Abstract: The present disclosure provides a method of manufacturing bis(2-hydroxyethyl) cyclohexane-1,4-dicarboxylate (BHCD) and derivatives thereof. The method includes the following steps. A first reactant including bis-hydroxyethyl terephthalate (BHET) is provided. 2-(2-hydroxyethoxy)ethyl 2-hydroxyethyl terephthalate (BHEET) is added to the first reactant including BHET to form a second reactant. The second reactant is hydrogenated.

Abstract: A water repellent film (200) according to the present invention includes a first layer (10) having a plurality of fine protrusions (100) on the surface thereof, a second layer (20) covering the fine protrusions (100) and having a water repellent property, and a third layer (30) provided on the surface of the first layer (10) on the opposite side of the fine protrusions (100). When a modulus of elasticity of the first layer (10) is defined as E1, a modulus of elasticity of the second layer (20) is defined as E2, and a modulus of elasticity of the third layer (30) is defined as E3, a definition of E2>E1>E3 is fulfilled. Accordingly, the water repellent film having excellent resistance to abrasion in which a fine structure is not easily abraded and damaged by an external friction force or the like can be obtained.

Abstract: Disclosed is a polyvinyl chloride resin latex which is prepared by polymerization using a decreased amount of polymerization water in an early polymerization stage and then additional polymerization water in a late polymerization stage, so that the polyvinyl chloride resin latex has an increased solid content and a decreased water content and thus finally remarkably reduces energy consumption in a spray drying process.

Abstract: Processes for making a polyvinyl chloride (PVC) dry blend composition with a phthalate-free, bio-based plasticizer and filler, having a bulk density of greater than 0.67 g/cc and an extrusion rate of greater than 65 gm/minute for a single screw extruder of 0.75 in barrel diameter with a 25:1 L:D general purpose polyethylene screw at 75 rotations per minute screw speed, and compositions made by the processes are provided.

Abstract: Waterborne coating compositions are disclosed that include a latex emulsion polymer, and, as a coalescent, a diester of hydroxypivalyl hydroxypivalate. The coating compositions of the invention have a reduced VOC content and provide satisfactory coalescing activity.

Abstract: The present invention relates to the manufacture of alkyl p-toluates from an alkyl p-toluic acid ester and a mono-functional, branched, linear or cyclic medium chain length alkyl alcohol, and their use as a plasticizer in polymers. Additionally, the present invention relates to articles and materials comprising such alkyl p-toluates.

Abstract: Processes for making a polyvinyl chloride (PVC) dry blend composition with a phthalate-free, bio-based plasticizer and filler, having a bulk density of greater than 0.67 g/cc and an extrusion rate of greater than 65 gm/minute for a single screw extruder of 0.75 in barrel diameter with a 25:1 L:D general purpose polyethylene screw at 75 rotations per minute screw speed, and compositions made by the processes are provided.

Abstract: A vibration-damping rubber composition is provided, which is used as a material for a rubber member of a liquid-filled vibration-damping rubber device in which a glycol liquid is sealingly contained. The rubber composition comprises: (A) a chloroprene rubber as a major component; and (B) an aromatic hydrocarbon plasticizer. The rubber composition makes it possible to suppress increase in the hardness of the rubber member (chamber wall) after thermal aging and reduction in durability.

Abstract: The present invention is directed towards compositions having lecithin and a plasticizer. Processes for producing such compositions are further disclosed. The present invention is also directed towards uses of the novel compositions as a dispersant in order to disperse compounds, such as in the fields of coatings, inks, cosmetics and the like. In one embodiment, the dispersants of the present invention are used to disperse pigments.

Abstract: A polyvinyl chloride-type covering material for electric wire that has an excellent damage-resistance property, cold-resistance property and low-temperature property after aging. The covering material containing a polyvinyl chloride comprises, with respect to 100 parts by mass of the polyvinyl chloride, (A) 15 to 30 parts by mass of a plasticizer comprising 15 parts by mass or more of one or more plasticizers selected from trimellitate plasticizers and pyromellitate plasticizers, (B) 2 to 10 parts by mass of a chlorinated polyolefin, and (C) 1 to 6 parts by mass of a methyl methacrylate-butadiene-styrene copolymer.

Abstract: Presently disclosed are high purity unsaturated fatty acid esters with an ester moiety characterized by having from five to seven members in a ring structure, which esters when epoxidized find particular utility as primary plasticizers in flexible polyvinyl halide applications. Also disclosed are processes for making the high purity esters.

Abstract: C7-C12 secondary alcohol esters of cyclohexanecarboxylic acids are especially useful as plasticizers for PVC and other plasticizable polymers. In embodiments, these plasticizers are useful in plastisol formulations to help improved processability of flexible PVC material. In other embodiments these same plasticizers can be used in blends with other plasticizers to improve processability. In preferred embodiments these same plasticizers can be used to prepare flexible PVC compounds with enhanced low temperature flexibility, low toxicity, and improved resistance to outdoor aging.

Abstract: Plasticizer blends of C10 to C14 dialkyl phthalates or C8 to C10 trimellitates and C11 to C14 dialkyl adipates are provided. The blends may be used in the manufacture of flexible PVC formulations, for example, as wire and cable coatings, having in several embodiments, good performance over a wide temperature range and are particularly useful for automotive cables.

Abstract: Esters of cyclohexane polycarboxylic acids are used as plasticisers for polyvinyl chloride to enable products with comparable mechanical properties to be obtained using less polyvinyl chloride. Use of these esters also produces formulations with increased stability to ultra-violet light, improved low temperature properties, lower viscosity and improved processability as well as reduced smoke on burning. The esters of cyclohexane polycarboxylic acids may be used alone or in admixture with other plasticisers when the esters of cyclohexane polycarboxylic acids may act as viscosity depressants. Fast fusing plasticisers may also be included. The formulations and processes of making these formulations are particularly useful in the production of a range of goods from semi-rigid to highly flexible materials and are particularly useful in the production of medical materials, toys, and food contact articles.

Abstract: The present invention is a replacement plasticizer system made from or containing an epoxidized fatty acid ester plasticizer as a primary plasticizer and a secondary plasticizer. The replacement placement system is useful with a variety of polymers in applications such as wire-and-cable insulations, wire-and-cable jackets, coatings, adhesives, and castings.

Abstract: A subject matter of the present invention is a novel stabilizing ingredient for halogenated polymers comprising at least one ?-carbonyl compound, an additive composition for halogenated polymers comprising the ingredient and a stabilized composition based on a halogenated polymer. The invention provides improvements as regards stabilization of halogenated polymers. The invention can in particular be applied to the stabilization of poly(vinyl chloride).

Abstract: Vinylidene chloride copolymer composition characterized in that it comprises: (A) at least one vinylidene chloride copolymer which is a copolymer composed of vinylidene chloride in an amount of at least 50 wt % and of at least one comonomer at least one of which is chosen from (meth)acrylic monomers corresponding to the general formula: CH2?CR1R2, in which R1 is chosen from hydrogen and the methyl radical and R2 is the —CO—R3 radical in which R3 is the —O—R4 radical with R4 chosen from the linear or branched alkyl radicals containing from 1 to 18 carbon atoms optionally bearing one or more —OH radicals, the epoxyalkyl radicals containing from 2 to 10 carbon atoms and the alkoxyalkyl radicals containing a total of 2 to 10 carbon atoms; (B) from 0.5 to 4 parts by weight, per 100 parts by weight of (A), of epoxidized soybean oil; (C) from 0.

Abstract: Heavy metal-free compostable polymers, composites and articles anaerobically biodegrade in landfills in a relatively short time. Heavy metal-free composite polymeric articles and sheets such as indoor or outdoor signs, billboards, banners, images, protective barriers, backdrops and wall coverings have very useful service durations and yet are landfill biodegradable.

Abstract: A polyvinyl chloride composition having polyvinyl chloride resin and a plasticizer ester selected from di-butyl terephthalate, di-isobutyl terephthalate, or mixtures thereof.

Abstract: Presently disclosed are high purity unsaturated fatty acid esters with an ester moiety characterized by having from five to seven members in a ring structure, which esters when epoxidized find particular utility as primary plasticizers in flexible polyvinyl halide applications. Also disclosed are processes for making the high purity esters.

Abstract: Esters of cyclohexane polycarboxylic acids are used as plasticizers for polyvinyl chloride to enable products with comparable mechanical properties to be obtained using less polyvinyl chloride. Use of these esters also produces formulations with increased stability to ultra-violet light, improved low temperature properties, lower viscosity and improved processability as well as reduced smoke on burning. The esters of cyclohexane polycarboxylic acids may be used alone or in admixture with other plasticizers when the esters of cyclohexane polycarboxylic acids may act as viscosity depressants. Fast fusing plasticizers may also be included. The formulations are particularly useful in the production of a range of goods from semi-rigid to highly flexible materials and are particularly useful in the production of medical materials such as blood bags and tubing.

Abstract: An environmentally-friendly ceramic-plastic composite and the preparation method thereof. The composite comprises: thermoplastics, bamboo or wood flour, plasticizer, inner and outer lubricant, crosslinking modifier, filling agent, flame retardant, pigment and ash raw material.

Abstract: The invention relates to mixtures of isononyl furan-2,5-dicarboxylate of formula (I), methods for producing said mixtures of isononyl furan-2,5-dicarboxylate of formula (I), compositions containing mixtures of isononyl furan-2,5-dicarboxylate of formula (I), uses of the mixtures of isononyl furan-2,5-dicarboxylate of formula (I) as plasticizers, and uses of the aforementioned compositions containing isononyl furan-2,5-dicarboxylate of formula (I).

Abstract: A PVC composition comprising PVC and a C4-C30 alkyl pyrrolidone additive present in an amount of 0.1 to 20 phr sufficient to improve PVC processing or treatment compared to a control composition without said additive.

Abstract: The instant invention relates to a composition and process for the stabilization of halogen containing polymer slurries, in particular polyvinylchloride (PVC). The composition comprises a halogen containing polymer in the form of an aqueous suspension or emulsion, a partially hindered phenolic antioxidant and selected sulfur containing antioxidants, which are both solid at 20° C. A further aspect of the invention is the use of specific antioxidant mixtures for the stabilization of halogen containing polymer suspensions or emulsions, in particular PVC.

Abstract: Esters of cyclohexane polycarboxylic acids are used as plasticisers for polyvinyl chloride to enable products with comparable mechanical properties to be obtained using less polyvinyl chloride. Use of these esters also produces formulations with increased stability to ultra-violet light, improved low temperature properties, lower viscosity and improved processability as well as reduced smoke on burning. The esters of cyclohexane polycarboxylic acids may be used alone or in admixture with other plasticisers when the esters of cyclohexane polycarboxylic acids may act as viscosity depressants. Fast fusing plasticisers may also be included. The formulations are particularly useful in the production of a range of goods from semi-rigid to highly flexible materials and are particularly useful in the production of medical materials such as blood bags and tubing.

Abstract: PVC resin-based compositions that include biochemical plasticizers as the primary plasticizers are provided. The compositions include PVC resin, a compatibilizer, one or more biochemical plasticizers and, optionally, a thermoplastic elastomer impact modifier. The biochemical plasticizers are present in substantial quantities in the compositions and, in some embodiments, are the only plasticizers present in the compositions.

Abstract: Both the viscosity of a plastisol comprising a dispersed polymer, a plasticizer for the polymers and at least one liquid diluent, and exudation of liquids from articles formed from the plastisol are minimized when the difference between 1) the weighted average of the Hildebrand solubility parameter values of all liquid ingredients, including plasticizer, in the plastisol and 2) the Hildebrand solubility parameter of the dispersed polymer is ±0.6 to ±1. The plastisols of the present invention are suitable for fabrication into films and molded objects, and as coating materials for a variety of metallic and non-metallic substrates.

Abstract: The present invention relates to materials for making cable jackets, particularly riser and plenum cables. The materials provide low flammability and allow the cable to meet UL 910 or NFPA 262 or UL 1666 specifications. The material contains PVC resin, a plasticizer, a metal oxide particle, and optionally a brominated phthalate. Preferably, the metal oxide particle is spherical amorphous silicon dioxide. More preferably, the spherical amorphous silicon dioxide has a mean particle size of about 100-200 nm and/or a BET surface area of about 10-30 m2/g. The metal oxide particle is also preferably metal oxide particle non-porous, non-ionic, and/or non-hydrated.

Abstract: A soft, pelletizable poly(vinyl chloride) plastisol having a Shore A hardness of less than about 70 is disclosed. The plasticizers employed in the plastisol can be petroleum-based plasticizers or bioplasticizers or both. A method of gelation, fusion, and controlled cooling in an agitating chamber permits a conventional liquid plastisol to be transformed into the pelletizable plastisol strand. If a pelletizer is used after cooling into strands or other shapes, then pelletized plastisol results. The formulation of liquid plastisol for hardness is unaffected by the transformation. The solidified plastisol can be stored for later extrusion or molding into a final plastic article shape.

Abstract: “The present invention relates to a novel PVC resin composition, produced such that the numerical ration of the renewable carbon in the composition relative to the total carbon in the composition is greater than or equal to 30%. Said composition can be used in the manufacture of automobile interior parts and thus meets all the necessary requirements for this use.

Abstract: A plasticizer capable of fast gelling and capable of imparting storage stability on plastisols contains dialkyl terephthalate, wherein the alkyl radicals of said dialkyl terephthalate have a longest carbon chain of at least 4 carbon atoms and have a total number of carbon atoms per alkyl radical of 5.

Abstract: A composition comprises a polyvinylchloride homopolymer, a biodegradable plasticizer and either a swelling agent or a carbohydrate coupled to the polyvinylchloride homopolymer or a combination thereof. The composition may further comprise a blowing agent. A coated fabric comprises a textile substrate and a biodegradable coating at least partially coating the textile substrate, wherein the biodegradable coating degrades at least 60% after 28 days under the ASTM D584 standard. A method of making a biodegradable coating comprises providing a polymer and blending a biodegradable plasticizer with the polymer to form a blend. A method of making a coated textile comprises providing a textile and a composition comprising a polymer, a biodegradable plasticizer, and at least one other component; applying the composition to the textile; and curing the composition, thereby making a coated textile.

Abstract: The present invention relates to a method of preparing a polymer resin based on a halogenated vinyl polymer and a copolymer bearing associative groups, comprising the steps that consist in forming a latex of each of these polymers, blending said latices, then isolating and drying the polymers contained in said latices in order to form a pulverulent resin. The present invention also relates to said resin, to a pulverulent composition containing said resin, and also to the use of this composition for manufacturing rigid or plasticized materials.

Abstract: Compositions of vinyl halide polymers such as PVC are rendered compostable by a prodegradant system of a monomeric adduct of an organotitanate or zirconate and an organotin. PVC sheets and composites are compostable in landfills.

Abstract: A polymer composition is provided that includes plastisols and organosols having reduced viscosities and which provide desirable physical properties in films or shaped articles formed from the polymer compositions. The polymer composition includes a finely divided polymer and a liquid phase comprising at least one high solvating plasticizer. The polymer composition includes at least one surfactant having a hydrophilic/lipophilic balance (HLB) value of 12 or more.

Abstract: Esters of cyclohexane polycarboxylic acids are used as plasticisers for polyvinyl chloride to enable products with comparable mechanical properties to be obtained using less polyvinyl chloride. Use of these esters also produces formulations with increased stability to ultra-violet light, improved low temperature properties, lower viscosity and improved processability as well as reduced smoke on burning. The esters of cyclohexane polycarboxylic acids may be used alone or in admixture with other plasticisers when the esters of cyclohexane polycarboxylic acids may act as viscosity depressants. Fast fusing plasticisers may also be included. The formulations are particularly useful in the production of a range of goods from semi-rigid to highly flexible materials and are particularly useful in the production of medical materials such as blood bags and tubing.

Abstract: A composition for stabilising halide-containing polymers, said composition comprising compounds represented by the general formula (I) wherein X, Y, and Z are each independently selected from the group consisting of hydrogen, alkyl, alkenyl, alkynyl, amino, and groups having the structure (II) wherein R1 and R2 are each independently selected from the group consisting of hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl, phenyl, phenylalkyl and aryl group, A is oxygen (O) or sulfur (S); and wherein the dashed double line represents an optional double bond.

Abstract: The invention relates to a composition containing at least one plasticizer and silicon dioxide particles having an average particle size of 150 nm or less. According to the invention, the proportion of silicon dioxide particles is from 10 to 80% by weight and the proportion of plasticizer is from 90 to 20% by weight, where the sum of the proportions of silicon dioxide particles and of the plasticizer is at least 80% by weight. The invention makes it possible to mix nanoparticles into any polymeric materials in a simple way.

Abstract: Plastisols are provided which are effective for providing a foamed composition having an improved color. The plastisol includes a dispersed phase and a liquid phase. The dispersed phase includes an organic polymer and the liquid phase includes a plasticizer for said polymer. The plasticizer utilized has a hydroxyl number of about 30 or greater, and an acidity of not less than about 0.1% as benzoic acid.

Abstract: Disclosed herein are effect pigment PVC plastisol, uses thereof, and proceses for producing effect pigment PVC plastisol. In one embodiment, an effect pigment PVC plastisol comprises: (A) at least one finely divided PVC homopolymer having particle sizes of from 0.04 to 40 ?m, and which as a dispersion in a plasticizer exhibits dilatancy, (B) at least one finely divided PVC homopolymer having particle sizes of from 1 to 400 ?m, and which as a dispersion in a plasticizer exhibits pseudoplasticity, (C) at least one plasticizer, and (D) at least one effect pigment.

Abstract: A bio-degradable PVC laminated fabric is provided. The biodegradable PVC laminated fabric comprises one or more bio-degradable laminating layers and one or more bio-degradable or regular scrims. The one or more bio-degradable laminating layers comprise plastic resin and bio-degradable additive. The one or more bio-degradable scrims comprise plastic resin and bio-degradable additive. Each of the one or more scrims is laminated on at least one of the bio-degradable laminating layer. Each bio-degradable laminating layer comprises bio-degradable additive by a first weight ratio.

Abstract: Lubricant compositions and processes for producing such lubricant compositions. More specifically, low viscosity lubricant compositions for the working surface of an extrusion die during the processing of plastics that require lubricants to render them processable, such as polyvinyl chloride, chlorinated polyvinyl chloride, polyvinylidene chloride and copolymers thereof. The lubricant composition may include up to about 70% by weight of at least one metal salt while maintaining a melt viscosity low enough to process on conventional finishing equipment such as prill towers or pastillating equipment.

Abstract: C9 to C11 alkyl benzoates are used as plasticisers for polyvinyl chloride in particular in combination with plasticisers such as di-2-ethyl hexyl phthalate, diisononyl phthalate, di-2-propyl heptyl phthalate, diisodecyl phthalate or di-2-ethyl hexyl terephthalate. The use of the C9 to C11 alkyl benzoates provides low viscosity low volatility plasticisers, which are fast fusing with lower hot bench gelation temperature and which can be used to reduce the staining problems associated with use of di-2-ethyl hexyl phthalate and diisononyl phthalate. The low viscosity of the C9 to C11 alkyl benzoates allows the formulation of solvent free flexible PVC formulations meeting stringent VOC limitations.

Abstract: Polyvinyl chloride (PVC) compositions including PVC; fibrous material; and a primary plasticizer component including a low extractable plasticizer are disclosed. The compositions can be useful in the production of flooring products that exhibit improved plasticizer hydrocarbon extraction resistance.

Abstract: A thermoplastic alloy is disclosed comprising poly(vinyl halide) and an olefin-based uncrosslinked elastomer having thermoplastic properties. The alloy can be made into a polymeric skin using slush molding techniques.

Abstract: Esters of cyclohexane polycarboxylic acids are used as plasticisers for polyvinyl chloride to enable products with comparable mechanical properties to be obtained using less polyvinyl chloride. Use of these esters also produces formulations with increased stability to ultra-violet light, improved low temperature properties, lower viscosity and improved processability as well as reduced smoke on burning. The esters of cyclohexane polycarboxylic acids may be used alone or in admixture with other plasticisers when the esters of cyclohexane polycarboxylic acids may act as viscosity depressants. Fast fusing plasticisers may also be included. The formulations are particularly useful in the production of a range of goods from semi-rigid to highly flexible materials and are particularly useful in the production of medical materials such as blood bags and tubing.

Abstract: Provided is a method of preparing a vinylchloride-based resin. The method includes adding to a vinylchloride-based latex an acid, preferably, 1-7 parts by weight of the acid based on 100 parts by weight of a solid of the vinylchloride-based latex; optionally, incubating the resultant mixture at a temperature of 30˜60° C. for 30 minutes to 3 hours; and drying the mixture. Therefore, it is possible to reduce the viscosity of a vinylchloride-based plastisol, thereby improving the processability of the plastisol.

Abstract: The invention relates to a material for use in contact with drinking water as well as having microbe-resistant properties, based on a vulcanized rubber mixture, comprising a rubber component as well as usual mixture ingredients, whereby according to the invention, the rubber component is butyl rubber or a halogenated rubber. This material is particularly used for the production of a hose that comprises a core and cover, particularly in connection with an embedded reinforcement support, whereby the material according to the invention is used at least for the core. In this connection, the core is preferably equipped with an additional inner layer of non-cross-linked polyethylene, whereby this inner layer is in direct contact with the drinking water.

Abstract: Provided are a plasticizer composition including a hydroxypivalyl hydroxypivalate ester and a neopentylglycol ester, and a method of preparing the plasticizer composition. The plasticizer composition provides a polyvinyl chloride resin having excellent properties of heat loss, migration resistance and plasticization efficiency, and tensile strength, elongation, etc.