Two Or More N-n Bonds Patents (Class 524/192)
  • Patent number: 11884846
    Abstract: Described is an adhesive composition in the form of an aqueous polymer dispersion comprising tackifiers, a compound crosslinking via keto or aldehyde groups and a pressure-sensitive adhesive polymer which is formed by emulsion polymerization from soft (meth)acrylic ester monomers, acid monomers, monomers having keto or aldehyde groups, styrene and optionally further monomers, wherein the polymerization may be carried out in the presence of chain transfer agents. The pressure-sensitive adhesive polymer has certain gel contents. The pressure-sensitive adhesive composition may be used to produce adhesive labels, adhesive tapes or adhesive films.
    Type: Grant
    Filed: April 10, 2019
    Date of Patent: January 30, 2024
    Inventors: Matthias Gerst, Dirk Wulff
  • Patent number: 11292892
    Abstract: Disclosed is a flame retardant composition containing (A) an amine phosphate and (B) a zinc glycerolate. It is preferred that component (A) contain an amine pyrophosphate and that the mass ratio of component (A) to component (B) be 99.99:0.01 to 60:40. The flame retardant composition preferably further contains (C) zinc oxide, wherein the content of component (C) is 0.01 to 10 parts by mass per 100 parts by mass of the sum of components (A) and (B). The flame retardant composition preferably further contains (D) hydrotalcite, wherein the content of component (D) is 0.01 to 5 parts by mass per 100 parts by mass of the sum of components (A) and (B).
    Type: Grant
    Filed: May 15, 2018
    Date of Patent: April 5, 2022
    Assignee: ADEKA CORPORATION
    Inventors: Yang Ni, Yutaka Yonezawa, Naoko Tanji
  • Patent number: 9828509
    Abstract: The present invention is a composition comprising a) an aqueous dispersion of TiO2 particles encapsulated with an encapsulating acrylic or styrene-acrylic polymer comprising from structural units of diacetone acrylamide; and b) adipic acid dihydrazide. The composition is useful in coatings applications and shows a surprising improvement in gloss over compositions that do not include diacetone acrylamide functionalized encapsulating polymer and adipic acid dihydrazide.
    Type: Grant
    Filed: June 29, 2016
    Date of Patent: November 28, 2017
    Assignee: Rohm and Haas Company
    Inventors: James C. Bohling, David G. Kelly, Pu Luo, Yogesh Tiwary
  • Patent number: 9670336
    Abstract: We provide a method for producing a rubber composition that includes a rubber component (A) including natural rubber, at least one filler (B) selected from an inorganic filler and carbon black, and a hydrazide compound (C), the method comprising compounding in an optional preliminary compounding stage and a plurality of compounding stages, and adding the hydrazide compound (C) and kneading in the preliminary compounding stage and/or a first compounding stage, the hydrazide compound (C) being represented by general formula (I): R—CONHNH2, where R represents an alkyl group having from 1 to 30 carbon atoms, a cycloalkyl group having from 3 to 30 carbon atoms, or an aryl group. We also provide a rubber composition produced with this method.
    Type: Grant
    Filed: March 24, 2014
    Date of Patent: June 6, 2017
    Assignee: BRIDGESTONE CORPORATION
    Inventors: Aya Saiki, Haruki Minojima
  • Patent number: 9267075
    Abstract: The invention is directed to stable crosslinked water-soluble swellable polymers and methods for making same. More particularly, the invention relates to a composition comprising expandable polymeric particles having anionic sites and labile crosslinkers and stable crosslinkers, said particle mixed with a fluid and a cationic crosslinker that is capable of further crosslinking the particle on degradation of the labile crosslinker and exposure of the anionic sites so as to form a gel. A particularly important use is as an injection fluid in petroleum production, where the expandable polymeric particles are injected into target zone and when the heat and/or suitable pH of the target zone cause degradation of the labile crosslinker and the particle expands, the cationic crosslinker crosslinks the polymer to form a gel, thus diverting water to lower permeability regions and improving oil recovery.
    Type: Grant
    Filed: January 17, 2014
    Date of Patent: February 23, 2016
    Assignees: ConocoPhillips Company, University of Kansas
    Inventors: Ahmad Moradi-Araghi, James H. Hedges, David R. Zornes, Riley B. Needham, Huili Guan, Jenn-Tai Liang, Cory Berkland, James P. Johnson, Min Cheng, Faye Lynn Scully
  • Publication number: 20150064425
    Abstract: An ink composition contains a pigment; a copolymer comprising a phosphoric acid group or phosphonic acid group; a hydrosoluble solvent; and water, wherein the pigment is represented by the following chemical formula 1 and satisfies the following relation 1: Y/X?0.20??Relation 1 where X represents a peak intensity at a Bragg (2?±0.2°) angle in a range of 2? of from 26.5° to 27.5° and Y represents a peak intensity at a Bragg (2?±0.2°) angle in a range of 2? of from 11.0° to 11.5° to a CuK? X-ray having a wavelength of 1.541 ?.
    Type: Application
    Filed: August 11, 2014
    Publication date: March 5, 2015
    Inventors: Akihiko MATSUYAMA, Mitsuru Naruse, Masayasu Nonogaki, Kazukiyo Nagai, Keita Katoh, Yuusuke Koizuka
  • Publication number: 20150031795
    Abstract: After step (I) of kneading a diene rubber and a carbon black to be mixed with each other, and then discharging the resultant mixture containing the diene rubber and the carbon black from an internal mixer, step (II) of kneading the mixture again in the internal mixer to crush a re-aggregate of the carbon black in the mixture, and step (III) of charging the dihydrazide compound into the internal mixer, and kneading the mixture and the dihydrazide compound to be mixed with each other are carried out. The period of step (II) for the kneading is 15 seconds or longer, and the rotating speed of the stirring rotor of the internal mixer is 35 rpm or more. The period of step (III) for the kneading is 40 seconds or longer, and the rotating speed of the stirring rotor of the internal mixer is from 15 to 25 rpm.
    Type: Application
    Filed: March 14, 2014
    Publication date: January 29, 2015
    Applicant: TOYO TIRE & RUBBER CO., LTD.
    Inventor: Ikuo Ihara
  • Patent number: 8846788
    Abstract: A polyacetal resin composition containing 100 parts by weight of a polyacetal resin, 0.01 to 5 parts by weight of a colorant selected from inorganic and organic pigments, 0.01 to 3 parts by weight of a polyamide resin having a melting point or softening point of 180° C. or less, or a polyetheresteramide resin, 0.01 to 1 part by weight of an aromatic dihydrazide compound or an aliphatic dihydrazide compound having a solubility of less than 1 g relative to 100 g of water at 20° C., and 0.01 to 1 part by weight of a sterically hindered phenolic compound, or a combination of a hindered amine-based light stabilizer and an ultraviolet absorber, exhibits an excellent thermal stability and is capable of suppressing formaldehyde generation and mechanical strength deterioration.
    Type: Grant
    Filed: September 3, 2009
    Date of Patent: September 30, 2014
    Assignee: Mitsubishi Engineering-Plastics Corporation
    Inventors: Masayuki Nagai, Kunihiko Fujimoto
  • Publication number: 20140242280
    Abstract: A method for applying a multilayer coating comprising a basecoat and a clearcoat is disclosed. The basecoat is a curable aqueous composition comprising (1) polymeric particles prepared from ethylenically unsaturated compounds including a multi-ethylenically unsaturated monomer and a keto or aldo-functional monomer, and (2) a polyhydrazide.
    Type: Application
    Filed: February 28, 2013
    Publication date: August 28, 2014
    Applicant: PPG INDUSTRIES OHIO, INC.
    Inventors: Shanti Swarup, Xiangling Xu, Richard J. Sadvary, Anthony M. Chasser
  • Patent number: 8815003
    Abstract: Crosslinking systems suitable for use in a polymer melt composition wherein the polymer melt composition comprises a hydroxyl polymer; polymeric structures made from such polymer melt compositions; and processes/methods related thereto are provided.
    Type: Grant
    Filed: November 20, 2013
    Date of Patent: August 26, 2014
    Assignee: The Procter & Gamble Company
    Inventors: Stephen Wayne Heinzman, Linda Evers Smith, Gregory Charles Gordon, Larry Neil Mackey, John Gerhard Michael, Mark Ryan Richards
  • Patent number: 8765850
    Abstract: Provided is a polyacetal resin composition obtained from a raw material composition containing a polyacetal resin, a hydrazine derivative, and a compound for lowering the melting point of the hydrazine derivative, wherein a mixture of the hydrazine derivative and the compound satisfies both of the following conditions: T1<T2 and T1<T3, in which T1 is an apex temperature of an endothermic peak of the mixture having a maximum endothermic capacity by, with DSC, heating and cooling the mixture in accordance with a predetermined temperature program and then heating it at a predetermined rate until the mixture fuses; and T2 and T3 represent apex temperatures of endothermic peaks of the hydrazine derivative and the polyacetal resin having a maximum endothermic capacity, respectively by the similar treatment.
    Type: Grant
    Filed: October 27, 2009
    Date of Patent: July 1, 2014
    Assignee: Asahi Kasei Chemicals Corporation
    Inventors: Takashi Iwamoto, Yukiyoshi Sasaki, Mitsuhiro Horio, Syuuichi Kudou
  • Publication number: 20130331494
    Abstract: A coating for application to the surface of an interior building product comprises: a resin formulation such as a melamine formaldehyde resin characterized by its ability to strengthen the interior building product when applied as a coating to the building product; and an aldehyde scavenger selected from the group consisting of; tetraethylene pentamine, propionamide, caprolactam, ammonium hydroxide, sodium bisulfate, sodium metabisulfite, ammonium primary phosphate, ammonium secondary phosphate, a combination of ammonium primary phosphate and ammonium secondary phosphate, a combination of ammonium primary phosphate, ammonium secondary phosphate and a sulfite, a polyvinyl alcohol; adipic dihydrazide and a combination of a polyvinyl alcohol and adipic dihydrazide.
    Type: Application
    Filed: August 9, 2013
    Publication date: December 12, 2013
    Applicant: USG Interiors, LLC
    Inventors: Runhai Lu, Terry L. Rosenstiel, Salvatore Immordino, Weixin D. Song
  • Publication number: 20130289165
    Abstract: Reinforced rubber composition based at least (a) on an elastomeric matrix comprising natural rubber as the predominant diene elastomer, (b) on a reinforcing filler comprising carbon black in a weight fraction of more than 50% relative to the total weight of the filler, and (c) on a compound belonging to the families of hydrazides or hydrazones or to the family of amines, wherein the carbon black is dispersed in the elastomeric matrix with a Z value of greater than or equal to 80. This rubber composition is intended, for example, for the manufacture of a semi-finished rubber product intended for a tyre of motor vehicles.
    Type: Application
    Filed: December 19, 2011
    Publication date: October 31, 2013
    Applicants: MICHELIN RECHERCHE ET TECHNIQUE S.A., COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN
    Inventors: Stéphanie De Landtsheer, Damien Thomasson
  • Publication number: 20130035416
    Abstract: A polyacetal resin composition and molded article having a high metallic gloss, small change in a color tone according to the viewing angle, high weld performance, and high mechanical properties can be provided in which the amount of formaldehyde to be produced in molding and recycle is suppressed, the mold deposit is improved, and the repeated impact resistance after aging is high. A polyacetal resin composition comprising: (A) 100 parts by mass of a polyacetal copolymer resin, and (B) 0.1 to 10 parts by mass of an aluminum pigment, the aluminum pigment having a coin-like or flake-like flat shape, a volume average particle size D50 of 15 to 50 ?m, an average surface roughness Ra of 20 to 50 nm, and an average height Rc of depressions and projections in a surface roughness curve of 80 to 200 nm.
    Type: Application
    Filed: April 15, 2011
    Publication date: February 7, 2013
    Applicant: ASAHI KASEI CHEMICALS CORPORATION
    Inventors: Mitsuhiro Horio, Syuichi Kudou, Seizaburoh Asai
  • Publication number: 20130023612
    Abstract: A coating for application to the surface of an interior building product comprises: a resin formulation such as a melamine formaldehyde resin characterized by its ability to strengthen the interior building product when applied as a coating to the building product; and an aldehyde scavenger selected from the group consisting of; tetraethylene pentamine, propionamide, caprolactam, ammonium hydroxide, sodium bisulfate, sodium metabisulfite, ammonium primary phosphate, ammonium secondary phosphate, a combination of ammonium primary phosphate and ammonium secondary phosphate, a combination of ammonium primary phosphate, ammonium secondary phosphate and a sulfite, a polyvinyl alcohol; adipic dihydrazide and a combination of a polyvinyl alcohol and adipic dihydrazide.
    Type: Application
    Filed: June 7, 2012
    Publication date: January 24, 2013
    Applicant: USG INTERIORS, LLC
    Inventors: Runhai Lu, Terry L. Rosenstiel, Salvatore Immordino, Weixin D. Song
  • Publication number: 20120277359
    Abstract: Tire component which is not in contact with air or with an inflation gas, comprising a rubber composition based on (a) an elastomeric matrix based on natural rubber, (b) a reinforcing filler, (c) from more than 2.5 to 8.5 phr of sulphur and (d) a dihydrazide compound corresponding to the following formula: in which R is a divalent hydrocarbon radical chosen from substituted or unsubstituted aromatic radicals having 6 to 20 carbon atoms, linear or branched, saturated or unsaturated, aliphatic radicals having 2 to 20 carbon atoms, and n is equal to 0 or 1. These tire components are more particularly those which comprise thread-like reinforcing elements, more especially metallic thread-like reinforcing elements, such as the carcass or crown plies of the tire.
    Type: Application
    Filed: December 22, 2009
    Publication date: November 1, 2012
    Applicants: Michelin Recherche et Technique S.A., Societe De Technologie Michelin
    Inventors: Julien Thuilliez, Stephanie De Landtsheer, Brigitte Chauvin
  • Publication number: 20120270966
    Abstract: Reinforced rubber composition based on at least (a) an elastomeric matrix predominantly based on natural rubber, (b) a reinforcing filler predominantly based on an inorganic filler, (c) a coupling agent and (d) a dihydrazide compound corresponding to the following formula I: in which R is a divalent hydrocarbon radical chosen from aromatic radicals having from 6 to 20 carbon atoms or saturated or unsaturated aliphatic radicals having from 2 to 20 carbon atoms and n has the value 0 or 1. This rubber composition is intended, for example, for the manufacture of a semi-finished rubber product intended for the tires of motor vehicles.
    Type: Application
    Filed: December 22, 2009
    Publication date: October 25, 2012
    Applicants: Michelin Recherche et Technique S.A., Societe De Technologie Michelin
    Inventors: Julien Thuilliez, Stephanie De Landtsheer, Brigitte Chauvin
  • Publication number: 20120178861
    Abstract: A polyolefin resin composition is excellent in processing cycle and mechanical characteristics and provides small deformation during molding, i.e., small deformation due to anisotropicity in shrinkage factors. Specifically, provided is a polyolefin resin composition obtained by incorporating 0.01 to 10 parts by mass of, preferably 0.05 to 5 parts by mass of (B) a compound represented by the following formula (I) with respect to 100 parts by mass of (A) a polyolefin resin, preferably a polypropylene. The polyolefin resin composition may also contain, if necessary, a phenolic, phosphorus, thioether or hydroxyamine antioxidant, an ultraviolet absorbent, a hindered amine light stabilizer, or other nucleator, or the like.
    Type: Application
    Filed: October 7, 2010
    Publication date: July 12, 2012
    Applicant: ADEKA CORPORATION
    Inventors: Kazukiyo Nomura, Mitsuru Fukushima
  • Publication number: 20120123035
    Abstract: The invention relates to a method for producing a body including: preparing a granular mixture including a) at least 90 wt % of mineral oxide grains; b) 0.3 to 3 wt % of resin polycondensed with formaldehyde and/or the derivatives thereof, the percentage being calculated in terms of dry resin extract; c) 0.001 to 1 wt % of a hardening agent, the percentage being calculated in terms of dry hardener extract; d) 0.005 to 0.35 wt % of a formaldehyde scavenger compound; and e) 0.2 to 3 wt % of water; contacting said granular mixture with a surface of a forming tool; and insufflating a gas flow at 50 to 380 degrees into the granular mixture for 1 to 300 seconds in order to at least partially cure said mixture, the formaldehyde scavenger being carbohydrazide.
    Type: Application
    Filed: July 9, 2010
    Publication date: May 17, 2012
    Applicant: HUTTENES ALBERTUS FRANCE
    Inventors: Stéphane Sarrazin, Manuel Vargas
  • Publication number: 20110230602
    Abstract: A polyacetal resin composition containing 100 parts by weight of a polyacetal resin, 0.01 to 5 parts by weight of a colorant selected from inorganic and organic pigments, 0.01 to 3 parts by weight of a polyamide resin having a melting point or softening point of 180° C. or less, or a polyetheresteramide resin, 0.01 to 1 part by weight of an aromatic dihydrazide compound or an aliphatic dihydrazide compound having a solubility of less than 1 g relative to 100 g of water at 20° C., and 0.01 to 1 part by weight of a sterically hindered phenolic compound, or a combination of a hindered amine-based light stabilizer and an ultraviolet absorber, exhibits an excellent thermal stability and is capable of suppressing formaldehyde generation and mechanical strength deterioration.
    Type: Application
    Filed: September 3, 2009
    Publication date: September 22, 2011
    Applicant: MITSUBISHI ENGINEERING-PLASTICS CORPORATION
    Inventors: Masayuki Nagai, Kunihiko Fujimoto
  • Publication number: 20110218279
    Abstract: The present invention provides a polyolefin-based resin composition containing a crystal nucleating agent having a specific structure, which polyolefin-based resin composition has a superior transparency and whose crystallization is facilitated. The polyolefin-based resin composition is characterized by comprising, with respect to 100 parts by mass of a polyolefin-based resin, 0.
    Type: Application
    Filed: August 21, 2009
    Publication date: September 8, 2011
    Inventors: Tsuyoshi Urushihara, Kazukiyo Nomura, Naoto Ueda, Yota Tsuneizumi
  • Patent number: 7910643
    Abstract: A polylactic acid resin composition in which polylactic acid is blended with dibasic acid bis(benzoylhydrazide) represented by general formula (I) below; and a process for producing heat-resistant polylactic acid resin moldings, wherein after the polylactic acid resin composition is melted, the polylactic acid resin composition melted is filled in a die of a molding machine and molded accompanied with crystallization, in which the temperature of the die has been set in a range not higher than the initiation temperature of crystallization and not lower than the glass transition temperature determined with a differential scanning calorimeter (DSC).
    Type: Grant
    Filed: September 2, 2005
    Date of Patent: March 22, 2011
    Assignee: Adeka Corporation
    Inventors: Etsuo Tobita, Naoshi Kawamoto, Tsuyoshi Urushihara, Hitoshi Saito, Hisashi Okuyama, Naomi Okuyama, legal representative, Takeshi Kanamori, Mitsuru Nakano, Hirotaka Okamoto
  • Publication number: 20110015321
    Abstract: Provided is a polyacetal resin composition obtained from a raw material composition containing a polyacetal resin, a hydrazine derivative, and a compound for lowering the melting point of the hydrazine derivative, wherein a mixture of the hydrazine derivative and the compound satisfies both of the following conditions: T1<T2 and T1<T3, in which T1 is an apex temperature of an endothermic peak of the mixture having a maximum endothermic capacity by, with DSC, heating and cooling the mixture in accordance with a predetermined temperature program and then heating it at a predetermined rate until the mixture fuses; and T2 and T3 represent apex temperatures of endothermic peaks of the hydrazine derivative and the polyacetal resin having a maximum endothermic capacity, respectively by the similar treatment.
    Type: Application
    Filed: October 27, 2009
    Publication date: January 20, 2011
    Applicant: ASAHI KASEI CHEMICALS CORPORATION
    Inventors: Takashi Iwamoto, Yukiyoshi Sasaki, Mitsuhiro Horio, Syuuichi Kudou
  • Publication number: 20100273018
    Abstract: Aqueous coating composition comprising (1) at least one vinyl polymer having a Mw?15 k Da and a Tg?0° C. formed from (i) 0.1 to 20 wt % of vinyl monomer(s) containing acid functional groups and (ii) 0 to 0.49 wt % of vinyl monomer(s) containing a carbonyl functional group(s) and (2) 0.01 to 10 wt % of at least one polyhydrazine compound B where said composition provides a film coating of König hardness ?40 s.
    Type: Application
    Filed: July 6, 2010
    Publication date: October 28, 2010
    Inventors: Jurgen SCHEERDER, Yvonne Wihelmina Smak, Gerardus Comelis Overbeek
  • Patent number: 7816433
    Abstract: A polyacetal resin composition comprising (A) 100 parts by mass of polyacetal resin generating formaldehyde in an amount of not more than 100 ppm when heated at a temperature of 200° C. for 50 minutes under the nitrogen atmosphere and (B) 0.01 to 5 parts by mass of a hydrazide compound can provide an article which is remarkably reduced in an emission amount of formaldehyde even though molded either at a higher temperature or under molding conditions wherein the resin temperature rises partially. Therefore, the polyacetal resin composition can be molded according to various molding methods and under a wide range of molding conditions. The article molded from the resin composition has succeeded in reducing the emission amount of formaldehyde, measured according to VDA275 method, to not more than 1 mg/kg, the level never achieved before, and therefore is usable for various applications where a reduced VOC is required.
    Type: Grant
    Filed: October 21, 2004
    Date of Patent: October 19, 2010
    Assignee: Asahi Kasei Chemicals Corporation
    Inventors: Sumio Komatsu, Yukiyoshi Sasaki
  • Publication number: 20100174017
    Abstract: A polylactic acid resin composition in which polylactic acid is blended with dibasic acid bis(benzoylhydrazide) represented by general formula (I) below; and a process for producing heat-resistant polylactic acid resin moldings, wherein after the polylactic acid resin composition is melted, the polylactic acid resin composition melted is filled in a die of a molding machine and molded accompanied with crystallization, in which the temperature of the die has been set in a range not higher than the initiation temperature of crystallization and not lower than the glass transition temperature determined with a differential scanning calorimeter (DSC).
    Type: Application
    Filed: September 2, 2005
    Publication date: July 8, 2010
    Applicant: ADEKA CORPORATION
    Inventors: Etsuo Tobita, Naoshi Kawamoto, Tsuyoshi Urushihara, Hitoshi Saito, Hisashi Okuyama, Naomi Okuyama, Takeshi Kanamori, Mitsuru Nakano, Hirotaka Okamoto
  • Publication number: 20100120954
    Abstract: An olefine polymer composition comprises a stabilizing amount of a metal deactivator comprising a polymeric hydrazine derivative. The deactivator is of formula (I), in which at least one of R1 and R2 comprise a polymeric radical that includes a substituted or unsubstituted aromatic radical. The olefin polymers include polyethylene and polypropylene.
    Type: Application
    Filed: March 17, 2008
    Publication date: May 13, 2010
    Inventors: Pascal E.R.E.J. Lakeman, Thoi H. Ho, Ronald Wevers
  • Patent number: 7691929
    Abstract: The present invention is directed a method of flame retarding a polymeric substrate using a specific group of azo and peroxide derivatives as flame retardants, to flame retardant compositions as well as to novel azo compounds usable as flame retarding compounds.
    Type: Grant
    Filed: January 9, 2009
    Date of Patent: April 6, 2010
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Nicolas Ronan, Carl-Eric Magnus Wilën
  • Publication number: 20090005474
    Abstract: A pigment dispersion includes a color pigment represented by formula (I): wherein R1 to R10 are independently selected from the group consisting of hydrogen, a halogen atom, a methyl group, an ethyl group, a methoxy group, an ethoxy group, —CF3, —COOH, —COOCH3, —SO2NH—C6H5, —CONH—C6H5, —CONH—C6H5—CONH2, and —CONH2; and a polymeric dispersant, having via a linking group covalently linked to its polymeric backbone, at least one pending chromophore group which has a molecular weight smaller than 95% of the molecular weight of said color pigment. The pigment dispersion can be advantageously used in inkjet inks.
    Type: Application
    Filed: June 23, 2006
    Publication date: January 1, 2009
    Applicant: AGFA GRAPHICS NV
    Inventors: Wojciech Jaunky, Geert Deroover, Johan Loccufier, Lambertus Groenendaal
  • Patent number: 7005004
    Abstract: Aqueous, colloidal gas black suspension, containing a gas black, an azo compound of formula 1, and water. The aqueous, colloidal gas black suspensions is produced in that the gas black and the azo compound of general formula 1 are dispersed in water. It may be used to produce inks, ink jet inks, paints, printing inks, latices, textiles, leather, adhesives, silicones, plastics materials, concrete and construction materials.
    Type: Grant
    Filed: March 30, 2004
    Date of Patent: February 28, 2006
    Assignee: Degussa AG
    Inventors: Werner Kalbitz, Gerd Tauber, Heinz Zoch, Stephan Lüdtke, Thomas Lüthge, Ralph Mcintosh
  • Publication number: 20020103278
    Abstract: A waterborne coating composition for a cured film having improved film properties and uniform film formation comprising a binder polymer containing a reactive keto group, at least one carboxylic monohydrazide or dihydrazide or polyhydrazide compound, and a reaction moderator. More specifically, the waterborne coating composition comprises (a) at least one binder polymer comprising at least one or more copolymerizable monoethylenically unsaturated monomers, wherein at least one of the monoethylenically unsaturated monomers contains at least one reactive keto group; and (b) at least one monohydrazide or dihydrazide or polyhydrazide compound; and (c) at least one reaction moderator. Reaction moderators moderate or retard the crosslinking process before film formation occurs and then act to catalyze the film formation crosslinking reaction. The final cured film product of the waterborne coatings produced by this invention have a much higher crosslink density per unit time and a uniform film formation.
    Type: Application
    Filed: September 14, 2001
    Publication date: August 1, 2002
    Inventors: John M. Krajnik, Victor H. Lam, Lynn O. Sabo, James M. Camerson, Martin L. Mittleman, Kuyler M. Wise
  • Patent number: 6046252
    Abstract: A binder composition of a phenolic novolac resin and a (lower) alkoxylated triazine-formaldehyde resin curing agent is disclosed. The triazine resins have sufficient carbon atoms in the alkoxy groups so as to provide a curing agent having a water solubility of less than 15%. The binder cures at high temperatures so as to provide improved flow and prolonged workability to the composition. The compositions are useful in refractory applications having a need for high temperature curing agents such as for maintenance and repair within refractory vessels by gunning/spraying, manufacture of electrodes by the Soderberg method, and for use in blast furnace tap holes.
    Type: Grant
    Filed: February 25, 1997
    Date of Patent: April 4, 2000
    Assignee: Borden Chemical, Inc.
    Inventor: Arthur H. Gerber
  • Patent number: 5973042
    Abstract: There is provided a highly water-absorptive polymer composition comprising:(A) 100 parts by weight of a highly water-absorptive polymer having a crosslinked structure, comprising as its constituent a carboxyl group and/or a carboxylate group; and(B) 0.05 to 10 parts by weight of an additive selected from the group consisting of an oxalic acid (salt) compound, a sulfate of a metal selected from titanium, zirconium and vanadium, and a crystalline or noncrystalline, high-purity particulate titania having a mean particle diameter of 1 .mu.m or less, a specific surface area of 10 m.sup.2 /g or more as determined by the Brunauer-Emmett-Teller method, and, when crystalline, a crystal structure of a mixed type of rutile and anatase.
    Type: Grant
    Filed: June 11, 1996
    Date of Patent: October 26, 1999
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Kenji Yoshinaga, Shozo Kitagawa, Toshiko Nakamura, Miho Tanaka, Kiichi Ito
  • Patent number: 5846451
    Abstract: A crosslinking type liquid crystal polymer, an oriented crosslinking film thereof, and a method of producing the oriented crosslinking film are disclosed. The crosslinking type liquid crystal polymer comprises a liquid crystal polymer containing a polyfunctional azide compound represented by the following formula (A);R.sup.1 --(N.sub.3).sub.n (A)wherein R.sup.1 represents an organic group and n represents an integer of from 1 to 5.
    Type: Grant
    Filed: November 26, 1996
    Date of Patent: December 8, 1998
    Assignee: Nitto Denko Corporation
    Inventors: Shusaku Nakano, Amane Mochizuki, Hironori Motomura, Kyoko Izumi
  • Patent number: 5705549
    Abstract: A rubber composition comprises a particular copolymer containing isobutylene unit, a paramethylstyrene unit and a parabromomethylstyrene unit; natural rubber and/or diene synthetic rubber; carbon black; and at least one hydrazide compound, and has a low value of tan .delta. at 60.degree. C. with maintaining tan .delta. at 0.degree. C. at a high level.
    Type: Grant
    Filed: April 15, 1996
    Date of Patent: January 6, 1998
    Assignee: Bridgestone Corporation
    Inventor: Masahiro Hojo
  • Patent number: 5648404
    Abstract: A binder composition of a phenolic novolac resin and a (lower) alkoxylated triazine-formaldehyde resin curing agent is disclosed. The triazine resins have sufficient carbon atoms in the alkoxy groups so as to provide a curing agent having a water solubility of less than 15%. The binder cures at high temperatures so as to provide improved flow and prolonged workability to the composition. The compositions are useful in refractory applications having a need for high temperature curing agents such as for maintenance and repair within refractory vessels by gunning/spraying, manufacture of electrodes by the Soderberg method, and for use in blast furnace tap holes.
    Type: Grant
    Filed: April 11, 1994
    Date of Patent: July 15, 1997
    Assignee: Borden Inc.
    Inventor: Arthur Harry Gerber
  • Patent number: 5539015
    Abstract: A synthetic resin composition comprises an aqueous medium, a surfactant, and a resin and filler dispersed in the aqueous medium by the surfactant. The surfactant comprises a first high molecular weight compound having a weight-average molecular weight of at least 10000 and a second high molecular weight compound having a weight-average molecular weight of not less than 150 and less than 10000. In the synthetic resin composition, a solid material is well dispersed and the viscosity doesn't remarkably increase even if a solid content is increased. So, the increased amount of a non-volatile matter may be used and the storage stability improves. Further, flame retardation, deodorization, heat resistance and light fastness also improve. In addition, an interior material coated with the synthetic resin composition is provided.
    Type: Grant
    Filed: May 27, 1994
    Date of Patent: July 23, 1996
    Assignees: Kabushiki Kaisha Toyota Chuo Kenkyusho, Toyota Jidosha Kabushiki Kaisha, Toyoda Boshoku Corporation, Dainippon Ink and Chemicals, Incorporated
    Inventors: Mitsumasa Horii, Masahiro Sugiura, Seiji Onoda, Yoshio Yamada, Osamu Araki, Yoshiro Umemoto, Kazuo Ito, Takatoshi Sekihara, Akihiro Matsuyama, Masaaki Izumichi, Kiyoshi Umehara, Reizaburo Tomioka
  • Patent number: 5534569
    Abstract: Heat generation of a rubber composition can be lowered by incorporating to the composition a compound of the formula, (I), (II) or (III), ##STR1## where A is an aromatic group, hydantoin ring or C.sub.0-18 straight chain hydrocarbon group, B is an aromatic group, X is hydroxy or amino, Y is pyridyl or hydrozino.
    Type: Grant
    Filed: March 8, 1995
    Date of Patent: July 9, 1996
    Assignee: Bridgestone Corporation
    Inventor: Akiko Etoh
  • Patent number: 5492952
    Abstract: Provided is an ink comprising a compound having at least one carbonyl group and a hydrazide compound selected from the group consisting of a styrene-maleic acid resin having at least two hydrazide groups, a polyacrylic acid having at least two hydrazide groups and a compound represented by the formula ##STR1## wherein R represents (CH.sub.2).sub.n or C.sub.6 H.sub.
    Type: Grant
    Filed: March 15, 1994
    Date of Patent: February 20, 1996
    Assignee: Canon Kabushiki Kaisha
    Inventors: Masahiko Tonogaki, Yuko Suga, Akio Kashiwazaki, Aya Takaide
  • Patent number: 5155151
    Abstract: A thermoplastic resin composition having improved heat stability which comprises a thermoplastic resin which contains at least 5% by weight of an .alpha.-alkyl-substituted aromatic copolymer comprising .alpha.-alkyl-substituted aromatic vinyl compound and at least one other comonomer copolymerizable therewith, wherein the composition contains a metal-deactivating agent which has a molecular weight of not more than 2,000 and at least one group of the formula: ##STR1## or an organometallic colorant containing free metal in an amount of not more than 2,000 ppm, from which a molded article having no or less silver streaks can be produced.
    Type: Grant
    Filed: February 21, 1992
    Date of Patent: October 13, 1992
    Assignee: Sumitomo Naugatuck Co., Ltd.
    Inventors: Kenji Hashimoto, Syuzi Takahashi, Hiroyuki Minematsu
  • Patent number: 5153069
    Abstract: A dispersing agent for dispersing solid particles in an organic liquid having the composition ##STR1## wherein ##STR2## is the residue of a polyester chain having a molecular weight of at least 1700, derived from a hydroxycarboxylic acid containing 16-22 carbon atoms, ##STR3## is the residue of a mono or polyamide having up to 12 amido bonds, which is amino terminated in both ends and wherein R.sub.1 and R.sub.2 are each independently hydrogen or alkyl or alkenyl containing up to 20 carbon atoms;Z is a salt of a carboxylic acid containing 8-18 carbon atoms and a diamine NHR.sub.3 --T--NH.sub.2 wherein T is alkylene or alkenylene containing 2-12 carbon atoms and optionally comprising one or more oxygen or nitrogen bridges and R.sub.3 is hydrogen or alkyl or alkenyl containing up to 20 carbon atoms;Q is a carboxylic acid containing 8-18 carbon atoms or a diamine NHR.sub.3 --T--NH.sub.2, wherein T and R.sub.3 are defined as above.Said dispersing agent can be used for preparing an easily dispersable pigment.
    Type: Grant
    Filed: March 5, 1991
    Date of Patent: October 6, 1992
    Assignee: Giuseppe Canestri
    Inventor: Giuseppe Canestri
  • Patent number: 4973618
    Abstract: Oligormeric polyether/urethanes with semicarbazide end-groups protect spandex fibers from discoloration in atmospheric fumes and/or light. The oligomers are prepared from polyether glycols, diisocyanates and N,N-dialkylhydrazine.
    Type: Grant
    Filed: September 29, 1989
    Date of Patent: November 27, 1990
    Assignee: E. I. Du Pont de Nemours & Company
    Inventor: Arnoldus J. Ultee
  • Patent number: 4855344
    Abstract: An aqueous printing ink or its semiaqueous or substantially nonaqueous concentrates exemplified as comprising a substantially homogeneous system of the components:(1) from about 4 to about 90 weight % of one or more polyester materials having an acid component of from about 75 to about 84 mole % isophthalic acid and conversely from about 25 to about 16 mole % 5-sodiosulfoisophthalic acid, and having a glycol component of from about 45 to about 60 mole % diethylene glycol and conversely from about 55 to about 40 mole % 1,4-cyclohexanedimethanol or ethylene glycol or mixtures thereof;(2) from none to about 70 weight % of pigment material;(3) from about 0.01 to about 90 weight % of water; and(4) one or more acetylacetonates of the formula M[CH--(COCH.sub.3).sub.2 ].sub.n wherein M is Al, Zr, Ni, Ca, V, or Fe, and n is the chemical valence of M, the weight ratio of polyester to total acetylacetonates being from about 10,000/1 to about 10/1.
    Type: Grant
    Filed: May 16, 1988
    Date of Patent: August 8, 1989
    Assignee: Eastman Kodak Company
    Inventors: David L. Nealy, Louis A. Wilkin, Fred D. Barlow, Jr.
  • Patent number: 4839408
    Abstract: The invention relates to a stabilized polyolefin composition, which composition is stabilized against deterioration caused by contact with heavy metals and improved in coloration properties. This is achieved by blending a polyolefin with:(A) a phenolic compound represented by the formula (I), ##STR1## wherein R.sub.1 represents a C.sub.1 -C.sub.3 alkyl group, (B) a metal deactivator having one or more ##STR2## groups in the side chain, and (C) a sulfur-containing compound represented by the formula (II-1), (II-2), (II-3) or (II-4): ##STR3## wherein R.sub.2 represents a C.sub.4 -C.sub.20 alkyl group, ##STR4## wherein R.sub.3 represents a C.sub.4 -C.sub.20 alkyl group, ##STR5## wherein R.sub.4 represents a C.sub.3 -C.sub.18 alkyl group, and R.sub.5 and R.sub.6 independently represent a hydrogen atom or a C.sub.1 -C.sub.6 alkyl group, ##STR6## wherein R.sub.7 represents a C.sub.3 -C.sub.18 alkyl group.
    Type: Grant
    Filed: August 15, 1988
    Date of Patent: June 13, 1989
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Yoshiharu Fukui, Kazuhisa Kuroda, Tamaki Ishii, Manji Sasaki
  • Patent number: 4826903
    Abstract: Composition useful for molding into articles such as food containers, beverage bottles, cured structural plastics and the like comprising molding grade linear or unsaturated polyester or polycarbonate (a) containing a mono-4-acryloxystyryl or bis-4-acyloxystyryl compound or (b) having reacted therewith or copolymerized therein a styryl residue derived from a mono-4-acryloxystyryl or bis-4-acyloxystyryl compound, having the formula ##STR1## wherein R.sup.4 and R.sup.5 represent the acyl radical and the other radicals are as defined in the specification.Preferred compositions comprise a linear polyester containing a styryl residue as an integral part of the polymer chain. The styryl residues absorb ultraviolet radiation in the range of about 250 to about 390 nm. The residues are non-extractable from the polymer and stable at the conditions at which the polymers are manufactured and processed.
    Type: Grant
    Filed: February 22, 1988
    Date of Patent: May 2, 1989
    Assignee: Eastman Kodak Company
    Inventors: Max A. Weaver, Samuel D. Hilbert, Wayne P. Pruett, Clarence A. Coates, Jr.
  • Patent number: 4769410
    Abstract: Crosslinkable polymeric compositions which are dissolved or dispersed in an organic solvent, a process for their preparation and their use.These polymeric compositions which undergo crosslinking at room temperature or elevated temperatures after drying are obtained by reacting polymeric organic compounds containing carbonyl groups with polyhydrazides in the presence of monoketones or monoaldehydes.They are useful as crosslinking agents for polyepoxide compounds.
    Type: Grant
    Filed: October 10, 1986
    Date of Patent: September 6, 1988
    Assignee: BASF Aktiengesellschaft
    Inventors: Rainer Blum, Gerd Rehmer, Rolf Osterloh, Wolfgang Druschke, Hans Sander
  • Patent number: 4666966
    Abstract: A polyurethane composition comprising an effective amount of a stabilizer compound represented by the general formula ##STR1## wherein, X is a residue represented the formula ##STR2## and at least three of Y.sub.1, Y.sub.2, Y.sub.3, and Y.sub.4 are residues represented by the general formula ##STR3## wherein R.sub.1 and R.sub.2 are each an alkyl or aralkyl group with the proviso that at least one of R.sub.1 and R.sub.2 is attached through its primary carbon to the nitrogen atom and the total number of carbon atoms of R.sub.1 and R.sub.2 is at least 4, the other one of Y.sub.1, Y.sub.2, Y.sub.3, and Y.sub.4, if present, is a glycidyl derivative residue, and Z is a residue represented by the general formula ##STR4## wherein R.sub.3 and R.sub.
    Type: Grant
    Filed: March 12, 1986
    Date of Patent: May 19, 1987
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Yoshihisa Fujimoto, Seizi Gotou, Yoshiharu Fujita
  • Patent number: 4618637
    Abstract: The invention relates to polymer mixtures which comprise a polyphenylene ether which have been stabilized with oxalyldihydrazide against oxidative degradation.
    Type: Grant
    Filed: December 16, 1985
    Date of Patent: October 21, 1986
    Assignee: General Electric Company
    Inventors: Johannes H. G. M. Lohmeijer, Jacobus W. M. Noordermeer, Jan Bussink
  • Patent number: 4447571
    Abstract: A process for providing water based anionic polyurethanes having improved thermal oxidation color stability. Water dispersed amine salts of anionic prepolymers prepared from the reaction of polyhydroxy compounds and dihydroxy carboxylic acids with diisocyanates are chain-extended with hydrazine or hydrazide and thereafter optionally with a diamine, when cured at temperatures in excess of 150.degree. C., form polyurethane products having substantially no discoloration and good mechanical properties. Alternately, the hydrazide may be employed as an additive rather than as a chain-extender. The process is particularly useful when employing cross-linking agents which react only at high temperatures.
    Type: Grant
    Filed: October 15, 1981
    Date of Patent: May 8, 1984
    Assignee: Witco Chemical Corporation
    Inventors: Shmuel Dabi, Peter Loewrigkeit