Ethylenic Monomer Contains A Chalcogen Heterocycle Patents (Class 524/531)
  • Patent number: 5705559
    Abstract: Disclosed is a process for preparing crosslinked resin particles which comprises dispersing a resin having both a water-dispersible function and a self-crosslinkable function in one molecule in an aqueous medium and then three-dimensionally crosslinking.
    Type: Grant
    Filed: February 21, 1995
    Date of Patent: January 6, 1998
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Hiroyuki Sakamoto, Kenshiro Tobinaga, Yasuyuki Tsuchiya, Hisaichi Muramoto, Yusuke Ninomiya, Keizou Ishii, Shinichi Ishikura
  • Patent number: 5650233
    Abstract: Disclosed are a photo-setting colored filter composition, a color filter, a process for the preparation thereof, a curable resin, and a curable resin composition. The photo-setting colored filter composition of the present invention has an excellent photo-curability, miscibility in the composition, and developability.The curable resin composition is excellent in stability of the composition, tackiness, developability, sensitivity, anti-strippability, and hydrolysis resistance compared to conventional curable resin compositions.
    Type: Grant
    Filed: January 2, 1996
    Date of Patent: July 22, 1997
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Hiroto Miyake, Koichi Okumura, Toshio Endo
  • Patent number: 5589534
    Abstract: An aqueous coating composition is provided which comprises a generally lipophilic crosslinkable binder, optionally a chemical curing/crosslinking agent for the crosslinkable binder, and a special reactive amphiphatic emulsifier comprising a lipophilic backbone having separately pendant therefrom (a) at least one activated unsaturated group and (b) at least one of a specified class of hydrophilic polyoxyalkylene groups, and possessing an HLB value of at least 6.0.
    Type: Grant
    Filed: January 10, 1994
    Date of Patent: December 31, 1996
    Assignee: Akzo Nobel N.V.
    Inventors: Carl W. Metzger, Bernhard H. Feith, Ute Gruber, Angelika A. Zedler, Mario M. M. van Wingerde
  • Patent number: 5559192
    Abstract: An air curing polymer composition is disclosed which contains acetoacetate functional polymer and an autoxidizable material. The composition cures on exposure to oxygen. One pack stable ambient curing compositions and a method of stabilizing acetoacetate functional groups to prevent hydrolysis are also disclosed.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: September 24, 1996
    Assignee: Rohm and Haas Company
    Inventors: Daniel A. Bors, Alvin C. Lavoie, William D. Emmons
  • Patent number: 5548018
    Abstract: An aqueous primer composition comprising a copolymer wherein a cationic monomer, a specific alkoxysilane monomer, a silane macromonomer and an ethylenically unsaturated monomer are contained in aqueous medium. For this reason, regardless of the alkalinity of the substrate, the aqueous primer composition can form a highly water-resistant, alkali-resistant, tough film. Furthermore, compared with the prior art, a higher concentration and a lower viscosity, so that the resulting primer composition shows excellent penetration into the substrate at high concentration and provides for sufficient substrate-reinforcing and water-proofing effects. Moreover, when forming a film thereby and forming a finish layer thereon, this composition shows a high affinity for the top coating or adhesive to insure a firm integration of the finish layer with the substrate surface.
    Type: Grant
    Filed: May 19, 1995
    Date of Patent: August 20, 1996
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventor: Masao Maekawa
  • Patent number: 5512633
    Abstract: Copolymers of vinyl aromatic monomers and propoxylated allyl alcohols having an average of 2 or less oxypropylene groups are disclosed. The copolymers, which have hydroxyl numbers of 80-260 mg KOH/g and number average molecular weights from 500-3500, are particularly useful for polyurethanes, alkyd resins and coatings, melamine-based coatings, and unsaturated polyester resins.
    Type: Grant
    Filed: April 12, 1995
    Date of Patent: April 30, 1996
    Assignee: Arco Chemical Technology, L.P.
    Inventor: Shao-Hua Guo
  • Patent number: 5494954
    Abstract: An organic colloidal dispersion of polar polymeric microparticles synthesized directly in a non-aqueous polar medium is disclosed. The dispersion is particularly useful for controlling rheological properties such as sag and metallic flake orientation in coating compositions.
    Type: Grant
    Filed: November 21, 1994
    Date of Patent: February 27, 1996
    Assignee: PPG Industries, Inc.
    Inventors: Suryya K. Das, Soner Kilic
  • Patent number: 5486561
    Abstract: There is disclosed a polypropylene resin composition which comprises (a) polypropylene; (b) ethylene/.alpha.-olefin copolymer elastomer having a specific range of Mooney viscosity; (c) modified polyolefin having a specific functioal group at either or both end thereof; and (d) specific compound such as stearic acid monoglyceride, stearyl diethanolamine, N-diethanol stearylamide and N-diethanol dodecanaeamide. The above composition is excellent in elasticity, peeling strength and recoating properties, can be painted immediately after degreasing without pretreatment with trichloroethane, etc. and is well suited for polypropylene bumper materials to be painted, etc.
    Type: Grant
    Filed: April 21, 1993
    Date of Patent: January 23, 1996
    Assignee: Idemitsu Petrochemical Co., Ltd.
    Inventors: Koki Hirano, Ryuichi Ohki, Yutaka Kobayashi
  • Patent number: 5482991
    Abstract: Novel pressure-sensitive adhesives are described which show significant resistance to solvents and working fluids such as jet fuel, hydraulic fluid, de-icing fluid and the like. Adhesive compositions comprise nonaqueous dispersions of copolymers of acrylic monomers prepared in the presence of a vinyl-substituted fluoroalkyl siloxane having the general formula I and a macromonomeric stabilizer. The adhesives prepared from the adhesive compositions exhibit excellent adhesion to glass, aluminum, and low surface-energy materials such as fluoroalkyl siloxane elastomers.
    Type: Grant
    Filed: September 16, 1994
    Date of Patent: January 9, 1996
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Ramesh C. Kumar, Albert I. Everaerts, Yvan A. Bogaert
  • Patent number: 5468787
    Abstract: A curable composition of a monomeric heterocyclic acrylic or methacrylic ester and an acrylate or methacrylate polymer is used to promote tissue repair, especially cartilage repair.
    Type: Grant
    Filed: June 16, 1994
    Date of Patent: November 21, 1995
    Inventors: Michael Braden, Sandra Downes, Mangala P. Patel, Kenneth W. M. Davy
  • Patent number: 5447970
    Abstract: An aqueous dispersed resin composition is disclosed, comprising (A) an aqueous dispersion of carbonyl-containing resin particles having an inner layer and an outermost layer, which is obtained by emulsion polymerization of a monomer mixture comprising (a) not less than 0.5% by weight of a carbonyl-containing monomer containing at least one aldo group or keto group and one polymerizable unsaturated double bond in the molecule thereof, (b) not less than 0.5% by weight of an ethylenically unsaturated carboxylic acid, (c) not more than 99% by weight of a monomer having a water-solubility of not more than 8 g/100 ml at 20.degree. C.
    Type: Grant
    Filed: April 7, 1994
    Date of Patent: September 5, 1995
    Assignee: Mitsubishi Yuka Badische Co., Ltd.
    Inventors: Toyoji Tomita, Masahiro Aoki, Takeo Tsukamoto, Takeshi Awata, Ryutaro Hayashi
  • Patent number: 5426149
    Abstract: Glass reinforced of epoxy modified styrene/styrene copolymer and one or more polymers of styrene, are provided.Methods of making these blends and articles made therefrom are provided.
    Type: Grant
    Filed: November 15, 1993
    Date of Patent: June 20, 1995
    Assignee: Phillips Petroleum Company
    Inventor: Randy J. Skarlupka
  • Patent number: 5412022
    Abstract: A lyo gel is provided in which the gelling agent is an organic, fully synthetic polymer, which is crosslinked via its carboxylic acid groups and via metal compounds, and the swelling agent is a low-volatility, inert organic liquid having a volatility, as defined by its evaporation loss, of less than 0.5% by weight after 2 hours at 105.degree. C. in accordance with ASTM D 972. The lyo gel is useful for sealing devices involving the use of electrical current because the initially two-component reaction solution is sufficiently liquid at room temperature to fill even small spaces, such as gaps and joints between bodies.
    Type: Grant
    Filed: June 14, 1993
    Date of Patent: May 2, 1995
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Johannes Andres, Juergen Wichelhaus, Reimar Heucher
  • Patent number: 5393824
    Abstract: Compositions are disclosed that are the urea derivatives of succinylated polyolefins (maleated polyolefins). The urea derivatives of succinylated polyolefins are of the formula; ##STR1## wherein R is a polyolefin attached at any point along the hydrocarbon chain. The urea derivative of succinylated polyolefins is useful as a coupling agent to couple polyolefins with dissimilar polymers having an excess of unreacted acid groups such as polyesters.
    Type: Grant
    Filed: June 27, 1994
    Date of Patent: February 28, 1995
    Assignee: Eastman Chemical Company
    Inventor: Thomas D. Roberts
  • Patent number: 5342915
    Abstract: Aqueous dispersions contain a polyurethane which consists essentially ofa) organic polyisocyanates and, if required, minor amounts of monoisocyanates,b) dihydroxy compounds having a molecular weight of from more than 500 to 10,000 g/mol and at least 2 carboxyl or carboxylate groups in the molecule and which are obtainable by reacting dihydroxy compounds with tetracarboxylic dianhydrides in a molar ratio of from 2:1 to 1.05:1,c) if required, polyhydroxy compounds which differ from (b) and have a molecular weight of from more than 500 to 5,000 g/mol,d) if required, compounds having at least one group which is reactive toward isocyanate and at least one anionic group or group convertible into an anionic group and having a molecular weight of from 60 to 500 g/mol ande) if required, compounds which differ from d) and e) and have at least 2 groups which are reactive toward isocyanate and a molecular weight of from 60 to 500 g/mol.
    Type: Grant
    Filed: December 9, 1992
    Date of Patent: August 30, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Ulrike Licht, Karl Haeberle, Erich Gulbins, Maria G. Rau, Gernot Franzmann, Michael Portugall
  • Patent number: 5336712
    Abstract: This invention is a process for producing stable polymer emulsions and latexes with an average particle size of less than one micron. The polymers are block copolymers of conjugated dienes and vinyl aromatic hydrocarbons which may or may not contain polar functionality. The process comprises making a polymer cement of the polymer and a blend of a solvent for the polymer and a cosolvent(s), emulsifying the polymer cement by adding it to an aqueous phase containing at least one surfactant and removing the solvent, cosolvent and excess water.
    Type: Grant
    Filed: March 23, 1993
    Date of Patent: August 9, 1994
    Assignee: Shell Oil Company
    Inventors: David M. Austgen, Jr., Jeffrey G. Southwick
  • Patent number: 5306757
    Abstract: Disclosed is an emulsified alkenylsuccinic acid sizing agent useful for acid papermaking. The sizing agent has a solid concentration of at least 25% by weight and comprises an alkenylsuccinic acid which is the reaction product of a branched internal olefin and maleic anhydride and which has been dispersed in water by an emulsifying and dispersing agent comprising polyvinyl alcohol. The sizing agent results in good storage stability and has an excellent sizing effect at a low addition ratio immediately after completion of high-temperature papermaking and over a wide pH range.
    Type: Grant
    Filed: December 21, 1992
    Date of Patent: April 26, 1994
    Assignee: Mitsubishi Oil Co., Ltd.
    Inventors: Shigeto Hatanaka, Yoshio Takahashi, Hideto Umekawa
  • Patent number: 5304464
    Abstract: The present invention relates to a macromolecule of proteinaceous nature which activates sperm motility, a process for the preparation thereof by purification of the macromolecule from extracellular fluids, pharmaceutical preparations containing the macromolecule and antibodies directed against determinants specific to the macromolecule and the use thereof as a method to assay the potential fertility of sperm.
    Type: Grant
    Filed: November 27, 1991
    Date of Patent: April 19, 1994
    Assignees: Eva Akerlof, Ake Pousette, Applied Research Systems ARS Holding N.V.
    Inventors: Eva Akerlof, Ake Pousette
  • Patent number: 5256705
    Abstract: A composition including a gel, water absorbent hydrocarbon polymer with pendant anionic groups and a tackifier. The gel composition is activated with moisture so that the water absorbent composition migrates to engage and absorb the water. The composition is used as a protective filling around communication wires prior to wrapping and as a filling inside the cable cover containing the wires. The composition eliminates shorts caused by moisture contact with such wires.
    Type: Grant
    Filed: August 28, 1989
    Date of Patent: October 26, 1993
    Assignee: WaterGuard Industries, Inc.
    Inventor: Clarence S. Freeman
  • Patent number: 5252674
    Abstract: Graft polymers having graft shells of copolymers of styrenes, .alpha.-methyl styrenes, acrylonitrile, C.sub.1 -C.sub.4 vinyl carboxylic acids, C.sub.1 -C.sub.8 alkyl acrylates and/or alkyl methacrylates, maleic acid derivatives, vinyl(idene) chloride and mixtures thereof on the one hand and monomers corresponding to formula I ##STR1## in which R.sup.1 =H, CH.sub.3,R.sup.2 =C.sub.1 -C.sub.8 alkylene,R.sup.3 =C.sub.1 -C.sub.4 alkylon the other hand andgraft bases of particulate diene and/or acrylate rubbers having particle diameters (d.sub.50) of from 80 to 800 nm, and thermoplastic molding compounds containing these graft polymers.
    Type: Grant
    Filed: January 2, 1990
    Date of Patent: October 12, 1993
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karl-Erwin Piejko, Christian Lindner, Gerd Fengler, Hans-Eberhard Braese, Jurgen Kirsch
  • Patent number: 5248705
    Abstract: A method for forming a porous carbonaceous preform comprises, forming a mixture comprised of up to about 50 volume percent of furfuryl alcohol or tetrahydrofurfuryl alcohol, about 1 to 10 volume percent of a nonionic polyethylene oxide polymer ranging in molecular weight from about 100,000 to 5,000,000, about 30 to 80 volume percent of a carbonaceous material, and the balance water. The mixture is cast to form a body, and heated to decompose the polymer and form the porous preform. A molding composition for carbonaceous material comprises, up to about 50 volume percent of furfuryl alcohol or tetrahydrofurfuryl alcohol, about 1 to 10 volume percent of a nonionic polyethylene oxide polymer ranging in molecular weight from about 100,000 to 5,000,000, about 30 to 80 volume percent of the carbonaceous material, and the balance water.
    Type: Grant
    Filed: March 29, 1993
    Date of Patent: September 28, 1993
    Assignee: General Electric Company
    Inventors: Henry C. McGuigan, William B. Hillig, Peter J. Merschter
  • Patent number: 5240544
    Abstract: An adhesive composition comprising a modified, ethylene/.alpha.-olefin copolymer rubber or a modified, ethylene/.alpha.-olefin/non-conjugated diene copolymer rubber containing 0.1-10% by weight of at least one member selected from the group consisting of an acid anhydride and a dicarboxylic acid, and, if necessary, as an amine compound,(i) 0.2-2 moles of a dialkylamine per mole of the acid anhydride in said modified copolymer rubber when said modified copolymer rubber contains no dicarboxylic acid;(ii) 0.2-2 moles of a polyamine compound per mole of the total amount of the acid anhydride and the dicarboxylic acid in said modified copolymer rubber; or(iii) 0.2-2 moles of a dialkylamine per mole of the acid anhydride in said modified copolymer rubber and 0.2-2 moles of a polyamine compound per mole of the acid anhydride in said modified copolymer rubber when said modified copolymer rubber contains no dicarboxylic acid.
    Type: Grant
    Filed: April 17, 1992
    Date of Patent: August 31, 1993
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Yoshio Tanimoto, Nobuyuki Yoshida, Mitsuji Tsuji, Eiichi Usuda, Kouji Satou
  • Patent number: 5216074
    Abstract: A thermoplastic elastomer composition comprising 99-1 parts by weight of (i) a hydrogenated diene polymer which is a hydrogenation product of a straight or branched chain block copolymer consisting of (C) a polybutadiene block segment having a 1,2-vinyl content of not more than 20% and (D) a block segment which is a polybutadiene or an alkenyl aromatic compound-butadiene copolymer, the butadiene portion of which has a 1,2-vinyl content of 25-95% and 1-99 parts by weight of (ii) at least one of a thermoplastic resin or a rubbery polymer.
    Type: Grant
    Filed: July 13, 1990
    Date of Patent: June 1, 1993
    Assignee: Japan Synthetic Rubber Co., Ltd.
    Inventors: Takateru Imai, Masanobu Nagano, Masaaki Mawatari, Toshio Teramoto, Minoru Hasegawa
  • Patent number: 5214080
    Abstract: A process for the production of a nonaqueous dispersion-type resin having excellent dispersion stability and a uniform particle size, which comprises uniformly polymerizing in an aliphatic and/or alicyclic hydrocarbon-type organic solvent a vinyl monomer having a solubility parameter different by 1.1 or more from that of said organic solvent, or a vinyl monomer mixture containing at least 1% by weight of said monomer and a reactive resin soluble in said hydrocarbon-type organic solvent and having a molecular weight of 2,000 or more, and then replacing the organic solvent in the obtained uniform polymer solution with another organic solvent that does not dissolve the nonaqueous dispersion-type resin to thereby conduct phase inversion into a non-aqueous dispersion.
    Type: Grant
    Filed: December 19, 1991
    Date of Patent: May 25, 1993
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Goro Iwamura, Hidetoshi Konno, Akio Shoji
  • Patent number: 5128417
    Abstract: A modified 3-methylbutene-1 polymer as prepared by grafting a monomer containing an unsaturated group onto a 3-methylbutene-1 homo- or copolymer, a 3-methylbutene-1 polymer composition comprising a 3-methylbutene-1 polymer and a fibrous material, and a molded article comprising a mold of a 3-methylbutene-1 polymer and a thin metallic layer provided on the mold.
    Type: Grant
    Filed: June 18, 1990
    Date of Patent: July 7, 1992
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Yoshinori Suga, Eiji Tanaka, Nobuo Enokido, Yasuo Maruyama
  • Patent number: 5120795
    Abstract: A) 100 parts by weight of at least one finely divided plastic which consists ofa) from 30 to 100% by weight of methyl methacrylate (monomer I),b) from 0 to 70% by weight of an acrylate of a C.sub.1 -C.sub.8 alkanol or of a methacrylate of a C.sub.2 -C.sub.8 -alkanol or of a mixture of these monomers (monomers II),c) from 0 to 15% by weight of an .alpha.,.beta.-monoethylenically unsaturated mono- and/or dicarboxylic acid of 3 to 5 carbon atoms (monomers III),d) from 0 to 20% by weight of copolymerizable monomers which contain at least one nitrogen base group and/or one hyroxyl group (monomers IV) ande) from 0 to 5% by weight of other copolymerizable monomers (monomers V), in polymerized form,B) from 30 to 300 parts by weight of at least one polymer which consists ofa) from 5 to 100% by weight of glycidyl acrylate and/or methacrylate (monomers VI),b) from 0 to 95% by weight of an acrylate or methacrylate of a C.sub.1 -C.sub.
    Type: Grant
    Filed: December 15, 1989
    Date of Patent: June 9, 1992
    Assignee: BASF Aktiengesellschaft
    Inventors: Ulrich Filges, Oral Aydin, Hermann Anders
  • Patent number: 5110857
    Abstract: Ultravioletsetting resin composition contains fragmentary quartz glass powder in the ratio of 50 to 200 parts to 100 parts of the ultravioletsetting resin. The surface hardness of the ultravioletsetting resin of the present invention is increased in a short time by the application of ultraviolet rays.
    Type: Grant
    Filed: March 23, 1990
    Date of Patent: May 5, 1992
    Assignee: Aisin Seiki Kabushiki Kaisha
    Inventors: Akio Inagaki, Kiyotaka Nakai, Hitoshi Tauchi
  • Patent number: 5093399
    Abstract: A process for preparing a free-flowing powder is disclosed, which powder is useful in primer compositions. The process comprises the steps of (a) dissolving a polar group-containing modified propylene polymer (MPP) at an elevated temperature in a solvent for the MPP, (b) cooling the solution to precipitate particles of the MPP, (c) collecting the precipitated particles by simultaneously centrifuging and spraying the particles with a liquid capable of removing the solvent from the particles and which is also a solvent for a film forming resin, such as an epoxy, which is present in the primer composition, (d) continuing step (c) until substantially all of the solvent for the MPP has been removed from the particles, and (e) collecting the resulting powder, which has an average particle size of less than about 5 microns.
    Type: Grant
    Filed: December 14, 1989
    Date of Patent: March 3, 1992
    Assignee: Morton International, Inc.
    Inventor: Richard L. Brook
  • Patent number: 5091487
    Abstract: A vinyl chloride resin for safety glass, comprising either particles of a copolymer of a vinyl chloride monomer and an epoxy-containing monomer, having a particle diameter up to 5 .mu.m and a greater epoxy content in an outer portion than in a an inner portion of the particles, or agglomerates of the particles, and process for the preparation of this resin, comprising either adding an epoxy-containing monomer into a polymerization reaction mixture of a vinyl chloride monomer substantially during a latter half of the polymerization reaction of the polymerization mixture or adding an epoxy-containing monomer and a vinyl chloride monomer either in the form of a mixture solution or separately but at the same time into a polymerization mixture of the vinyl chloride monomer.
    Type: Grant
    Filed: May 8, 1990
    Date of Patent: February 25, 1992
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Toshihiko Hori, Eitaro Nakamura, Toyoichi Arai
  • Patent number: 5087666
    Abstract: There are provided compositions comprising poly(arylene sulfide), polymeric rubber, polyethylene, and carboxylic anhydride; and methods for making these compositions. Articles produced from the compositions have reduced shrinkage and improved impact strength.
    Type: Grant
    Filed: July 10, 1990
    Date of Patent: February 11, 1992
    Assignee: Phillips Petroleum Company
    Inventors: Michael C. Yu, John B. Allison
  • Patent number: 5073600
    Abstract: A process is provided according to the present invention comprising the steps of: functionalizing a base polymer by grafting alpha-beta unsaturated carboxylic acid, anhydride or ester to a base polymer, the base polymer being selected from the group of hydrogenated polymer of a conjugated diolefin and a copolymer of conjugated diolefins and monoalkenyl arenes, the grafting being performed in a blending device capable of imparting high mechanical energy and in the presence of 3 to 15 percent by weight, based on base polymer, of a suitable diluent oil; reacting the functionalized polymer with an amine; and recovering an animated polymer. This process results in a lower level of scission, crosslinking and coupling than processes which are essentially oil free. The product of this process is an excellent lubricating oil viscosity index improver and additionally has dispersant characteristics.
    Type: Grant
    Filed: October 12, 1989
    Date of Patent: December 17, 1991
    Assignee: Shell Oil Company
    Inventors: John Eugene Gorman, John A. Morris
  • Patent number: 5011871
    Abstract: An impact resistance thermoplastic molding composition contains, each percentage being based on A+B, from 80 to 55% by weight of a hard matrix A of a copolymer containing at least 95% by weight of an aromatic vinyl monomer a.sub.11 of from 8 to 10 carbon atoms and at least one comonomer a.sub.12 in a proportion of 0.1 to 5% by weight, based on A, and from 45 to 20% by weight of a soft phase B which, uniformly dispersed in the hard matrix, has an average particle diameter d.sub.50 (volume average) of from 3.5 to 9 .mu.m and is obtainable by polymerization of the mixture of monomers a.sub.11 and a.sub.12 in the presence of an elastomer (rubber) and subsequent isolation of the useful product, wherein the comonomer a.sub.12 has the general formula I ##STR1## where X is --OR.sup.2, --COOR.sup.2 or --CONHR.sup.3,R.sup.1 is hydrogen or methyl andR.sup.2 and R.sup.3 are each alkyl of from 1 or 2 to 10 carbon atoms with at least one OH or epoxy group or at least one other polar group.
    Type: Grant
    Filed: March 15, 1989
    Date of Patent: April 30, 1991
    Assignee: BASF Aktiengesellschaft
    Inventors: Rainer Bueschl, Adolf Echte, Konrad Schulte, Hans Mittnacht
  • Patent number: 4997875
    Abstract: Disclosed is a composition comprising about from 20 to 65 percent by weight of a fiber reinforcing-agent, preferably glass fiber, dispersed in as-polymerized propylene polymer material, e.g., propylene homopolymer, having a melt flow rate (MFR) of about from 55 to 430 dg/min. The composition is useful in the manufacture of large and complex fiber-reinforced articles and parts by injection molding.
    Type: Grant
    Filed: March 31, 1989
    Date of Patent: March 5, 1991
    Assignee: Himont Incorporated
    Inventors: Kathleen A. Geddes, Ralph A. Guyer, Richard C. Miller
  • Patent number: 4988759
    Abstract: A coating composition which cures at ambient temperatures and contains 20-80% by weight of a binder and 80-20% by weight of a solvent for the binder, wherein the binder contains about:A. an acrylic polymer A of polymerized monomers of methyl methacrylate and monomers of styrene, alkyl methacrylate and/or alkyl acrylate each having 2-12 carbon atoms in the alkyl group and said polymer having pending from the polymer backbone aminoester groups, hydroxy aminoester groups or hydroxyamine groups,B. an acrylic crosslinking polymer B of polymerized monomers of at least 3% by weight, based on the weight of the crosslinking polymer, of a glycidyl constituent of glycidyl methacrylate or acrylate and the remainder of the monomers are alkyl methacrylate an acrylate each having 1-12 carbon atoms in the alkyl group and optionally contains at least 3% by weight, based on the weight of the crosslinking polymer, of an alkyl methacrylate or acrylate having a pendent group of the formula ##STR1## C.
    Type: Grant
    Filed: September 26, 1989
    Date of Patent: January 29, 1991
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Herman C. Den Hartog, George T. Palmer, Ara G. Yeramyan
  • Patent number: 4987177
    Abstract: A coating composition which cures at ambient temperatures and contains 20-80% by weight of a binder and 80-20% by weight of a solvent for the binder, wherein the binder contains about:A. 60-80% by weight, based on the weight of the binder, of an acrylic polymer A of polymerized monomers of methyl methacrylate and monomers of styrene, alkylmethacrylate and/or alkyl acrylate each having 2-12 carbon atoms in the alkyl group and said polymer having pending from the polymer backbone aminoester groups, hydroxy aminoester groups or hydroxyamine groups,B.
    Type: Grant
    Filed: July 18, 1989
    Date of Patent: January 22, 1991
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Herman C. Den Hartog, George T. Palmer
  • Patent number: 4980412
    Abstract: Aqueous solutions or dispersions of self-crosslinking binders based on ionically modified polycarboxylic acid polyanhydrides, wherein the binders dissolved or dispersed in water have(a) a total content of lateral carboxylic acid ester, carboxylic acid thioester or carboxylic acid amide groups of up to 500 milliequivalents per 100 grams solids,(b) a content of chemically incorporated carboxylate groups of from 10 to 500 milliequivalents per 100 grams solids and(c) a content of ammonium groups of from 10 to 500 milliequivalents per 100 grams solids,are prepared which comprises a first reaction step wherein polyanhydrides (A) containing intramolecular carboxylic anhydride groups are at least partly reacted, with or without inert solvents, with blocked amines (B) which are activatible by water and which, in addition to blocked amino groups, contain at least one anhydride-reactive hydroxy, mercapto or amino group, in a molar ratio of anhydride groups to anhydride-reactive groups of 10:1 to 0.
    Type: Grant
    Filed: November 27, 1989
    Date of Patent: December 25, 1990
    Assignee: Bayer Aktiengesellschaft
    Inventor: Harald Blum
  • Patent number: 4927871
    Abstract: Disclosed is a process for producing a modified ultrahigh-molecular-weight polyolefin composition, which comprises mixing a powder of an ultrahigh-molecular-weight polyolefin (A) having an intrinsic viscosity of at least 5 dl/g, a flowability improver (B) having a melting point lower than the melting point of the ultrahigh-molecular-weight polyolefin (A), a monomer (C) having an olefinically unsaturated bond and a radical initiator (D) with stirring at the melting point of the flowability improver (B) or a higher temperature but below the melting point of the ultrahigh-molecular-weight polyolefin (A), and then melt-kneading them at the melting point of the ultrahigh-molecular-weight polyolefin (A) or a higher temperature to react the monomer (C) with the ultrahigh-molecular-weight polyolefin (A).
    Type: Grant
    Filed: July 15, 1988
    Date of Patent: May 22, 1990
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Yoshiji Ohori, Hirofumi Harazoe
  • Patent number: 4818792
    Abstract: A high solids, stable, nonaqueous dispersion, comprising a low Tg copolymer, having a Tg between about -10.degree. C. and about 30.degree. C., particularly adapted for use as a clear coat automotive finish. The copolymer is the copolymerization product of monomers whose Tg is above about 50.degree. C., polar monomers whose Tg is up to about 15.degree. C. and .alpha., .beta. ethylenically unsaturated stabilizer copolymers. The stabilizer copolymers are formed from .alpha., .beta. ethylenically unsaturated monomers and at least one oxirane containing compound and have a molecular weight of about 2,000 to about 25,000, are soluble in aliphatic solvents and have a Tg of about -60.degree. C. to about 0.degree. C. These nonaqueous dispersions result in coatings having high % solids, ease of application, minimal sagging and good gloss and DOI. They are preferably made by copolymerizing ethylenically unsaturated monomers with about 0.
    Type: Grant
    Filed: April 14, 1987
    Date of Patent: April 4, 1989
    Assignee: BASF Corporation
    Inventors: Glenn E. Martin, Timothy D. Salatin, Vincent C. Cook
  • Patent number: 4816503
    Abstract: Polymer concretes having a high bond strength and/or long working times are made from a curable composition of norbornyl modified unsaturated polyester or polyesteramide resins blended with a polymerizable monomer such as styrene, an aggregate mixture such as sand and gravel and an effective amount of styrene acrylonitrile copolymers, styrene alphamethylstyrene copolymers, or a styrene acrylonitrile copolymer mixture with no more than 25% by weight polystyrene.
    Type: Grant
    Filed: April 8, 1987
    Date of Patent: March 28, 1989
    Assignee: The Dow Chemical Company
    Inventors: William C. Cunningham, Randy A. Ramsey, Randal E. Autenrieth
  • Patent number: 4795792
    Abstract: A copolymer of an olefin and maleic anhydride is produced in the form of particles by co-polymerizing an olefin having 2 to 8 carbon atoms with maleic anhydride in a solvent capable of dissolving both co-monomers, but incapable of dissolving the copolymer in the presence of a dispersant of an oil-soluble, cationic copolymer comprising (a) ethylenically unsaturated monomer units having cationic groups of a quaternary ammonium salt and (b) lipophilic, ethylenically unsaturated monomer units.
    Type: Grant
    Filed: April 28, 1988
    Date of Patent: January 3, 1989
    Assignee: Kao Corporation
    Inventors: Shoji Ohtani, Yoshiyuki Muroi, Rikio Tsushima
  • Patent number: 4755553
    Abstract: A primer composition composed of 1 to 100 parts by weight of a chlorinated carboxyl group-containing .alpha.-olefin polymer and 100 parts by weight of an organic solvent therefor, the improvement wherein(i) said chlorinated carboxyl group-containing .alpha.-olefin polymer is a post-chlorination product [C] of a graft-modified propylene polymer [B] having a chlorine content of 10 to 35% by weight, said graft-modified propylene polymer [B] having an acid value of 6 to 187 mg-KOH/g-polymer and obtained by grafting an unsaturated dicarboxylic acid anhydride to a propylene polymer [A] having an intrinsic viscosity [.eta.], determined at 135.degree. C. in decalin, of 0.6 to 10 dl/g and comprising 70 to 100 mole % of propylene and 0 to 30 mole % of an .alpha.-olefin other than propylene, and(ii) said solvent is an organic solvent boiling at about 60.degree. to about 200.degree. C.
    Type: Grant
    Filed: October 23, 1986
    Date of Patent: July 5, 1988
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Kotaro Kishimura, Riichiro Nagano
  • Patent number: 4742121
    Abstract: Improved coating compositions which incorporate acrylate resins having multiple carbon-to-carbon bond unsaturation attached to the polymer chain through ester and/or urethane linkage are derived from the reaction product of:(1) an acrylate resin having multiple epoxide functionality attached to the polymer chain through an ester or ether linkage reacted with an unsaturated carboxylic acid preferably acrylic or methacrylic acid; or(2) an acrylate resin having multiple hydroxyl group functionality reacted with an organoisocyanate having 0.5 to 1.0 unit of carbon-to-carbon unsaturation per mole of isocyanate.Such coatings are particularly useful in formulating gel coat composites which exhibit hydrolytic stability and good weatherability.
    Type: Grant
    Filed: November 7, 1986
    Date of Patent: May 3, 1988
    Assignee: The Glidden Company
    Inventor: Perry A. Toman
  • Patent number: 4711927
    Abstract: Aqueous ink compositions are disclosed which are an admixture a colorant, a resin binder which is the Diels-Alder adduct of maleic anhydride and 2,3- and 6,7-poly(alloocimene) or the partial-ester thereof and a solvating proportion of water. The inks are useful in flexographic and gravure printing.
    Type: Grant
    Filed: November 12, 1986
    Date of Patent: December 8, 1987
    Assignee: Union Camp Corporation
    Inventors: Mark S. Pavlin, James C. West
  • Patent number: 4704427
    Abstract: A method for improving the physical properties of a rubber having --C(CH.sub.3).dbd.C-- type unsaturated bonds, characterized by subjecting said rubber to two reactions consisting of a modification reaction by Lewis acid and a carboxylation reaction in any desired order.
    Type: Grant
    Filed: March 27, 1986
    Date of Patent: November 3, 1987
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Shizuo Kitahara, Fujito Nakakawaji
  • Patent number: 4670504
    Abstract: There is provided a tackifier composition especially suited for use with natural rubber latex and formed from an olefin resin, preferably a polymerized terpene hydrocarbon resin condensed with an unsaturated carboxylic acid or anhydride, optionally partially esterified with a C.sub.1 -C.sub.30 alcohol or phenol, and neutralized with a base, preferably a volatile base such as an amine, and then dispersed in an aqueous medium. The tackifier when added to a latex forms compositions useful particularly as pressure sensitive adhesives.
    Type: Grant
    Filed: July 8, 1985
    Date of Patent: June 2, 1987
    Assignee: Sylvachem Corporation
    Inventors: Carlos G. Cardenas, James M. Evans, Charles J. Stark, William J. Ehmann
  • Patent number: 4629754
    Abstract: A binder composition which is pigmentable comprising from 30 to 99 wt % of a mineral lubricating oil extract and from 70 to 1 wt % of a petroleum resin and/or coumarone-indene resin, characterized in that the petroleum resin and/or coumarone-indene resin contains moieties derived from carboxylic acid, carboxylic acid anhydride or hydroxyl groups.
    Type: Grant
    Filed: September 23, 1985
    Date of Patent: December 16, 1986
    Assignee: Shell Oil Company
    Inventors: Johannes L. M. Syrier, Willem C. Vonk, Gerrit van Gooswilligen
  • Patent number: 4611015
    Abstract: Polymer concrete compositions comprising an unsaturated thermosettable resin(s) and/or ethylenically unsaturated monomer(s), an aggregate component and a water absorbent polymer are cured to provide polymer concrete with enhanced adhesion to substrates, especially wet concrete. A primer or coating composition for concrete comprising a water absorbent polymer and an unsaturated thermosettable composition is also disclosed.
    Type: Grant
    Filed: December 13, 1984
    Date of Patent: September 9, 1986
    Assignee: The Dow Chemical Company
    Inventors: Robert E. Hefner, Jr., Deborah I. Haynes
  • Patent number: 4611028
    Abstract: Copolymers adapted for use as stabilizers in dispersions and stable dispersions, including crosslinked dispersions containing microgel particles, prepared therefrom. Stabilizer bears pendent ethylenic unsaturation capable of reacting with monomers employed in random copolymerization used to make the dispersion polymer. Stabilizer comprises a random copolymer segment of ethylenically unsaturated monomers, some of which are characterized in that homopolymers thereof would be substantially insoluble in the organic liquid used to form the stable dispersion and some of which are characterized in that homopolymers thereof would be substantially soluble in the organic liquid used to form the stable dispersion.
    Type: Grant
    Filed: December 21, 1984
    Date of Patent: September 9, 1986
    Assignee: Ford Motor Company
    Inventors: Stephen C. Peng, John D. Nordstrom
  • Patent number: 4608411
    Abstract: The present invention provides grafted ethylene copolymers usable more especially as additives for inhibiting the depositions in crude oils.Said copolymer being formed of ethylene and at least one monomer with ethylenic unsaturation, chosen from vinyl esters of C.sub.2 to C.sub.18 monocarboxylic acids, the alkyl esters in the C.sub.1 to C.sub.12 range of unsaturated monocarboxylic acids from the C.sub.3 to C.sub.12 range and the .alpha., .beta.-unsaturated dicarboxylic compounds, on which are fixed the grafts of a homo or copolymer of an .alpha., .beta.-unsaturated monocarboxylic acid ester with at least one alkanol of a chain length equal to or greater than C.sub.12 and at least 20% of which is of a chain length equal to or greater than C.sub.22. Such copolymers may be used more especially as additives for inhibiting the deposition of paraffins and for improving the flow properties of the crude oils.
    Type: Grant
    Filed: October 23, 1985
    Date of Patent: August 26, 1986
    Assignee: Societe Nationale Elf Aquitaine
    Inventors: Gilles Meunier, Rene Brouard, Bernard Damin, Denis Lopez
  • Patent number: 4585809
    Abstract: An aqueous dispersion of a copolymer comprising:(A) from 20 to 90 percent by weight of an unsaturated carboxylic acid of the formula ##STR1## where R.sub.1, R.sub.2, R.sub.3 are hydrogen, alkyl, or --(CH.sub.2).sub.n COOM and M is a proton or an alkali metal or alkaline earth metal or an ammonium cation, and(B) from 10 to 80 percent of at least one other comonomer different from and copolymerizable with A; methods of making a ready-to-use foundry molding sand by mixing such a dispersion with sand; and such ready-to-use foundry molding sands.
    Type: Grant
    Filed: February 10, 1984
    Date of Patent: April 29, 1986
    Assignee: Rohm GmbH
    Inventors: Heinz-Jochen Auer, Wolfgang Klesse, Peter Quis, Walther W. Szubinski