Interpolymer With At Least One Aliphatic Hydrocarbon Monomer, E.g., Butyl Rubber, Etc. Patents (Class 524/574)
  • Patent number: 4427812
    Abstract: The present invention relates to a process for the gelation (i.e. thickening) of salt water which includes the steps of forming a solvent system of an organic liquid or oil and a polar cosolvent, the polar cosolvent being less than about 15 weight percent of the solvent system, a viscosity of the solvent system being less than about 100 cps; dissolving a nonionic surfactant and water insoluble, neutralized or unneutralized sulfonated polymer in the solvent system to form a solution, a concentration of the neutralized, or unneutralized sulfonated polymer in the solution being about 0.01 to about 0.5 weight percent, the concentration of the nonionic surfactant in the solvent system being about 0.0001 to about 1.
    Type: Grant
    Filed: May 3, 1982
    Date of Patent: January 24, 1984
    Assignee: Exxon Research and Engineering Co.
    Inventors: Dennis G. Peiffer, Robert D. Lundberg, Thad O. Walker
  • Patent number: 4426468
    Abstract: A sealant composition particularly suitable for vehicle tires comprising a cured butyl rubber present only in the form of a copolymer having a molecular weight in excess of 100,000 and one or more tackifiers, the tensile strength, elongation and cross-link density of the composition being adjusted to produce the necessary properties for tire sealants.
    Type: Grant
    Filed: August 30, 1982
    Date of Patent: January 17, 1984
    Assignee: Rockcor, Inc.
    Inventors: Joel V. Ornum, Jessie T. Chiu
  • Patent number: 4426473
    Abstract: The present invention relates to a process for the gelation (i.e. thickening) of an aqueous acid solution which includes the steps of forming a solvent system of an organic liquid or oil and a polar cosolvent, the polar cosolvent being less than about 15 weight percent of the solvent system, a viscosity of the solvent system being less than about 100 cps; dissolving a neutralized sulfonated polymer in the solvent system to form a solution, a concentration of the neutralized sulfonated polymer in the solution being about 0.01 to about 0.5 weight percent, a viscosity of the solution being less than about 200 cps; and admixing or contacting said solution with about 5 to about 500 volume percent of the aqueous acid solution, the aqueous acid solution being immiscible with the organic liquid and the polar cosolvent and neutralized sulfonated polymer transferring from the organic liquid to the aqueous acid phase, thereby causing the aqueous acid phase to thicken (i.e. interfacial viscosification).
    Type: Grant
    Filed: May 3, 1982
    Date of Patent: January 17, 1984
    Assignee: Exxon Research and Engineering Co.
    Inventors: Dennis G. Peiffer, Robert D. Lundberg, Thad O. Walker
  • Patent number: 4425462
    Abstract: The present invention relates to sulfonated elastomeric polymers which are copolymers of isoprene and sodium styrene sulfonate or teropolymers of isoprene, styrene and sodium styrene sulfonate wherein these sulfonated polymers function as viscosification agents when added to oil-based drilling muds which are the fluids used to maintain pressure, cool drill bits and lift cuttings from the holes in the drilling operation for oil and gas wells. The sulfonated and elastomeric polymers have about 5 to about 100 meq. of sulfonate groups per 100 grams of the sulfonated elastomeric polymer, wherein the sulfonated groups are neutralized with a metallic cation or an amine or ammonium counterion. A polar cosolvent can optionally be added to the mixture of oil drilling mud and sulfonated elastomeric polymer, wherein the polar cosolvent increases the solubility of the sulfonated elastomeric polymer in the oil drilling mud by decreasing the strong ionic interactions between the sulfonate groups of the sulfonated polymer.
    Type: Grant
    Filed: September 13, 1982
    Date of Patent: January 10, 1984
    Assignee: Exxon Research and Engineering Co.
    Inventors: S. Richard Turner, Robert D. Lundberg, Thad O. Walker
  • Patent number: 4412028
    Abstract: The present invention relates to a process for forming a gel having improved creep resistance at elevated temperatures and having a viscosity of at least about 100,000 cps which includes the steps forming a solvent system of an organic liquid and a water miscible cosolvent, the water miscible cosolvent being less than about 15 wt. % of the solvent system, a viscosity of the solvent system being less than about 1000 cps; dissolving a neutralized sulfonated polymer in the solvent system to form a solution, adding a free radical generating initiator to the solution at a concentration level of about 0.01 to about 1%, a concentration of the neutralized sulfonated polymer in the solution being about 0.5 to about 20 wt. %, a viscosity of the solution being less than about 20,000 cps; and adding under shear conditions about 5 to about 500 vol.
    Type: Grant
    Filed: December 29, 1981
    Date of Patent: October 25, 1983
    Assignee: Exxon Research and Engineering Co.
    Inventors: Robert D. Lundberg, Robert R. Phillips, Lee A. McDougall
  • Patent number: 4412029
    Abstract: A permanently elastic dielectric composition comprising a resilient dielectric base material, an electrically polarizable component having low electrical conductivity to increase the relative dielectric constant of the composition, and a component displaying metal conductivity for maintenance of the relative dielectric constant at high power frequencies.
    Type: Grant
    Filed: March 2, 1981
    Date of Patent: October 25, 1983
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Dieter Kehr, Manfred Viebranz
  • Patent number: 4386179
    Abstract: A composition of matter composed of a thermoplastic elastomeric hydrocarbon block copolymer having 0.1 to 8 percent polysiloxane, or silicone oil, uniformly distributed throughout. The composition exhibits improved surface, elasticity, and tensile strength characteristics as well as superior processibility. The block copolymer may take the form of styrene-ethylene-butylene-styrene in which the styrene blocks have a molecular weight of 5,000 to 40,000 and the ethylene-butylene block has a molecular weight of 20,000 to 500,000. Uniformly dispersed mineral oil may constitute 10 to 60 percent of the composition's total weight which may also include less than 45 percent polypropylene. Combining the copolymer with the silicone oil occurs under the influence of a pressure of 1,500 to 2,500 p.s.i. such as provided by extrusion blending. The resulting elastomeric composition may extrude in sheets as thin as 0.015, 0.010 or even 0.005 inch, which a puller may thin even further.
    Type: Grant
    Filed: May 7, 1980
    Date of Patent: May 31, 1983
    Assignee: Medical Research Associates, Ltd.
    Inventor: Robert E. Sterling
  • Patent number: 4386185
    Abstract: Silica-reinforced rubber compositions are prepared employing a mercaptan-substituted phosphonate as a coupling agent. Preparation and use of the mercaptan-substituted phosphonate coupling agent is illustrated using dimethyl 3-mercaptopropylphosphonate and a butadiene/styrene emulsion polymerized copolymer reinforced with a precipitated hydrated silica.
    Type: Grant
    Filed: November 5, 1981
    Date of Patent: May 31, 1983
    Assignee: Phillips Petroleum Company
    Inventors: Gary D. Macdonell, Carl J. Stacy
  • Patent number: 4366284
    Abstract: The disclosed water stopper and water stopping process use an aqueously-swelling water-stopping composition consisting of 10 to 40 weight % of rubber whose main ingredient is reclaimed rubber, 10 to 20 weight % of silicic compound, 10 to 60 weight % of bentonite, and 10 to 40 weight % of plasticizer. The aforesaid water-stopping composition may be extruded into an elongated water stopper with or without a core therein, which water stopper can be inserted into a joint gap or other gap of structural members to stop water at the gap.
    Type: Grant
    Filed: January 21, 1981
    Date of Patent: December 28, 1982
    Assignee: Hayakawa Rubber Company Limited
    Inventors: Yoshinobu Ishido, Hideo Tanaka