Sulfur Bonded Directly To Nitrogen Patents (Class 524/168)
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Patent number: 5032633Abstract: Thermoplastic molding compositions that contain(A) 10 to 90 parts by weight of polyamide 12, and 90 to 10 parts by weight of polyamide 10,12 and/or polyamide 12,12; and(B) 0 to 25 wt. % of a plasticizer, exhibit improved low temperature impact strength. The molding compositions may be used for the production of molded objects, especially tubes.Type: GrantFiled: February 28, 1990Date of Patent: July 16, 1991Assignee: Huels AktiengesellschaftInventors: Michael Schlobohm, Franz-Josef Schlautmann
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Patent number: 5025041Abstract: Pearlescent coating compositions comprising a resin binder system, coated mica particles and a manganese salt of an azo pigment, these coating compositions being of particular value in two coat automotive paint systems wherein the pearlescent composition is applied as the base coat which is covered with a clear top coat to provide paint systems with intense color, high pearlescence and excellent durability.Type: GrantFiled: June 15, 1989Date of Patent: June 18, 1991Assignee: Ciba-Geigy CorporationInventors: Johannes Pfenninger, Edward E. Jaffe
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Patent number: 4987168Abstract: Molding compositions of thermoplastic plasticizer-containing polyamides exhibit greatly reduced migration of plasticizer or no migration at all due to having 0.1 to 20% by weight of sterically hindered carbodiimides of the formulaR.sub.1 --N.dbd.C.dbd.N--[R.sub.2 --N.dbd.C.dbd.N].sub.2 --R.sub.3wherein n is 0 to 100; R.sub.1 and R.sub.3 are individually a monovalent radical taken from the class consisting of aliphatic having 1 to 20 carbon atoms, cycloaliphatics having 6 to 20 carbon atoms, and aromatics having 8 to 20 carbon atoms and also having substituents; and R.sub.2 is a divalent radical taken from the class consisting of aliphatics having 1 to 20 carbon atoms, cycloaliphatic having 6 to 20 carbon atoms, and aromatics having 8 to 20 carbon atoms and also having substituents.Type: GrantFiled: June 9, 1989Date of Patent: January 22, 1991Assignee: EMS-Inventa AGInventor: Franz Kerschbaumer
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Patent number: 4968737Abstract: Molding compounds comprising aromatic polyamides which contain from 0.001 to 10% by weight of a low molecular weight sulfonic acid amide display low melt viscosities and an increased resistance to hydrolysis and are thermoplastically processible.Type: GrantFiled: February 27, 1989Date of Patent: November 6, 1990Assignee: Huels AktiengesellschaftInventors: Juergen Finke, Martin Bartmann, Friedrich-Georg Schmidt
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Patent number: 4929652Abstract: The invention relates to polyolefines stabilized against damage caused by light and containing(A) at least one polyalkylpiperidine light stabilizer,(B) an organic salt of zinc or magnesium and(C) either(C.sub.1) a UV absorber or(C.sub.2) a pigment or(C.sub.3) a UV absorber and a pigment.Type: GrantFiled: April 27, 1988Date of Patent: May 29, 1990Assignee: Ciba-Geigy CorporationInventor: Francois Gugumus
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Patent number: 4910243Abstract: Dinonylnaphthalene sulfonic acid, derivatives thereof and mixtures of any of them, are effective as dispersants for nonaqueous fluid compositions containing finely divided solid particles when added in an effective amount less than that necessary to act as a catalyst for any organic binder resin comprising an aminoplast and coreactants in the composition or in formulations made from the composition.Type: GrantFiled: December 23, 1987Date of Patent: March 20, 1990Assignee: King Industries, Inc.Inventors: Rudolph Berndlmaier, Richard J. Shain
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Patent number: 4837258Abstract: A flame retardant, impact resistant carbonate polymer composition comprising a mixture of one or more carbonate polymers, an impact modifying quantity of a rubbery polymer containing residual ethylenic unsaturation, a fluorine containing polymer of the fibril forming type flame retarding quantities of an aromatic sulfur containing compound and a chlorine or bromine substituted organic compound, and, optionally a melt stability enhancing quantity of an organoposphorus compound.Type: GrantFiled: August 4, 1988Date of Patent: June 6, 1989Assignee: The Dow Chemical CompanyInventors: Michael K. Laughner, Samuel A. Ogoe
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Patent number: 4826902Abstract: A coating composition based on an acrylic resin which is useful for preparing lubricated steel products such as steel sheets or tubes is disclosed. The coating composition contains as additives a rust preventive which is a mixture of a sulfonamidecarboxylic acid and an cyclic amine and a water repellent. It exhibits improved rust-preventing properties when lubricated steel products having a coating film formed from the coating composition are stored for a prolonged period under coiled or stacked conditions.Type: GrantFiled: March 11, 1988Date of Patent: May 2, 1989Assignees: Nippon Oil & Fats Co., Ltd., Sumitomo Metal Industries, Ltd.Inventors: Hiroki Hanabata, Hideo Kawaguchi, Hiroshi Fukudome, Ryoichi Noumi, Hiromi Izaiku, Koichi Komai, Kisuke Yoshida
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Patent number: 4820346Abstract: A hot-melt ink for an ink jet printer is formed from a solid organic solvent having a melting point less than 150.degree. C. and a low molecular weight thermosetting resin having a high hydroxyl number, together with a dye. The ink has excellent jetting characteristics, forms a hard, stable print raised above the surface of the substrate, provides high dot resolution, and remains colorfast both in the ink jet printer and on the paper, even when exposed to continued high temperatures. It is non-toxic and odorless, and eminently suitable for office document preparation and other applications. In a preferred embodiment, the inks comprise color subtractive dyes, making them suitable for use in multi-color printing.Type: GrantFiled: March 31, 1987Date of Patent: April 11, 1989Assignee: Howtek, Inc.Inventor: Michael T. Nowak
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Patent number: 4782103Abstract: Ultra violet light resistant polycarbonates are produced having processing or heat stability by adding compatible UV absorbing compounds and aromatic sulfonimides. The UV absorbing compounds are used in amounts from about 0.01 to about 5.0% by weight and the sulfonimides are used in an amount from about 0.0001 to about 10.0%. The preferred UV absorber is 2-(2'-hydroxy-5'-t-octylphenyl)-benzotriazole. The preferred sulfonimide is N-(p-tolylsulfonyl)-p-toluenesulfonimide.Type: GrantFiled: August 19, 1987Date of Patent: November 1, 1988Assignee: The Dow Chemical CompanyInventor: Samuel A. Ogoe
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Patent number: 4727101Abstract: A carbonate polymer composition comprising a carbonate polymer such as a bisphenol-A homopolycarbonate which carbonate polymer contains an amount of a salt represented by the formula: ##STR1## wherein Ar is an aromatic group, R is a monovalent organic moiety, or Ar and R collectively are a divalent aromatic moiety M is a cation, and n is a number corresponding to the valence of M and an amount of a free aromatic sulfimide, which carbonate polymer composition resists combustion upon exposure to an ignition source, exhibits good optical properties, and exhibits molecular weight stability. Optionally, a halogenated organic compound may be added to the composition.Type: GrantFiled: June 26, 1986Date of Patent: February 23, 1988Assignee: The Dow Chemical CompanyInventors: Samuel A. Ogoe, Hani Farah, Kevin F. Dick, Grace M. Willis
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Patent number: 4626563Abstract: Flame retardant carbonate polymers containing an aromatic sulfimide, a monomeric or polymeric halogenated organic compound, a metal sulfate having a pka from 1 to 5 and a fibril forming polytetrafluoroethylene as additives in effective amounts give carbonate polymers that are not only flame retardant but are melt stable i.e. show little loss in molecular weight during processing or melt shearing.Type: GrantFiled: April 24, 1985Date of Patent: December 2, 1986Assignee: The Dow Chemical CompanyInventors: Samuel A. Ogoe, Kevin F. Dick
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Patent number: 4579898Abstract: The drop in melt index observed when linear polyethylenes are melt processed is reduced by adding a small amount, e.g., about 0.01 to 2 weight percent of an aromatic sulfonhydrazide such as p-toluenesulfonhydrazide.Type: GrantFiled: December 24, 1984Date of Patent: April 1, 1986Assignee: Mobil Oil CorporationInventors: Peter J. Canterino, Fred C. Schwab
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Patent number: 4558081Abstract: A carbonate polymer such as a bisphenol-A homopolycarbonate containing a small amount of (1) a metal salt of an aromatic sulfonamide or a metal salt of an inorganic acid, such as a metal salt of a perhalometalate complex, (2) a halogenated organic compound and, (3) a melamine, exhibits improved flame retardant properties.Type: GrantFiled: October 26, 1984Date of Patent: December 10, 1985Assignee: The Dow Chemical CompanyInventor: Lowell S. Thomas
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Patent number: 4510279Abstract: A methacrylate resin composition for optical information recording medium, excellent in releasability from mold, consisting of (A) 100 parts by weight of a methacrylate resin and (B) 0.1 to 3.0 parts by weight of a surface active agent having a fluoroalkyl group.Type: GrantFiled: August 6, 1982Date of Patent: April 9, 1985Assignees: Mitsubishi Rayon Co., Ltd., Sony CorporationInventors: Masaaki Kishimura, Nobuyuki Arakawa
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Patent number: 4457930Abstract: 3-Iodopropargyl-sulphamides of the formula ##STR1## in which R represents hydrogen, alkyl, optionally substituted cycloalkyl, optionally substituted phenylalkyl, optionally substituted heterocyclylalkyl or optionally substituted phenyl, andR.sup.1 and R.sup.2 are identical or different and represent alkyl, orR.sup.1 and R.sup.2 represent an alkylene bridge which, together with the nitrogen atom at which they are located, form a ring which can be interrupted by further hetero atoms,which are microbicidally active.Type: GrantFiled: August 26, 1983Date of Patent: July 3, 1984Assignee: Bayer AktiengesellschaftInventors: Hans-Georg Schmitt, Wilfried Paulus, Hermann Genth, Wilhelm Brandes, Paul Reinecke, Hans Scheinpflug
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Patent number: 4452855Abstract: The adhesion of fibrous polymeric aromatic amide reinforcing material to rubber stock is improved by treating the fibrous material with an aliphatic sulfonylazide having the general formula R(Cl).sub.x (SO.sub.2 N.sub.3).sub.y, where R is an aliphatic or cycloaliphatic hydrocarbon radical containing at least 5 carbon atoms, y is from about 1 to about 4 and x is from 0 up to about 2y; heating the treated fibrous material at a temperature and for a period of time sufficient to decompose substantially all the sulfonylazide groups; then coating the resulting material with an adhesive; and finally, embedding the coated material into rubber stock which is then vulcanized.Type: GrantFiled: February 11, 1983Date of Patent: June 5, 1984Assignee: Hercules IncorporatedInventors: Gregory I. Brodsky, Bernard J. Scheve
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Patent number: 4435172Abstract: Absorbent articles are rendered more blood absorptive by incorporating water soluble amido compounds having the formulaH.sub.2 N--X--NH.sub.2where X is --CO--, --CS--, --SO-- or --SO.sub.2 --, and nonionic surfactants into the articles.Type: GrantFiled: September 22, 1982Date of Patent: March 6, 1984Assignee: The Dow Chemical CompanyInventor: James R. Gross
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Patent number: 4429063Abstract: Anaerobically curable sealant and adhesive compositions comprising polymerizable acrylate esters or methacrylate esters and a redox system as accelerator are stabilized by the addition of sulfamide derivatives containing the group ##STR1## The stabilization may be further improved by using the sulfamides in combination with phenolic anti-oxidants, particularly sterically hindered phenols, without reducing the curing rate of the compositions.Type: GrantFiled: September 15, 1982Date of Patent: January 31, 1984Assignee: W. R. Grace & Co.Inventor: Karl Reich
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Patent number: 4426476Abstract: Textiles are rendered water and oil resistant by contacting them with a composition containing water-insoluble fluoroaliphatic radical- and aliphatic chlorine-containing ester and water-insoluble fluoroaliphatic radical-containing polymer.Type: GrantFiled: February 3, 1982Date of Patent: January 17, 1984Assignee: Minnesota Mining and Manufacturing CompanyInventor: John C. C. Chang
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Patent number: 4418170Abstract: A method for stabilizing organic polymers against copper-catalyzed oxidative decomposition by means of N,N-bis-salicyloyl hydrazine as a metal deactivator is described wherein dust development of the metal deactivator is precluded with certainty and negative property changes of the stabilized organic polymers are avoided. For this purpose, it is provided that a paste which contains finely-crystalline N,N'-bis-salicyloyl hydrazine in fine distribution in a liquid to wax-like aliphatic hydrocarbon of low volatility is worked into the polymer. The method is particularly well suited for stabilizing polyolefins for cable and wire insulation.Type: GrantFiled: July 19, 1982Date of Patent: November 29, 1983Assignee: Siemens AktiengesellschaftInventors: Wolfgang von Gentzkow, Manfred Schmiedel
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Patent number: 4414347Abstract: A rapid setting .alpha.-cyanoacrylate-based adhesive composition having an improved stabilizer therein. The stabilizer is a sulfamide derivative containing the group ##STR1## Stabilizing may be further improved by using the sulfamides in combination with phenolic anti-oxidants, particularly sterically hindered phenols, without reducing the curing rate of the composition.Type: GrantFiled: September 15, 1982Date of Patent: November 8, 1983Assignee: Teroson GmbHInventors: Karl Reich, Heinz Sieger
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Patent number: 4382798Abstract: An anti-soiling treating agent comprising(a) a perfluoroalkyl-containing hybrid urethane compound (I) resulting from the addition reaction of two perfluoroalkyl-containing alcohols which have a difference in melting point of at least 20.degree. C. and are selected from compounds of the following formulaRf--A--B--OHwherein Rf represents a linear or branched perfluoroalkyl group, A is the group --CH.sub.2 --.sub.Type: GrantFiled: August 10, 1981Date of Patent: May 10, 1983Assignee: Dainippon Inc. & Chemicals Inc.Inventors: Yasuyuki Suzuki, Tadashi Ito
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Patent number: 4352904Abstract: Polyethylene terephthalate resin compositions containing filler or reinforcing agent, a selected sodium or potassium salt of a hydrocarbon acid or a salt of a selected organic polymer containing pendant carboxyl groups, and a selected low molecular weight organic ester, ketone, sulfone, sulfoxide, nitrile or amide. Articles molded from the compositions have high gloss when molded at temperatures below 110.degree. C.Type: GrantFiled: January 5, 1979Date of Patent: October 5, 1982Assignee: E. I. Du Pont de Nemours and CompanyInventor: Edward J. Deyrup
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Patent number: RE32334Abstract: Polyethylene terephthalate resin compositions containing filler or reinforcing agent, a selected sodium or potassium salt of a hydrocarbon acid or a salt of a selected organic polymer containing pendant carboxyl groups, and a selected low molecular weight organic ester, ketone, sulfone, sulfoxide, nitrile or amide. Articles molded from the compositions have high gloss when molded at temperatures below 110.degree. C.Type: GrantFiled: March 11, 1986Date of Patent: January 20, 1987Assignee: E. I. Du Pont de Nemours and CompanyInventor: Edward J. Deyrup