Two Or More Solid Polymers Or At Least One Solid Polymer And At Least One Specified Intermediate Condensation Product Patents (Class 524/271)
  • Patent number: 6034159
    Abstract: A hot melt adhesive for multipurpose bookbinding comprising a) from about 35% to about 40% by weight of a styrene-isoprene-styrene bloc copolymer; b) from about 25% to about 50% by weight of at least one compatible tackifying resin; c) from about 5% to about 30% by weight of a synthetic high melt point wax; d) from about 5% to about 30% by weight of a solid benzoate plasticizer; e) up to about 25% of a compatible wax; and f) up to about 15% of a compatible polymer.
    Type: Grant
    Filed: July 3, 1996
    Date of Patent: March 7, 2000
    Assignee: H.B. Fuller Licensing & Financing, Inc.
    Inventor: David B. Malcolm
  • Patent number: 6022914
    Abstract: The present invention relates to a pressure-sensitive adhesive composition containing a non-halogen, non-intumescent flame-retardant system comprising at least one flame-retardant agent with the provisos that the flame-retardant system does not comprise Sb.sub.2 O.sub.3 or does not consist only of alumina trihydrate.
    Type: Grant
    Filed: November 27, 1995
    Date of Patent: February 8, 2000
    Assignee: 3M Innovative Properties Company
    Inventors: Petra Nowak, Robert D. Waid, William D. Coggio
  • Patent number: 5994437
    Abstract: The invention is a thermofusible adhesive composition comprising:a at least one essentially amorphous poly(alpha-olefin),b at least one copolymer of ethylene and an alkyl (meth)acrylate, the cloud point being below 170.degree. C.
    Type: Grant
    Filed: June 12, 1995
    Date of Patent: November 30, 1999
    Assignee: Elf Atochem S.A.
    Inventors: Jean Lebez, Jean-Michel Pierrot, Eric Radigon
  • Patent number: 5981627
    Abstract: This invention relates to stable one-part latex compositions prepared by aqueous emulsion polymerization wherein a core-shell polymer is formed, the core formed by emulsion polymerization of an ethylenically unsaturated monomer in the presence of an epoxy resin and the shell polymer formed by emulsion polymerization of a hydroxy carboxyl containing monomer composition in the presence of the core, providing that the monomers in both the core and the shell do not contain amino functional groups, and post-adding to the formed core-shell polymer an organic compound having at least one amino functional group which is available for later reaction with the epoxy resin upon drying to produce a crosslinked polymer product.
    Type: Grant
    Filed: October 9, 1992
    Date of Patent: November 9, 1999
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Yen-Jer Shih, Arthur B. Pruiksma
  • Patent number: 5981649
    Abstract: A rubber composition suitable for use in grips of articles such as golf clubs, tennis rackets, bicycles and tools, comprising (1) a rubber component containing an ethylene-propylene-diene rubber (EPDM), and (2) 5 to 100 parts by weight of a polyisobutylene having a viscosity average molecular weight of 6,000 to 50,000, which provides grips having good feeling of touch, good non-slipping properties in both fine and rainy weather, and giving a small feeling of impact to mis-shot of golf balls as compared with conventional grips.
    Type: Grant
    Filed: May 19, 1993
    Date of Patent: November 9, 1999
    Assignee: Sumitomo Rubber Industries, Ltd.
    Inventors: Hidenori Hiraoka, Akihiko Hamada
  • Patent number: 5942569
    Abstract: A polymeric composition in pellet form comprising a tacky hot melt composition, comprising a) from about 5% by weight to about 90% by weight of a thermoplastic polymer, b) from about 0% by weight to about 65% by weight of a tackifying resin, c) from about 0% to about 50% by weight of a plasticizer, d) up to about 2% by weight of an antioxidant, and a pelletizing aid, wherein the tacky hot melt composition has some minimum amount of tackifier or plasticizer and is a pressure sensitive adhesive having a storage modulus, G', at about 25.degree. C., of less than about 5.times.10.sup.6 dynes/cm.sup.2, and each pellet has a substantially tack-free surface.This invention further discloses a polymeric composition in pellet form suitable for molding articles. The composition comprises a tacky hot melt composition comprising at least one high molecular weight triblock copolymer of the general configuration A-B-A and a plasticizer and a pelletizing aid.
    Type: Grant
    Filed: August 31, 1998
    Date of Patent: August 24, 1999
    Assignee: H.B. Fuller Licensing & Financing, Inc.
    Inventors: Eugene R. Simmons, Kevin J. Sweeney, Jeffrey S. Lindquist, Christopher E. Olson, Freddie C. Carter, James R. Farmer
  • Patent number: 5939483
    Abstract: A hot melt useful for packaging comprising a) from about 10% to about 40% by weight of a block copolymer; b) up to about 20% of a compatible polymer wherein the total polymer content does not exceed 40% by weight; c) from about 25% to about 60% by weight of at least one tackifying resin; d) from about 5% to about 25% by weight of a compatible plasticizer; and e) from about 10% to about 40% by weight of at least one wax component wherein the viscosity of the hot melt adhesive is less than about 1500 cPs at about 150.degree. C.
    Type: Grant
    Filed: July 14, 1997
    Date of Patent: August 17, 1999
    Assignee: H.B. Fuller Licensing & Financing, Inc.
    Inventor: Michelle C. Kueppers
  • Patent number: 5932648
    Abstract: A low viscosity, low VOC content fumigation adhesive formulation which is comprised ofa) 100 parts by weight (pbw) of a blend of a styrene-diene triblock copolymer, hydrogenated or unhydrogenated, having a weight average molecular weight of 30,000 to 200,000 and a polystyrene content of from 10 to 40% by weight of the polymer, and a styrene-diene diblock copolymer having a weight average molecular weight of 10,000 to 40,000 and a polystyrene content of from 10 to 40% by weight of the polymer, wherein the diblock comprises from 60 to 95% by weight of the polymer blend,b) 75 to 275 parts by weight (pbw) of a tackifying resin which is compatible with the diene blocks, andc) 50 to 200 parts by weight (pbw) of a solvent for the polymer.
    Type: Grant
    Filed: September 11, 1996
    Date of Patent: August 3, 1999
    Assignees: Shell Oil Company, AC Products
    Inventors: James Louis Troska, Larry McArthur Kegley, William Brian Dances
  • Patent number: 5925459
    Abstract: Use of a transparent grip tab for a strip of adhesive film for a temporary bond based on thermoplastic rubber and tackifier resins, where the adhesive film is of high elasticity and low plasticity and where the adhesion is lower than the cohesion, the adhesion largely disappears when the film is extended, the ratio of peel force to tear load is at least 1:1.5, and where an adhesive bond produced therewith can be detached by pulling on the adhesive film in the direction of the bond plane.
    Type: Grant
    Filed: July 1, 1997
    Date of Patent: July 20, 1999
    Assignee: Beiersdorf AG
    Inventors: Dieter Zimmermann, Bernd Luhmann
  • Patent number: 5912295
    Abstract: This invention relates to a removable grade hot melt pressure sensitive adhesive comprising from about 5% to about 30% by weight of the adhesive of a block copolymer having styrene endblocks and ethylene/butylene or ethylene/propylene midblocks and having a coupling efficiency of less than about 65% and a melt index of greater than about 20 grams/10 minutes; from about 10% to about 50% by weight of the adhesive of at least one block copolymer having styrene endblocks and a coupling efficiency from about 65% to about 100%; from about 20% to about 60% by weight of the adhesive of a tackifying resin and from about 10% to about 40% by weight of the adhesive of a liquid plasticizing oil.
    Type: Grant
    Filed: October 24, 1997
    Date of Patent: June 15, 1999
    Assignee: H.B. Fuller Licensing & Financing, Inc.
    Inventors: Susan T. Oeltjen, Jeffrey S. Lindquist
  • Patent number: 5910527
    Abstract: A hot melt construction adhesive having a high acid number and which possesses superior properties for the construction of disposable soft goods. The adhesive composition includes an A-B-A block copolymer; a resin; a compatible mineral oil; and an antioxidant; and wherein the hot melt construction adhesive has a viscosity of less than 10,000 cP at 325.degree. F., a melting point of less than 190.degree. F., and an acid number of greater than 30.
    Type: Grant
    Filed: August 19, 1997
    Date of Patent: June 8, 1999
    Assignee: Ato Findley, Inc.
    Inventors: Mark D. Alper, Diane Strelow
  • Patent number: 5901766
    Abstract: The present invention relates to a pneumatic tire having a tread containing (a) from 50 to 90 phr (parts by weight of rubber per 100 total parts of rubber) of a rubber which, in its uncured state, has a glass transition temperature in the range of from -80.degree. C. to -110.degree. C. and (b) from 15 to 50 phr of a resin.
    Type: Grant
    Filed: August 26, 1997
    Date of Patent: May 11, 1999
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Paul Harry Sandstrom, Edward John Blok, John Joseph Andre Verthe
  • Patent number: 5902849
    Abstract: A filling compound for electrical and optical equipment in the form of cables, connectors, plugs etc. and to assemblies thus produced, is provided. Electrical and optical equipment in the form of cables, connectors, plugs etc. have to be protected against harmful influences penetrating from outside, particularly water, and also against mechanical damage during laying or as a result of exposure to heat. The filling compound is based on a stellate substance, i.e. a substance having a branched molecular structure in which, ideally, 3 or more branches, more particularly polymeric chains, radiate from a single branching point. The filling compound is flexible at very low temperatures but, on the other hand, does not run out, even at extremely high temperatures.
    Type: Grant
    Filed: November 12, 1996
    Date of Patent: May 11, 1999
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Reimar Heucher, Juergen Wichelhaus, Johannes Andres
  • Patent number: 5869562
    Abstract: This invention relates to an envelope coated with a hot melt pressure sensitive adhesive composition preferably comprising a) from about 10% to about 40% by weight in the adhesive of at least one block copolymer selected from the group consisting of styrene-isoprene-styrene block copolymers, styrene-butadiene-styrene block copolymers and mixtures thereof wherein the block copolymers comprise from about 15% to about 35% styrene by weight in the copolymer and diblock contents from about 0% to about 90% by weight in the copolymer; and b) from about 60% to about 90% by weight in the adhesive of a modifier selected from the group consisting of solid tackifying resins, liquid tackifying resins, liquid elastomers and mixtures thereof. The invention further relates to an improved oil-free pressure sensitive adhesive that is low in viscosity and provides a destructive bond and resists deformation of high density spun polyolefin materials.
    Type: Grant
    Filed: March 28, 1997
    Date of Patent: February 9, 1999
    Assignee: H. B. Fuller Licensing & Financing, Inc.
    Inventors: Jeffrey S. Lindquist, Janelle C. Cameron, Eugene R. Simmons
  • Patent number: 5869555
    Abstract: A polymeric composition in pellet form comprising a tacky hot melt composition, comprising a) from about 5% by weight to about 90% by weight of a thermoplastic polymer, b) from about 0% by weight to about 65% by weight of a tackifying resin, c) from about 0% to about 50% by weight of a plasticizer, d) up to about 2% by weight of an antioxidant, and a pelletizing aid, wherein the tacky hot melt composition has some minimum amount of tackifier or plasticizer and is a pressure sensitive adhesive having a storage modulus, G', at about 25.degree. C., of less than about 5.times.10.sup.6 dynes/cm.sup.2, and each pellet has a substantially tack-free surface.This invention further discloses a polymeric composition in pellet form suitable for molding articles. The composition comprises a tacky hot melt composition comprising at least one high molecular weight triblock copolymer of the general configuration A-B-A and a plasticizer and a pelletizing aid.
    Type: Grant
    Filed: November 18, 1996
    Date of Patent: February 9, 1999
    Assignee: H. B. Fuller Licensing & Financing Inc.
    Inventors: Eugene R. Simmons, Kevin J. Sweeney, Jeffrey S. Lindquist, Christopher E. Olson, Freddie C. Carter, James R. Farmer
  • Patent number: 5859111
    Abstract: A process is described for preparing aqueous polymeric dispersions of a dispersion of an interpenetrated polymer of a hydrophobic polyurethane and a polymer prepared from ethylenically unsaturated monomers, and optionally a dispersion of another monomer that will enhance the performance of the interpenetrated polymer.
    Type: Grant
    Filed: December 18, 1996
    Date of Patent: January 12, 1999
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Pravin K. Kukkala, Andrew J. Kielbania, Osamu Futakuchi
  • Patent number: 5856386
    Abstract: A crystalline thermoplastic resin composition comprises a rosin acid metallic salt and a crystalline thermoplastic resin. Optionally, a compatibilizing agent may also be included. The rosin acid metallic salt, which acts as a crystal nucleating agent, increases the crystallization rate of the crystalline thermoplastic resin and enables the formation of fine crystals of the resin. Thus, the crystalline thermoplastic resin composition can crystallize at a high rate, and provide molded articles having excellent mechanical properties and/or optical properties.
    Type: Grant
    Filed: January 22, 1997
    Date of Patent: January 5, 1999
    Assignees: Mitsui Petrochemicals Industries, Ltd., Arakawa Chemical Industries, Ltd.
    Inventors: Hideki Sakai, Mikio Nakagawa, Tetsuji Kasai, Kimio Ueda, Masao Maeda, Yukiharu Yamada, Hiroyuki Hori, Junji Tan, Kan Matsumoto
  • Patent number: 5856387
    Abstract: A pressure sensitive adhesive of a mutually immiscible first elastomer (styrene-butadiene block copolymer) exhibiting a first glass transition temperature and a second elastomer (e.g., a styrene-isoprene-styrene block copolymer) exhibiting a second glass transition temperature greater than the first is tackified by a tackifying system comprising tackifier preferentially miscible with the second elastomer to provide a dynamic mechanical spectrum plot of tangent delta versus temperature in .degree.C. showing two separate and distinct glass transition temperature peaks. The mixture exhibits excellent processability and ambient and low temperature adhesive properties.
    Type: Grant
    Filed: August 29, 1997
    Date of Patent: January 5, 1999
    Assignee: Avery Dennison Corporation
    Inventors: Yukihiko Sasaki, Jesse Ercillo
  • Patent number: 5840797
    Abstract: A light weight, vibration-damping composition having effective amounts of at least one butyl rubber, at least one tackifying resin, at least one pigment and substantially spherical microspheres is disclosed. The present composition has a specific gravity of about 1.0 to 1.2 and has effective damping effects at low temperatures as well as temperatures up to about 60.degree. C. This composition is effective for use in the transportation industry, the building industry, the aerospace industry and the appliance industry.
    Type: Grant
    Filed: September 16, 1996
    Date of Patent: November 24, 1998
    Assignee: H. B. Fuller Licensing & Financing, Inc.
    Inventor: Raj V. Singh
  • Patent number: 5834538
    Abstract: A pressure sensitive adhesive(PSA) composition includes a latex system of an aqueous polymer dispersion derived from ethylenically-unsaturated monomers in the presence of a water soluble protective colloid. The PSA compositions are used in the manufacture of a variety of articles that are intended to be easily attachable to another substrate by the application of pressure alone.
    Type: Grant
    Filed: June 18, 1996
    Date of Patent: November 10, 1998
    Assignee: Hercules Incorporated
    Inventors: Jacobus G. deHullu, Dirk Kruythoff, Willemien G. Salomons, Adriana Veldhorst
  • Patent number: 5786418
    Abstract: A hot melt adhesive is described which possesses superior properties for the construction of disposal soft articles and more specifically disposable soft articles which may be exposed to moisture for prolonged periods of time. The adhesive composition includes about 10% to about 60% by weight of a butene-1-ethylene copolymer; about 20% to about 80% by weight of a tackifying resin; about 5% to about 30% by weight of a plasticizer; and about 0.1% to about 3% by weight of an antioxidant, wherein the ingredients total 100%, by weight, of the entire adhesive composition.
    Type: Grant
    Filed: July 3, 1996
    Date of Patent: July 28, 1998
    Assignee: Findley Adhesives, Inc.
    Inventors: Diane Strelow, Mark Alper
  • Patent number: 5773506
    Abstract: The present invention provides a block copolymer pressure sensitive adhesive (PSA) composition. The block copolymer has at least one midblock segment and at least one endblock segment. The midblock comprises a polymerized conjugated diene segment or hydrogenated derivative thereof. The endblock comprises a polymerized monovinyl aromatic segment having a number average molecular weight less than about 8,000. The PSA further comprises at least one tackifier or oil that is compatible with the low molecular weight endblock segment of the block copolymer. The PSA composition of the invention has a reduced elastic index and is capable of dissipating stress. This is useful in providing tapes which are capable of withstanding stresses such as those caused by temperature fluctuations, dimensional changes in the backing, or the recovery forces of a backing applied under tension. The present invention also provides a method of reducing the elastic index of a block copolymer PSA composition.
    Type: Grant
    Filed: December 9, 1996
    Date of Patent: June 30, 1998
    Assignee: Minnesota Mining and Manufacturing
    Inventors: Mark K. Nestegard, Jingjing Ma
  • Patent number: 5763516
    Abstract: Hot-melt adhesive compositions useful for packaging are disclosed. These hot-melt adhesive compositions are based on modified polyethylene and contain a linear, low density copolymer or terpolymer of ethylene and another alpha-olefin, a polyethylene graft copolymer, a tackifying resin, and a high-melting low viscosity wax. The hot-melt adhesive compositions disclosed herein produce very good adhesive bonds, even at high speed packaging conditions under a broad range of ambient packaging temperatures. These inventive adhesive compositions have a novel combination of good hot tack and good adhesive bond properties, even at extreme conditions.
    Type: Grant
    Filed: April 24, 1996
    Date of Patent: June 9, 1998
    Assignee: H.B. Fuller Licensing & Financing, Inc.
    Inventor: Darryl Aubrey Godfrey
  • Patent number: 5760117
    Abstract: The gels of the the invention may be made non-adhearing, non-sticking, non-tacky by incorporating an advantage amount of fatty acids, metal stearates, and waxes.
    Type: Grant
    Filed: December 29, 1995
    Date of Patent: June 2, 1998
    Assignee: Applied Elastomerics, Inc.
    Inventor: John Y. Chen
  • Patent number: 5750607
    Abstract: Hot melt adhesive compositions, comprising(a) a radial multiarmed block copolymer (AB).sub.n X, wherein A is a block predominantly derived from a monovinylaromatic compound, B is a block predominantly derived from butadiene and which optionally has been partially or completely hydrogenated,X is the residue of a multifunctional coupling agent,n is in the range of from 3 to 6,(b) a linear block copolymer AB, the components (a)+(b) being present in an amount of 100 parts by weight,(c) a tackifying resin, which is compatible with the blocks B, in an amount of from 100 to 500 parts by weight,(d) a plasticizer in an amount of from 100 to 300 parts by weight,(e) an antioxidant-UV stabiliser in an amount from 0.
    Type: Grant
    Filed: March 6, 1997
    Date of Patent: May 12, 1998
    Assignee: Shell Oil Company
    Inventors: Eric-Jack Gerard, Noel Raymond Maurice De Keyzer, Birgitte Maria Ludovica Christine Van De Vliet
  • Patent number: 5750622
    Abstract: The present invention provides high service temperature, low viscosity rubber compounds and hot melt adhesive and/or sealant compositions by combining from 2 to 30% by weight of a polyphenylene ether resin having an I.V. of 0.07 to 0.25 deciliters per gram (dl/g) with from 70 to 98% by weight of an asymmetric radial elastomeric vinyl aromatic hydrocarbon/conjugated diene block copolymer having one of the following formulae: (I) (A--HD).sub.x --Y--(UD).sub.z or (II) (UD--A--HD).sub.x --Y or (III) (UD--A--HD).sub.x --Y--(UD).sub.z wherein A is a vinyl aromatic hydrocarbon block having a weight average molecular weight of from 4000 to 16,000, HD is a hydrogenated conjugated diene block having a weight average molecular weight of from 10,000 to 50,000, Y is a multifunctional coupling agent, UD is a partially hydrogenated conjugated diene block having a weight average molecular weight of from 1000 to 45,000, x is an integer from 2 to 30, z is an integer from 1 to 20, and x+z ranges from 3 to 31.
    Type: Grant
    Filed: March 20, 1997
    Date of Patent: May 12, 1998
    Assignee: Shell Oil Company
    Inventor: Glenn Roy Himes
  • Patent number: 5741840
    Abstract: A hot melt pressure sensitive adhesive comprising a) from about 15% to about 30% by weight of a linear styrene-ethylene/butylene-styrene copolymer having a styrene content from about 15% to about 35% by weight and a coupling efficiency of less than about 75%; b) from about 20% to about 50% by weight of a tackifying resin selected from the group consisting of those tackifying resins having a softening point of less than about 100.degree. C.; c) from about 30% to about 50% by weight of a plasticizing oil; and d) up to about 15% of a compatible polymer wherein the total polymer content does not exceed 30% by weight of the adhesive wherein the hot melt pressure sensitive adhesive fails cohesively during use.
    Type: Grant
    Filed: July 3, 1996
    Date of Patent: April 21, 1998
    Assignee: H.B. Fuller Licensing & Financing, Inc.
    Inventors: Jeffrey S. Lindquist, Lisa L. Ryan
  • Patent number: 5728759
    Abstract: New water base pressure sensitive adhesives with capability of use in production of high temperature quality masking tape are aqueous dispersions of the following mixture of components in the percentages by weight as specified:______________________________________ Component Percentage ______________________________________ Adhesive entity 45 to 65 Tackifier resin 20 to 40 Plasticizer 1 to 20 Stabilizer 0.1 to 10 Curing entity 0.1 to 10 Optional additives 0 to 20 ______________________________________The various components constitute the disperse phase of the aqueous dispersion and have a combined weight of between about 30 to 70% of the total weight, the curing entity is a combination of a plurality of curing agents that exhibit different curing speeds and the adhesive entity is a combination of a plurality of adhesive elastomers having different molecular weights.High temperature quality masking tapes made from the new PS adhesives avoid "freeze down" and "ghosting".
    Type: Grant
    Filed: August 15, 1995
    Date of Patent: March 17, 1998
    Inventor: Charles O. Pike
  • Patent number: 5721302
    Abstract: A high shear strength, solvent-free water-based adhesive composition for removably fixing flooring materials which includes a major amount of an aqueous latex dispersion of a polymer latex base material with an optional minor amount of polyether or polyester-polyurethane synthetic resin, an amount of rosin acid ester hardener, an amount of a thickener together with an amount of inert filler and an amount of a plasticizer/extender in sufficient water to adjust the percent solids to the desired amount.
    Type: Grant
    Filed: September 17, 1996
    Date of Patent: February 24, 1998
    Inventors: Benny R. Wood, Howard Burchett, Jr.
  • Patent number: 5705551
    Abstract: The cuttability of elastomeric pressure-sensitive adhesives, particularly of hot-melt tackified mutually immiscible elastomers, is improved by the addition of surfactants containing polyethylene-oxide and polypropylene-oxide blocks.
    Type: Grant
    Filed: June 20, 1994
    Date of Patent: January 6, 1998
    Assignee: Avery Dennison Corporation
    Inventors: Yukihiko Sasaki, Jesse C. Ercillo
  • Patent number: 5688356
    Abstract: The present invention is directed to a water-based adhesive composition comprising an admixture of a first aliphatic water-based urethane resin that is the reaction product of polycaprolactonediol or polycaprolactonetriol, 4,4-methylene bis(cyclohexylisocyanate), and dimethylolpropionic acid extended with a diamine, and a second aliphatic water-based urethane resin that is the reaction product of 2,6-hexanediol, 4,4-methylene bis(cyclohexylisocyanate), and dimethylolpropionic acid extended with a diamine. The first aliphatic water-based urethane resin comprises from about 99 to about 20 percent by weight of the composition, and the second aliphatic water-based urethane resin comprises from about 1 to about 80 percent by weight of the composition. The invention is also directed to methods of adhering a substrate and a workpiece using the adhesive composition of the invention.
    Type: Grant
    Filed: November 6, 1996
    Date of Patent: November 18, 1997
    Assignee: Olin Corporation
    Inventor: Efraim Sagiv
  • Patent number: 5686515
    Abstract: A process for manufacture of articles comprised of polyethylene terephthalate wherein the PET is colored with a composition comprised of a wax dispersant, ethylene copolymer, and a colorant. In a preferred embodiment, the wax dispersant is a maleated polyethylene wax. In an alternative embodiment, the wax dispersant is a low molecular weight polyethylene wax and the composition further includes linear low density polyethylene. A preferred ethylene copolymer is ethylene-(meth)acrylic acid.
    Type: Grant
    Filed: November 13, 1995
    Date of Patent: November 11, 1997
    Assignee: The M.A. Hanna Company
    Inventors: Tracy L. Phillips, Ronald M. Harris, Alan R. Burgess, Judy A. Johnston
  • Patent number: 5686179
    Abstract: An improved adhesive roofing tape is based on a combination of brominated butyl rubber and EPDM. A non-diene block terpolymer is interspersed in the cross-liked polymer network. A plasticizer, a phenolic tackifier, a high melting point non-phenolic tackifier and a low melting point non-phenolic tackifier are included to provide resiliency and permanent tack at low temperatures. A method of making the adhesive roofing tape is also provided.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: November 11, 1997
    Inventors: Daniel John Cotsakis, Ronald Lynn Senderling, Nicholas John Shears
  • Patent number: 5670566
    Abstract: A carton, case or tray formed utilizing a hot melt adhesive composition said adhesive consisting essentially of a) 10 to 60% by weight of at least one ethylene n-butyl acrylate copolymer containing 25 to 45% by weight n-butyl acrylate and having a melt index of at least about 850; b) 20 to 60% of a rosin ester tackifying resin; c) 10 to 50% by weight of a microcrystalline or paraffin wax having a melting point of 150.degree. to 200.degree. F.; d) 1 to 20% by weight of a polymeric additive selected from the group consisting of ethylene vinyl acetate containing 10 to 40% by weight vinyl acetate, ethylene methyl acrylate polymers containing 10 to 28% methyl acrylate, ethylene acrylic acid copolymers having an acid number of 25 to 150, polyethylene, polypropylene, poly-(butene-1-co-ethylene), and lower melt index ethylene n-butyl acrylate copolymers; and e) 0 to 1.5% stabilizer, said adhesive characterized by a viscosity of less than 3000 cps at 135.degree. C., fiber tearing bonds from within the range of -35.
    Type: Grant
    Filed: January 6, 1995
    Date of Patent: September 23, 1997
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Ingrid Liedermooy, Daniel C. Stauffer, Paul P. Puletti
  • Patent number: 5670577
    Abstract: This invention relates to hot melt adhesive compositions useful for waterproofing stitched seams and a method of using the same. This invention particularly relates to certain hot melt adhesives which can be directly applied to a stitched seam such that the resulting seam is resistant to water penetration.
    Type: Grant
    Filed: November 27, 1996
    Date of Patent: September 23, 1997
    Assignee: H. B. Fuller Licensing & Financing, Inc.
    Inventor: Glen E. Dawson, Jr.
  • Patent number: 5665811
    Abstract: An alkenylsuccinic acid emulsion sizing agent having a solid concentration of at least 30% by weight, which comprises an active component comprising:(1) from 70 to 95 parts by weight of an alkenylsuccinic acid obtained by reacting a branched internal olefin having 12 to 18 carbon atoms with maleic anhydride; and(2) from 5 to 30 parts by weight of an oxidized wax; andwherein the active component is dispersed in water using a high-molecular weight dispersion stabilizer or a mixed system of a high-molecular weight dispersion stabilizer with an emulsifier.
    Type: Grant
    Filed: October 13, 1995
    Date of Patent: September 9, 1997
    Assignee: Mitsubishi Oil Co., Ltd.
    Inventors: Yasusuke Takeda, Sadao Kotsuka, Takeshi Kouchi
  • Patent number: 5663228
    Abstract: A pressure sensitive adhesive of a mutually immiscible first elastomer (styrene-butadiene block copolymer) exhibiting a first glass transition temperature and a second elastomer (e.g., a styrene-isoprene-styrene block copolymer) exhibiting a second glass transition temperature greater than the first is tackified by a tackifying system comprising tackifier preferentialIy miscible with the second elastomer to provide a dynamic mechanical spectrum plot of tangent delta versus temperature in .degree.C. showing two separate and distinct glass transition temperature peaks. The mixture exhibits excellent processability and ambient and low temperature adhesive properties.
    Type: Grant
    Filed: February 28, 1994
    Date of Patent: September 2, 1997
    Assignee: Avery Dennison Corporation
    Inventors: Yukihiko Sasaki, Jesse Ercillo
  • Patent number: 5656367
    Abstract: A biodegradable binder for nonwoven stock is prepared as an emulsion of 5-200% solids of poly(hydroxybutyrate/hydroxyvalerate) copolymer in water in which the copolymer comprises 70-100 mole percent of 3-hydroxybutyrate and 0-30 percent of 3-hydroxyvalerate.
    Type: Grant
    Filed: April 29, 1994
    Date of Patent: August 12, 1997
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Carmine P. Iovine, John H. Walton
  • Patent number: 5656679
    Abstract: This invention relates to improved water-soluble acrylic latex compositions. In particular, this invention relates to acrylic latex compositions produced by reacting monomers with water-soluble support resins derived from reacting a modified rosin with an alkanolamine containing at least one secondary amine and at least one hydroxyl group. These acrylic latex compositions can be utilized to produce water-based flexographic and gravure ink formulations.
    Type: Grant
    Filed: May 17, 1996
    Date of Patent: August 12, 1997
    Assignee: Westvaco Corporation
    Inventor: G. Frederick Hutter
  • Patent number: 5652288
    Abstract: A rapid hardening, solvent-free water-based adhesive composition includes an amount of an aqueous latex dispersion of polyester-polyurethane synthetic resin, an amount of rosin acid ester hardener, an amount of a thickener together with an amount of inert filler and an amount of a plasticizer/extender in sufficient water to adjust the percent solids to the desired amount. Optionally, the adhesive composition also includes an amount of polyisocyanate cross-linker to provide additional environmental stability.
    Type: Grant
    Filed: April 19, 1996
    Date of Patent: July 29, 1997
    Inventors: Benny R. Wood, Howard Burchett, Jr.
  • Patent number: 5639812
    Abstract: An alkenylsuccinic emulsion sizing agent comprising an active component comprising a mixture of(1) from 50 to 100 parts by weight of an alkenylsuccinic acid obtained by reacting a linear internal olefin having 10 to 14 carbon atoms with maleic anhydride; and(2) from 0 to 50 parts by weight of one or more components selected from the group consisting of rosin, rosin derivatives, tall oil, fatty acids, petroleum resins and paraffin wax; andwherein the active component is dispersed in water using an emulsifier and/or a high-molecular weight dispersion stabilizer.
    Type: Grant
    Filed: October 13, 1995
    Date of Patent: June 17, 1997
    Assignee: Mitsubishi Oil Co., Ltd.
    Inventors: Yasusuke Takeda, Sadao Kotsuka, Takeshi Kouchi
  • Patent number: 5624986
    Abstract: The novel adhesives of this invention contain a blend of components that result in the adhesive having a physical property that changes at a controlled rate as a function of time after application until it reaches a final equilibrium value.The adhesives can contain a thermoplastic polymer base, a tackifying resin, and an aromatic plasticizer optionally in combination with other ingredients. The plasticizer tackifier combination is chosen such that the tackifier/plasticizer interaction causes the initial value of the physical property after application to change, at a controlled rate, to a final equilibrium level.
    Type: Grant
    Filed: October 17, 1995
    Date of Patent: April 29, 1997
    Assignee: H. B. Fuller Licensing & Financing Inc.
    Inventors: William L. Bunnelle, Christopher M. Ryan
  • Patent number: 5618883
    Abstract: A hot melt pressure sensitive adhesive composition comprising a tackified ethylene-propylene rubber modified with a copolymer of a styrene ethylene-propylene block copolymer and/or a styrene ethylene -butylene block is provided. The pressure sensitive adhesive exhibits high cohesive strength and adhesion to polar and apolar surfaces.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: April 8, 1997
    Assignee: Avery Dennison Corporation
    Inventors: Sebastian S. Plamthottam, Ramon Roman, John Landers, Roger H. Mann, Karl Josephy, Ronald Ugolick
  • Patent number: 5614577
    Abstract: There are provided a pressure-sensitive adhesive and other compositions which free radical cured mixtures of at least one unsaturated elastomeric polymer and at least one organic additive which is substantially nonresponsive to action of free radicals and present in an amount sufficient to modify the properties of the cured elastomeric polymer.
    Type: Grant
    Filed: April 11, 1994
    Date of Patent: March 25, 1997
    Assignee: Avery Dennison Corporation
    Inventors: Yukihiko Sasaki, Kevin Lossner
  • Patent number: 5596028
    Abstract: An anaerobic adhesive which undergoes setting only by attaching it to an article without applying any special energy, and an anaerobically setting adhesive sheet prepared by coating or impregnating a sheet with the above anaerobic adhesive and well-balanced between storage stability and setting properties, the anaerobic adhesive comprising;(A) a rubber-based resin having adhesion properties,(B) a compound which has both the capability of absorbing oxygen and the capability of forming peroxide, and which shows an oxygen absorption amount of 0.1 to 3.0% (weight of absorbed oxygen/weight) and an active oxygen amount of 0.01 to 1.0% (weight of active oxygen/weight),(C) an ethylenically unsaturated monomer or oligomer, and(D) an organic peroxide.
    Type: Grant
    Filed: April 7, 1995
    Date of Patent: January 21, 1997
    Assignee: Toyo Ink Manufacturing Co., Ltd.
    Inventors: Masato Yanagi, Satoru Kagao, Makoto Dohi, Sanae Nakaizumi
  • Patent number: 5591792
    Abstract: The invention relates to an adhesive resin composition comprising an ethylene polymer having a melting point of 70 to 132.degree. C., a density of 0.88 to 0.94% g/cm.sup.3 and a melt flow rate (MFR) of 0.05 to 50 g/10 min. and/or a modified product thereof with an unsaturated carboxylic acid or its derivative (component A); a tackifier (component B); and a block copolymer containing at least one polymer block mainly composed of a vinyl aromatic hydrocarbon and at least one polymer block mainly composed of a conjugated diene or a hydrogenated product thereof (component C). This composition is useful as an adhesives showing excellent adhesion over a wide temperature range as well as processability by film molding, sheet molding, blow molding, etc. It is available for laminates comprising various kinds of resins such as polyolefins, styrenic resins, polyesters, acrylic resins and polyamides.
    Type: Grant
    Filed: January 10, 1995
    Date of Patent: January 7, 1997
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Masafumi Hattori, Chikako Ikeda, Satoru Sugimoto, Tatsuoki Saito, Hitoshi Yamada, Etsushi Akashige
  • Patent number: 5574084
    Abstract: Modifiers for ethylene copolymers for use in hot melt adhesives are provided, particularly modifiers for ethylene vinyl acetate-based adhesives which improve adhesive properties are provided. Blends comprising ethylene copolymers, modifiers and tackifiers and applications thereof are also provided for.
    Type: Grant
    Filed: November 14, 1994
    Date of Patent: November 12, 1996
    Assignee: Exxon Chemical Patents, Inc.
    Inventor: Andrew J. Peacock
  • Patent number: 5571860
    Abstract: An emulsion adhesion composition comprising a polyvinyl alcohol stabilized polymer emulsion; the polymer comprising 40 to 94.5% by weight of a vinyl ester of an C.sub.1 -C.sub.13 alkanoic acid, 5 to 40% by weight ethylene and 0.5 to 10% by weight N-vinyl formamide or N-vinyl pyrrolidone, the adhesive being characterized by superior adhesion and heat resistance.
    Type: Grant
    Filed: June 2, 1995
    Date of Patent: November 5, 1996
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Pravin K. Kukkala, Malcolm F. Hallam, M. Erin Jones, Richard K. Vetterl
  • Patent number: 5559165
    Abstract: A pressure sensitive hot melt adhesive comprising a block copolymer and 60 to 95 parts of a liquid diluent, the adhesive being characterized by a midblock Tg less than -10.degree. C., a G' less than 15.times.10.sup.4 dynes/cm.sup.2 at 10 rad/s, 25.degree. C., a G" of 1 to 6.times.10.sup.4 dynes/cm.sup.2 and a tensile strength greater than 10 psi exhibit superior properties, without the need for any curing operation after cooling.
    Type: Grant
    Filed: August 8, 1995
    Date of Patent: September 24, 1996
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventor: Charles W. Paul
  • Patent number: 5550175
    Abstract: A solvent-free hot melt process, for preparing a non-thermosettable, pressure-sensitive adhesive from a tackified non-thermoplastic hydrocarbon elastomer. The process employs a continuous compounding device that has a sequence of alternating conveying and processing zones. The processing zones masticate and mix materials in them. Non-thermoplastic elastomers having high molecular weight may be readily compounded into adhesives in the process.
    Type: Grant
    Filed: May 5, 1995
    Date of Patent: August 27, 1996
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Timothy D. Bredahl, Harold Leverty, Robert L. Smith, Richard E. Bennett, David J. Yarusso, Daniel C. Munson, Anthony R. Plepys