Abstract: A process for rapidly forming a flexible mold for finely detailed objects from a radiatively curable molding composition includes coating at least a portion of the surface of a three-dimensional object with a fluid molding composition. The coating is cured by exposing the fluid coating to radiative energy to form an elastic, flexible layer of cured molding composition on the object. The coating and curing steps can be repeated to build up the flexible mold until a predetermined minimum has been attained. The cured molding composition is removed from the object, and is suitable for immediate use as a mold to cast duplicate reproductions of the object.

Abstract: A vinyl halide resin (PVC) flooring composition having reduced water absorption containing polyhydric alcohol, metal salt stabilizer, filler and an aromatic carboxylic acid such as benzoic, methylbenzoic or naphthoic acid as an anti-water absorption agent. The compositions may be employed for dramatic improvement against swelling and buckling of flooring tile and sheet.

Abstract: Tetrahalophthalate esters are disclosed herein as flame retardant processing aids for polystyrene resins.

Abstract: A method of producing an emulsion polymer which comprises adding a polymerizable monomer to an emulsion polymer containing a high-molecular-weight compound having a weight average molecular weight of 20,000 to 2,000,000 as a seed polymer, the amount of the unsaturated monomer being 1.5 to 9.5 times the total volume of the solids in the emulsion polymer, and thereafter, polymerizing the monomer in the presence of a film-forming aid.

Abstract: Disclosed is an anti-stat which is effective in polyvinyl chloride polymeric parts to dissipate charge phenomena occurring at a surface thereof. The anti-stat comprises an ethoxylated fat-forming alcohol and a dibasic acid-capped fat-forming alcohol which is incorporated in an effective amount in the polyvinyl chloride polymeric material.

Abstract: A boot for an automobile comprises two terminal annular parts and a barrel part intervening between the two terminal annular parts. This boot is obtained by injection molding a flexible PVC material. The flexible PVC material of one type (I) is composed of a polymer component and a plasticizer, which polymer component is obtained by blending high polymerization degree and low polymerization degree PVC's respectively having an average polymerization degree in specific ranges, with the mixing ratio of the two PVC's being in a specific range. The flexible PVC material of the other type (II) is composed of a polymer component and a plasticizer, which polymer component is obtained by blending a cross-linked resin having a non-gel component average polymerization degree and a cross-linking degree in respectively specific ranges with a non-cross-linked resin having an average polymerization degree in a specific range, with the mixing ratio of the two PVC's in a fixed range.

Abstract: A one-part curing composition comprising a compound (a) having two or more structural groups, per molecule, expressed by the general formula: ##STR1## wherein R.sup.1, R.sup.2, and R.sup.3 are groups selected from an alkyl group having 1 to 6 carbon atoms, a phenyl group, and a chloromethyl group, and a polymer (b) having two or more isocyanate groups per molecule, has a good stability in storage under conditions which exclude moisture and humidity, and which further cures in the presence of humidity. This composition does not foam under high temperatures and humidities and has a good heat resistance.

Abstract: Thermally stable hot applied plastisol compositions are especially useful in the assembly of metal parts. The compositions have adhesive and sealant qualities which allow them to be used in automotive assembly plants. Compositions of the invention comprise as major ingredients finely divided polyvinyl chloride resin, plasticizer, thermoplastic polymeric resin which is solid at room temperature but softens to a flowable state at application temperature, and an adhesion promotion system. Optionally a filler, wax, heat stabilizer, pigment, wetting agent, or mixtures thereof may be added. The individual components work synergistically to get good application properties, metal adhesion, wash-out resistance, and paintability.

Abstract: A coating composition, containing a fluoropolymer, a film-forming adjuvant resin which is different from the fluoropolymer and adapted to react with the group represented by F in the functional organosilane of formula I and which is selected from the group consisting of acrylic resins, polyepoxide resins, polyester resins, aminoplast resins and mixtures thereof; and an amount effective to promote adhesion of a functional organosilane represented by formula I: ##STR1## wherein A represents an organo group containing from 1 to 18 carbon atoms,G represents an organo group containing from 2 to 10 carbon atoms,X represents a hydrolyzable group; andb is an integer from 0 to 2, andF represents amino, polyamino, glycidoxy, mercapto, cyano, allyl, vinyl, urethano, halo, isocyanato, ureido, imidazolinyl, acrylato or methacrylato.

Abstract: A mineral-oil-free composition of matter useful as a cable splice encapsulant comprises between about 20% and about 60% polyurethane, by weight of the cured encapsulant, the balance comprising plasticizer(s) and optionally, additives such as catalysts, antioxidants and fungicides.

Abstract: A deodorizing coating formulation is composed of a white or substantially colorless deodorizing agent, a binder resin and a liquid medium. The deodorizing agent may preferably be composed of 10-90 parts by weight of a zinc compound and 90-10 parts by weight of an aliphatic polycarboxylic acid, aromatic polycarboxylic acid, acidic polymer or a sulfate of aluminum, or a salt thereof. A deodorizing sheet can be obtained by coating and/or impregnating a base sheet with the deodorizing coating formulation and then drying the resulting base sheet. The deodorizing sheet can shield a flavor or odor from external flavors or odors while maintaining air permeability, it is suitable for wrapping foods having strong flavors or odors.

Abstract: A process for the preparation of polyester polyols having an acid number of less than 1, a hydroxyl number of approximately 20 to about 400, and having a functionality of efficaciously 2 to 3, wherein polycarboxylic acids and/or their anhydrides and multivalent alcohols are polycondensed, preferably in the absence of common esterification catalysts, at temperatures of from about 150.degree. to 250.degree. C., optionally under reduced pressure, up to an acid number of from 20 to 5. The resulting polycondensate is then oxyalkylated per carboxyl group using from 1 to 5 moles of an alkylene oxide, for example 1,2-propylene oxide and/or preferably ethylene oxide, in the presence of at least one tertiary amine catalyst from the group consisting of N-methylimidazole, diazabicyclo[2,2,2]octane, diazabicyclo[5,4,0]undec-7-ene and pentamethyldiethylenetriamine and mixtures thereof, in a quantity of from about 0.001 to 1.0 weight percent based on the weight of the polycondensate, at temperatures from about 100.degree.

Abstract: Optical devices such as optical disk substrates and lenses are prepared by molding a resin composition comprising 100 parts by weight of a mixture of 30 to 70% by weight of a polymer in which 50% by weight or more is composed of aromatic vinyl monomer units and 70 to 30% by weight of a polyphenylene ether, and 0.005 to 2 parts by weight of an organic carboxylic acid.

Abstract: A vinyl halide resin (PVC) flooring composition having reduced water absorption containing polyhydric alcohol, metal salt stabilizer, filler and an aromatic carboxylic acid such as benzoic acid as an anti-water absorption agent. The compositions may be employed for dramatic improvement against swelling and buckling of flooring tile and sheet.

Abstract: Disclosed is a composition suitable for the preparation of a gasket for use in the production of shaped resin articles by cast polymerization. The composition is comprises (A) 100 weight parts of a vinyl chloride resin, (B) 30 to 70 weight parts of a carboxylic acid ester or phosphoric acid ester plasticizer, (C) 0.5 to 10 weight parts of an epoxy type plasticizer and (D) 0.1 to 5 weight parts of a barium- or zinc-containing stabilizer.

Abstract: High solids aqueous based pressure sensitive adhesives may be prepared by directly emulsifying the tackifier resin into a polymeric latex provided the tackifier is heated, plasticized and emulsified and mixed with the latex on a high shear mixer. This gives an adhesive which is faster drying and gives comparable properties to lower solids adhesives.

Abstract: Tetrahalophthalate esters are disclosed herein as flame retardant processing aids for polystyrene resins.

Abstract: An elastomeric blend composition having improved tear properties and having a viscosity at 0.73 sec.sup.-1 and at 200.degree. C. of about 8.times.10.sup.3 to about 8.times.10.sup.5 poises, said composition formable into an elastomeric article, which comprises:(a) a neutralized sulfonated EPDM terpolymer having a viscosity at 0.73 sec.sup.-1 and at 200.degree. C. of about 5.times.10.sup.4 poises to about 5.times.10.sup.6 poises and about 10 to about 50 meq. sulfonate groups per 100 grams of said sulfonated EPDM terpolymer, said sulfonate groups being neutralized; and(b) about 2 to about 60 parts by weight of a fluorohydrocarbon elastomer per 100 parts of such sulfonated EPDM terpolymer.

Abstract: A gelled dielectric encapsulant material and process therefor for use in reenterable and nonreenterable communication cable splices as well as applications relating to encapsulation of electronic components comprises a plasticizer which does not stress crack polycarbonate, an aliphatic or aromatic carboxylic acid, and a basic oxide or hydroxide.

Abstract: Peroxide vulcanizable chlorinated polyethylene compositions can, after being press cured at a temperature of 204.degree. Centigrade for a period of ten minutes, withstand ozone-induced cracking for a period of 168 hours or more when elongated 60% and exposed to 200 parts of ozone per hundred million parts of air at a temperature of 400.degree. Centigrade.

Abstract: A synthetic resin matrix system for the delayed and extended duration delivery of drugs to humans and animals is disclosed consisting of a polymer, such as poly(2-hydroxyethylmethacrylate), referred to as PHEMA, an organic solvent, such as polyethylene glycol (PEG), and a hydrogen binding plasticizer, such as dimethylsulfoxide (DMSO). The plasticizer regulates the set-up time of the synthetic resin so that the more plasticizer present, the shorter the set-up time. The plasticizer also has a direct shortening effect upon the cure time and also profoundly influences many of the physical characteristics of the resultant synthetic resin matrix system. A variety of drugs can be embodied in the fabricated matrix system and administered to the patient (or animal) by different modes of application, including but not limited to oral, topical, rectal, subcutaneous implant, or organ-specific implant such as in the conjunctival sac of the eye.

Abstract: A synthetic resin matrix dressing is disclosed consisting essentially of a polymer, such as poly(2-hydroxyethylmethacrylate), referred to as PHEMA, an organic solvent, such as polyethylene glycol (PEG), and a hydrogen bonding plasticizer, such as dimethylsulfoxide (DMSO). The plasticizer regulates the set-up time of the synthetic resin so that the more plasticizer present, the shorter the set-up time. The dressing may be applied to the treatment site in veterninary use in the form of a paste for the in-situ curing or setting thereof, or the dressing may be preformed and then applied to the treatment site. A variety of drug agents may be incorporated in the synthetic resin matrix so as to result in the time released administration of the drug agent to the area of the skin covered by the dressing. A method of treatment using this dressing is also disclosed.

Abstract: It has been discovered that by adding one or more strong organic carboxylic acids to conventional acrylate and/or methacrylate based adhesive compositions, the bonding characteristics thereof change dramatically.Thermoplastic materials whose bondability is most dramatically enhanced by the compositions of the present invention are nylon and blends of nylon and nylon-like materials with other polymers.Thermoset materials which exhibit dramatically enhanced bondability comprise homogeneous materials such as epoxies, and composite materials such as polyesters, urethanes, and/or epoxies, containing glass, minerals, and the like, which are polar or have hydrogen bonding capability.The present invention thus utilizes acrylate and/or methacrylate based adhesive compositions as a base material. To this base material is added an effective amount of one or more strong organic carboxylic acids, e.g., acids having a relatively high dissociation constant (K.sub.d or K.sub.1d).

Abstract: An improved bedding composition for use in sealing insulating glass units to frames, mullions, or the like is provided. The bedding compound includes a polar solvent, a plasticizer, and an elastomer and is compatible with available insulating glass sealant compositions including hot melt adhesives.

Abstract: Polyimide film prepared from a precursor solutions of polyamic acid in a solvent can be dried during or following the thermal or chemical conversion step, which produces a polyimide, by adding to the solution a small amount of an alkyl ester of phthalic, terephthalic, or isophthalic acid, casting the solution on a flat surface and heating the solution on the flat surface at about 100.degree.-200.degree. C.; then, removing the resulting partially converted film from the flat surface and heating it, under restraint, to about 200.degree.-375.degree. C., to bring about complete conversion and remove virtually all of the solvent. Polyimide films are useful in various applications where high temperature resistance is required, including composites for aerospace applications and for circuit boards for electronic equipment.

Abstract: Thermoplastic molding compositions comprising a polycarbonate resin, a thermoplastic polyester and an impact modifier were found to maintain their impact performance, especially at low temperatures, while exhibiting a reduced melt viscosity upon the blending therewith a relatively small amount of a certain ester plasticizer.

Abstract: A plasticized polyurethane gel system comprising the reaction product of an isocyanate compound and a polyol in the presence of a plasticizer compound having a total solubility parameter of between about 8.3 and 8.9 or between about 9.1 and 9.7.

Abstract: A process for producing a thermoplastic resin molding which comprises adding to a thermoplastic resin an organic compound which is compatible with said thermoplastic resin to form a homogeneous phase at a molten state of said thermoplastic resin and causes phase separation by cooling, molding the composition by melting, and solidifying it by cooling; and the molding thus obtained.

Abstract: A novel method for producing a composite ester from dibasic acid, diol and monovalent alcohol through a dehydrating esterification reaction in the first step and then alcohol removing ester interchange reaction in the second step.

Abstract: Pressure-sensitive adhesives which are mixed immediately prior to application, or need drying equipment tend to be expensive in use while those applied as hot melts tend to have poor heat resistance. According to the invention an adhesive composition curable by atmospheric moisture is provided, the composition comprising a prepolymer component with isocyanate functionality between 2.0 and 3.0 together with one or more polyetherurethane prepolymers having NCO groups available for reaction with water for chain extension, the cured adhesive composition having a glass transition temperature below 20.degree. C.

Abstract: A medical instrument is disclosed which is a shaped article of a resin composition comprising 100 parts by weight of a vinyl chloride type resin, 10 to 80 parts by weight of a di-n-alkyl ester of phthalic acid whose alkyl groups each possess 8 to 14 carbon atoms and whose numbers of carbon atoms in said alkyl groups average 9 to 14, and 1 to 18 parts by weight of a stabilizer. The medical instrument exudes only an extremely small amount of plasticizer and excels in permeability to gas.

Abstract: A composition having utility as a plasticizer for halogen-containing resins is a mixture of (a) at least two diesters of terephthalic acid or (b) at least two triesters of trimellitic acid. The diesters of terephthalic acid are represented by the general formula ##STR1## wherein R.sub.1 is a phenyl radical or an aliphatic hydrocarbon radical of the formula C.sub.n H.sub.m, wherein n is an integer of 1 through 8 inclusive and m is equal to 2n+1; R.sub.2 is either hydrogen or an aliphatic hydrocarbon having one, two, three or four carbon atoms; x is an integer of 2 to 4 inclusive; y is an integer of 2 to 4 inclusive.The trialkyl esters of trimellitic acid are represented by the general formula ##STR2## wherein R.sub.1 is a phenyl radical or an aliphatic hydrocarbon radical of the formula C.sub.n H.sub.m wherein n is an integer of 1 through 8 inclusive and m is equal to 2n+1; R.sub.

Abstract: A pneumatic tire having a low fuel consumption and all-weather running performances is disclosed, which comprises a tread composed of a rubber composition containing 30-80 parts by weight of carbon black having IA of not less than 70 mg/g and DBP absorption of not less than 90 ml/100 g, based on 100 parts by weight of a rubber blend consisting of 97-10 parts by weight of at least one diene rubber having a content of bound styrene of 0-30% and a content of vinyl bond in butadiene unit of 25-95%, 3-30 parts by weight of butyl rubber and/or halogenated butyl rubber, and 0-87 parts by weight of the other diene rubber.

Abstract: A gelled dielectric encapsulant material and process therefor for use in reenterable and nonreenterable communication cable splices as well as applications relating to encapsulation of electronic components comprises a plasticizer which does not stress crack polycarbonate, an aliphatic or aromatic carboxylic acid, and a basic oxide or hydroxide.

Abstract: A thermoplastic, melt-processible, elastomeric composition based on partially crosslinked compatible blends of an ethylene copolymer and a vinyl or vinylidene halide polymer.

Abstract: An antistatic additive for polymers, particularly polyurethanes is disclosed comprising an ionizable metal salt and an enhancer comprising a non-ionizable salt or ester of an organic acid.

Abstract: Improvement of stability of dynamic performance of pneumatic tire tread composition, by adding at least one of some esters such as phosphoric acid ester, fatty acid ester in a definite ratio to the known composition comprising styrene-rich SBR added with a processing oil and carbon black respectively in higher ratio for improving dynamic performance.

Abstract: A thermoplastic, melt-processible, elastomeric composition based on partially crosslinked compatible blends of an ethylene copolymer and a vinyl or vinylidene halide polymer.

Abstract: A radiation sterilized medical device made of a resin compound comprising 100 parts by weight of vinyl chloride resin, 0.001 to 5 parts by weight of at least one metal oxide selected from the group consisting of magnesium oxide, calcium oxide, and zinc oxide and 5 to 200 parts by weight of a dialkyl phthalate of the formula ##STR1## wherein m and n are each an integer of the value of substantially 6 to 12 and the average of m an n, (m+n)/2, is not more than 11.5. The invention also provides the method of preparing said medical device and the specified resin.

Abstract: Thermoplastic hot melt compositions and process for forming such compositions are disclosed. The compositions comprise a polyurethane having at least one plasticizer reacted therein formed by heating a reaction mixture comprising at least one isocyanate having a functionality less than about 2, at least one long chain polyol, at least one chain extender and the at least one plasticizer at a temperature of at least about 330.degree. F. where the components are present in an amount as defined in the specification. The process is adequately reflected by the above language.

Abstract: An additive for coating compositions which is a blend of(A) 20-50% by weight of a polyisocyanate of one of the following formulas: ##STR1## where R.sup.1 is (CH.sub.2).sub.6, (B) 1-15% by weight of an ester of a polyalkylene glycol alkyl alkylate, an alkyl phthalate or an alkyl aromatic phthalate(C) 1-10% by weight of a blend of ultraviolet light stabilizers and(D) 25-78% by weight of organic solvent; the additive can be added to acrylic lacquers, nitrocellulose lacquers, acrylic-alkyd enamels and acrylic polyurethane enamels to provide flexible finishes for flexible substrates used in automobile and truck bodies.

Abstract: According to the invention, a resin composition having an electromagnetic wave shielding effect is provided. The resin composition comprises 35 to 90 wt % of an ABS resin or a mixture of the ABS resin and an AS resin, 1 to 25 wt % of a plasticizer and 5 to 40 wt % of carbon fibers. The carbon fibers are uniformly dispersed in the resin ingredient without being broken or cut at the step of mixing and dispersing the resin components, thus exhibiting improved electromagnetic wave shielding effect.

Abstract: The invention relates to a process for isocyanurating hexamethylene-diisocyanate containing polyol adduct thereof using a novel catalyst and to a paint composition formed from of the product of the above mentioned process and polyol, and to the composition yielding a paint film showing an excellent light resistance and weather resistance, especially high yellowing resistance.

Abstract: According to the invention, a resin composition having an electromagnetic wave shielding effect is provided. The resin composition comprises 35 to 90 wt % of an ABS resin or a mixture of the ABS resin and an AS resin, 1 to 25 wt % of a plasticizer and 5 to 40 wt % of carbon fibers. The carbon fibers are uniformly dispersed in the resin ingredient without being broken or cut at the step of mixing and dispersing the resin components, thus exhibiting improved electromagnetic wave shielding effect.

Abstract: A propylene polymer composition containing (i) 100 parts by weight of a polypropylene and/or a propylene-ethylene copolymer and (ii) 0.05 to 2 parts by weight of triallyl(iso)cyanurate and/or diallyl(iso)phthalate, or (i) 100 parts by weight of a polypropylene and/or a propylene-ethylene copolymer, (ii) 0.01 to 0.5 part by weight of triallyl(iso)cyanurate and/or diallyl(iso)phthalate, and (iii) 0.005 to 0.2 part by weight of an organic peroxide.This propylene composition has excellent resistance against high-energy radiation without impairing the desired properties of the propylene polymer per se.

Abstract: An elastomeric composition whose scorch is inhibited comprises [I] a halogen-containing elastomer, [II] a di- or tri-thiol-s-triazine compound and [III] at least one polycarboxylic acid compound selected from the group consisting of (A) a polycarboxylic acid having at least two carboxyl groups capable of forming an acid anhydride group in the molecule and (B) a halogen-substituted polycarboxylic acid anhydride.

Abstract: A steering wheel is disclosed, which is produced by injection molding a resin composition comprising (i) a crosslinked vinyl chloride polymer having a gel fraction of at least 20% and a non-gelled portion having an average polymerization degree of from 2000 to 3000, (ii) a non-crosslinked vinyl chloride homopolymer having an average polymerization degree of from 800 to 1000, and (iii) a liquid plasticizer, wherein the weight ratio of polymer component (i) to polymer component (ii) is from 50/50 to 80/20 and (iii) the amount of liquid plasticizer is from 70 to 130 parts by weight per 100 parts by weight of the total amount of the two polymers (i) and (ii). The steering wheel has excellent properties with respect to uniformity in matte surface, wear resistance and lightfastness.

Abstract: A synthetic resin wound dressing (e.g., a burn wound dressing) is disclosed consisting essentially of a polymer, such as poly(2-hydroxyethylmethacrylate), referred to as PHEMA, an organic solvent, such as polyethylene glycol (PEG), and a hydrogen binding plasticizer, such as dimethylsulfoxide (DMSO). The plasticizer regulates the set-up time of the synthetic resin so that the more plasticizer present, the shorter the set-up time. The dressing may be applied to the wound site in the form of a paste for the in situ curing or setting thereof, or the dressing may be preformed and then applied to the wound site. A variety of drug agents (e.g., silver sulfadiazine) may be incorporated in the synthetic resin so as to result in the time released administration of the drug agent to the area of the skin (e.g., a burn wound site or the like) covered by the wound dressing. A method of treatment using this dressing is also disclosed.

Abstract: Poly(vinyl chloride) resin compositions containing an ethylenically-unsaturated compound having carbonylamino or thiocarbonylamino groups. These compositions are readily convertible at low temperatures to crosslinked polymers and are radiation-curable to dimensionally stable articles and films that are clear and that do not exude oily materials.

Abstract: Polyethylene terephthalate resin compositions containing filler or reinforcing agent, a selected sodium or potassium salt of a hydrocarbon acid or a salt of a selected organic polymer containing pendant carboxyl groups, and a selected low molecular weight organic ester, ketone, sulfone, sulfoxide, nitrile or amide. Articles molded from the compositions have high gloss when molded at temperatures below 110.degree. C.