Inorganic Nonreactive Material Patents (Class 524/566)
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Patent number: 6447697Abstract: A colorized fire retardant composition comprising a fire retardant and a colorant, wherein the colorant is an aqueous dispersion of a pigment formed by polymerizing at least one monomer in the presence of at least one dye. The composition is particularly useful in combating and controlling fires by discharging the composition towards the fuel, or potential fuel, of a fire.Type: GrantFiled: March 3, 1999Date of Patent: September 10, 2002Assignee: Astaris, LLCInventor: Howard L. Vandersall
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Patent number: 6372840Abstract: In a dispersion containing acrylic polymer microparticles, particularly useful in automotive coatings, the dispersion is formed by free radical addition copolymerization of unsaturated monomers in a hydrocarbon dispersing medium in the presence of first and second polymeric dispersion stabilizers. The first polymeric dispersion stabilizer has an acrylic backbone and polyester side chains, and the second polymeric dispersion stabilizer is a branched polyester formed from the reaction of polyol, polyacid or anhydride, and fatty acid.Type: GrantFiled: June 28, 2000Date of Patent: April 16, 2002Assignee: PPG Industries Ohio, Inc.Inventors: Mohamad D. Shalati, Susana C. Steppan, Michael A. Mayo
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Patent number: 6372856Abstract: A dip-formed rubber article is produced by dip-forming a vulcanizable rubber latex composition comprising an unsaturated nitrile-conjugated diene copolymer rubber latex, a sulfur-containing vulcanizer, and at least one vulcanization accelerator selected from (i) dithiocarbamic acid compounds of the formula (1): wherein R1 and R2 independently represent and hydrocarbon group having at least 6 carbon atoms, and (ii) zinc dithiocarbamate compounds of the formula (2): wherein R1 and R2 are as defined above.Type: GrantFiled: January 16, 2001Date of Patent: April 16, 2002Assignee: Nippon Zeon Co., Ltd.Inventors: Yutaka Ozawa, Hisanori Ohta
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Patent number: 6326420Abstract: A pigment dispersion which includes a pigment, an aqueous carrier and a pigment dispersant. The pigment dispersant is prepared by controlled radical polymerization initiated in the presence of a monomeric initiator having at least two radically transferable groups. The pigment dispersant has at least one of the following polymer chain structures: &phgr;-[(G)p—(E)s—T]z and &phgr;-[(E)3—(G)p—T]z where G is a hydrophobic residue of at least one radically polymerizable ethylenically unsaturated monomer; E is a hydrophilic residue of at least one radically polymerizable ethylenically unsaturated monomer; &phgr; is a residue of or derived from the initiator, and is free of the radically transferable group; T is or is derived from the radically transferable group of the initiator; z is 2 to 10; p and s are at least one and are selected such that the pigment dispersant has a number average molecular weight of at least 500.Type: GrantFiled: December 16, 1999Date of Patent: December 4, 2001Assignee: PPG Industries Ohio, Inc.Inventors: Kevin C. Olson, Simion Coca, James B. O'Dwyer, Karl F. Schimmel
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Patent number: 6288158Abstract: A process for modifying superabsorbent polymers is disclosed. The surface of a polymer containing hydrolyzed polyacrylonitrile in the form of particulates, is modified by crosslinking in a water/alcohol reaction mixture and in the presence of silica. The resulting product features improved absorbency under load and lesser degree of gel blocking.Type: GrantFiled: February 9, 1999Date of Patent: September 11, 2001Assignee: Bayer AktiengesellschaftInventors: Sergej Schapowalov, Günter Sackmann, Rolf-Volker Meyer, Siegfried Korte
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Patent number: 6277900Abstract: The present invention relates to copolymers consisting of (a) 1-99% by weight of structural units of the formula (1) where R1 is hydrogen or methyl, R4 is C1-C22-alkylene, R5 is C1-C22-alkyl or hydrogen, and X is ammonium, lithium, sodium, potassium, an amine or a mixture of these substances, and (b) 99-1% by weight of structural units of the formula (2) where R1 is hydrogen or methyl, R2 and R3, independently of one another, are hydrogen, or C2-C22-alkyl, wherein component b) is not hydrolysed and the copolymers have been prepared by a solution precipitation polymerization in a nonaqueous solvent or a water-miscible, organic solvent having a low water content which is a precipitant for the copolymer. The invention furthermore relates to a process for cementing subterranean wells using a cement slurry comprising the following components: a) water of various salinity cement a novel copolymer in a concentration of 0.01-5% bwoc, preferably from 0.05 to 0.Type: GrantFiled: November 19, 1998Date of Patent: August 21, 2001Assignee: Clariant GmbHInventors: Reinhard Oswald, Volker Frenz, Juergen Tonhauser, Aranka Tardi, Pierre Maroy, Florence L'Alloret
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Patent number: 6197848Abstract: A composition comprising an ethylene containing polymer, a crosslinking agent and a treated filler material. The treated filler material comprises a treating agent which is a polymer comprising acrylonitrile and at least one other monomer. A preferred treated filler material is a treated carbon black and a preferred ethylene containing polymer is an ethylene vinyl acetate (EVA) polymer. A semiconductive composition of the present invention may be advantageously utilized in electrical wire and cable application.Type: GrantFiled: February 17, 1998Date of Patent: March 6, 2001Assignee: Cabot CorporationInventors: Robert S. Whitehouse, Thomas F. Reed
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Patent number: 6187857Abstract: A vulcanizable dip-forming rubber latex composition comprising an unsaturated nitrile-conjugated diene copolymer rubber latex, a sulfur-containing vulcanizer, and a vulcanization accelerator comprising at least one compound selected from (i) dithiocarbamic acid compounds of the formula: and (ii) zinc dithiocarbamate compounds of the formula: wherein R1 and R2 are hydrocarbon groups having at least 6 carbon atoms which may be the same or different, and an optional thiazole compound. A rubber article dip-formed from the rubber latex composition has no crack occurrence, good surface luster and good vulcanization properties, and does not contain a nitrosamine, and therefore, is suitable for medical use.Type: GrantFiled: January 22, 1999Date of Patent: February 13, 2001Assignee: Nippon Zeon Co., Ltd.Inventors: Yutaka Ozawa, Hisanori Ohta
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Patent number: 6174942Abstract: Flame retardant blends comprising a polycarbonate portion containing spirobiindane units, at least one addition polymer such as a styrene-acrylonitrile or ABS copolymer, and at least one phosphoryl flame retardant have high temperature stability properties superior to those of similar blends not containing the spirobiindane units. Blends in which the polycarbonate portion contains such units in amounts up to 5 mole percent also have excellent ductility.Type: GrantFiled: July 8, 1999Date of Patent: January 16, 2001Assignee: General Electric CompanyInventors: Jos Herman Peter Bastiaens, John Robert Campbell, Gary Charles Davis, Luc Carlos Govaerts
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Patent number: 6150455Abstract: A thermostable polymer electrolyte gel containing an acrylonitrile polymer, an electrolyte and a solvent, the acrylonitrile polymer having an acrylonitrile content of from 89 wt % to 98 wt % and meeting the following relationship:1,040,000-(A.times.10,000).ltoreq.B.ltoreq.1,490,000-(A.times.10,000)where A is the acrylonitrile content in wt % and B is the weight average molecular weight of the acrylonitrile polymer, the polymer electrolyte gel having an ion conductivity of 10.sup.-3 S/cm or higher at 20.degree. C., exhibiting the "retention of shape" in a thermostability test, and containing the acrylonitrile polymer in a proportion of from 3 wt % to 9 wt %. The thermostable polymer electrolyte gel can be produced by dissolving an acrylonitrile polymer and an electrolyte in a solvent to prepare a solution of the polymer, and cooling the polymer solution to a temperature of 0.degree. C. or lower.Type: GrantFiled: November 4, 1997Date of Patent: November 21, 2000Assignees: Toyo Boseki Kabushiki Kaisha, Japan Exlan Company, Ltd.Inventors: Hiroyuki Takamiya, Ryosuke Nishida, Tatsuaki Sumitani
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Patent number: 6087453Abstract: This invention provides a vulcanizable rubber composition comprising (a) 100 parts by weight of a nitrile-containing highly saturated copolymer rubber obtained by hydrogenating the conjugated diene portions of an unsaturated nitrile-conjugated diene-unsaturated carboxylic acid ester copolymer, (b) 10 to 100 parts by weight of a metallic salt of an .alpha.,.beta.-ethylenically unsaturated carboxylic acid, (c) 0.1 to 30 parts by weight of an organic peroxide vulcanizing agent, and optionally (d) 0.5 to 30 parts by weight of a compound of a group 2A metal in the periodic table. The vulcanized product of this composition is useful as a seal for Freons because it is excellent in low-temperature resistance and resistance to Freon gas permeation and has resistance to the production of cracks in the rubber surface due to the foaming of Freon gas.Type: GrantFiled: July 30, 1998Date of Patent: July 11, 2000Assignee: Nippon Zeon Co., Ltd.Inventor: Koichi Nishimura
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Patent number: 6057392Abstract: A method is disclosed for processing a rubber composition comprising thermomechanically mixing the rubber composition while maintaining a rubber temperature in a range of from 160.degree. C. to 190.degree. C. for a period of time ranging from 4 to 8 minutes, wherein said rubber composition is characterized by(i) 100 parts by weight of at least one sulfur vulcanizable elastomer containing olefinic unsaturation;(ii) 10 to 250 phr of a filler selected from the group consisting of silica, carbon black and mixtures thereof; and(iii) 0.5 to 50 phr of an ester of the formula: ##STR1## wherein R.sup.1 is selected from the group consisting of alkyls having from 16 to 18 carbon atoms and alkenyls and alkadienyls having from 16 to 18 carbon atoms; and R.sup.2 is selected from the group consisting of alkyls having from 12 to 22 carbon atoms.Type: GrantFiled: February 17, 1998Date of Patent: May 2, 2000Assignee: The Goodyear Tire & Rubber CompanyInventors: Lawson Gibson Wideman, Paul Harry Sandstrom
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Patent number: 6031042Abstract: Nitrile rubber compositions, articles of manufacture made therefrom, and methods of making them, are disclosed. The nitrile rubber compositions of the invention are substantially free of zinc oxide, and have good strength and chemical resistance while being softer than many conventional nitrile rubbers. The invention provides articles of manufacture, including gloves, which are soft, yet strong, and can be economically manufactured.Type: GrantFiled: June 20, 1996Date of Patent: February 29, 2000Assignee: North Safety Products Inc.Inventor: Timothy M. Lipinski
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Patent number: 6011107Abstract: A coating composition for producing a water washable, protective coating, comprising, by weight, 10-50% of a mixture of at least two acrylic polymers each having different molecular weights, acid numbers, and glass transition temperatures. The composition includes water and an alkali, in an amount sufficient to maintain the composition at a pH in the range of 7.5 to 9.5 and is further characterized in that the average molecular weight of the mixture of the at least two acrylic polymers is in the range of approximately 35,000 to 100,000. The average acid number of the mixture is in the range of approximately 65 to 150 and the glass transition temperature of a coating produced by the evaporation of the water from the composition is in the range of 0 to 70.degree. C.Type: GrantFiled: August 25, 1998Date of Patent: January 4, 2000Assignee: Gage Products CompanyInventors: Jeffrey Maxwell, Xenophon G. Saquet
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Patent number: 5916931Abstract: An aerosol propellant for sealing punctures in tires comprises a methylene chloride-in-water emulsion comprising water, methylene chloride, a curable acrylonitrile-butadiene-styrene (ABS) polymer latex and a surfactant, the emulsion having been blended with a fibrous plugging/matting agent, a carbon dioxide containing propellant or propellant blend in an amount sufficient to at least partially inflate a tire, and a corrosion inhibitor. The tire inflator/sealer provides an ozone friendly product.Type: GrantFiled: August 25, 1997Date of Patent: June 29, 1999Assignee: Engine Fog Inc.Inventors: Lawrence J. Adams, Paul D. Hughett
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Patent number: 5861442Abstract: Process of mixing a fugitive plasticizer, e.g., ethylene carbonate, with moist particulate polyacrylonitrile then removing the water enabling adjustment of the melt viscosity for extrusion of the polyacrylonitrile into film, fiber, pellets and shaped articles. Stretching and heating the extruded polyacrylonitrile film or fiber causes the fugitive plasticizer to exude and vaporize from the film or fiber, carrying with it any remaining acrylonitrile monomer. The resulting film or fiber exhibits substantially increased molecular weight, thus enhancing the tensile strength and barrier properties of the polyacrylonitrile product. The process also produces polyacrylonitrile foam products. A novel cross-linking agent for polyacrylonitrile, divinyloxybutane, is disclosed. Thermostabilizing agents for polyacrylonitrile, N-maleimides and stilbene derivatives, are also disclosed.Type: GrantFiled: August 8, 1996Date of Patent: January 19, 1999Assignee: Solcar Polymer, Limited PartnershipInventors: Edmund H. Merz, Roy A. White, John P. Fouser, Norman Fishman
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Patent number: 5747559Abstract: A composition comprising an ethylene containing polymer, a crosslinking agent and a treated filler material. The treated filler material comprises a treating agent which is a polymer comprising acrylonitrile and at least one other monomer. A preferred treated filler material is a treated carbon black and a preferred ethylene containing polymer is an ethylene vinyl acetate (EVA) polymer. A semiconductive composition of the present invention may be advantageously utilized in electrical wire and cable application.Type: GrantFiled: November 22, 1995Date of Patent: May 5, 1998Assignee: Cabot CorporationInventors: Robert S. Whitehouse, Thomas F. Reed
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Patent number: 5703189Abstract: An saturated nitrile-conjugated diene copolymer obtained by copolymerizing acrylonitrile with butadiene in the presence of a free radical initiator and an alkylthiol compound as a molecular weight modifier. A part of the monomers is incorporated in a monomer charge before polymerization, and the remainder thereof is added in a polymerization mixture during polymerization. The alkylthiol compound has 12 to 16 carbon atoms, which include at least three tertiary carbon atoms, and further has a sulfur atom directly bound to at least one of the tertiary carbon atoms. The copolymer has a Mooney viscosity of 15 to 450 and a bound nitrile content of 10 to 60% by weight. The breadth (.DELTA.AN) of compositional distribution of the unsaturated nitrile in the copolymer is 3 to 20. The copolymer is used in combination with a sulfur-containing vulcanizer.Type: GrantFiled: February 28, 1997Date of Patent: December 30, 1997Assignee: Nippon Zeon Co., Ltd.Inventors: Suguru Tsuji, Yuichi Uchizono
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Patent number: 5688858Abstract: The invention relates to a polymer suitable as a dispersant, built up fromA) 0-80 mol % of one or more monomers having the formula ##STR1## in which R.sub.1, R.sub.2, R.sub.3 and R.sub.4 may be the same or different and represent H or alkyl,B) 0-70 mol % of one or more monomers having the formula ##STR2## in which R.sub.5, R.sub.6 and R.sub.7 may be the same or different and represent H or alkyl and R.sub.8 is alkyl or substituted alkyl, and the alkyl group R.sub.Type: GrantFiled: June 7, 1995Date of Patent: November 18, 1997Assignee: Efka Chemicals B.V.Inventors: Peter Hermann Quednau, Walter Andreas Wulff
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Patent number: 5661203Abstract: Organosiloxane compositions exhibiting excellent vibration damping properties comprise(A) from 70 to 99.9 weight percent of a liquid polyorganosiloxane,(B) from 0.1 to 10 weight percent of hollow particles of a thermoplastic organic resin, and(C) from 0 to 20 weight percent of a thickener.Type: GrantFiled: April 17, 1996Date of Patent: August 26, 1997Assignee: Dow Corning Toray Silicone Co., Ltd.Inventors: Shoji Akamatsu, Yasue Kanzaki
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Patent number: 5651995Abstract: A nitrile group-containing highly saturated copolymer rubber which is a product obtained by hydrogenating the conjugated diene portion of an unsaturated nitrile-conjugated diene copolymer. The highly saturated copolymer rubber has an alkylthio group having 12 to 16 carbon atoms, which include at least three tertiary carbon atoms, and having a sulfur atom which is directly bound to at least one of the tertiary carbon atom, and the highly saturated copolymer rubber further has a Mooney viscosity of 15 to 200 and an iodine value not larger than 80. The highly saturated copolymer rubber is produced copolymerizing an unsaturated nitrile, a conjugated diene and an optional copolymerizable monomer by using as a molecular weight modifier an alkylthiol compound having 12 to 16 carbon atoms, which include at least three tertiary carbon atoms, and having a sulfur atom which is directly bound to at least one of the tertiary carbon atoms; and then, hydrogenating the thus-obtained copolymer.Type: GrantFiled: June 7, 1995Date of Patent: July 29, 1997Assignee: Nippon Zeon Co., Ltd.Inventors: Motofumi Oyama, Yoshiaki Aimura, Kazuyoshi Nakajima, Osamu Mori, Mitsugu Ishihara
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Patent number: 5589520Abstract: Process of mixing a fugitive plasticizer, e.g., ethylene carbonate, with moist particulate polyacrylonitrile then removing the water enabling adjustment of the melt viscosity for extrusion of the polyacrylonitrile into film, fiber, pellets and shaped articles. Stretching and heating the extruded polyacrylonitrile film or fiber causes the fugitive plasticizer to exude and vaporize from the film or fiber, carrying with it any remaining acrylonitrile monomer. The resulting film or fiber exhibits substantially increased molecular weight, thus enhancing the tensile strength and barrier properties of the polyacrylonitrile product. The process also produces polyacrylonitrile foam products. A novel cross-linking agent for polyacrylonitrile, divinyloxybutane, is disclosed. Thermostabilizing agents for polyacrylonitrile, N-maleimides and stilbene derivatives, are also disclosed.Type: GrantFiled: February 3, 1995Date of Patent: December 31, 1996Assignee: Solcas Polymer, Limited PartnershipInventors: Edmund H. Merz, Roy A. White, John P. Fouser, Norman Fishman
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Patent number: 5559178Abstract: A composition for coating wet rubber particles during extrusion and pelletization prior to drying comprising an inorganic partitioning agent, a thickener and binder reagent, water and a water soluble anionic dispersant, and the process for application to elastomers including those of low viscosity or high resin content to improve their processability during manufacture.Type: GrantFiled: January 18, 1994Date of Patent: September 24, 1996Assignee: DSM Copolymer, Inc.Inventor: Lincoln Widmer
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Patent number: 5468800Abstract: Aqueous binders for liquid coating agents which contain a film-forming, aqueous plastic dispersion and a crosslinking component can be stored in ready-to-use form and quickly harden after being processed into a coating, at room temperature or a temperature just slightly above, forming a hard, dry, crosslinkable film. The plastic dispersion is an emulsion polymer with polymerized units of an ethylenically-unsaturated, radically polymerizable monomer with an alkylene urea side group. The crosslinking agent contains at least two, possibly protected, aldehyde groups.Type: GrantFiled: February 3, 1994Date of Patent: November 21, 1995Assignee: Roehm GmbH Chemische FabrikInventors: Karl J. Folsch, Marita Kaufmann, Jurgen Hartmann
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Patent number: 5434205Abstract: A process for providing extrudable polyacrylonitrile compositions. Dry, particulate polyacrylonitrile having a moisture content of less than about 1.5 percent is mixed with a liquid plasticizer such as ethylene carbonate or propylene carbonate at a mixing temperature of about 140.degree. C. to about 180.degree. C. This process produces an extrudable polyacrylonitrileplasticizer composition which can be extruded to form film, fiber or other extruded or co-extruded products.Type: GrantFiled: August 4, 1993Date of Patent: July 18, 1995Assignee: Solcas Polymer Limited PartnershipInventor: Norman Fishman
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Patent number: 5412048Abstract: Spherical monodispersed polymeric particles are prepared from vinyl monomers and crosslinking polymerizable polyvinyl monomers. More particularly, a novel process for producing spherical monodispersed gel particles that are about 1-6 .mu.m in size and contain at least about 0.5 to about 3 weight percent (based on polymerizable vinyl monomer/vinyl polymer) of a polymerizable polyvinyl monomer is disclosed. The process comprises the steps of combining an isoalkanol solvent, a polymerizable vinyl monomer and a crosslinking polymerizable polyvinyl monomer under timed and monitored conditions.Type: GrantFiled: July 26, 1993Date of Patent: May 2, 1995Assignee: General Electric CompanyInventors: Kathryn L. Longley, John C. Schmidhauser
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Patent number: 5338605Abstract: Hollow carbon and graphite filaments having a specific gravity of about 20-50% less than conventional solid carbon fibers made of the same precursor resin are formed by spinning hollow precursor resin filaments. These low density hollow carbon filaments have improved insulating properties compared with conventional solid carbon fibers and have an excellent bending strength to weight ratio.Type: GrantFiled: April 22, 1991Date of Patent: August 16, 1994Assignee: Ketema, Inc.Inventors: Robert L. Noland, Timothy D. O'Brien
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Patent number: 5304590Abstract: Process of mixing a fugitive plasticizer, e.g., ethylene carbonate, with moist particulate polyacrylonitrile then removing the water enabling adjustment of the melt viscosity for extrusion of the polyacrylonitrile into film, fiber, pellets and shaped articles. Stretching and heating the extruded polyacrylonitrile film or fiber causes the fugitive plasticizer to exude and vaporize from the film or fiber, carrying with it any remaining acrylonitrile monomer. The resulting film or fiber exhibits substantially increased molecular weight, thus enhancing the tensile strength and barrier properties of the polyacrylonitrile product. The process also produces polyacrylonitrile foam products. A novel cross-linking agent for polyacrylonitrile, divinyloxybutane, is disclosed. Thermostabilizing agents for polyacrylonitrile, N-maleimides and stilbene derivatives, are also disclosed.Type: GrantFiled: January 21, 1992Date of Patent: April 19, 1994Assignee: Solcas Polymer, Inc.Inventors: Edmund H. Merz, Roy A. White, John P. Fouser, Norman Fishman
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Patent number: 5244943Abstract: A nitrile group-containing rubber latex comprising an aqueous dispersion of a nitrile group-containing highly saturated rubber having an iodine value of not more than 120. The said rubber latex can be produced by converting a solution of a nitrile group-containing highly saturated polymer rubber having an iodine value of not more than 120 in an inert solvent into an oil-in-water emulsion using water and an emulsifier, and removing the solvent from the resulting emulsion.Type: GrantFiled: May 6, 1992Date of Patent: September 14, 1993Assignee: Nippon Zeon Co., Ltd.Inventors: Motofumi Oyama, Osamu Mori, Nagatoshi Sugi
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Patent number: 5218025Abstract: Rubber filled with an inorganic whity filler such as white carbon is improved in its vulcanized rubber properties such as tensile strength, tear strength and heat build-up resistance by incorporating thereto a dinitrodiamine compound represented by the formula of ##STR1## wherein X is a divalent aliphatic, alicyclic or aromatic group which may contain halogen or oxygen in the group, R.sup.1 is hydrogen, an aliphatic group, an alicyclic group or an aromatic group, with the proviso that two nitrogen atoms linking through X may further link through R.sup.1 when both X and R.sup.1 are the aliphatic groups, and R.sup.2 and R.sup.3 independently of one another are each hydrogen or an alkyl of 1 to 12 carbon atoms, with the proviso that R.sup.2 and R.sup.3 may conjointly form a ring. The dinitrodiamine compound acts as a coupling agent for the rubber and the inorganic whity filler.Type: GrantFiled: July 28, 1992Date of Patent: June 8, 1993Assignee: Sumitomo Chemical Company, LimitedInventors: Isao Kurimoto, Naoki Inui, Tetsuo Yamaguchi
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Patent number: 5218039Abstract: Stable emulsions and dispersions of both the water-in-oil and oil-in-water types are prepared by subjecting mixtures of the two phases to shear stress in the presence of nitrile group-containing copolymers capable of forming hydrogels containing at least 90% by weight of water at room temperature.Type: GrantFiled: April 28, 1987Date of Patent: June 8, 1993Assignee: Kingston Technologies, Inc.Inventors: Vladimir Stoy, Jan Lovy
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Patent number: 5214091Abstract: Disclosed in this invention is a thermoplastic resin composition comprising a thermoplastic resin, a conductive inorganic filler and/or a non-conductive inorganic filler, and an adduct of an ethylene oxide with a saponified product of a copolymer of ethylene and a vinyl ester of a saturated carboxylic acid. The adduct of an alkylene oxide with a saponified product of a copolymer of ethylene and a vinyl ester of a carboxylic acid is an additive having excellent compatibility with the thermoplastic resin and useful for improving dispersibility of the inorganic filler.Type: GrantFiled: March 4, 1992Date of Patent: May 25, 1993Assignee: Sumitomo Chemical Company, LimitedInventors: Hisao Tanaka, Sumio Hara
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Patent number: 5166227Abstract: High amounts of silicon dioxide are readily incorporated into an emulsion polymerized elastomer by mixing an aqueous dispersion of silicon dioxide with a latex of the emulsion polymer and subsequently spray drying the mixture. Free flowing, fine-size (e.g., less than 500 micrometers) particles are produced with generally complete incorporation of silicon dioxide. The presence of the silicon dioxide permits rubbers with low gel and/or low Mooney viscosity to be spray dried whereas previously this could not be accomplished. Compared to conventional means of adding a silica to a bale rubber, the above powdered masterbatch gives shorter mixing times with lower power consumption with improved physical properties, such as tensile strength.Type: GrantFiled: November 29, 1990Date of Patent: November 24, 1992Assignee: Zeon Chemicals USA, Inc.Inventors: Charles C. Raines, Philip H. Starmer
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Patent number: 5158606Abstract: A printing ink composition having a high degree of rub-off resistance comprising (a) a dispersion of a pigment in a vehicle containing a C.sub.7 -C.sub.40 oil and (b) a polymer latex emulsified in said dispersion. When employed for printing at high speeds, an anti-misting compound such as tridecyl acid phosphate, phosphoric acid, glycerol, or propylene carbonate is preferentially added to the ink composition. Where cost is not of paramount concern, a polytetrafluoroethylene wax is preferentially added to the ink composition.Type: GrantFiled: March 6, 1991Date of Patent: October 27, 1992Assignee: Sun Chemical CorporationInventors: Daniel J. Carlick, Robert W. Bassemir, Ramasamy Krishnan, Richard R. Durand, Jr.
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Patent number: 5149732Abstract: Rubber compositions are disclosed for integral attachment of polymeric and metallic materials. Improved bondability is attributed to the use of a selected base rubber blended with a selected class of inorganic or organic fillers, silane compounds and vulcanizing agents such that the finished composition is provided with a specified range of Mooney viscosities. Also disclosed is a method of hose-metal fitting connection by the application of the composition. Gas- and oil-impermeability characteristics are greatly enhanced.Type: GrantFiled: March 6, 1990Date of Patent: September 22, 1992Assignee: The Yokohama Rubber Co., Ltd.Inventors: Shigeru Igarashi, Osamu Ozawa, Tetsu Kitami
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Patent number: 5115011Abstract: This invention relates to a process for producing a quality-improved water-absorbent polymer in which the aqueous liquid (I), which is obtained by mixing in an aqueous medium at least one kind of a water-soluble salt (A) selected from a group of halogenated compounds, sulfates, acetates, and nitrates, which are derived from at least one kind of a polyvalent metal selected from a group of aluminum, calcium, and magnesium, with at least one kind of a water-soluble salt (B) selected from a group of monovalent metal salts and ammonium salts, which are derived from at least one kind of an oxyacid selected from a group of sulfurous acid and thiosulfuric acid, is mixed with a water-absorbent polymer (II) in a proportion of that the water-soluble salt of the polyvalent metal (A) is in a range of 0.1.about.10 parts by weight against 100 parts by weight of the water-absorbent polymer (II) and the water-soluble salt of the oxyacid (B) is in a range of 0. 1.about.Type: GrantFiled: February 20, 1990Date of Patent: May 19, 1992Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.Inventors: Nobuyuki Harada, Toshihiro Okuno, Tadao Shimomura
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Patent number: 5093410Abstract: A shaped article of gypsum possessing heretofore unattainable high strength, a method for the production of the shaped article, and a method for the production of inclusion water indispensable to the hardening by hydration of the production of the shaped article of gypsum are disclosed.Type: GrantFiled: July 17, 1991Date of Patent: March 3, 1992Assignee: Osaka Yuki Kagaku Kogyo Kabushiki KaishaInventors: Taiji Kambayashi, Hideyuki Mekata, Hiroyuki Kataoka, Chuzo Kato
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Patent number: 5068313Abstract: The present invention relates to a process for minimizing or reducing the amount of residual free hydrazine in polymer latices. The process is particularly useful in the manufacture of hydrogenated nitrile rubber which is resistant to oxidative degradation at high temperatures, as well as resistant to corrosive environments such as acid environments. Nitrile rubbers are useful in the manufacture of fan belts, seals, gaskets, and hoses in increasingly small and hot-running car engines.Type: GrantFiled: May 16, 1989Date of Patent: November 26, 1991Assignee: Olin CorporationInventor: Henry W. Schiessl
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Patent number: 5057601Abstract: This invention relates to a process for making nitrile rubber characterized by being essentially gel-free and at least about 90% saturated. The process comprising reacting an ethylenically unsaturated polymer in latex from, hydrazine, and an oxidant, followed by coagulation and filtration in order to isolate the reduced rubber. The process utilizes a reaction mixture containing a high molar ratio of hydrazine to unsaturated polymer.Type: GrantFiled: November 6, 1989Date of Patent: October 15, 1991Assignee: Olin CorporationInventors: Henry W. Schiessl, Francis W. Migliaro, Jr.
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Patent number: 5026765Abstract: Carpet coating compositions are disclosed which comprise 40 to 80 percent by weight filler and 20 to 60 percent by weight of a latex binder, the binder comprising an emulsion polymer ofa) 40 to 80% by weight of a vinyl ester of an alkomoic acid, the acid having from 1 to 13 carbon atoms;b) 5 to 25% by weight of a copolymerizable comonomer having a Tg of at least 50.degree. C.; and;c) 10 to 30% ethylene.Type: GrantFiled: December 15, 1989Date of Patent: June 25, 1991Assignee: National Starch and Chemical Investment Holding CorporationInventors: Howard G. Katz, David Lunsford, Paul R. Mudge
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Patent number: 5025062Abstract: Coating materials based on synthetic resin contain, as binders, polymers which consist ofA) from 60 to 100% by weight of a tert-butyl ester of an .alpha.,.beta.-ethylenically unsaturated carboxylic acid or dicarboxylic acid of not more than 5 carbon atoms or a mixture of such tert-butyl esters,B) from 0 to 40% by weight of an acrylate or methacrylate of a nontertiary C.sub.1 -C.sub.20 -alkanol or a mixture of these monomers,C) from 0 to 20% by weight of vinyl chloride, vinyl acetate and/or vinyl propionate, the relationship m.sub.C .ltoreq.0.5 m.sub.B being applicable to the amounts m.sub.B and m.sub.C of the monomers B and C,C) from 0 to 10% by weight of acrylic acid, methacrylic acid, acrylamide and/or methacrylamide andE) from 0 to 5% by weight of other copolymerizable monomers.Type: GrantFiled: May 3, 1990Date of Patent: June 18, 1991Assignee: BASF AktiengesellschaftInventors: Gregor Ley, Wolfgang Schultze, Johannes Vinke, Eckehardt Wistuba
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Patent number: 5019617Abstract: Rubber compositions are disclosed which exhibit enhanced dynamic modulus and tensile strength characteristics. A selected type of carbon black, resorcinsol and/or its precondensate and hexamethoxymethyl melamine are combined in specified amounts with a selected class of starting rubbers. The carbon black has specified nitrogen adsorption surface area, dibutyl phthalate adsorptivity and Dst mode of diameter.Type: GrantFiled: September 21, 1989Date of Patent: May 28, 1991Assignee: The Yokohama Rubber Co., Ltd.Inventors: Hiroyuki Kaidoo, Takao Muraki
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Patent number: 5017630Abstract: High amounts of silicon dioxide are readily incorporated into an emulsion polymerized elastomer by mixing an aqueous dispersion of silicon dioxide with a latex of the emulsion polymer and subsequently spray drying the mixture. Free flowing, fine-size (e.g., less than 500 micrometers) particles are produced with generally complete incorporation of silicon dioxide. The presence of the silicon dioxide permits rubbers with low gel and/or low Mooney viscosity to be spray dried whereas previously this could not be accomplished. Compared to conventional means of adding a silica to a bale rubber, the above powdered masterbatch gives shorter mixing times with lower power consumption with improved physical properties, such as tensile strength.Type: GrantFiled: August 17, 1989Date of Patent: May 21, 1991Assignee: Zeon Chemicals USA, Inc.Inventors: Charles C. Raines, Philip H. Starmer
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Patent number: 5013783Abstract: Hydrogenated nitrile rubbers filled with sodium aluminium silicate suffer relatively little deterioration of the mechanical properties, e.g. elongation at break, during hot air aging.Type: GrantFiled: June 11, 1990Date of Patent: May 7, 1991Assignee: Bayer AktiengesellschaftInventors: Joachim Thormer, Ernst Rohde, Zsolt Szentivanyi
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Patent number: 4954614Abstract: This invention relates to a process for reducing or eliminating hydrazine from a mixture containing hydrazine and a polymer, wherein the polymer is in latex form.Type: GrantFiled: May 11, 1989Date of Patent: September 4, 1990Assignee: Olin CorporationInventors: Henry W. Schiessl, Steven A. Manke
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Patent number: 4897440Abstract: An improved, abrasion-resistant rice hulling roll comprises a core with coating of a nitrile rubber compound, particularly a carboxylated nitrile rubber compound. The hulling rolls of this invention are characterized by substantially improved wear life as compared to conventional rolls made of styrene-butadiene rubber (SBR). The nitrile rubbers are also useful in other wear-resistant applications.Type: GrantFiled: March 3, 1988Date of Patent: January 30, 1990Inventor: Ching-Tsan Lo
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Patent number: 4886704Abstract: This invention relates to a strippable coating film for use as a masking material serving to create attractively finished boundaries, for example, in multi-color painting of automobiles and the like, as well as a coating method using such a coating film.A coating film containing 1 to 20 parts by weight of carbon black per 100 parts by weight of the resin component present therein is suitable. Especially preferred is a coating film formed of an acrylic emulsion paint and having an adhesion to the substrate of 20 to 1000 g/inch as expressed in terms of 180.degree. peeling strength. It is disclosed that, by equipping a YAG laser with a Q-switching oscillator unit and operating the Q-switch at a pulse repetition frequency of 0.5 to 30 kHz, the coating film can be cleanly cut to achieve an attractive finish in multi-color painting.Type: GrantFiled: June 26, 1987Date of Patent: December 12, 1989Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Keiichi Kamada, Motoyuki Torikai, Yasuo Ohkita
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Patent number: 4851469Abstract: Rubber compositions are disclosed which are capable of exhibiting superior adhesion and high water resistance in bonding rubbers to brass and to organic fiber cords and also to different rubbers. Such bonding characteristics can be obtained by the use of specified amounts of a selected class of organic sulfur-containing compounds combined with sulfur-curable rubbers, silica, resorcin donors and methylene donors. Hoses are also disclosed which have these compositions applied as adhesive layers.Type: GrantFiled: November 16, 1988Date of Patent: July 25, 1989Assignee: The Yokohama Rubber Co., Ltd.Inventor: Tomoji Saitoh
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Patent number: 4831069Abstract: A spinning solution for acrylonitrile polymers is disclosed, which has a viscosity of 30 to 520 poises (at 50.degree. C.) and which comprises an acrylonitrile polymer having a reduced viscosity of not less than 4.0, a solvent, and water, wherein the water concentration and the polymer concentration fall within the range in the drawing surrounded by straight lines connecting point A (1 wt % and 30 wt % respectively), point B (1 wt % and 10 wt % respectively), and point C (10 wt % and 10 wt % respectively). The spinning solution exhibits satisfactory spinnability in spite of its high polymer concentration and provides void-free acrylonitrile fibers having a highly circular cross-section and excellent mechanical strength.Type: GrantFiled: November 16, 1987Date of Patent: May 16, 1989Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Teruhiko Sugimori, Yoshifumi Furutani, Yoshinobu Shiraishi, Toshiyuki Yasunaga
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Patent number: 4822845Abstract: It now has been found that uncured rubber composition comprising rubbers having an unsaturated carbon chain and at least one carbon black can be improved by including therein, a minor property-improving amount of at least one aromatic heterocyclic di-N-oxide compound of the partial formula ##STR1## wherein the depicted carbon atoms are part of an optionally substituted aromatic ring, and R.sup.1 and R.sup.2 are each independently hydrogen, hydrocarbyl, halohydrocarbyl, hydrocarbyloxy, hydrocarbyl sulfonyl, hydrocarbyl thio, hydrocarbylsulfoxidyl, halogen, amino,--CN--OH--CHO--CH(O hydrocarbyl)2--C(O)R.sup.3--C(O)OR.sup.3--C(N--OH)R.sup.3--C(O)NR.sup.3 R.sup.6--CH.dbd.N--NH--C(O)OR.sup.3--CH.sub.2 OC(O)CH.sub.3--R.sup.4 YR.sup.3--C(O)NHR.sup.4 OH--C(NH)NR.sup.7 R.sup.8,or--C(O)NHN(R.sup.3).sub.2wherein each R.sup.3 is independently hydrogen or a hydrocarbyl group, R.sup.4 is a divalent hydrocarbyl group, R.sup.6 is hydrogen, hydrocarbyl, --R.sup.4 OR.sup.3, or --R.sup.4 COOR.sup.3 ; R.sup.Type: GrantFiled: April 13, 1987Date of Patent: April 18, 1989Assignee: The Firestone Tire & Rubber & CompanyInventors: Daniel F. Graves, Hans-Wilhelm Engels