From Acetylenic Monomer Patents (Class 524/550)
  • Patent number: 8969491
    Abstract: An aqueous dispersion containing a vinylidene chloride polymer (P1) containing vinylidene chloride in a proportion of at least 50% by weight, and at least one random, alternating or gradient copolymer (C1) having: a) at least one monomer unit (m1) carrying at least one phosphonate group —PO(OH)(OR1) with R1 being a hydrogen atom or an alkyl radical comprising from 1 to 11 carbon atoms, and b) monomer units (m2) which represent at least 50% by weight of the copolymer (C1), derived from at least one monomer (M2) chosen from styrene, maleic anhydride, itaconic acid and the (meth)acrylic monomers corresponding to the general formula CH2=CR2R3 in which R2 and R3 are described herein, copolymer (C1) not containing monomer units derived from vinylidene chloride.
    Type: Grant
    Filed: October 4, 2006
    Date of Patent: March 3, 2015
    Assignee: Solvay SA
    Inventors: Christophe Fringant, Yves Vanderveken, Cedric Loubat, Gilles Boutevin
  • Patent number: 8273822
    Abstract: The present invention pertains to a reversible thermochromic system comprising a ?-phenylvinylketone or a ?-phenyl polyacetylenyl ketone with at least one acidic hydrogen and a base and to a reversible thermochromic composition comprising the reversible thermochromic system and a carrier material and to novel substituted ?-phenylvinylketones or ?-phenyl polyacetylenyl ketones with at least one acidic hydrogen.
    Type: Grant
    Filed: January 25, 2007
    Date of Patent: September 25, 2012
    Assignee: BASF SE
    Inventors: Mirko Rossi, Graziano Zagnoni, Manuele Vitali, Dario Lazzari, Walter Fischer
  • Patent number: 7999032
    Abstract: An acrylic resin composition suitable for use as films excellent in transparency, weatherability, hardness, impact resistance, flex cracking resistance, and formability. The resin composition comprises an acrylic graft copolymer (A) including a rubbery acrylic ester polymer (A-a) and a methacrylic polymer (B) comprising 80 wt. % or more methyl methacrylate units, the acrylic resin composition having a specific value of reduced viscosity (0.2-0.8 dl/g), specific values of content (5-45 wt. %) and average particle diameter (50-200 nm) of the rubbery polymer (A-a), a specific relationship between the particle diameter and the crosslinking agent amount (0.02d?w?0.05d; d, average particle diameter (nm); w, amount of crosslinking agent (wt. %)), and a specific value of the degree of grafting (50-250%). The resin composition contains an ultraviolet absorber incorporated therein through copolymerization.
    Type: Grant
    Filed: July 5, 2006
    Date of Patent: August 16, 2011
    Assignee: Kaneka Corporation
    Inventors: Kazuhito Wada, Kimihide Nishimura, Norito Doi
  • Publication number: 20110172351
    Abstract: An organic insulating material includes a prepolymer of a cage structure compound having a polymerizable unsaturated bond-containing group and a cage structure with an adamantane structure as the minimal unit. The prepolymer has a number-average molecular weight of between 2,000 and 500,000 based on polystyrene and measured by gel permeation chromatography. The prepolymer includes unsaturated bonds produced by reaction between the polymerizable unsaturated bonds and the unreacted polymerizable unsaturated bonds. The prepolymer has a residue rate of unreacted polymerizable unsaturated bonds of between 20% and 80%.
    Type: Application
    Filed: March 18, 2011
    Publication date: July 14, 2011
    Applicant: SUMITOMO BAKELITE CO., LTD.
    Inventors: Yohko Sano, Mihoko Matsutani, Kazuyoshi Fujita
  • Publication number: 20110089110
    Abstract: A method of manufacturing a filled polymeric membrane includes a first step of preparing a filler suspension having a solvent for a glassy polymer and nanometre-sized particles. The nanometre-sized particles in the filler suspension are aggregated in aggregates having an average aggregate size in the range between 50 nm and smaller than 200 nm. In a following step, the glassy polymer is added to the filler suspension to obtain a polymer suspension. Next, the glassy polymer is dissolved in the polymer suspension. In a next step, the polymer suspension is cast on a substrate, followed by a step of removing the solvent. A filled polymeric membrane includes aggregates of nanometre-sized filler particles. The membrane is used in pervaporation and nanofiltration.
    Type: Application
    Filed: August 25, 2008
    Publication date: April 21, 2011
    Applicant: Vlaamse Instelling Voor Technologisch Onderzoek N.V. (VITO)
    Inventors: Kristien De Sitter, Steven Mullens, Lieven Gevers
  • Publication number: 20100234522
    Abstract: The present invention pertains to a reversible thermochromic system comprising a ?-phenylvinylketone or a ?-phenyl polyacetylenyl ketone with at least one acidic hydrogen and a base and to a reversible thermochromic composition comprising the reversible thermochromic system and a carrier material and to novel substituted ?-phenylvinylketones or ?-phenyl polyacetylenyl ketones with at least one acidic hydrogen.
    Type: Application
    Filed: January 25, 2007
    Publication date: September 16, 2010
    Inventors: Mirko Rossi, Graziano Zagnoni, Manuele Vitali, Dario Lazzari, Walter Fischer
  • Publication number: 20100130672
    Abstract: A polymer and composition useful in forming an insulating film provided with a low permittivity, a high heat resistance, and a high mechanical strength and an insulating film obtained from these and an electronic device having the same are provided. The polymer for forming an insulating film according to the present invention is characterized by being obtained by polymerizing a reactive compound represented by Formula (1). The insulating film according to the present invention is formed using a composition for forming an insulating film including that polymer, has molecular spaces having an average space size of 0.7 nm to 5 nm, and has a permittivity of 2.3 or less. The electronic device according to the present invention has the insulating film.
    Type: Application
    Filed: January 27, 2010
    Publication date: May 27, 2010
    Applicant: SUMITOMO BAKELITE CO., LTD.
    Inventors: Yohko SANO, Kazuyoshi Fujita, Sumitoshi Asakuma
  • Publication number: 20100125120
    Abstract: Described herein are substantially linear copolymeric compositions having at least two azide groups and at least two non-activated acetylene groups. The azide groups and the non-activated acetylene groups are reacted to cure the substantially linear copolymer composition. Also, described are methods of making and using such substantially linear copolymeric compositions.
    Type: Application
    Filed: November 14, 2008
    Publication date: May 20, 2010
    Inventors: Michael D. Crandall, Yvan A. Bogaert, Aron Y. Goodner, Werner M.A. Grootaert, Anthony P. Manzara
  • Publication number: 20100029004
    Abstract: Duration monitoring co-topo-polymeric compositions and methods for making and using the same are provided. Indicator compositions of the invention include an organic polymer and undergo a color change, which may be reversible or irreversible, in a time dependent manner following an initiation event. Also provided are indicator devices that include the indicator compositions of the invention. The compositions of the invention find use in a variety of different applications.
    Type: Application
    Filed: July 28, 2009
    Publication date: February 4, 2010
    Inventor: Hans O. Ribi
  • Patent number: 7612155
    Abstract: A film forming composition includes a polymer of a compound represented by formula (I): wherein R1, R2 and R3 each independently represents a substituent containing a carbon-carbon double bond or carbon-carbon triple bond; X1, X2 and X3 each independently represents any substituent; l and n each stands for an integer of from 0 to 15 and m stands for an integer of from 0 to 14, with the proviso that l, m and n do not represent 0 simultaneously; o and q each independently stands for an integer of from 0 to 15 and p independently stands for an integer of from 0 to 14; and r stands for 0 or 1, with the proviso that when r=0, R1 and R3 each independently represents a substituent containing a carbon-carbon double bond.
    Type: Grant
    Filed: April 25, 2007
    Date of Patent: November 3, 2009
    Assignee: FUJIFILM Corporation
    Inventors: Yasufumi Watanabe, Katsuyuki Watanabe
  • Patent number: 7569649
    Abstract: A film forming composition includes a compound having a cage structure; and a compound having a conjugated diene structure.
    Type: Grant
    Filed: September 13, 2007
    Date of Patent: August 4, 2009
    Assignee: FUJIFILM Corporation
    Inventor: Hidetoshi Hiraoka
  • Patent number: 7544736
    Abstract: The present invention is drawn to a method of generating functionalized latex particulates in a colloidal suspension. The method can comprise steps of protecting functional groups present on polymerizable monomers with photo labile groups to form protected monomers; polymerizing the protected monomers to form a protected polymer; and exposing the protected polymer to a wavelength of light that removes the photo labile groups from the functional groups, thereby forming the functionalized latex particulates. These latex particulates can be used in a wide variety of applications, including in ink-jet ink printing applications.
    Type: Grant
    Filed: October 25, 2005
    Date of Patent: June 9, 2009
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Zhang-Lin Zhou, Sivapackia Ganapathiappan
  • Publication number: 20090104371
    Abstract: A film forming composition is provided that includes (A) a radical polymerization initiator, and (B-1) a compound represented by Formula (1) below and/or a polymer polymerized using at least a compound represented by Formula (1) below, and/or (B-2) a compound represented by Formula (2) below and/or a polymer polymerized using at least a compound represented by Formula (2) below (in Formula (1), the two R1s denote groups consisting only of carbon and hydrogen, which may be identical to or different from each other, and may be linked to each other to form a 6- or higher-membered ring structure, and the R2s denote hydrogen atoms or are represented by Formula (3) below and may be identical to or different from each other provided that at least one of the R2s is represented by Formula (3)) (in Formula (2), the two R4s and the two R5s denote groups consisting only of carbon and hydrogen, which may be identical to or different from each other, R4 and R4, and R5 and R5 may be linked to each other to form a 6-
    Type: Application
    Filed: September 16, 2008
    Publication date: April 23, 2009
    Applicant: FUJIFILM CORPORATION
    Inventors: Hidetoshi Hiraoka, Makoto Muramatsu
  • Publication number: 20090081377
    Abstract: A film-forming composition, includes: a photoacid generator; and a crosslinked or crosslinkable polyphenylene that is a product of a Diels-Alder reaction between at least one kind of a compound having two or more diene functional groups and at least one kind of a compound having two or more dienophile functional groups, in which at least one of the compounds has three functional groups as the functional group, and a method for producing a film, includes: applying the film-forming composition to a substrate; and irradiating the applied composition with an electron beam or an electromagnetic wave at a wavelength larger than 200 nm.
    Type: Application
    Filed: September 25, 2008
    Publication date: March 26, 2009
    Applicant: FUJIFILM CORPORATION
    Inventor: Yohei KUBO
  • Publication number: 20090029059
    Abstract: A two-part epoxy composition is provided that comprises a first part having a mixture of an epoxy resin and an anhydride, and a second part having a curing agent. Also provided is a method for making a substantially bis-?-glycol free epoxy resin for two-part epoxy compositions, and a method for applying a two-part epoxy composition to a system of water piping.
    Type: Application
    Filed: July 26, 2007
    Publication date: January 29, 2009
    Inventors: David L. Stanley, David J. Dunn
  • Publication number: 20080242794
    Abstract: A polymer composite comprising a melt-processed polymer compounded with a color stabilizer comprising a bromate or iodate ion, and a silver-based antimicrobial agent. The specified color stabilizers are particularly superior in inhibiting undesirable darkening or discoloration of melt-processed polymers compounded with silver-based antimicrobial agents containing a grain-size controlling additive.
    Type: Application
    Filed: March 30, 2007
    Publication date: October 2, 2008
    Inventors: David W. Sandford, Thomas N. Blanton
  • Publication number: 20080176977
    Abstract: An aqueous bubble solution includes at least one water soluble polymer, at least one surfactant, and at least one fast drying solvent or solvent blend. The water soluble polymer forms a strong and resilient bubble wall. The surfactant(s) lowers the surface tension of the solution to create a bubble blowing film. The fast evaporating solvent or solvent blend acts to harden the bubble wall by dehydration and rapid evaporation. Bubbles blown from the solution will air dry within seconds and exhibit extraordinary strength. The bubbles do not evaporate and resist breakage upon collision with a dry surface. The bubbles remain translucent and fully preserved for hours or even days while resting on a surface.
    Type: Application
    Filed: January 23, 2007
    Publication date: July 24, 2008
    Inventor: John Pastorello
  • Patent number: 7309752
    Abstract: A polymer obtained by polymerizing, in a presence of a polymerization initiator, a compound having a cage structure with at least 11 carbon atoms and an ethylenic double bond; a film forming composition containing the polymer; an insulating film formed using the composition; and an electronic device.
    Type: Grant
    Filed: September 27, 2006
    Date of Patent: December 18, 2007
    Assignee: FUJIFILM Corporation
    Inventors: Katsuyuki Watanabe, Hidetoshi Hiraoka
  • Patent number: 6995206
    Abstract: The present invention is drawn to a method of generating functionalized latex particulates in a colloidal suspension. The method can comprise steps of protecting functional groups present on polymerizable monomers with photo labile groups to form protected monomers; polymerizing the protected monomers to form a protected polymer; and exposing the protected polymer to a wavelength of light that removes the photo labile groups from the functional groups, thereby forming the functionalized latex particulates. These latex particulates can be used in a wide variety of applications, including in ink-jet ink printing applications.
    Type: Grant
    Filed: July 28, 2003
    Date of Patent: February 7, 2006
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Zhang-Lin Zhou, Sivapackia Ganapathiappan
  • Patent number: 6762238
    Abstract: A coating composition which contains a polymeric complex between polyaniline and a polymeric ion. In addition to the said polymeric complex, the composition contains a water-dispersable binder. The composition is useful as a water-borne paint to be applied onto a metal substrate electrophoretically or non-electrophoretically.
    Type: Grant
    Filed: August 31, 2001
    Date of Patent: July 13, 2004
    Assignee: The Board of Governors for Higher Education, State of Rhode Island and Providence Plantations
    Inventors: Sze Cheng Yang, Richard Brown
  • Patent number: 6130263
    Abstract: The present invention includes processes and resulting structures for producing moisture absorbing desiccant entrained polymers. A polymer is caused to assume a molten state, typically by applying heat and melting the polymer. To achieve certain results in the hardened end product, such as rigidity and durability, the polymer normally acts as a moisture barrier in a solidified state, both before and after melting. A desiccating agent is blended into the polymer so that the desiccating agent is distributed within the polymer. A channeling agent is also blended into the polymer so that it is distributed within the polymer. The blending of the components is preferably done before the polymer is caused to assume a molten state. Together, the polymer, desiccating agent and channeling agent create a blended mixture. The mixture is solidified so that the channeling agent forms passages in the mixture through which moisture is communicable to desiccating agent that is entrained within the mixture.
    Type: Grant
    Filed: March 5, 1997
    Date of Patent: October 10, 2000
    Assignee: Capitol Specialty Plastics, Inc.
    Inventor: Ihab M. Hekal
  • Patent number: 5905114
    Abstract: The present invention relates to low-odor binders which can be processed without solvent and are based on aqueous styrene-acrylate polymer dispersions, having a mean film-forming temperature of below 10.degree. C.The invention also relates to low-emission coating compositions, especially emulsion paints, which comprise these binders.
    Type: Grant
    Filed: May 22, 1997
    Date of Patent: May 18, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Roland Baumstark, Rolf Dersch
  • Patent number: 5292792
    Abstract: Intrinsically conductive or semiconductive stable polyacetylides and methods of forming same. The unique soluble metallic polyacetylides may be formed as a conductive adherent film for coating glass, ceramics and metals. The polyacetylides may also be synthesized with pendant organic anions and cations for conductive or semiconductive materials, including integrated circuit subunits, printed circuit board equivalents and thin film electrodes in an organic battery. The polyacetylides may also be synthesized with organic crosslinkers forming high tensile strength polymers comparable to steel. A simultaneous polymerization initiation for forming the conductive polymers is also disclosed by which catalyst/reductant initiation and non-chemical initiation are used to initiate polymerization.
    Type: Grant
    Filed: April 21, 1992
    Date of Patent: March 8, 1994
    Inventor: Evan B. Carew
  • Patent number: 5232820
    Abstract: This invention relates to novel thermochromic quaternized polyacetylene salt derivatives which are visually imageable by exposure to a light source generating energy in a wavelength of from about 400 nm to about 1500 nm said salt derivative having a thermosensitivity of at least 50.degree. C. and defined by the formula ##STR1## or a homopolymer thereof wherein X is the N-quaternized monovalent radical of a dye having an optical absorbance in a wavelength of from about 400 nm to about 1500 nm; V is the cationic residue of a carboxyl, sulfonate, thioate, thiolic, thionic or phosphonate radical; n has a value of from 2 to 4 and X' is hydrogen, C.sub.4 to C.sub.25 alkyl, a polar hydrophilic group which promotes hydrogen bonding containing a radical of the group of an amino, amido, hydroxy, ester, ether, phenol, carboxy, halo, sulfonyl, sulfoxy, sulfinyl, silyl, silyoxy, phosphoro, phosphate, keto, carbamate, aldehyde, urea, urethane, a metal salt group or X' is selected from the group defined for X.
    Type: Grant
    Filed: March 9, 1992
    Date of Patent: August 3, 1993
    Assignee: ISP Investments Inc.
    Inventors: David F. Lewis, John C. Hornby
  • Patent number: 5137964
    Abstract: This invention relates to novel thermochromic quaternized polyacetylene salt derivatives which are visually imageable by exposure to a light source generating energy in a wavelength of from about 400 nm to about 1500 nm said salt derivatives having a thermosensitivity of at least 50.degree. C. and defined by the formulaXV--C.tbd.C).sub.n X'or a homopolymer thereof wherein X is the N-quaternized monovalent radical of a dye having an optical absorbance in a wavelength of from about 400 nm to about 1500 nm; V is the cationic residue of a carboxyl, sulfonate, thioate, thiolic, thionic or phosphonate radical; n has a value of from 2 to 4 and X' is hydrogen, C.sub.4 to C.sub.25 alkyl, a polar hydrophilic group which promotes hydrogen bonding containing a radical of the group of an amino, amido, hydroxy, ester, ether, phenol, carboxy, halo, sulfonyl, sulfoxy, sulfinyl, silyl, silyoxy, phosphoro, phosphate, keto, carbamate, aldehyde, urea, urethane, a metal salt group or X' is selected from the group defined for X.
    Type: Grant
    Filed: March 18, 1991
    Date of Patent: August 11, 1992
    Assignee: ISP Investments Inc.
    Inventors: David F. Lewis, John C. Hornby
  • Patent number: 4873284
    Abstract: Bismaleimide resion systems containing a bismaleimide and a multinuclear alkenyl and/or alkynyl arene as comonomers have improved toughness while maintaining high glass transition temperatures.
    Type: Grant
    Filed: January 20, 1988
    Date of Patent: October 10, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Peter Ittemann, Philipp Eisenbarth
  • Patent number: 4596852
    Abstract: Process for molding an acetylene high polymer by press-forming a gel-like composition composed of 5 to 95% by weight of an acetylene high polymer having a fibril structure and 95 to 5% by weight of an organic solvent.
    Type: Grant
    Filed: July 12, 1985
    Date of Patent: June 24, 1986
    Assignee: Showa Denko K.K.
    Inventors: Yukio Kobayashi, Hideki Shirakawa, Sakuji Ikeda
  • Patent number: 4381363
    Abstract: A polymeric composition comprised of a mixture of an acetylene-terminated polymer and an hydroxy-substituted, polynuclear, aromatic derivative as a cure retarding additive.
    Type: Grant
    Filed: September 10, 1981
    Date of Patent: April 26, 1983
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventor: Theodore J. Reinhart, Jr.