Heavy Metal Or Aluminum Patents (Class 524/204)
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Patent number: 5491185Abstract: A corrosion-resistant coating which can be applied directly to a surface as self-priming topcoat comprising an epoxy resin binder and a combination of pigments consisting essentially of an aluminum triphosphate, zinc salts of benzoic acids, and an alkaline earth metal phosphate such as zinc-barium phosphate. In addition, the coating contains up to about 30 parts by weight of a titanium dioxide pigment, up to about 2.0 parts by weight of an oil soluble surface active agent and up to about 50 parts by weight of at least one organic paint solvent.Type: GrantFiled: March 7, 1994Date of Patent: February 13, 1996Assignee: The United States of America as represented by the Secretary of the NavyInventors: Charles R. Hegedus, Donald J. Hirst, Anthony T. Eng
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Patent number: 5462985Abstract: A matte electrodepositable coating composition and a process for preparation thereof, the composition comprising a fluorine-containing resin, an acrylic resin, an amino resin, and an aluminum complex compound, which are dissolved or dispersed in water, the fluorine-containing resin and the acrylic resin both containing a carboxyl group and a hydroxyl group in molecules thereof, the differences in acid value and hydroxyl value between the fluorine-containing resin and the acrylic resin each being not more than 50, the average acid value of the fluorine-containing resin and the acrylic resin being not less than 35, the average hydroxyl value of the fluorine-containing resin and the acrylic resin being not less than 70, the proportion of the fluorine-containing resin and the acrylic resin being in the range of 20/80 to 80/20 by weight, and the aluminum complex compound being represented by formula (1) or (2):Al(OR.sup.1)(OR.sup.2)(L) (1)Al(L.sup.1)(L.sup.2)(L.sup.3) (2)wherein R.sup.1 and R.sup.Type: GrantFiled: December 29, 1994Date of Patent: October 31, 1995Assignee: Taogosei Co., Ltd.Inventors: Toshiaki Takei, Satoshi Kayamori, Hiroyuki Ota
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Patent number: 5459173Abstract: Stable thiol-ene compositions are provided which comprise a polythiol, a polyene and a stabilizer system comprising an alkenyl substituted phenolic compound having a formula: ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 are independently selected from the group consisting of H, OR, a C.sub.1 -C.sub.8 alkyl, substituted alkyl, alkenyl or substituted alkenyl, a C.sub.6 -C.sub.20 aryl or substituted aryl, or a cyano group; R.sup.4 is H, R, OR, halogen, COR, COOR, or SR; R.sup.5 is OH, OR, OCOR, OCOOR, OCONHR, or OTMS; R is a C.sub.1 -C.sub.6 alkyl, a cycloalkyl, or a C.sub.6 -C.sub.20 caryl or substituted aryl; x and y are 1, 2, or 3; z is 0, 1, or 2; and x+y+z=2, 3, or 4; or a formula: ##STR2## where x, y, z, w, R.sup.1 R.sup.2 R.sup.3, R.sup.4 and R.sup.5 are defined as above, except that x+y+z=2-6, and R.sup.6 is CH.sub.2, C(CH.sub.3).sub.2, O, S, or SO.sub.Type: GrantFiled: June 22, 1993Date of Patent: October 17, 1995Assignee: Loctite CorporationInventors: David M. Glaser, Anthony F. Jacobine, Paul J. Grabek
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Patent number: 5434197Abstract: Decreasing the transmittal of near infra-red radiation through transparent glassy polymers, such as methacrylic ester polymers or those containing a high proportion of N-methyl dimethylglutarimide units, by use of a blended absorber is extremely difficult to accomplish because of the thermal instability of such absorbers under conditions necessary to process the glassy polymer. Use of very low levels of a specific class of thermally stable additives produces a thermally stable polymer blend which may be converted into transparent sheet exhibiting lowered transmittal of near infra-red radiation and useful for many glazing applications.Type: GrantFiled: July 12, 1994Date of Patent: July 18, 1995Assignee: Atohaas B.V.Inventor: Leslie A. Cohen
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Patent number: 5427821Abstract: A corrosion-resistant polyurethane coating for application directly to a face as a self-priming topcoat comprising major amount of a polyurethane binder and minor amount of a combination of pigments consisting essentially of an aluminum phosphate, zinc salts of benzoic acids, and an alkaline earth metal phosphate such as zinc-barium phosphate. In addition, the coating contains up to about 30 parts by weight of a titanium dioxide pigment, up to about 2.0 parts by weight of an oil soluble surface active agent and up to about parts by weight of at least one organic solvent.Type: GrantFiled: June 20, 1994Date of Patent: June 27, 1995Assignee: The United States of America as represented by the Secretary of the NavyInventors: Charles R. Hegedus, Donald J. Hirst, Anthony T. Eng
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Patent number: 5422187Abstract: A vapor phase corrosion inhibitor-desiccant composite comprising silica gel granules coated with a vapor phase corrosion inhibitor component. The corrosion inhibitor component is selected from a formulation comprising anhydrous molybdates such as ammonium dimolybdate, sodium molybdate and amine molybdates mixed with benzotriazole and sodium nitrate, or from a formulation comprising amine benzoates, amine nitrates and benzotriazole. The composites can be impregnated into foam, extruded with polyolefin films which can additionally be laminated with metallized second film, or encapsulated in an air-permeable container. The corrosion inhibitor formulations have vapor pressures which provide ongoing corrosion protection for susceptible articles situated favorably with respect to the composite.Type: GrantFiled: October 14, 1993Date of Patent: June 6, 1995Assignee: Cortec CorporationInventors: Boris A. Miksic, Joseph M. Foley, Tsi-Zong Tzou
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Patent number: 5403880Abstract: A corrosion-resistant polyurethane coating for application directly to a face as a self-priming topcoat comprising major amount of a polyurethane binder and minor amount of a combination of pigments consisting essentially of an aluminum phosphate, zinc salts of benzoic acids, and an alkaline earth metal phosphate such as zinc-barium phosphate. In addition, the coating contains up to about 30 parts by weight of a titanium dioxide pigment, up to about 2.0 parts by weight of an oil soluble surface active agent and up to about 50 parts by weight of at least one organic solvent.Type: GrantFiled: March 7, 1994Date of Patent: April 4, 1995Assignee: The United States of America as represented by the Secretary of the NavyInventors: Charles R. Hegedus, Donald J. Hirst, Anthony T. Eng
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Patent number: 5308903Abstract: A corrosion-resistant coating which can be applied directly to a surface as self-priming topcoat comprising a polyurethane resin binder and a combination of pigments consisting essentially of a molybdate-modified zinc phosphate, zinc salts of benzoic acids, and an alkaline earth metal phosphate such as zinc-barium phosphate. In addition, the coating contains up to about 35 parts by weight of a titanium dioxide pigment, up to about 3.0 parts by weight of an oil soluble dispersant agent and up to about 50 parts by weight of at least one organic solvent.Type: GrantFiled: May 14, 1993Date of Patent: May 3, 1994Assignee: The United States of America as represented by the Secretary of the NavyInventors: Charles R. Hegedus, Donald J. Hirst, Anthony T. Eng
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Patent number: 5294352Abstract: A composition for the detackification and clarification of acid and alkaline paint and lacquer waste waters and paint spray booth wastes, comprising:an inorganic-organic and/or organic adduct alloy polymer composition having the formula:A.multidot.B.sup.+ .multidot.D.sup.+wherein:A=[(SiO.sub.2 /Me.sup.I.sub.2 O).sub.u Me.sup.II.sub.m Me.sub.m.sup.III(OH) p.sup.(SO 4.sup.) y.sup.(Aci) (2m+3n)-p-2y].sub.4wherer=1 to 98% bw;u=0 to 10% bw; ##STR1## where: x=0 to 98% bw; Z is a divalent substituted or unsubstituted aliphatic, cycloaliphatic, heterocyclic or aromatic radicalD.sup.+ (PQAM).sub.wwherew=2 to 98% b.w. of polyquaternized polymer (PQAM)Me.sub.m.sup.II is selected from the divalent cationic group comprising: Mg, Zn, Ca, and Fe.sup.2+m=0 to 5Me.sub.n.sup.III is a tri-or more valent metal selected from the group comprising: Fe, Al, and Al-Zn complexes;n=1 to 20Aci is selected from the monovalent anionic group comprising Cl.sup.-, Br.sup.-, I.sup.-, NO.sub.3 --, H.sub.2 PO.sub.4 --, CH.sub.3 COO.sup.-, OH.Type: GrantFiled: April 15, 1993Date of Patent: March 15, 1994Inventor: John J. Waldmann
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Patent number: 5290599Abstract: A corrosion-resistant coating which can be applied directly to a surface as self-priming topcoat comprising a polyurethane resin binder and a combination of pigments consisting essentially of an alkaline earth metal metaborate, zinc salts of benzoic acids, and an alkaline earth metal phosphate such as zinc-barium phosphate. In addition, the coating contains from 5-40 parts by weight of a titanium dioxide pigment, up to about 3.0 parts by weight of an oil soluble dispersant and up to about 50 parts by weight of at least one organic solvent.Type: GrantFiled: April 16, 1993Date of Patent: March 1, 1994Assignee: The United States of America as represented by the Secretary of the NavyInventors: Charles R. Hegedus, Donald J. Hirst, Anthony T. Eng
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Patent number: 5281635Abstract: A homogeneous composition for forming on firing a film of precious metal, which is one or more of platinum, palladium, gold and silver, on a substrate, for instance to decorate table ware, comprises polymeric resin and a solution, in water and a co-solvent, of thiolate of the precious metal, the composition containing 3-22% by weight of the precious metal as the thiolate, and the co-solvent, resin and thiolate being such that as the composition on a substrate dries and is progressively heated in firing, the water evaporates off to leave a homogeneous composition of the resin and thiolate in the co-solvent, then the co-solvent evaporates off to leave a homogeneous composition of the thiolate in the resin, and then the thiolate decomposes to the precious metal while the resin volatilise.Type: GrantFiled: April 29, 1992Date of Patent: January 25, 1994Assignee: Johnson Matthey Public Limited CompanyInventor: Peter T. Bishop
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Patent number: 5270374Abstract: An anti-nitriding composition comprising a water-based alkyd resin having suspended therein particulate tin and titanium dioxide; a thixotropic agent maintains the particulates in suspension during storage and application; the composition includes surfactant and co-solvent to impart paint-like characteristics. The composition is suitable for use as a local shield during the heat treatment of metals to prevent nitriding or ferritic nitro-carburization at temperatures in the range of about 850.degree. F. to about 1150.degree. F. The water-based formulation is safe to use and to transport, and has an air drying time at normal working temperatures comparable to those drying times previously achievable only with organic-solvent based anti-nitriding compositions.Type: GrantFiled: January 21, 1992Date of Patent: December 14, 1993Inventor: Glenn O. Ratliff
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Patent number: 5236983Abstract: A corrosion-resistant coating which can be applied directly to a surface as self-priming topcoat comprising a polyurethane binder and a combination of pigments consisting essentially of an alkaline earth metal phosphosilicate, zinc salts of benzoic acids, and an alkaline earth metal phosphate such as zinc-barium phosphate. In addition, the coating contains up to about 35 parts by weight of a titanium dioxide pigment and up to about 3.0 parts by weight of an oil soluble surface active agent and up to about 50 parts by weight of at least one organic solvent.Type: GrantFiled: December 20, 1991Date of Patent: August 17, 1993Assignee: The United States of America as represented by the Secretary of the NavyInventors: Charles R. Hegedus, Donald J. Hirst, Anthony T. Eng
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Patent number: 5210122Abstract: A polymeric composition having aromatic polycarbonate or aromatic polycarbonate like properties which process at significantly lower temperatures than aromatic polycarbonate in admixture with an additive which is incompatible with an aromatic polycarbonate at standard processing temperature.Type: GrantFiled: April 24, 1991Date of Patent: May 11, 1993Assignee: General Electric CompanyInventors: Luca P. Fontana, Kenneth F. Miller, Edgar E. Bostick
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Patent number: 5202367Abstract: A corrosion-resistant coating which can be applied directly to a surface as self-priming topcoat comprising an epoxy resin binder and a combination of pigments consisting essentially of an alkaline earth metal phosphosilicate, zinc salts of benzoic acids, and an alkaline earth metal phosphate such as zinc-barium phosphate. In addition, the coating contains up to about 35 parts by weight of a titanium dioxide pigment, up to about 3.0 parts by weight of an oil soluble surface active agent and up to about 50 parts by weight of at least one organic solvent.Type: GrantFiled: March 31, 1992Date of Patent: April 13, 1993Assignee: The United States of America as represented by the Secretary of the NavyInventors: Charles R. Hegedus, Donald J. Hirst, Anthony T. Eng
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Patent number: 5166235Abstract: Concentrate of a flame retardant additive, in the form of nonextruded particles, each one comprising:A) a matrix of a nonextruded, as polymerized particle, preferably spheroidal, of a polymer or copolymer of olefins having porosity greater than or equal to 15%, expressed as a percent of the void volume on the total volume of the particle,B) the product of reaction between bismuth or antimony trichloride or tribromide, or their mixtures, and one or more amines; wherein said product (B) is made "in situ" and deposited on the surface of the matrix and inside the pores thereof.Type: GrantFiled: October 23, 1991Date of Patent: November 24, 1992Assignee: Himont IncorporatedInventors: Guido Bertelli, Paolo Goberti
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Patent number: 5147915Abstract: An alkali-soluble coating formulation is disclosed. Such a coating formulation comprises a volatile, aqueous carrier; an alkali-soluble hydrophilic polymer, in the aqueous carrier; an alkali-soluble multivalent metal ion-containing bond-forming agent, also in the aqueous carrier; and an effective amount of a volatile alkali ingredient, in the aqueous carrier, for dissolving both the hydrophilic polymer as well as the multivalent metal ion-containing bond-forming agent. The relative amounts of hydrophilic polymer and multivalent metal ion-containing bond-forming agent, in the aqueous carrier, are effective for forming an alkali-soluble polymeric coating on a substrate, upon evaporation of the volatile, aqueous carrier therefrom.Type: GrantFiled: September 13, 1991Date of Patent: September 15, 1992Assignee: S. C. Johnson & Son, Inc.Inventors: Glenn C. Calhoun, Robert W. Stackman, Michael E. Klinkhammer
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Patent number: 5130361Abstract: A corrosion-resistant coating which can be applied directly to a surface as self-priming topcoat comprising from about 10 to 90 percent by weight of an epoxy binder and 5 to 65 percent by weight of a combination of metal salts or pigments which consist essentially of calcium borosilicate, zinc salts of benzoic acids, and an alkaline earth metal phosphate such as zinc-barium phosphate. In addition, the coating may contain up to about 30 percent by weight of a titanium dioxide pigment and up to about 75 percent by weight of at least one organic solvent.Type: GrantFiled: August 2, 1991Date of Patent: July 14, 1992Assignee: The United States of America as represented by the Secretary of the NavyInventors: Charles R. Hegedus, Donald J. Hirst, Anthony T. Eng
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Patent number: 5124385Abstract: A corrosion-resistant coating which can be applied directly to a surface as self-priming topcoat comprising from about 10 to 90 percent by weight of a polymeric polyurethane binder and 5 to 65 percent by weight of a combination of metal salts or pigments which consist essentially of calcium borosilicate, zinc salts of benzoic acids, and an alkaline earth metal phosphate such as zinc-barium phosphate. In addition, the coating may contain up to about 30 percent by weight of a titanium dioxide pigment and up to about 75 percent by weight of at least one organic solvent.Type: GrantFiled: May 13, 1991Date of Patent: June 23, 1992Assignee: The United States of America as represented by the Secretary of the NavyInventors: Charles R. Hegedus, Donald J. Hirst, Anthony T. Eng
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Patent number: 5110854Abstract: An anti-nitriding composition comprising a water-based alkyd resin having suspended therein particulate tin and titanium dioxide; a thixotropic agent maintains the particulates in suspension during storage and application; the composition includes surfactant and co-solvent to impart paint-like characteristics. The composition is suitable for use as a local shield during the heat treatment of metals to prevent nitriding or ferritic nitro-carburization at temperatures in the range of about 850.degree. F. to about 1150.degree. F. The water-based formulation is safe to use and to transport, and has an air drying time at normal working temperatures comparable to those drying times previously achievable only with organic-solvent based anti-nitriding compositions.Type: GrantFiled: March 8, 1990Date of Patent: May 5, 1992Inventor: Glenn O. Ratliff
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Patent number: 5110849Abstract: The present invention concerns a thermoplastic polyester resin composition comprising a thermoplastic polyester and a metal alcoholate salt of an aromatic alcohol containing a hydroxy group directly attached to the aromatic ring as the essential ingredient, having a high crystallization rate, excellent moldability upon molding at low temperature, less molecular weight reduction during production and molding of the resin composition, and satisfactory melt degradation stability and hydrolysis resistance.Type: GrantFiled: August 10, 1990Date of Patent: May 5, 1992Assignee: Toray Industries, Inc.Inventors: Hiroo Karasawa, Kiichi Kometani, Kiyokazu Nakamura
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Patent number: 5100942Abstract: This invention relates to a corrosion-resistant coating capable of being lied to various substrates, e.g., particularly metal and plastic surfaces, as a single coat characterized as having a high-gloss, good adhesion and a high degree of flexibility. The corrosion inhibiting composition comprises an acrylic resin containing an effective amount of a corrosion-inhibiting pigment system consisting essentially of critical amounts of at least one zinc phosphate, zinc molybdate and at least one zinc salt of a benzoic acid.Type: GrantFiled: April 3, 1991Date of Patent: March 31, 1992Assignee: The United States of America as represented by the Secretary of the NavyInventors: Charles R. Hegedus, Donald J. Hirst, William J. Green, Anthony T. Eng
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Patent number: 5093396Abstract: An alkali-soluble coating formulation is disclosed. Such a coating formulation comprises a volatile, aqueous carrier; an alkali-soluble hydrophilic polymer, in the aqueous carrier; an alkali-soluble multivalent metal ion-containing bond-forming agent, also in the aqueous carrier; and an effective amount of a volatile alkali ingredient, in the aqueous carrier, for dissolving both the hydrophilic polymer as well as the multivalent metal ion-containing bond-forming agent. The relative amounts of hydrophilic polymer and multivalent metal ion-containing bond-forming agent, in the aqueous carrier, are effective for forming an alkali-soluble polymeric coating on a substrate, upon evaporation of the volatile, aqueous carrier therefrom.Type: GrantFiled: July 26, 1990Date of Patent: March 3, 1992Assignee: S. C. Johnson & Son, Inc.Inventors: Glenn C. Calhoun, Robert W. Stackman, Michael E. Klinkhammer
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Patent number: 5043373Abstract: A high-gloss, corrosion-resistant coating which can be applied directly to surface comprising about 30 to 82 percent by weight of a polymeric binder and 18 to 70 percent by weight of a pigment system consisting essentially of zinc molybdate, zinc salt of benzoic acids, and zinc phosphate in specific ratio's. The coating exhibits good adhesion, flexibility, chemical- and weather-resistance.Type: GrantFiled: November 28, 1989Date of Patent: August 27, 1991Assignee: The United States of America as represented by the Secretary of the NavyInventors: Charles R. Hegedus, Donald J. Hirst, Anthony T. Eng, William J. Green
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Patent number: 4973606Abstract: A membrane of an organic polymer, which contains a crystalline carrier compound capable of selective transport of low molecular weight substances, and the preparation and use of the said membrane.Type: GrantFiled: November 17, 1988Date of Patent: November 27, 1990Assignee: BASF AktiengesellschaftInventors: Hans-Josef Sterzel, Axel Sanner
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Patent number: 4935459Abstract: Flameproofed compositions of matter include an organic synthetic resin and, as a flame retardant therefor, an effective flameproofing amount of specified nitrogenous/halometallic compounds, certain of which are per se novel.Type: GrantFiled: August 24, 1989Date of Patent: June 19, 1990Assignee: AtochemInventors: Daniel Sallet, Pierre Deloy, Valerie Mailhos-Lefievre, Pierre Poisson
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Patent number: 4885324Abstract: A coating for metallic or polymeric composite substrates is disclosed which erforms both as a primer and as a topcoat. It comprises a two component aliphatic polyurethane binder, with titanium dioxide, zinc molybdate, zinc phosphate, an organo-zinc salt, and titanium dioxide vesiculated bead pigments in controlled amounts. The coating exhibits good adhesion, corrosion inhibition, flexibility, chemical and weather resistance, and opacity.Type: GrantFiled: March 28, 1989Date of Patent: December 5, 1989Assignee: The United States of America as represented by the Secretary of the NavyInventors: Charles R. Hegedus, William J. Green
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Patent number: 4874806Abstract: An emulsion paint of an improved shear resistance has been developed containing as a filling agent a titanium chelate which is the reaction product of a titanium orthoester, a glycol a glycol ether, an alkanolamine and an alpha-hydroxy carboxylic acid.Type: GrantFiled: July 13, 1988Date of Patent: October 17, 1989Assignee: Tioxide Group PLCInventors: Peter D. Kay, Keith McDonald
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Patent number: 4861816Abstract: A polyvinyl chloride resin composition for powder molding which is excellent in resistance to mold staining and in amine resistance, the improvement wherein the polyvinyl chloride composition contains blended therein 0.1-10 parts by weight of a stabilizer mixture of barium salt of the carboxylic acid and zinc salt of a carboxylic acid, each having a melting point not lower than 250.degree. C., the barium and zinc metallic weight ratio being 1:5 to 5:1, and 0.1-10 parts by weight of a metal perchlorate and/or perchlorate ion type hydrotalcite compound per 100 parts by weight of a polyvinyl chloride resin.Type: GrantFiled: December 9, 1987Date of Patent: August 29, 1989Assignee: Sumitomo Chemical CompanyInventors: Masanori Kobayashi, Isao Matsuura, Akira Wakatsuki, Yu Shida
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Patent number: 4798857Abstract: Disclosed are complexes of bismuth or antimony halides with amines having formula:R.cndot.(MeX.sub.3)y,where R is dicyandiamide, guanamine, 2-guanidinobenz-imidazole, isophoronediamine, piperazine, melamine or a compound having from 2 to 9 triazine rings condensed or linked to each other through at least one --NH-- group; Me is Bi or Sb; X is chlorine or bromine; and y is a number from 0.3 to 4. Processes for preparing the complexes and flame retardant thermoplastic polymer compositions containing the complexes are also disclosed.Type: GrantFiled: December 30, 1987Date of Patent: January 17, 1989Assignee: HIMONT IncorporatedInventors: Guido Bertelli, Patrizia Busi, Renato Locatelli
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Patent number: 4731400Abstract: A thermoplastic resin composition having excellent transparency and a high ultraviolet transmittance and free from a reddish color is obtained from a polymer or copolymer of 4-methyl-1-pentene and a blue pigment. Preferably, the composition further comprises a black pigment and/or a red pigment.Type: GrantFiled: December 16, 1985Date of Patent: March 15, 1988Assignee: Mitsui Petrochemical Industries, Ltd.Inventor: Hiromi Shigemoto
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Patent number: 4701518Abstract: Antimicrobial activity is imparted to nylon during its preparation by adding to the nylon-forming monomer(s), a zinc compound (e.g. zinc ammonium carbonate) and a phosphorus compound (e.g. benzene phosphinic acid). The compounds are added in amounts sufficient to form in situ a reaction product containing at least 300 ppm of zinc, based on the weight of nylon prepared. Fibers made from the resulting nylon contain the reaction product uniformly dispersed therein and have antimicrobial activity of a permanent nature.Type: GrantFiled: May 8, 1986Date of Patent: October 20, 1987Assignee: Monsanto CompanyInventors: Scott E. Osborn, Vincent J. Farrugia, LeMoyne W. Plischke, Chester C. Wu
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Patent number: 4673631Abstract: A triboelectrically chargeable composition for use in development of electrostatic latent images. The composition contains a metal complex of an amino acid compound having an amino or mono-substituted amino group and a carboxylic group. The composition is embodied typically as a positively chargeable toner and also as a charge-imparting material for charging a toner.Type: GrantFiled: December 13, 1985Date of Patent: June 16, 1987Assignee: Canon Kabushiki KaishaInventors: Hiroshi Fukumoto, Katsuhiko Tanaka, Yoji Kawagishi
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Patent number: 4670523Abstract: A magnet wire enamel having improved runnability and insulating properties is described comprising nylon containing 0.25% to 20% by weight titanium chelate. The nylon can be a sole coat, outermost coating, or bond coat.Type: GrantFiled: July 19, 1985Date of Patent: June 2, 1987Assignee: Essex Group, Inc.Inventor: Francois A. Lavallee
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Patent number: 4661548Abstract: An aqueous copolymer emulsion useful as a ceramic tile adhesive contains filler material, a zinc compound and an aqueous emulsion of a copolymer containing residues of an unsaturated aliphatic hydrocarbon monomer, an unsaturated monomer copolymerizable therewith and a small amount of residues containing carboxyl groups.Type: GrantFiled: November 20, 1985Date of Patent: April 28, 1987Assignee: Scott Bader Company LimitedInventor: Robert G. Parker
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Patent number: 4632954Abstract: This invention is directed to a method of improving the heat aging properties of a halogen-containing rubber comprising adding an effective amount of a compound selected from the group consisting of aromatic amino acids, related compounds, and salts of hydroxy benzoic acid to said halogen-containing rubber prior to vulcanization, and then vulcanizing.Type: GrantFiled: June 27, 1985Date of Patent: December 30, 1986Assignee: Calgon CorporationInventor: Albert J. Dalhuisen
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Patent number: 4632951Abstract: Flameproofing additives for plastics materials consisting of a coating- and carrier material. The coating consists of metal oxides, the carrier of organic compounds, in which halogen is bound to carbon. The combination of the two components of the flameproofing additives has an inhibiting action on the fire and gives plastics materials an effective fire protection according to the invention, for example, V-2 to V-0 according to UL 94.Type: GrantFiled: June 19, 1985Date of Patent: December 30, 1986Assignee: Bayer AktiengesellschaftInventors: Karl Fuhr, Friedemann Muller, Theobald Eicher
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Patent number: 4626283Abstract: Amine-complexed zinc salts of organic diacids selected from the group consisting of (i) dicarboxylic acids, (ii) diphenols, and (iii) phthalic acids. Specifically disclosed compounds include C.sub.2 -C.sub.3 alkylene diamine-complexed zinc salts of thiodiphenol and sulfonyldiphenol, and ethylene diamine-complexed salts of phthalic, isophthalic and terephthalic acids. Such amine-complexed zinc salts have utility as corrosion inhibitors in coating compositions for metallic substrates, e.g., paints based on alkyds, latexes or linseed oil. Also disclosed are anticorrosion additives, comprising the aforementioned amine-complexed salts distended on mineral fillers such as kaolin, and a method of making same by reaction of zinc oxide, amine, and organic diacid, at elevated temperatures, in an aqueous slurry of the mineral filler. At least the dicarboxylic acid and diphenol derived salts also display utility as inhibitors of marine growth (algae and barnacles) on substrates.Type: GrantFiled: March 21, 1985Date of Patent: December 2, 1986Assignee: Engelhard CorporationInventors: Evon Martins, Richard A. Slepetys
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Patent number: 4622069Abstract: A composition for forming electroless plating on ceramics which comprises (i) 1 weight part of at least one member selected from the group consisting of organic palladium compounds and organic silver compounds, (ii) 0.1 to 200 weight parts of at least one member selected from the group consisting of organic metal compounds, (iii) 10 to 1000 weight parts of an organic solvent and optionally (iv) 1 to 500 weight parts of at least one member selected from the group consisting of high molecular compounds and particulate inorganic substances.Type: GrantFiled: November 15, 1985Date of Patent: November 11, 1986Assignee: Okuno Chemical Industry Co., Ltd.Inventors: Yoshito Akai, Nobuyuki Konaga, Yasunori Arisato, Masatoshi Wada, Yukikazu Moritsu
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Patent number: 4568485Abstract: The invention relates to plastics materials of high electrical conductivity containing TCNQ complexes and stabilized against the emission of HCN and to mouldings, films and coatings of such materials, as well as to the use of the plastics material for the production of antistatic foils and coatings onto substrates.Type: GrantFiled: September 17, 1984Date of Patent: February 4, 1986Assignee: Bayer AktiengesellschaftInventors: Friedrich Jonas, Jurgen Hocker
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Patent number: 4439562Abstract: Disclosed is a mass-dyed polymeric material, e.g. polyester, comprising, as dyestuff, a compound or mixture of compounds of formula I ##STR1## herein the nuclei A, B and D may bear one or more substituents and Me is Ni or Cu. The mass-dyed polymeric material is preferably prepared by incorporating the compounds of formula I in form of a master-batch.Type: GrantFiled: August 16, 1982Date of Patent: March 27, 1984Assignee: Sandoz Ltd.Inventor: Hans Bohler
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Patent number: 4425279Abstract: Tridodecylammonium molybdates having the empirical formula[(C.sub.12 H.sub.25).sub.3 NH].sub.a Mo.sub.b O.sub.cwhere a, b and c are (2,6,19); (6,7,24) or (4,8,26) are disclosed as novel amine molybdates which are useful as smoke retardant additives for vinyl chloride polymer compositions.Type: GrantFiled: July 28, 1982Date of Patent: January 10, 1984Assignee: The B. F. Goodrich CompanyInventor: William J. Kroenke
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Patent number: 4424164Abstract: Dimethyldioctadecylammonium molybdates having the empirical formula?(CH.sub.3).sub.2 (C.sub.18 H.sub.37).sub.2 N!.sub.a Mo.sub.b O.sub.cwhere a, b and c are (2, 6, 19); (6, 7, 24) or (4, 8, 26) are disclosed as novel amine molybdates which are useful as smoke retardant additives for vinyl chloride polymer compositions.Type: GrantFiled: July 28, 1982Date of Patent: January 3, 1984Assignee: The B. F. Goodrich CompanyInventor: William J. Kroenke
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Patent number: 4424294Abstract: Injection moldable amide-imide homopolymers and copolymers containing titanates. These amide-imides are useful in engineering plastic applications.Type: GrantFiled: March 31, 1983Date of Patent: January 3, 1984Assignee: Standard Oil Company, (Indiana)Inventor: Wassily Poppe
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Patent number: 4419479Abstract: Reinforced polymer compositions comprising a minor effective amount of a particulate metal reinforcing agent are provided. A preferred particulate metal reinforcing agent preferably comprises a plurality of discrete particles, each further comprising nickel, chromium and titanium carbide. Polymer compositions adapted to undergo a color change when subjected to a particular thermal history for a particular time interval are also provided.Type: GrantFiled: January 14, 1983Date of Patent: December 6, 1983Assignee: Regal International, Inc.Inventor: Virgil E. Springer
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Patent number: 4410650Abstract: An olefin polymer composition containing an ultraviolet light stabilizer. The ultraviolet light stabilizer is a zerovalent nickel complex the organic portion of which is an ester of pentaerythritol phosphite.Type: GrantFiled: August 9, 1982Date of Patent: October 18, 1983Assignee: Borg-Warner Chemicals, Inc.Inventors: Elyse M. Lewis, Leo L. Valdiserri
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Patent number: 4399247Abstract: Aqueous organopolysiloxane compositions are disclosed which are useful for durably treating substrates such as fibers, textiles and sheet-form materials. The aqueous organopolysiloxane compositions further contain an acid to adjust the pH of the composition to a non-basic value, an organic ester of titanic, zirconic or germanic acid and a surfactant to render the composition homogeneous. The organopolysiloxane contains monovalent hydrocarbon groups, aminohydrocarbon groups, hydroxy- or ether hydrocarbon groups and, optionally silicon-bonded hydroxyl and/or alkoxy groups.Type: GrantFiled: June 17, 1982Date of Patent: August 16, 1983Assignee: Toray Silicone Company, Ltd.Inventors: Isao Ona, Masaru Ozaki, Katsutoshi Usui, Yoichiro Taki
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Patent number: 4374048Abstract: An electrically conductive composition comprises a poly (vinylacetal) polymer, a TCNQ salt uniformity dispersed throughout the polymer, and optionally a plasticizer.Type: GrantFiled: August 7, 1981Date of Patent: February 15, 1983Assignee: The United States of America as represented by the Secretary of the NavyInventors: Oh-Kil Kim, Robert B. Fox
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Patent number: 4371651Abstract: Stabilizer compositions and polyvinyl halide resin compositions containing 1,3-dicarbonyl compounds having the formula: ##STR1## as well as metal and organotin enolate salts thereof, effective in enhancing the resistance to deterioration by heat and light of polyvinyl halide resins.Type: GrantFiled: January 21, 1981Date of Patent: February 1, 1983Assignee: Phoenix Chemical CorporationInventors: William E. Leistner, Motonobu Minagawa, Kouji Tsuruga, Masashi Harada
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Patent number: RE33223Abstract: The invention relates to plastics materials of high electrical conductivity containing TCNQ complexes and stabilized against the emission of HCN and to mouldings, films and coatings of such materials, as well as to the use of the plastics material for the production of antistatic foils and coatings onto substrate.Type: GrantFiled: January 15, 1988Date of Patent: May 29, 1990Assignee: Bayer AktiengesellschaftInventors: Friedrich Jonas, Jurgen Hocker