Water Dnrm Patents (Class 524/598)
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Patent number: 11162021Abstract: The embodiments described herein generally relate to methods and chemical compositions for use with wellbore treatment processes. In one embodiment, a composition is provided comprising a mineral acid and a retardation agent selected from the group of an amine containing compound, an amide containing compound, lignosulfonate, and combinations thereof.Type: GrantFiled: June 19, 2018Date of Patent: November 2, 2021Assignee: Hexion Inc.Inventors: Li Jiang, Jan Beetge
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Patent number: 11130255Abstract: A method of producing a thermally modified and impregnated wooden product is described herein. One or more pieces of wood are thermally modified. The thermally modified wood is formed into a wooden object by hand, tool, machine, a computer numerical controlled machine, or combinations thereof. The wooden object is then impregnated with one or more treatment agents to produce the thermally modified and impregnated wooden product. The wooden object is impregnated by applying pressure or heat while the object is in the presence of the one or more treatment agents. Minimal, if any, deformation of the thermally modified wooden object occurs during impregnation.Type: GrantFiled: May 21, 2018Date of Patent: September 28, 2021Inventor: Trey Michael Fisher
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Patent number: 10745556Abstract: Provided are an amino resin composition, a varnish, a coating layer, and a product. The amino resin composition comprises a repeating unit represented by the following Formula (I): A 13C-NMR spectrum of the amino resin composition has a first characteristic peak at 159 ppm to 161 ppm and a second characteristic peak at 70 ppm to 80 ppm. Based on the integral value of the first characteristic peak as 1, the integral value of the second characteristic peak is in the range from 0.01 to 0.25. Adopting the amino resin composition can accelerate the drying of the varnish and ensure the coating layer and the product have high hardness, high gloss and excellent color stability.Type: GrantFiled: March 19, 2020Date of Patent: August 18, 2020Assignee: CHANG CHUN PLASTICS CO., LTD.Inventors: Ren-Wei Tsai, You-Ting Chen, Kuo-Pin Wu, Yung-Sheng Lin, I-Chiang Lai, Yi-Sern Wong, Kuen-Yuan Hwang
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Patent number: 9911999Abstract: The invention relates to a method for producing an anion-exchange polymer material having an IPN or semi-IPN structure, said method consisting in: (A) preparing a homogeneous reaction solution containing, in a suitable organic solvent, (a) at least one organic polymer bearing reactive halogen groups, (b) at least one tertiary diamine, (c) at least one monomer comprising an ethylenic unsaturation polymerizable by free radical polymerization, (d) optionally at least one cross-linking agent including at least two ethylenic unsaturations polymerizable by free radical polymerization, and e) at least one free radical polymerization initiator; and (B) heating the prepared solution to a temperature and for a duration that are sufficient to allow both a nucleophilic substitution reaction between components (a) and (b) and a free radical copolymerization reaction of components (c) and optionally (d) initiated by component (e).Type: GrantFiled: September 11, 2015Date of Patent: March 6, 2018Assignees: ELECTRICITE DE FRANCE, UNIVERSITE DE CERGY PONTOISEInventors: Philippe Stevens, Fouad Ghamouss, Odile Fichet, Christian Sarrazin
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Patent number: 8900667Abstract: Disclosed are coating compositions that can be one-component, ambient curable, and waterborne. The coating compositions include a polymer that is the reaction product of a polycarbodiimide and a ketocarboxylic acid. Also disclosed are substrates coated with a coating deposited from such compositions, as well as methods for depositing a coating on a substrate, and coated substrates.Type: GrantFiled: December 18, 2009Date of Patent: December 2, 2014Assignee: PPG Industries Ohio, Inc.Inventors: Carol L. Boggs, Anthony M. Chasser, Kurt G. Olson, Narayan K. Raman, Irina G. Schwendeman, Shanti Swarup, Venkateshwarlu Kalsani
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Patent number: 8735507Abstract: The instant invention provides a crosslinkable aqueous composition, method of producing the same, crosslinked compositions, and method of producing the same. The crosslinkable composition comprising: an aqueous dispersion comprising; (a) water; (b) a polycarbamate comprising at least an average of 2.0 carbamate functional groups; (c) a polyaldehyde comprising at least two aldehyde groups; (d) an acid catalyst; and (e) optionally one or more surfactants; wherein said aqueous dispersion has a pH in the range of less than 7; and wherein said composition is capable of being crosslinked at a temperature in range of less than 80° C. upon substantial removal of water.Type: GrantFiled: December 27, 2012Date of Patent: May 27, 2014Assignees: Dow Global Technologies LLC, Rohm and Haas CompanyInventors: Eric Greyson, John N. Argyropoulos, Paul Foley, Andrew Swartz, Nahrain E. Kamber, Caroline Slone, Manesh N. Sekharan
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Patent number: 8653174Abstract: The present invention provides a multicomponent composition that is substantially isocyanate-free and comprises a polycarbamate as a first component and a polyaldehyde or an acetal or hemiacetal thereof as a second component and further comprises an effective amount of a triggering agent such that the first and second components to cure at a temperature of from 0C to less than 80C to form a crosslinked polyurethane. The multicomponent composition forms an ambient temperature curable composition when all of its components are combined that has a pH of 7.0 or less. The present invention also provides processes crosslinked polyurethanes, and the crosslinked polyurethanes prepared by the processes.Type: GrantFiled: June 15, 2011Date of Patent: February 18, 2014Assignee: Dow Global Technologies LLCInventors: Jeffrey R. Anderson, John N. Argyropoulos, Debkumar Bhattacharjee, Paul Foley, Gary E. Spilman, Huiqing Zhang
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Patent number: 8592518Abstract: The present invention provides thermosetting aqueous binder compositions of one or more cyclic enamine, including bis-enamines and di- or higher functional enamines, optionally containing a water soluble or dispersible or dispersible primary amine compound. The binders are at least substantially formaldehyde free, need no polycarboxylic or polycarboxylate component, and yet provide excellent hot wet tensile strength when cured for as little time as a minute or less in use.Type: GrantFiled: June 3, 2011Date of Patent: November 26, 2013Assignees: Dow Global Technologies LLC, Rohm and Haas CompanyInventors: Brad Bailey, William C. Finch, Hyun K. Jeon, Charles James Rand, Robert L. Sammler, Francis J. Timmers, Barry Weinstein
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Patent number: 8461253Abstract: Disclosed are coating compositions that can be one-component, ambient curable, and waterborne. The coating compositions comprise acrylic copolymer resin particles comprising carbonyl functional groups and a crosslinking agent comprising functional groups, such as hydrazide groups, that are reactive with carbonyl groups.Type: GrantFiled: January 15, 2010Date of Patent: June 11, 2013Assignee: PPG Industries Ohio, Inc.Inventors: Ronald R. Ambrose, Mark S. Gaston, Brian K. Rearick, Irina G. Schwendeman, Venkateshwarlu Kalsani, Hongying Zhou, Michael J. Ziegler
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Publication number: 20120316270Abstract: The present invention provides manufacturing of and the use of novel diethylene tricarbamide and its condensation reaction products formed by reacting with formaldehyde as wood composite binder resins and in other applications. These resins have thermosetting capabilities and therefore usefulness as binders for wood and other materials with superior resin properties of low cost, colorlessness, exceptionally good binding, and fast curing characteristics, as well as very low formaldehyde emissions. The synthesized novel starting material for the thermosetting resins of the present invention is diethylene tricarbamide.Type: ApplicationFiled: April 27, 2012Publication date: December 13, 2012Inventor: Moon Kim
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Patent number: 8133933Abstract: Phenolic resin binder systems for sand molds, used in metal casting, which improve the quality of thermally reclaimed sand, are described. The substantial or complete elimination of calcium compounds (e.g., calcium stearate and calcium hydroxide, conventionally employed as a mold lubricant and a resin curing catalyst, respectively) allows the thermally reclaimed sand to be reused over multiple thermal reclamation cycles without the adverse effects previously encountered.Type: GrantFiled: August 11, 2006Date of Patent: March 13, 2012Assignee: Georgia-Pacific Chemicals LLCInventors: Richard Rediger, Edward Lucas
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Publication number: 20110313091Abstract: The present invention provides a multicomponent composition that is substantially isocyanate-free and comprises a polycarbamate as a first component and a polyaldehyde or an acetal or hemiacetal thereof as a second component and further comprises an effective amount of a triggering agent such that the first and second components to cure at a temperature of from 0 C. to less than 80 C. to form a crosslinked polyurethane. The multicomponent composition forms an ambient temperature curable composition when all of its components are combined that has a pH of 7.0 or less. The present invention also provides processes crosslinked polyurethanes, and the crosslinked polyurethanes prepared by the processes.Type: ApplicationFiled: June 15, 2011Publication date: December 22, 2011Applicant: DOW GLOBAL TECHNOLOGIES LLCInventors: John N. ARGYROPOULOS, Debkumar Bhattacharjee, Paul Foley, Gary E. Spilman, Huiqing Zhang
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Publication number: 20110306726Abstract: The present invention provides thermosetting aqueous binder compositions of one or more cyclic enamine, including bis-enamines and di- or higher functional enamines, optionally containing a water soluble or dispersible or dispersible primary amine compound. The binders are at least substantially formaldehyde free, need no polycarboxylic or polycarboxylate component, and yet provide excellent hot wet tensile strength when cured for as little time as a minute or less in use.Type: ApplicationFiled: June 3, 2011Publication date: December 15, 2011Inventors: Brad C. BAILEY, Robert L. Sammler, Francis J. Timmers, Hyun K. Jeon, William C. Finch, Charles J. Rand, Barry Weinstein
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Patent number: 8076409Abstract: The present invention provides a dispersant and compositions thereof. The dispersant is a residue of a non-aromatic hydrocarbyl substituted carboxylic acid containing three or more acid groups (A), wherein the dispersant may be represented by the Formula and salts thereof: [U—(Y)x-T-N(R1)c-A]d-Z(Q1)j-Wc, wherein the variables are defined herein.Type: GrantFiled: December 5, 2006Date of Patent: December 13, 2011Assignee: Lubrizol LimitedInventors: Dean Thetford, Neil L. Simpson
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Publication number: 20110301286Abstract: An additive comprising a phosphazene compound that has at least two reactive functional groups and at least one capping functional group bonded to phosphorus atoms of the phosphazene compound. One of the at least two reactive functional groups is configured to react with cellulose and the other of the at least two reactive functional groups is configured to react with a resin, such as an amine resin or a polycarboxylic acid resin. The at least one capping functional group is selected from the group consisting of a short chain ether group, an alkoxy group, and an aryloxy group. Also disclosed are an additive-resin admixture, a method of treating a wood product, and a wood product.Type: ApplicationFiled: May 27, 2011Publication date: December 8, 2011Applicant: BATTELLE ENERGY ALLIANCE, LLC.Inventors: Mason K. Harrup, Harry W. Rollins
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Patent number: 7872088Abstract: Disclosed are binders including urea-extended phenol-formaldehyde alkaline resole resins to which melamine-containing resin has been added, and non-woven fiber compositions made therewith. The disclosed binders may be cured to low formaldehyde-emission and low trimethylamine-emission, water-resistant thermoset binders.Type: GrantFiled: February 15, 2007Date of Patent: January 18, 2011Assignee: Knauf Insulation GmbHInventors: William S. Miller, Brian L. Swift, Scott L. Stillabower
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Patent number: 7781521Abstract: This invention provides methods for producing furfural-urea resins and adhesives. The includes dissolving urea in hot water to produce a hot aqueous solution, mixing furfural with the aqueous solution, adding an acid catalyst such as maleic anhydride to the furfural containing aqueous solution upon which a resinification reaction begins immediately. The resinification reaction is quenched by cooling to a pre-selected temperature to produce a resin or adhesive.Type: GrantFiled: June 29, 2007Date of Patent: August 24, 2010Assignee: Infinity Wood Ltd.Inventors: Marc Henry Schneider, Jonathan Greer Phillips
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Patent number: 7759436Abstract: Film-forming materials include nonionic metal coordinating structures. Nonionic metal coordinating structures can coordinate metals, such as metal catalysts and metal substrates. Example film-forming materials can be the product of a poly-functional epoxide and a nucleophilic ligand having a nonionic metal coordinating structure, or the product of a poly-functional alcohol and an electrophilic ligand having a nonionic metal coordinating structure.Type: GrantFiled: October 26, 2006Date of Patent: July 20, 2010Assignee: BASF Coatings GmbHInventors: Timothy S. December, Sergio Gonzalez, Günther Ott, Karl-Heinz Grosse-Brinkhaus
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Publication number: 20100105272Abstract: Provided is thermosetting urea-formaldehyde (UF) resin binder formulation, preferably prepared with modified styrene-maleic anhydride. The formulation has a viscosity in the range of from 3 to 10 cP and a surface tension of from 35 to 50 mN/m, and is prepared using a UF resin composition exhibiting a viscosity of from 175 to 250 cP.Type: ApplicationFiled: December 30, 2009Publication date: April 29, 2010Inventors: Souvik Nandi, Guodong Zheng, Jawed Asrar, Philip Francis Miele
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Patent number: 7572848Abstract: A coatable composition that comprises water, a film-forming organic polymer, and a leveling agent comprising an anionic species represented by the formula wherein Rf represents a perfluoroalkyl group having from 4 to 6 carbon atoms, and R represents H or an alkyl group having from 1 to 18 carbon atoms.Type: GrantFiled: December 21, 2005Date of Patent: August 11, 2009Assignee: 3M Innovative Properties CompanyInventors: Patricia M. Savu, Michael J. Parent, William M. Lamanna
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Publication number: 20090186981Abstract: The present invention provides a composition containing a particulate solid, an organic medium and/or water and a compound of Formula (1) and salts thereof. Formula 1 wherein R is H or C1-30-optionally substituted hydrocarbyl; or R may be R?C—O (an acyl group where R? is hydrogen, alkyl, aryl or an optionally substituted alkyl or aryl); U is oxygen, —NH or —NR??; R?? is a C1-30-optionally substituted hydrocarbyl Y is C2-4-alkyleneoxy; T is the residue of substituted acetic acid or propionic acid; Z is the residue of a polyamine and/or polyimine; W is the residue of an oxide, urea or dibasic acid or anhydride thereof, or mixtures thereof; x is from 2 to 90; and v represents the maximum available number of amino and/or imino groups in Z which does not carry the group R—U—(Y)x-T-.Type: ApplicationFiled: December 6, 2005Publication date: July 23, 2009Applicant: Noveon Inc.Inventor: Dean Thetford
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Publication number: 20080308242Abstract: Storage-stable glyoxalated polyacrylamide polymers and high solids aqueous compositions formulated with them are described. These glyoxalated polyacrylamide compositions can be used as additives for papermaking, providing paper with good dry and temporary wet strength, and increasing papermaking de-watering rates.Type: ApplicationFiled: June 13, 2008Publication date: December 18, 2008Applicant: BUCKMAN LABORATORIES INTERNATIONAL, INC.Inventors: Chen Lu, James Drew Ward
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Publication number: 20080277084Abstract: ASA sizing emulsions are described, as well as emulsifying agents containing starch and a terpolymer of acrylamide/quaternary ammonium compound/glyoxal, and an ASA blend that contains ASA and a co-surfactant blend of anionic surfactant and nonionic surfactant. Processes for sizing paper products with the emulsions are also described.Type: ApplicationFiled: May 8, 2008Publication date: November 13, 2008Applicant: BUCKMAN LABORATORIES INTERNATIONAL, INC.Inventors: Daniel H. Denowski, Manuel Ruiz, Walter B. Hill, JR.
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Publication number: 20080262144Abstract: The invention relates to aqueous, radiation-curable resins, to a process for preparing them, and to their use.Type: ApplicationFiled: August 23, 2003Publication date: October 23, 2008Applicant: DEGUSSA GMBHInventors: Patrick Glockner, Lutz Mindach
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Publication number: 20080160854Abstract: Provided is thermosetting urea-formaldehyde (UF) resin binder formulation modified with a thickener. The formulation preferably has a viscosity in the range of from 3 to 10 cP and a surface tension of from 35 to 50 mN/m, and is preferably prepared from a binder composition exhibiting a viscosity of from 175 to 250 cP.Type: ApplicationFiled: December 28, 2006Publication date: July 3, 2008Inventors: Souvik Nandi, Guodong Zheng, Jawed Asrar, Philip Francis Miele
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Patent number: 7087675Abstract: The ?-hydroxy carbamate, ethylenically unsaturated monomer of the invention can be polymerized as a homopolymer or copolymerized with other monomers. The polymerization can be carried out in an aqueous medium. The ?-hydroxy carbamate monomer is polymerized to form water-soluble homopolymers or, if polymerized as a mixture with one or more comonomers, copolymers that are soluble, emulsifiable, or dispersible in water. The ?-hydroxy carbamate monomer can be used as a replacement monomer for acrylamide.Type: GrantFiled: March 19, 2003Date of Patent: August 8, 2006Assignee: BASF CorporationInventors: Walter H. Ohrbom, Patricia A. Herrel
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Patent number: 6946504Abstract: Aqueous formulation for enhancing flowability and setting properties of gypsum, slurries, comprising wax, polyvinyl-alcohol and a sulphonated melamine polycondensate are used for imparting water repellency to gypsum wall boards.Type: GrantFiled: April 2, 2002Date of Patent: September 20, 2005Assignee: Walker Industries Holding LimitedInventor: Laurence Anthony Sinnige
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Patent number: 6815495Abstract: A coating solution for producing a cured coating, particularly for metallic surfaces, includes (1) a binder containing organic polymers with optional organic or inorganic addictions and (2) at least one of a melamine resin, an epoxy resin, a polyurethane resin, an alkyd resin, or mixtures thereof. The coating solution, in the liquid state, contains water. The binder contains 50-100% phenolic resin, preferably based on phenol and/or resorcinol.Type: GrantFiled: May 17, 2001Date of Patent: November 9, 2004Assignee: DaimlerChrysler AGInventors: Anita Marten, Daniela Maichel
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Patent number: 6765056Abstract: The aqueous-based cross-linkable binder composition comprising (A) an aqueous dispersion of an aldehyde-functional polyurethane having a number average molecular weight of more than 1,000 and an average aldehyde functionality of ≧2, which polyurethane comprises ionic and/or non-ionic dispersing groups, and (B) a low-molecular weight aldehyde-reactive cross-linker selected from the group of low-molecular weight polyamines and low-molecular weight compounds comprising at least one group of one of the formulae E1—CHR1—E2 and H—C—(E1E2E3), wherein —E1, —E2 and —E3 are independently chosen from electron-withdrawing groups such as —P(═O)—O—, —CO—, —CN, —SO2—, —NO2 and wherein R1 has the meaning of hydrogen or a hydrocarbon radical having 1 to 10 carbon atoms.Type: GrantFiled: August 13, 2001Date of Patent: July 20, 2004Assignee: Akzo Nobel N.V.Inventors: Klaus Hobel, Josephus Christiaan Van Oorschot, Keimpe Jan Van Den Berg
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Patent number: 6720392Abstract: An aqueous amino resin blend comprises aliphatic linear, branched or cyclic amines A containing at least one primary, secondary or tertiary amino group, at least one hydroxyl group and 2 to 20 carbon atoms, and amino resins B, and is used as an impregnating resin in the production of finished foils and edgings.Type: GrantFiled: May 6, 2002Date of Patent: April 13, 2004Assignee: Solutia Germany GmbH & Co. KGInventors: Frank Scholl, Johann Wonner, Wolfgang Scholz
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Patent number: 6706808Abstract: The presently disclosed invention relates to a phenolic binder comprising a premix of a urea modified phenol-formaldehyde resole resin, a curing agent, and an additive selected from the group consisting of ammonium lignosulfonate, melamine and a melamine derivative. A method for reducing gaseous emissions in the manufacture of fibrous insulation materials is also disclosed.Type: GrantFiled: August 3, 1999Date of Patent: March 16, 2004Assignee: Owens Corning Fiberglas Technology, Inc.Inventors: Yadollah Delaviz, Susan Muench, Kathleen Bullock
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Patent number: 6699943Abstract: The present invention is directed to a curable, water-based coating composition utilized in waterborne coating systems. The coating composition is the reaction product of a water-based copolymer prepared by free-radical polymerization, and a cross-linking agent. The copolymer is the reaction product of a first block and a second block. The first block is the reaction product of a first ethylenically unsaturated monomer, acrylic acid, and a second ethylenically unsaturated monomer, methyl methacrylate, as well as the reaction product of a vinylaromatic hydrocarbon monomer, diphenylethylene. The second block is the reaction product of a plurality of ethylenically unsaturated monomers, styrene, 2-ethylhexyl methacrylate, cyclohexyl methacrylate, and carbonate-modified glycidyl methacrylate including a carbonate functional group that is subsequently converted into a carbamate functional group by ammonium hydroxide.Type: GrantFiled: December 22, 2000Date of Patent: March 2, 2004Assignee: BASF CorporationInventors: Swaminathan Ramesh, Paul Lessek, Wolfgang Bremser
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Patent number: 6521700Abstract: Coating composition especially for preparing automotive surfacers, comprising a condensation product A of a carboxyl group-containing resin A1 and a hydroxyl group-containing resin A2, and a curing agent C, which becomes active only at elevated temperature of at least 80° C., and comprises a mixture of a water-insoluble blocked isocyanate C1 and a hydrophilically modified isocyanate C2.Type: GrantFiled: November 28, 2000Date of Patent: February 18, 2003Assignee: Solutia Austria GmbHInventors: Gert Dworak, Wrner Staritzbichler
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Patent number: 6518387Abstract: The present invention relates to a soybean-based adhesive resin including a soybean flour and a cross-linking agent. The cross-linking agent is reacted with the functional groups in the soybean flour to form an adhesive resin. The present invention also relates to a method of making a soybean-based adhesive resin. This method involves providing an aqueous solution of soybean flour and adding a cross-linking agent to the solution under conditions effective to cross-link the soybean flour so that an adhesive resin is formed. Also disclosed is a composite product which includes particulate plant material and the soybean-based adhesive resin. The adhesive is prepared by reacting the cross-linking agent with the functional groups in the soybean flour. The present invention also relates to a method of making a composite product by providing particulate plant material and applying the soybean-based adhesive resin to the particulate plant material.Type: GrantFiled: September 4, 2001Date of Patent: February 11, 2003Assignee: Iowa State University Research Foundation, Inc.Inventors: Monlin Kuo, Deland J. Myers, Howard Heemstra, Daniel Curry, Daniel O. Adams, Douglas D. Stokke
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Patent number: 6515042Abstract: Aqueous self-crosslinking copolymer dispersions ABC obtainable by free-radically initiated copolymerization in the first stage of a monomer mixture A comprising olefinically unsaturated monomers A1 having carbonyl groups, unsaturated carboxylic acids or monoesters of unsaturated dicarboxylic acids A2, monomers A3 selected from vinylaromatic compounds, n-butyl methacrylate and also alkyl esters of unsaturated carboxylic acids or dialkyl esters of unsaturated dicarboxylic acids, esters A4 selected from alkyl esters of unsaturated carboxylic acids of dialkyl esters of unsaturated dicarboxylic acids, and other free-radically polymerizable monomers A5, and subsequent addition of a second monomer mixture B and further polymerization in the second stage, the mixture B comprising olefinically unsaturated monomers B1 corresponding to A1, esters B2 corresponding to A4, and monomers B3 corresponding to A5, and subsequently adding compounds C having hydrazine or hydrazide groups.Type: GrantFiled: October 15, 1999Date of Patent: February 4, 2003Assignee: Solutia Austria GmbHInventors: Ingo Kriessmann, Rami-Raimund Awad, Hannelore Gsöll, Bernhard Hirschmann, Karl Rossmann
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Publication number: 20020147262Abstract: Aqueous self-crosslinking copolymer dispersions ABC obtainable by free-radically initiated copolymerization in the first stage of a monomer mixture A comprising olefinically unsaturated monomers A1 having carbonyl groups, unsaturated carboxylic acids or monoesters of unsaturated dicarboxylic acids A2, monomers A3 selected from vinylaromatic compounds, n-butyl methacrylate and also alkyl esters of unsaturated carboxylic acids or dialkyl esters of unsaturated dicarboxylic acids, esters A4 selected from alkyl esters of unsaturated carboxylic acids of dialkyl esters of unsaturated dicarboxylic acids, and other free-radically polymerizable monomers A5, and subsequent addition of a second monomer mixture B and further polymerization in the second stage, the mixture B comprising olefinically unsaturated monomers B1 corresponding to A1, esters B2 corresponding to A4, and monomers B3 corresponding to A5, and subsequently adding compounds C having hydrazine or hydrazide groups.Type: ApplicationFiled: October 15, 1999Publication date: October 10, 2002Inventors: INGO KRIESSMANN, RAMI-RAIMUND AWAD, HANNELORE GSOLL, BERNHARD HIRSCHMANN, KARL ROSSMANN
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Patent number: 6441122Abstract: Urea-extended phenol/formaldehyde alkaline resole binders suitable for fiberglass and having a high binding efficiency are disclosed. These binders are prepared by adding a minor quantity of melamine in an amount such that the binder solution contains no solid melamine particulates at room temperature. The resulting binders, when applied to fiberglass and cured, have a binding efficiency close to 100%, and further increase the recovery and physical properties of the binder-containing fiberglass product.Type: GrantFiled: January 5, 1995Date of Patent: August 27, 2002Assignee: Johns Manville International, Inc.Inventors: Gerard J. DeMott, Thomas John Taylor, Glenn S. Aspholm
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Patent number: 6309707Abstract: The present invention relates to a coating composition comprising at least three components, characterized in that component (I) contains as binder at least one acrylate copolymer which is dissolved or dispersed in organic solvent and has a number-average molecular weight of between 1000 and 30,000, an OH number of from 40 to 200 and an acid number of from 5 to 150 and/or polyester resin having a number-average molecular weight of between 1000 and 30,000, an OH number of from 30 to 250 and an acid number of from 5 to 150 and/or polyurethane resin having a number-average molecular weight of between 1000 and 30,000, an OH number of from 20 to 200 and an acid number of from 5 to 150, and, if desired, a further binder, the binder components being selected such that a 50% strength solution of the binder in ethoxyethyl propionate has a viscosity at 23° C. of ≦2.Type: GrantFiled: December 20, 1996Date of Patent: October 30, 2001Assignee: BASF Coatings AGInventors: Bernd Mayer, Uwe Meisenburg, Egbert Nienhaus
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Patent number: 6306947Abstract: An aqueous emulsion which comprises as a resin component a self-emulsifiable copolymer in which at least one ethylenically unsaturated monomer and at least one urethane prepolymer having at least one mercapto group and at least one hydrophilic, polar group are bonded by radical polymerization or in which at least one ethylenically unsaturated monomer, at least one organic polyisocyanate, at least one compound having at least one mercapto group and at least one active hydrogen-containing group and at least one compound having at least one hydrophilic, polar group and at least one active hydrogen-containing group are bonded by urethanization reaction and radical polymerization. The aqueous emulsion is better in storage stability than conventional ones.Type: GrantFiled: May 27, 1999Date of Patent: October 23, 2001Assignees: Nippon Polyurethane Industry Co., Ltd., Asia Industry Co., Ltd.Inventors: Takeshi Morishima, Shunsuke Murakami, Toshiaki Sasahara, Shin Konishi, Kazuya Sugimoto
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Patent number: 6300411Abstract: The present invention discloses an aqueous resin composition containing (A) a copolymer of (a) a monomer having one or more aldehyde groups or ketone groups, and a radical polymerizable unsaturated bond, in a molecule, with (b) a monomer having a radical polymerizable unsaturated bond copolymerizable with the monomer (a); (B) a hydrazine compound of the following formula (1) where R1, R2, R3 and R4 independently represent a hydrogen atom, or a hydroxyl group, p denotes an integer of 0 to 3, and q denotes an integer of 2 to 8, provided that the relationships p+q≦8 and p<q are satisfied; and an aqueous medium. When the aqueous resin composition of the present invention is applied and then dried, a film excellent in film intactness, transparency, whitening after water immersion, and adhesion after water immersion can be formed.Type: GrantFiled: March 19, 1999Date of Patent: October 9, 2001Assignee: Mitsubishi Chemical CorporationInventors: Toshiya Seko, Kazuhide Hayama, Yasuo Kitani, Kazumasa Kinugasa
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Patent number: 6284825Abstract: Solutions of aminotriazine resins at least 30 mol % of whose alkylol groups are etherified with a C1-C16 alkanol in a mono-C1-C4 alkyl glycol of the formula R1—O—(R2—O—)w(R3—O—)x(R2—O—)y(R3—O—)z H. I where R1 is C1-C4 alkyl, R2 is CH2—CH2 and R3 is and w, x, y and z are an integer from 0 to 10 and at least one of them is other than 0 or in a solvent mixture which consists to the extent of at least 20% by weight a of mono-C1-C4 alkyl glycol of the above formula.Type: GrantFiled: October 1, 1999Date of Patent: September 4, 2001Assignee: BASF AktiengesellschaftInventors: Wolfram Weiss, Gerhard Fischer, Manfred Niessner, Werner Schnurr
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Patent number: 6235826Abstract: Coating agent for producing an electric insulating coating on an electro steel sheet with good punching quality, weldability, annealing stability and high insulation resistance. Said agent comprises a metal organic and an organic film-forming agent and, optionally, chemically inert inorganic pigments and/or filler and other common additives such as antifoaming agents, leveling agents, catalyzers and the like.Type: GrantFiled: May 27, 1999Date of Patent: May 22, 2001Assignee: Herberts Austria GmbHInventor: Michael Wimmer
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Patent number: 6166111Abstract: An aqueous binder composition having a reduced tendency to yellow containingA) 20 to 95 wt-% of a water-dilutable organic polyol component that is present in the form of an aqueous solution or dispersion, contains one or more polymer-modified polyester resins which contain carboxylate groups and hydroxyl groups and has been prepared by the polymerization of olefinically unsaturated monomers in the presence of an unsaturated polyester resin that is copolymerized with the monomers andB) 5 to 80 wt-% of at least one heat-activatable cross-linking resin,wherein the percentages are based on the solids contents of components A) and B) and add up to 100%; and their use in heat-curable coating compositions.Type: GrantFiled: July 20, 1995Date of Patent: December 26, 2000Assignee: Bayer AktiengesellschaftInventors: Volker Schneider, Harald Blum, Lothar Kahl, Hans-Gunter Schmitz, Nusret Yuva
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Patent number: 6114434Abstract: Resins AB which are dilutable in water following neutralization and have an acid number of from 25 to 160 mg/g, obtainable by reacting mass fractions, based in each case on the sum of the masses of the solids in the reaction mixture, of A from 30 to 90% of at least one acid-functional polymer selected from polyesters, dimerized and oligomerized unsaturated aliphatic carboxylic acids and polymers of olefinically unsaturated monomers, each having an acid number of from 30 to 240 mg/g, and B from 10 to 70% of at least one water-insoluble aldehyde resin or ketone resin obtainable by condensing ketones, ketones together with aldehydes, ketones with urea or aldehydes with urea, having a hydroxyl number from 20 to 300 mg/g, a softening point of from 60 to 140.degree. C. and a number-average molar mass of from 500 to 3000 g/mol.Type: GrantFiled: October 6, 1998Date of Patent: September 5, 2000Assignee: Vianova Resins AGInventors: Peter Tuemmler, Gerald Hobisch, Hellmuth Kasch
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Patent number: 6028133Abstract: A phenolic resin modified with an alkali salt of sulfite or bisulfite in order to provide compatibility with a wax emulsion sizing agent, an adhesive prepared from the phenolic resin and wax emulsion, and the use of the adhesive in making bonded composites such as wood products, including, parallel strand lumber, oriented strand board (OSB), laminated veneer lumber (LVL), medium density fiberboard, wafer board and particle board, and textile products.Type: GrantFiled: March 20, 1998Date of Patent: February 22, 2000Assignee: Georgia-Pacific Resins, Inc.Inventors: Brian M. Peek, Barry W. Sewell
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Patent number: 6001925Abstract: Modified melamine-formaldehyde resins prepared by reacting melamine with formaldehyde at a F:M molar ratio in the range of about 1.55:1-2.5:1 under alkaline conditions, wherein the resin is prepared in the presence of about 1-10 wt % dicyandiamide and about 1-10 wt % sorbitol based on the total weight of resin solids. The resins are used to impregnate substrates in the preparation of decorative laminates. The laminates can be used to produce, for example, furniture, countertops or flooring.Type: GrantFiled: January 14, 1998Date of Patent: December 14, 1999Assignee: Georgia-Pacific Resins, Inc.Inventors: Benjamin D. Gapud, Mary K.A. Shoemake, Eric A. Searcy
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Patent number: 5976615Abstract: A curable coating composition is described comprising a carbamate functional material and a crosslinking agent, reactive with the carbamate group. The composition further comprises a third component that is a mixture of catalysts including a phosphorus containing acid or acid derivative and other acid catalysts. Coatings prepared with this coating composition can be cured and coated with additional coating(s), providing good intercoat adhesion to the subsequent coating.Type: GrantFiled: July 9, 1997Date of Patent: November 2, 1999Assignee: BASF CorporationInventors: Gregory G. Menovcik, John G. Partyka, Aimee R. Barach, Sanjay Mehta
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Patent number: 5962582Abstract: Hydrophilic, hydrolytically-stable synthetic resins obtainable by reacting a hydroxyl-functional synthetic resin such as a ketone, ketone/aldehyde and/or urea/aldehyde and/or a hydrogenated product of the hydroxyl-functional synthetic resin thereof with a polycarboxylic acid, polycarboxylic anhydride, polycarboxylic ester and/or polycarbonyl halide, where 70-100 mol % of the polycarboxylic acid and/or derivatives is linked chemically via an ester linkage to the hydroxyl-functional synthetic resin by way of only one single function and 0-30 mol % of the acid and/or acid derivative is so linked by way of more than one function.Type: GrantFiled: October 17, 1997Date of Patent: October 5, 1999Assignee: Huels AktiengesellschaftInventor: Hartwig Lange
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Patent number: 5908912Abstract: An electrodepositable coating composition is provided comprising (a) an active hydrogen-containing, cationic salt group-containing resin electrodepositable on a cathode; (b) a curing agent for transurethanation, transamidation or transesterification curing like at least a partially capped polyisocyanate curing agent; and (c) a catalytic mixture of bismuth and an amino acid or amino acid precursor. Optionally, an auxiliary acid may be present to increase the effectiveness of the amino acid in the mixture with bismuth.Type: GrantFiled: June 3, 1997Date of Patent: June 1, 1999Assignee: PPG Industries Ohio, Inc.Inventors: Raphael O. Kollah, Matthew S. Scott, Gregory J. McCollum, Joseph A. Bethoski
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Patent number: 5824725Abstract: A water soluble chemical composition for use as a soil stabilizer, conditer and structuring agent includes a dispersing agent such as a polyanionic sulfonated urea-melamine formaldehyde condensate, an aggregating agent such as a non-ionic water soluble urea-formaldehyde condensate having relative weight average molecular weights between 400 to 10,000 and polydispersity between 2.5 to 10, and a basic salt like di-sodium tetra borate and/or a neutral salt like sodium chloride and a nitrogen potassium or phosphorous containing compound such as potassium nitrate, phosphoric acid, potassium dihydrogen orthophosphate and the like, wherein the ratio of urea-formaldehyde to sulfonated urea-melamine-formaldehyde is between 0.2:1 to 2.0:1 and the final solid contents of this composition is between 1-15%. These compositions are then sprayed on top of sand or soil with conventional equipment and will impart significant improvements in their mechanical properties and their erosion resistance to water and wind.Type: GrantFiled: June 6, 1997Date of Patent: October 20, 1998Assignee: King Fahd University of Petroleum And Minerals Research InstituteInventor: Shawqui M. Lahalih