Conjugated Diene Hydrocarbon Monomer Patents (Class 524/571)
  • Patent number: 7335411
    Abstract: Vulcanizable elastomeric compositions and vulcanizates are prepared by employing a strong acid. The strong acid is believed to enhance the reaction between a silica particle and a silica-reactive compound.
    Type: Grant
    Filed: October 26, 2005
    Date of Patent: February 26, 2008
    Assignee: Bridgestone Corporation
    Inventors: Chenchy Jeffrey Lin, William L. Hergenrother
  • Publication number: 20080039562
    Abstract: The disclosure herein relates to organofunctional silanes and mixtures of organofunctional silanes possessing mercaptan and hydrocarbyl and/or heterocarbyl functionality. These silanes reduce or eliminate the generation of volatile organic compounds (VOC's) during use, aid in the processing of filled elastomeric materials and enhance the end-use properties of the filled elastomer. The present disclosure relates to a rubber composition and article comprising these silanes.
    Type: Application
    Filed: August 14, 2006
    Publication date: February 14, 2008
    Applicant: General Electric Company
    Inventors: Antonio Chaves, Eric R. Pohl, Christopher M. Hartshorn
  • Publication number: 20080033103
    Abstract: A rubber composition for a tire having greatly shortened vulcanization time, good silica dispersibility and, after vulcanization, superior braking capability, abrasion resistance and low rolling resistance, comprising (A) 100 parts by weight of a conjugated diene-based rubber, (B) 90 to 150 parts by weight of a reinforcing filler containing silica, (C) 0 to 40 parts by weight of an oil, (D) 4 to 20% by weight, based upon the weight of the silica, a silane coupling agent having the formula (I): Y3Si—CnH2nA ??(I) wherein Y indicates a C1 to C25 alkyl or alkoxyl group or a chloro group, the three Y's may be the same or different, n is an integer of 1 to 6, A is a mercapto group or SmZ group, where Z is the group: and m is an integer of 1 to 6) (E) sulfur, and (F) 0.05 to 5 parts by weight of a thiuram disulfide-based vulcanization accelerator having the formula (II): wherein R5, R6, R7 and R8 are independently hydrocarbon groups having 2 to 18 carbon atoms, is provided.
    Type: Application
    Filed: September 7, 2005
    Publication date: February 7, 2008
    Applicant: THE YOKOHAMA RUBBER CO., LTD.
    Inventors: Yoshihiro Kameda, Naoya Amino
  • Publication number: 20080027162
    Abstract: This invention relates to the preparation of silica-rich rubber compositions which contain silica reinforcement and silica coupler together with a specified combination of zinc oxide and long chain (fatty) carboxylic acid such as stearic acid. The silica, silica coupling agent, zinc oxide and stearic acid are combined in a manner to form a complex network. The silica is a precipitated silica in a form of silica aggregates which contain hydroxyl groups on its surface. A preferred silica coupling agent is a bis (3-trialkoxysilylalkyl) polysulfide which contains an average of from 2 to about 4, preferably from 2 to about 2.6, connecting sulfur atoms in its polysulfidic bridge. The invention further relates to tires having a component thereof such as, for example, a tread.
    Type: Application
    Filed: July 25, 2006
    Publication date: January 31, 2008
    Inventors: Kuo-Chih Hua, Shingo Futamura, Wen-Liang Hsu, Paul Harry Sandstrom
  • Patent number: 7321005
    Abstract: A method of making an encapsulant composition. The method includes: providing a first quantity of resin material of epoxy or cyanate ester resins; adding to the first quantity of resin material a second quantity of flexibilizing agent; adding to the first quantity of resin material a third quantity of filler material; blending the resin material. After adding the flexibilizing agent, adding the filler material, and blending the resin material, applying the composition to a gap between a substrate and a semiconductor chip. After applying the composition to the gap, pregelling the composition. After pregelling the composition, substantially curing the composition.
    Type: Grant
    Filed: March 19, 2007
    Date of Patent: January 22, 2008
    Assignee: International Business Machines Corporation
    Inventor: Konstantinos I. Papathomas
  • Publication number: 20080015295
    Abstract: An anhydrous gel composition is provided for holding and dispersing into the surrounding air space, in a time controlled manner, a volatile composition contained within the gel. The gel composition is formed by crosslinking a polymer solution that contains the volatile composition. In one embodiment the gel composition comprises about 8% to about 25% by weight of an anhydride functionalized polymer; about 0.3% to about 10% by weight of total crosslinker reagent; and about 50% to about 90% by weight of a functional volatile component.
    Type: Application
    Filed: July 11, 2006
    Publication date: January 17, 2008
    Inventors: Virgil AG Williams, Jamie L. Arbolino
  • Patent number: 7319123
    Abstract: An initiator is presented for anionically polymerizing monomers, to provide a functional head group on the polymer. A polymer having a functional head group derived from a sulfur containing anionic initiator, and optionally as additional functional group resulting from the use of a functional terminating reagent, coupling agent or linking agent is also provided. A method is presented for anionically polymerizing monomers comprising the step of polymerizing the monomers with a sulfur containing anionic initiator to provide a functional head group on the polymer. An elastomeric compound, comprising a functional polymer and filler is also described. Also provided is a tire having decreased rolling resistance resulting from a tire component containing a vulcanizable elastomeric compound.
    Type: Grant
    Filed: December 2, 2006
    Date of Patent: January 15, 2008
    Assignee: Bridgestone Corporation
    Inventors: Terrence E. Hogan, William Hergenrother, Yuan-Yong Yan, David Lawson
  • Patent number: 7316842
    Abstract: High-viscosity elastomeric adhesive compositions including a high softening point tackifier resin in combination with a base polymer can be used to create elastomeric composite laminates having effective adhesion and elastic properties. The elastomeric adhesive compositions suitably have a viscosity between about 100,000 and about 500,000 cps at between about 300 degrees Fahrenheit (149 degrees Celsius) and about 350 degrees Fahrenheit (177 degrees Celsius). Facing layers, such as nonwoven webs, films, elastic strands, fastening material, absorbent material, and the like, can be laminated to one or both surfaces of the elastomeric compositions to form elastomeric composite laminates. A method of making such compositions and laminates involves forming the compositions into elastomeric adhesive films and/or strands.
    Type: Grant
    Filed: November 4, 2003
    Date of Patent: January 8, 2008
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Peiguang Zhou, Gregory K. Hall
  • Patent number: 7314894
    Abstract: The present invention provides a rubber composition which can sufficiently improve performance on ice and snow and wet gripping properties, and a pneumatic tire using the same. The rubber composition comprises, based on 100 parts by weight of diene rubber (A), 2 to 20 parts by weight of short fiber (B) having an average fiber diameter of 10 to 100 ?m and average fiber length of 0.01 to 4 mm, 1 to 10 parts by weight of particles (C) having a Moh's hardness of at least 5 and average particle size of at most 500 ?m, and 1 to 15 parts by weight of starch/plasticizer composite material (D), and the pneumatic tire has a tread made of the rubber composition.
    Type: Grant
    Filed: July 24, 2003
    Date of Patent: January 1, 2008
    Assignee: Sumitomo Rubber Industries, Ltd.
    Inventors: Takuya Horiguchi, Akira Minakoshi
  • Publication number: 20070299190
    Abstract: Provided for herein is a process to produce an essentially homogeneous single liquid phase hydrocarbon-rubber cement from a polymer slurry comprising a hydrocarbon-rubber, a diluent, and unreacted monomer(s), the process comprising: (a) contacting the polymer slurry with a hydrocarbon solvent; and (b) removing the diluent in amounts not sufficiently more than is necessary to produce the essentially homogeneous single liquid phase hydrocarbon-rubber cement wherein the mass fraction of monomer(s) in the hydrocarbon-rubber cement, based on the total amount of hydrocarbon-rubber present in the hydrocarbon-rubber cement, is less than the mass fraction of monomer(s) in the hydrocarbon-rubber slurry, based on the total amount of hydrocarbon-rubber present in the hydrocarbon-rubber slurry, wherein the diluent comprises a hydrofluorocarbon.
    Type: Application
    Filed: June 23, 2006
    Publication date: December 27, 2007
    Inventors: Michael F. McDonald, Scott T. Milner, D. Shaffer Timothy, N. Webb Robert, D. Hembree Richard
  • Patent number: 7312271
    Abstract: Methods are provided for making a solution masterbatch containing a diene elastomer in an organic solvent and a reinforcing silica filler dispersed therein, comprising the steps of (a) mixing a precipitated silica having an average particle size substantially equivalent to an average particle size of a powdered silica, with a diene elastomer in a first organic solvent; and (b) desolventizing the mixture to form a solution masterbatch preparation. The use of such desolventized solution masterbatches in vulcanizable rubber compounds results in excellent processing characteristics with improved dispersion of fillers, including polymeric nanoparticles. The compounds also demonstrate improved properties, including reduced hysteresis.
    Type: Grant
    Filed: December 29, 2005
    Date of Patent: December 25, 2007
    Assignee: Bridgestone Corporation
    Inventors: Zhong-Ren Chen, Sunji Araki, William M. Cole, William Hergenrother, Sandra Warren
  • Publication number: 20070293610
    Abstract: This invention relates to a silica reinforced rubber composition containing an ionic compound and article having a component thereof. The invention particularly relates to an article such as a rubber tire having a component of such rubber composition. Said ionic compound is composed of a combination of an organic cation moiety and an organic or inorganic anion moiety. Said ionic compound is desirably an ionically conductive ionic compound. The invention particularly relates to improvement of one or more physical properties of a rubber composition by an inclusion of such ionic compound and/or providing a path of least electrical resistance for a electrically resistive component of an article such as a tire by an inclusion in the rubber composition of said component of an ionically conductive ionic compound composed of a combination of an organic cation moiety and an organic or inorganic anion moiety.
    Type: Application
    Filed: June 19, 2006
    Publication date: December 20, 2007
    Inventors: Adel Farhan Halasa, Wen-Liang Hsu, Aaron Scott Puhala
  • Patent number: 7291663
    Abstract: A conductive roller or a conductive belt is composed of a conductive elastomer composition including a polymer composition having a plurality of carbon-to-carbon double bonds and containing not less than 40 mol % of ethylene oxide; an organometallic salt containing a fluoro group or/and a sulfonyl group; and an elastomer having a plurality of carbon-to-carbon double bonds.
    Type: Grant
    Filed: June 16, 2003
    Date of Patent: November 6, 2007
    Assignee: Sumitomo Rubber Industries, Ltd.
    Inventors: Takayuki Hattori, Tetsuo Mizoguchi
  • Patent number: 7288323
    Abstract: The rubber compositions described herein have been found to have an exceptionally long life as a spring-biased actuator diaphragm material that maintains its position compressed, e.g., bolted, between opposed flanges, while maintaining excellent compressibility, low temperature flexibility, hydrocarbon resistance, abrasion resistance and mechanical strength. The compositions include a copolymer rubber component; a plasticizer for the copolymer rubber; a vulcanizing agent for the copolymer rubber; a silica filler; and a coupling agent, such as a silane coupling agent, capable of coupling the silica filler to the copolymer rubber.
    Type: Grant
    Filed: November 13, 2003
    Date of Patent: October 30, 2007
    Assignee: Fisher Controls International, LLC
    Inventor: Ted D. Grabau
  • Patent number: 7285584
    Abstract: The invention relates to a tire having at least one component comprised of a rubber composition which contains a hydrophobated, pre-silanized silica, namely a pre-silanized silica hydrophobated with an epoxidized soybean oil and/or epoxidized rubber tree seed oil in situ within said rubber composition. Such tire component may be, for example although not limited to, a tire tread, sidewall and/or sidewall insert.
    Type: Grant
    Filed: December 16, 2005
    Date of Patent: October 23, 2007
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Wen-Liang Hsu, Shingo Futamura, Kuo-Chih Hua, Kenneth Allen Bates, Ping Zhang
  • Publication number: 20070244240
    Abstract: An adhesive composition containing an aqueous butadiene polymer latex, and an acid scavenging compound, wherein the adhesive comprises essentially no phenolic resin or methylene donor compounds. The aqueous covercoat adhesive is particularly well suited for rubber to metal bonding applications. The adhesive have shown excellent adhesion to a number of compounds but perform best on natural rubber compounds and prefer higher cure temperatures to lower cure temperatures. Further, the formulation has been developed without the need for a methylene donor such as 2-polyoxymethylene dimethylether (gamma POM).
    Type: Application
    Filed: April 13, 2007
    Publication date: October 18, 2007
    Inventor: Douglas H. Mowrey
  • Patent number: 7273906
    Abstract: A dip-forming latex obtained by copolymerization of (a) 50-89.5 weight parts of a conjugated diene monomer, (b) 10-40 weight parts of an ethylenically unsaturated nitrile monomer, (c) 0.5-10 weight parts of an ethylenically unsaturated acid monomer and (d) 0-20 weight parts of other copolymerizable ethylenically unsaturated monomer (the total of these monomers is 100 weight parts), wherein the copolymerization is initiated with a monomer mixture comprising at least 80 wt. % of (a), at least 50 wt. % of (b), 10-90 wt. % of (c) and least 80 wt. % of (d), and thereafter, the remainders of monomers are added to a polymerization system to continue copolymerization. This latex gives a dip-formed article exhibiting good softness of touch, high tensile strength and good retention of close fittingness.
    Type: Grant
    Filed: February 27, 2003
    Date of Patent: September 25, 2007
    Assignee: Zeon Corproation
    Inventors: Hisanori Ota, Shunjin Aihara, Kazumi Kodama
  • Patent number: 7256233
    Abstract: A rubber composition usable for the manufacture of tires, based on at least one diene elastomer, one reinforcing inorganic filler and a coupling agent providing the bond between the inorganic filler and the elastomer. The inorganic filler comprises a synthetic aluminosilicate of the formula: MxSiAlyOa(OH)b, (H2O)c??(I) in which: M is a cation selected from of K+, Na+, Ca++ and mixtures of these cations; x>0; y>0; a?0; b?0, c?0 and a+b>0, and having the following characteristics: (a) a BET specific surface area of between 20 and 300 m2/g; (b) an average particle size by mass (dw) of between 20 and 400 nm; and (c) an ultrasound disagglomeration rate (?) greater than 5×10?4 ?m?1/min.
    Type: Grant
    Filed: June 20, 2005
    Date of Patent: August 14, 2007
    Assignee: Michelin Recherche et Technique S.A.
    Inventors: Laure Simonot, Anne Veyland, Arnaud Lapra, Emmanuel Custodero
  • Patent number: 7256229
    Abstract: The present invention discloses a paper coating latex containing copolymeric ionic monomer, a paper coating composition containing thereof, and a paper coated with the composition. More specifically, the present invention provides a styrene-butadiene latex for paper coating which contains sodium methallyl sulfonate, an ionic monomer copolymerizing with monomers used in latex manufacturing, as a monomer for emulsion polymerization, and has excellent stability and fluidity, a paper coating composition containing thereof, and a paper coated with the composition.
    Type: Grant
    Filed: October 8, 2002
    Date of Patent: August 14, 2007
    Assignee: LG Chem. Ltd.
    Inventors: Seung-Uk Yeu, Ho-Yeul Choi, Wan-Sik Cha, Seung-Hun Yang, Chang-Sun Han
  • Patent number: 7247669
    Abstract: This invention relates to a rubber composition prepared with reinforcement comprised of a combination of precipitated silica aggregates and pelletized rubber reinforcing carbon black composites of carbon black and organic binder of a controlled hardness and to a tire with at least one component comprised of and derived from such rubber composition in which said carbon black pellet composites are disintegrated (fragmented) in situ within said rubber composition in the presence of particulate precipitated silica and silica coupling agent. In one aspect the invention relates to a tire having a component of a rubber composition comprised of at least one conjugated diene-based elastomer and reinforcing filler comprised of a combination of precipitated silica, silica coupling agent and fragmented rubber reinforcing carbon black pellet composites, said pellets having a controlled hardness value.
    Type: Grant
    Filed: August 11, 2005
    Date of Patent: July 24, 2007
    Assignee: The Goodyear Tire & Rubber Company
    Inventor: Paul Harry Sandstrom
  • Patent number: 7241824
    Abstract: A sulphur-vulcanizable rubber composition usable for the manufacture of tires, based on at least: (A)—one diene elastomer selected from the group consisting of polybutadienes, natural rubber, synthetic polyisoprenes, butadiene copolymers, isoprene copolymers and mixtures of these elastomers (component A); (B)—a reinforcing white filler (component B); (C)—a coupling agent (white filler/diene elastomer) bearing at least one activated double ethylene bond (component C), with which there is associated: (D)—between 0.05 and 1 phr (parts by weight per hundred of elastomer) of a heat-triggered radical initiator (component D). The coupling agent is in particular an alkoxysilane of the family of alkoxy(C1–C4)-silylpropyls, in particular a trialkoxy(C1–C4)-silylpropyl methacrylate, in particular trimethoxy-silylpropyl methacrylate. Process for preparing such a rubber composition. Tire or semi-finished product, in particular tread, for a tire comprising a rubber composition according to the invention.
    Type: Grant
    Filed: June 24, 2002
    Date of Patent: July 10, 2007
    Assignee: Michelin Recherche et Technique S.A.
    Inventors: Jean-Luc Mangeret, Jean-Claude Tardivat
  • Patent number: 7235600
    Abstract: The present invention concerns a waterborne copolymer dispersion comprising at least one alkenyl functional dendritic polymer being copolymerized to the polymer backbone of at least one homo or copolymer obtainable by polymerization, such as emulsion polymerization, in an aqueous medium of at least one at least one polymerizable allyl, vinyl, maleic or diene monomer. The dendritic polymer is built up from a dendritic core polymer and at least one alkenyl functional compound bonded to the core polymer. In a further aspect the present invention concerns the use of said copolymer dispersion.
    Type: Grant
    Filed: August 13, 2003
    Date of Patent: June 26, 2007
    Assignee: Celanese Emulsion Norden AB
    Inventors: Jan-Erik Jonsson, Ola Karlsson
  • Patent number: 7222650
    Abstract: This invention discloses a process for synthesizing an amine functionalized monomer that comprises (1) reacting a secondary amine with a 2,3-dihalopropene to produce a vinyl halide containing secondary amine having a structural formula selected from the group consisting of wherein R and R? can be the same or different and represent allyl, alkoxyl or alkyl groups containing from 1 to about 10 carbon atoms, and wherein X represents a halogen atom, and wherein m represents an integer from 4 to about 10, and wherein X represents a halogen atom; and (2) reacting the vinyl halide containing secondary amine with a vinyl magnesium halide to produce the monomer having a structural wherein R and R? can be the same or different and represent alkyl, allyl or alkoxyl groups containing from 1 to about 10 carbon atoms, and wherein m represents an integer from about 4 to about 10.
    Type: Grant
    Filed: May 5, 2003
    Date of Patent: May 29, 2007
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Adel Farhan Halasa, Wen-Liang Hsu, Kenneth Allen Bates, Shingo Futamura
  • Patent number: 7222380
    Abstract: SEEPS gel and gel foam molded shape articles for use in medical and sport health care, such use include therapeutic hand exercising grips, dental floss, crutch cushions, cervical pillows, bed wedge pillows, leg rest, cushions, mattress, bed pads, elbow padding, dermal pads, wheelchair cushions, helmet liner, cold and hot packs, exercise weight belts, traction pads and belts, cushions for splints, slings, and braces, cushions for the hand, wrist, finger, fore, knee, leg, clavicle, shoulder, foot, ankle, back, rib, soles for orthopedic shoes, and the like.
    Type: Grant
    Filed: April 21, 2003
    Date of Patent: May 29, 2007
    Assignee: Applied Elastomerics, Inc.
    Inventor: John Y. Chen
  • Patent number: 7211619
    Abstract: A stabilized high-vinyl polybutadiene composition comprising a high-vinyl polybutadiene, and an antioxidant defined by the formula where each R1 and R2, which may be the same or different, are mono-valent organic groups, or where each R1, which may be the same or different, is a mono-valent organic group and the two R2 groups join to form a divalent organic group.
    Type: Grant
    Filed: August 7, 2001
    Date of Patent: May 1, 2007
    Assignee: Bridgestone Corporation
    Inventors: Luo Steven, Koji Masaki, Tatsuro Hamada
  • Patent number: 7202295
    Abstract: A rubber composition usable for the manufacture of tires, based on at least one diene elastomer, a reinforcing inorganic filler and a coupling agent providing the bond between the inorganic filler and the elastomer, wherein said inorganic filler comprises a silicon carbide having the following characteristics: (a) a BET specific surface area of between 20 and 200 m2/g; (b) an average particle size (by mass), dW, of between 10 and 350 nm. Tires or semi-finished products for tires such as treads comprising said rubber composition.
    Type: Grant
    Filed: July 2, 2003
    Date of Patent: April 10, 2007
    Assignee: Michelin Recherche et Technique S.A.
    Inventors: Laure Simonot, Thierry Chartier, Emmanuel Custodero
  • Patent number: 7199175
    Abstract: A tire tread comprising a rubber composition based on (phr: parts by weight per hundred parts of elastomer): (i) a diene elastomer; (ii) more than 50 phr of an inorganic filler as reinforcing filler; (iii) between 2 and 15 phr of an (inorganic filler/diene elastomer) coupling agent; (iv) between 1 and 10 phr of a methylene acceptor, and (v) between 0.5 and 5 phr of a methylene donor. This tread has, after mechanical running-in of the tire for which it is intended (“auto-accommodation”), a rigidity gradient which increases radially from the surface towards the inside of the tread. Use of such a tread for the manufacturing or recapping of tires. Tires comprising a tread according to the invention, in particular of the snow or ice type (“winter” tires).
    Type: Grant
    Filed: January 28, 2003
    Date of Patent: April 3, 2007
    Assignee: Michelin Recherche et Technique S.A.
    Inventor: Didier Vasseur
  • Patent number: 7192997
    Abstract: A composition for use in making an encapsulant usable in the encapsulation of a semiconductor chip assembled to a substrate with C4 solder interconnections therebetween, which in turn may form part of an electronic package. The composition comprises a resin, a flexibilizing agent and a filler material.
    Type: Grant
    Filed: February 7, 2001
    Date of Patent: March 20, 2007
    Assignee: International Business Machines Corporation
    Inventor: Konstantinos I. Papathomas
  • Patent number: 7186776
    Abstract: The present invention relates to a sulfur-cross-linkable elastomeric composition that is useful for the manufacture of tires. This elastomeric composition is based on at least one isoprene elastomer (in particular natural rubber), a reinforcing inorganic filler (in particular, silica), and an (inorganic filler/isoprene elastomer) coupling agent. The coupling agent is a multifunctional polyorganosiloxane (POS), which comprises functions denoted as “Y” and “X”, wherein the Y function is at least one hydroxyl or hydrolyzable function grafted to the silicon atoms of the coupling agent and the X function is a group bearing at least one activated ethylene double bond and is grafted to the silicon atoms of the coupling agent. This POS is, in particular, a POS having an imide, acid or ester function, the ethylene double bond of which is activated by at least one adjacent carbonyl group (—C?O).
    Type: Grant
    Filed: September 22, 2004
    Date of Patent: March 6, 2007
    Assignee: Michelin Recherche et Technique S.A.
    Inventors: Jean-Claude Tardivat, Salvatore Pagano, Christel Thonier, Nathalie Guennouni
  • Patent number: 7176260
    Abstract: The invention is the manipulation of the zinc oxide content and sulfur content of nitrile butadiene rubbers and selected vulcanization conditions that can be achieved economically with common production facilities. The manipulation of these components affects the relaxation property of gloves formed by this material. Produced are gloves that have a relaxation property, higher than 50%, and a low modulus (approximately 3 Mpa). The glove maintains decent ultimate tensile strength (>20 Mpa) and elongation (>500%). The glove is produced by a vulcanization process, which lasts from 5 to 60 minutes at temperatures ranging from 300° F. to 400° F. The tensile strength and elongation are well above the ASTM requirements for medical gloves. The current ASTM requirements are ASTM D412-92. Thanks to sufficient vulcanization, the films produced provide satisfactory protection from viral penetration. The tearing strength is also better because of the lower modulus.
    Type: Grant
    Filed: January 13, 2004
    Date of Patent: February 13, 2007
    Assignee: Microflex Corporation
    Inventor: Jian Tao
  • Patent number: 7172651
    Abstract: Pigment suitable for use in coating compositions for inkjet recording media. Surfaces of an inorganic particulate are interacted with a water-soluble polyvalent metal salt in an aqueous medium. The treated particle surfaces have a significant cationic surface charge imparted to them. The salt is a salt of a metal of Group II or Group III of the Periodic Table. Inkjet recording media treated with a coating composition containing the above pigment provide high density, fast-drying, and non-feathering ink images with suitable water fastness, while the coating compositions also offer cost advantages and improved rheology at higher pigment levels over coatings based on silica pigments.
    Type: Grant
    Filed: June 17, 2003
    Date of Patent: February 6, 2007
    Assignee: J.M. Huber Corporation
    Inventors: Ching-Yih Chen, Ricky L. Giddens, Richard D. Carter
  • Patent number: 7159259
    Abstract: Novel gelatinous compositions and articles are formed from an intimate melt blend admixture of one or more of a selected block SEEPS copolymers in combination with one or more polymers of poly(styrene-butadiene-styrene), poly(styrene-butadiene)n, poly(styrene-isoprene-styrene), poly(styrene-isoprene)n, poly(styrene-ethylene-propylene), poly(styrene-ethylene-propylene-styrene)n, poly(styrene-ethylene-butylene-styrene)n, poly(styrene-ethylene-butylene), poly(styrene-ethylene-propylene)n, poly(styrene-ethylene-butylene)n, polystyrene, polybutylene, poly(ethylene-propylene), poly(ethylene-butylene), polypropylene, and polyethylene, and a plasticizing oil.
    Type: Grant
    Filed: December 31, 2002
    Date of Patent: January 9, 2007
    Assignee: Applied Elastomerics, Inc.
    Inventor: John Y. Chen
  • Patent number: 7153893
    Abstract: It is an object of the present invention to provide an ink composition with excellent gas resistance, fixability, and bronzing resistance, as well as a recording method and recorded matter in which this ink composition is used. The present invention achieves this object by means of an ink composition in which a pigment is dispersed in a solvent, and a copolymer, which contains structural units originating in an aromatic compound monomer and structural units originating in a C5 or higher diene compound and/or structural units originating in a non-diene compound, is included, wherein the copolymer has a sulfonic acid group, and the proportion of structural units originating in the aromatic compound monomer is 30 to 60 wt % with respect to the weight of the copolymer (100 wt %). In the present invention, styrene, ?-methylstyrene, o-methylstyrene, p-methylstyrene, m-methylstyrene, chlorostyrene, or vinyl benzoate is selected as the above-mentioned aromatic compound monomer.
    Type: Grant
    Filed: October 17, 2003
    Date of Patent: December 26, 2006
    Assignee: Seiko Epson Corporation
    Inventors: Hiroaki Segawa, Tsuyoshi Sano
  • Patent number: 7153919
    Abstract: An initiator is presented for anionically polymerizing monomers, to provide a functional head group on the polymer. A polymer having a functional head group derived from a sulfur containing anionic initiator, and optionally as additional functional group resulting from the use of a functional terminating reagent, coupling agent or linking agent is also provided. A method is presented for anionically polymerizing monomers comprising the step of polymerizing the monomers with a sulfur containing anionic initiator to provide a functional head group on the polymer. An elastomeric compound, comprising a functional polymer and filler is also described. Also provided is a tire having decreased rolling resistance resulting from a tire component containing a vulcanizable elastomeric compound.
    Type: Grant
    Filed: October 30, 2003
    Date of Patent: December 26, 2006
    Assignee: Bridgestone Corporation
    Inventors: Terrence E. Hogan, William Hergenrother, Yuan-Yong Yan, David Lawson
  • Patent number: 7129289
    Abstract: A two-part sizing composition that imparts improved resistance to hydrolysis of reinforced composites including a size composition and a binder composition is provided. The size composition may include one or more coupling agents, one or more lubricants, and at least one wetting agent. The binder composition may include a copolymer formed from maleic anhydride and at least one other copolymerizable monomer, at least one crosslinking agent, and a surfactant or mixture of surfactants. In at least one exemplary embodiment, the maleic anhydride copolymer is a maleic anhydride-butadiene copolymer partial ammonium salt. The size composition may be applied to a reinforcing fiber material before the binder size material is applied. The two-part size composition may be applied to a reinforcing fiber material to form a reinforcing fiber product which may then be densified or compacted to form a densified reinforcing fiber product, such as a pellet.
    Type: Grant
    Filed: March 19, 2004
    Date of Patent: October 31, 2006
    Assignee: Owens Corning Composites S.P.R.L.
    Inventors: Willy H. Piret, Nadia Masson
  • Patent number: 7098268
    Abstract: This invention relates to a resin composition useful as a vibration-damping agent and the like. The resin composition is formulated by adding 1 wt % or more of styrenated phenol obtained by the reaction of a phenol with styrene to a polycyclic aromatic oligomer obtained by condensing a polycyclic aromatic compound containing 2 to 3 rings and formaldehyde. The polycyclic aromatic oligomer is obtained by the reaction of a polycyclic aromatic compound with formaldehyde and, if necessary, further with a phenol in the presence of an acid catalyst and has a number average molecular weight of 300–1000. The styrenated phenol is obtained by the reaction of 1 mole of a phenol with 1–2.5 moles of styrene in the presence of an acid catalyst.
    Type: Grant
    Filed: August 1, 2002
    Date of Patent: August 29, 2006
    Assignee: Nippon Steel Chemical Co., Ltd.
    Inventors: Toshihide Senzaki, Takahiro Imamura
  • Patent number: 7094822
    Abstract: The present invention relates to thermally conductive, elastomeric pads. The pads can be made by injection-molding a thermally conductive composition comprising about 30 to 60% by volume of an elastomer polymer matrix and about 25 to 60% by volume of a thermally conductive filler material. The resultant pads have heat transfer properties and can be used as a thermal interface to protect heat-generating electronic devices.
    Type: Grant
    Filed: June 17, 2004
    Date of Patent: August 22, 2006
    Assignee: Cool Shield, Inc.
    Inventors: E. Mikhail Sagal, Kevin A. McCullough, James D. Miller
  • Patent number: 7084201
    Abstract: A composition of matter and a solvent system for use in providing a water resistant coating to basement walls is disclosed. The solvent system comprises a chlorinated solvent blend. The solvent system and coating composition have no flash point, are non-flammable and provide an improved consistent coating when applied to walls.
    Type: Grant
    Filed: November 14, 2003
    Date of Patent: August 1, 2006
    Assignee: Wall-Guard Corporation of Ohio
    Inventors: Michael Garfield, Paul E. Marshall, Jr.
  • Patent number: 7081494
    Abstract: The present invention has for its object to provide a curable composition which, despite its low viscosity, gives a cured product with a high gel fraction, low residual tack, low modulus, high elongation, and good flexibility. The present invention relates to a curable composition comprising the following two components: (A) a vinyl polymer having at least one crosslinking silyl group on the average per molecule: and (B) a photocurable substance, (C) an air oxidation-curable substance, (D) a high molecular plasticizer, (E) a reactive plasticizer or (F) a compound having one silanol group in its molecule and/or a compound capable of reacting with moisture to give a compound having one silanol group in the molecule.
    Type: Grant
    Filed: August 7, 2003
    Date of Patent: July 25, 2006
    Assignee: Kaneka Corporation
    Inventors: Masayuki Fujita, Nobuhiro Hasegawa, Yoshiki Nakagawa
  • Patent number: 7071251
    Abstract: The invention relates to a tire having at least one component (e.g. tread) of a rubber composition comprised of a styrene/butadiene elastomer composite comprised of a styrene/butadiene elastomer and a functionalized styrene/butadiene elastomer containing an internal silicon atom therein as a part of the elastomer, and at least one pendent silanol group and/or siloxy group from said silicon atom. Said elastomer composite is comprised of a significant polymodal (e.g. bimodal) molecular weight distribution between said styrene/butadiene elastomer and said functionalized styrene/butadiene elastomer. Said rubber composition contains synthetic, precipitated silica aggregates having hydroxyl groups on their surface which may be pre-treated (hydrophobated) to reduce hydroxyl groups contained on their surface prior to blending with said styrene/butadiene composite. Said rubber composition may contain a dispersion therein of a silica/plasticizer composite.
    Type: Grant
    Filed: July 28, 2003
    Date of Patent: July 4, 2006
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Georges Marcel Victor Thielen, Marc Weydert
  • Patent number: 7070705
    Abstract: Insulation for a rocket motor is provided, as is a method for insulating a rocket motor. The insulation includes a cured elastomer and vapor-grown carbon fibers dispersed in the cured elastomer. The cured elastomer is preferably formed from a precursor composition comprising an EPDM terpolymer. Generally, the vapor-grown carbon fibers have an internal graphitized tube surrounded by a sheath of vapor-deposited amorphous carbon.
    Type: Grant
    Filed: February 5, 2004
    Date of Patent: July 4, 2006
    Assignee: Alliant Techsystems Inc.
    Inventors: Albert R. Harvey, John W. Ellertson
  • Patent number: 7067577
    Abstract: The present invention relates to a resin composition comprising a resin and apatite, wherein referring to the particulate form of said apatite present in the resin composition thus obtained, the apatite is present in a particulate form having an average diameter or average thickness (d) of not greater than 100 nm and an average aspect ratio (L/D) of not smaller than 5 as defined by the ratio of the average length (L) to said average diameter or average thickness (d).
    Type: Grant
    Filed: October 4, 2001
    Date of Patent: June 27, 2006
    Assignee: Asahi Kasei Kabushiki Kaisha
    Inventors: Masaaki Aramaki, Kenya Sonobe
  • Patent number: 7060748
    Abstract: A catalyst paste composition for making electrodes has a uniform dispersion condition of a carbon black supporting a hydrogen reduction catalyst and is excellent in storage stability. The catalyst paste composition comprises a carbon black supporting a hydrogen reduction catalyst, an electrolyte, a water-soluble sulfonated polymer and a solvent.
    Type: Grant
    Filed: May 20, 2003
    Date of Patent: June 13, 2006
    Assignees: JSR Corporation, Honda Motor Co.,Ltd.
    Inventors: Makoto Higami, Keiichi Bessho
  • Patent number: 7041746
    Abstract: The invention pertains to an accelerator system, such as an accelerator system for synthetic polyisoprene latex. The accelerator system comprises dithiocarbamate and thiourea and can produce synthetic polyisoprene films having a tensile strength of about 3,000 psi to about 5,000 psi at low curing temperatures. The invention also pertains to a method for curing synthetic polyisoprene latex.
    Type: Grant
    Filed: December 22, 2003
    Date of Patent: May 9, 2006
    Assignee: R.T. Vanderbilt Company, Inc.
    Inventor: Robert Thomas Dzikowicz
  • Patent number: 7041379
    Abstract: Elastomer coating composition are disclosed which cure at room temperature, and form highly flex-resistant, durable, and flexible protective layer on elastomers and provides excellent adhesion to elastomeric and metal substrates. The coating is a solvent solution of (A) a carboxylated hydrogenated acrylonitrile-butadiene copolymer, and (B) a room temperature isocyanate curing component. Coated bonded elastomer-metal composites are obtained without an additional application of heat to cure the coating.
    Type: Grant
    Filed: September 4, 2003
    Date of Patent: May 9, 2006
    Assignee: Lord Corporation
    Inventors: James R. Halladay, Frank J. Krakowski
  • Patent number: 7037590
    Abstract: The present invention relates to a water vapor-permeable coating composite containing one or more flexible substrates, which are coated on one or both sides with one or more identical or different coating compositions, provided that at least one coating composition contains, as binder, a silica sol-modified aqueous polymer dispersion prepared from unsaturated monomers.
    Type: Grant
    Filed: November 1, 2002
    Date of Patent: May 2, 2006
    Assignee: Bayer Aktiengesellschaft
    Inventors: Thorsten Rische, Tillmann Hassel, Jürgen Meixner, Detlef-Ingo Schütze
  • Patent number: 6998452
    Abstract: This invention relates to a process for producing a free radical control agent of the structural formula: wherein Z is selected from the group consisting of wherein R1 is an alkyl group of 1 to 4 carbon atoms, cyclohexyl or phenyl; wherein R2 is an alkoxy group of 1 to 8 carbon atoms or a cycloalkoxy group of 5 to 8 carbon atoms; wherein Alk is a divalent hydrocarbon of 1 to 18 carbon atoms; and wherein Y represents a functional group that is capable of activating a vinylic carbon toward free radical addition; said process comprising the steps of (1) reacting a mercaptosilane of the structural formula: Z-Alk-SH with carbon disulfide in the presence of a phase transfer catalyst and an alkali metal hydroxide to produce a trithiocarbonate salt; and (2) reacting the trithiocarbonate salt with a halogen containing compound of the structural formula X-Y to produce the free radical control agent, wherein X represents a halogen atom.
    Type: Grant
    Filed: January 14, 2005
    Date of Patent: February 14, 2006
    Assignee: The Goodyear Tire & Rubber Company
    Inventor: Dane Kenton Parker
  • Patent number: 6984687
    Abstract: The invention is directed to an oil extended rubber and composition comprising: a solution-polymerized elastomer derived from at least one conjugated diene monomer and at least one vinyl aromatic monomer, the elastomer coupled with at least one metal selected from the group consisting of silicon and tin; and from about 5 to about 70 parts by weight, per 100 parts by weight of elastomer (phr), of a process oil having a glass transition temperature of from about ?80° C. to about ?40° C., a polycyclic aromatic content of less than 3 percent by weight as determined by the IP346 method, and an aromatic content of less than 20 percent by weight as measured by ASTM D2140.
    Type: Grant
    Filed: January 19, 2004
    Date of Patent: January 10, 2006
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Steven Kristofer Henning, Edward Lee Johnson, Michael Lester Kerns
  • Patent number: 6977276
    Abstract: The invention is directed to an oil extended rubber and composition comprising: a solution polymerized elastomer derived from isoprene and optionally at least member of the group consisting of conjugated dienes and vinyl aromatic monomers; and from about 5 to about 70 parts by weight, per 100 parts by weight of elastomer (phr), of a process oil having a glass transition temperature of from about ?80° C. to about ?40° C. and a polycyclic aromatic content of less than 3 percent by weight as determined by the IP346 method.
    Type: Grant
    Filed: December 15, 2003
    Date of Patent: December 20, 2005
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Steven Kristofer Henning, Marc Weydert, Georges Marcel Victor Thielen, Edward Lee Johnson, Michael Lester Kerns
  • Patent number: 6974851
    Abstract: The present invention relates to a shaped article for high purity applications containing at least one peroxide curable compound containing a substantially gel-free butyl polymer. In another of its aspects, the present invention relates to a sealing material and a medical device containing at least one peroxide-curable compound containing a substantially gel-free butyl polymer. In still another of its aspects, the present invention relates to a fuel cell containing at least one peroxide curable compound containing a substantially gel-free butyl polymer. In still another of its aspects, the present invention relates to halogen-free and sulfur-free shaped articles.
    Type: Grant
    Filed: May 13, 2003
    Date of Patent: December 13, 2005
    Assignee: Bayer Inc.
    Inventors: Adam Gronowski, Susmita Bhattacharjee, Gabor Kaszas