Four Or More Fluorine Atoms Patents (Class 524/546)
  • Publication number: 20120101214
    Abstract: The present invention provides a low-molecular weight polytetrafluoroethylene powder that, when used as an additive in a coating material, etc., can form a coating with excellent texture and gliding properties, while also improving dispersibility and viscosity; and a production process therefor. The present invention is a process for producing a low-molecular weight polytetrafluoroethylene powder, the process comprising: an emulsion polymerization step of polymerizing at least tetrafluoroethylene in the presence of a polymerization initiator and an aqueous medium to produce emulsified particles thereof; an agglomeration step of agglomerating the emulsified particles to form an agglomerated powder thereof; and a suspension polymerization step of polymerizing at least tetrafluoroethylene in the presence of the agglomerated powder, a polymerization initiator, and an aqueous medium.
    Type: Application
    Filed: March 31, 2010
    Publication date: April 26, 2012
    Applicant: DAIKIN INDUSTRIES, LTD.
    Inventors: Taku Yamanaka, Masayuki Tsuji, Shunji Kasai, Yasuhiko Sawada
  • Publication number: 20120095150
    Abstract: The present invention provides a fluororubber composition that has excellent heat resistance and excellent mechanical properties at high temperatures. The fluororubber composition comprises a peroxide cross-linkable fluororubber (A); a carbon black (B); a peroxide cross-linking agent (C); and a low-self-polymerizing cross-linking accelerator (D), wherein to 100 parts by mass of the fluororubber (A), the amount of the carbon black (B) is 5 to 50 parts by mass, the amount of the cross-linking agent (C) is 0.01 to 10 parts by mass, and the amount of the cross-linking accelerator (D) is 2.5 parts by mass or smaller.
    Type: Application
    Filed: August 25, 2011
    Publication date: April 19, 2012
    Applicant: DAIKIN INDUSTRIES, LTD.
    Inventors: Daisuke OTA, Yutaka Ueta, Masanori Kitaichi, Shoji Fukuoka
  • Publication number: 20120073628
    Abstract: The present invention relates to a coating agent for a solar cell module obtained by dispersing silica fine particles (A) with an average particle diameter of 15 nm or less and low-refractive index resin particles (B) with a refractive index of 1.36 or less in an aqueous medium, in which the solid content is 5% by mass or less, and the mass ratio of the silica fine particles (A) to the low-refractive index resin particles (B) in the solid content (silica fine particles (A)/low-refractive index resin particles (B)) is more than 20/80 and less than 70/30. The coating agent for a solar cell module is capable of forming an anti-reflection film at room temperature with excellent reflectance-reducing effect, abrasion resistance and weather resistance.
    Type: Application
    Filed: July 6, 2010
    Publication date: March 29, 2012
    Applicant: MITSUBISHI ELECTRIC CORPORATION
    Inventors: Yasuhiro Yoshida, Yoshinori Yamamoto, Teruhiko Kumada
  • Publication number: 20120077915
    Abstract: The present invention provides an aqueous fluororesin dispersion comprising a melt-processable fluororesin which is low in fluorinated surfactant concentration and excellent in dispersion stability even when the concentration of the melt-processable fluororesin is high. The present invention is related to an aqueous fluororesin dispersion comprising a melt-processable fluororesin particle dispersed in an aqueous medium, wherein a concentration of the melt-processable fluororesin is 55 to 75% by mass relative to the aqueous fluororesin dispersion, and a fluorinated surfactant content in the aqueous fluororesin dispersion is not higher than a level corresponding to 100 ppm of the melt-processable fluororesin.
    Type: Application
    Filed: December 8, 2011
    Publication date: March 29, 2012
    Applicant: DAIKIN INDUSTRIES, LTD.
    Inventors: Chie SAWAUCHI, Nobuhiko TSUDA
  • Publication number: 20120077926
    Abstract: The present invention provides a method for producing a fluororubber composition that has excellent heat resistance and excellent mechanical properties at high temperatures. The production method comprises the step of mixing a fluororubber (A) and a carbon black (B) in the presence of an organic amine compound (C1) and/or an acid acceptor (C2) to prepare a mixed product, wherein the mixed product has a highest temperature Tm of 80° C. to 220° C. while being mixed and has a highest temperature of 80° C. to 220° C. upon being discharged.
    Type: Application
    Filed: August 25, 2011
    Publication date: March 29, 2012
    Applicant: DAIKIN INDUSTRIES, LTD.
    Inventors: Daisuke OTA, Yutaka UETA, Masanori KITAICHI, Shoji FUKUOKA
  • Publication number: 20120065321
    Abstract: A catalyst composition comprising a cation and an anion of the formula Anq?Qpm+, wherein m, n, p, and q are positive integers, wherein m*p=n*q, wherein Qm+ is an organo onium, and Aq? is an anion, provided that at least one Aq? is selected from the formula (I) wherein each R independently is H, halo, alkyl, aryl, aralkyl, or cycloalkyl, and which also may be halogenated, fluorinated, or perfluorinated, wherein two or more of R and R? groups may together form a ring, wherein each R group independently may contain one or more heteroatom(s), wherein R? can be the same as R, with the proviso that R? cannot be halo, and wherein the catalyst composition is essentially free of hydrocarbon containing alcohol.
    Type: Application
    Filed: June 24, 2010
    Publication date: March 15, 2012
    Inventors: Werner M.A. Grootaert, Kim M. Vogel, Dennis E. Vogel
  • Patent number: 8110249
    Abstract: An antireflective coating composition includes a photopolymerizable acrylate monomer (C1); a particle-type metal fluoride (C2) with a refractive index of 1.40 or less; a photopolymerization initiator (C3); and at least one liquid dispersion-enhancing chelating agent (C4) selected from the group consisting of Mg(CF3COO)2, Na(CF3COO), K(CF3COO), Ca(CF3COO)2, Mg(CF2COCHCOCF3)2 and Na(CF2COCHCOCF3). This composition ensures good mechanical strength, excellent adhesion to a substrate, short curing time by UV curing, prevention of dust attachment, good erasure of stain, good dust removal and good scratch resistance, so it is usefully for making an antireflective coating film of a display.
    Type: Grant
    Filed: July 6, 2007
    Date of Patent: February 7, 2012
    Assignee: LG Chem, Ltd.
    Inventors: Joon-Koo Kang, Mi-Young Han, Young-Eun Lee, Young-Jun Hong, Yeong-Rae Chang
  • Publication number: 20120029140
    Abstract: The present invention provides a low-staining room temperature curable coating composition having an excellent low-staining property and recoatability, and comprising (A) a hydroxyl-containing resin, (B) an isocyanate based curing agent, (C) an organosilicate based hydrophilizing agent, (D) a recoatability modifier and (E) an organic solvent, in which the recoatability modifier (D) comprises at least (D1) an amide-containing polymer and (D2) a silane coupling agent.
    Type: Application
    Filed: March 18, 2010
    Publication date: February 2, 2012
    Applicant: DAIKIN INDUSTRIES, LTD.
    Inventors: Akira Chida, Shinya Murakami, Susumu Wada
  • Publication number: 20120022200
    Abstract: Provided is a filled fluororesin sheet excellent in stress relaxation properties, in particular stress relaxation properties at a high temperature. The filled fluororesin sheet includes a fluororesin and an inorganic filler having a revised Mohs hardness of not less than 8, in a fluororesin:inorganic filler volume ratio of 30-55:70-45 (wherein the total of the two is 100).
    Type: Application
    Filed: March 25, 2010
    Publication date: January 26, 2012
    Applicant: NIPPON VALQUA INDUSTRIES, LTD.
    Inventor: Shinya Kurokawa
  • Publication number: 20120015165
    Abstract: Disclosed is an antistaining sheet including a base material sheet and an antistaining layer formed on the base material sheet. The antistaining layer includes a photocatalyst and a thermoplastic resin to be decomposed by the photocatalyst, and thus has a self-collapsing property. The antistaining layer is stronger in self-collapsing property in the surface portion thereof than in the interior portion.
    Type: Application
    Filed: July 31, 2009
    Publication date: January 19, 2012
    Inventor: Noriaki Ogawa
  • Patent number: 8097673
    Abstract: An aqueous fluoropolymer dispersion comprising an aqueous medium, fluoropolymer particles, and an amine oxide surfactant. Coagulated fluoropolymer resin is produced from the dispersion by adding an acidic reagent in sufficient amount to cause coagulation and separation of the coagulated fluoropolymer resin from the aqueous medium. Another particulate component such as particular polymer, filler, pigment, solid lubricant, etc., may be added to the dispersion and co-coagulated to form a mixture of coagulated fluoropolymer resin and particulate component.
    Type: Grant
    Filed: April 29, 2011
    Date of Patent: January 17, 2012
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Clay Woodward Jones
  • Publication number: 20120009005
    Abstract: Disclosed herein is a water-based erasable ink for use in a writing instrument. The ink comprises platy-like pigment particles, film formers and an aqueous vehicle. Also disclosed are writing instruments using such inks as well as comprising a reservoir containing a water based erasable ink having a non-shear-thinning composition and a porous fiber nib in fluid communication with this reservoir. Related methods of forming an erasable marking are also disclosed.
    Type: Application
    Filed: June 6, 2011
    Publication date: January 12, 2012
    Inventors: Pawel CZUBAROW, Joshua Hart POLLACK, Jeremy SCHWARTZ
  • Publication number: 20110314840
    Abstract: This invention is comprised of the following innovations: various devices/instruments which may be used in the preparation of a compact monolayer [made up of a suitable organic material (or organic compound)] as well as the carbonization of the latter; efficient methods for preparing a compact monolayer which is free from all “other” materials that were used in the various processes involved in the said preparation of the said compact monolayer; various methods for carbonizing a compact monolayer by means of a suitable “heat source” (which allows the application of a sudden searing “heat” extremely quickly) in order to produce a graphene layer, where the said heat source may be a “hot surface” or a suitable “radiation type beam” such as a suitable laser beam, or a suitable maser beam, or a suitable electron beam; and finally, various methods to provide a protective layer for a graphene layer.
    Type: Application
    Filed: June 2, 2011
    Publication date: December 29, 2011
    Inventor: Hamid-Reza Jahangiri-Famenini
  • Publication number: 20110294944
    Abstract: A peroxide curable perfluoroelastomer comprising: recurring units derived from tetrafluoroethylene (TFE); recurring units derived from perfluoroethylvinylether (EVE), in an amount of between 2 and 17% by moles, with respect to total recurring units derived from TFE, perfluoromethylvinylether (MVE) and EVE; and recurring units derived from perfluoromethylvinylether (MVE), in an amount of between 23 and 35% by moles, with respect to total recurring units derived from TFE, perfluoromethylvinylether (MVE) and EVE. A process for its manufacture and its use for the manufacture of cured articles.
    Type: Application
    Filed: February 8, 2010
    Publication date: December 1, 2011
    Applicant: SOLVAY SOLEXIS S.P.A.
    Inventors: Claudia Manzoni, Milena Stanga, Margherita Albano
  • Publication number: 20110294945
    Abstract: The present invention provides an aqueous fluoropolymer dispersion having good mechanical characteristics and storage stability and containing substantially no fluorinated surfactant. The present invention is related to an aqueous fluoropolymer dispersion comprising a dispersed fluoropolymer particle with an average primary particle diameter of 50 to 400 nm, a surface layer of the dispersed fluoropolymer particle being obtained by emulsion polymerization of a monomer composition consisting of 99.999 to 98 mole percent of tetrafluoroethylene and 0.001 to 2 mole percent of a modifier monomer, a fluorinated surfactant content being not higher than 50 ppm, a fluoropolymer content being 20 to 75% by mass, and a nonfluorinated nonionic surfactant content being 2 to 15% by mass relative to 100% by mass of the fluoropolymer.
    Type: Application
    Filed: August 8, 2011
    Publication date: December 1, 2011
    Applicant: DAIKIN INDUSTRIES, LTD.
    Inventors: Chie SAWAUCHI, Nobuhiko TSUDA
  • Publication number: 20110294938
    Abstract: A peroxide curable perfluoroelastomer comprising: recurring units derived from tetrafluoroethylene (TFE); and recurring units derived from perfluoromethylvinylether (MVE); such perfluoroelastomer possessing a Mooney Viscosity (ML2+9) at 121° C. of from 25 to 140 MU, when measured according to ASTM D1646 standard, and comprising such MVE recurring units in an amount of from 26 to 33% by moles with respect to total moles of TFE and MVE. A process for the manufacture of such perfluoroelastomer, and cured articles obtainable therefrom.
    Type: Application
    Filed: February 8, 2010
    Publication date: December 1, 2011
    Applicant: SOLVAY SOLEXIS S.P.A.
    Inventors: Milena Stanga, Claudia Manzoni, Margherita Albano
  • Publication number: 20110263367
    Abstract: Described herein is a belt comprising a body made of elastomeric material, embedded in which is a plurality of longitudinal filiform resistant inserts, and a working surface covered with a covering fabric; advantageously the working surface is constituted by a toothing. The covering fabric is treated with a coating treatment. The coating treatment comprises a fluorinated elastomer. Advantageously, the coating treatment moreover comprises an antifriction agent and an elastomer formed by at least one copolymer obtained starting from a diene monomer and a monomer containing nitrile groups, more advantageously modified with a salt of an unsaturated carboxylic acid.
    Type: Application
    Filed: January 10, 2008
    Publication date: October 27, 2011
    Inventors: Carlo Baldovino, Marco Di Meco
  • Publication number: 20110244248
    Abstract: The present invention provides a method of coating at least one surface of a substrate comprising the step of applying a coating comprising fibres onto the at least one surface of the substrate, wherein upon application of the coating on the at least one surface of the substrate, the surface exhibits hydrophilicity or greater hydrophilicity compared to an uncoated surface. The present invention also provides a coating for coating at least one surface of a substrate, wherein the coating comprises fibres, and wherein a surface coated with the coating exhibits hydrophilicity or greater hydrophilicity compared to an uncoated surface. The anti-wetting coating may have a high degree of transparency.
    Type: Application
    Filed: December 11, 2008
    Publication date: October 6, 2011
    Inventors: Ying Jun Liu, Ramakrishnan Ramaseshan, Yi Xiang Dong, Kumar Abhishek
  • Patent number: 8017660
    Abstract: Highly fluorinated ion-exchange polymers achieve dissolution in aqueous tetrahydrofuran at lower pressures and temperatures than in other solvents, with few or no side products being formed.
    Type: Grant
    Filed: February 26, 2008
    Date of Patent: September 13, 2011
    Assignee: E.I. du Pont de Nemours and Company
    Inventor: Qun Sun
  • Patent number: 8013071
    Abstract: A composition for aqueous coating material which has a low content of an organic solvent and presents little burden on the environment and which is excellent in storage stability. A composition for aqueous coating material, which comprises a synthetic resin containing a fluorinated copolymer (A) comprising from 40 to 60 mol % of a fluoroolefin unit, from 3 to 50 mol % of an alkyl vinyl ether or alkyl vinyl ester unit, from 4 to 30 mol % of a hydroxyl group-containing vinyl ether unit and 0.
    Type: Grant
    Filed: January 19, 2010
    Date of Patent: September 6, 2011
    Assignee: Asahi Glass Company, Limited
    Inventors: Naoko Sumi, Takashi Morizumi, Isao Kimura
  • Publication number: 20110198224
    Abstract: The subject invention provides a process for efficiently producing electret coarse powder useful as electrophoretic particles for a large-screen display. The process for producing electret coarse powder comprises irradiating a fluorine-containing resin sheet with an electron beam or a radial ray to convert the fluorine-containing resin sheet into an electret sheet, and pulverizing the electret sheet.
    Type: Application
    Filed: March 5, 2010
    Publication date: August 18, 2011
    Applicant: SAKURA COLOR PRODUCTS CORPORATION
    Inventors: Tomotika Yoshitsugi, Hiroshi Inoue
  • Publication number: 20110183114
    Abstract: Exemplary embodiments provide materials and methods for polymer-based fixing members that have a textured surface with reduced surface energy and increased surface hydrophobicity.
    Type: Application
    Filed: January 25, 2010
    Publication date: July 28, 2011
    Applicant: XEROX CORPORATION
    Inventors: Woo Soo KIM, Yu Qi, Nan-Xing Hu
  • Patent number: 7985790
    Abstract: A fluoropolymer composition comprising: at least one thermoplastic partially fluorinated fluoropolymer [polymer (F)]; water; less than 15% wt (based on total weight of composition) of a water-soluble solvent mixture [mixture (M)] comprising: at least one alcohol solvent [solvent (A)]; at least one glycol derivative solvent having a boiling point of at least 100° C. [solvent (GD)], wherein the solvent (GD) is a derivative of a compound comprising at least two hydroxyl groups, wherein at least one of the hydroxyl group has been derivatized to yield an ether or an ester bond.
    Type: Grant
    Filed: December 4, 2006
    Date of Patent: July 26, 2011
    Assignee: Solvay Solexis, S.p.A.
    Inventors: Fabio Polastri, Tiziana Poggio, Julio A. Abusleme
  • Publication number: 20110175252
    Abstract: Methods for preparing an electrode comprise: providing a mixture of carbon particles and a solvent and shearing the mixture to form a dispersion of the carbon particles in the solvent; adding non-fibrillated POLY(TETRAFLUOROETHYLENE) to the dispersion to provide a resultant mixture and shearing the resultant mixture until at least a portion of the poly(tetrafluoroethylene) has been fibrillated; processing the resultant mixture into a sheet; and attaching the sheet onto a current collector. Methods for preparing sheet for the electrode and composition for the sheet are also provided.
    Type: Application
    Filed: August 10, 2009
    Publication date: July 21, 2011
    Inventors: Jianyun Liu, Wel Cai, Hai Yang, Liping Zheng, Rihua Xiong
  • Publication number: 20110172338
    Abstract: The present invention provides a processing additive which can bring about improvements in moldability at Mooney viscosity levels at which the dispersibility in a melt-processable resin is high and which further can work at reduced addition levels. The present invention is a processing additive comprising a fluoropolymer having an acid value of not lower than 0.5 KOH mg/g.
    Type: Application
    Filed: January 13, 2011
    Publication date: July 14, 2011
    Applicant: DAIKIN INDUSTRIES, LTD.
    Inventors: Shinji MURAKAMI, Ken OKANISHI, Masahiko OKA
  • Publication number: 20110171451
    Abstract: It is an object of the present invention to provide a fluororesin film usable as the outermost layer of a back sheet for a solar cell module, which is a dark type fluororesin film having a sufficient electric insulation property and weather resistance, and which is particularly excellent in thermal resistance; and a back sheet for a solar cell module employing such a film. A dark type fluororesin film, which is a fluororesin film to be used for a back sheet of a solar cell module, which contains an ethylene-tetrafluoroethylene copolymer as the main component and contains from 1.0 to 4.5 parts by mass of a carbon black having a pH of from 8 to 10 as measured according to JIS K6221 section 6.4.2 based on 100 parts by mass of the ethylene-tetrafluoroethylene copolymer. Further, a back sheet 1 comprising a laminate including a fluororesin film 11 being the dark type fluororesin film as the outermost layer.
    Type: Application
    Filed: March 23, 2011
    Publication date: July 14, 2011
    Applicant: ASAHI GLASS COMPANY, LIMITED
    Inventor: Hiroshi ARUGA
  • Publication number: 20110156356
    Abstract: The seal member includes a tetrafluoroethylene-propylene copolymer (FEPM) and carbon nanofibers. The seal member has a number of cycles to fracture of 10 or more when subjected to a tension fatigue test at a temperature of 150° C., a maximum tensile stress of 2 N/mm, and a frequency of 1 Hz. The seal member exhibits excellent heat resistance and abrasion resistance.
    Type: Application
    Filed: December 28, 2009
    Publication date: June 30, 2011
    Applicants: NISSIN KOGYO CO., LTD., SCHLUMBERGER TECHNOLOGY CORPORATION, SHINSHU UNIVERSITY, MEFS KABUSHIKI KAISHA
    Inventors: Toru NOGUCHI, Hiroyuki UEKI, Shigeki INUKAI, Masaei ITO, Raghu MADHAVAN, Morinobu ENDO, Satoshi IINOU
  • Patent number: 7968613
    Abstract: The present invention relates generally to the use of talc as a chemical foaming agent in perfluoropolymers to form foamable and foamed compositions. For example, in one aspect, a foamable composition is disclosed, which comprises (i) one or more base perfluoropolymers comprising at least 50 percent by weight of the composition, and (ii) talc blended with the one or more base perfluoropolymers, where the talc comprises 3 percent to about 15 percent by weight of the composition. Each of the perfluoropolymers is selected from the group consisting of tetrafluoroethylene/perfluoromethylvinyl ether copolymer (MFA), hexafluoropropylene/tetrafluoroethylene copolymer (FEP) and perfluoroalkoxy (PFA) and any blend thereof, where hydrogen-containing fluoropolymers are absent from the composition. The one or more base perfluoropolymers are melt-processable at one or more elevated processing temperatures of at least about 600° F.
    Type: Grant
    Filed: August 1, 2008
    Date of Patent: June 28, 2011
    Inventors: Charles A. Glew, Kenneth R. Boyle, Bradley Lane Kent, Jeffrey A Hrivnak
  • Patent number: 7968640
    Abstract: A non-stick coating application for high heat welding environments comprised of a fluorinated polymer combined with acidified graphite to which a hardening agent, such as alumina, may be added in some embodiments.
    Type: Grant
    Filed: June 24, 2009
    Date of Patent: June 28, 2011
    Assignee: Teledyne Scientific & Imaging, LLC
    Inventors: Rahul Ganguli, Ten-Luen T. Liao, Roberto S. Santos
  • Publication number: 20110152443
    Abstract: A method of manufacturing a polymer material which is allowed to manufacture ?-phase PVDF easily and stably in a short time is provided. The method of manufacturing a polymer material includes a step of mixing an ionic liquid and a polymer compound including ?-phase polyvinylidene difluoride to form a mixture, and then heating the mixture.
    Type: Application
    Filed: December 16, 2010
    Publication date: June 23, 2011
    Applicant: SONY CORPORATION
    Inventors: Kanako Ito, Daisuke Ito, Shinichi Uesaka
  • Patent number: 7964274
    Abstract: Tensile strength after heat aging of articles molded from melt-fabricable perfluoropolymer is improved by incorporating polytetrafluoroethylene as dispersed submicrometer-size particles into the melt-fabricable perfluoropolymer.
    Type: Grant
    Filed: November 16, 2006
    Date of Patent: June 21, 2011
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Ralph Munson Aten, Heidi Elizabeth Burch, Sharon Ann Libert
  • Publication number: 20110144255
    Abstract: An object of the present invention is to provide an aqueous fluoropolymer dispersion inhibited from viscosity rising and excellent in mechanical stability in spite of a low fluorinated surfactant concentration. The invention provides an aqueous fluoropolymer dispersion comprising particles of a fluoropolymer as dispersed in an aqueous medium wherein a fluorinated surfactant (A) having a molecular weight lower than 1000 amounts to not higher than 100 ppm of the mass of the fluoropolymer, the aqueous fluoropolymer dispersion containing an anionic surfactant (B) other than the fluorinated surfactant (A) as well as a water-soluble polymer (C).
    Type: Application
    Filed: February 24, 2011
    Publication date: June 16, 2011
    Applicant: DAIKIN INDUSTRIES, LTD.
    Inventors: Chie SAWAUCHI, Nobuhiko TSUDA, Wade Martin SIMPSON
  • Publication number: 20110143143
    Abstract: The present teachings include a coating composition which includes a liquid, fluoropolymer particles, carbon nanotubes, and a dispersant. The dispersant has a thermal degradation temperature below the melting temperature of the fluoropolymer particles.
    Type: Application
    Filed: December 16, 2009
    Publication date: June 16, 2011
    Applicant: XEROX CORPORATION
    Inventors: Yu Qi, Nan-Xing Hu, David C. Irving, Patrick J. Finn
  • Publication number: 20110136957
    Abstract: A resin material for a refrigeration circuit comprising a compressor for a refrigerant, a condenser, a depressurizing/expanding means, and an evaporator, the resin material being disposed in the refrigeration circuit at such a position that the resin part comes into direct contact with the refrigerant. The resin material is characterized in that when R1234yf is used as the refrigerant, the resin material has chemical resistance at least to the refrigerant itself or ingredients generated by the decomposition of the refrigerant. This resin material is prevented from undergoing a chemical reaction with the refrigerant R1234yf itself or ingredients generated by the decomposition thereof. Consequently, refrigerant leakage caused by the decomposition of the resin material is prevented. Furthermore, clogging and a decrease in refrigerating performance, which are caused by the circulation of an undesirable compound through the circuit, are prevented.
    Type: Application
    Filed: July 13, 2009
    Publication date: June 9, 2011
    Inventors: Hiromitsu Kamishima, Tomoaki Matsuzaki, Takayuki Matsumoto, Shunji Komatsu, Hidenori Hosoi
  • Patent number: 7956120
    Abstract: An aqueous fluoropolymer dispersion comprising an aqueous medium, fluoropolymer particles, and an amine oxide surfactant. Coagulated fluoropolymer resin is produced from the dispersion by adding an acidic reagent in sufficient amount to cause coagulation and separation of the coagulated fluoropolymer resin from the aqueous medium. Another particulate component such as particular polymer, filler, pigment, solid lubricant, etc., may be added to the dispersion and co-coagulated to form a mixture of coagulated fluoropolymer resin and particulate component.
    Type: Grant
    Filed: January 15, 2010
    Date of Patent: June 7, 2011
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Clay Woodward Jones
  • Patent number: 7956112
    Abstract: An aqueous fluoropolymer dispersion comprising an aqueous medium, fluoropolymer particles, and an amine oxide surfactant. Coagulated fluoropolymer resin is produced from the dispersion by adding an acidic reagent in sufficient amount to cause coagulation and separation of the coagulated fluoropolymer resin from the aqueous medium. Another particulate component such as particular polymer, filler, pigment, solid lubricant, etc., may be added to the dispersion and co-coagulated to form a mixture of coagulated fluoropolymer resin and particulate component.
    Type: Grant
    Filed: October 23, 2007
    Date of Patent: June 7, 2011
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Clay Woodward Jones
  • Patent number: 7947775
    Abstract: Aqueous dispersions on non-melt flowable PTFE and melt-fabricable perfluoropolymer are mixed together, followed by recovery of the resultant mixture of the dispersed particles of each of these polymers, and melt mixing of the resultant mixture of particles to obtain a blend in which the PTFE particles form the disperse phase and the perfluoropolymer forms the continuous phase, the melt mixing producing advantageous melt viscosities and the blend exhibiting advantageous physical properties even at high PTFE contents of about 30 wt %.
    Type: Grant
    Filed: September 29, 2009
    Date of Patent: May 24, 2011
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Sundar Kilnagar Venkataraman, Ralph Munson Aten, Heidi Elizabeth Burch
  • Patent number: 7939605
    Abstract: The invention relates to the field of chemistry and relates to long-term stable oil PTFE dispersions, such as can be used, for example, in transmissions or bearings, and a method for the production thereof. The object of the present invention is therefore to disclose a long-term stable oil PTFE dispersion as well as a simple and cost-effective method for the production thereof. The object is attained with an oil PTFE dispersion comprising PTFE particles and a monoolefinically or polyolefinically unsaturated oil, wherein molecules of the olefinically unsaturated oil are covalently/chemically coupled to PTFE (primary) particle surfaces via radical reactions, and wherein a permanent charge separation between the PTFE particle surfaces and the coupled oil molecules is present and a fine dispersion of the PTFE particles in the oil or oil mixture is present.
    Type: Grant
    Filed: December 9, 2008
    Date of Patent: May 10, 2011
    Assignee: Leibniz—Institut Fuer Polymerforschung Dresden E.V.
    Inventor: Dieter Lehmann
  • Patent number: 7939591
    Abstract: The present disclosure relates to a resin composition having excellent thermal stability, light reflectivity and color, and, preferably, flame retardancy. The present disclosure also relates to a method for producing a resin composition which comprises mixing 60 to 99.9 parts by weight of polycarbonate resin (component A) with 0.1 to 40 parts by weight of titanium dioxide pigment (component B), wherein component B (i) satisfies 0.05?(b)?(a)?0.6, when weight. reduction at 23 to 100° C. by thermogravimetric analysis (TGA) is (a) wt % and weight reduction at 23 to 300° C. by TGA is (b) wt %, and (ii) satisfies 0.001?(d)/(c)?0.01 and 0.001?(e)/(c)?0.02, when weight percentages derived from Ti, Al and Si elements in X-ray fluorescence analysis are (c) wt %, (d) wt % and (e) wt %, respectively.
    Type: Grant
    Filed: May 18, 2006
    Date of Patent: May 10, 2011
    Assignee: Teijin Chemicals, Ltd.
    Inventor: Takuya Tomoda
  • Publication number: 20110103854
    Abstract: Provided are fuser members and printing apparatuses including fuser members. The fuser member can include a substrate and a top coat layer including a hyper nanocomposite disposed over the substrate, wherein the hyper nanocomposite can include a plurality of nanoparticles substantially uniformly dispersed in one or more cross-linked hyperbranched polymers selected from the group consisting of polycarbosilane, polycarbosilixane, polycarbosilazene, and polyfluorocarbon.
    Type: Application
    Filed: November 2, 2009
    Publication date: May 5, 2011
    Applicant: XEROX CORPORATION
    Inventors: David J. Gervasi, Santokh Badesha, Alan R. Kuntz
  • Publication number: 20110098393
    Abstract: A highly heat-resistant fluororesin, such as tetrafluoroethylene resin or tetrafluoroethylene-perfluoroalkyl vinyl ether copolymer, is filled with 0.5 to 1 weight % of a non-black insulating pigment that has a heat resistance such that discoloration does not occur when the fluororesin is baked. Green insulating pigment whose main component is a TiO2—CoO—NiO—ZnO system or a ZnO—CoO system, or blue insulating pigment whose main component is a CoO—Al2O3 system or a CoO—Al2O3—Cr2O3 system is used singly or in a combination, as the non-black insulating pigment. A highly arc-resistant insulator is provided that secures an insulating capacity and at the same time that secures an excellent ability to prevent both interior and exterior deterioration of the insulator and that avoids color heterogeneity and localized discoloration.
    Type: Application
    Filed: December 29, 2010
    Publication date: April 28, 2011
    Inventors: Yoshihiko Hirano, Norimitsu Kato
  • Patent number: 7919557
    Abstract: An aqueous coating composition which has a low content of an organic solvent, whereby a burden on an environment is small; in which an increase of the molecular weight, gelation, etc. are suppressed; which performs excellent storage stability and provides a coating film having good water permeability/water which composition is obtained by dispersing a fluorocopolymer (A) obtained by solution polymerization in an aqueous medium, and which comprises a repeating unit (1) of fluoroolefin, a repeating unit (2) of a vinyl or allyl monomer, a repeating unit (3) of a vinyl or allyl monomer having a hydroxyl group bonded thereto, and a unit (4) of a vinyl or allyl monomer having a carboxylate group bonded thereto, and which comprises a fluorocopolymer (A) wherein a proportion of the repeating unit (4) is from 0.4 mol % to less than 4 mol % based on the total repeating units, and an aqueous medium, wherein an amount of an organic solvent contained in the composition is from 0 to 1 mass %.
    Type: Grant
    Filed: March 25, 2010
    Date of Patent: April 5, 2011
    Assignee: Asahi Glass Company, Limited
    Inventors: Naoko Sumi, Takashi Morizumi, Isao Kimura
  • Publication number: 20110073344
    Abstract: A composition for forming a gasket comprises a curable elastomer material and 0.1-20 weight % (e.g., 4-10 weight %) carbon nanotubes dispersed throughout the elastomer material. A dispensed bead of elastomer material exhibits a Slump ratio of at least 0.7. The composition provides the correct balance of rheology/dispensing characteristics, seal characteristics, and contamination profile characteristics required in form-in-place gasket applications, while simultaneously providing a conductive form-in-place gasket.
    Type: Application
    Filed: September 29, 2010
    Publication date: March 31, 2011
    Applicant: HYPERION CATALYSIS INTERNATIONAL, INC.
    Inventors: Yuanheng ZHANG, Mark HYMAN, Robert Bernard ANDERSON, III, Dylan LAM
  • Patent number: 7910648
    Abstract: A protective coating applied to the underwater portion of a marine vessel operable to inhibit the growth of marine foulants. The coating comprises a polymer, a marine biocide, a preservative, and optionally an antimicrobial agent. In certain embodiments, the marine biocide, preservative, and optional antimicrobial agent are chemically bonded with the polymer thereby significantly reducing the ability of the biocide, preservative, and antimicrobial agent to leach from the coating into the surrounding environment.
    Type: Grant
    Filed: July 16, 2007
    Date of Patent: March 22, 2011
    Assignee: Reintjes Marine Surface Technologies, LLC
    Inventor: Larry Weidman
  • Publication number: 20110014451
    Abstract: Disclosed is a diamond film that can solve a problem of a conventional thin film of diamond which, due to insoluble, infusible and hardly machinable properties of the diamond, is produced by plasma CVD requiring the use of a disadvantageously large apparatus. Specifically, a nanodiamond film, which can be simply produced without the need to use a large apparatus, is disclosed. The nanodiamond film is characterized by comprising a nanodiamond. The nanodiamond film has a thickness of not more than 5000 nm.
    Type: Application
    Filed: March 2, 2009
    Publication date: January 20, 2011
    Inventor: Toshihiko Tanaka
  • Publication number: 20100327855
    Abstract: A non-stick coating application for high heat welding environments comprised of a fluorinated polymer combined with acidified graphite to which a hardening agent, such as alumina, may be added in some embodiments.
    Type: Application
    Filed: June 24, 2009
    Publication date: December 30, 2010
    Inventors: Rahul Ganguli, Ten-Luen T. Liao, Roberto S. Santos
  • Patent number: 7855254
    Abstract: The invention pertains to a multi-phase thermoplastic fluoropolymer composition, comprising a thermoplastic fluoropolymer and discrete domains of melt-processable perfluoropolymer, to the articles therefrom and to a process for manufacturing thermoplastic fluoropolymer compositions. The multi-phase thermoplastic fluoropolymer composition comprises: —at least one thermoplastic fluoropolymer (A); and —from 0.1 to 10% by weight of (A) of at least one melt-processible perfluoropolymer (B), and is characterized in that the polymer (B) is present in the composition in phase-separated domains in a continuous phase mainly comprising (A), at least 75% by volume of said domains having maximal dimension not exceeding 1 ?m. The process of the invention comprises mixing: (i) a thermoplastic fluoropolymer (A); (ii) a melt-processible perfluoropolymer (B) under the form of particles having an average primary particle size not exceeding 300 nm; (iii) and optionally other additives or filling materials.
    Type: Grant
    Filed: April 25, 2006
    Date of Patent: December 21, 2010
    Assignee: Solvay Solexis S.p.A.
    Inventors: Julio A. Abusleme, Claudia Manzoni, Giambattista Besana
  • Patent number: 7855259
    Abstract: To provide a method for producing a melt-processable fluororesin, which is capable of increasing the molecular weight of the fluororesin and preventing coloration of the fluororesin, by using a specific fluorinated emulsifier other than ammonium perfluorooctanoate. A method for producing a melt-processable fluororesin which is characterized in that a fluorinated monomer is emulsion-polymerized in an aqueous medium containing a fluorinated emulsifier of a formula (I) XCF2CF2(O)mCF2CF2OCF2COOA wherein X is a hydrogen atom or a fluorine atom, A is a hydrogen atom, an alkali metal or NH4, and m is an integer of 0 or 1.
    Type: Grant
    Filed: April 17, 2008
    Date of Patent: December 21, 2010
    Assignee: Asahi Glass Company, Limited
    Inventors: Atsushi Funaki, Hiroki Kamiya
  • Publication number: 20100317789
    Abstract: The present invention describes polymer compositions comprising fluoroelastomer and expanded perlite and uses thereof.
    Type: Application
    Filed: December 28, 2007
    Publication date: December 16, 2010
    Inventors: Michael Greene, Roger Norman Rothon, Nigel Julian Keith Danvers, Qingchun Hu
  • Patent number: 7851573
    Abstract: To provide an aqueous polytetrafluoroethylene (PTFE) emulsion which does not substantially contain ammonium perfluorooctanoate, and which is obtained by emulsion polymerization. Further, to provide a PTFE fine powder which is obtained from the aqueous PTFE emulsion and is excellent in a paste extrusion processability, and a porous material. An aqueous polytetrafluoroethylene emulsion obtained by carrying out emulsion polymerization of tetrafluoroethylene alone or together with another copolymerizable monomer in an aqueous medium, wherein a fluorinated emulsifier of the formula (1): CF2CF2(O)mCF2CF2OCF2COOA wherein X is a hydrogen atom or a fluorine atom, A is a hydrogen atom, an alkali metal or NH4, and m is an integer of 0 or i, is used in an amount of from 1,500 to 20,000 ppm, based on the final yield of polytetrafluoroethylene.
    Type: Grant
    Filed: April 17, 2008
    Date of Patent: December 14, 2010
    Assignee: Asahi Glass Company, Limited
    Inventors: Shinya Higuchi, Hiroki Kamiya, Jun Hoshikawa, Yasuhiko Matsuoka