Carbocyclic Ring Wherein One Of The Nuclear Carbons Thereof Is Double Bonded Directly To An Oxygen Atom So As To Form A C=o Group Therewith, E.g., Cyclohexanone, Etc. Patents (Class 524/360)
  • Patent number: 4690962
    Abstract: An electronic circuit having an electrically conductive pattern formed on a substrate and having on at least one surface of the substrate a film obtained from a soluble polymerizable oligomer of the formula: ##STR1## wherein D is ##STR2## wherein M is --C.tbd.C--, --C.tbd.C--C.tbd.C, --O--, ##STR3## wherein R is an alkyl or aromatic group; wherein Ar is an aromatic group; wherein x is an integer greater than two but less than 30, z is either zero or an integer, and y is an integer wtih the sum of y and z equal to x; and wherein n is an integer from 1 to 10. The substrate is coated by applying the above composition to the substrate and then hardening the composition by further polymerization. Preferred compositions contain the above described oligomer and certain plasticizers and/or toughening agents.
    Type: Grant
    Filed: April 7, 1986
    Date of Patent: September 1, 1987
    Assignee: International Business Machines Corporation
    Inventors: Roger J. Clark, James Economy, Mary A. Flandera, John R. Susko, Robin A. Wheater
  • Patent number: 4649067
    Abstract: One-component baking enamels of polyesters, containing hydroxyl groups, and polyisocyanates, wherein the polyisocyanate component consists of 2-methyl-1,5-diisocyanatopentane (MPDI) having the formula (I): ##STR1## which is blocked totally or partially by .epsilon.-caprolactam or acetoxime, or a mixture of the same with 2-ethyl-1,4-diisocyanatobutane (EBDI) having the formula (II): ##STR2## which is blocked totally or partially by .epsilon.-caprolactam or acetoxime, wherein the diisocyanate mixture of (I) and (II) has about 88 to 99% by weight of (I) and about 12 to 1% by weight of (II) and the free isocyanate (NCO) content is up to about 10% by weight.The one-component baking enamels are suitable for application to metal, glass and plastic objects and exhibit excellent flexibility and weather resistance.
    Type: Grant
    Filed: May 24, 1984
    Date of Patent: March 10, 1987
    Assignee: Chemische Werke Huls Aktiengesellschaft
    Inventor: Rainer Gras
  • Patent number: 4642249
    Abstract: The present invention provides a clear lacquer based on polyvinylidene fluoride which comprises:(a) 30 to 45 wt. % of polyvinylidene fluoride with a K value of 40 to 55,(b) 4 to 15 wt. % of an acrylate resin,(c) 33 to 50 wt. % of latent, high boiling solvent,(d) 3 to 15 wt. % of low boiling solvent,(e) 0.01 to 1.0 wt. % of flowing adjuvant,(f) 0.01 to 0.95 wt. % of light protection agent. The present invention also provides a process for coating metallic surfaces, wherein this clear lacquer is applied to a metal surface and stoved at a temperature of from 250.degree. to 350.degree. C.
    Type: Grant
    Filed: April 3, 1986
    Date of Patent: February 10, 1987
    Assignee: Solvay & Cie, Societe Anonyme
    Inventor: Werner Goll
  • Patent number: 4618635
    Abstract: Described herein are compositions comprising the reaction product of a polyol, a multi-functional isocyanate, a lactone-acrylate adduct and an hydroxyalkyl acrylate. These compositions are suitable for use as curable coatings.
    Type: Grant
    Filed: May 17, 1985
    Date of Patent: October 21, 1986
    Assignee: Union Carbide Corporation
    Inventors: Claiborn L. Osborn, Joseph V. Koleske, Kenneth Drake
  • Patent number: 4609703
    Abstract: Novel copolymers of acrylic acid and cyanoethylacrylate, and the use of such copolymers as primers for bonding metal-containing coatings to organic polymer substrates, are disclosed. The copolymers of the present invention may be linear or crosslinked, may further comprise hydroxyethylacrylate, and are preferably of low molecular weight when used in solution as a primer.
    Type: Grant
    Filed: June 5, 1985
    Date of Patent: September 2, 1986
    Assignee: PPG Industries, Inc.
    Inventor: Thomas G. Rukavina
  • Patent number: 4581407
    Abstract: An essentially isocyanate-free polyurethane polyurea polyethylenic oligomer is disclosed which is unusually strong and elastic. This oligomer is the reaction product of: (1) organic diisocyanate; (2) a stoichiometric deficiency of difunctional materials reactive therewith and consisting essentially of: (A) polyoxyalkylene glycol having a molecular weight of from 200 to 1000; (B) dihydric bisphenol-based alkylene oxide adduct containing from 2-10 alkylene groups per molecule; and (C) polyoxyalkylene diprimary amine having a molecular weight of from 150 to 800. In all of these, the alkylene groups contain from 2-4 carbon atoms. Components (A) and (B) are present in a weight ratio of from 1:4 to 9:1 and component (C) is present to supply from 30 to 60 equivalent percent of the total equivalents of component (2). The polyurethane polyurea so-constituted is capped with monohydric ethylenic compound, such as 2-hydroxyethyl acrylate, to provide a molecular weight in the range of about 5,000 to about 30,000.
    Type: Grant
    Filed: February 20, 1985
    Date of Patent: April 8, 1986
    Assignee: DeSoto, Inc.
    Inventor: Steven R. Schmid
  • Patent number: 4501829
    Abstract: A coating composition comprising (A) a polyester resin modified with a lactone having 6 to 8 ring carbon atoms (I) or a mixture of said lactone-modified polyester resin (I) and a non-modified polyester resin (II), the lactone content being from 5 to 40% by weight of the total polyester resin (in solid) (I) or (I+II), the number average molecular weight being 800.about.200 mg KOH/g and wherein the resinous acid value is 2.about.20 mg KOH/g, (B) a crosslinking agent, (C) a pigment and (D) optionally other resins. The composition is useful as an intercoat paint for automobile bodies.
    Type: Grant
    Filed: September 6, 1983
    Date of Patent: February 26, 1985
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Shoji Oda, Kunihiko Ehara, Hirotoshi Umemoto, Shinji Nakano
  • Patent number: 4454276
    Abstract: A polyamide acid composition for preparing a polyimide which can extend the pot life of the composition comprising a solution of a polyamide acid in an organic solvent, the polyamide acid being a precursor of the polyimide, a dehydrating agent, a catalyst and a pot life extending agent which can lower a rate of conversion of the polyamide acid to the polyimide, and the process for preparing the polyimide from said polyamide acid composition. According to the present invention the pot life can be extremely extended to give the composition an enough flowability for a long time without reducing the excellent properties such as a heat resistance and an electric insulation of the obtained polyimide.
    Type: Grant
    Filed: September 29, 1982
    Date of Patent: June 12, 1984
    Assignee: Kanegafuchi Chkagaku Kogyo Kabushiki Kaisha
    Inventors: Junji Uda, Tsuneo Yamamoto, Takumi Kosugi
  • Patent number: 4416925
    Abstract: For the coating of plastics with polyvinylidene fluoride, finely divided polyvinylidene fluoride is dispersed in a solvent mixture of(a) at least one high-boiling, organic solvent with a boiling point up to 250.degree. C., which dissolves polyvinylidene fluoride little or not at all, and(b) at least one strongly polar latent organic solvent for polyvinylidene fluoride, the dispersion obtained is dissolved in(c) at least one low-boiling polar organic solvent with a boiling point up to 120.degree. C., the plastic surface is coated with the solution and the latter is baked on at a temperature of 100.degree. to 300.degree. C.A bake-on varnish suitable for the method contains, for example:3 to 25 wt.-% of polyvinylidene fluoride, 5 to 20 wt.-% of at least one high-boiling organic solvent with a boiling point up to 250.degree. C.,1 to 10 wt.-% of at least one strongly polar latent organic solvent for polyvinylidene fluoride and 60 to 90 wt.-% of a low-boiling polar organic solvent with a boiling point up to 120.
    Type: Grant
    Filed: August 24, 1981
    Date of Patent: November 22, 1983
    Assignee: SKW Trostberg Aktiengesellschaft
    Inventor: Werner Goll
  • Patent number: 4407994
    Abstract: Disclosed is a method for sizing paper wherein the sizing agent employed is a hydrophobic cellulose reactive sizing agent such as a ketene dimer sizing agent. There is employed in combination with the sizing agent a novel sizing accelerator. Disclosed also is a novel sizing composition comprised of the sizing agent and the accelerator, the accelerator being a water-soluble nitrogen-containing reaction product of (1) a water-soluble polyaminopolyamide, such as that derived by reaction of adipic acid and diethylene-triamine; (2) an epihalohydrin, such as epichlorohydrin; and (3) a composition comprising, by weight, from about 20% to about 65% bis(hexamethylene)triamine, said composition being the residue obtained after recovery of hexamethylenediamine from its manufacture by hydrogenation of adiponitrile.
    Type: Grant
    Filed: July 2, 1981
    Date of Patent: October 4, 1983
    Assignee: Hercules Incorporated
    Inventors: Ralph A. Bankert, David H. Dumas
  • Patent number: 4393160
    Abstract: This invention relates to novel terpolymers of 3-methylcyclopentene, 2-cyclopentene-1-acetic acid and sulfur dioxide. Positive electron beam resist media prepared from the subject terpolymers possesses excellent sensitivity and development latitude and unexpectedly are developable with conventional aqueous alkaline developers.
    Type: Grant
    Filed: February 9, 1982
    Date of Patent: July 12, 1983
    Assignee: RCA Corporation
    Inventor: Thomas R. Pampalone
  • Patent number: 4341686
    Abstract: Adhesive products comprising an aminoalkyltrialkoxysilane, polyvinyl chloride powder, silicic acid and an organic solvent are employed to attach cover layers to cellular and non-cellular polyurethanes.
    Type: Grant
    Filed: July 29, 1981
    Date of Patent: July 27, 1982
    Assignee: BASF Aktiengesellschaft
    Inventors: Sarbananda Chakrabarti, John Hutchison, Otto Volkert
  • Patent number: 4341683
    Abstract: Ink formulations for use in printing polyvinyl butyral sheets are described. The formulations comprise polyvinyl formal, and polyvinyl butyral sheets printed using the formulations are found to have a reduced tendency to exhibit blocking.
    Type: Grant
    Filed: May 4, 1981
    Date of Patent: July 27, 1982
    Assignee: Monsanto Company
    Inventor: James A. Snelgrove
  • Patent number: 4332706
    Abstract: Internal reflection of an optical glass is suppressed by applying a coating material comprising a material selected from coal tar and coal tar pitch and a resin selected from vinylidene chloride series copolymers and halogenated epoxy resins.
    Type: Grant
    Filed: May 13, 1980
    Date of Patent: June 1, 1982
    Assignee: Canon Kabushiki Kaisha
    Inventors: Haruo Uehara, Kunio Satomi
  • Patent number: 4331581
    Abstract: A process for forming a paste suitable for the preparation of dispersions and coatings is disclosed, said process comprising (1) dissolving a selectively hydrogenated monoalkenyl arene (A) - conjugated diene (B) block polymer in a first solvent, which first solvent is a good solvent for both the A blocks and the B blocks, (2) adding a second solvent to the solution, wherein said second solvent is a good solvent for the A blocks and a poor solvent for the B blocks, therein forming a suspension of micelles, and (3) adding a third solvent to the suspension of micelles, wherein said third solvent is a poor solvent for both the A blocks and the B blocks, therein forming an elastosol paste.
    Type: Grant
    Filed: August 10, 1981
    Date of Patent: May 25, 1982
    Assignee: Shell Oil Company
    Inventor: Sol Davison
  • Patent number: RE30922
    Abstract: The products of the invention are vinyl end-capped oligomers which are prepared from 2,4-bis (p-aminobenzyl) aniline and a vinyl substituted aromatic monoamine, the principal component of which is the compound whose structure is shown in FIG. 3. The products are prepared from either of two (2) precursors. The first precursor is a compound whose structure is shown in FIG. 2 and which is prepared from 2,4-bis (p-aminobenzyl) aniline, a dianhydride of an aromatic tetracarboxylic acid such as 3,3'4,4'-benzophenonetetracarboxylic acid (BTDA) and a vinyl substituted aromatic monoamine, such as 3-aminophenyl-ethylene (APE). The second precursor is a complex amine salt having the structure shown in FIG. 6 and which is prepared from 2,4-bis-(p-aminobenzyl) aniline, a dialkyl ester of BTDA and APE.
    Type: Grant
    Filed: August 25, 1980
    Date of Patent: May 4, 1982
    Assignee: Gulf Oil Corporation
    Inventors: William J. Heilman, Daniel J. Hurley