Abstract: Thermotropic liquid crystalline polymers are produced by the reaction of a polyester made from an aromatic dicarboxylic acid and a diol, one or more hydroxycarboxylic acids, a stoichiometric excess of an aromatic diol, and a carboxylic acid anhydride. Also disclosed are novel liquid crystalline polymers that may be produced by this process. These liquid crystalline polymers are useful as molding resins and shaped articles thereof are produced. In particular, the articles include films, sheets, containers and portions thereof comprising these LCPs.

Abstract: The present invention relates to a resin composition comprising a resin and apatite, wherein referring to the particulate form of said apatite present in the resin composition thus obtained, the apatite is present in a particulate form having an average diameter or average thickness (d) of not greater than 100 nm and an average aspect ratio (L/D) of not smaller than 5 as defined by the ratio of the average length (L) to said average diameter or average thickness (d).

Abstract: A polyester composition includes a ligand capable of coordinating to a metal or metal ion, wherein the ligand includes at least one donor atom selected from the group consisting of a nitrogen atom, a sulfur atom, and an oxygen atom. Consequently, it is possible to inactivate a metal catalyst which adversely affects heat resistance. As a result, it is possible to obtain polyester compositions and films having excellent heat resistance, colorability, and weathering resistance. Moreover, in the process of producing a polyester, by separating and recovering a catalyst by adding a ligand which is capable of coordinating to a metal or metal ion and which includes at least one donor atom selected from the group consisting of a nitrogen atom, a sulfur atom, and an oxygen atom, it is possible to improve the heat resistance of the polyester composition.

Abstract: An ink jet ink composition comprising water, a pigment, a humectant and a hyperbranched polymer having end groups consisting essentially of hydrophilic moieties, said hyperbranched polymer having the following formula: HB—Xg wherein: HB is a hyperbranched polymer core; X is a hydrophilic end group; and g is an integer of at least 2.

Abstract: The invention relates to aqueous crosslinkable binder dispersions comprising hydroxy-functional copolymers based on ethylene glycol monoallyl ether, to a process for preparing them and to the use of the dispersions in coating materials.

Abstract: Coating compositions based on nonlinear, low molecular weight, polyester-based polyols having low viscosity and high solids content made by reacting a branched, polyhydric alcohol having at least three hydroxyl groups, such as trimethylolpropane; a glycol or diol; and a compound selected from the group consisting of a aliphatic or aromatic dicarboxylic acid, C1–C6 alkyl ester, anhydride, diacid halide, or mixtures thereof. The nonlinear, polyester-based polyols are quite effective in maintaining a high solids content while lowering viscosity when blended with other coating resins, such as acrylic resins, making the coating resins more effective in cured coatings by improving flexibility, impact resistance and hardness without adversely affecting appearance, solvent resistance, and/or accelerated weathering. This invention also relates to the process of coating a substrate with these coating compositions.

Abstract: To provide a resin composition, in which a liquid crystal polymer is made into fiber in a molded article to exhibit an extremely high reinforcing effect which has not been available yet, and from which a molded article having an excellent mechanical strength can be manufactured in a stable manner. That is, a thermoplastic resin composition, wherein 100 parts by weight in total consisting of 99-50 parts by weight of a thermoplastic polyester resin (A) not forming an anisotropic molten phase and 1-50 parts by weight of a liquid crystal polymer (B) capable of forming an anisotropic molten phase is blended with 0.001-2.

Abstract: A pigment-based ink jet ink set and image-recording element combination is described, wherein the ink jet image-recording element has a gloss value of at least 5 when measured at 60°, and wherein each ink in the ink set has a normalized differential specular reflectance, N?RS(X), of less than 1.25. N?RS(X) is defined as the maximum value within a set of N?RS(Xn) values in which each N?RS(Xn) is the normalized specular reflectance for a density patch of a printed test image. The printed test image consists of a series of at least eleven density patches printed such that the ink laydown of the patches increases incrementally, from no ink laydown to a maximum level generating a density of at least 1.

Abstract: The present invention relates to the production of dispersions and is particularly suitable for making dispersions with a viscous or solid dispersed phase in a continuous phase with a lower viscosity.

Abstract: The invention relates to a thermosetting coating mass, comprising a carboxyl functional polyester, and/or a carboxyl functional polyacrylate, a ?-hydroxyalkylamide, in which a portion of the hydroxyl groups are chemically blocked and/or fillers and/or heat stabilisers and/or triboadditives and/or further additives, such as, for example, dispersing and degassing agents.

Abstract: An uncured epoxy adhesive comprising a resin component, a hardener component, and a microencapsulated accelerator component. The microencapsulated accelerator component comprises an infrared absorber, an accelerator and a wall that covers substantially the entire surface of the accelerator. The epoxy adhesive is cured by exposing it to infrared energy. The infrared energy is absorbed by the infrared absorber which disintegrates the wall and allows the accelerator to come into contact with the other adhesive components and initiate the curing polymerization reaction.

Abstract: A polyurethane composition comprising: A) from 3 to 35% by weight of a polymeric composition comprising 1) at least one polymer and 2) at least one thermoset in amounts of from 0.5 to 50% by weight, based on the sum of A1) and A2), prepared by reaction in the polymer matrix A1) of a) at least one starting component containing NH2 groups and b) at least one starting component containing NCO groups, a) and b) having simultaneously or independently a functionality of ?2 and at least one starting component having a functionality of >2 being present in amounts of from 0.5 to 100% by weight, based on the weight of A2); B) from 15 to 45% by weight in the polymeric composition A), based thereon, of at least one amorphous and/or crystalline polyester having an OH number of from 10 to 250 mg KOH/g; C) from 7 to 25% by weight in the polymeric composition A), based thereon, of at least one curing agent based on blocked polyisocyanates, isocyanurates and/or uretdiones having a functionality of at least 1.

Abstract: An aqueous dispersion based on an amorphous unsaturated polyester resin obtained by polycondensing a mixture of Dicidol isomers and one or more saturated and/or unsaturated dicarboxylic acids.

Abstract: Individual compounds that provide effective toning (or bluing) to combat yellowing within polyester articles (such as bottles, containers, and the like) are provided. Such a novel toner permits effective neutralization of yellowness while also providing highly desirable low haze and increased brightness due to a sharp absorption peak within the needed range of wavelengths (e.g., from about 565 to 590 nm) and a narrow half-height band width. Furthermore, such an individual compound is preferably liquid in nature and may thus be incorporated within an added ultraviolet absorber solution or shelf-stable dispersion to facilitate addition within target polyesters at various stages of production. The particular UV absorbers desired as additives within target polyesters also tend to exhibit certain yellowing effects that require attention as well. The inventive single bluing agent compound thus also accords effective neutralization of such UV absorber yellowing as well.

Abstract: Polymerized fatty acid-based polyamides may be combined with low polarity and high polarity co-solvents to produce homogeneous water-in-oil emulsions. These emulsions have the appearance of white or translucent creams, with stiffnessranging from soft and greasy, to hard and able to support weight. These emulsions are stable in the presence or absence of surfactant, and are formed easily by mixing components with heat and then cooling. These emulsions are useful in applications favoring an oil base, such as skin creams and cosmetics with emulsions of low stiffness, and car polish with emulsions of greater stiffness.

Abstract: A polyester resin composition containing a thermoplastic polyester resin; a polyester copolymer containing a monomer having at least one of an amino group, an imino group, an amido group, and a sulfonic acid group; a layered silicate; and an antioxidant. The monomer having at least one of an amino group, an imino group, an amido group, and a sulfonic acid group is contained in the polyester copolymer in an amount of 5 to 15 mol %. The monomer having at least one of an amino group, an imino group, an amido group, and a sulfonic acid group is contained in the polyester resin composition in an amount of 1 to 5 mol % based on a total polyester content of the polyester resin composition. The antioxidant is contained in the polyester resin composition in an amount of 0.01% to 1.0% by mass.

Abstract: The present invention is directed to a polymeric pigment dispersant to be used as a grind resin to incorporate pigment into a pigment dispersion for a coating composition. The polymeric pigment dispersant is the reaction product of dipentaerylthritol, hexahydrophthalic anhydride, glycidylneodecanoate, dimethylethanolamine, and polyphosphoric acid. The present invention is also directed to a method of preparing the polymeric pigment dispersant. In this method, the dipentaerythritol and the hexahydrophthalic anhydride are polymerized to form an intermediate compound. Next, an epoxy group of the glycidylneodecanoate reacts with the intermediate compound, and then the dimethylethanolamine salts the intermediate compound. Finally, the polyphosphoric acid is added to form the completed polymeric pigment dispersant. The polymeric pigment dispersant has improved stability in the pigment dispersion and is utilized for efficient wetting and grinding of the pigment in the pigment dispersion.

Abstract: The present invention relates to powdered thermosetting compositions including a binder which comprises a carboxyl group containing amorphous isophthalic acid containing polyester, a carboxyl group containing semi-crystalline polyester, at least 10 parts by weight, based on the total weight of the binder, of a specific glycidyl group containing acrylic copolymer and a curing agent having functional groups reactive with the polyesters' carboxyl groups. The powdered thermosetting compositions are useful for the preparation of powdered paints and varnishes which give low gloss coatings having an outstanding flow, a remarkable weatherability and excellent mechanical properties.

Abstract: An abradable dry powder coating (22) composition for coating onto a surface (12) for subsequent curing to form into an abradable coating, including a powder (16) formed of uncured thermoset resin with at least 15 volume percent filler, wherein the filler does not substantially melt below the cure temperature of the resin. Method for making the coating composition includes melt-mixing the thermoset resin with at least 15 volume percent of filler, cooling the resulting mass composite, and then breaking the cooled mass composite into powder particles (16). Method of coating an article with an abradable coating includes applying the dry composite powder with the filler therein onto a substrate and curing the dry powder composition, preferably by electrostatic coating. An article is also disclosed which is coated with the abradable coating.

Abstract: This invention relates to an UV stabilizing additive composition comprising an ortho-hydroxy triazine compound, a hindered hydroxybenzoate compound and optionally a hindered amine compound. This additive composition may be used to stabilize materials from UV radiation. This invention also contemplates a method of stabilizing a material by contacting the material with the UV stabilizing additive composition.

Abstract: Disclosed is a thermogelling biodegradable aqueous polymer solution useful in providing a bioactive agent delivery system. The present invention provides a thermogelling biodegradable aqueous polymer solution with a polyethylene glycol (PEG) block and a biodegradable polyester block, where the blocks are linked to form a polymer of a general structure comprising the formula of An(B), where n is greater than 2 and A is selected from the group consisting of a polyethylene glycol block and a biodegradable polyester block, B is selected from the group consisting of a polyethylene glycol block and a biodegradable polyester block, and A is different from B.

Abstract: An object of the present invention is to provide a liquid crystalline polyester resin composition to produce a molded article without generating black foreign materials even if exposed to high temperature. This object is achieved by providing a liquid crystalline polyester resin composition comprising a liquid crystalline polyester and at least one phosphite compound of the formula (I): wherein, R1 represents a hydrogen atom or, an alkyl group having 1 to 4 carbon atoms or a phenyl group, and R2 represents an alkyl group having 1 to 4 carbon atoms or a phenyl group.

Abstract: A polyester composition prepared by melting and blending a polyester with a glycidyl ester compound, a glycidyl ether compound and a catalyst has good hydrolysis resistance and, when melted, gives little gas generation and undergoes little viscosity change. It is most favorable for parts of automobile, electric and electronic appliances such as connectors.

Abstract: Excellent tracking index as well as flame-resistant properties are achieved with other desirable characteristics of LCPs in a resin composition consisting essentially of: a) a wholly aromatic polyester which is melt processible and which displays anisotropy in the molten state; b) a non-conductive filler material having a diameter of less than about 3 m, with said non-conductive filler material being present in an amount sufficient to increase the comparative tracking index (CTI) rating of said composition to above 220 volts and render the composition non-burning. Optionally, an extraordinarily small amount of non-volatile fluorescent brightener can be added to the resin composition. In combination with the non-conductive filler, the fluorescent brightener is found to surprisingly and significantly improves the flame-retardant property of the resin. Such compositions are advantageously employed in electrical and electronic apparatuses.

Abstract: Intaglio printing inks in paste form having both improved dispersibility and chemical resistance are provided and, in particular, dispersibility in tap water is provided in some formulations. The paste ink comprises an alkyd resin, having a degree of neutralization between about 10% and about 35% and an acid number between about 30 and 110, optionally containing an unsaturated oily component, an anionic or nonionic surfactant and an organic base selected from the group consisting of alcohol-amines, and substituted polyethyleneimines, wherein the substituted polyethyleneimines are modified with epichlorohydrine or alkoxylated and the organic base has a boiling point higher than 150° C. The ink may also comprise water.

Abstract: The present invention provides coating compositions that include reactive diluents and have high performance, low VOC levels, and low irritation levels. Certain embodiments of the present invention include water and water-dispersible polymers and other embodiments do not include water.

Abstract: The present invention is to provide an aqueous dispersion of polyester resin with an excellent molecular weight stability, its production method, and an aqueous coating composition. An aqueous dispersion of polyester resin having an acid value of 8 to 40 mg KOH/g and a weight average molecular weight of 9,000 or more contains an organic solvent less than 0.5% by mass. A method for producing the aqueous dispersion of polyester resin comprising a step of at first obtaining an aqueous dispersion of polyester resin containing not lower than 0.5% by mass of an organic solvent by adding the polyester resin and a basic compound to an aqueous medium to make the resulting mixture aqueous and a step of removing the organic solvent from the aqueous dispersion. An aqueous coating composition can be obtained by adding a curing agent to the foregoing aqueous dispersion of polyester resin.

Abstract: A coating solution for producing a cured coating, particularly for metallic surfaces, includes (1) a binder containing organic polymers with optional organic or inorganic addictions and (2) at least one of a melamine resin, an epoxy resin, a polyurethane resin, an alkyd resin, or mixtures thereof. The coating solution, in the liquid state, contains water. The binder contains 50-100% phenolic resin, preferably based on phenol and/or resorcinol.

Abstract: An aqueous dispersion of a segmental copolymer, wherein the aqueous dispersion has a Hard/Soft Balance Advantage value of at least 25% is disclosed. A method for preparing the aqueous dispersion of a segmental copolymer is also disclosed, as is a film produced thereby.

Abstract: An ink for ink jet recording which inclides a water-insoluble ionic group-containing polymer added to a colored fine particle dispersion containing at least a hydrophobic high-boiling organic solvent having a boiling point of 150° C. or more and an oil-soluble dye. In a preferred embodiment, the water-insoluble ionic group-containing polymer is converted by emulsification dispersion into a fine particle dispersion and added to the colored fine particle dispersion, and the oil-soluble dye is represented by specific formulae.

Abstract: A heat-transfer label is particularly well-suited for use on silane-treated glass containers of the type that are subjected to pasteurization conditions, regardless of whether the glass containers have been pre-treated previously with polyethylene, oleic acid, stearate or the like. The heat transfer label comprises (a) a support portion consisting of a sheet of paper or film overcoated with a layer of releasable material such as polyethylene and (b) a transfer portion over said support portion for transfer of the transfer portion from the support portion to an article, upon application of heat to the support portion, and placing the transfer portion in contact with the article.

Abstract: The present invention is directed to an aqueous dispersion of a polyester salt and polymeric vehicles which include the aqueous dispersions of a polyester salt. The polymeric vehicle is particularly effective for providing coating binders in cured primer coatings. The primer coating compositions are useful for multilayer paint coating films which have at least two layers of paint film including the cured primer coating composition film. The use of the primer polymeric vehicles of the present invention in conjunction with one or more additional overlaying top coating film layers provide a multiple layer coatings having improved adhesion and chip resistance.

Abstract: Acetoacetate-functional alkyd resins are disclosed, as are compositions including such resins in combination with at least one drier and an organic solvent. The acetoacetate-functional alkyd resin described is the reaction product of an alkyd resin with an alkyl acetoacetate. Also disclosed are methods of preparing such compositions, and uses for such compositions.

Abstract: An adhesion promoter additive contains at least one unsaturated, amorphous polyester containing 1) an acid component comprising at least one &agr;,&bgr;-unsaturated dicarboxylic acid, and 2) an alcohol component. The alcohol component contains at least 5% of a dicidol mixture of the isomeric compounds a) 3,8-bis(hydroxymethyl)tricyclo[5.2.1.02,6]decane, b) 4,8-bis(hydroxy-methyl)-tricyclo[5.2.1.02,6]decane and c) 5,8-bis-(hydroxymethyl)tricyclo[5.2.1.02,6]decane. Each isomer is present in the dicidol mixture in a proportion of from 20 to 40% by weight. A sum of the isomeric compounds a)-c) is from 90 to 100% by weight.

Abstract: Liquid coating compositions having improved mar and scratch resistance are disclosed. The coatings generally comprise one or more particles that have been modified to render the particles more surface active. The improved resistance is achieved without affecting the appearance or mechanical performance of the coatings. Methods for using the coatings, and the substrates coated therewith, are also disclosed.

Abstract: A waterborne acetoacetate-functionalized alkyd coating composition is disclosed which includes an acetoacetate-functionalized alkyd resin, at least one drier, and water. The acetoacetate-functionalized alkyd resin is the reaction product of (i) an alkyd resin, and (ii) an alkyl acetoacetate. Also disclosed is a method of preparing a waterborne acetoacetate-functionalized alkyd coating composition which includes the step of contacting an acetoacetate-functionalized alkyd resin with at least one drier in the presence of water.

Abstract: Vinyl monomers having polyenic side chains derived from highly unsaturated fatty acids represented by the general formula: R1COOH wherein R1 is a C19-24 hydrocarbon having 5 or 6 unsaturated bonds, and the derivatives thereof. Vinyl monomers having polyenic side chains derived from highly polyunsaturated fatty acids and the polymers of said monomers can be provided. In addition polymers having double bonds in the side chain into which various functional groups can be introduced can be provided. Useful utilization of fatty acid esters remaining as the residue in distillation of fish oil can be provided.

Abstract: An ink for an ink jet includes a coloring composition comprising a dispersion medium and coloring particulates containing an oil-soluble dye represented by formula (1) and a polymer selected from the group consisting of polyurethanes, polyesters, polyamides, polyureas and polycarbonates. The formula (1) satisfies at least one of following (i) to (v): (i) A represents —NR4R5, R4 and R5 each represents independently a C1-18 alkyl group having a substituent group; (ii) At least one of R2 and R7 represents a substituted alkyl group; (iii) R8 represents an aryl group having two or more substituent groups; (iv) Two or more substituent groups represented by —NR170SO2R171 are present in the molecule; and (v) One or more carboxyl groups are present in the molecule.

Abstract: A process for preparing an aqueous dispersion of pigment-containing polymer particles, comprising the steps of (A) removing an organic solvent from a mixture (I) comprising an organic solvent solution of a polymer, water and optionally a neutralizing agent to give a solvent-removed product; and (B) subjecting the solvent-removed product obtained in step (A) to a dispersion treatment, wherein a pigment is added to the mixture (I) or the solvent-removed product. The aqueous dispersion of pigment-containing polymer particles can be suitably used for a water-based ink for inkjet printing.

Abstract: The invention provides a matt, thixotropic paint formulation comprising a resin system and a matting agent. The matting agent comprises a hydrophobic metal oxide, which has a surface moiety (i.e., one or more surface moieties) selected from the group consisting of trimethyl silyl, vinyl dimethyl silyl, acryl dimethyl silyl, and dimethyl silyl. Morever, the paint formulation is characterized by having thixotropic properties such that it does not sag at a notch height of about 75 &mgr;m when measured with an anti-sag meter after application to a substrate. The invention also provides a method of producing such a paint formulation. The invention further provides a substrate having a surface coated with the matt, thixotropic paint formulation of the invention.

Abstract: The present invention provides a copolyester resin composition which has good physical properties, biodegradability and processability and a process for preparing and/or producing the same. To improve the biodegradability and physical properties of the copolyester, the present invention applied multi-stage reaction step, and copolyester resin having number average molecular weight of from 30,000 to 70,000, weight average molecular weight of from 100,000 to 600,000, melting point of from 55° C. to 120° C., and melt index of from 0.1 to 30 g/10 minute (190° C., 2,160 g) is obtained. The processability and physical properties of the copolyester resin of the present invention has been greatly enhanced by incorporating (i) an “aromatic-aliphatic prepolymers” having number average molecular weight of from 300 to 30,000 and the contiguous repeating unit of aromatic group in the dicarboxylic acid position of “aromatic-aliphatic prepolymers” is less than 5.

Abstract: An ink jet ink composition of water, a dye, a humectant and a hyperbranched polymer.

Abstract: An adhesion promoter additive contains at least one unsaturated, amorphous polyester containing 1) an acid component comprising at least one &agr;,&bgr;-unsaturated dicarboxylic acid, and 2) an alcohol component. The alcohol component contains at least 5% of a dicidol mixture of the isomeric compounds a) 3,8-bis(hydroxymethyl)tricyclo[5.2.1.02,6]decane, b) 4,8-bis(hydroxy-methyl)-tricyclo[5.2.1.02,6]decane and c) 5,8-bis-(hydroxymethyl)tricyclo[5.2.1.02,6]decane. Each isomer is present in the dicidol mixture in a proportion of from 20 to 40% by weight. A sum of the isomeric compounds a)-c) is from 90 to 100% by weight.

Abstract: Aqueous primary dispersion, substantially or completely devoid of volatile organic substances, method for the production thereof and use of the same Aqueous primary dispersion, substantially or entirely free of volatile organic compounds, and comprising dispersed and/or emulsified, solid and/or liquid polymer particles and/or dispersed solid core/shell particles with a particle diameter ≦500 nm, preparable by free-radical micro- or miniemulsion polymerization of at least one olefinically unsaturated monomer in the presence of at least one hydrophobic additive and of at least one oligomeric polyester with a number-average molecular weight of from 150 to 1 500 daltons, a hydroxyl number of from 100 to 1 000 mg KOH/g, and an acid number <20 mg KOH/g and also a process for preparing it and its use as a coating material, adhesive or sealing compound or to prepare a coating material, an adhesive or a sealing compound.

Abstract: The present invention relates to modified alkyd polymers, and compositions made from such polymers, wherein the alkyd polymers are modified with polyol-containing latex compositions and/or diol-containing latex compositions. The invention further relates to compositions prepared from such modified alkyd compositions.

Abstract: An aqueous binder composition containing a substantially infinitely water-dilutable or dispersible mixture of an epoxide and an epoxide crosslinking agent and the related method of its use for making glass fiber products, such as fiberglass insulation.

Abstract: Pastes containing flatting agents and/or texture additives, containing A) 5 to 30 wt. % of one or more thixotropic (meth)acrylic copolymers and/or one or more thixotropic polyesters B) 15 to 45 wt. % of one or more flatting and/or texturing agents, C) 30 to 65 wt. % of one or more organic solvents and optionally wetting and dispersing agents, rheology modifiers, catalysts and optionally further additives and auxiliaries, wherein the proportions of components A), B) and C) add up to 100 wt. % and the weight ratio of thixotropic (meth)acrylic copolymer and/or thixotropic polyester: flatting and/or texturing agents is 1:6 to 1:0.8.

Abstract: Self-crosslinking aqueous coating compositions are disclosed comprising a water-dispersible alkyd having both sulfonate and acetoacetate functionality, a suitable bi- or poly-functional primary amine, and a monofunctional primary or cycloaliphatic secondary amine. The crosslinking of the composition includes oxidative curing via the fatty acid segments of the alkyd, and crosslinking via reaction between the acetoacetate groups of the alkyd and the primary amine groups of the polyfunctional amine. The aqueous alkyd systems disclosed do not require the presence of amines for the purpose of dispersing the alkyds, while exhibiting superior tack-free and through-dry times when used in coating compositions. Performance levels are achieved that heretofore had required increases in molecular weight and Tg, with a concomitant increase in VOC levels. Also disclosed are methods of making the inventive compositions.

Abstract: The present invention provides a coating composition for producing difficult-to-wet surfaces, comprising i) at least one finely divided powder whose particles have a hydrophobic surface and a porous structure characterized by a BET surface area (determined in accordance with DIN 66131) of at least 1 m2/g, and ii) at least one film-forming binder characterized by a surface tension <50 mN/m, the weight ratio of powder to binder being at least 1:4. It also provides a process for producing difficult-to-wet surfaces, and provides for the use of the coating compositions for producing surfaces having a self-cleaning effect and for reducing the flow resistance for liquids in pipes.

Abstract: The invention concerns anti-static, peroxide-stable molding compounds on the basis of polyamides and/or polyesters, whereby the molding compounds are modified with very pure conductive carbon black with a low specific surface area. These anti-static molding compounds can be used for the production of injection-molded or extruded parts and the production of sheets or multi-layer hoses and tubes.