At Least One Carboxylic Acid Ester Patents (Class 524/53)
  • Patent number: 11932707
    Abstract: The present invention relates to a method and an arrangement for dissolving starch. Specifically, the present invention relates to a method for dissolving starch by introducing mechanical force to at least partially gelatinized aqueous starch.
    Type: Grant
    Filed: February 6, 2020
    Date of Patent: March 19, 2024
    Assignee: Kemira Oyj
    Inventors: Asko Karppi, Perttu Heiska, Mika Suvanto, Matti Hietaniemi
  • Patent number: 11859076
    Abstract: The present disclosure provides biodegradable and compostable playdough compositions. In addition, the present disclosure also relates to playdough compositions based on recycled breads as a primary constituent. Processes of manufacturing the playdough compositions is also disclosed.
    Type: Grant
    Filed: August 31, 2022
    Date of Patent: January 2, 2024
    Assignee: SHACHAR GROUP LTD
    Inventors: Ifat Hammer, Tal Liezer, Yitzhak Shahar, Ana Dotan, Gali Levy
  • Patent number: 11834589
    Abstract: The present disclosure relates to a modified environment-friendly corn starch adhesive, comprising the following components in parts by weight: 30 parts of corn starch, 300-400 parts of water, 0.2-3 parts of oxidant, and 80-120 parts of polyvinyl alcohol, 1-5 parts of cross-linking agent, 3-5 parts of calcium chloride, 0.1-3 parts of urea, 0.2-0.5 parts of defoamer, and an appropriate amount of sodium hydroxide (to adjust pH), the cross-linking agent is a modified boric acid cross-linking agent prepared by reacting boric acid with epichlorohydrin, water and citric acid at 80-100° C. The surface of the modified boric acid cross-linking agent is bonded with a large number of epoxy groups and carboxyl groups, which can react with the carboxyl and aldehyde groups of the oxidized starch. These reactions can form synergistic effect with boric acid, which together improve the bonding efficiency and improve the adhesive strength of the colloid.
    Type: Grant
    Filed: October 16, 2020
    Date of Patent: December 5, 2023
    Assignee: HONGSHENG TECHNOLOGY (BEIJING) CO., LTD
    Inventors: Zhongda Duan, Runda Yan
  • Patent number: 11401447
    Abstract: Cationic or zwitterionic polymer adhesives, adhesive articles, aqueous polymerizable pre-adhesive reaction mixtures, and methods of preparation that include internal incorporation of a phenolic resin. The aqueous polymerizable pre-adhesive reaction mixtures include one or more cationic (meth)acrylate monomers, one or more low Tg nonionic monomer having a (meth)acryloyl group, optionally one or more anionic (meth)acrylate monomers, and one or more phenolic resins.
    Type: Grant
    Filed: March 3, 2020
    Date of Patent: August 2, 2022
    Assignee: 3M INNOVATIVE PROPERTIES COMPANY
    Inventors: Ibrahim A. El Hedok, Mahfuza B. Ali, Elizabeth E. Johnson, Mark D. Purgett, Youhoon Kim, Prince P. Antony
  • Patent number: 10208170
    Abstract: The present invention relates to a process for producing surface-postcrosslinked water-absorbent polymer particles by coating of water-absorbent polymer particles having a content of residual monomers in the range from 0.03 to 15% by weight with at least one surface-postcrosslinker and thermal surface-postcrosslinking at temperatures in the range from 100 to 180° C.
    Type: Grant
    Filed: November 7, 2013
    Date of Patent: February 19, 2019
    Assignee: BASF SE
    Inventors: Thomas Daniel, Norbert Herfert, Stephan Bauer, Katrin Baumann, Birgit Reinhard, Jürgen Freiberg, Christophe Bauduin, Katarzyna Dobrosielska-Oura, Michael A. Mitchell
  • Patent number: 9090753
    Abstract: The present invention provides a rubber composition exhibiting good workability and suitable for use in an inner liner of a tire. Specifically, the present invention provides a rubber composition, comprising: a rubber component; an inorganic filler having an aspect ratio of 2 to 200; and optionally at least one of carbon black and a metal salt of aliphatic acid, wherein contents of the inorganic filler, the carbon black and the metal salt of aliphatic acid satisfy following formula (1): C?0.016×(A?0.5×B)?1.18??(1) In formula (1), “A” represents a content (parts by mass) of the inorganic filler with respect to 100 parts by mass of the rubber component, “B” represents a content (parts by mass) of the carbon black with respect to 100 parts by mass of the rubber component, and “C” represents a content (parts by mass) of the metal salt of aliphatic acid with respect to 100 parts by mass of the rubber component.
    Type: Grant
    Filed: August 1, 2012
    Date of Patent: July 28, 2015
    Assignee: BRIDGESTONE CORPORATION
    Inventors: Kumiko Konno, Motoaki Kanou
  • Publication number: 20150147551
    Abstract: The present invention relates to the use of thermoplastic starch in the manufacture of an adhesive and ultrathin waterproof-breathable film, said thermoplastic starch being provided in the form of an alloy with at least one hydrophilic functionalized polyolefin obtained either by copolymerization or by grafting of a polyolefin backbone with an unsaturated monomer, said unsaturated monomer being grafted by PEGs and/or forming a metal salt. This film can be used in a textile product in the medical field, hygiene, luggage, the clothing industry, the garment industry, domestic or household equipment, furniture, fitted carpets, the automobile industry, industry, in particular industrial filtration, agriculture and/or the construction industry.
    Type: Application
    Filed: June 7, 2013
    Publication date: May 28, 2015
    Inventors: Benoît Brule, Guillaume Le, Perrine Babin, Laurent B. Cartier, Frédéric Malet
  • Publication number: 20150141547
    Abstract: The present invention is directed to a process for the preparation of an aqueous suspension of self-binding pigmentary particles comprising the following stages: (a) forming one or more aqueous suspensions of at least one inorganic matter comprising calcium carbonate; (b) forming or obtaining one or more aqueous solutions or suspensions or emulsions of at least one binder; and (c) co-grinding the aqueous suspension or suspensions obtained in stage a) with the aqueous solutions or suspensions or emulsions obtained in stage b) in a mill so as to obtain an aqueous suspension of self-binding pigmentary particles.
    Type: Application
    Filed: November 18, 2014
    Publication date: May 21, 2015
    Applicant: Omya International AG
    Inventors: Patrick Gane, Joachim Schoelkopf
  • Publication number: 20150119506
    Abstract: Various processes and methods are disclosed for incorporating polyvinyl alcohol additives into products. In one embodiment, polyvinyl alcohol particles are dissolved in a solvent without the use of external heat to form a polyvinyl alcohol solution for incorporation into a product. In an alternative embodiment, polyvinyl alcohol particles are directly incorporated into a starch-based adhesive composition. Through the processes of the present disclosure, solid polyvinyl alcohol particles can be delivered directly to a manufacturing facility where the product that incorporates the polyvinyl alcohol additive is being made or formulated. In this manner, since the polyvinyl alcohol particles are not predissolved, the costs associated with shipping and transporting the polyvinyl alcohol product are greatly reduced.
    Type: Application
    Filed: January 9, 2015
    Publication date: April 30, 2015
    Inventors: Eduardo Romero-Nochebuena, Martin Craig Hoofnagle, Jose A. Briones, Emily A. Duff
  • Publication number: 20150096698
    Abstract: The present invention concerns a process for preparing self-binding pigment particles from an aqueous suspension of calcium carbonate containing material, wherein an anionic binder and at least one cationic polymer are mixed with the suspension.
    Type: Application
    Filed: May 2, 2013
    Publication date: April 9, 2015
    Inventors: Daniel Gantenbein, Joachim Schoelkopf, Patrick A.C. Gane
  • Publication number: 20150094404
    Abstract: A styrenic composition including a polar modified styrenic co-polymer resulting from the polymerization of a combined mixture of at least one styrenic monomer and at least one comonomer and a biodegradable component is disclosed. The at least one comonomer includes a polar functional group and the polar modified styrenic co-polymer and the biodegradable component are combined to obtain a styrenic composition having a biodegradable component. Also disclosed is a method of enhancing bio-polymer miscibility in a styrenic based polymer. The polarity of a blend is manipulated by combining a styrenic monomer and a polar co-monomer to form a combined mixture and subjecting the combined mixture to polymerization to obtain a styrenic polymer blend to which a bio-polymer is added.
    Type: Application
    Filed: December 10, 2014
    Publication date: April 2, 2015
    Inventors: Wei Wang, David W. Knoeppel, Jose M. Sosa
  • Publication number: 20150059999
    Abstract: The present invention relates to an aqueous calcium carbonate containing composition, to methods for producing such aqueous calcium carbonate containing compositions and to the use of the aqueous calcium carbonate containing composition in paper, paper coating, plastics and/or paint applications and as filler in paper.
    Type: Application
    Filed: March 21, 2013
    Publication date: March 5, 2015
    Inventors: Samuel Rentsch, Daniel E. Gerard, Matthias Buri, Patrick A.C. Gane, Vesa Kukkamo
  • Publication number: 20150045480
    Abstract: An exemplary embodiment of the present invention provides starch-based hot melt adhesive comprised of a composition including starch, a thermoplastic polymer, a tackifier, a plasticizer, and an adhesion promoter. The hot melt adhesive according to the exemplary embodiment of the present invention contains about 25 to 55 weight % of the starch which is infinitely renewable biomass, and, thus, it is less harmful and more eco-friendly and has a reduced manufacturing costs and is less sensitive to exhaustion of petroleum-based resources, as compared with the conventional hot melt adhesive mainly containing a petroleum-based material. Further, the hot melt adhesive according to the exemplary embodiment of the present invention imparts excellent adhesion strength and workability at the time of adhesion between different kinds of adherends such as a hydrophobic adherend and a hydrophilic adherend and can be applied to various fields such as packaging, bookbinding, construction, woodworking, and textile fields.
    Type: Application
    Filed: August 10, 2012
    Publication date: February 12, 2015
    Applicant: DAESANG CORPORATION
    Inventors: Young Seong Jeon, Se Na Lee, Jee Young Yoon, Jun Soo Lee, Ssang Ok Kim
  • Patent number: 8932678
    Abstract: Disclosed is a composition (e.g., a texture composition) comprising, consisting of, or consisting essentially of calcium carbonate and superabsorbent polymer that can absorb at least about 50 times its mass and having a particle size of about 250 microns or less, wherein the composition is substantially free of a setting-type cementitious material. In some embodiments, cellulosic thickener content is reduced or eliminated from the texture composition. Also disclosed is a method of finishing a substrate comprising applying to the surface a wet composition comprising, consisting of, or consisting essentially of calcium carbonate and superabsorbent polymer that can absorb at least about 50 times its mass and having a particle size of about 250 microns or less, wherein the composition is substantially free of a setting-type cementitious material, and drying the composition on the substrate.
    Type: Grant
    Filed: June 18, 2012
    Date of Patent: January 13, 2015
    Assignee: United States Gypsum Company
    Inventor: Jeffrey F. Grussing
  • Publication number: 20140329937
    Abstract: Energy-activated room temperature-pumpable polymer compositions, devices for activating and processing the same into solid cellular or non-cellular polymeric materials that can be used as adhesives, sealants, coatings or gasket materials, and methods of making and using the same. The compositions according to the invention include solid particles that include one or more polymers, which are emulsified, dispersed or suspended in a liquid carrier together with at least one processing aid, such as a reactive blowing agent, a low molecular weight surfactant, a high molecular weight surfactant, one or more compounds found in latex paint, starch, cellulosic derived products and combinations of two or more thereof. The processing aids provide various benefits including, for example, reduced density, improved process hygiene, improved foam stability, faster bonding times and/or lower processing temperatures.
    Type: Application
    Filed: February 13, 2014
    Publication date: November 6, 2014
    Applicant: H.B. FULLER COMPANY
    Inventors: Michael W. Jorgenson, David J. Alessio, Samuel Dipre, Kenneth E. Heyde, Jeffrey C. Krotine, William C. Stumphauzer, Anthony A. Parker, Joseph J. Wolf
  • Publication number: 20140296392
    Abstract: The invention relates to a printing ink system containing glycosidic polymers and polyolefin- and/or Fischer-Tropsch-waxes and/or amide waxes and/or bio-based waxes and optionally pigments, binders and/or solvents. The glycosidic polymer has a specific surface area according to BET from a minimum 0.45 m2/g and a particle size distribution having an uniformity coefficient (D60/D10) to a maximum of 3.5.
    Type: Application
    Filed: August 4, 2012
    Publication date: October 2, 2014
    Applicant: CLARIANT FINANCE (BVI) LIMITED
    Inventors: Sebastijan Bach, Gerd Hohner, Timo Herrlich, Rainer Fell, Daniela True
  • Patent number: 8841363
    Abstract: The present invention relates to copolymers obtainable by free-radical polymerization of i) 10% to 90% by weight, based on the total weight of components i to iv, of at least one monomer selected from the group consisting of a C8-C30 alkyl (meth)acrylate, C8-C30 vinyl ester, C8-C30 vinyl ether, C8-C30 olefin, and triglyceride of unsaturated C8-C30 carboxylic acids; ii) 0.
    Type: Grant
    Filed: October 2, 2009
    Date of Patent: September 23, 2014
    Assignee: BASF SE
    Inventors: Motonori Yamamoto, Ulrike Licht, Dietrich Scherzer
  • Publication number: 20140272300
    Abstract: This invention relates to an aqueous binder composition containing a) at least one polymer P and b) at least one saccharide compound S, such that an amount of the saccharide compound S is ?10 and ?400 parts by weight per 100 parts by weight of polymer P, wherein an amount of an additional formaldehyde-containing binder is ?50 parts by weight per 100 parts by weight of the summed overall amounts of the polymer P and the saccharide compound S. This invention also relates to a process for producing a shaped articles from granular and/or fibrous substrates where an aqueous binder composition of the present invention is applied to the granular and/or fibrous substrate, the granular and/or fibrous substrate thus treated is optionally shaped and then the granular and/or fibrous substrate thus obtained is thermally treated. This invention also relates to shaped articles obtained by a process of the present invention.
    Type: Application
    Filed: May 29, 2014
    Publication date: September 18, 2014
    Applicant: BASF SE
    Inventors: Christian KRUEGER, Ulrich SCHUETZE, Oliver LABISCH
  • Publication number: 20140243458
    Abstract: Provided is a powdery hydrophilic polymer by aggregating a hydrophilic polymer comprising a water-in-oil emulsion in a liquid form by emulsion breaking and granulating the aggregate, followed by drying. As an emulsion breaker, ionic surfactants, nonionic surfactants having an HLB value of 11 to 20, or oil-soluble polymer compounds having a hydrophilic group and a hydrophobic group can be used. The powdery hydrophilic polymer obtained by this method exhibits excellent effects as a flocculating agent.
    Type: Application
    Filed: January 13, 2012
    Publication date: August 28, 2014
    Applicant: HYMO CORPORATION
    Inventors: Manabu Tonami, Kiyoshi Aoyama, Kazuyuki Hirata
  • Patent number: 8809423
    Abstract: The invention relates to a starch based biodegradable material comprising starch, polyvinyl-alcohol-co-vinylacetate copolymer and at least one plasticizer and to articles obtained therefrom particularly suitable to be injection molded.
    Type: Grant
    Filed: December 11, 2007
    Date of Patent: August 19, 2014
    Assignee: Novamont S.p.A.
    Inventors: Catia Bastioli, Angelos Rallis, Roberto Lombi
  • Publication number: 20140110301
    Abstract: A water soluble film useful in unit-dose chemical packaging is disclosed. The film may include: a water soluble saccharide and a polyvinyl alcohol copolymer consisting essentially of: (a) from 80 to 99 mole percent of vinyl alcohol and vinyl ester monomer; and (b) from 1 to 20 mole percent of a pyrrolidone comonomer. Such compositions may be used to provide a water-soluble film simultaneously satisfying requirements in regard to water solubility, biodegradability, and physical properties, even when used for packaging of harsh, oxidizing chemicals.
    Type: Application
    Filed: October 22, 2013
    Publication date: April 24, 2014
    Applicant: SEKISUI SPECIALTY CHEMICALS AMERICA, LLC.
    Inventors: Paula Carrier, Vingh Nguyen, Regan Pollock, Richard Vicari
  • Publication number: 20140079935
    Abstract: A biodegradable, polyolefin-based material composition having incorporated therein thermoplastic starch particles is described. The material includes from about 5% to about 45% of a thermoplastic starch (TPS), from about 55% to about 95% of a polyolefin or mixtures of polyolefins, at least 9% of a compatibilizer and has a bio-based content of 5%-97% using ASTM D6866-10, method B.
    Type: Application
    Filed: March 15, 2013
    Publication date: March 20, 2014
    Applicant: THE PROCTER & GAMBLE COMPANY
    Inventor: Norman Scott Broyles
  • Publication number: 20140061089
    Abstract: Provided is a composition for a starch container, comprising: 20 to 60 weight % of an undenatured starch; 5 to 30 weight % of a pulp fiber powder; 0.1 to 2 weight % of a photocatalyst; 0.5 to 5 weight % of a release agent; and 0.01 to 5 weight % of a capsule type blowing agent preparations; and the remainder being a solvent. Also provided is a starch container using the composition. The above-described composition of the present invention may be used not only as a material for a disposable container which has improved blowing property, and which is lightweight and has improved moldability, but also as a material for an eco-friendly starch container having eco-friendly characteristics.
    Type: Application
    Filed: May 17, 2012
    Publication date: March 6, 2014
    Applicant: YOUL CHON CHEMICAL CO., LTD.
    Inventors: Heon Moo Kim, Kang Soo Kim
  • Publication number: 20140033950
    Abstract: A curable aqueous binder has two primary components. The first component is a bio-based material or mixture of bio-based materials such as starch or polyvinyl alcohol. The second component is one or more compounds selected from the group of urea, polyurea and substituted urea. The first and second components make up most (i.e. 50% or more) of all solids in the binder. The dry weight of the second component is preferably 25% or more of the dry weight of the first component. The solids content of the binder is preferably between 6 wt % and 20 wt %. A method of making a mineral fiber product includes a step of curing a binder as described above in situ on a mass of mineral fibers at a temperature of 175 degrees C. or more. A preferred binder is a mixture of urea and starch in a ratio by weight between 50-50 and 80-20 in water at a solids content of 10-20 wt %, substantially without other components, and may be used as a replacement for formaldehyde or petrochemical based resins.
    Type: Application
    Filed: August 2, 2013
    Publication date: February 6, 2014
    Applicant: Ecosynthetix Ltd.
    Inventor: Uttam Kumar SAHA
  • Publication number: 20140005308
    Abstract: The present invention concerns a method for manufacturing a starch-based plasticized composition comprising starch and a plasticizer said plasticizer comprising 1,3-propanediol (PDO). The invention also concerns a plasticized material comprising the plasticized starch composition of the invention and a polymer.
    Type: Application
    Filed: March 18, 2011
    Publication date: January 2, 2014
    Applicant: METABOLIC EXPLORER
    Inventor: Sophie Macedo Galvaing
  • Publication number: 20130337175
    Abstract: Disclosed is a composition (e.g., a texture composition) comprising, consisting of, or consisting essentially of calcium carbonate and superabsorbent polymer that can absorb at least about 50 times its mass and having a particle size of about 250 microns or less, wherein the composition is substantially free of a setting-type cementitious material. In some embodiments, cellulosic thickener content is reduced or eliminated from the texture composition. Also disclosed is a method of finishing a substrate comprising applying to the surface a wet composition comprising, consisting of, or consisting essentially of calcium carbonate and superabsorbent polymer that can absorb at least about 50 times its mass and having a particle size of about 250 microns or less, wherein the composition is substantially free of a setting-type cementitious material, and drying the composition on the substrate.
    Type: Application
    Filed: June 18, 2012
    Publication date: December 19, 2013
    Applicant: UNITED STATES GYPSUM COMPANY
    Inventor: Jeffrey F. GRUSSING
  • Publication number: 20130289171
    Abstract: A curable aqueous composition that includes a first polymer that includes carboxyl groups, and a second component that includes a second water insoluble polymer and a stabilizer. The second component includes functional groups that react with the carboxyl groups of the first polymer during cure, is free from carboxylic acid groups, or a combination thereof. The composition, when dry, exhibits a first Tg of at least 10° C. and a second Tg of at least 50° C.
    Type: Application
    Filed: April 30, 2012
    Publication date: October 31, 2013
    Applicant: H.B. Fuller Company
    Inventors: Wayne P. Miller, Patrick D. Gleason, Michael Wright
  • Publication number: 20130267632
    Abstract: The invention concerns an aqueous starch-containing polymer dispersion obtainable by co-polymerisation of ethylenically unsaturated monomers comprising: (a) from 20 to 50 wt % of at least one of styrene or substituted styrene; (b) from 20 to 60 wt % t-butyl (meth)acrylate; and, (c) from 0 to 20 wt % of at least one ethylenically unsaturated co-polymerisable monomer being different from (a) and (b), in the presence of (d) from 10 to 50 wt % cationic starch, wherein the sum of (a)+(b)+(c)+(d) is 100%. The invention further concerns preparation and use thereof.
    Type: Application
    Filed: December 12, 2011
    Publication date: October 10, 2013
    Applicant: Akzo Nobel Chemicals International B.V.
    Inventors: Ralf Krückel, Martin Werner
  • Patent number: 8530557
    Abstract: Thermoplastic polymer compositions comprising starch and articles made therefrom are water stable or may be rendered so. One method of making water stable thermoplastic compositions comprises the steps of mixing destructured starch with polyhydric alcohol and acid, and forming an ester condensation reaction product from at least a portion of the polyhydric alcohol and acid. In some embodiments, a pre-polymer formed from the ester condensation reaction may be provided as a pre-polymer that is mixed with the starch.
    Type: Grant
    Filed: July 18, 2012
    Date of Patent: September 10, 2013
    Assignee: The Procter & Gamble Company
    Inventors: Isao Noda, Michael M. Satkowski, William M. Allen, Jr., James T. Knapmeyer
  • Patent number: 8486187
    Abstract: The invention relates to a coating composition comprising at least one binder and a multipurpose additive obtainable by reacting a vegetable oil with a diol or by transesterifying a vegetable oil lower alkyl ester with a diol, both reactions in the presence of a catalyst. The multipurpose additive is used to replace partly the solvent of the coating composition and/or to replace partly the binder thus reducing the VOC content and the viscosity.
    Type: Grant
    Filed: January 9, 2007
    Date of Patent: July 16, 2013
    Assignee: BASF SE
    Inventors: Lothar Alexander Engelbrecht, Roedolph Van Bohemen
  • Publication number: 20130164515
    Abstract: Embodiments of the present invention provide a paper surface sizing composition, a paper web coated on one or more sides or surfaces with a paper surface sizing composition, and a method for treating one or more sides of the paper web with a paper surface sizing composition to impart benefits relating to one or more of the following properties: (1) brightness; (2) opacity; (3) paper smoothness; (4) print quality; (5) optionally ink dry time (e.g., for ink jet printing where the sizing composition has option); and (6) optionally minimizing or eliminating edge welding (e.g., for paper webs used in, for example, form printing).
    Type: Application
    Filed: February 18, 2013
    Publication date: June 27, 2013
    Applicant: INTERNATIONAL PAPER COMPANY
    Inventor: International Paper Company
  • Publication number: 20130157030
    Abstract: The invention relates to a novel binder system and its use for bonding textile fabrics as well as products containing such bonded textile fabrics. The materials of the invention are suitable for the manufacture of lining materials which can be used in the manufacture of sarking membranes, roofing sheets and water-proof sheetings, in particular of coated sarking membranes, roofing sheets and water-proof sheetings, or in the manufacture of carpets and PVC floorings as a textile backing or as a textile reinforcement.
    Type: Application
    Filed: December 14, 2012
    Publication date: June 20, 2013
    Applicant: JOHNS MANVILLE
    Inventor: JOHNS MANVILLE
  • Patent number: 8465622
    Abstract: The present invention relates to a sizing composition that, when applied to paper substrate, creates a substrate, preferably suitable for inkjet printing, having increased print density, enhanced print mottle, as well as print sharpness, low HST, and/or image dry time, the substrate preferably having high brightness and reduced color-to-color bleed as well. In addition, the present invention relates to a method of reducing the HST of a paper substrate by applying the sizing composition to at least one surface thereof. Further, the application relates to methods of making and using the sizing composition, as well as methods of making and using the paper containing the sizing composition.
    Type: Grant
    Filed: November 3, 2011
    Date of Patent: June 18, 2013
    Assignee: International Paper Company
    Inventors: Yan C. Huang, Kapil M. Singh, David B. Shelmidine, Jeff R. Becker, Paul J. Fosco
  • Patent number: 8465584
    Abstract: An aqueous slurry of finely divided fillers which are at least partly coated with anionic latices, wherein the slurry is obtainable by treating an aqueous slurry of finely divided fillers with an aqueous dispersion comprising at least one anionic latex and at least one degraded starch, preparation of the aqueous slurries and their use as an additive to the paper stock in the production of filler-containing paper, filler-containing cardboard or filler-containing board by draining the paper stock.
    Type: Grant
    Filed: November 30, 2009
    Date of Patent: June 18, 2013
    Assignee: BASF SE
    Inventors: Joerg Nieberle, Anton Esser
  • Patent number: 8445564
    Abstract: The present invention provides composite materials derived from aqueous binder compositions comprising defatted soy flour of no greater than 43 micron mesh particle size, polymer particles of at least one emulsion (co)polymer, one or more amino resin, and, optionally, one or more reducing sugar. Also provided are methods of making and using composite materials containing the binder compositions.
    Type: Grant
    Filed: December 10, 2010
    Date of Patent: May 21, 2013
    Assignee: Rohm and Haas Company
    Inventor: Michael DeWayne Kelly
  • Patent number: 8435354
    Abstract: Thermoplastic polymer compositions comprising starch and articles made therefrom are water stable or may be rendered so. One method of making water stable thermoplastic compositions comprises the steps of mixing destructured starch with polyhydric alcohol and triglyceride, and forming a transesterification reaction product from at least a portion of the polyhydric alcohol and triglyceride.
    Type: Grant
    Filed: October 10, 2006
    Date of Patent: May 7, 2013
    Assignee: The Procter & Gamble Company
    Inventors: Isao Noda, Michael M. Satkowski, William M. Allen, Jr., James T. Knapmeyer
  • Publication number: 20130091764
    Abstract: Disclosed are bonding agents useful in the production of pelletized or briquetted fuels. The bonding agents may be incorporated into a feed containing the fuel material, providing both adhesion and cohesion of the fines to produce a uniform and predictable pellet or briquette. Specifically, the bonding composition contains a solubulized starch, a sugar source and/or a diol or polyol compound, and optionally a polymer selected from polyvinyl alcohol (PVOH), PVOH copolymers, polyvinyl acetate (PVA), polyvinyl acetate copolymers (PVAc), ethylene vinyl acetate (EVAc or VAE) or any subset or combination of such polymers. Also disclosed are methods of preparing the bonding agents and to densified and/or torrefied biomass products prepared therewith.
    Type: Application
    Filed: October 17, 2012
    Publication date: April 18, 2013
    Applicant: Momentive Specialty Chemicals Inc.
    Inventor: Momentive Specialty Chemicals Inc.
  • Patent number: 8410200
    Abstract: A polymer composition and its use for thin film packaging applications including on a dry basis: a) from 45 to 90% by weight of starch; b) from 0.1 to 15% by weight of a water soluble polymer selected from polyvinyl alcohol, polyvinylacetate, and copolymers of ethylene and vinyl alcohol which have a melting point compatible with the molten state of the starch component; and c) from 5 to 45% by weight of one or more plasticizers having a molecular weight in the range of 50-6000, more preferably 50-2500 and more preferably still 100-400 and desirably selected from the group consisting of sorbitol, glycerol, maltitol, xylitol, mannitol, erythritol, glycerol trioleate, tributyl citrate, acetyl tri-ethyl citrate, glyceryl triacetate, 2,2,4-trimethyl-1,3-pentanediol diisobutyrate, polyethylene oxide, ethylene glycol, diethylene glycol or polyethylene glycol.
    Type: Grant
    Filed: April 18, 2007
    Date of Patent: April 2, 2013
    Assignee: Plantic Technologies Limited
    Inventors: Nicholas R. Oakley, Nicholas J. McCaffrey, Kishan C. Khemani
  • Publication number: 20130059949
    Abstract: A method of preparing a stable dispersion of flocculated filler particles for use in papermaking processes comprises use of microparticle prior to, simultaneous to, and/or after addition of a first flocculating agent to an aqueous dispersion of filler particles, followed by addition of a second flocculating agent to the dispersion and further optional shearing of the resultant filler flocs to the desired particle size resulting in shear resistant filler flocs with a defined and controllable size distribution. In addition, a neutralizing coagulant can be added to the dispersion to partially or completely neutralize the charge of the filler before the microparticle and/or the first flocculating agent is added.
    Type: Application
    Filed: November 1, 2012
    Publication date: March 7, 2013
    Inventors: Weiguo Cheng, Katherine M. Broadus, Dorota Smoron, Shawnee M. Wilson
  • Publication number: 20120315454
    Abstract: A thermoplastic film composition that includes a polymer blend of multiple inherently incompatible polymer components is described. The composition includes a polymer blend having about 5 wt. % to about 45 wt. % of a plasticized natural polymer, about 5 wt. % to about 40 wt % of a polyolefin, a biodegradable polymer, and a compatibilizer with both a polar and a non-polar moiety on the same polymer molecule. The total plasticized natural and biodegradable polymers constitute a majority or predominant phase (?51 wt. %), while petroleum-based olefinic polymers form the minority phase. The composition can be made into a film containing at least one renewable, natural polymer component. Also described are the articles of manufacture that may use such films.
    Type: Application
    Filed: December 1, 2010
    Publication date: December 13, 2012
    Inventors: James H. Wang, Yan Wang, Xueen George Hao, Tongtong Zhang
  • Publication number: 20120296015
    Abstract: A process for manufacturing a biodegradable composition, involves compounding of at least (a) thermoplastic starch (TPS), (b) a vinyl ester polymer and (c) one or more plasticizer(s) for component (b), wherein the one or more plasticizer(s) (c) and optionally part of the vinyl ester polymer (b) is introduced only when all or a major part of thermoplastic starch is destructurized from granular/native starch. Preferably diacetin is used for plasticizer (c), and introduced only after destructurizing the starch.
    Type: Application
    Filed: October 26, 2010
    Publication date: November 22, 2012
    Applicant: STICHTING KENNIS EXPLOITATIE RB
    Inventors: Jacob Johannes Van Heemst, Erwin Zant, Geraldus Gerardus Johannes Schennink, Jan Arie Rodenburg, Joost Rodenburg, Thijs Rodenburg
  • Publication number: 20120289629
    Abstract: The present invention relates to a method for preparing novel thermoplastic amylaceous compositions, as well as to such thermoplastic amylaceous compositions.
    Type: Application
    Filed: January 14, 2011
    Publication date: November 15, 2012
    Applicant: Roquette Freres
    Inventors: René Saint-Loup, Jérôme Gimenez, Didier Lagneaux
  • Publication number: 20120279421
    Abstract: Thermoplastic polymer compositions comprising starch and articles made therefrom are water stable or may be rendered so. One method of making water stable thermoplastic compositions comprises the steps of mixing destructured starch with polyhydric alcohol and acid, and forming an ester condensation reaction product from at least a portion of the polyhydric alcohol and acid. In some embodiments, a pre-polymer formed from the ester condensation reaction may be provided as a pre-polymer that is mixed with the starch.
    Type: Application
    Filed: July 18, 2012
    Publication date: November 8, 2012
    Inventors: Isao Noda, Michael M. Satkowski, William M. Allen, JR., James T. Knapmeyer
  • Publication number: 20120252936
    Abstract: Binder for granular and/or fibrous substrates
    Type: Application
    Filed: April 2, 2012
    Publication date: October 4, 2012
    Applicant: BASF SE
    Inventors: Christian Krüger, Ulrich Schütze, Oliver Labisch
  • Patent number: 8263689
    Abstract: The invention relates to water-based adhesives for industrial applications obtained by mixing water-redispersible polymer powder and water-soluble polymer powder with water, wherein the weight ratio of the water-redispersible polymer powder to the water-soluble polymer powder is from about 0.001:1 to 100:1 and the water-based adhesive has a set speed of less than 300 sec, when measured with a 36 ?m thick layer at 23° C. and 50% relative humidity and 385 ?m thick carton boards with a weight of 275+/?3 g/m2 and Cobb values on one side of 43 g/min/m2 and 27 g/min/m2 on the other side, has a solids content of about 7.5 to 70 wt.-% and a Brookfield viscosity at 23° C. at 20 rpm, measured according to the ASTM D1084 standard, of about 500 to 10,000 mPas. The water-based industrial adhesive has the capability to bond a low surface tension substrate to a cellulosic substrate, in particular with a weight-ratio of water-redispersible polymer powder to water-soluble polymer powder from about 0.
    Type: Grant
    Filed: September 5, 2006
    Date of Patent: September 11, 2012
    Assignee: Henkel AG & Co. KGaA
    Inventors: Nalini Patel, Rebecca Stopps, Christophe Magnin
  • Publication number: 20120225978
    Abstract: Binder for granular and/or fibrous substrates
    Type: Application
    Filed: February 29, 2012
    Publication date: September 6, 2012
    Applicant: BASF SE
    Inventors: Christian Krüger, Alexander Centner, Oliver Labisch
  • Publication number: 20120216709
    Abstract: Water stable fibers and articles made therefrom are formed from a thermoplastic composition comprising destructured starch, polyhydric alcohol, acid, and optionally triglyceride. Processes for making water stable compositions may comprise melt extruding a mixture of destructured starch, polyhydric alcohol, acid, and optionally triglyceride, to form an extrudate, and heating the mixture, extrudate, or both to provide a water stable article.
    Type: Application
    Filed: May 7, 2012
    Publication date: August 30, 2012
    Inventors: Isao Noda, Michael M. Satkowski, William M. Allen, JR., James T. Knapmeyer
  • Publication number: 20120149813
    Abstract: The present invention provides composite materials derived from aqueous binder compositions comprising defatted soy flour of no greater than 43 micron mesh particle size, polymer particles of at least one emulsion (co)polymer, one or more amino resin, and, optionally, one or more reducing sugar. Also provided are methods of making and using composite materials containing the binder compositions.
    Type: Application
    Filed: December 10, 2010
    Publication date: June 14, 2012
    Inventor: Michael DeWayne Kelly
  • Publication number: 20120139154
    Abstract: A process of producing a thermoplastic starch/polymer blend involves introducing dry starch into a twin-screw extruder at a first location along the extruder, introducing a plasticizer into the twin-screw extruder at a second location along the extruder downstream of the first location to form a starch paste and then gelatinizing the starch paste in the extruder to form thermoplastic starch, and, introducing dry polymer at ambient temperature into the twin-screw extruder at a third location along the extruder downstream of the second location to form a blend with the thermoplastic starch in the extruder.
    Type: Application
    Filed: February 2, 2010
    Publication date: June 7, 2012
    Inventors: Michel Huneault, Hongbo Li
  • Publication number: 20120142823
    Abstract: The invention relates to a blend of one or more biodegradable polymers with one or more impact modifiers, for the purpose of improving the impact properties of the biodegradable polymer(s). The biodegradable polymer is preferably a polylactide or polyhydroxy butyrate. The composition comprises 30-99.9 weight percent of degradable polymer and 0.1 to 15 weight percent of one or more impact modifiers. Haze levels can be controlled by the composition and percentage of impact modifier (or modifiers) selected, to produce a polymer composition having an appearance ranging from translucent to opaque.
    Type: Application
    Filed: November 13, 2007
    Publication date: June 7, 2012
    Inventors: Zuzanna Cygan, Jeffrey Brake