Metal Patents (Class 524/166)
  • Patent number: 6790899
    Abstract: A combination of a potassium salt of a perfluoroalkane sulfonate and a sodium salt of toluene sulfonic acid, preferably in the presence of an antidrip agent to provide high melt strength, act synergistically to provide flame-retarded polycarbonate compositions at low levels. Thus, a flame-retarded polycarbonate resin can be made by adding to the polycarbonate resin an effective flame-retardant amount of a potassium salt of a perfluoroalkane sulfonate and a sodium salt of toluene sulfonic acid. The two salts may be formulated in advance into an additive composition.
    Type: Grant
    Filed: October 29, 2002
    Date of Patent: September 14, 2004
    Assignee: General Electric Company
    Inventors: Rajendra K. Singh, Ye-Gang Lin
  • Patent number: 6774164
    Abstract: A novel emulsion polymerization process for the production of fluoroelastomers is disclosed wherein a partially fluorinated anionic surfactant of the formula F—(CF2CF2)n—CH2CH2SO3M, where n is an integer from 2 to 9, or mixtures thereof, and M is a cation having a valence of 1, is used as the dispersing agent.
    Type: Grant
    Filed: August 24, 2001
    Date of Patent: August 10, 2004
    Assignee: DuPont Dow Elastomers L.L.C.
    Inventors: Donald Frederick Lyons, Albert Lloyd Moore, Phan Linh Tang
  • Patent number: 6774165
    Abstract: A method of preparing an amine-free emulsion of alkaline earth metal sulfonates is disclosed. A solution of water and a nonionic, associative thickener of the type normally used for viscosity and thixotropy modification of latex compounds is combined with an overbased or neutral earth metal sulfonate or sulfonate complex to produce the emulsion. Mixtures of these emulsified products with other ingredients such as neutral diluent oils, linear alcohol/hydrocarbon mixtures, tall oil fatty acids, non-ionic surfactants, oxidized polyethylene waxes, small levels of microcrystalline wax, petrolatums, and/or calcium salts of oxidized petrolatums is also disclosed. The resulting emulsions find application in the modification of asphalt emulsions, the formulation of temporary coatings for the protection of painted automotive surfaces (transit coatings for automobiles) and in the prevention of corrosion of metal surfaces.
    Type: Grant
    Filed: July 24, 2000
    Date of Patent: August 10, 2004
    Assignee: Stoney Creek Technologies, LLC
    Inventors: Steven D. Clark, Paul Morrison, Pedro Velis
  • Patent number: 6740697
    Abstract: A flame retardant thermoplastic molding composition is disclosed. The composition contains an amorphous thermoplastic polymer, at least one flame retardant in the form of a fully or partially halogenated sulfonic acid salt and at least on alkaline earth metal sulfate and/or one oxide having an average particle size of up to 400 nm.
    Type: Grant
    Filed: August 17, 2001
    Date of Patent: May 25, 2004
    Assignee: Bayer Aktiengesellschaft
    Inventors: Axel Brenner, Walter Köhler, Martin Döbler
  • Patent number: 6730725
    Abstract: The present invention relates to a polycarbonate which can be obtained by a melting method and has a viscosity-average molecular weight of 16000 to 27000, and whose loss angle &dgr; and complex viscosity &eegr;* (Pa·s) measured under the conditions of 250° C. and an angular velocity of 10 rad/s satisfy the following relation (1): 4,700≦Tan &dgr;/(&eegr;*)−0.
    Type: Grant
    Filed: April 10, 2002
    Date of Patent: May 4, 2004
    Assignee: Mitsubishi Engineering-Plastics Corp.
    Inventors: Tatsuya Masuki, Hiroshi Yoshioka, Takao Tayama, Masaaki Miyamoto
  • Patent number: 6727302
    Abstract: A transparent, fire resistant polycarbonate composition comprises polycarbonate, poly(methylphenylsiloxane) and a salt based flame retardant. These polycarbonate compositions can attain UL94 V0 ratings at 1.6 millimeter thickness, previously possible only with a halogenated fire retardant.
    Type: Grant
    Filed: April 3, 2001
    Date of Patent: April 27, 2004
    Assignee: General Electric Company
    Inventors: Johannes M. D. Goossens, Bart P. G. Hendrix, Walter van der Heijden, Christianus J. J. Maas, Hendrik Verhoogt
  • Patent number: 6727303
    Abstract: A flame retardant aromatic polycarbonate resin composition comprising: (1) 100 parts by weight of resin components comprising 50 to 100 wt % of an aromatic polycarbonate resin (component A-1), 0 to 50 wt % of a styrene-based resin (component A-2) and 0 to 50 wt % of an aromatic polyester resin (component A-3); and (2) 0.1 to 10 parts by weight of a silicone compound (component B) which contains an Si—H group and an aromatic group in the molecule based on 100 parts by weight of the total of the resin components, wherein the silicone compound is at least one selected from silicone compounds which have (1) an Si—H group content (Si—H content) of 0.1 to 1.
    Type: Grant
    Filed: August 28, 2002
    Date of Patent: April 27, 2004
    Assignee: Teijin Chemicals, Ltd.
    Inventors: Tetsushi Ono, Akinari Itagaki, Masaaki Yamaya, Yoshiteru Kobayashi
  • Patent number: 6653376
    Abstract: A water dispersion type water and oil repellent composition which is capable of imparting durable water resistance to clothing for which high water and oil repellency is required and which is capable of imparting high oil repellency to paper. The water dispersion type water and oil repellent composition comprises 1) an aqueous medium, 2) a polymer of a monomer having a polyfluoroalkyl group and one polymerizable unsaturated group and 3) a mono(or poly)ol or an alkylene oxide thereof, as essential components.
    Type: Grant
    Filed: January 21, 2000
    Date of Patent: November 25, 2003
    Assignee: Asahi Glass Company Ltd.
    Inventors: Shuichiro Sugimoto, Kyouichi Kaneko, Takashige Maekawa, Minako Shindo
  • Patent number: 6624242
    Abstract: An aqueous dispersion of (a) 0.1-40% by wt. of a low molecular weight, low melting point, water-insoluble polymer in which the polymer particles have a size <10 microns, and (b) 0.001-30% by wt. of an anionic emulsifier.
    Type: Grant
    Filed: August 8, 2001
    Date of Patent: September 23, 2003
    Assignee: ISP Investments Inc.
    Inventors: James F. Curry, Kolazi S. Narayanan, Ronald H. Goehner, Jr., Domingo I. Jon, George B. Beestman
  • Patent number: 6613824
    Abstract: Disclosed are flame retardant resinous compositions comprising (i) at least one aromatic polycarbonate; (ii) at least one of a second polymer having structural units derived from one or more monomers selected from the group consisting of vinyl aromatic monomers, monoethylenically unsaturated nitrile monomers, and C1-C12 alkyl (meth)acrylate monomers; (iii) at least one rubber modified graft copolymer; (iv) at least one polymeric or non-polymeric organic phosphorus species; (v) at least one antidrip agent; and (vi) at least one perfluoroalkanesulfonate salt present in an amount in a range between about 0.01 wt % and about 0.25 wt %, based on the weight of the entire composition. Also disclosed are methods for making said compositions.
    Type: Grant
    Filed: November 12, 2001
    Date of Patent: September 2, 2003
    Assignee: General Electric Company
    Inventors: John Robert Campbell, Thomas Miebach, Monica Marugan, Thomas Arnold Ebeling
  • Publication number: 20030105197
    Abstract: The invention relates to an improved water-based polymer coating composition comprising a polymer resin, water and surfactant. As an improvement over prior water-based polymer coating compositions an anionic and/or nonionic surfactant is present in an amount effective to plasticize the coating formed from the composition. A water-based polymer coating composition of the invention is also substantially free from cosolvents. The invention also relates to a method of coating a substrate and a substrate which has been coated with a coating formulation of the invention.
    Type: Application
    Filed: April 26, 2002
    Publication date: June 5, 2003
    Applicant: Eastman Chemical Company
    Inventors: Martha Jean Collins, Richard Alvin Martin, Rebecca Reid Stockl
  • Publication number: 20030065072
    Abstract: The invention relates to a process to make stabilized PVC wherein use is made of at least one compound of the formula 1
    Type: Application
    Filed: August 6, 2002
    Publication date: April 3, 2003
    Inventors: Daniel Stephan Van Es, Jacco Van Haveren, Augustinus Emmanuel Frissen, Johannes Cornelis Van Der Kolk, Gerard Hubert Frans Schmets, Hendrik Willem Huisman, Heather Blue Harvey
  • Patent number: 6503976
    Abstract: A coating composition for fabrics includes wetted microspheres containing a phase change material dispersed throughout a polymer binder, a surfactant, a dispersant, an antifoam agent and a thickener. Preferred phase change materials include paraffinic hydrocarbons. The microspheres may be microencapsulated. To prepare the coating composition, microspheres containing phase change material are wetted and dispersed in a dispersion in a water solution containing a surfactant, a dispersant, an antifoam agent and a polymer mixture. The coating is then applied to a fabric.
    Type: Grant
    Filed: December 11, 2000
    Date of Patent: January 7, 2003
    Assignees: Outlast Technologies, Inc., R. H. Wyner Associates, Inc.
    Inventors: Joseph L. Zuckerman, Robert J. Pushaw, Bernard T. Perry, Daniel M. Wyner
  • Patent number: 6492446
    Abstract: A latex compound for dip molding, which can be used for production of a high-quality dip-molded product that is excellent in oil resistance and mechanical strength, has uniform film thickness and soft feeling to the skin and is free of pinholes, as is required for gloves etc. especially in the medical fields, and assumes no stickiness on the surface of the molded product after molding. This object is attained by a latex compound for dip molding which comprises a copolymer latex (L) obtained by emulsion polymerization of a monomer mixture and 0.05 to 5.0 parts by weight of a bubble breaker (A) consisting of a C8-22 fatty acid or a salt thereof, and if necessary, 0.1 to 5.0 parts by weight of a di C5-12 alkyl sulfosuccinate salt (B) and/or 0.5 to 10.0 parts by weight of a C13-20 alkyl benzene sulfonate (C) per 100 parts by weight of the monomer mixture.
    Type: Grant
    Filed: June 16, 2000
    Date of Patent: December 10, 2002
    Assignee: Takeda Chemical Industries, Ltd.
    Inventors: Yuichiro Kajiwara, Masaaki Tsuji, Shigeo Suzuki, Takashi Suetsugu, Hiroshi Ban
  • Patent number: 6476099
    Abstract: A joint compound composition comprising a filler, a binder and a hydrocarbon substituted sulfate, sulfonate, sulfuric acid or sulfonic acid is disclosed. The composition of the present invention produces a joint compound that shrinks less and is resistant to cracking and cratering.
    Type: Grant
    Filed: November 28, 2000
    Date of Patent: November 5, 2002
    Assignee: United States Gypsum Company
    Inventors: Scott D. Cimaglio, Frank A. Wawrzos, Charles J. Miller
  • Publication number: 20020111436
    Abstract: A polymer composition containing carboxyl group which is excellent in water solubility, thickening properties and flow characteristics. This composition comprises (A) a crosslinked polymer comprising (a) an &agr;,&bgr;-unsaturated carboxylic acid and (b) a compound having at least two ethylenically unsaturated groups, and (B) at least one polymer selected from among polymers comprising vinylpyrrolidone as an essential monomer and polyethylene oxide.
    Type: Application
    Filed: November 15, 1999
    Publication date: August 15, 2002
    Inventors: MASATO FUJIKAKE, SHINJI KOBAYASHI, SHIGEKI HAMAMOTO, MITSUTAKA TABATA, TOMOKI KAWAKITA
  • Patent number: 6426377
    Abstract: The present invention relates to a process for improving the stability of aqueous polymer dispersions to thermal and/or mechanical effects and comprises adding to said aqueous polymer dispersions at least one salt of a bis-C4-C18-alkyl ester of a sulfonated dicarboxylic acid having 4 to 8 carbon atoms.
    Type: Grant
    Filed: July 14, 2000
    Date of Patent: July 30, 2002
    Assignee: BASF Aktiengesellschaft
    Inventors: Matthias Gerst, Bernhard Schuler, Burkhardt Dames
  • Patent number: 6369143
    Abstract: A radiation-sensitive polymer and a chemical amplification resist composition based on the polymer, which can be easily controlled in sensitivity by regulating the content and kind of the carboxylic acid-grafted norbornene derivatives in the matrix polymer and is superior in adherence to substrate and dry etch resistance, so that it can be formed into resist patterns improved in transparency, photosensitivity and resolution by use of KrF or ArF excimer lasers. The polymer is represented by the formula I: wherein, X is an acid-dissociable grafted norbornene derivative selected from the group consisting of the formulas II and III; Y is a carboxylic acid-grafted norbornene derivative represented by the formula IV, and l, m, n and o each are a repeating number not more than 0.5, satisfying the condition that l+m+n+o=l and 0.4≦o≦0.
    Type: Grant
    Filed: June 21, 1999
    Date of Patent: April 9, 2002
    Assignee: Korea Kumho Petrochemical Co., Ltd.
    Inventors: Joo-Hyeon Park, Seong-Ju Kim, Dong-Chul Seo, Sun-Yi Park
  • Patent number: 6353046
    Abstract: Improved fire-retarded properties can be imparted to polycarbonate resin composition by incorporating into the polycarbonate a fire-retardant component containing a perfluoroallkane sulfonate such as potassium perfluorobutane sulfonate and a cyclic siloxane such as octaphenylcyclotetrasiloxane. The fire-retardant component is suitably added at levels to form a polycarbonate composition in which the perfluoroalkane sulfonate is present in an amount of from 0.02 to 0.1 phr relative to the composition as a whole, and the cyclic siloxane is present in an amount of at least 0.02 relative to the composition as a whole.
    Type: Grant
    Filed: April 28, 2000
    Date of Patent: March 5, 2002
    Assignee: General Electric Company
    Inventors: Niles Richard Rosenquist, Rajendra Kashinath Singh, Jeffrey Hayward Wengrovius
  • Patent number: 6342550
    Abstract: The purpose of the present invention is to provide a flame-retardant polycarbonate resin composition which contains phosphorus-free flame-retardant(s), has an excellent impact resistance, an excellent heat resistance as well as an excellent moldability, and can satisfy a severe flammability level. According to the present invention, there is provided a flame-retardant polycarbonate resin composition which comprises (A) 100 parts by weight of an aromatic polycarbonate resin, (B) 0.01-5 parts by weight of an organic sulfonic acid metal salt, (C) 0.01-5 parts by weight of a fluorinated polyolefin, (D) 0.2-20 parts by weight of a diene-containing multi-layered polymer, and wherein the content of a phosphorus-containing flame-retardant is less than 0.5 parts by weight.
    Type: Grant
    Filed: November 15, 1999
    Date of Patent: January 29, 2002
    Assignee: Mitsubishi Engineering Plastics Corporation
    Inventors: Kazuhiko Ishii, Ken Shimomai
  • Publication number: 20020004541
    Abstract: Reduced pour point ethylene oxide/propylene oxide block copolymer surfactants, pour point depressants for reducing the pour point of such surfactants, and a process for preparing such surfactants, wherein the reduced pour point is achieved without adversely affecting the properties or structure of the parent ethylene oxide/propylene oxide block copolymer surfactant or contributing to the formation of a hazy product. According to the present invention, the pour point of ethylene oxide/propylene oxide block copolymer surfactants may be reduced by mixing a parent ethylene oxide/propylene oxide block copolymer surfactant with a pour point depressant comprising a low molecular weight glycol, water, and a dialkyl sulfosuccinate.
    Type: Application
    Filed: July 13, 2001
    Publication date: January 10, 2002
    Applicant: Huntsman Petrochemical Corporation
    Inventors: David Charles Lewis, Donald Hugh Champion
  • Patent number: 6329452
    Abstract: This invention relates to polyurethane compositions, and relates in particular to elastic polyurethane fibres resulting therefrom, which contain a dialkyl sulphosuccinate as an additive and/or which are finished with a polydialkylsiloxane, with a dialkyl sulphosuccinate and optionally with a mineral oil. As a result of this addition or of the preparation of the polyurethane composition or of the elastic polyurethane fibres with dialkyl sulphosuccinate, electrostatic charging of the polymer, such as that which occurs during the processing of warp-knitted fabric made of polyurethane fibres for example, is suppressed.
    Type: Grant
    Filed: February 5, 1999
    Date of Patent: December 11, 2001
    Assignee: Bayer Aktiengesellschaft
    Inventor: Stephan Hütte
  • Patent number: 6232381
    Abstract: The process of this invention can be utilized to stabilize tin-coupled rubbery polymers. This process involves adding a chelating diamine or a sodium alkoxide to the rubbery polymer after the tin coupling has been carried out. This invention more specifically discloses a process for improving the stability of a tin-coupled rubbery polymer which comprises adding a sodium alkoxide to the tin-coupled rubbery polymer subsequent to the time at which the tin-coupled rubbery polymer is coupled. Sodium alkoxide is a representative example of a sodium alkoxide that can be used to stabilize the tin-coupled rubbery polymer.
    Type: Grant
    Filed: July 30, 1999
    Date of Patent: May 15, 2001
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Wen-Liang Hsu, Adel Farhan Halasa
  • Patent number: 6207738
    Abstract: A coating composition for fabrics includes wetted microspheres containing a phase change material dispersed throughout a polymer binder, a surfactant, a dispersant, an antifoam agent and a thickener. Preferred phase change materials include paraffinic hydrocarbons. The microspheres may be microencapsulated. To prepare the coating composition, microspheres containing phase change material are wetted and dispersed in a dispersion in a water solution containing a surfactant, a dispersant, an antifoam agent and a polymer mixture. The coating is then applied to a fabric.
    Type: Grant
    Filed: May 5, 1997
    Date of Patent: March 27, 2001
    Assignee: Outlast Technologies, Inc.
    Inventors: Joseph L. Zuckerman, Robert J. Pushaw, Bernard T. Perry, Daniel M. Wyner
  • Patent number: 6153304
    Abstract: Articles of manufacture are provided with a low surface energy, permanently non-stick, non-fouling and ice-phobic surface by a system of coating comprising applying a primary coating having a surface energy of 22-28 dynes/cm.sup.2 comprising a novel polymeric material having non-stick and hardness properties and then applying a top coating having lower surface energy of from about 18-21 dynes/cm.sup.2 comprising a siliconic polymer and interdigitating means to make the top coating permanent, the means preferably comprising a bi- or polyfunctional organic compound adapted to wet the surface of the primary coating and chemically or physically bond thereto and to couple to the siliconic polymeric substance in the top coating. The coated substrates are resistant to marking by graffiti, to adherence by marine fouling organisms, and frozen ice on the surface is easily removed.
    Type: Grant
    Filed: August 13, 1999
    Date of Patent: November 28, 2000
    Assignee: Decora Incorporated
    Inventors: John Ralph Smith, Nissim N. Garti
  • Patent number: 6150455
    Abstract: A thermostable polymer electrolyte gel containing an acrylonitrile polymer, an electrolyte and a solvent, the acrylonitrile polymer having an acrylonitrile content of from 89 wt % to 98 wt % and meeting the following relationship:1,040,000-(A.times.10,000).ltoreq.B.ltoreq.1,490,000-(A.times.10,000)where A is the acrylonitrile content in wt % and B is the weight average molecular weight of the acrylonitrile polymer, the polymer electrolyte gel having an ion conductivity of 10.sup.-3 S/cm or higher at 20.degree. C., exhibiting the "retention of shape" in a thermostability test, and containing the acrylonitrile polymer in a proportion of from 3 wt % to 9 wt %. The thermostable polymer electrolyte gel can be produced by dissolving an acrylonitrile polymer and an electrolyte in a solvent to prepare a solution of the polymer, and cooling the polymer solution to a temperature of 0.degree. C. or lower.
    Type: Grant
    Filed: November 4, 1997
    Date of Patent: November 21, 2000
    Assignees: Toyo Boseki Kabushiki Kaisha, Japan Exlan Company, Ltd.
    Inventors: Hiroyuki Takamiya, Ryosuke Nishida, Tatsuaki Sumitani
  • Patent number: 5919854
    Abstract: Aqueous dispersions of cationic water-soluble polymers are provided, as well as processes for making and methods of using the same.
    Type: Grant
    Filed: October 3, 1996
    Date of Patent: July 6, 1999
    Assignee: Cytec Technology Corp.
    Inventors: Sun-Yi Huang, Louis Rosati, Joseph J. Kozakiewicz
  • Patent number: 5916635
    Abstract: This invention relates to water-based hydrophilic coatings suitable for giving hydrophilicity primarily to the surface of aluminum and to a process for manufacturing precoated fin materials for heat exchangers with use of said coatings. The coatings are composed of colloidal silica with a dispersed particle diameter of 5 to 100 nm, water-soluble polymers containing at least carboxylic acid polymers, anionic surfactants and water; the colloidal silica and the water-soluble polymers are present at a weight ratio of 30:70 to 70:30 on a solid basis in a combined content of 4 to 20% by weight, the content of carboxyl group in the carboxylic acid polymers contained in the water-soluble polymers is 20 to 63% by weight, the anionic surfactants are alkali salts of sulfosuccinic acid monoalkyl esters with alkyl groups containing 1 to 18 carbon atoms and present in an amount of 5 to 20% by weight of the combined solid content of the colloidal silica and the water-soluble polymers, and the pH is 1 to 5 as a whole.
    Type: Grant
    Filed: March 26, 1998
    Date of Patent: June 29, 1999
    Assignee: Nippon Light Metal Company, Ltd.
    Inventors: Toru Ishii, Kazuhiko Yamazaki, Reiko Takasawa
  • Patent number: 5882780
    Abstract: Elastic polyester fibers having a high anti-cohesive property (separability) include (A) a polyester elastomer and (B) 0.2 to 10%, based on the weight of the elastomer, of an anti-cohesive agent including (a) at least one alkali metal salt of organic sulfonic acid of the formula: R.sup.1 --S0.sub.3 M, wherein R.sup.1 =C.sub.5-25 hydrocarbon group, M=alkali metal, and (b) at least one compound of the formulae (2)-(6): R.sup.2 --X.sub.p --CH.sub.2 CH.sub.2 OH (2), R.sup.3 --COO--CH.sub.2 CH(OH)CH.sub.2 OH (3), R.sup.4 --COO--(CH.sub.2 CH.sub.2 O).sub.m --H (4), R.sup.5 --O--(CH.sub.2 CH.sub.2 O).sub.n H (5) and R.sup.6 --CONHCH.sub.2 CH.sub.2 NHCO--R.sup.7 (6), wherein R.sup.2 -R.sup.7 =C.sub.5-25 hydrocarbon group, X=--CONY or ##STR1## group, p=0 or 1, m, n=5 to 50.
    Type: Grant
    Filed: July 3, 1997
    Date of Patent: March 16, 1999
    Assignee: Teijin Limited
    Inventors: Yasuo Yamamura, Mikio Tashiro, Yasuyuki Yamazaki, Takeshi Honjou, Nobuyuki Yamamoto, Michihiro Yamada
  • Patent number: 5830929
    Abstract: Thermoplastic concentrates comprising inorganic pigments, such as titanium dioxide, treated with a dialkyl sulfosuccinate treating agent, of the formula ROOCCHSO.sub.3 MCH.sub.2 COOR', where R and R' are monovalent alkyl radicals containing from about 2 to about 20 carbon atoms and M is a metallic monovalent cation, are disclosed. Such treatment improves the dispersibility of the pigments in thermoplastic resins. The treatment also enables the production of thermoplastic concentrates comprising a high percentage of treated inorganic pigment dispersed in a thermoplastic resin.
    Type: Grant
    Filed: January 24, 1997
    Date of Patent: November 3, 1998
    Assignee: Kerr-McGee Chemical Corporation
    Inventor: Rodney D. Stramel
  • Patent number: 5804611
    Abstract: The present invention relates to a composition used for hydrophilization, which comprises:(A) a compound having a polyoxyalkylene chain, and(B) hydrophilic crosslinked polymer fine particles made of a copolymer composed of:2-50% by weight of (a) a hydrophilic monomer having a polymerizable double bond and a polyoxyalkylene or polyvinylpyrrolidone chain,20-97% by weight of (b) a (meth)acrylamide type monomer,1-30% by weight of (c) a crosslinkable unsaturated monomer,2-50% by weight of (d) a carboxyl group-containing polymerizable unsaturated monomer, and0-50% by weight of (e) a monomer having one polymerizable unsaturated group in the molecule, other than the monomers (a), (b), (c) and (d).Said composition can form a hydrophilic film superior in retention of hydrophilicity, stability and press formability, on, for example, the surfaces of heat exchanger fins.
    Type: Grant
    Filed: September 18, 1996
    Date of Patent: September 8, 1998
    Assignee: Kansai Paint Co., Ltd.
    Inventors: Noboru Takoh, Masahiro Kondo, Hiroshi Inoue
  • Patent number: 5747570
    Abstract: Water-absorbing resin compositions obtained by adding a water-soluble thiol compound in the process of drying or pulverizing a hydrogel of a water-absorbing resin which is obtained by polymerizing a water-soluble monomer having a polymerizable unsaturated group optionally with a polysaccharide, in the presence of a crosslinking agent and water. Composition of the present invention are highly efficient in water absorption and safe for having extremely low amounts of residual monomer and water-soluble component.
    Type: Grant
    Filed: October 4, 1995
    Date of Patent: May 5, 1998
    Assignee: Sanyo Chemical Industries, Ltd.
    Inventors: Masashi Date, Keiji Tanaka, Tsuyoshi Yuki, Kenjiro Tsubota, Satoshi Tamabuchi
  • Patent number: 5721299
    Abstract: Electrically conductive and abrasion resistant polymeric compositions, methods of fabrication thereof and uses thereof are described. Admixtures of abrasion resistant materials and electrically conductive polymeric materials are formed. Many of these admixtures are light transmitting and can be used as an abrasion resistant light transmitting electrostatic discharge layers. The light transmitting discharge layer is useful as a surface coating for visual displays such as CRT screens to avoid electrostatic accumulation of dust and scratching.
    Type: Grant
    Filed: February 9, 1994
    Date of Patent: February 24, 1998
    Assignee: International Business Machines Corporation
    Inventors: Marie Angelopoulos, Ali Afzali-Ardakani, Jack A. Dickerson, Thomas B. Pillsbury, Karl J. Puttlitz, Jane M. Shaw, Jeffrey D. Gelorme
  • Patent number: 5660890
    Abstract: This invention relates to a water-based coating comprising as separate components (A) a grind component comprising in admixture (1) a water compatible overbased alkaline earth alkyl-aryl sulfonate; (2) an organic amine; and (3) an inorganic borate corrosion inhibitor; and (B) a liquid component comprising (1) water; (2) an acrylic emulsion; (3) an organic amine. The coatings are particularly useful for coating ferrous metal surfaces.
    Type: Grant
    Filed: September 30, 1996
    Date of Patent: August 26, 1997
    Assignee: Ashland Inc.
    Inventors: Rosanna Pall Rudy, Andrew Anthony Romano
  • Patent number: 5659058
    Abstract: A process for rendering polymer compositions antistatic and the products of such process are described. The polymeric material is treated with a combination of selected trineoalkoxy amino zirconates and trineoalkoxy sulfonyl zirconates. These latter materials are soluble in the polyolefins, polyesters, polyamides, polyethers, polycarbonates, and polystyrenes and remain stable during the processing of these polymers. Furthermore, the antistatic agents of the invention are thermally stable to temperatures up to 825.degree. F., do not "bloom" during the polymer processing, and are colorless, permanent, non-blooming and non-moisture dependent.
    Type: Grant
    Filed: May 31, 1995
    Date of Patent: August 19, 1997
    Assignee: Kenrich Petrochemicals, Inc.
    Inventor: Salvatore Joseph Monte
  • Patent number: 5624992
    Abstract: An aqueous polymer dispersion with a solids volume concentration of at least 50% by volume is obtainable by polymerizing monomers by the method of free radical aqueous emulsion polymerization with the addition of at least one fine and at least one coarse aqueous starting polymer dispersion.
    Type: Grant
    Filed: March 29, 1995
    Date of Patent: April 29, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Oral Aydin, Michael Portugall, Josef Neutzner, Walter Maechtle
  • Patent number: 5621030
    Abstract: The present invention is directed to a printable release composition used for pressure sensitive labels and the like. The invention is also directed to an article, such as a label, that comprises a substrate such as paper, optionally a thermal transfer primer coating coated onto the substrate and a release layer coated onto the transfer primer coating or onto the substrate. The printable release composition of the present invention may be used with labels having permanent, repositionable or removable adhesives. The particular composition of the release layer depends on the type of adhesive that is appropriate for the desired end use.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: April 15, 1997
    Assignee: Moore Business Forms, Inc.
    Inventors: Adele C. Shipston, David K. Rice, II
  • Patent number: 5605948
    Abstract: The invention relates to a polymer mixture which comprises the following constituents: Ai) a graft copolymer built up from a rubber-like graft base consisting substantially of a butadiene rubber, on which one or more vinylaromatic monomeric compounds and one or more unsaturated nitrile monomeric compounds have been grafted or Aii) a mixture of Ai and an aromatic polycarbonate, and B) a copolyether ester block copolymer having a polyether block which is derived from an ethylene-oxide-capped poly-(propylene oxide)glycol, having an ethylene oxide content of 15-35% by weight and a number-averaged molecular weight of 1,500-3,000.
    Type: Grant
    Filed: April 11, 1995
    Date of Patent: February 25, 1997
    Assignee: General Electric Company
    Inventors: Jean-Marie G. L. Dumont, Johannes J. de Bont, Johannes C. Gosens, Ronald van der Wal
  • Patent number: 5605737
    Abstract: A white-colored porous polymer film having elongated spherical pores, which is characterized in that said pores exposed on a surface created by cutting the film along longitudinal direction satisfy the following formulae, possesses a low density, good surface and mechanical property and good processability: ##EQU1## wherein, P.sub.L,90 is an average length of longer axes of 90% or more of the exposed pores;P.sub.D,90 is an average length of shorter axes of 90% or more of the exposed pores;P.sub.L/D,50 is an average of the longer axis to the shorter axis length ratios of the exposed pores;P.sub.N is the number of exposed pores per 1000 .mu.m.sup.2 of the exposed surface; andP.sub.A is the ratio of the exposed pore area to the exposed surface area.The polymer film of the present invention comprises a polyester and polyolefin resin mixture, inorganic particles, a metal sulfonate and a hindered phenol.
    Type: Grant
    Filed: April 8, 1996
    Date of Patent: February 25, 1997
    Assignee: SKC Limited
    Inventors: Young-Jin Lee, Sang-Il Kim, Bum-Sang Kim
  • Patent number: 5574101
    Abstract: An acrylic resin composition comprising at least one polyamide elastomer consisting of hard segments and soft segments in a specified ratio, an acrylic resin and optionally at least one electrolyte, which has excellent permanent antistatic properties, is good in transparency, has a very faint color, is inexpensive, and is only slightly deteriorated in transparency even when immersed in water.
    Type: Grant
    Filed: May 26, 1995
    Date of Patent: November 12, 1996
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Kiyoshi Kawakami, Yuzuru Ishibashi, Toshio Suzuki
  • Patent number: 5548009
    Abstract: A process for improving the storage life of a one-component silicone paste containing an alkali metal phosphate and which cures with elimination of acetic acid on exposure to atmospheric moisture, which comprises adding to such paste an acidic additive bearing the functional group --SO.sub.3 H or hydrogen chloride in a concentration sufficient to convene the alkali metal phosphate into the alkali metal salt of the acidic additive.
    Type: Grant
    Filed: April 26, 1994
    Date of Patent: August 20, 1996
    Assignee: Bayer Aktiengesellschaft
    Inventors: Wilhelm Weber, Karl-Heinz Sockel, Hans-Heinrich Moretto
  • Patent number: 5521238
    Abstract: The present invention relates to an organopolysiloxane emulsion composition comprising a hydroxy or alkoxy-endblocked diorganopolysiloxane, an alkoxy-group containing organosilicon compound, surfactant, and water. The compositions of this invention are characterized by a lack of offensive odor, high productivity and good storage stability. The organopolysiloxane emulsions of this invention are useful as fiber treatment agents. The fibers treated with the organopolysiloxane emulsion of this invention exhibit good feel.
    Type: Grant
    Filed: December 22, 1994
    Date of Patent: May 28, 1996
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Isao Ona, Masaru Ozaki, Toshio Saruyama, Masahiko Suzuki
  • Patent number: 5494952
    Abstract: A process for the production of a stabilized polycarbonate which comprises melt-polycondensing an aromatic dihydroxy compound and a carbonic acid diester in the presence of a polycondensation catalyst and then, after the reaction mixture shows an intrinsic viscosity of at least 0.1, adding at least one stabilizer selected from the group consisting of specific compounds having a sulfanate group and a sulfonic acid anhydride group in an amount of 0.01 to 500 ppm of a polycarbonate to be formed, to form a polycarbonate having a desired intrinsic viscosity.
    Type: Grant
    Filed: May 10, 1995
    Date of Patent: February 27, 1996
    Assignee: Teijin Limited
    Inventors: Masumi Hirata, Wataru Funakoshi, Katsushi Sasaki
  • Patent number: 5492950
    Abstract: There is provided a mixture of acrylic emulsion polymers based on 70 to 95 parts by weight of a first polymer containing from about 95 to 97.5% by weight of an alkyl ester of acrylic acid and from about 2.5 to 5% by weight of a mixture of carboxylic acids tackified by a second acrylic emulsion polymer containing 10 to 20% by weight of carboxylic acid or hydroxyethyl methacrylate.
    Type: Grant
    Filed: March 23, 1993
    Date of Patent: February 20, 1996
    Assignee: Avery Dennison Corporation
    Inventors: Ian Brown, Stuart A. Harris
  • Patent number: 5431726
    Abstract: A tire gel balancing composition having a Storage modulus of between 3000 and 15000 Pa and the Specific Gravity less than 1000 kg/m.sup.3 in the temperature range between -20.degree. and +90.degree. C., preferably its Storage modulus is about 9000 Pa, is capable of balancing tires by being able to flow under the vibrations caused by imbalance in a wheel assembly. The composition preferably comprises a mixture of: 1) paraffinic oils, polybutene oils, polyol esters, including castor oil, or polyol ethers; 2) hydrophobic or hydrophilic fumed silica; 3) polyalkyl-methacrylates, styrene-ethylene-propylene block copolymers or polyhydroxycarboxylic acid derivatives; and optionally corrosion inhibitors and antioxidants.
    Type: Grant
    Filed: August 1, 1991
    Date of Patent: July 11, 1995
    Assignee: Performance Products Corporation
    Inventor: Alvin Ronlan
  • Patent number: 5426142
    Abstract: The present invention relates to the preparation of aqueous based polymers bearing reactive functional groups. More particularly, this invention relates to waterborne or water dispersed polymers that are equivalent in performance in applications formerly dominated by solvent based polymers.Polymers of the present invention have many uses including adhesives, saturant applications, solutions or dispersions in water or water-cosolvent mixtures, and are most useful as coatings and sealants for wood, glass, metal, concrete and binders for mortars and non-wovens.More specifically, surface coatings produced from polymers of the present invention exhibit improved properties such as: for example, durability, toughness, solvent resistance, dirt pickup resistance, print and block resistance and mar resistance.
    Type: Grant
    Filed: August 25, 1993
    Date of Patent: June 20, 1995
    Assignee: Rohm and Haas Company
    Inventors: William J. Rosano, Frederick J. Schindler
  • Patent number: 5405894
    Abstract: A corrosion protection composition comprising a thermoplastic elastomeric block copolymer, a colloidal size amorphous overbased sulphonate of an alkaline earth metal, a tackifier resin and optionally a plasticizer for the block copolymer.
    Type: Grant
    Filed: June 17, 1993
    Date of Patent: April 11, 1995
    Assignee: Exxon Chemical Patents Inc.
    Inventor: Robert D. M. Best
  • Patent number: 5403879
    Abstract: The polyester film of the present invention comprising titanium compound, silica compound, fluorescent pigment and antistatic agent as additives is a white-colored, opaque film and has low gloss, superior surface printing and antistatic properties, and increased resistance against discoloring. The film is useful in manufacturing white boards, various magnetic cards, printing paper, packaging materials and the like.
    Type: Grant
    Filed: June 6, 1994
    Date of Patent: April 4, 1995
    Assignee: SKC Limited
    Inventors: Sang-Il Kim, Moon-Sun Kim
  • Patent number: 5395870
    Abstract: There are disclosed a vinyl resin composition which comprises a resin composition comprising a vinyl polymer, a polyamideimide elastomer obtained by reacting a mixture of caprolactam, an aromatic polycarboxylic acid and a specified polyoxyethylene glycol, with 0-0.5 mole of a diamine, etc., per 1 mole of glycol contained in said mixture, the glycol component being present in a proportion of 85-30% by weight in said elastomer and the relative viscosity of the elastomer being at least 1.5 (at 30.degree. C.), and an electrolyte added as desired, and articles molded from the composition.
    Type: Grant
    Filed: October 25, 1993
    Date of Patent: March 7, 1995
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Yoshio Suzuki, Masashi Sakamoto
  • Patent number: 5382613
    Abstract: A polyphenylene ether molding composition which contains at least one alkylsulfonate as antistatic and at least one light stabilizer of the formula III ##STR1## has better antistatic properties and greater light stability than is the case for simultaneous use of alkylsulfonates and previously known light stabilizers, such as, for example, tetramethylpiperidinyl derivatives.
    Type: Grant
    Filed: September 27, 1993
    Date of Patent: January 17, 1995
    Assignee: Hoechst AG
    Inventors: Klaus-Dieter Bergner, Gerhard Pfahler