a polycarbonate resin, 0.001 to 1 part by mass of a metal salt compound, and 0.005 to 5 parts by mass of a polycarbosilane compound has significantly improved flame resistance and high transparency and causes markedly reduced outgassing and mold fouling, without losing impact resistance and heat resistance.