Adding Nonreactive Material To Chemically Modified Solid Polymer Patents (Class 524/572)
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Publication number: 20110160388Abstract: A process for producing a modified conjugated diene-based copolymer comprising bringing a modifier into reaction with the active end of a copolymer of a conjugated diene compound and an aromatic vinyl compound having the active end, wherein a compound having (i) a hydrolyzable functional group having silicon and (ii) a group which can be converted into a protonic amino group or a protonic amino group protected with an eliminable functional group after the reaction is used as the modifier, a step of adding a condensation catalyst is conducted after the modifier is brought into the reaction, and the content of the unit of the aromatic vinyl compound and the structure of the chain of the aromatic vinyl compound are specified.Type: ApplicationFiled: April 28, 2009Publication date: June 30, 2011Applicant: Bridgestone CorporationInventors: Ken Tanaka, Yoichi Ozawa, Ryuji Nakagawa, Takuo Sone, Takaimi Matsumoto, Yutaka Nagata
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Publication number: 20110136969Abstract: The invention relates to a rubber composition which contains silica reinforcement and functionalized crosslinks, particularly crosslinked functionalized precipitated silica, including sulfur crosslinked functionalized silica and associated cured rubber compositions, and to articles of manufacture having a component thereof such as, for example tires. A dimercaptothiadiazole is used to form the crosslinked network within the rubber composition.Type: ApplicationFiled: December 7, 2009Publication date: June 9, 2011Inventors: Bruce Raymond Hahn, Alexander Thomas Miller
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Publication number: 20110126953Abstract: The present invention relates to a tire puncture sealant and a pneumatic tire containing such puncture sealant as a built-in puncture sealant. The sealant composition contains silica reinforcement and butyl rubber depolymerized in the presence of a balanced and cooperative combination of organoperoxides comprised of a minor amount of 4,4-di(tertiary butylperoxy) valerate depolymerization initiator and a major amount of dicumyl peroxide depolymerization propagator, the combination of which has been observed to have a synergistic effect.Type: ApplicationFiled: December 2, 2009Publication date: June 2, 2011Inventor: Joseph Alan Incavo
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Publication number: 20110108183Abstract: The invention is a two-part composition comprising: A) in one part (i) one or more isocyanate functional prepolymers; and B) in a second part (ii) one or more compounds having isocyanate reactive groups; (iii) one or more fillers selected such that the composition is nonconductive; (iv) one or more catalysts for the reaction of isocyanate groups with active hydrogen containing compounds wherein either or both of the one or more isocyanate functional prepolymers and the one or more compounds having isocyanate reactive groups have solid organic particles grafted thereto such that the composition contains from about 6 to about 13 percent by weight of the total composition of solid organic particles. In a preferred embodiment, the second part comprises from about 35 to about 65 percent by weight of one or more compound having isocyanate reactive groups which have solid organic particles grafted to the backbone.Type: ApplicationFiled: July 14, 2009Publication date: May 12, 2011Inventor: Dietmar Golombowski
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Patent number: 7928159Abstract: A process for providing interaction between particulate filler and a functionalized polymer involves a composition that includes at least three components: (1) a polymer that includes a functional group including an acidic cation of a primary or secondary amine functionality, (2) a material including a functionality capable of reacting with the acidic cation, and (3) particulate filler. The amine functionality from (1) is allowed to interact with (3) after being neutralized by the action of the acid-reactive functionality from (2). The process is useful in the formation of vulcanizates and articles made therefrom.Type: GrantFiled: May 26, 2006Date of Patent: April 19, 2011Assignee: Bridgestone CorpororationInventor: Yuan-Yong Yan
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Publication number: 20110082253Abstract: The invention provides a elastomeric polymer composition comprising the reaction product of at least the following: i) a living anionic elastomeric polymer; ii) a silane modifier compound represented by the Formula I or Formula 2: (RIO)3Si—R4—S—SiR33, Formula 1 (R13O)3Si—R9-N(SiR10R11R12 Formula 2 iii) a modifier compound represented by one of the following Formulas 3 to 6: (R1O)x(R2)ySi—R4—S—SiR33, Formula 3 (R13O)P(R14)qSi—R9—N(SiR10R11R12)2 Formula 4, Formule 5, Formule 6Type: ApplicationFiled: May 29, 2009Publication date: April 7, 2011Inventors: Sven Thiele, Evemarie Hamann, Joachim Kiesekamp
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Publication number: 20110065833Abstract: The invention relates to a rubber mixture, in particular for pneumatic vehicle tires, bands, and belts, having improved abrasion behavior. The rubber mixture is characterized by the following composition: at least one diene rubber and—at least one precipitated silicic acid having a CTAB surface area greater than or equal to 150 m2/g and a BET surface area greater than or equal to 150 m2/g and a DBP number between 180 and 350 g/100 g and a full width at half maximum, which is standardized to the location of the reflection, of the reflection of less than or equal to 0.95 and a homogeneity ratio d 25% to d 75% of 1.00 to 1.80 and a relative width Ypressed in the compressed state of less than or equal to 2.8 (g nm)/ml and a fineness index F.V.pressed in the compressed state between 100 and 140, and further additives.Type: ApplicationFiled: October 6, 2010Publication date: March 17, 2011Inventors: Carmen Schmidt, Carla Recker, Thomas Fey
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Patent number: 7863371Abstract: A rubber composition for an inner liner improving rolling resistance performance of a tire and further improving processability is provided. A rubber composition for an inner liner comprising at least 30 parts by weight of silica having a BET specific surface area of less than 150 m2/g and at most 5 parts by weight or less of carbon black based on 100 parts by weight of a rubber component comprising a natural rubber and a tire having an inner liner comprising the same.Type: GrantFiled: March 2, 2006Date of Patent: January 4, 2011Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Tomoaki Hirayama, Takao Wada, Mamoru Uchida
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Publication number: 20100317794Abstract: A method for producing a modified conjugated diene polymer includes carrying out a modification reaction that reacts a modifier that includes a specific compound with a conjugated diene polymer having a cis-1,4-bond content of 98.5% or more and possessing an active end to introduce the modifier into the active end of the conjugated diene polymer to obtain a modified conjugated diene polymer. The modified conjugated diene polymer that exhibits excellent wear resistance, excellent mechanical properties, and reduced cold flow can be obtained by the method.Type: ApplicationFiled: December 27, 2007Publication date: December 16, 2010Applicant: JSR CORPORATIONInventors: Ryouji Tanaka, Takuo Sone, Toshihiro Tadaki
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Publication number: 20100232088Abstract: An electrolytic capacitor sealer capable of fulfilling the requirement such as long-term heat resistance without risk of reversion due to crosslinking with an organic peroxide and an electrolytic capacitor using such a sealer are provided.Type: ApplicationFiled: March 31, 2008Publication date: September 16, 2010Inventors: Hiroaki Fujita, Kazuhiko Kimura, Masatoshi Iemura, Masashi Ozawa, Makoto Ashiura, Tetsuji Kawazura
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Patent number: 7776951Abstract: There is provided a rubber composition in which strength and weather resistance are improved and the use of petroleum resource is suppressed as much as possible, and a tire comprising thereof. A rubber composition comprising 3 to 12 parts by weight of a pigment derived from resources other than petroleum, 10 parts by weight or less of carbon black and 30 parts by weight or more of silica based on 100 parts by weight of rubber components comprising an epoxidized natural rubber and/or a natural rubber.Type: GrantFiled: January 20, 2006Date of Patent: August 17, 2010Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Tomoaki Hirayama, Takao Wada, Mamoru Uchida
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Patent number: 7759411Abstract: The present invention provides an ink composition comprising at least a pigment, a polymer which encapsulates the pigment to make the pigment dispersible in the ink composition, a multivalent metal ion and water, wherein the polymer is a vinyl polymer obtained by polymerizing: A) at least one specific vinyl monomer, B) a monomer having a salt-forming group, C) a macromer having a number average molecular weight of 500 to 500,000, and D) a monomer copolymerizable with the monomers A), B) and C), and wherein the content of the multivalent metal ion is from 3 to 500 ppm based on the total amount of the ink composition. Also disclosed are an ink jet recording method using the ink composition and recorded matter obtained by the ink jet recording method.Type: GrantFiled: March 29, 2006Date of Patent: July 20, 2010Assignee: Seiko Epson CorporationInventor: Tetsuya Aoyama
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Publication number: 20100152370Abstract: The present invention relates to rubber mixtures with functionalized diene rubbers and with microgels, to a production process, and to the use of the mixtures for the production of low-abrasion motor-vehicle tyres which have wet-slip resistance and which have low rolling resistance.Type: ApplicationFiled: October 15, 2009Publication date: June 17, 2010Applicant: LANXESS DEUTSCHLAND GMBHInventors: Norbert Steinhauser, Werner Obrecht, David Hardy, Thomas Gross
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Publication number: 20100152369Abstract: The method for producing a modified conjugated diene based (co)polymer, according to the present invention comprises a step of reacting a conjugated diene based (co)polymer with a metal halide compound to obtain a modified conjugated diene based (co)polymer, the conjugated diene based (co)polymer having a weight-average molecular weight of 150,000 to 2,000,000 and being obtained by bonding, to a polymer having at least a conjugated diene unit, an alkoxysilyl group and an optionally protected primary amino group. The method can satisfactorily produce a conjugated diene based (co)polymer which has a high Mooney viscosity, excellent shape stability and good processability.Type: ApplicationFiled: March 21, 2008Publication date: June 17, 2010Applicant: JSR CORPORATIONInventors: Masahiro Shibata, Takaomi Matsumoto, Tamotsu Nagaoka, Takuo Sone, Toshihiro Tadaki
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Patent number: 7737218Abstract: Provided is a method comprising reacting the anionic living end of a polymer with a compound selected from the group consisting of tin halides and silicon halides to produced a polymer with a homolytically cleavable group containing a Sn—C bond or a Si—C bond. An engineered plastic may then be produced by adding the polymer containing a homolytically cleavable group containing a Sn—C bond or a Si—C bond to a solvent comprising at least one vinyl monomer; (b) optionally adding at least one additional inert solvent; (c) optionally adding additives selected from the group consisting of extender oils, modifiers, and antioxidants; and (d) initiating polymerization of the at least one vinyl monomer by the use of an initiator and/or heat, wherein a free radical is produced from the polymer containing a homolytically cleavable group containing a Sn—C bond or a Si—C bond.Type: GrantFiled: December 29, 2006Date of Patent: June 15, 2010Assignee: Bridgestone CorporationInventors: James E. Hall, David F. Lawson
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Publication number: 20100139128Abstract: Curable rubber compositions and cured articles are based on the use of zinc activator compositions for the sulfur cure. Activator compositions contain zinc and a polymeric component having a plurality of COOH groups, at least some of which are neutralized with the zinc. With polymeric zinc activators, sulfur cure can be activated at levels of zinc below those used in conventional systems.Type: ApplicationFiled: December 1, 2009Publication date: June 10, 2010Inventor: Thomas W. Wilson, III
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Publication number: 20100132868Abstract: The invention provides vulcanizable rubber compound having improved tensile mechanical and dynamic viscoelastic properties. The compounds are formed by mixing an elastomer, containing unsaturated carbon-carbon bonds in its molecular structure, with a reinforcing inorganic filler silica in the presence of an alkyl alkoxysilane and a non-sulfur coupling agent that binds to the rubber backbone with an “ene” linkage or a 1,3 dipolar addition linkage. In particular, the coupling agent and the alkyl alkoxysilane are present in the compound in a weight ratio of about 0.0001:1 to about 1:1.Type: ApplicationFiled: December 1, 2009Publication date: June 3, 2010Applicant: BRIDGESTONE CORPORATIONInventors: William L. Hergenrother, Chenchy Jeffrey Lin, Yaohong Chen
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Publication number: 20100132863Abstract: The present invention provides a rubber composition that is used for forming a ply having superior processability upon preparation thereof, with a reduced hysteresis loss, a clinch that is capable of achieving both of good physical characteristics, such as rigidity, hardness and mechanical strength, and improvements in processability and a tread that has high rigidity with a small hysteresis loss and is superior in processability upon preparation thereof, while reducing the amount of use of materials derived from petroleum resources, and a pneumatic tire provided with these. The ply, the clinch apex and the tread are made from a rubber composition that has 100 parts by mass of a rubber component composed of a natural rubber and/or a modified natural rubber, and 25 to 80 parts by mass of silica having a BET specific surface area of not more than 150 m2/g, and the pneumatic tire is provided with these.Type: ApplicationFiled: February 27, 2008Publication date: June 3, 2010Inventors: Takashi Miki, Keiji Ikeda
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Publication number: 20100130664Abstract: The invention includes terminating compounds, polymers, rubber compositions and tires. The terminating compounds can provide terminating groups on the polymer. Polymers can be homopolymers, copolymers and terpolymers, and can include repeat units provided from conjugated diene monomers. Rubber compositions can be made from the polymers, and tires and various parts of tires can be made from those rubber compositions.Type: ApplicationFiled: November 24, 2008Publication date: May 27, 2010Applicant: The Goodyear Tire & Rubber CompanyInventors: Michael Joseph Rachita, Joseph John Kulig, Robert Alan Woloszynek
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Patent number: 7718728Abstract: This invention relates to a rubber composition having a high interaction between rubber component and carbon black, a good wear resistance and an excellent low heat buildup (low hysteresis loss), and more particularly to a rubber composition comprising (A) 100 parts by mass of a rubber component containing not less than 10% by mass of a conjugated diene polymer having a polymer chain with at least one functional group selected from the group consisting of particular substituted amino group and cyclic amino group, (B) not less than 20 parts by mass of carbon black and (C) not more than 1.0 part by mass of a polycyclic aromatic compound (PCA).Type: GrantFiled: March 19, 2004Date of Patent: May 18, 2010Assignee: Bridgestone CorporationInventors: Satoshi Mikami, Kentaro Fujino, Yoichi Ozawa, Akira Suzuki
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Publication number: 20100113683Abstract: The method for producing a modified conjugated diene based (co)polymer, according to the present invention comprises (a) obtaining a primarily modified polymer by carrying out a primary modification reaction wherein at least one member selected from the group consisting of an alkoxysilane compound and a silanol compound is introduced into the active alkali metal terminal of a conjugated diene based (co)polymer having an active alkali metal terminal, and (b) obtaining a secondarily modified polymer (a modified conjugated diene based (co)polymer) by subjecting the above-obtained primarily modified polymer to reactions comprising (b1) and (b2). (b1): a reaction with a condensation accelerator comprising a metal element. (b2): a reaction with at least one member selected from the group consisting of inorganic acids and metal halides.Type: ApplicationFiled: March 21, 2008Publication date: May 6, 2010Applicants: JSR CORPORATION, BRIDGESTONE CORPORATIONInventors: Takaomi Matsumoto, Masahiro Shibata, Takuo Sone, Toshihiro Tadaki, Ken Tanaka, Ryuji Nakagawa
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Publication number: 20100099795Abstract: The present invention has its object to provide a rubber composition that can be used for a tread to supply a tire excellent in low heat build-up property and wet grip performance. The present invention relates to a rubber composition including a rubber component that contains a modified styrene-butadiene rubber in an amount of 5% by weight or more per 100% by weight of the rubber component, the modified styrene-butadiene rubber having, in a main chain thereof, a constitutional unit derived from a specific nitrogen-containing compound; and the rubber composition further including silica in an amount of 10 to 150 parts by weight per 100 parts by weight of the rubber component.Type: ApplicationFiled: October 15, 2009Publication date: April 22, 2010Inventor: Kenichi UESAKA
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Patent number: 7700686Abstract: A process for producing a modified polymer which increases low heat buildup and reinforcing capability of a rubber composition and which has excellent abrasion resistance, mechanical characteristics, and processability; a modified polymer obtained by the process; and a rubber composition using the modified polymer are provided. The process comprises a step of carrying out a modification reaction on the active end of a conjugated diene polymer having a vinyl content of below 10%, a cis-1,4 bond content of 75% or higher, and an active end, using an alkoxysilane compound, and a step of carrying out a condensation reaction in the presence of a condensation accelerator comprising a compound of an element belonging to at least one of the groups 4A (excluding Ti), 2B, 3B, and 5B of the periodic table.Type: GrantFiled: March 17, 2006Date of Patent: April 20, 2010Assignee: JSR CorporationInventors: Ryouji Tanaka, Kouichirou Tani, Takuo Sone, Toshihiro Tadaki
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Publication number: 20100071818Abstract: A vulcanizable rubber composition is presented that comprises an elastomer; a reinforcing filler selected from silica, carbon black, and mixtures thereof, a cure agent; and an amino alkoxy-modified silsesquioxane (AMS) comprising one or more compounds selected from the group consisting of an amino AMS, an amino/mercaptan co-AMS, an amino/blocked mercaptan co-AMS, mixtures thereof, and weak acid-neutralized solid and aqueous solutions thereof. Addition of such compounds to the rubber composition provides improved dynamic viscoelastic and mechanical properties of the vulcanized rubber compound and predict that tire components, especially tread stocks, will provide tires having improved snow traction, lower rolling resistance but equal wet traction, increased rebound, decreased hysteresis, and a general improvement in tire performance.Type: ApplicationFiled: December 31, 2008Publication date: March 25, 2010Inventors: William L. Hergenrother, Chenchy Jeffrey Lin
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Publication number: 20100068491Abstract: In order to provide a non-stick coating which permits a very high coat thickness even under load, a polymeric matrix with embedded non-stick particles is used.Type: ApplicationFiled: November 5, 2007Publication date: March 18, 2010Inventors: Dirk Richter, Christian Pluta
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Publication number: 20100063202Abstract: The invention includes a siloxy-amine functionalized rubbery polymer, which exhibits good reinforcing characteristics and filler dispersing effect, a method for making, and a rubber composition including the same. In one embodiment, a process for manufacturing includes polymerizing a conjugated diene monomer using an organolithium compound as an initiator in a hydrocarbon solvent. Next, an active terminal end of the polymer is reacted with a functionalized terminating agent represented by: RN—(CH2)XSi(OR1)3, ??Formula (I) wherein R, in combination with the nitrogen (N) atom, is a substituted or unsubstituted heterocyclic aromatic or non-aromatic compound which includes a ring structure with one or more nitrogen atoms as part of the ring; R1 represents a group having 1 to 18 carbon atoms selected from an alkyl, a cycloalkyl, an allyl, or an aryl; and X is an integer from 1 to 20.Type: ApplicationFiled: September 10, 2008Publication date: March 11, 2010Applicant: The Goodyear Tire & Rubber CompanyInventors: Adel Farhan Halasa, Nicola Constantini, Frank Schmitz
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Publication number: 20100056712Abstract: A conjugated diene polymer is provided that comprises a conjugated diene-based constituent unit and a constituent unit of formula (I), at least one terminus of the polymer being modified by a compound having a linkage of formula (II): wherein X1, X2, and X3 independently denote a group as defined in the specification. wherein p denotes 0 or 1, T denotes a group as defined in the specification.Type: ApplicationFiled: August 21, 2009Publication date: March 4, 2010Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventor: Mayumi OSHIMA
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Publication number: 20100056713Abstract: A conjugated diene polymer is provided that comprises a conjugated diene-based constituent unit and a constituent unit of formula (I) below, at least one terminus of the polymer being modified by a compound of formula (II): wherein X1, X2, and X3 independently denote a group of formula (Ia) below, a hydroxy group, a hydrocarbyl group, or a substituted hydrocarbyl group, and at least one of X1, X2, and X3 is a group of formula (Ia) below or a hydroxy group, wherein R1 and R2 independently denote a hydrocarbyl group having 1 to 6 carbon atoms, a substituted hydrocarbyl group having 1 to 6 carbon atoms, a silyl group, or a substituted silyl group, and R1 and R2 may be bonded so as to form, together with the nitrogen atom, a ring structure, wherein n denotes an integer of 1 to 10, R3, R4, and R5 independently denote a hydrocarbyl group having 1 to 4 carbon atoms or a hydrocarbyloxy group having 1 to 4 carbon atoms, at least one of R3, R4, and R5 is a hydrocarbyloxy group, and A denotes a nitrogen atomType: ApplicationFiled: August 21, 2009Publication date: March 4, 2010Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventor: Mayumi Oshima
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Publication number: 20100016500Abstract: A process for producing a modified polymer that exhibits low rolling resistance, excellent mechanical properties (e.g., tensile strength), high wet-skid resistance, and excellent wear resistance when vulcanized, a modified polymer obtained by the process, and a rubber composition containing the same. The process includes subjecting an alkali metal active end of a conjugated diene polymer to a modification reaction with an alkoxysilane compound, the conjugated diene polymer being produced by subjecting a diene monomer or a diene monomer and a monomer other than the diene monomer to anionic polymerization in a hydrocarbon solvent using an alkali metal initiator, and subjecting the resulting product to a condensation reaction in the presence of a condensation accelerator that includes a compound of at least one element among the elements of the groups 4A (excluding Ti), 2B, 3B, and 5B of the periodic table.Type: ApplicationFiled: October 25, 2007Publication date: January 21, 2010Applicants: JSR CORPORATION, BRIDGESTONE CORPORATIONInventors: Takuo Sone, Takaomi Matsumoto, Kouichirou Tani, Koji Masaki, Ken Tanaka
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Publication number: 20100000639Abstract: A method for preparing a tire tread, the method comprising vulcanizing a vulcanizable composition comprising a rubber component including a functionalized polymer and a cure system, where the cure system includes sulfur and a disulfide compound represented by the formula I R1—S—S—R3—S—S—R2 where R3 represents a divalent organic group and R1 and R2 each independently include a monovalent organic group including a nitrogen atom.Type: ApplicationFiled: December 31, 2008Publication date: January 7, 2010Inventors: Amy Randall, Terrence E. Hogan, William L. Hergenrother
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Publication number: 20090326102Abstract: The invention disclosed herein relates to an improved process for making elastomeric polyisoprene articles. In particular, the process of the invention is a system which produces synthetic polyisoprene articles exhibiting tensile strength properties similar to that of solvent-based processes using natural rubber latex. The process comprises an accelerator composition at the pre-cure stage comprising a dithiocarbamate, a thiazole and a guanidine compound. In a preferred embodiment, the accelerator composition comprises zinc diethyldithiocarbamate (ZDEC), zinc 2-mercaptobenzothiazole (ZMBT) and diphenyl guanidine (DPG), in conjunction with a stabilizer, such as sodium caseinate. The invention also includes an elastomeric polyisoprene product made by the process, such as a surgeon's glove.Type: ApplicationFiled: September 4, 2009Publication date: December 31, 2009Inventors: Shiping WANG, Yun-Siung Tony YEH, Randell WENIG, Wong Weicheong
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Publication number: 20090283186Abstract: The present invention is directed to a method of making a rubber composition, comprising the steps of A) obtaining a diene-based elastomer selected from the group consisting of natural rubber, synthetic polyisoprene, polybutadiene, solution polymerized styrene-butadiene rubber (SSBR), and emulsion polymerized styrene-butadiene rubber (ESBR); B) mixing the diene-based elastomer with a halogenating agent to form an intermediate elastomer; and C) mixing the intermediate elastomer with a carbon black. There is further disclosed a rubber composition made by the foregoing method, and a pneumatic tire comprising the rubber composition.Type: ApplicationFiled: May 15, 2008Publication date: November 19, 2009Inventor: Gabor Kaszas
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Patent number: 7608664Abstract: In one embodiment of the present invention, a curable sealant composition and method for its preparation are provided. The composition includes a polymer which is prepared by functionalizing a poly(conjugated diene) with a curable group such as a tetra-substituted silicon compound and then substantially hydrogenating the functionalized polymer in the presence of a Ziegler type catalyst. The composition can further include additional curable sealant ingredient selected from the group consisting of plasticizers, fillers, reinforcing agents, modifiers, curing catalysts/hardeners, stabilizers, and mixtures thereof.Type: GrantFiled: January 18, 2006Date of Patent: October 27, 2009Assignee: Bridgestone CorporationInventors: James H. Pawlow, Yuan-Yong Yan, Takayuki Yako, Jason T. Poulton
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Publication number: 20090247696Abstract: A conjugated diene polymer is provided that includes a conjugated diene-based constituent unit and a constituent unit represented by Formula (I) below, the constituent unit represented by Formula (I) being present between a conjugated diene-based constituent unit and a conjugated diene-based constituent unit, and the content of the constituent unit represented by Formula (I) being 1 unit or 2 units per polymer chain. In the formula, X1, X2, and X3 independently denote a group as defined in the specification.Type: ApplicationFiled: March 24, 2009Publication date: October 1, 2009Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Toru FUJII, Mayumi Oshima
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Publication number: 20090227730Abstract: The instant invention discloses a process for preventing contact discoloration of substrates coming into contact with elastomers and stabilizing elastomers to prevent oxidative, thermal, dynamic, light-induced and/or ozone-induced degradation, which comprises incorporating into the elastomers, or applying to these, at least a compound of the formula (I) wherein R1 is C1-C12alkyl, R2 is C1-C12alkyl, or R1 and R2 together with the carbon atom to which they are attached form an unsubstituted or with C1-C4alkyl substituted C5-C12cycloalkyl ring; R3 is hydrogen or —CH2—S(O)m—R5, R4 and R5 independently of each other are unsubstituted or with cyano substituted C5-C18-alkyl; C7-C9phenylalkyl, unsubstituted or with halogen, hydroxyl, cyano or C1-C4alkyl substituted phenyl or naphthyl; benzothiazolyl or —R6—CO2—R7, R6 is C1-C18alkylene, R7 is C1-C18alkyl, and m is 0, 1 or 2.Type: ApplicationFiled: October 2, 2006Publication date: September 10, 2009Applicant: Ciba CorporationInventors: Michèle Gerster, Hans-Rudolf Meier, Gerrit Knobloch, Pierre Rota-Graziosi
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Publication number: 20090209699Abstract: The invention is directed to a method of manufacturing a rubber composition with improved processing properties and optimized abrasion characteristics. Three methods with differing number of processing steps for the manufacture of a rubber composition with improved processing properties and optimized abrasion characteristics are disclosed.Type: ApplicationFiled: November 28, 2008Publication date: August 20, 2009Inventors: Hajo Weinreich, Norbert Muller, Ulrike Ohnemuller, Carla Recker
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Publication number: 20090203826Abstract: The invention includes a siloxy-imine functionalized rubbery polymer, which exhibits good reinforcing characteristics and filler dispersing effect, a method for making, and a rubber composition including the same. In one embodiment, a process for manufacturing the functionalized rubbery polymer includes polymerizing a conjugated diene monomer using an organolithium compound as an initiator in a hydrocarbon solvent. Next, an active terminal end of the polymer is reacted with a functionalized terminating agent, represented by the general formula: RCH?N(CH2)XSi(OR1)YR23-Y, ??Formula (1) wherein R represents a group consisting of an aryl or substituted aryl having 6 to 18 carbon atoms, or a heterocycle or heteroaryl having 3 to 18 carbon atoms; R1 and R2 each independently represents a group having 1 to 18 carbon atoms selected from an alkyl, a cycloalkyl, an allyl, and or aryl; X is an integer from 1 to 20; and Y is an integer from 1 to 3.Type: ApplicationFiled: February 13, 2008Publication date: August 13, 2009Inventors: Michael Joseph Rachita, Kenneth Allen Bates, Vanessa Marika Riedlinger, Tang Hong Wong
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Patent number: 7534839Abstract: Anionically-polymerized living polymers are sequentially functionalized with certain agents X? and Y?. A method of preparing a functionalized polymer comprising the steps of reacting the polymer with a functionalizing agent X?, and then further reacting the polymer with a functionalizing agent Y?.Type: GrantFiled: June 9, 2004Date of Patent: May 19, 2009Assignee: Bridgestone CorporationInventors: David F. Lawson, Christine Rademacher, Christopher Robertson
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Patent number: 7517936Abstract: A curable sealant composition is provided. The composition includes a polymer including at least conjugated dime contributed monomer units in a backbone of the polymer and terminal groups including silicon. The composition also includes additional sealant ingredients selected from the group consisting of plasticizers, filler, reinforcing agents, modifiers, curing catalysts/hardeners, stabilizers, and mixtures thereof.Type: GrantFiled: April 2, 2004Date of Patent: April 14, 2009Assignee: Bridgestone CorporationInventors: Takayuki Yako, Jason T. Poulton, Yuan-Yong Yan
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Publication number: 20090093587Abstract: A modified butyl rubber composition comprising a butyl rubber modified by mixing, under heating, (a) a compound having a nitroxide-free radical in the molecule thereof, which is stable at an ordinary temperature even in the presence of oxygen, (b) a radical initiator, and (c) a bi- or more-functional radical polymerizable monomer and further by compounded with (d) a bi- or more-functional radical polymerizable monomer, which is different from the ingredient (c).Type: ApplicationFiled: September 29, 2008Publication date: April 9, 2009Applicant: THE YOKOHAMA RUBBER CO., LTD.Inventors: Makoto Ashiura, Tetsuji Kawazura
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Patent number: 7501465Abstract: A resin composition includes an alicyclic structure-containing polymer; a hindered amine compound; and a releasing agent, wherein the releasing agent and the alicyclic structure-containing polymer satisfy the following relationship: 10?|s1?s2|?0.8 [(MPa)0.5], wherein s1 represents a solubility parameter of the releasing agent, and s2 represents a solubility parameter of the alicyclic structure-containing polymer. The resin composition can be used as optical materials, such as a lens, a diffraction grating, and a prism, especially in the field of using blue laser, and has excellent releasability, transparence and colorless property as well as excellent resistance to laser.Type: GrantFiled: January 17, 2005Date of Patent: March 10, 2009Assignee: Zeon CorporationInventors: Taichi Sawaguchi, Koji Minami
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Patent number: 7498387Abstract: A first-order modified, hydrogenated polymer comprising (1) a hydrogenated polymer obtained by hydrogenating at least one unhydrogenated polymer selected from the group consisting of a polymer comprising conjugated diene monomer units and a copolymer comprising conjugated diene monomer units and vinyl aromatic hydrocarbon monomer units, and (2) a functional group-containing first-order modifier group bonded to the hydrogenated polymer (1), wherein the content of the vinyl aromatic hydrocarbon monomer units, vinyl aromatic hydrocarbon block ratio, weight average molecular weight, and hydrogenation ratio (as measured with respect to the double bonds in the conjugated diene monomer units) of the first-order modified, hydrogenated polymer are, respectively, within specific ranges.Type: GrantFiled: April 10, 2003Date of Patent: March 3, 2009Assignee: Asahi Kasei Chemicals CorporationInventors: Takaaki Matsuda, Shigeki Takayama, Toshinori Shiraki, Shigeo Nakajima, Yasuhiro Kusanose
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Patent number: 7485684Abstract: This invention relates to a tire which is comprised of a generally toroidal-shaped carcass with an outer circumferential tread, two spaced beads, at least one ply extending from bead to bead and sidewalls extending radially from and connecting said tread to said beads, wherein said tread is adapted to be ground-contacting, and wherein said tread is a cured the rubber formulation which is comprised of (1) hydroxylamine end-group functionalized rubbery polymer of the structural formula: wherein P represents polymer chains of the rubbery polymer, and wherein (i) R1 and R2 are independently selected from the group consisting of substituted or unsubstituted straight, branched, or cyclic alkylgroups, alkenyl groups, alkynyl groups, aryl groups, heteroaryl groups, alkaryl groups, alkoxyl groups, halo-alkyl groups, and combinations thereof; or (ii) R1 and R2 taken together with the carbon and nitrogen to which they are attached form a 5 to 8 membered ring; and (2) a filler selected from the group consisting of caType: GrantFiled: September 5, 2006Date of Patent: February 3, 2009Assignee: The Goodyear Tire & Rubber CompanyInventor: Dane Kenton Parker
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Publication number: 20090005496Abstract: A method for producing a conjugated diene polymer is provided that includes a step of polymerizing a conjugated diene-containing monomer in a hydrocarbon solvent in the presence of an alkali metal catalyst, thus giving a polymer having a catalyst-derived alkali metal at one terminus of a polymer chain comprising a conjugated diene-based monomer unit, and a step of reacting the polymer obtained in the step of polymerizing and a trialkoxysilane compound represented by the formula below. (In the formula, M denotes an oxygen atom or a sulfur atom, R1, R2, and R3 independently denote an alkyl group having 1 to 4 carbon atoms, m denotes an integer of 1 to 5, and n denotes an integer of 0 to 5.Type: ApplicationFiled: June 17, 2008Publication date: January 1, 2009Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Naoaki MAEDA, Mayumi Oshima, Katsunari Inagaki
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Publication number: 20090005497Abstract: A method for producing a conjugated diene polymer is provided that includes a step of polymerizing a conjugated diene-containing monomer in a hydrocarbon solvent in the presence of an alkali metal catalyst, thus giving a polymer having a catalyst-derived alkali metal at one terminus of a polymer chain comprising a conjugated diene-based monomer unit, and a step of reacting the polymer obtained in the step of polymerizing and a trialkoxysilane compound represented by the formula below. (In the formula, Y and Z independently denote an oxygen atom or a sulfur atom, R1, R2, and R3 independently denote an alkyl group having 1 to 4 carbon atoms, m denotes an integer of 1 to 5, and n denotes an integer of 0 to 5.Type: ApplicationFiled: June 17, 2008Publication date: January 1, 2009Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Naoaki MAEDA, Mayumi Oshima, Katsunari Inagaki
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Patent number: 7470742Abstract: The present invention provides a rubber composition for covering a carcass cord, which makes it possible to consider an effect on environment, prepare for decrease in supply quantity of petroleum resources in future, reduce rolling resistance and improve rubber strength and processability, and a tire prepared by using the rubber composition. The rubber composition for covering a carcass cord of the present invention comprises 25 to 80 parts by mass of silica, 1 to 15 parts by mass of a silane coupling agent and 3 to 30 parts by mass of an organic vulcanizing agent represented by the following general formula (1): —(R—Sx)n— wherein R is —(CH2—CH2—O)m—CH2—CH2—; x is an integer of 2 to 6; n is an integer of 10 to 400; and m is an integer of 2 to 5, based on 100 parts by weight of a diene rubber, and a tire prepared by using the rubber composition.Type: GrantFiled: June 12, 2007Date of Patent: December 30, 2008Assignee: Sumitomo Rubber Industries, Ltd.Inventor: Tetsuya Kunisawa
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Publication number: 20080206468Abstract: A thermoplastic composition includes particular amounts of a poly(arylene ether), a hydrogenated block copolymer, a copolymer of ethylene and an alpha-olefin, a plasticizer, a white pigment, and an ultraviolet radiation stabilizer. The composition exhibits excellent light stability, and it is particularly useful for forming white or off-white cable insulation.Type: ApplicationFiled: February 28, 2007Publication date: August 28, 2008Inventors: Steven Raymond Klei, James Edward Pickett, James Jun Xu
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Publication number: 20080206449Abstract: A thermoplastic composition includes particular amounts of a poly(arylene ether), a hydrogenated block copolymer, a plasticizer, a white pigment, and an ultraviolet radiation stabilizer. The composition exhibits excellent light stability, and it is particularly useful for forming white or off-white cable insulation.Type: ApplicationFiled: February 28, 2007Publication date: August 28, 2008Inventors: Steven Raymond Klei, James Edward Pickett, James Jun Xu
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Patent number: 7405256Abstract: There is provided a run flat tire having a side reinforcing layer in which low exothermic property and high hardness are compatible and durability is improved. A rubber composition containing 10 to 100 parts by weight of carbon black with a nitrogen adsorption specific area of 30 to 100 m2/g and a dibutyl phthalate oil absorption amount of 50 ml/100 g or more and 2 parts by weight or more of sulfur or a sulfur compound, based on 100 parts by weight of a rubber component containing 10 to 50% by weight of a conjugated diolefin polymer or a copolymer of a diolefin and an aromatic vinyl compound having a primary amino group and an alkoxysilyl group and having a glass transition point of ?30° C. or less in which a bifunctional or more monomer is copolymerized in a polymer chain and/or at least a portion of a (co)polymer chain is coupled with a bifunctional or more coupling agent, and a run flat tire having a side reinforcing layer comprising the rubber composition.Type: GrantFiled: April 14, 2006Date of Patent: July 29, 2008Assignee: Sumitomo Rubber Industries, Ltd.Inventor: Kazuo Hochi
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Publication number: 20080161467Abstract: A rubber formulation with good wet traction properties includes one or more elastomers and at least two types of particulate filler materials including at least one of which has a relatively high free surface energy in water (i.e., a supplemental filler). The formulation containing the supplemental filler(s) can provide a vulcanizate that has a British pendulum (skid) number that is at least ˜5% greater than that of a vulcanizate made from an essentially identical formulation that does not contain the supplemental filler(s). Also provided is a method for providing such a formulation which involves identifying one or more supplemental fillers having relatively high free surface energies in water, replacing at least 15% (by wt.) of one or more of the conventional particulate fillers in the formulation with an approximately equivalent volume of supplemental filler particles, and providing the modified formulation.Type: ApplicationFiled: December 31, 2007Publication date: July 3, 2008Inventors: Xiao-Dong Pan, Pat Sadhukhan, Hiroshi Mouri, Michael W. Hayes, Dennis R. Brumbaugh