Oh Group Other Than As Part Of A Cooh Group, E.g., Salicylic Acid, Etc. Patents (Class 524/291)
  • Patent number: 5216061
    Abstract: Hindered phenol stabilized, stereoregular polymers of branched, higher alpha-olefins can be modified with unsaturated silanes, carboxylic acids, and/or carboxylic acid anhydrides in the presence of a free radical generator in the polymer melt. These polymers can also contain additional additives, such as glass fibers. An aliphatic thio compound is added after the grafting procedure for maximum beneficial effect.
    Type: Grant
    Filed: January 11, 1991
    Date of Patent: June 1, 1993
    Assignee: Phillips Petroleum Company
    Inventor: Edwin Boudreaux, Jr.
  • Patent number: 5216054
    Abstract: A polymer composition comprising resin components comprising (a) 5-95 weight % of a polyamide resin, and (b) 5-95 weight % of polyolefin + unsaturated carboxylic acid-modified polyolefin, and (c) additives comprising the following compounds in amounts per 100 parts by weight of the total composition: (1) 0.1-2 parts by weight of a substituted hydrazine: (2) 0.05-2 parts by weight of a hindered phenol compound; (3) 0.05-0.5 parts by weight of a phosphite or phosphonite; and (4) 0.15-1 parts by weight of a thiodipropionate.
    Type: Grant
    Filed: February 27, 1992
    Date of Patent: June 1, 1993
    Assignee: Tonen Sekiyukagaku Kabushiki Kaisha
    Inventors: Kunio Iwanami, Kissho Kitano, Yukihiko Yagi, Takashi Mikami
  • Patent number: 5214084
    Abstract: A polypropylene resin containing an .alpha.-olefinic copolymer rubber and an inorganic filler is stabilized by incorporating therein the following 6 components:(A) a hindered phenolic compound having a molecular weight of not less than 500,(B) a high-molecular hindered piperidine compound such as poly[{6-(1,1,3,3-tetramethylbutyl)amino-1,3,5-triazine-2,4-diyl}{(2,2,6,6- tetramethyl-4-piperidyl)-imino}hexamethylene{(2,2,6,6-tetramethyl-4-piperid yl)imino}],(C) a low-molecular hindered piperidine compound such as 2-methyl-2-(2,2,6,6-tetramethyl-4-piperidyl)amino-N-(2,2,6,6-tetramethyl-4 -piperidyl)propionamide,(D) a benzoate compound such as 2,4-di-t-butylphenyl 3,5-di-t-butyl-4-hydroxybenzoate,(E) a phosphorous compound such as bis(2,4-di-t-butylphenyl) pentaerythritol diphosphite, and(F) an amide compound such as ethylene-bisstearylamide. This composition may also contain a sulfur compound such as dialkyl thiodipropionate and pentaerythritol tetrakis(3-alkylthiopropionate).
    Type: Grant
    Filed: August 24, 1992
    Date of Patent: May 25, 1993
    Assignee: Sumitomo Chemical Company, Ltd.
    Inventors: Tamaki Ishii, Shinichi Yachigo
  • Patent number: 5214049
    Abstract: The present invention provides a resin composition which is excellent in balance of mechanical properties and processability, solvent resistance and chemical resistance. This composition comprises:(a) a polyphenylene ether resin,(b) a thermoplastic polyester resin, and(c) a compound represented by the formula:(HO)mR.sup.1 (COOR.sup.2)nwherein R.sup.1 represents a straight or branched chain saturated aliphatic hydrocarbon group of 2-20 carbon atoms, R.sup.2 represents a hydrogen atom or an alkyl or aryl group of 1-20 carbon atoms and R.sup.1 and R.sup.2 may be identical or different and m and n each represents an integer of 1 or more or a derivative thereof.This composition may further contain a rubber-like polymer.
    Type: Grant
    Filed: December 12, 1991
    Date of Patent: May 25, 1993
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Takashi Maruyama, Yukio Mizuno
  • Patent number: 5214087
    Abstract: Polyvinyl halide-EVOH polymer compositions exhibiting a reduced tendency to stick to metal surfaces, and in particular, to chrome surfaces are described which comprise(A) at least one vinyl halide polymer;(B) from 1 to about 40% based on the weight of the vinyl halide polymer, of at least one ethylene-vinyl alcohol copolymer; and(C) from about 0.01 to about 5 phr of at least one phenolic antioxidant of the formula ##STR1## wherein R.sub.1 is hydrogen, or a hydroxyl or an alkyl group; R.sub.2 is an alkyl, alkoxy or a carboxylic ester group; and R.sub.3 is a hydroxy or an alkyl group.An improved process for melt blending mixtures comprising vinyl halide polymers and ethylene-vinyl alcohol copolymers on metal-surfaced compounding equipment is described which comprises adding to the mixture prior to melt blending, from about 0.01 to about 5 phr of the phenolic antioxidant described above.
    Type: Grant
    Filed: March 26, 1990
    Date of Patent: May 25, 1993
    Assignee: The B. F. Goodrich Company
    Inventors: Thomas C. Braden, Sally A. Kline
  • Patent number: 5212222
    Abstract: Melt-stable polyacetal molding compositions include a polyacetal base resin, and a carbon black-impregnated ethylenic carrier polymer in amounts to yield between about 0.1 to 30 parts by weight of carbon black. The ethylenic carrier polymer is preferably present in an amount between 0.3 to 8 times by weight of the carbon black impregnated therewithin. The compositions of this invention further contain a co-stabilization package which includes a first stabilizer selected from nitrogen-containing compounds, fatty acid ester compounds, and metal-containing compounds which contain a hydroxide, an inorganic acid salt or a carboxylic acid salt of an alkali metal or an alkaline earth metal, and a second stabilizer which is a hindered phenolic compound. Preferably, the first and second stabilizers are each used in amounts between 0.01 to 5 parts by weight, based on 100 parts by weight of the polyacetal base resin.
    Type: Grant
    Filed: January 29, 1992
    Date of Patent: May 18, 1993
    Assignee: Polyplastics Co., Ltd.
    Inventors: Masamichi Mitsuuchi, Tsuyoshi Minamisawa, Hiroshi Kitamura, Hideo Kakizaki
  • Patent number: 5208279
    Abstract: A weather-resistant polyacetal resin composition which comprises(A) 100 part by weight of a polyacetal resin,(B) 0.01 to 5 parts by weight of a weathering (light) stabilizer and(C) 0.5 to 60 parts by weight of a graft copolymer comprising (a) an olefin (co)polymer and (b) one or more vinyl (co)polymers which are chemically bonded to each other to form a branched or crosslinked structure.The surface of a molded article made from the composition is excellent in weathering resistance, so that it undergoes less crack and reduced discoloration.
    Type: Grant
    Filed: June 25, 1991
    Date of Patent: May 4, 1993
    Assignee: Polyplastics Co., Ltd.
    Inventor: Toru Katsumata
  • Patent number: 5205916
    Abstract: An improved aqueous electrocoating composition having a binder of an epoxy-amine adduct and a blocked polyisocyanate crosslinking agent; wherein the improvement is the use of an antioxidant additive which is a combination of a phenolic antioxidant and a sulfur-containing antioxidant. The additive reduces overbake yellowing of the composition and the intercoat delamination of the composition and the topcoat upon exterior exposure.
    Type: Grant
    Filed: December 11, 1991
    Date of Patent: April 27, 1993
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Ding Y. Chung, Kenneth S. Kirshenbaum
  • Patent number: 5196461
    Abstract: Thermoplastic polymer blends comprising a major proportion by weight of certain monovinylidene aromatic copolymers and a minor proportion by weight of an acetal polymer have good processability and a beneficial combination of physical and chemical properties including thermal/dimensional stability, chemical resistance and creep resistance. Said polymer blends are suitable for use in the preparation of a variety of molded utilitarian articles having good appearance and paintability.
    Type: Grant
    Filed: September 16, 1991
    Date of Patent: March 23, 1993
    Assignee: The Dow Chemical Company
    Inventors: Martin J. Guest, P. F. M. v/d Berghen, Ludo M. Aerts, Antonios Gkogkidis, Abraham F. de Bert
  • Patent number: 5191010
    Abstract: An emulsion having a dye developing property, comprising aqueous polymer emulsion particles and contained therein, an organic dye developer.
    Type: Grant
    Filed: October 23, 1990
    Date of Patent: March 2, 1993
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Katsumi Inagaki, Kenzo Miyamoto, Masayoshi Sekiya
  • Patent number: 5185841
    Abstract: The optical fibre element comprises at least one optical fibre housing constituted by a polyolefin material having at least one additive which protects it against degradation due to oxidation, heat or the proximity of metals, and (b) at least one H.sub.2 -absorbing buffer. The additive is selected from the group comprising anti-oxidants, stabilizers and metal deactivators which cause a reduction in the hydrogen absorption capacity of less than 30% in the, or each, H.sub.2 -absorbing buffer when the, or each, buffer has been in contact with said polyolefin containing the, or each, additive for 30 days at 100.degree. C. in an air atmosphere saturated with water vapor at 150 mbar.
    Type: Grant
    Filed: November 8, 1991
    Date of Patent: February 9, 1993
    Assignee: Pirelli Cavi S.p.A.
    Inventors: Claudio Bosisio, Antonio Campana
  • Patent number: 5185391
    Abstract: The invention is a composition containing a polymer formed by side ring opening of an arylcyclobutene compound and an effective amount of an antioxidant.
    Type: Grant
    Filed: November 27, 1991
    Date of Patent: February 9, 1993
    Assignee: The Dow Chemical Company
    Inventor: Theodore M. Stokich, Jr.
  • Patent number: 5176872
    Abstract: Improved resin compositions for use in multiple cavity stretch blow molding processes comprising: (a) a propyleneethylene copolymer resin including from about 5% to about 15% of a second stage polymer characterized by a cycle time of T.sub.1, when used to produce containers in multiple cavity stretch blow molding processes; (b) from about 0.1% to about 1.0% of a nucleating agent prepared by irradiating in air a mixture of a propylene homo or copolymer and about 500 to about 3000 ppm of antioxidant with a sufficient amount of ionizing radiation to cause said nucleating agent to have a xylene insoluble content of at least 30%. The improved resin composition is characterized by a cycle time of T.sub.2 when used to produce containers in multiple cavity stretch blow molding processes such that the ratio of T.sub.2 /T.sub.1 is less than 0.95.
    Type: Grant
    Filed: February 19, 1992
    Date of Patent: January 5, 1993
    Assignee: Rexene Products Company
    Inventors: Bennie M. Lucas, V. Krishnamurthy, John R. Bonser
  • Patent number: 5175200
    Abstract: The present invention provides: a novel poly(arylene sulfide) (PAS) composition having an increased comparative tracking index (CTI) rating; a novel method wherein the inventive composition is formed and molded to produce a useful article; a novel article produced by the inventive molding method; a novel method wherein the inventive composition is formed and used to encapsulate an article; and a novel encapsulated article produced by the inventive encapsulation method. The inventive PAS composition comprises: poly(arylene sulfide) resin; talc; and an amount of hindered phenol sufficient to increase the composition's CTI rating.
    Type: Grant
    Filed: November 6, 1991
    Date of Patent: December 29, 1992
    Assignee: Phillips Petroleum Company
    Inventor: Nathaniel Harry, Sr.
  • Patent number: 5175349
    Abstract: The present invention relates to the use of nucleus-substituted 4-hydroxyphenyl propionic acid compounds for stabilizing organic polyisocyanates.
    Type: Grant
    Filed: March 1, 1991
    Date of Patent: December 29, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Pramod Gupta, Christian Konig, Hans-Jurgen Rabe, Hans-Wilhelm Engels, Wilfried Nolte, Chiraranjan Podder
  • Patent number: 5173530
    Abstract: Stable dispersions of polyols having a viscosity lower than 10,000 mPa.times.sec and containing dispersed particles of polyvinylchloride, having a size within the range of from 1 to 10 micrometers and impregnated by the said polyols.
    Type: Grant
    Filed: May 30, 1991
    Date of Patent: December 22, 1992
    Assignee: Montedipe S.p.A.
    Inventors: Piero Andreola, Sauro Gaiba, Eugenio Bianchin, Carlo Mulas
  • Patent number: 5164436
    Abstract: Waxy esters of aromatic alcohols with long-chain carboxylic acids give lubricants and release agents for highly transparent thermoplastics which reduce the transparency of these plastics to a far lesser degree than the previously customary montan wax esters of aliphatic alcohols.
    Type: Grant
    Filed: July 15, 1991
    Date of Patent: November 17, 1992
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Karl Maier, Gerd Hohner, Jan-Peter Piesold
  • Patent number: 5164479
    Abstract: Disclosed are a material for extrusion molding comprising a styrene-based polymer having a high degree of syndiotactic configuration, a melt viscosity of 10.sup.3 to less than 10.sup.6 poise measured at 300.degree. C. and a shearing rate of 10/sec, and a crystallinity of 15% or more, a process for preparation of the said material and a process for preparation of a molding product therefrom.The molding product prepared according to the present invention has excellent properties such as heat resistance and chemical resistance.
    Type: Grant
    Filed: January 16, 1990
    Date of Patent: November 17, 1992
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Keisuke Funaki, Komei Yamasaki
  • Patent number: 5164435
    Abstract: A stabilized thermoplastic resin composition is provided which comprises the following components (i), (ii) and (iii):(i) 100 parts by weight, based on the total amount of the following (A), (B) and (C), of a mixture comprising (A) about 10-100% by weight of a polyphenylene ether, (B) 0-about 90% by weight of an alkenyl aromatic resin, and (C) 0-about 90% by weight of a crystalline thermoplastic resin, total amount of (A) and (B) being at least about 15% by weight of the total amount of (A), (B) and (C),(ii) 1-50 parts by weight of an alkenyl aromatic elastomer (non-hydrogenated), and(iii) a stabilizer comprising (D) 0.01-5 parts by weight of a sulfur compound and (E) 0.01-5 parts by weight of at least one phenol compound.
    Type: Grant
    Filed: September 19, 1991
    Date of Patent: November 17, 1992
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Hiroomi Abe, Kenji Nagaoka, Yasuro Suzuki, Takashi Sanada
  • Patent number: 5162403
    Abstract: Premoulding materials having long-term controllable B-stage characteristic, comprising phenol resins, optionally with reagents, additives and adjuvants, are characterized in that they contain hydraulic binder and/or its components as well as an agent that reduces the alkalinity and optionally the content of free metal ions. For its preparation, 1 part by wt. phenol resin is mixed with less than 4 parts by wt. of a hydraulic binder and/or its components as well as less than 0.2 equivalent parts by weight of the agent. The phenol resin premoulding materials according to the invention thicken quickly to a desired B-stage, are capable of maintaining the attained plateau, and thus allow the manufacture of heat-curable composites of desired rheology and reactivity.
    Type: Grant
    Filed: August 2, 1990
    Date of Patent: November 10, 1992
    Assignee: Reichhold Chemie Ges.m.b.H.
    Inventor: I. Thomas Fucik
  • Patent number: 5162412
    Abstract: This invention relates to thermoplastic molding compositions, particularly thermoplastic polyesters, having incorporated therein a fluorinated polyolefin to improve wear resistance. More particularly, disclosed are polyester compositions having improved wear resistant good properties comprising a polyester resin, most preferably a poly(butylene terephalate) resin; a fluorinated polyolefin compound and a hindered phenolic compound and an ester compound, the last two components serving as a migrator package that serves to push a disproportionate amount of the fluorinated polyolefin within the subsurface of the resulting composition to thereby augment the wear resistant effect of the fluorinated polyolefin.
    Type: Grant
    Filed: July 26, 1991
    Date of Patent: November 10, 1992
    Assignee: General Electric Company
    Inventor: Ping Y. Liu
  • Patent number: 5162405
    Abstract: The present invention comprises novel single-functional and mixtures of multi-functional oligomeric performance additive compounds having one or more components of Structure A R1 ? ? ##STR1## (The definitions of R, Z1, Z2, Z3, A1, A2, A3 and y are given in the Summary Section), their uses and polymeric compounds and compositions containing them which have enhanced oxidative stabilities, enhanced ultraviolet (UV) and light stabilites and/or enhanced flame retardance. An example is the bis sulfonic acid bispotassium salt reaction product from an oligomeric caprolactone diol (TONE.RTM. 260), 2-sulfobenzoic acid anhydride and potassium carbonate, and use of this product, at levels up to about 3.0%, in a general purpose bisphenol A polycarbonate resin, to enhance the fire resistance or flame retardance of the polycarbonate resin.
    Type: Grant
    Filed: March 22, 1991
    Date of Patent: November 10, 1992
    Assignee: ELF Atochem North America, Inc.
    Inventors: Ronald E. MacLeay, Jose Sanchez, Daryl L. Stein
  • Patent number: 5158992
    Abstract: Disclosed are olefin polymers in nonextruded, aspolymerized particle form having a regular, essentially symmetrical geometrical shape, which are stabilized by depositing on their surface a mixture which is either melted, or in which at least stabilizer (A) is in the liquid state, and which comprises the following stabilizers (percent by weight on the polymer):A) from 0.02% to 0.015% of one or more organic phosphites or phosphonites or mixtures thereof, which are liquid at room temperature or have melting point below 100.degree. C.;B) from 0.025% to 0.2% of one or more phenolic antioxidants with melting point from 45.degree. to 130.degree. C.; and, optionally, one or more of the following additional components:C) from 0.05% to 0.5% of one or more thioethers, or organic polysulfides or mixtures thereof;D) from 0.1% to 1.0% of one or more light stabilizers which are liquid at room temperature or have a melting point below 150.degree. C.
    Type: Grant
    Filed: July 30, 1990
    Date of Patent: October 27, 1992
    Assignee: HIMONT Incorporated
    Inventors: Giancarlo Caselli, Giuseppe Gorini
  • Patent number: 5158997
    Abstract: Disclosed is an olefin polymer-based thermoplastic elastomer comprising a propylene polymer material, an amorphous olefin copolymer rubber, and optionally a semicrystalline, essentially linear ethylene-C.sub.3-4 alpha-olefin copolymer, having incorporated therein zinc salts of certain mercapto compounds and sterically hindered di-tertiary butyl phenol compounds. The compositions exhibit good retention of properties at elevated temperatures.
    Type: Grant
    Filed: August 31, 1991
    Date of Patent: October 27, 1992
    Assignee: Himont Incorporated
    Inventor: Dominic A. Berta
  • Patent number: 5155153
    Abstract: A stabilizing composition for thermoplastic organic polymers containing measured quantities of: (a) a sterically hindered phenol; (b) a triarylphosphite; and (c) a dialkylthiodipropionate. Stabilized polymer compositions are also described containing a thermoplastic organic polymer, in particular a polyolefin, and a stabilizing quantity of said stabilizing composition, which possess excellent characteristics in relation to their melt flow index and color when subjected to repeated extrusion and in relation to their long-term thermal stability.
    Type: Grant
    Filed: September 25, 1991
    Date of Patent: October 13, 1992
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Carlo Neri, Roberto Podesta, Giovanni Sandre
  • Patent number: 5151460
    Abstract: Thermoplastic compositions comprising polyphenylene ethers and polyesters, impact-modified by glycidyl (meth)acrylate grafted EPDM and compatibilized by an aromatic polycarbonate exhibit high impact strength alone and when combined with other impact modifiers. Their shear sensitive viscosity properties makes them uniquely suitable for extrusion and blow molding applications.
    Type: Grant
    Filed: November 21, 1989
    Date of Patent: September 29, 1992
    Assignee: General Electric Co.
    Inventors: John B. Yates, III, Charles F. Pratt, Angelika H. McHale
  • Patent number: 5147909
    Abstract: Substituted 1,3,2-benzoxazaphospholidines of formula I ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are independently hydrogen, alkyl, cycloalkyl, phenylalkyl or aryl, n is 1 to 4, and T is an n-valent aliphatic or aromatic hydrocarbon radical are effective in stabilizing organic materials against the deleterious effects of oxygen, heat and actinic radiation.
    Type: Grant
    Filed: September 23, 1991
    Date of Patent: September 15, 1992
    Assignee: Ciba-Geigy Corporation
    Inventors: Paul A. Odorisio, Stephen D. Pastor, James L. Hyun
  • Patent number: 5147911
    Abstract: Compounds of formula I ##STR1## wherein n is 2-4, R.sub.1 is alkyl, cycloalkyl, phenylalkyl, phenyl or a radical of formula II ##STR2## R.sub.2, R.sub.3 and R.sub.4 are independently hydrogen, alkyl, cycloalkyl, phenylalkyl or aryl, or R.sub.3 and R.sub.4 together are alkyl, R.sub.5 and R.sub.6 are independently hydrogen, alkyl, cycloalkyl or phenylalkyl, R.sub.7 is hydrogen, alkyl or a group of the formula --(CH.sub.2).sub.k COOR.sub.8, where k is 0-2 and R.sub.8 is hydrogen or alkyl, and T is an n-valent hydrocarbon radical which may be interrupted by heteroatoms, are useful stabilizers for substrates subject to the deleterious effects of oxygen, heat and/or actinic radiation.
    Type: Grant
    Filed: September 23, 1991
    Date of Patent: September 15, 1992
    Assignee: Ciba-Geigy Corporation
    Inventors: Peter Hofmann, Paul A. Odorisio, Glen T. Cunkle, Don Sabrsula
  • Patent number: 5147910
    Abstract: Substituted 3H-1,3,2-oxazaphospholidines of formula I ##STR1## where R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are independently hydrogen, alkyl, cycloalkyl, phenylalkyl or aryl, n is 1 to 4 and T is an n-valent aliphatic or aromatic hydrocarbon radical are effective in stabilizing organic materials against the deleterious effects of oxygen, heat and/or actinic radiation.
    Type: Grant
    Filed: September 23, 1991
    Date of Patent: September 15, 1992
    Assignee: Ciba-Geigy Corporation
    Inventors: Paul A. Odorisio, James L. Hyun, Sai P. Shum, Raymond Seltzer
  • Patent number: 5143956
    Abstract: The invention relates to free-flowing polyamide molding compounds which are characterized by a content of new liquid-crystalline compounds corresponding to general formulae (I) and/or (II) and to the new liquid-crystalline compounds corresponding to general formulae (I) and/or (II).
    Type: Grant
    Filed: February 19, 1991
    Date of Patent: September 1, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Harald Pielartzik, Hans-Detlef Heinz, Rolf Dhein, Aziz E. Sayed
  • Patent number: 5132344
    Abstract: A stabilized polyethylene composition containing catalyst residues comprising at least one transition metal comprises (a) polyethylene, (b) 100 to 2000 ppm by weight based on the total weight of the composition of one or more antioxidants of the phenolic type and (c) 100 to less than 2000 ppm by weight, based on the total weight of the composition of zinc oxide but substantially no calcium stearate. The composition has improved color and improved resistance to coloration effects.
    Type: Grant
    Filed: April 30, 1991
    Date of Patent: July 21, 1992
    Assignee: BP Chemicals Limited
    Inventor: Jean-Baptiste Matteodo
  • Patent number: 5128405
    Abstract: Polyoxymethylene molding compositions include a polyoxymethylene base resin and contain, based upon the weight of the polyoxymethylene base resin, between 0.01 to 5% by weight of a hindered phenolic antioxidant, and between 0.01 to 5% by weight of an amine polymer having a molecular weight of at least 1000 and comprised essentially of structural units of the following formula (1): ##STR1## wherein R represent a hydrogen atom, an alkyl group, a phenyl group, an alkyl-substituted phenyl group, an NH.sub.2 group directly bonded to the carbon atom, or --X--NH.sub.2 -- where X represents an alkylene group, a carbonyl group, a carboxyalkylene group, an alkyleneoxycarbonylalkyl group, a phenylene group, an alkyl-substituted phenylene group, an amido group or an alkyleneamido group.
    Type: Grant
    Filed: December 20, 1990
    Date of Patent: July 7, 1992
    Assignee: Polyplastics Co., Ltd.
    Inventor: Noriyuki Sugiyama
  • Patent number: 5128398
    Abstract: A compound represented by the formula of: ##STR1## wherein R is hydrogen or methyl. This compound is useful as a stabilizer for butadiene polymers.
    Type: Grant
    Filed: February 12, 1990
    Date of Patent: July 7, 1992
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Manji Sasaki, Shinichi Yachigo, Kikumitsu Inoue, Shinya Tanaka, Takeshi Takata, Kanako Ida
  • Patent number: 5124388
    Abstract: Disclosed are films, containers and container liners comprising a copolyester having repeat units from terephthalic acid and 1,4-cyclohexanedimethanol, and a hindered phenolic antioxidant.
    Type: Grant
    Filed: May 7, 1990
    Date of Patent: June 23, 1992
    Assignee: Eastman Kodak Company
    Inventors: Wayne P. Pruett, Charles W. Ramsey, Sarah J. Webb, Joey C. Carico
  • Patent number: 5118734
    Abstract: A weather-resistantt polyacetal molding composition are comprised of a polyacetal base resin, and a weather-resistance effective amount of a stabilization package which includes (i) a weather stabilizer for the polyacetal base resin, (ii) an acrylic resin, and (iii) an oxyalkylene polymer comprised of repeating oxyalkylene units each having 2 to 8 adjacent carbon atoms.
    Type: Grant
    Filed: September 11, 1991
    Date of Patent: June 2, 1992
    Assignee: Polyplastics Co., Ltd.
    Inventor: Toru Katsumata
  • Patent number: 5118735
    Abstract: A composition comprising (A) (i) a crosslinked organosilicon polymer or crosslinkable organosilicon prepolymer comprising alternating (a) cyclic polysiloxane or tetrahedral siloxysilane residues and (b) polycyclic hydrocarbon residues derived from polycyclic polyenes having at least two non-aromatic, non-conjugated carbon-carbon double bonds in their rings linked through carbon to silicon bonds, wherein at least one of the cyclic polysiloxanes or tetrahedral siloxysilanes (a) or the polycyclic polyenes (b) used to form the polymer or prepolymer has more than two reactive sites; or (ii) a crosslinked or crosslinkable linear poly(organohydrosiloxane) polymer having at least 30% of its .tbd.
    Type: Grant
    Filed: October 5, 1990
    Date of Patent: June 2, 1992
    Assignee: Hercules Incorporated
    Inventor: Julia S. Burnier
  • Patent number: 5114995
    Abstract: Talc filled thermoplastic polyester compositions which have been modified by the addition of a butadiene-based impact modifier are stabilized against degradation by the addition thereto of a specific phosphorous compound.
    Type: Grant
    Filed: December 6, 1990
    Date of Patent: May 19, 1992
    Assignee: Hoechst Celanese Corp.
    Inventors: Michael D. Golder, David K. Walker
  • Patent number: 5106893
    Abstract: A fiber-reinforced polymer composition containing resin components including (a) 30-90 weight % of a polyamide resin, and (b) 10-70 weight % of polyolefin+unsaturated carboxylic acid-modified polyolefin, based on the resin components; and, per 100 parts by weight of the total components, (c) 5-50 parts by weight of glass fibers, and (d) additives including the following set of additives: 0.1-1 parts by weight of N,N'-hexamethylene-bis (3,5-di-tert-butyl-4-hydroxy-hydrocinnamide); 0.1-1 parts by weight of triethylene glycol-bis [3-(3-tert-butyl-5-methyl-4-hydroxyphenyl) propionate]; and 0.1-1 parts by weight of pentaerythrityl-tetrakis [3-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate]. An alternative set of additives are 0.1-2 parts by weight of N,N'-bis [3-(3,5-di-tert-butyl-4-hydroxyphenyl) propionyl] hydrazine; 0.05-0.5 parts by weight of pentaerythrityl-tetrakis [3-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate]; 0.05-0.5 parts by weight of distearyl-pentaerythritol diphosphite; and 0.
    Type: Grant
    Filed: February 7, 1991
    Date of Patent: April 21, 1992
    Assignees: Tonen Sekiyukagaku Kabushiki Kaisha, Nippondenso Co., Ltd.
    Inventors: Kunio Iwanami, Kissho Kitano, Kiyotada Narukawa, Masato Sakuma, Takashi Mikami, Masami Esaki, Koji Egashira, Hiroyuki Wakabayashi, Fumio Kato
  • Patent number: 5102939
    Abstract: Stabilizing, synergistically acting mixtures of phenolic antioxidants and sulphur-containing elastic-thermoplastic graft products having terminal thioalkyl groups.
    Type: Grant
    Filed: October 10, 1990
    Date of Patent: April 7, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Herbert Eichenauer, Alfred Pischtschan, Karl-Heinz Ott
  • Patent number: 5100930
    Abstract: Disclosed herein is a food container of a resin composition composed of a polyolefin and an inorganic filler, said resin composition containing (i) a phenolic antioxidant and (ii) a slip agent and/or antistatic agent, said phenolic antioxidant being at least one kind selected from .beta.-(4-hydroxy-3-t-butyl-5-alkylphenyl)propionic acid esters, hindered phenols having an isocyanuric acid ester, 1,3,5-tris(3,5-di-t-butyl-4-hydroxybenzyl)-2,4,6-trimethylbenzene, specific phenol compounds, and 6-hydroxychroman compounds. The food container has a low level of offensive odors and discoloration.
    Type: Grant
    Filed: June 28, 1990
    Date of Patent: March 31, 1992
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Yoshiharu Fukui, Kazuhisa Kuroda
  • Patent number: 5096947
    Abstract: A composition comprises a thermoplastic or polymeric resin; an organic peroxide; and an organic sulfide antioxidant represented by Formula I, II or III: ##STR1## wherein m, n, r, R.sup.1, R.sup.2, R.sup.3, R.sup.5, R.sup.6, R.sup.7 and R.sup.8 are as set forth in the Summary of the Invention.
    Type: Grant
    Filed: May 6, 1991
    Date of Patent: March 17, 1992
    Assignee: Atochem North America, Inc.
    Inventors: Joseph M. Bohen, Edward P. Hibbard, Vasanth R. Kamath, James L. Reilly
  • Patent number: 5096951
    Abstract: A polyoxymethylene molding composition which exhibits improved ambient and heat aged color stability includes a metal deactivator and calcium hydroxystearate. One preferred composition of the invention includes: (a) greater than about 95 weight percent of polyoxymethylene, (b) between about 0.01 to about 0.1 weight percent of 3 salicyloyl-amido-1,2,4 triazole or tris-2-tert.butyl- 4-thio-(2'methyl-4'hydroxy-5'tert.butyl) phenyl-5-methyl phenyl phosphite, (c) between about 0.015 to about 0.4 weight percent of 2,4,6-triamino-sym-triazine, (d) between about 0.25 to about 1.0 weight percent of tetrakis(methylene-(3,5-di-tert-butyl- 4-hydroxyhydrocinnamate)) methane, (e) between about 0.05 to about 0.2 weight percent of calcium 12-hydroxystearate, and (f) between about 0.1 to about 0.3 weight percent of N-N'-ethylenebisstearamide. Due to their enhanced color stability, the compositions of this invention find particular utility as molded automobile components.
    Type: Grant
    Filed: December 13, 1990
    Date of Patent: March 17, 1992
    Assignee: Hoechst Celanese Corporation
    Inventor: Andrew Auerbach
  • Patent number: 5086095
    Abstract: Weather-resistant polyacetal resin compositions and molded articles formed of the same include a polyacetal base resin, and a weather-resistant effective amount of a weather stabilizing package comprised of (i) a weather stabilizer that is at least one selected from the group consisting of benzotriazoles, benzophenones, aromatic benzoates, cyanoacrylates, oxalanilides and hindered amines (ii) a homopolymer or copolymer of acrylic or methacrylic acid, or ester derivatives thereof, and (iii) a fluororesin.
    Type: Grant
    Filed: October 15, 1990
    Date of Patent: February 4, 1992
    Assignee: Polyplastics Co., Ltd.
    Inventor: Toru Katsumata
  • Patent number: 5070124
    Abstract: The present invention is a composition comprising crosslinked polyolefin resins and an amount of organic sulfide antioxidants sufficient to stabilize the resin against thermal or oxidative degradation, wherein the organic sulfide antioxidant is represented by Formula I, II or III ##STR1## wherein m, n, R, R.sup.1, R.sup.2, R.sup.3, R.sup.5, R.sup.6, R.sup.7 and R.sup.8 are as set forth in the Summary of the Invention.
    Type: Grant
    Filed: October 31, 1989
    Date of Patent: December 3, 1991
    Assignee: Atochem North America, Inc.
    Inventors: Joseph M. Bohen, James L. Reilly
  • Patent number: 5063263
    Abstract: Incorporation into polyacetal molding compositions stabilized for processing with a non-meltable polymer stabilizer of 0.01-1.00 weight percent of at least one meltable co-stabilizer, said co-stabilizer being a thermal stabilizer for polyacetal, and 0.02-1.0 weight percent of at least one primary antioxidant results in significantly improved long term stability, as evidenced by greater retention of physical properties over time, of such compositions.
    Type: Grant
    Filed: June 11, 1990
    Date of Patent: November 5, 1991
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Richard A. Hayes, Leonard E. R. Kosinski, Mark E. Wagman
  • Patent number: 5057563
    Abstract: Substituted aminoxy propionamide derivatives corresponding to the formula ##STR1## said derivatives being useful as color improvers and stabilizers in various polymeric substrates.
    Type: Grant
    Filed: March 13, 1990
    Date of Patent: October 15, 1991
    Assignee: Ciba-Geigy Corporation
    Inventor: Ramanathan Ravichandran
  • Patent number: 5051460
    Abstract: A stabilized melt processable composition containing a halopolymer (e.g., an ethylene chlorotrifluoroethylene copolymer) and an effective stabilizing amount of an ester of a (4-hydroxy-5-alkylphenyl) alkanoic acid and at least one phosphite. Such compositions may be melt processed and extruded at high temperatures (e.g., up to 305.degree. C.) and retain their stability. These compositions are especially desirable in wire and cable coating applications.
    Type: Grant
    Filed: September 18, 1989
    Date of Patent: September 24, 1991
    Assignee: Ausimont, U.S.A., Inc.
    Inventors: Sheldon J. Kirsch, Chii-Shu Chen
  • Patent number: 5049604
    Abstract: A stabilized resin composition comprising a resin, a piperidine derivative represented by the formula (III) ##STR1## wherein R.sub.1 is a hydrogen atom or an alkyl group having 1 to 3 carbom atoms; R.sub.2 is a hydrogen atom or an alkyl group having from 1 to 2 carbon atoms; and R.sub.3 and R.sub.4 are each independently an alkyl group having 1 to 12 carbon atoms, a phenol-type antioxidant and a sulfur-containing antioxidant. The composition simultaneously meets heat resistance, oxidation resistance and light resistance requirements.
    Type: Grant
    Filed: October 19, 1990
    Date of Patent: September 17, 1991
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Takeo Fujii, Tamaki Ishii, Shinichi Yachigo, Tatsuo Kaneoya, Yukoh Takahashi, Yuzo Maegawa, Haruki Okamura, Eizo Okino
  • Patent number: 5047461
    Abstract: A butadiene polymer composition containing a phenolic compound represented by the formula: ##STR1## wherein R.sub.1 is an alkyl having 1 to 4 carbon atoms;R.sub.2 and R.sub.3 are each independently a group represented by --C(CH.sub.3).sub.2 --R' in which R' is an alkyl having 1 to 5 carbon atoms or phenyl, andR.sub.4 is hydrogen or methyl,and a sulfur-containing compound represented by the formula:(R.sub.5 --S--CH.sub.2 CH.sub.2 COOCH.sub.2).sub.4 Cwherein R.sub.5 is an alkyl having 4 to 20 carbon atoms. The composition is stable against the thermal deterioation and discoloration in the absence of oxygen as well as against the thermal and oxidative deterioration in the presence of oxygen.
    Type: Grant
    Filed: December 23, 1988
    Date of Patent: September 10, 1991
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Takeshi Takata, Shinichi Yachigo, Manji Sasaki, Kikumitsu Inoue, Shinya Tanaka
  • Patent number: 5045581
    Abstract: A butadiene polymer composition containing a phenolic compound represented by the formula: ##STR1## wherein R.sub.1 is an alkyl having 1 to 4 carbon atoms, R.sub.2 and R.sub.3 are each independently a group represented by --C(CH.sub.3).sub.2 --R' in which R' is an alkyl having 1 to 5 carbon atoms or phenyl, and R.sub.4 is hydrogen or methyl, and a phosphorus-containing compound represented by the formula: ##STR2## wherein R.sub.5 and R.sub.6 are each independently an alkyl having 1 to 9 carbon atoms.The composition is stable against the thermal deterioration and discoloration in the absence of oxygen as well as against the exposure to oxides of nitrogen gas.
    Type: Grant
    Filed: December 21, 1988
    Date of Patent: September 3, 1991
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Takeshi Takata, Shinichi Yachigo, Manji Sasaki, Kikumitsu Inoue, Shinya Tanaka