Solid Polymer Derived From Nitrogen Heterocycle Monomer Patents (Class 524/516)
  • Patent number: 11649368
    Abstract: The present invention is directed to a coating composition or paint comprising a multistage latex with at least first and second stages, wherein the composition or paint is substantially free of volatile organic compounds (VOC) and capable of film formation even in the absence of coalescent agents. The base paint formulation is capable of being tinted at a point-of-sale (i.e. in-store) using a colorant composition of a type and quantity required to produce a paint of desired color and finish. The paints, show improved block resistance, scrub resistance and tack resistance. Rheological techniques as described herein may be used to determine tack resistance, print resistance, and other performance characteristics.
    Type: Grant
    Filed: August 31, 2021
    Date of Patent: May 16, 2023
    Inventors: Tessie Rose Ewert, Tyler Bell, Robert Sandoval, Mary Jane Hibben
  • Patent number: 10800927
    Abstract: The present invention provides an aqueous composition for coating substrates comprising: one or more emulsion copolymer, the emulsion copolymer being a copolymerization product of a monomer mixture comprising a monomer of formula I, wherein R1 is hydrogen or methyl, X is a divalent organic alkylene oxide group, n is an integer ranging from 1 to 50 and R2 is hydrogen or an aliphatic or aromatic hydrocarbon group having from 1 to 20 carbon atoms, and a phosphate surfactant. When incorporated into a coating composition, the coating composition show both improved stain-resistance properties and anti-clogging properties.
    Type: Grant
    Filed: December 22, 2014
    Date of Patent: October 13, 2020
    Assignees: Dow Global Technologies LLC, Rohm and Haas Company
    Inventors: Zhen Qian, Xuzhi Zhu, Jianming Xu, Qingwei Zhang, Wei Cui, Jintao Liu
  • Patent number: 10336849
    Abstract: The present application relates to novel copolymers and processes for the preparation thereof, where the copolymers comprise, as building blocks: a C1-20-alkyl (meth)acrylate and/or C8-20-vinylaromatics (monomer a); a monoethylenically unsaturated, hydrophilic monomer comprising at least one sulfonic acid group (—SO3M) (monomer b); and a monoethylenically unsaturated monomer comprising at least one oxazoline group (monomer c); and where the fraction of the monomers a) and b) is in total less than 50% by weight, based on the total amount of the monomers in the copolymer A.
    Type: Grant
    Filed: June 24, 2015
    Date of Patent: July 2, 2019
    Assignee: BASF SE
    Inventors: Matthias Zorn, Yvonne Dieckmann, Iris Peters-Steuer, Kathrin Michl
  • Patent number: 9017473
    Abstract: The invention relates to a method of neutralizing paints, that includes adding at least one associative neutralizing agent to a formulation such as a pigment concentrate, a white paint base or paint. The associative neutralizing agent includes at least one neutralizing group N and at least one nitrogenous associative group A bonded together by at least one “spacer” group Sp. The invention also relates to pigment concentrates and to paints containing at least one such associative neutralizing agent.
    Type: Grant
    Filed: September 25, 2009
    Date of Patent: April 28, 2015
    Assignee: Arkema France
    Inventors: Bruno Van Hemelryck, Manuel Hidalgo
  • Publication number: 20150099841
    Abstract: A method of production of a nitrile copolymer rubber composition which contains a nitrile copolymer rubber, layered inorganic filler, vinyl chloride resin, and plasticizer including the steps of adding, to an aqueous dispersion of a vinyl chloride resin, 10 to 100 wt % of the total amount of plasticizer which is used and 0 to 100 wt % of the total amount of layered inorganic filler which is used to prepare an aqueous dispersion of a vinyl chloride resin which contains a plasticizer (A) and mixing an aqueous dispersion of a nitrile copolymer rubber (B) which may contain a plasticizer and/or layered inorganic filler and the aqueous dispersion of a vinyl chloride resin (A), then causing them to coagulate to form crumbs and filtering and drying the same is provided.
    Type: Application
    Filed: March 7, 2013
    Publication date: April 9, 2015
    Inventors: Akira Tsukada, Tomoyuki Shibuya, Yoshihisa Takeyama, Tadashi Nakamura
  • Patent number: 8920920
    Abstract: Disclosed are blended latex dispersions which can be used as binders in paper coating compositions. Such latex dispersions comprise a first copolymer of a vinyl ester of an alkanoic acid having from 1 to 13 carbon atoms and ethylene; and a second copolymer of (i) styrene and butadiene, (ii) styrene, butadiene and acrylonitrile, or (iii) styrene and an acrylic monomer, wherein the first and second copolymers are colloidally dispersed in an aqueous medium comprising a surfactant. The paper coating compositions containing latex dispersion binders of this type preferably exhibit especially desirable coating strength as quantified by the Dry Pick Values which such compositions provide.
    Type: Grant
    Filed: November 16, 2012
    Date of Patent: December 30, 2014
    Assignee: Celanese International Corporation
    Inventors: Rajeev Farwaha, Chris L. Lazaroff, Frederick F. Cazenave, III, Nancy Susan Coulson
  • Patent number: 8920682
    Abstract: The disclosure generally relates to a dispersion of nanoparticles in a liquid medium. The liquid medium is suitably water-based and further includes an ionic liquid-based stabilizer in the liquid medium to stabilize the dispersion of nanoparticles therein. The stabilizer can be polymeric or monomeric and generally includes a moiety with at least one quaternary ammonium cation from a corresponding ionic liquid. The dispersion suitably can be formed by shearing or otherwise mixing a mixture/combination of its components. The dispersions can be used to form nanoparticle composite films upon drying or otherwise removing the liquid medium carrier, with the stabilizer providing a nanoparticle binder in the composite film. The films can be formed on essentially any desired substrate and can impart improved electrical conductivity and/or thermal conductivity properties to the substrate.
    Type: Grant
    Filed: March 18, 2011
    Date of Patent: December 30, 2014
    Assignee: Eastern Michigan University
    Inventor: John Texter
  • Publication number: 20140373716
    Abstract: Provided are a gas barrier resin composition, and a gas barrier composite film excellent in gas barrier properties with respect to oxygen, carbon dioxide gas, water vapor or the like, particularly in gas barrier properties even after hot water treatment. The gas barrier resin composition includes an oxazoline group-containing aqueous polymer (A), an aqueous acrylic resin (B) and/or an aqueous polyester resin (C) each at a specific concentration, wherein the ratio of the mole number of the oxazoline group to the mole number of the carboxyl group [the ratio of the mole number of the oxazoline group (x mmol) to the mole number of the carboxyl group (y mmol), which is indicated as (x/y)×100 (mol %)], is within the specific range. The gas barrier composite film uses this composition.
    Type: Application
    Filed: December 13, 2012
    Publication date: December 25, 2014
    Inventors: Masaru Shimizu, Daisuke Matoba
  • Publication number: 20140364511
    Abstract: A stable, aqueous composition containing a crosslinked, nonionic, amphiphilic polymer capable of forming a yield stress fluid in the presence of a surfactant is disclosed. The yield stress fluid is capable of suspending insoluble materials in the form of particulates and/or droplets requiring suspension or stabilization.
    Type: Application
    Filed: September 13, 2012
    Publication date: December 11, 2014
    Applicant: LUBRIZOL ADVANCED MATERIALS, INC.
    Inventors: Krishnan Chari, Shui-Jen Raymond Hsu, Wei-Yeih Yang, Prachur Bhargava, Murat Kadir
  • Publication number: 20140350140
    Abstract: Fiber for reinforcing rubber products, which comprises fiber coated with a coating film formed by a treating agent, wherein the treating agent comprises a rubber latex containing at least a vinylpyridine/styrene/butadiene terpolymer, a latex of an acrylonitrile/butadiene/styrene terpolymer, and a water-soluble condensate of resorcinol and formaldehyde.
    Type: Application
    Filed: December 20, 2013
    Publication date: November 27, 2014
    Applicant: SOVOUTRI SOCIETE VOULTAINE DE TRANSFORMES INDUSTRIELS
    Inventor: Kimihiro ANDO
  • Patent number: 8865312
    Abstract: A coating composition for a solar cell backsheet of the present invention includes: (a) 10 to 40 mass % of vinyl ester resin or unsaturated polyester resin; (b) 30 to 60 mass % of vinyl monomer and/or (meth)acrylate monomer; (c) 5 to 40 mass % of denaturant (The components (a) to (c) are 100 mass % in total); (d) 0.1 to 15 parts by mass of an ultraviolet curing agent relative to 100 parts by mass in total of the components (a) to (c); and (e) 5 to 20 parts by mass of a white colorant relative to 100 parts by mass in total of the components (a) to (c).
    Type: Grant
    Filed: June 25, 2010
    Date of Patent: October 21, 2014
    Assignees: Riken Technos Corp., BASF SE
    Inventors: Michihisa Tasaka, Hiroyasu Kanno
  • Publication number: 20140303304
    Abstract: Use of cationic polymers comprising quaternary nitrogen atoms as antistat in coating compositions, characterized in that the polymers are selected from the group consisting of compounds according to the formula (I), polydiallyldialkylamines and copolymers thereof, polyalkyleneimines, polyvinylimidazoles and copolymers thereof, and mixtures of these. The effect of the antistat is that dust adheres to a lesser degree to the coating of the composition. The compositions are employed more particularly in the interior architectural sector.
    Type: Application
    Filed: October 19, 2012
    Publication date: October 9, 2014
    Inventors: Burkhard Frost, Fabien Brand
  • Publication number: 20140296418
    Abstract: An adhesive hydrogel contains: a polymer matrix of a copolymer of a monofunctional monomer and a crosslinking monomer (a); another polymer component; water; and a polyhydric alcohol, wherein: either a structural unit derived from the monofunctional monomer contained in the polymer matrix or the other polymer component or both contain a structural unit derived from at least one compound (b) selected from the group consisting of ethylenically unsaturated carboxylic acids, ethylenically unsaturated carboxylic acid salts, and ethylenically unsaturated carboxylic acid derivatives having a hydroxyl group, an acid group, a salt thereof, an amino group, and/or an ammonium group; and the other polymer component contains a polymer compound (c) with a side chain having an oxyalkylene group or a polyoxyalkylene group.
    Type: Application
    Filed: July 4, 2012
    Publication date: October 2, 2014
    Applicant: SEKISUI PLASTICS CO., LTD.
    Inventors: Kaori Sato, Takaaki Hatori, Yasuhiro Fujiwara
  • Publication number: 20140242757
    Abstract: An adhesive composition for a pre-applied underfill sealant comprising: (a) a radical polymerizable monomer having one or more functional groups selected from the group consisting of vinyl group, maleimide group, acryloyl group, methacryloyl group and allyl group, (b) a polymer having a polar group, (c) a filler, and (d) a thermal radical initiator.
    Type: Application
    Filed: May 1, 2014
    Publication date: August 28, 2014
    Applicants: HENKEL IP & HOLDING GMBH, HENKEL JAPAN LIMITED
    Inventors: Sugiura Yoko, Horiguchi Yusuke, Mieko Sano, Gina Hoang
  • Publication number: 20140235782
    Abstract: To obtain a hydrophilic macromonomer mixture which is a highly polymerized hydrophilic macromonomer, has few components not bonded to the polymer chain after polymerization, and is less likely to leaching. Provided is a macromonomer mixture containing macromonomer A being a macromonomer having a group obtained by further introducing a polymerizable group into a reactive group derived from a polymerization initiator at an end thereof; and macromonomer B being a macromonomer having a group obtained by further introducing a polymerizable group into a reactive group derived from a chain transfer agent at an end thereof.
    Type: Application
    Filed: April 29, 2014
    Publication date: August 21, 2014
    Applicant: Johnson & Johnson Vision Care, Inc.
    Inventors: Kazuhiko Fujisawa, Masataka Nakamura
  • Patent number: 8765838
    Abstract: A non-aqueous ink composition for inkjet printing, comprising 5 to 15% by mass of pigment relative to a mass of the non-aqueous ink composition, a pigment dispersant in such an amount that a mass ratio of the pigment dispersant to the pigment ranges from 0.2 to 2.0, and an organic solvent, the pigment dispersant comprising (A) a polyamide having a polyester side chain and/or a copolymer of vinylpyrrolidone and a C10-40 alkene, and (B) an alkyl(alkyl)acrylate copolymer having a C12-25 alkyl group and a nitrogen-containing group in such an amount that a mass ratio of the dispersant (B) to a total of the dispersant (A) and the dispersant (B), (B)/[(A)+(B)], ranges from 0.75 to 0.99. The ink composition has good storage stability and causes no satellite even printed in an environment of a low temperature.
    Type: Grant
    Filed: September 27, 2011
    Date of Patent: July 1, 2014
    Assignee: Riso Kagaku Corporation
    Inventors: Tetsuo Hosoya, Toshihiro Endo
  • Publication number: 20140179839
    Abstract: The invention relates to colorant compositions, and aqueous latex paints or other water-borne coatings made from them, which have a mitigated environmental impact. Levels of solvents, additives and impurities comprising volatile non-aqueous constituents, alkylphenol ethoxylates (and derivatives thereof), crystalline silica, and/or formaldehyde are decreased relative to those typical of preceding generations of colorants and tinted aqueous latex paints and other water-borne coatings. On the other hand, paint-performance as indicated by any of Stormer viscosity stabilization, rheological profile flow/leveling and sag resistance, water sensitivity and color transfer resistance is comparable to a paint in which the aforementioned solvents, additives and impurities are still present.
    Type: Application
    Filed: March 5, 2010
    Publication date: June 26, 2014
    Applicant: Columbia Insurance Company
    Inventors: Yong Yang, Mohammed Asif, Robert J. Sheerin
  • Patent number: 8759434
    Abstract: This invention provides a method to form nano-sized dispersed structure consisting of aqueous sodium silicate and polyvinyl pyrrolidone (PVP) solutions, and a binder consisting of a nano-sized dispersed structure and calcium chloride dihydrate solution. The invention provides also a method to immobilize sand dunes and wind-blown dust by using the binder.
    Type: Grant
    Filed: November 30, 2012
    Date of Patent: June 24, 2014
    Assignees: Abu Dhabi University, United Arab Emirates University
    Inventors: Abdel-Mohsen Onsy Mohamed, Maisa Mabrouk El-Gamal
  • Publication number: 20140170362
    Abstract: An adhesive article for masking a portion of a substrate surface from a liquid coating applied to the surface includes a support having first and second opposed major surfaces, and a cationic or zwitterionic adhesive composition disposed on at least a portion of at least one of the first and second opposed major surfaces. The adhesive composition provides a barrier that impedes the migration of the coating past the edge of the adhesive article.
    Type: Application
    Filed: December 10, 2013
    Publication date: June 19, 2014
    Applicant: 3M INNOVATIVE PROPERTIES COMPANY
    Inventors: Mahfuza B. Ali, Elizabeth E. Johnson, Michael D. Crandall
  • Patent number: 8742004
    Abstract: A highly durable coating composition particularly suited for use on printed articles requiring protection from exposure to the natural elements, chemical exposure, or abrasion. The coating composition generally comprises a fluoropolymer resin, an acrylic polyol resin and a melamine resin. Optionally, a polyisocyanate crosslinking agent may also be included to accelerate curing of the coating.
    Type: Grant
    Filed: March 14, 2013
    Date of Patent: June 3, 2014
    Inventor: Donald D. Sloan
  • Patent number: 8742003
    Abstract: The present invention relates to silylated amino resins, to processes for preparing them, to their use, and to coating compositions comprising them.
    Type: Grant
    Filed: July 13, 2012
    Date of Patent: June 3, 2014
    Assignee: BASF SE
    Inventors: Christina Haaf, Markus Hickl, Ruediger Stark, Horst Hintze-Bruening, Bernd Bruchmann, Dirk Schmelter, Thomas Gloege, Christine Roesch
  • Publication number: 20140128517
    Abstract: A method for dissolving and degassing a polymer is described, including a dissolution/degassing step. In the dissolution/degassing step, a mixture containing the polymer and a solvent is agitated, in a pressure-reduced condition with a gauge pressure of ?50 to ?90 kPa and at a temperature lower than the boiling point of the solvent in the pressure-reduced condition but higher than the freezing point of the same, to dissolve the polymer and simultaneously degas the polymer solution, so as to obtain a polymer solution.
    Type: Application
    Filed: April 19, 2012
    Publication date: May 8, 2014
    Applicant: MITSUBISHI RAYON CO., LTD.
    Inventors: Katsuhiko Shinada, Masahiko Mizuta
  • Patent number: 8716372
    Abstract: Fluid activatable adhesive compositions and activating fluid(s) for activating the adhesive composition are described herein. The adhesive compositions contain at least two polymers with different hydrophilicities. The hydrophilic polymer has quick tack when exposed to a hydrophilic solvent, such as water or other aqueous solvent, while the hydrophobic polymer provides strong adhesion to a paper or polymeric substrate. The adhesive composition may contain particulate fillers which enable fast exhaustion of the activation fluid out of the adhesive when applied to a substrate, thereby allowing the hydrophobic polymers of the adhesive composition to achieve strong adhesion of the liner-free label to the paper or polymeric substrate. The particulate fillers may also function as anti-blocking agents when liner-free label media are tightly wound in a roll.
    Type: Grant
    Filed: February 6, 2012
    Date of Patent: May 6, 2014
    Assignee: NuLabel Technologies, Inc.
    Inventors: Benjamin David Lux, Daniel Youngwhan Cho, Felix Perets Shvartsman
  • Patent number: 8710139
    Abstract: An acrylic pressure-sensitive adhesive composition contains 100 parts by mass of an acrylic polymer (A), 1 to 70 parts by mass of a (meth)acrylic polymer (B) having a weight average molecular weight (Mw) of 1000?Mw<30000, and 1 to 50 parts by mass of a hydrogenated tackifying resin (C). The (meth)acrylic polymer (B) is a polymer having a weight average molecular weight smaller than that of the acrylic polymer (A) as a pressure-sensitive adhesive composition, and functions as a tackifying resin along with the hydrogenated tackifying resin (C).
    Type: Grant
    Filed: February 27, 2013
    Date of Patent: April 29, 2014
    Assignee: Nitto Denko Corporation
    Inventors: Kiyoe Shigetomi, Masayuki Okamoto, Masato Yamagata, Jun Akiyama
  • Publication number: 20140107278
    Abstract: The present invention provides a fluorine-containing curable resin that can impart high stain resistant properties to the surface of a cured coating film and can exhibit high stain resistant properties even when curing is performed in an air atmosphere (in the presence of oxygen). It is also an object to provide an active-energy-ray-curable composition that uses the fluorine-containing curable resin and can exhibit high stain resistant properties even when curing is performed in an air atmosphere and a cured product of the active-energy-ray-curable composition. To achieve the object, there is provided a fluorine-containing curable resin including a poly(perfluoroalkylene ether) chain, a maleimide group, and a mercapto group in a structure of a urethane polymer or a polymer composed of a monomer having a polymerizable unsaturated group.
    Type: Application
    Filed: June 11, 2012
    Publication date: April 17, 2014
    Applicant: DIC CORPORATION
    Inventors: Yusuke Ozaki, Hideya Suzuki
  • Publication number: 20140100315
    Abstract: A nitrile copolymer latex composition containing a latex of a nitrile copolymer rubber (A) having ?,?-ethylenically unsaturated nitrile monomer units in 10 to 75 wt %, conjugated diene monomer units in 5 to 89.9 wt %, and cationic monomer units and/or monomer units able to form cations in 0.1 to 20 wt %, an inorganic filler (B) having an aspect ratio of 30 to 2,000, and a plasticizer (C) having an SP value by the HOY method of 8 to 10.2 (cal/cm3)1/2, wherein a content of said plasticizer (C) is 0.1 to 200 parts by weight with respect to said nitrile copolymer rubber (A) as 100 parts by weight is provided.
    Type: Application
    Filed: December 12, 2013
    Publication date: April 10, 2014
    Applicant: ZEON CORPORATION
    Inventors: Akira TSUKADA, Kazuhiro EJIRI, Chikara KATANO
  • Publication number: 20140086862
    Abstract: The present invention provides colored resin particles having excellent adhesiveness, a method for producing the same, and use thereof. Each of the colored resin particles is surface-coated with a polymer derived from a nitrogen-containing aromatic compound, and has an irregular shape with a circular appearance when viewed from a direction in which a projected area thereof becomes maximum, and with a non-circular appearance when viewed from a direction in which the projected area thereof becomes minimum.
    Type: Application
    Filed: January 30, 2012
    Publication date: March 27, 2014
    Applicant: SEKISUI PLASTICS CO., LTD.
    Inventors: Masaaki Nakamura, Ryosuke Harada
  • Patent number: 8673277
    Abstract: Disclosed are multi-staged acrylic based core-shell polymers comprising a linear core polymer and at least one subsequently polymerized shell polymers is crosslinked. The core-shell polymers surprisingly provide desirable rheological, clarity, and aesthetic properties in aqueous surfactant containing compositions, particularly at low pH.
    Type: Grant
    Filed: July 7, 2011
    Date of Patent: March 18, 2014
    Assignee: Lubrizol Advanced Materials, Inc.
    Inventors: Krishnan Tamareselvy, Deborah S. Filla, Steven J. Smith, David L. Dashiell, Gary Gray, Yi Yang, John J. Mullay
  • Patent number: 8657947
    Abstract: The present invention relates to silylated amino resins, to processes for preparing them, to their use, and to coating compositions comprising them.
    Type: Grant
    Filed: September 10, 2012
    Date of Patent: February 25, 2014
    Assignee: BASF SE
    Inventors: Bastian Noller, Reinhold Schwalm, Christine Roesch, Thomas Breiner, Jean-Francois Stumbe, Christina Haaf
  • Patent number: 8653286
    Abstract: Methods for forming maleimide functionalized polymers are provided. In one such embodiment, a maleimide functionalized polymer is prepared in a method that includes a step of carrying out a reverse Diels-Alder reaction. Intermediates useful in the methods, as well as methods for preparing the intermediates, are also provided. Also provided are polymeric reagents, methods of using polymeric reagents, compounds and conjugates.
    Type: Grant
    Filed: August 7, 2012
    Date of Patent: February 18, 2014
    Assignee: Nektar Therapeutics
    Inventors: Samuel P. McManus, Antoni Kozlowski, Tracy L. Hutchison, Brian Bray, Xiaoming Shen
  • Publication number: 20140037951
    Abstract: A pressure-sensitive adhesive composition includes: 100 parts by mass of a polymer (A) having a glass transition temperature lower than 0° C.; and 0.05 parts by mass to 20 parts by mass of a (meth)acrylic polymer (B) having a weight average molecular weight (MwB) of 1000?MwB<30000 that contains, as monomer units, both a (meth)acrylic monomer having an alicyclic structure represented by the following general formula (1) and a monomer having a polyoxyalkylene skeleton: CH2?C(R1)COOR2??(1) [wherein R1 represents a hydrogen atom or a methyl group and R2 represents an alicyclic hydrocarbon group having an alicyclic structure.
    Type: Application
    Filed: July 30, 2013
    Publication date: February 6, 2014
    Applicant: NITTO DENKO CORPORATION
    Inventors: Kiyoe SHIGETOMI, Ryo KANNO, Masayuki OKAMOTO, Masato YAMAGATA
  • Patent number: 8637601
    Abstract: There is provided a fluorine-containing polymer having an ionic group which has a heteroaromatic ring and is useful as a material comprising various heteroaromatic ring compounds having a stable fluorine-containing heteroaromatic ring, and further fluorine-containing polymer having a heteroaromatic ring which is useful as a starting material of the above-mentioned polymer or a curing agent. Also, there is provided a fluorine-containing polymer having a heteroaromatic ring such as imidazole in its side chain, a polymer salt thereof, and a polymer composition comprising such a polymer and a polymer salt and a nano filler.
    Type: Grant
    Filed: July 3, 2012
    Date of Patent: January 28, 2014
    Assignee: Daikin Industries, Ltd.
    Inventors: Yuzo Komatsu, Haruhiko Mohri, Hirokazu Aoyama
  • Publication number: 20140024278
    Abstract: Synthesized base resin compositions that include a raw resin and a maleimide and/or bismaleimide monomer as well as compounded varnishes that include a raw resin or synthesized base resin as well as a monomer, flame retardant and initiator as well as prepregs and laminates made using the synthesized base resin and compounded varnishes.
    Type: Application
    Filed: March 15, 2013
    Publication date: January 23, 2014
    Applicant: ISOLA USA CORP.
    Inventor: ISOLA USA CORP.
  • Publication number: 20140018473
    Abstract: Disclosed are aqueous latex-based coating compositions which comprise a blend of an ethylene-vinyl acetate emulsion copolymer component and a selected type of acrylic emulsion copolymer component. The acrylic copolymer component comprises primarily acrylate ester co-monomers or acrylic ester co-monomers and vinyl aromatic, e.g., styrene, co-monomers. The blend of these two emulsion copolymer types also contains a specific type of hydrazine-based, water-soluble cross-linking agent which can eventually react with the acrylic emulsion copolymer component. The acrylic emulsion copolymer is one which contains minor amounts of both 1) carboxy functional co-monomers such as itaconic and/or (meth)acrylic acids, and 2) keto- or aldehyde-containing co-monomers such as diacetone acrylamide. Such latex-based coating compositions can be formulated in the form of water-based paint compositions.
    Type: Application
    Filed: December 17, 2010
    Publication date: January 16, 2014
    Applicant: CELANESE INTERNATIONAL CORPORATION
    Inventors: Marc Theodorus Ratering, Rajeev Farwaha, Tara Joy Hansen
  • Patent number: 8604100
    Abstract: Disclosed are an ink composition for oil-based ballpoint pens which exhibits soft writing sensation due to low viscosity of 300 to 3000 cps, enables writing even at low temperatures and thus exhibits superior stability, and is free of leakage (of ink), and an oil-based ballpoint pen using the same.
    Type: Grant
    Filed: May 25, 2011
    Date of Patent: December 10, 2013
    Assignees: Suhan Corporation, Kotobuki & Co., Ltd.
    Inventors: Doo Young Chung, Soon Suck Lee
  • Patent number: 8580885
    Abstract: This invention provides a rubber composition highly balancing flexibility at a low temperature and a low rolling resistance, which is formed by compounding a low-molecular weight conjugated diene-based polymer (B) having at least one functional group, an aromatic vinyl compound content of less than 5% by mass and a weight average molecular weight as measured without terminating by modification through a gel permeation chromatography and converted to polystyrene of not less than 2,000 but less than 150,000 and a filler (C) into a high-molecular weight rubber component (A) having a weight average molecular weight as measured without terminating by modification through a gel permeation chromatography and converted to polystyrene of not less than 150,000.
    Type: Grant
    Filed: September 4, 2007
    Date of Patent: November 12, 2013
    Assignee: Bridgestone Corporation
    Inventors: Fuminori Ohta, Koji Masaki, Keisuke Kidono
  • Publication number: 20130284245
    Abstract: A multi-layered film, a backsheet for photovoltaic modules, a method of manufacturing the same, and a photovoltaic module are provided. The multi-layered film can be configured so that a resin layer including a fluorine-based polymer and an oxazoline group-containing polymer is formed on a substrate. As a result, the resin layer including the fluorine-based polymer can have excellent durability and weather resistance, and show high interfacial adhesive strength to the substrate. During the preparation of the multi-layered film, a drying process can also be performed at a relatively low temperature, so that the manufacturing costs can be reduced and the quality of the product can be prevented from being deteriorated by thermal deformation or thermal shock. The multi-layered film may be effectively used as the backsheet in a variety of photovoltaic modules.
    Type: Application
    Filed: June 26, 2013
    Publication date: October 31, 2013
    Inventors: Hyun Cheol KIM, Yoon Kyung Kwon
  • Publication number: 20130243993
    Abstract: A method of preparing a coating composition. The method comprises preparing a mixture that includes a releasing agent, thickening agents, and vinyl acetate-acrylic copolymer. Another embodiment is a method of forming a film, comprising, providing the coating composition and applying the coating composition to a surface. Another embodiment is a protective coating comprising a film, that includes the coating composition, applied to a surface of a manufactured product.
    Type: Application
    Filed: March 13, 2013
    Publication date: September 19, 2013
    Applicant: Groco Specialty Coatings Company
    Inventors: George W. Grogan, Robert H. Boyd
  • Publication number: 20130231207
    Abstract: There is disclosed a glass-fiber coating liquid for forming a coating layer on a glass fiber cord, prepared in the form of an emulsion consisting essentially of a monohydroxybenzene-formaldehyde resin (A) obtained by reaction of monohydroxybenzene (D) and formaldehyde (E), a vinylpyridine-styrene-butadiene copolymer (B) having a vinylpyridine monomer content of 17 to 35% by mass, a styrene monomer content of 20 to 40% by mass and a butadiene monomer content of 35 to 60% by mass, a chlorosulfonated polyethylene (C), an acrylonitrile-butadiene rubber (P); at least one of an antioxidant, a pH adjuster and a stabilizer; and water.
    Type: Application
    Filed: March 8, 2013
    Publication date: September 5, 2013
    Applicant: Central Glass Company, Ltd.
    Inventors: Takafumi Iwano, Katsuhiko Ogaki, Minekazu Kohama, Kazuhiro Yamamoto
  • Patent number: 8496920
    Abstract: Novel acrylamide and methacrylamide hydantoin monomers which can be reacted with other acrylamide, methacrylamide, acrylate, and methacrylate monomers to form copolymers, which upon halogenation, provide oxidative coatings which are biocidal for use with various materials including, but not limited to, textiles, filters, and latex paints.
    Type: Grant
    Filed: October 11, 2011
    Date of Patent: July 30, 2013
    Assignee: Auburn University
    Inventors: Shelby D. Worley, Royall M. Broughton, Hasan B. Kocer, Idris Cerkez
  • Publication number: 20130177758
    Abstract: An acrylic pressure-sensitive adhesive composition contains 100 parts by mass of an acrylic polymer (A), 1 to 70 parts by mass of a (meth)acrylic polymer (B) having a weight average molecular weight (Mw) of 1000?Mw<30000, and 1 to 50 parts by mass of a hydrogenated tackifying resin (C). The (meth)acrylic polymer (B) is a polymer having a weight average molecular weight smaller than that of the acrylic polymer (A) as a pressure-sensitive adhesive composition, and functions as a tackifying resin along with the hydrogenated tackifying resin (C).
    Type: Application
    Filed: February 27, 2013
    Publication date: July 11, 2013
    Applicant: NITTO DENKO CORPORATION
    Inventor: Nitto Denko Corporation
  • Publication number: 20130171438
    Abstract: A composition for colloidal crystals including core-shell particles and a monomer having a particular structure. The core-shell particles constitute 25% to 65% by weight of the composition, and the monomer constitutes 35% to 75% by weight of the composition. The core has an average particle size from 50 to 900 nm. Each particle includes a core and a shell. The shell is formed of a linear polymer composed of at least one of styrene and a monomer having a particular structure. One end of the linear polymer is covalently bonded to the core. The refractive index of the core (n(core)) satisfies the following formulae: wherein R1 denotes a hydrogen atom or a methyl group, and y is 0 or 1, n(shell)?n(core)?0.07, n(shell) denoting the refractive index of the shell, and n(B)?n(core)?0.07, n(B) denoting the refractive index of the monomer (B1) after curing.
    Type: Application
    Filed: June 1, 2011
    Publication date: July 4, 2013
    Applicant: NOF CORPORATION
    Inventors: Masaki Hayashi, Masumi Takamura
  • Publication number: 20130165578
    Abstract: Pneumatic rubber tire with a component comprised of a silica reinforced rubber composition comprised of a combination of functionalized polybutadiene rubber and functionalized styrene/butadiene elastomer.
    Type: Application
    Filed: October 31, 2012
    Publication date: June 27, 2013
    Inventors: William Paul Francik, Christin Louise Alwardt, Michael Joseph Rachita, Stephan Rodewald
  • Publication number: 20130130025
    Abstract: Disclosed are blended latex dispersions which can be used as binders in paper coating compositions. Such latex dispersions comprise a first copolymer of a vinyl ester of an alkanoic acid having from 1 to 13 carbon atoms and ethylene; and a second copolymer of (i) styrene and butadiene, (ii) styrene, butadiene and acrylonitrile, or (iii) styrene and an acrylic monomer, wherein the first and second copolymers are colloidally dispersed in an aqueous medium comprising a surfactant. The paper coating compositions containing latex dispersion binders of this type preferably exhibit especially desirable coating strength as quantified by the Dry Pick Values which such compositions provide.
    Type: Application
    Filed: November 16, 2012
    Publication date: May 23, 2013
    Applicant: CELANESE INTERNATIONAL CORPORATION
    Inventor: Celanese international corporation
  • Patent number: 8440273
    Abstract: A coating composition for forming a glossy, inkjet-receptive coating on a substrate includes (a) a cationic polymer, and (b) colloidal silica having an average particle size in the nanometer range.
    Type: Grant
    Filed: August 8, 2005
    Date of Patent: May 14, 2013
    Assignee: IP Investments Inc.
    Inventor: David K. Hood
  • Publication number: 20130116369
    Abstract: The present teachings include a coating composition of a powder of fluorine containing particles, aerogel particles and poly(alkylene carbonate). A method of making a fuser member and the fuser member resulting therefrom is also provided.
    Type: Application
    Filed: November 3, 2011
    Publication date: May 9, 2013
    Applicant: XEROX CORPORATION
    Inventors: Yu Qi, Qi Zhang, David C. Irving, Daniel L. Coughlin, JR., Carolyn P. Moorlag, Brynn M. Dooley, Nan-Xing Hu
  • Publication number: 20130115185
    Abstract: Disclosed are multi-staged acrylic based core-shell polymers comprising a linear core polymer and at least one subsequently polymerized shell polymers is crosslinked. The core-shell polymers surprisingly provide desirable rheological, clarity, and aesthetic properties in aqueous surfactant containing compositions, particularly at low pH.
    Type: Application
    Filed: July 7, 2011
    Publication date: May 9, 2013
    Applicant: LUBRIZOL ADVANCED MATERIALS, INC.
    Inventors: Krishnan Tamareselvy, Deborah S. Filla, Steven J. Smith, David L. Dashiell, Gary Gray, Yi Yang, John J. Mullay
  • Patent number: 8436068
    Abstract: A composition and a polymer are provided. The composition includes the polymer and a melamine derivative. The polymer has a formula of R is hydrogen, halide, alkyl group, alkoxyl group, haloalkyl group or nitro group. n is 1-5 of integer. x+y+z=1, x>0, y?0, z?0. The melamine derivative includes R1 is hydrogen, CqH2q+1, or m and q independently is 1-10 of integer. R2, R3 and R4 independently is hydrogen, halide, or C1-C54 alkyl group.
    Type: Grant
    Filed: April 26, 2011
    Date of Patent: May 7, 2013
    Assignee: Industrial Technology Research Institute
    Inventors: Feng-Yu Yang, Meei-Yu Hsu, Gue-Wuu Hwang, Po-Yuan Lo
  • Patent number: 8426513
    Abstract: This invention provides a rubber composition having excellent workability, fracture characteristics and wear resistance and low heat buildup, which comprises not less than 20 parts by mass of a reinforcing filler (B) and 5 to 60 parts by mass of a modified aromatic vinyl compound-conjugated diene compound copolymer (C) having at least one functional group, an aromatic vinyl compound content of 5 to 80% by mass, a vinyl bond content in a conjugated diene compound portion of 10 to 80% by mass and a weight average molecular weight as measured through a gel permeation chromatography and converted to polystyrene of 5,000 to 500,000 based on 100 parts by mass of a rubber component (A) containing not less than 10% by mass of a modified conjugated diene-based polymer having at least one functional group.
    Type: Grant
    Filed: August 30, 2006
    Date of Patent: April 23, 2013
    Assignee: Bridgestone Corporation
    Inventors: Naohisa Jinbo, Noriko Mori
  • Publication number: 20130095326
    Abstract: A coating composition for a solar cell backsheet of the present invention includes: (a) 10 to 40 mass % of vinyl ester resin or unsaturated polyester resin; (b) 30 to 60 mass % of vinyl monomer and/or (meth)acrylate monomer; (c) 5 to 40 mass % of denaturant (The components (a) to (c) are 100 mass % in total); (d) 0.
    Type: Application
    Filed: June 25, 2010
    Publication date: April 18, 2013
    Applicants: BASF SE, RIKEN TECHNOS CORP.
    Inventors: Michihisa Tasaka, Hiroyasu Kanno