Halogen Patents (Class 524/341)
  • Patent number: 4954542
    Abstract: Tetrahalophthalate esters are disclosed herein as flame retardant processing aids for polybutylene terephthalate (PBT) resins.
    Type: Grant
    Filed: March 25, 1988
    Date of Patent: September 4, 1990
    Assignee: Pennwalt Corporation
    Inventors: Joseph M. Bohen, Ronald F. Lovenguth
  • Patent number: 4921890
    Abstract: A process for improving the flame retardancy, hygroscopic, soil release and other properties of a polymer substrate is provided in which the substrate is contacted with a suitable aqueous mixture containing a water-soluble monomer and an organic halogen-containing hydrophobic carrier compound at a temperature of between about 40.degree. C. to 100.degree. C. Polymerization of the monomer is thereafter initiated by a chemical or physical initiator to form a polymer evenly disposed on the substrate. The flame retardancy, hygroscopic, soil release and other surface properties of the substrate are thereby improved. The mixture may be in the form of an emulsion wherein the hydrophobic carrier compound is emulsified by an appropriate agent. The invention also pertains to the improved substrates prepared in accordance with the present process.
    Type: Grant
    Filed: April 24, 1987
    Date of Patent: May 1, 1990
    Assignee: Intera Company, Ltd.
    Inventors: Katsumi Hayashi, Gregory A. Lentz
  • Patent number: 4908428
    Abstract: Quick-crystallizing polyester compositions comprising a mixture consisting or consisting essentially of a polyester thermoplastic resin and of 0.1-10% by weight of a nucleant selected from polymeric-base salts, or mixtures of salts, of alkali metals or alkaline-earth metals of the formula:M--(OOC--C.sub.6 H.sub.4 --COO--CH.sub.2 CH.sub.2 CH.sub.2 CH.sub.2).sub.m (OOC--Z--COOY).sub.n (ABRX) (1)whereinM is an alkali or alkaline-earth metal;Y is a group --CH.sub.2 CH.sub.2 --,--(CH.sub.2).sub.4 -- or --CH.sub.2 CH.sub.2 OCH.sub.2 CH.sub.2 --;Z is a group --C.sub.6 H.sub.4 --, or a group --(CH.sub.2).sub.q --, q being an integer from 7 to 10;A is an anion selected from the group consisting of carboxylate, sulphonate, sulphinate, phosphonate, phosphinate;B may be a single bond or a group selected from the group consisting of --CH.dbd.CH--, --CH.sub.2 --, --CH.sub.2 CH.sub.2 --;R is an arylene radical containing from 1 to 3 aromatic rings or a heterocyclic ring;X is a hydrogen atom or a group --COOM or --COO(CH.
    Type: Grant
    Filed: March 14, 1989
    Date of Patent: March 13, 1990
    Assignee: Montefibre S.p.A.
    Inventors: Catia Bastioli, Vittorio Bellotti, Luciano Del Giudice
  • Patent number: 4897307
    Abstract: The present invention relates to a process for the solvent-induced crystallization of amorphous poly(etheretherketone)-type polymer to produce an article, which process comprises:A. contacting a preformed article of a polymer comprising amorphous poly(etheretherketone)-type polymer with at least one organic compound in its liquid state which consists essentially of atoms of carbon and hydrogen, optionally with oxygen, nitrogen, sulfur, halogen or mixtures thereof having a molecular weight of between about 160 and 320 daltons at a temperature of between about 85.degree. C. and 145.degree. C. for a time effective to crystallize the poly(etheretherketone)-type polymer,B. removing the organic compound, andC. recovering the article comprising crystallized poly(etheretherketone)-type polymer. Poly(etheretherketone), poly(phenylenesulfide) or mixtures thereof are preferred polymer systems.
    Type: Grant
    Filed: August 11, 1987
    Date of Patent: January 30, 1990
    Assignee: The Dow Chemical Company
    Inventors: Henry N. Beck, Robert M. Nowak
  • Patent number: 4879329
    Abstract: An impact resistant flame-retardand resin composition comprising:100 parts by weight of a polymer mixture comprising a polycarbonate resin (A), a rubber-reinforced vinyl copolymer (B) and, optionally, a vinyl polymer (C);from 3 to 50 parts by weight of a high molecular weight halogenated compound of the following formula I having a halogen content of at least 10% by weight: ##STR1## wherein n is an average polymerization degree of from 35 to 100, each X independently represents hydrogen, chlorine or bromine, each of i, j, k and l is an integer of from 1 to 4, and each of R and R' independently is hydrogen, a methyl group, an epoxypropyl group, a phenyl group or ##STR2## wherein m is 0, 1, 2 or 3; and from 2 to 30 parts by weight of an antimony compound.
    Type: Grant
    Filed: October 18, 1988
    Date of Patent: November 7, 1989
    Assignee: Mitsubishi Rayon Company Ltd.
    Inventors: Masafumi Hongo, Mitsuaki Noda
  • Patent number: 4735983
    Abstract: A flame-retardant styrene-base resin composition is composed of 100 parts by weight of a styrene-base resin, 2.0-20.0 parts by weight of a halogenous flame retardant and 0.1-5.0 parts by weight of an antimony compound. The weight ratio of halogen atoms/antimony atoms in the resin composition is 5 or greater. The resin composition of this invention has well-balanced specific gravity, impact resistance and heat resistance and flame retardancy.
    Type: Grant
    Filed: March 25, 1987
    Date of Patent: April 5, 1988
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Masato Takaku, Ichiro Otsuka, Keizi Iio, Nobuyuki Tashiro, Daizo Natsugari, Hideo Ichikawa
  • Patent number: 4673701
    Abstract: Alkylidene bisphenol phosphites and phosphates having 2,2,6,6-tetramethyl piperidinyl groups are provided having the formula: ##STR1## wherein: R.sub.1 is alkyl having from one to about twelve carbon atoms;R.sub.2, R.sub.3 and R.sub.4 are each selected from the group consisting of hydrogen and alkyl having from one to about twelve carbon atoms;m is 0 or 1;n is 0 or 1;X is selected from the group consisting of ##STR2## wherein: R.sub.5 is selected from the group consisting of hydrogen, oxyl O.sup.2, alkyl having from one to about twelve carbon atoms; arylalkyl having from seven to about eighteen carbon atoms; 2,3-epoxypropyl, acyl having from one to about eight carbon atoms and ##STR3## in which R.sub.6 is selected from the group consisting of hydrogen, alkyl having from one to about twelve carbon atoms and phenyl, and Y.sub.1 is selected from the group consisting of hydrogen; acyl having from one to about twelve carbon atoms; and ##STR4## Z.sub.1 is selected from the group consisting of ##STR5## wherein R.
    Type: Grant
    Filed: December 28, 1984
    Date of Patent: June 16, 1987
    Assignee: Adeka Argus Chemical Co., Ltd.
    Inventors: Motonobu Minagawa, Yutaka Nakahara, Toshihiro Shibata, Ryozo Arata
  • Patent number: 4631302
    Abstract: A biocidal wax composition for preventing corrosion and biological fouling nd surface degradation of submerged structures comprises from about 10 to about 40 percent of total biocidal wax composition of a biocidal polymeric gel consisting of a polymer from the group consisting of a polyethylene, polypropylene, a copolymer of polyethylene and vinyl acetate, and mixtures thereof and a solvent selected from the group consisting of mineral oil, a paraffin wax and mixtures thereof, and a biocide; and from about 60 to about 90 percent of total biocidal wax composition of a wax matrix composition consisting of petrolatum, at least two chlorinated waxes, and a microcrystalline wax. The biocidal wax is prepared by shock-cooling a hot solution of a polymer through its cloud point, admixing a biocide with the gel, and admixing the above wax matrix composition with the gel.
    Type: Grant
    Filed: July 1, 1985
    Date of Patent: December 23, 1986
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventors: Robert F. Supcoe, Thomas Radakovich
  • Patent number: 4602051
    Abstract: According to the invention, a resin composition having an electromagnetic wave shielding effect is provided. The resin composition comprises 35 to 90 wt % of an ABS resin or a mixture of the ABS resin and an AS resin, 1 to 25 wt % of a plasticizer and 5 to 40 wt % of carbon fibers. The carbon fibers are uniformly dispersed in the resin ingredient without being broken or cut at the step of mixing and dispersing the resin components, thus exhibiting improved electromagnetic wave shielding effect.
    Type: Grant
    Filed: August 30, 1984
    Date of Patent: July 22, 1986
    Assignee: Denki Kagaku Kogyo Kabushiki Kaisha
    Inventors: Takeshi Nabeta, Isamu Hanahara
  • Patent number: 4582866
    Abstract: Flame retardant thermoplastic multi-block copolyester elastomer compositions containing a bromine-containing flame retardant; antimony trioxide; and an organophilic clay which is the reaction product of at least one quaternary ammonium salt with a smectite clay.
    Type: Grant
    Filed: April 30, 1984
    Date of Patent: April 15, 1986
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Albert L. Shain
  • Patent number: 4552911
    Abstract: The present invention relates to polycarbonate molding compositions containing additives of alkali or alkaline earth metal salts, tetrahalogenophthalimides and optional glass fibers, characterized in that they contain additive amounts of bromine.
    Type: Grant
    Filed: January 28, 1983
    Date of Patent: November 12, 1985
    Assignee: Bayer Aktiengesellschaft
    Inventors: Wolfgang Cohnen, Klaus Kircher, Peter R. Muller, Sivaram Krishnan, Dieter Neuray
  • Patent number: 4535112
    Abstract: A method for repairing perfluorocarbon copolymeric cation exchange membranes. A quantity of a perfluorocarbon copolymer having a desired pendant cation exchange functional group is partially solvated in a solvating dispersion media, applied to areas of the membrane to be repaired, and the dispersion media removed.
    Type: Grant
    Filed: September 21, 1983
    Date of Patent: August 13, 1985
    Assignee: Eltech Systems Corporation
    Inventors: G. Howard McCain, Leo L. Benezra, Craig E. Finch
  • Patent number: 4529760
    Abstract: Oligomers of 2,2,6,6-tetramethylpiperidinol polycarboxylic acid esters are provided having the formula: ##STR1## wherein: Z is the residue of an aliphatic or aromatic or nitriloaliphatic or hydroxy aliphatic polycarboxylic acid having from three to six carboxylic acid groups and from one to thirty carbon atoms; ##STR2## wherein R.sub.3 is hydrogen, alkyl and hydroxyalkyl having from one to about twenty carbon atoms; cycloalkyl having from six to about twenty carbon atoms; aryl having from six to about twenty carbon atoms; or cycloalkylene with the N in the ring and having from two to five carbon atoms;R is alkylene having from two to about twelve carbon atoms; cycloalkylene having from three to about twelve carbon atoms; phenylene having from six to about twenty carbon atoms; mixed alkylenecycloalkylene or alkylene phenylene or oxyalkylene having from two to about twelve carbon atoms; ##STR3## wherein R.sub.4 is alkyl having from one to about six carbon atoms;R.sub.
    Type: Grant
    Filed: November 1, 1983
    Date of Patent: July 16, 1985
    Assignee: Adeka Argus Chemical Co., Ltd.
    Inventors: William E. Leistner, Motonobu Minagawa, Yutaka Nakahara, Tohru Haruna, Atsushi Nishimura
  • Patent number: 4473523
    Abstract: An aromatic polyimide film having excellent mechanical, thermal and electrical properties, is continuously produced by the steps of:preparing a dope solution having a rotation viscosity of 500-10.sup.5 poises at 100.degree. C. by uniformly dissolving aromatic polyimide in a solvent consisting of at least one phenol compound; extruding the dope solution through a T-die at 50.degree. C. or more, but at least 30.degree. C. below the boiling point of the solvent, under conditions which cause the apparent viscosity and shear stress of the dope solution to be 500-5.times.10.sup.4 poises and 10.sup.4 -10.sup.6 dyne.multidot.cm.sup.-2, respectively, to form a filmy stream of the dope solution; placing the filmy stream of the dope solution on a surface of a supporting means while heating the surface at a temperature of 50.degree. C.
    Type: Grant
    Filed: January 12, 1983
    Date of Patent: September 25, 1984
    Assignee: UBE Industries, Ltd.
    Inventors: Yoshikazu Sasaki, Hiroshi Inoue, Youji Negi, Kazuhiko Sakai
  • Patent number: 4472543
    Abstract: A flame retardant diaphragm for speakers, etc. comprises an admixture of natural fibers and inorganic fibers. The admixture is impregnated with a thermosetting resin and an organic bromine compound, and heat-treated under pressure. The organic bromine compound acts as a flame retarder.
    Type: Grant
    Filed: May 26, 1982
    Date of Patent: September 18, 1984
    Assignees: Pioneer Electronic Corporation, Mogami Denki Kabushiki Kaisha
    Inventors: Kazuo Tsuchiya, Fumio Kawahara, Shigeru Watanabe
  • Patent number: 4460716
    Abstract: A process for preparing resin coated sand for shell molding foundry operations is disclosed wherein the resin utilized is a phenolic resin containing a bromophenol. The resin coated sand has improved shake-out properties and is especially formulated for low melting metals such as aluminum and magnesium castings.
    Type: Grant
    Filed: June 16, 1983
    Date of Patent: July 17, 1984
    Assignee: Sumitomo Durez Company, Ltd.
    Inventors: Yukio Saeki, Shigeru Nemoto, Yukio Tokunaga
  • Patent number: 4458036
    Abstract: Polyurethane foams prepared from the reaction of polyester polyol with organic isocyanate have improved flame retardance and dripping ember retardance by incorporation of an additive comprising (1) halogenated flame retardant, and (2) organic solvent soluble glycoluril-formaldehyde material.
    Type: Grant
    Filed: February 28, 1983
    Date of Patent: July 3, 1984
    Assignee: Stauffer Chemical Company
    Inventor: Gerald Fesman
  • Patent number: 4454278
    Abstract: A polyester, a polyester/polyamide or a polyester/polyamide/polyimide polymers are prepared from (a) a diaryl terephthalate or diaryl isophthalate, and (b) an aromatic polyol or of (a) and a mixture of (b), and an aromatic diamine, or of (a), (b), (c), and (d) a triaryl mellitate, or a copolycarbonate of any of the foregoing including units derived from (e) a diaryl carbonate. The resulting polyester, polyamide, polyester/polyamide or polyester/polyamide/polyimide polymers are adapted for use as an insulating coating on an electrical conductor.
    Type: Grant
    Filed: June 24, 1981
    Date of Patent: June 12, 1984
    Assignee: General Electric Company
    Inventors: Daniel W. Fox, John J. Keane
  • Patent number: 4447572
    Abstract: Polyamides, flame retarded with a halogenated derivative and blended with a polymer blend resin being at least partially incompatible and having a lower melt viscosity than the polyamide, to improve the arc tracking resistance of the polyamide, are disclosed. The polyamides are particularly useful in the manufacture of flame retarded electrical components.
    Type: Grant
    Filed: November 6, 1981
    Date of Patent: May 8, 1984
    Assignee: Occidental Chemical Corporation
    Inventors: Daniel J. Scharf, Charles S. Ilardo, Willis T. Schwartz, Gideon Salee
  • Patent number: 4446272
    Abstract: A resin composition having nice color tone and high crack-resistance as well as flame-retardancy is obtained by blending(A) 100 weight parts of a resin composition containing a rubber-reinforced vinyl aromatic polymer and polyphenylene ether represented by the following general formula: ##STR1## wherein each of R.sub.1 and R.sub.2 represents a monovalent residue such as the same or different alkyl group having 1-4 carbon atoms, aryl group, halogen and hydrogen, and n represents the polymerization degree or a polyphenylene ether onto which a vinyl aromatic compound is graft-copolymerized, in which the polyphenylene ether content is 5-70 wt. % (based on the weight of the resin part),(B) 1-30 weight parts of a halogenated aromatic compound and(C) 0.5-20 weight parts of a non-crystalline ethylene-propylene copolymer.
    Type: Grant
    Filed: September 10, 1981
    Date of Patent: May 1, 1984
    Assignee: Asahi-Dow Limited
    Inventors: Kunio Fukuda, Kichiya Tazaki, Akihisa Takano, Yuji Kusumi
  • Patent number: 4433031
    Abstract: Wood is preserved with a water-based treating solution containing a halogenated phenol wood preservative such as pentachlorophenol, a phenolic resin prepolymer such as a phenol formaldehyde prepolymer, and a coupling or solubilizing agent for enhancing the water compatibility of the various ingredients. The treatment is carried out by exposing the wood, while submerged in the treating solution, so one or more cycles of reduced pressure (i.e. vacuum) and elevated pressure.
    Type: Grant
    Filed: May 5, 1983
    Date of Patent: February 21, 1984
    Assignee: Cherokee Industries, Inc.
    Inventor: William R. Allen, Sr.
  • Patent number: 4433071
    Abstract: Polyurethane foams prepared from the reaction of polyester polyol with organic isocyanate have improved flame retardance and dripping ember retardance by incorporation of an additive comprising (1) halogenated flame retardant, and (2) water or alcohol soluble urea-formaldehyde resin.
    Type: Grant
    Filed: December 14, 1982
    Date of Patent: February 21, 1984
    Assignee: Stauffer Chemical Company
    Inventor: Gerald Fesman
  • Patent number: 4410648
    Abstract: An organic high polymer composition having an improved flame retarding property which is obtained by incorporating into a flame resistive composition comprising (a) an organic high polymer substance, (b) an organic flame retarder and (c) incombustible active inorganic powder (d) a polyfunctional compound and (e) an organic compound represented by the formula: ##STR1## wherein Z is an oxygen atom or a sulfur atom, A is a C.sub.2 -C.sub.20 divalent hydrocarbon group having or not substituents and forming a ring together with the adjacent two carbon atoms and B, and B is an oxygen atom or an amino group: --NY-- (Y being a hydrogen atom, a halogen atom or an organic group having not more than 30 carbon atoms) or its hydrolyzate.
    Type: Grant
    Filed: August 17, 1981
    Date of Patent: October 18, 1983
    Assignee: Dainichi-Nippon Cables, Ltd.
    Inventors: Hiroshi Kato, Chiaki Momose
  • Patent number: 4404305
    Abstract: Translucent polyorganosiloxane resin compositions exhibiting acceptable levels of flame retardancy contain from 1 to 10%, based on resin weight, of an organic halogen source in combination with finely divided glass particles. Translucent substrates coated with these resin compositions can be used in the exterior portions of buildings intended to be heated at least in part by solar energy.
    Type: Grant
    Filed: February 16, 1982
    Date of Patent: September 13, 1983
    Assignee: Dow Corning Corporation
    Inventor: Beth I. Gutek
  • Patent number: 4399195
    Abstract: Wood is preserved with a water-based treating solution containing a halogenated phenol wood preservative such as pentachlorphenol, a phenolic resin prepolymer such as a phenol formaldehyde prepolymer, and a coupling or solubilizing agent for enhancing the water compatibility of the various ingredients. The treatment is carried out by exposing the wood, while submerged in the treating solution, so one or more cycles of reduced pressure (i.e. vacuum) and elevated pressure.
    Type: Grant
    Filed: August 24, 1981
    Date of Patent: August 16, 1983
    Assignee: Cherokee Industries, Inc.
    Inventor: William R. Allen, Sr.
  • Patent number: 4396698
    Abstract: A loaded polymer latex composition is disclosed. The composition comprises an aqueous polymer latex whose dispersed phase is made up of a specified cross-linked quaternary salt polymer loaded with a specified hydrophobic substance. The latex composition can be advantageously employed as a mordant polymer in a photographic element for a color diffusion transfer process. Use of the latex improves light resistance without lowering the maximum densities of the film images.
    Type: Grant
    Filed: June 8, 1982
    Date of Patent: August 2, 1983
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yukio Karino, Masakazu Morigaki, Shinji Sakaguchi
  • Patent number: 4391844
    Abstract: Coatings made from soluable cross-linkable elastomers are shown. Particularly, techniques for solution cross-linking perfluorocarbon copolymers to generate resistant coatings for lining and coating applications are disclosed.
    Type: Grant
    Filed: June 26, 1981
    Date of Patent: July 5, 1983
    Assignee: Diamond Shamrock Corporation
    Inventors: Stanley K. Baczek, G. Howard McCain, Leo L. Benezra, Michael J. Covitch
  • Patent number: 4366279
    Abstract: A flame retardant polycarbonate resin composition comprising a polycarbonate resin, a nuclear substituted benzoic acid containing at least one substituent selected from the group consisting of thiosalicylic acid and dihydroxy benzoic acid, and tetrabromobisphenol A or ##STR1## .
    Type: Grant
    Filed: August 19, 1981
    Date of Patent: December 28, 1982
    Assignee: Idemitsu Kosan Company Limited
    Inventors: Tatsuya Tomioka, Norio Ogata
  • Patent number: 4355126
    Abstract: The present invention provides novel flame retardant, non-dripping thermoplastic molding compositions of polyphenylene ether resins or acrylonitrile-butadiene-styrene copolymers which include a flame retardant agent, and polytetrafluoroethylene.
    Type: Grant
    Filed: February 26, 1979
    Date of Patent: October 19, 1982
    Assignee: General Electric Company
    Inventors: William R. Haaf, Donald L. Reinhard