Polyhydric Aryl-oh Compound Patents (Class 524/345)
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Patent number: 9441081Abstract: The present invention relates to methods for making cross-linked, oxidatively stable, and highly crystalline polymeric materials. The invention also provides methods of treating irradiation-cross-linked antioxidant-containing polymers and materials used therewith.Type: GrantFiled: March 3, 2008Date of Patent: September 13, 2016Assignees: The General Hospital Corp., Cambridge Polymer Group, Inc.Inventors: Orhun K. Muratoglu, Stephen H. Spiegelberg
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Patent number: 9028942Abstract: The present invention is to provide a fluoroelastomer composition which can suppress generation of unvulcanized portions even when a quaternary phosphonium salt is used as a vulcanization accelerator. Specifically, the present invention is a fluoroelastomer composition containing a polyol-crosslinkable fluoroelastomer, a polyhydroxy aromatic compound, a quaternary phosphonium salt, a divalent metal oxide and/or divalent metal hydroxide and an antioxidant.Type: GrantFiled: August 11, 2011Date of Patent: May 12, 2015Assignee: Daikin Industries, Ltd.Inventor: Hiroyuki Tanaka
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Patent number: 8604113Abstract: The photosensitive resin composition of the present invention includes an alkali solubility resin including molecules each composed of a main chain having one end and the other end opposite to the one end, an organic group bonded to the one end thereof, the organic group having at least one unsaturated group, and a substituent group bonded to at least one of the other end of the main chain and a branch thereof, the substituent group having a cyclic chemical structure containing nitrogen atoms, and a photosensitive agent. Further, the insulating film of the present invention is composed of a cured product of the above photosensitive resin composition. Furthermore, the protective film of the present invention is composed of a cured product of the above photosensitive resin composition. Moreover, the Electronic equipment of the present invention is provided with the above protective film and insulating film.Type: GrantFiled: November 13, 2007Date of Patent: December 10, 2013Assignee: Sumitomo Bakelite Co., Ltd.Inventor: Hideyuki Toyoda
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Publication number: 20130072602Abstract: The present invention relates to a process for the preparation of polyether carbonate polyols by catalytic copolymerization of carbon dioxide (CO2) with alkylene oxides in the presence of one or more H-functional starter substances with the aid of double metal cyanide (DMC) catalysts and in the presence of additives A) chosen from the group consisting of sterically non-hindered phenols, catechols, pyrocatechols, thiazines, phenothiazines, thiazoles, benzothiazoles, oxazines, phenoxazines, 2,2,6,6-tetramethylpiperidine 1-oxyl and nitrostyrenes and optionally in the presence of metal salts B).Type: ApplicationFiled: March 24, 2011Publication date: March 21, 2013Applicant: BAYER INTELLECTUAL PROPERTY GMBHInventors: Christoph Gürtler, Jörg Hofmann, Thomas Ernst Müller, Aurel Wolf, Stefan Grasser, Burkhard Köhler
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Patent number: 8349965Abstract: A fluororubber composition according to the present invention contains 0.1 to 3 parts by weight of a polyol compound, 0.1 to 4 parts by weight of a peroxide crosslinking agent, and 1 to 9 parts by weight of a co-crosslinking agent per 100 parts by weight of a peroxide-crosslinkable fluoropolymer. A crack-resistant seal according to the present invention contains a crosslinked fluoropolymer and a polyol compound. The crack-resistant seal according to the present invention can be formed by crosslinking the fluororubber composition, and the resultant crack-resistant seal has particularly high crack resistance. With the fluororubber composition according to the present invention, a durable crack-resistant seal having high plasma resistance, crack resistance, and compression set and that produces few particles can be formed at low cost.Type: GrantFiled: March 12, 2009Date of Patent: January 8, 2013Assignee: Nippon Valqua Industries, Ltd.Inventors: Masanori Okazaki, Naoki Ohsumi
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Patent number: 8273847Abstract: A medical adhesive comprises a hydrophilic urethane prepolymer (UP) obtained by reacting a fluorine-containing nonaromatic polyisocyanate component (A) and a polyol component (B) having a hydrophilic polyol (B1), and a phenolic radical scavenger (PRS). The content of (PRS) is preferably 0.01 to 3% by weight based on the weight of (UP). The content of oxyethylene groups in (B) is preferably 30 to 100% by weight based on the weight of the oxyalkylene groups in (B). Preferably, (B) is a mixture of a random copolymer obtained by addition of ethylene oxide and propylene oxide to diols and polypropylene glycol. The content of isocyanate groups in the medical adhesive is 1 to 10% by weight based on the weight of (UP). The medical adhesive is suitable for bonding body tissues, such as lung, artery and heart in particular.Type: GrantFiled: March 23, 2005Date of Patent: September 25, 2012Assignee: Sanyo Chemical Industries, LtdInventors: Tetsuji Yoshimura, Tetsuya Yamada, Takehisa Matsuda
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Patent number: 8247505Abstract: The present invention provides a process for preparing a fluorine-containing elastomer in a high productivity comparable to that of non-iodine transfer polymerization process by carrying out an iodine transfer polymerization at high pressure. The present invention also provides a fluorine-containing elastomer prepared by this process, and fluorine-containing molded articles. The process is a batch copolymerization process conducted under conditions that the reduced temperature of the critical constant is at least 0.95 and the reduced pressure of the critical constant is at least 0.Type: GrantFiled: August 27, 2007Date of Patent: August 21, 2012Assignee: Daikin Industries, Ltd.Inventors: Yousuke Nishimura, Masaki Irie, Sadashige Irie, Manabu Fujisawa, Satoshi Tokuno, Mitsuru Kishine
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Publication number: 20110262637Abstract: The invention relates to a one component heat curable powder coating composition comprising a resin containing reactive unsaturations and wherein all said reactive unsaturations are carbon carbon double bonds connected directly to an electron withdrawing group, a thermal initiation system comprising a peroxide chosen from the group of compounds represented by formula (1), wherein R1 and R2 each independently stand for an optionally substituted alkyl of 1 to 30 C-atoms, wherein the 1 to 30 C-atoms do not include the C-atoms of the substituents or for an optionally substituted aryl of 6 to 18 C-atoms, wherein the 6 to 18 C-atoms do not include the C-atoms of the substituents, and a co-crosslinker chosen from the group of vinylethers, vinyletherurethanes, vinylesters, vinylamides, itaconates, enamines, vinylureas and mixtures thereof.Type: ApplicationFiled: November 6, 2009Publication date: October 27, 2011Inventors: Johan F.G.A. Jansen, Jan Pieter Drijfhout
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Patent number: 8034861Abstract: Golf balls consisting of a core and a cover are disclosed. The core is a solid, single-layer core formed from a rubber composition comprising a catechol. The core has a positive hardness gradient such that the difference between the core's surface hardness and the core's center hardness is 25 Shore C units or greater and/or the core has a diameter of from 1.51 inches to 1.59 inches.Type: GrantFiled: July 8, 2008Date of Patent: October 11, 2011Assignee: Acushnet CompanyInventors: Brian Comeau, David A. Bulpett, Douglas S. Goguen, Derek A. Ladd
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Patent number: 8030385Abstract: Golf balls comprising a core and a cover are disclosed. The core is a dual- or multi-layer core, wherein at least one layer is formed from a rubber composition comprising a base rubber and a catechol. The core layer formed from such rubber composition has a positive hardness gradient such that the difference between the layer's outer surface hardness and inner surface hardness is 5 Shore C units or greater.Type: GrantFiled: July 8, 2008Date of Patent: October 4, 2011Assignee: Acushnet CompanyInventors: Brian Comeau, David A. Bulpett, Douglas S. Goguen, Derek A. Ladd
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Publication number: 20100261821Abstract: A dispersible carbon nanotube (“CNT”) comprising a CNT backbone and an organic moiety attached to the carbon nanotube backbone and comprising a hydroxyl substituted C6 to C14 aromatic group are described, as well as a CNT-polymer composite and a method of manufacturing the CNT-polymer composite.Type: ApplicationFiled: October 13, 2009Publication date: October 14, 2010Applicants: SAMSUNG ELECTRONICS CO., LTD., KOREA ADVANCED INSTITUTE OF SCIENCE AND TECHNOLOGYInventors: Jong-jin PARK, Tae-gwan PARK, Yu-han LEE, Kwang-hee LEE
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Publication number: 20100178502Abstract: A composition comprises (a) a binder component which comprises (1) 5 to 100 weight percent of at least one natural oil derived polyol having at least about 50 percent primary hydroxyl groups and (2) sufficient additional polyol different from a natural oil derived polyol to make 100 percent wherein the natural oil derived polyol has an average of from 1.5 to 3 hydroxyl groups per molecule and an equivalent weight of from 200 to 5000; and (b) a crosslinking component reactive with hydroxyl groups.Type: ApplicationFiled: April 10, 2008Publication date: July 15, 2010Inventors: Gary E. Spilman, John N. Argyropoulos, Debkumar Bhattacharjee, Paul J. Popa, William A. Koonce
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Patent number: 7671123Abstract: A fluororesin aqueous dispersion comprising from 20 to 70 mass % of microparticles of a fluororesin and from 1 to 12 mass %, based on the mass of the fluororesin, of a non-ionic surfactant represented by the formula (1): R1—O-A-X??(1) wherein R1 is a C6-18 alkyl group, O is an oxygen atom, A is a polyoxyalkylene group comprising from 1 to 3 oxybutylene groups and from 5 to 20 oxyethylene groups, and X is a hydrogen atom or a methyl group.Type: GrantFiled: July 12, 2007Date of Patent: March 2, 2010Assignee: Asahi Glass Company, LimitedInventors: Jun Hoshikawa, Shinya Higuchi, Yasuhiko Matsuoka, Nobuyuki Yamagishi
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Patent number: 7544730Abstract: The present invention is directed to a golf ball having at least one layer formed from a rubber composition comprising a base rubber, a free radical initiator, and a catechol. The present invention is also directed to a golf ball having at least one layer formed from a rubber composition comprising a base rubber, a free radical initiator, and a resorcinol. Rubber compositions of the present invention may be present in any one or more of a core layer, a cover layer, or an intermediate layer.Type: GrantFiled: March 7, 2006Date of Patent: June 9, 2009Assignee: Acushnet CompanyInventors: Brian Comeau, David A. Bulpett, Douglas S. Goguen
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Patent number: 7439291Abstract: A solvent-resistant polymeric membrane comprising a solvent-inert polymer having a solubility parameter greater than 18 (J/cm3)0.5, such as a polyketone, a polyether ketone, polyarylene ether ketone ketone, a polyimide, a polyetherimide, or a polyphenylene sulfide, is described. The solvent-resistant polymeric membrane can be prepared by methods in which solvent-inert polymers form a solution at room temperature.Type: GrantFiled: September 14, 2005Date of Patent: October 21, 2008Assignee: General Electric CompanyInventors: Hua Wang, Anatoli Kogan, Jared Paul Ray, Gary William Yeager
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Publication number: 20080226584Abstract: The present invention relates to a substrate having one or more antimicrobial or antistatic properties. Such properties are imparted by applying a coating or film formed from a cationically-charged polymer composition. The polymer composition includes a noncationic ethylenically unsaturated monomer and an ethylenically unsaturated monomer capable of providing a cationic charge to the polymer composition. Optionally, the polymer composition includes a steric stabilization component incorporated into the cationically-charged polymer composition. The present invention also relates to a personal care product and polymeric material comprising a base polymer blended with the above cationically-charged polymer composition.Type: ApplicationFiled: May 6, 2008Publication date: September 18, 2008Inventor: Venkataram Krishnan
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Publication number: 20080171807Abstract: A two-component reaction resin includes a resin component (A), which contains, as curable constituent (a), at least one free radical-curable, ethylenically unsaturated compound, an agent (b) for adjusting the reactivity and the gel time and at least one comonomer (c) and a curing component (B), which is disposed separate therefrom to inhibit any reaction and is a curing agent for the resin of the resin component (A) and which, as agent (b) for adjusting the reactivity and the gel time, contains a pyrocatechol derivative of the general Formula (I):Type: ApplicationFiled: December 19, 2007Publication date: July 17, 2008Inventors: Emin Memet Kumru, Thomas Buergel, Armin Pfeil
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Patent number: 7375171Abstract: The present invention provides a process for preparing a fluorine-containing elastomer in a high productivity comparable to that of non-iodine transfer polymerization process by carrying out an iodine transfer polymerization at high pressure. The present invention also provides a fluorine-containing elastomer prepared by this process, and fluorine-containing molded articles. The process is a batch copolymerization process conducted under conditions that the reduced temperature of the critical constant is at least 0.95 and the reduced pressure of the critical constant is at least 0.80 wherein the reduced temperature and the reduced pressure are calculated using the Peng-Robinson formula from the critical temperature, the critical pressure and the composition ratio of each of the monomers in the gaseous phase in a reaction vessel, in which ethylenically unsaturated compounds containing at least one fluoroolefine are copolymerized in the presence of a compound having the formula: Rf1.Type: GrantFiled: January 22, 2004Date of Patent: May 20, 2008Assignee: Daikin Industries, Ltd.Inventors: Yousuke Nishimura, Masaki Irie, Sadashige Irie, Manabu Fujisawa, Satoshi Tokuno, Mitsuru Kishine
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Patent number: 7129311Abstract: An organohydrosiloxane composition comprising: a) one or more organohydrosiloxane compounds, each having at least one [—HSiR—O—] unit, wherein R?C1–C18 linear, branched, or cyclic alkyl, C1–C18 linear, branched, or cyclic alkoxy, or substituted or unsubstituted aryl, and b) an antioxidant compound shown in Formula (1) ?wherein the antioxidant compound is a phenolic compound and is present in a concentration from about 1 ppm to about 5,000 ppm and wherein R1 through R5 can each independently be H, OH, C1–C18 linear, branched, or cyclic alkyl, C1–C18 linear, branched, or cyclic alkoxy or substituted or unsubstituted aryl. The compositions of present invention exhibit stability and significantly extend the shelf life of organohydrosiloxane products and allow greater flexibility in handling these products in chemical processes or semiconductor manufacturing. The resulting stabilization of siloxanes prevents the possibility of complete polymerization (i.e.Type: GrantFiled: September 18, 2003Date of Patent: October 31, 2006Assignee: Arch Specialty Chemicals, Inc.Inventors: Daniel J. Teff, Gregory B. Smith, John L. Chagolla, Tim S. Andreyka
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Patent number: 7067595Abstract: A curable composition includes a functionalized poly(arylene ether), an olefinically unsaturated monomer, about 0.2 to about 5 parts by weight of a curing initiator per 100 parts by weight total of the functionalized poly(arylene ether) and the olefinically unsaturated monomer, and about 0.005 to about 1 part by weight of a curing inhibitor per 100 parts by weight total of the functionalized poly(arylene ether) and the olefinically unsaturated monomer. The weight ratio of the curing initiator to the curing inhibitor is about 1.2:1 to about 50:1. The composition provides improved and reproducible flow during the early stages of molding without compromising curing time. The composition is useful for preparing plastic-packaged electronic devices.Type: GrantFiled: October 3, 2003Date of Patent: June 27, 2006Assignee: General Electric CompanyInventors: Kenneth Paul Zarnoch, John Robert Campbell, Glen David Merfeld, John Austin Rude, Prameela Susarla, Michael Alan Vallance, Gary William Yeager
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Patent number: 6828374Abstract: A molding material comprises at least the following components A, B and C, with the component C arranged to contact a composite comprising the components A plus B. The components are elongated members identified as: A A continuous reinforcing fiber bundle, B A thermoplastic polymer or oligomer having a weight average molecular weight of 200 to 50,000 and a melt viscosity lower than that of the component C, and C A thermoplastic resin having a weight average molecular weight of 10,000 or more.Type: GrantFiled: September 18, 2001Date of Patent: December 7, 2004Assignee: Toray Industries, Inc.Inventors: Soichi Ishibashi, Tetsuyuki Kyono
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Patent number: 6809137Abstract: A rubber composition having excellent heat resistance and a pneumatic tire produced by using this rubber composition are provided. The rubber composition has, in a curve exhibiting a change in dynamic storage modulus during elevation of temperature, an intersection of an extrapolation line of a portion in which the dynamic storage modulus is approximately constant before rapidly decreasing at temperatures higher than 100° C. and an extrapolation line of a portion in which the dynamic storage modulus rapidly decreases, at a temperature of 170° C. or higher.Type: GrantFiled: June 7, 1999Date of Patent: October 26, 2004Assignee: Bridgestone CorporationInventors: Kenji Matsuo, Masahiro Hojo, Tomohisa Nishikawa, Kazuomi Kobayashi
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Patent number: 6777473Abstract: Compositions comprising one or more olefin polymers functionalized by at least one functionalization agent chosen from carboxylic acids, their esters, their anhydrides and their metal salts and one or more stabilizing agents comprising one or more sterically hindered phenol groups and at most one ester functional group. Process for their preparation and use of these compositions for compatibilizing olefin polymers with polymers, fillers and metal substrates which are incompatible with olefin polymers.Type: GrantFiled: October 29, 2001Date of Patent: August 17, 2004Assignee: Solvay Polyolefins Europe-Belgium (Societe Anonyme)Inventors: Marie-Paule Collard, Henri Wautier, Eric Fassiau, Eric Vandevijver
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Patent number: 6646042Abstract: Provided is a coating composition for damping purposes, capable of forming the thin film applicable to damping and sound absorption at a vibration- or sound-generation section of complex shape, which comprises the following coating components (i), (ii) and (iii): (i) a resin emulsion containing a polar group capable of forming the coating film containing the hydrogen bond which is formed when the polar group comes into contact with an aromatic compound as the following coating component (ii) having the hydrogen bond forming effect, (ii) an aromatic compound which has the effect of forming and controlling the hydrogen bond, and also has at least one hydroxyl group in the molecule, and (iii) an inorganic filler, and also provides a method for producing the same. Also a method of producing the coating composition is provided.Type: GrantFiled: July 6, 2001Date of Patent: November 11, 2003Inventors: Guozhang Wu, Tetsuya Ito, Masao Sumita
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Publication number: 20030130392Abstract: A rubber composition having excellent heat resistance and a pneumatic tire produced by using this rubber composition are provided.Type: ApplicationFiled: June 7, 1999Publication date: July 10, 2003Inventors: KENJI MATSUO, MASAHIRO HOJO, TOMOHISA NISHIKAWA, KAZUOMI KOBAYASHI
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Patent number: 6528562Abstract: A fluoropolyether rubber composition comprising (A) a linear fluoropolyether compound containing at least two alkenyl groups and having a perfluoroalkyl ether structure in its backbone, (B) an organosilicon compound having at least two silicon atom-bound hydrogen atoms which all form H—Si(CaH2a)Si structures wherein “a” is 1, 2 or 3, (C) a hydrosilylation catalyst, and (D) an antidegradant, typically an aromatic secondary amine compound is curable into products having heat resistance, chemical resistance, solvent resistance, parting property, water repellency, oil repellency, and weather resistance as well as resistance to acid, alkali and oxidative degradation.Type: GrantFiled: July 10, 2001Date of Patent: March 4, 2003Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Takashi Matsuda, Shinichi Sato, Noriyuki Koike
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Patent number: 6136902Abstract: To provide a polyacetal resin composition having an excellent corrosion inhibiting effect on metals, particularly reduced in the adverse effect on magnetic tapes or the like, and suitable for use in producing component parts of a magnetic tape cassette such as a reel hub or tape guide, 100 parts by weight of a polyacetal resin (A) is blended with 0.05 to 5 parts by weight of an antioxidant (B), 0.001 to 5 parts by weight of a specified nitrogen-containing compound (C), and 0.001 to 3 parts by weight of a boric acid compound.Type: GrantFiled: June 18, 1997Date of Patent: October 24, 2000Assignee: Polyplastics Co., Ltd.Inventors: Yoshihito Fukasawa, Sachio Anada
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Patent number: 5981073Abstract: Novel dibenzoylresorcinol-based compounds are disclosed wherein the dibenzoylresorcinol is bonded to the residue of either an alcohol or a carboxylic acid group, via a methylene carboxylate linking group; and wherein the dibenzoylresorcinol is bonded directly to a substituted or unsubstituted aryl group which does not include a pendent hydroxyl group. The groups attached to the dibenzoylresorcinol may contain a wide variety of functional sites which permit further reaction, e.g., copolymerization. The described compounds are very useful as UV light absorbers and may be used to form improved coating compositions which usually include a transparent, polymeric matrix material. The coating compositions may be applied to various substrates, e.g., thermoplastics, to afford a selection of enhanced properties, such as UV light resistance and abrasion resistance.Type: GrantFiled: January 16, 1997Date of Patent: November 9, 1999Assignee: General Electric CompanyInventors: James Edward Pickett, Wen P Liao, Amy Kathleen Simonian, Gregory Ronald Gillette
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Patent number: 5929147Abstract: An embrittlement-resistant polyolefin composition, including: (a) at least 80% by weight, based on the total weight of the polyolefin composition, of a crystalline polymer comprising either a propylene homopolymer having an isotactic index greater than 90 or a random copolymer of propylene and either ethylene or C.sub.4 -C.sub.10 1-olefins, (b) an elastomeric copolymer of ethylene and either propylene or butene-1, where the elastomeric copolymer is present in an amount sufficient to enhance the flexibility of the polyolefin composition, without adversely affecting the clarity of the polyolefin composition, and where the polyolefin composition has a heat distortion temperature of at least 60.degree. C. Optional components include a stabilizing amount of a hindered amine light stabilizer, an acid neutralizing agent, and a sorbitol-based compound. The composition may be used to manufacture medical articles and food packaging material which must be sterilized, either by irradiation or by autoclaving.Type: GrantFiled: June 18, 1996Date of Patent: July 27, 1999Assignee: Montell North America Inc.Inventors: David E. Pierick, Thomas J. O'Neal
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Patent number: 5869185Abstract: A polycarbonate substrate coated with an acrylic coating containing at least one polybenzoylresorcinol, and optionally a silicone hardcoat on the acrylic coating, wherein said at least one polybenzoylresorcinol has the formula ##STR1## wherein each A is independently a substituted or unsubstituted monocyclic aromatic radical wherein any substituents are hydrogen, halogen, alkoxy, C.sub.1-8 alkyl, or hydroxy, and R is hydrogen or a linear or branched aliphatic radical having less that about 10 carbon atoms.Type: GrantFiled: June 21, 1996Date of Patent: February 9, 1999Assignee: General Electric CompanyInventors: Steven Roger Bahr, James Edward Pickett, Karen Kueck Webb
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Patent number: 5700861Abstract: A fluororubber coating composition which contains (a) a fluororubber having a --CH.sub.2 -- group in a backbone; (b) a fluoropolyether fluorooil having a functional group capable of chemically bonding to the fluororubber (a) upon heating; (c) a vulcanizing agent and optionally vulcanizing aid; and (d) a medium. When the composition is applied to a substrate and calcined, permanent non-tackiness can be imparted to the substrate surface without impairing the characteristics of the fluororubber, such as elasticity, and the heat and chemical resistance.Type: GrantFiled: September 14, 1995Date of Patent: December 23, 1997Assignee: Daikin Industries Ltd.Inventors: Nobuyuki Tomihashi, Kiyotaro Terasaka
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Patent number: 5688863Abstract: A thermoplastic polyurethane urea prepared by reacting a reaction mixture ofa) one or more polyisocyanates, withb) one or more compounds having on average at least 1.8 Zerewitinoff-active hydrogen atoms and a molecular weight of between 400 and 10,000, andc) water,wherein the water is introduced into the reaction mixture with the aid of an effective quantity of one or more emulsifiers. The reaction mixture may additionally contain d) further conventional auxiliary substances and additives.Type: GrantFiled: January 5, 1996Date of Patent: November 18, 1997Assignee: Bayer AktiengesellschaftInventors: Stephan Kirchmeyer, Hanns-Peter Muller, Hans-Georg Wussow, Bodo Rehbold
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Patent number: 5571854Abstract: A phenolic resin molding material for molding at lower than normal pressures, comprising as resin components a combination of (A) a crystalline phenolic compound having two or more hydroxyphenyl groups and (B) a compound having two or more hydroxyl groups in the benzene ring, or (A), (B) and (C) a phenolic resin.Type: GrantFiled: November 15, 1994Date of Patent: November 5, 1996Assignee: Sumitomo Bakelite Company LimitedInventors: Tamotsu Ishida, Tsukasa Sakamoto, Hidenori Saito
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Patent number: 5476894Abstract: The invention relates to an improved color paste for the manufacture of internally printed, curved laminated glass panes.Prior art color pastes cause problems with respect to adhesion and optical accuracy or require a higher technical complexity during the baking process for producing internally printed laminated glass panes.Color pastes which constitute the invention and overcome the previous drawbacks are characterized by a print medium which contains 5,6,8-trihydroxy-1,4-naphthoquinone in addition to solvents.Type: GrantFiled: November 4, 1994Date of Patent: December 19, 1995Assignee: Cerdec Aktiengesellshcaft Keramische FarbenInventor: Adalbert Huber
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Patent number: 5470901Abstract: A polyphenylene sulfide resin composition comprising 100 parts by weight of a polyphenylene sulfide resin and 0.5 to 50 parts by weight of a crosslinked fluorine-containing elastomer, which has improved impact resistance while keeping excellent properties of the polyphenylene sulfide resin.Type: GrantFiled: January 23, 1995Date of Patent: November 28, 1995Assignee: Daikin Industries, Ltd.Inventors: Kazuo Ishiwari, Yoshihisa Yamamoto, Tetsuo Shimizu
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Patent number: 5434208Abstract: The invention relates to an optically non-linear active waveguiding material comprising an optically transparent polymer and a non-linear optical dopant comprising more than one donor-.pi.-acceptor unit.Dopants comprising more than one donor-.pi.-acceptor unit, especially dopants in which the donor-.pi.-acceptor units are positioned in a cyclic group, have a high hyperpolarizability and a charge-transfer absorption band wavelength which is about the same as that of dopants with only one donor-.pi.-acceptor unit.Especially suitable dopants for use are calix(4)arenes. These are provided with acceptor groups at the upper rim and with donor groups at the lower rim. In addition to having excellent hyperpolarizability, these compounds were found to be readily soluble in host polymers, such as polymethylene (meth) acrylate and polystyrene.Type: GrantFiled: July 7, 1993Date of Patent: July 18, 1995Assignee: Akzo Nobel N.V.Inventors: Jan G. Batelaan, Johannes F. J. Engbersen, Erik Kelderman, David N. Reinhoudt, Willem Verboom
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Patent number: 5290838Abstract: A novel neopentyl .alpha.-cyanoacrylate composition is provided. The composition which includes neopentyl .alpha.-cyanoacrylate has superior adhesive properties even at high temperatures and is characterized by the absence of the whitening phenomenon.Type: GrantFiled: September 11, 1992Date of Patent: March 1, 1994Assignee: Three Bond Co., Ltd.Inventors: Hiroyuki Mikuni, Toshiyuki Chikusa
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Patent number: 5286772Abstract: A polyolefin composition is disclosed comprising polyolefin with a synergistic antioxidant composition of a phenolic oxidation inhibitor and synergist capable of reacting with the phenoxyl radicals to form a phenolic group and regenerate the phenolic oxidation inhibitor. In a preferred embodiment of the invention, the synergist also acts as a metal-complexing agent capable of complexing with trace transition-metal-ions contaminants in the polyolefin.Type: GrantFiled: November 27, 1992Date of Patent: February 15, 1994Assignee: The University of UtahInventor: Natalya Rapoport
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Patent number: 5214087Abstract: Polyvinyl halide-EVOH polymer compositions exhibiting a reduced tendency to stick to metal surfaces, and in particular, to chrome surfaces are described which comprise(A) at least one vinyl halide polymer;(B) from 1 to about 40% based on the weight of the vinyl halide polymer, of at least one ethylene-vinyl alcohol copolymer; and(C) from about 0.01 to about 5 phr of at least one phenolic antioxidant of the formula ##STR1## wherein R.sub.1 is hydrogen, or a hydroxyl or an alkyl group; R.sub.2 is an alkyl, alkoxy or a carboxylic ester group; and R.sub.3 is a hydroxy or an alkyl group.An improved process for melt blending mixtures comprising vinyl halide polymers and ethylene-vinyl alcohol copolymers on metal-surfaced compounding equipment is described which comprises adding to the mixture prior to melt blending, from about 0.01 to about 5 phr of the phenolic antioxidant described above.Type: GrantFiled: March 26, 1990Date of Patent: May 25, 1993Assignee: The B. F. Goodrich CompanyInventors: Thomas C. Braden, Sally A. Kline
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Patent number: 5166246Abstract: Polyphenylene ether- polyamide compositions having improved resistance to water absorption and swell are provided by incorporating therein a phenolic compound.Type: GrantFiled: April 5, 1989Date of Patent: November 24, 1992Assignee: General Electric CompanyInventors: Robert R. Gallucci, John A. Rock
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Patent number: 5162414Abstract: Interpenetrating polymer network composition, of shaped solid polyester material, e.g. new or reused polyester containing particles, sheeting, fiber or fiber fabric, in a matrix of curable prepolymer resin, e.g. a thermosetting phenol-aldehyde resin of basic pH for providing a flame retardant composition, an interfacial dissolving agent for the polyester material, e.g. an aromatic alcohol and/or a halohydrocarbon, optionally an accelerator for the resin, e.g. a weak acid, and optionally a filler, e.g. in a weight ratio of matrix to polyester material of about 0.25-15:1, wherein the polyester material is distributed, e.g.Type: GrantFiled: January 17, 1989Date of Patent: November 10, 1992Assignee: Industrial Technology Research InstituteInventors: Jui-Chi Hung, Shih-June Tsai, Shen-Nan Tong, Peter T. K. Wu
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Patent number: 5082885Abstract: Improved thermal stability and melt stability is demonstrated by stabilized compositions comprising a linear alternating polymer of carbon monoxide and at least one ethylenically unsaturated hydrocarbon having incorporated therein a stabilizing quantity of a phenolic compound of defined structure.Type: GrantFiled: August 29, 1990Date of Patent: January 21, 1992Assignee: Shell Oil CompanyInventors: Robert Q. Kluttz, Johannes L. M. Syrier
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Patent number: 5039370Abstract: A mixture of benzyl alcohol and a hydroxy benzene is disclosed, for use in the bonding together of polyamide articles. In one embodiment, the mixture comprises 5 to 50% by weight of benzyl alcohol, 20 to 90% by weight of phenol; and 5 to 30% by weight of polyamide. In another embodiment, the mixture comprises 20 to 60% by weight of a benzyl alcohol, 20 to 60% by weight of ortho-dihydroxy benzene and 20 to 60% by weight of a lower alcohol having one to four carbon atoms. The mixture may be applied to a polyamide article, which may then be contacted with a second polyamide article and heated to effect bonding. In another embodiment, a pattern of the mixture may be applied, for instance on a polyamide film, the pattern corresponding to the bonds required in the polyamide article being manufactured. For example, the composition may be used to bond film or sheet together so as to form fluid flow passages therebetween e.g. as in a heat exchanger.Type: GrantFiled: February 12, 1990Date of Patent: August 13, 1991Inventor: Anthony J. Cesaroni
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Patent number: 4997857Abstract: A stabilizer for polymer/polyols characterized by four key features: (1) prepared from a starting polyol having a functionality greater than 4; (2) having at least 60% retained unsaturation; (3) having a viscosity greater than 2000 cSt; and (4) prepared where the starting polyol is capped with alkylene oxide and/or the adduct formed between the starting polyol and the reactive unsaturated compound is capped with ethylene oxide.Type: GrantFiled: September 30, 1986Date of Patent: March 5, 1991Assignee: Arco Chemical Technology, Inc.Inventors: John F. Timberlake, Siusun K. Leung, Edgar G. Shook, Donald W. Simroth, Richard C. Myerly
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Patent number: 4970272Abstract: Polyphenylene ether-polyamide compositions having improved resistance to water absorption and swell are provided by incorporating therein a phenolic compound.Type: GrantFiled: January 27, 1989Date of Patent: November 13, 1990Assignee: General Electric CompanyInventor: Robert R. Gallucci
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Patent number: 4935462Abstract: A mixture of benzyl alcohol and hydroxy benzene is disclosed, for use in the bonding together of polyamide articles. In embodiments, the mixture comprises 5 to 50% by weight of benzyl alcohol, 20 to 90% by weight of phenol and 5 to 30% by weight of polyamide. In other embodiments, the mixture comprises 20 to 60% by weight of benzyl alcohol, 20 to 60% by weight of ortho-dihydroxy benzene and 20 to 60% by weight of a lower alcohol having one to four carbon atoms. The mixture may be applied to a polyamide article, which may then be contacted with a second polyamide article and heated to effect bonding. In embodiments, the mixture may be applied in a pattern e.g. to polyamide in the form of film, so that a polyamide structure having a similar pattern of bonds may be obtained. For example, the composition may be used to bond film or sheet together so as to form fluid flow passages therebetween e.g. as in a heat exchanger.Type: GrantFiled: April 6, 1988Date of Patent: June 19, 1990Inventor: Anthony J. Cesarino
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Patent number: 4894398Abstract: A method for stabilizing an unsaturated organosilicone is disclosed wherein a stabilizing amount of a hydroxylamine compound is added to the organosilicone to prevent thermal polymerization of the latter. The organosilicone may be an alkoxysilane or an organopolysiloxane having in its molecule a reactive organic group bearing at least one radical selected from acryloxy, methacryloxy, acrylamide, methacrylamide, styryl or vinylbenzyl radicals. The hydroxylamine compound may be added either to the organosilicone or during the preparation of the alkoxysilane from its respective reactants.Type: GrantFiled: September 19, 1988Date of Patent: January 16, 1990Assignee: Dow Corning CorporationInventor: Howard M. Bank
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Patent number: 4886849Abstract: A composition consisting essentially of a blend of about 60 to 75% by weight of an isotactic butene-1 homopolymer with a melt index of more than 100 to 1000, about 23.5 to 39.88% by weight of stabilized propylene polymer, and about 0.02 to 1.5% by weight of high density polyethylene, and optionally, up to 0.1 to 1% of a mold release agent and articles prepared therefrom.Type: GrantFiled: February 27, 1989Date of Patent: December 12, 1989Assignee: Shell Oil CompanyInventors: Charles C. Hwo, Patrick M. Hughes
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Patent number: 4851462Abstract: A solvent based contact adhesive suitable for bonding cured EPDM membranes is disclosed. The adhesive includes a crosslinked halogenated butyl rubber, a low molecular weight, high softening point, thermoplastic aliphatic-type-based hydrocarbon resin and at least one organic solvent employed as a dispersion medium for the crosslinked halogenated butyl rubber and the resin. The disclosed adhesive exhibits superior heat aging and hot water immersion properties which are significant characteristics in roof applications.Type: GrantFiled: January 21, 1988Date of Patent: July 25, 1989Assignee: Uniroyal Plastics Company, Inc.Inventors: Chester T. Chmiel, David A. Young
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Patent number: 4724249Abstract: The invention is a rust proofing composition containing a copolymer in latex form derived from:(i) vinylidene chloride(ii) vinyl chloride; and(iii) one or more alkyl acrylates and/or alkyl metharcylates having from 1 to 12 carbon atoms is the alkyl group; anda chelating agent comprising pyrogallol, said pyrogallol being present in an amount between 0.5 and 5.0 percent by weight of said aqueous emulsion.Type: GrantFiled: February 17, 1987Date of Patent: February 9, 1988Assignee: Neutra Rust International LimitedInventor: Daniel C. Roberts