Solid Polymer Derived From Ethylenic Monomers Only Admixed With Ethylenic Monomer Patents (Class 524/529)
  • Patent number: 4413038
    Abstract: This invention provides a graft copolymer of at least one acrylic monomer and polystyrene, in which at least about 8 percent of the total weight of said graft copolymer is derived from acrylic acid, methacrylic acid, or both. It also provides anionic aqueous dispersions of such graft copolymers and coating compositions containing them.
    Type: Grant
    Filed: September 29, 1982
    Date of Patent: November 1, 1983
    Assignee: Mobil Oil Corporation
    Inventor: Michael A. Tobias
  • Patent number: 4413037
    Abstract: This invention provides a graft copolymer of at least one acrylic monomer and a random copolymer of a styrene and hydroxyethyl (meth)acrylate, in which at least about 8 percent of the total weight of said graft copolymer is derived from acrylic acid, methacrylic acid, or both. It also provides anionic aqueous dispersions of such graft copolymers and coating compositions containing them.
    Type: Grant
    Filed: September 29, 1982
    Date of Patent: November 1, 1983
    Assignee: Mobil Oil Corporation
    Inventor: Michael A. Tobias
  • Patent number: 4410656
    Abstract: The method of masticating diene rubber in the presence of maleic acid or maleic anhydride together with sulfur or an organic sulfur compound capable of generating a thiyl radical is shown.Improved tack, green strength or both are realized in the treated diene rubber.
    Type: Grant
    Filed: May 3, 1982
    Date of Patent: October 18, 1983
    Assignee: Monsanto Company
    Inventors: Aubert Y. Coran, Charles P. Rader, Chester D. Trivette, Jr.
  • Patent number: 4382127
    Abstract: The invention relates to a process for the preparation of suspensions of at least one polymer, said process comprising as a first step the preparation of a first suspension of at least one polymer in an organic liquid by chilling a solution of said polymer.In accordance with the invention, there is added to the first polymer suspension in a second step a powder of at least one polymer, which may be the same as or different from the first.Use of said process in the production of two-layer composites formed of an aluminum sheet and a polymer layer.
    Type: Grant
    Filed: September 3, 1981
    Date of Patent: May 3, 1983
    Assignee: Compagnie Francaise de Raffinage
    Inventors: Bruno Claude, Jean-Jacques Labaig, Christian Martinez
  • Patent number: 4366293
    Abstract: This invention provides a graft copolymer of at least one acrylic monomer and polystyrene, in which at least about 8 percent of the total weight of said graft copolymer is derived from acrylic acid, methacrylic acid, or both. It also provides anionic aqueous dispersions of such graft copolymers and coating compositions containing them.
    Type: Grant
    Filed: June 17, 1981
    Date of Patent: December 28, 1982
    Assignee: Mobil Oil Corporation
    Inventor: Michael A. Tobias
  • Patent number: 4360641
    Abstract: This invention provides a graft copolymer of at least one acrylic monomer and a random copolymer of a styrene and hydroxyethyl (meth)acrylate, in which at least about 8 percent of the total weight of said graft copolymer is derived from acrylic acid, methacrylic acid, or both. It also provides anionic aqueous dispersions of such graft copolymers and coating compositions containing them.
    Type: Grant
    Filed: June 17, 1981
    Date of Patent: November 23, 1982
    Assignee: Mobil Oil Corporation
    Inventor: Michael A. Tobias
  • Patent number: 4360640
    Abstract: This invention provides a graft copolymer of at least one acrylic monomer and a random copolymer of a styrene and allyl alcohol, in which at least about 8 percent of the total weight of said graft copolymer is derived from acrylic acid, methacrylic acid, or both. It also provides anionic aqueous dispersions of such graft copolymers and coating compositions containing them.
    Type: Grant
    Filed: June 17, 1981
    Date of Patent: November 23, 1982
    Assignee: Mobil Oil Corporation
    Inventor: Michael A. Tobias
  • Patent number: 4360642
    Abstract: This invention provides a graft copolymer of at least one acrylic monomer and a random copolymer of a styrene and (meth)acrylonitrile, in which at least about 8 percent of the total weight of said graft copolymer is derived from acrylic acid, methacrylic acid, or both. It also provides anionic aqueous dispersions of such graft copolymers and coating compositions containing them.
    Type: Grant
    Filed: June 18, 1981
    Date of Patent: November 23, 1982
    Assignee: Mobil Oil Corporation
    Inventor: Michael A. Tobias
  • Patent number: 4357440
    Abstract: A new compound, 2-hydroxy-3-t-butylamino-1-propyl methacrylate, and latex coating compositions containing said compound as a wet-adhesion aid.
    Type: Grant
    Filed: June 10, 1980
    Date of Patent: November 2, 1982
    Assignee: Union Carbide Corporation
    Inventor: David J. Schreck
  • Patent number: 4343729
    Abstract: Disclosed are novel organic pigments adapted particularly for use as tillers for paper. The organic pigments are finely divided particles obtained by graft copolymerizing an ethylenically unsaturated monomer, such as styrene, onto a water-soluble cationic prepolymer in an aqueous solution and in the presence of a free-radical polymerization initiator.
    Type: Grant
    Filed: January 21, 1981
    Date of Patent: August 10, 1982
    Assignee: Hercules Incorporated
    Inventors: William W. Maslanka, Gavin G. Spence
  • Patent number: 4337189
    Abstract: A process is described for making sterically stabilized non-aqueous dispersions of polymer microparticles, in which (1) monomers including at least one crosslinking monomer are polymerized in an aqueous medium at a temperature at least 10.degree. higher than the glass transition temperature of the polymer to be formed, in the presence of a block or graft copolymer stabilizing agent containing in the molecule, as the component solvated by the aqueous medium, a polymer chain derived from a polyethylene glycol of molecular weight at least 1000, under conditions such that there is at no time present a separate monomer phase and (2) the microparticles thus obtained are transferred into a non-aqueous medium which is capable of dissolving the polyethylene glycol in question, when the latter is in the non-hydrated state, to the extent of at least 10% by weight at room temperature.
    Type: Grant
    Filed: December 8, 1980
    Date of Patent: June 29, 1982
    Assignee: Imperial Chemical Industries Limited
    Inventors: Charles Bromley, Morice W. Thompson
  • Patent number: 4336177
    Abstract: A process is described for making sterically stabilized non-aqueous dispersions of composite polymer microparticles, in which (1) monomers including at least one crosslinking monomer are polymerized in an aqueous medium at a temperature at least 10.degree. higher than the glass transition temperature of the polymer to be formed, in the presence of a block or graft copolymer stabilizing agent, under conditions such that there is at no time present a separate monomer phase, (2) further monomers, not including any crosslinking monomer, are polymerized in the dispersion thus obtained, the presence of a separate monomer phase again being avoided, and (3) the microparticles are transferred from the resulting dispersion into a non-aqueous medium which is a solvent for the non-crosslinked polymer generated in (2). The microparticles are of value for incorporation into coating compositions the main film-forming constituent of which is compatible with the non-crosslinked component of the particles.
    Type: Grant
    Filed: December 4, 1980
    Date of Patent: June 22, 1982
    Assignee: Imperial Chemical Industries Limited
    Inventors: Alan J. Backhouse, Charles Bromley, Morice W. Thompson
  • Patent number: 4333971
    Abstract: The properties of a fibrous substrate are improved by application of a composition comprising a hydrophilic air-curing polymer and a compound comprising at least two free radical polymerizable unsaturated groups. The composition can optionally contain in addition a latex of a thermoplastic polymer.
    Type: Grant
    Filed: June 5, 1981
    Date of Patent: June 8, 1982
    Assignee: Monsanto Company
    Inventor: Donald N. Van Eenam
  • Patent number: 4330446
    Abstract: A silica complex composition suitable for the surface treatment of metals is disclosed, which comprises a water dispersible silica, an organic polymer soluble or dispersible in water and a di- or trialkoxy (or alkoxy-alkoxy) silane compound.
    Type: Grant
    Filed: May 17, 1979
    Date of Patent: May 18, 1982
    Assignee: Kansai Paint Co., Ltd.
    Inventor: Yoshiaki Miyosawa
  • Patent number: 4327005
    Abstract: Stable graft polymer dispersions are prepared employing in situ free-radical polymerization of ethylenically unsaturated monomer or monomers in polyol in the presence of an alkylene oxide adduct of a styrene-allyl alcohol copolymer stabilizer.
    Type: Grant
    Filed: August 18, 1980
    Date of Patent: April 27, 1982
    Assignee: BASF Wyandotte Corporation
    Inventors: Gerhard G. Ramlow, Duane A. Heyman, Richard A. Moore