From Phenol Reactant Patents (Class 524/611)
  • Patent number: 5777009
    Abstract: A polyestercarbonate copolymer blend which exhibits a glass transition temperature lower than bisphenol-A carbonate homopolymer, shows improved processability and fire-retardancy. The desired lower Tg and improved flow can be achieved by the polycondensation of a dihydric phenol and aliphatic dicarboxylic acid. The condensate is polymerized with a carbonate forming reagent. The resin is fire-retarded with a mixture of halogenated polycarbonate, potassium diphenylsulfone sulfonate and polytetrafluoroethylene.
    Type: Grant
    Filed: October 25, 1996
    Date of Patent: July 7, 1998
    Assignee: General Electric Company
    Inventors: Wie-Hin Pan, Dwight J. Patterson, Omar M. Boutni, Luca P. Fontana
  • Patent number: 5762851
    Abstract: A method for producing a polycarbonate pellet which comprises subjecting a melt-extruded polycarbonate to a cooling step and a cutting step, the steps being carried out in either order or simultaneously, and wherein the cooling step is performed by contacting the polycarbonate with a cooling water having an electric conductivity of 1 mS/cm or less as measured at 25.degree. C.
    Type: Grant
    Filed: January 16, 1997
    Date of Patent: June 9, 1998
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Hiroshi Hachiya, Kyosuke Komiya
  • Patent number: 5717057
    Abstract: A method for manufacturing polycarbonate in which an aromatic dihydroxy compound and a carbonic acid diester can be effectively subjected to melt polycondensation using a small amount of a catalyst, making it possible to manufacture polycarbonate having outstanding color matching, outstanding thermal stability, color-matching stability, etc., during molding, and outstanding water resistance is characterized in that when an aromatic dihydroxy compound and a carbonic acid diester are subjected to melt polycondensation in the presence of a catalyst, the catalyst is dissolved or dispersed as a catalyst solution, this catalyst solution is added to the melt polycondensation reaction system, and the aromatic dihydroxy compound and carbonic acid diester are subjected to melt polycondensation.
    Type: Grant
    Filed: December 28, 1995
    Date of Patent: February 10, 1998
    Assignee: General Electric Company
    Inventors: Takeshi Sakashita, Tomoaki Shimoda, Takashi Nagai
  • Patent number: 5710206
    Abstract: A gel or gelloid composition contains (a) more than 50% by weight (based on total polymer content) of a block copolymer containing relatively hard blocks and relatively elastomeric blocks; (b) a polyphenylene ether; and (c) at least 500 parts by weight of an extender liquid per 100 parts by weight of the block copolymer, which liquid extends and softens the elastomeric blocks of the block copolymer. The polyphenylene ether is present in an amount sufficient to increase the softening or melting temperature of the gel or gelloid composition over that of the same composition without polyphenylene ether. The gel or gelloid composition is useful for sealing applications.
    Type: Grant
    Filed: March 4, 1996
    Date of Patent: January 20, 1998
    Assignee: Raychem Limited
    Inventors: Jane Valarie Francis, Noel Marchel Michiel Overbergh, Jan Lodewijk M. F. G. Vansant
  • Patent number: 5696201
    Abstract: A process which permits the production of mouldings which have little odor and comprise fibrous semifinished products to which heat-curing novolak resins have been added and which are suitable for lining heat-emitting and/or sound-emitting vehicle parts, in which their binders are completely and uniformly crosslinked. The odor emission, in particular the formaldehyde emission, is thus reduced. This process furthermore permits the production of products having an unusually large layer thickness. The homogeneous polymerisation reaction is achieved by the use of a hot fluid in the form of a dry, saturated steam and under elevated pressure.
    Type: Grant
    Filed: December 29, 1995
    Date of Patent: December 9, 1997
    Assignee: Matec Holding AG
    Inventors: Carlo Cavalloni, Antonio La Grotteria, Harald Freyer
  • Patent number: 5639806
    Abstract: Proppants comprising a particle coated with a composition comprising bisphenol-aldehyde novolak resin, a bisphenol homopolymer or mixtures including such polymers are disclosed. Foundry sands comprising a particle coated with a composition comprising bisphenol-aldehyde novolak resin, a bisphenol homopolymer or mixtures including such polymers are disclosed. Methods of making and using these proppant particles in subterranean formations or making and using these foundry sands in foundries are also disclosed.
    Type: Grant
    Filed: March 28, 1995
    Date of Patent: June 17, 1997
    Assignee: Borden Chemical, Inc.
    Inventors: Calvin K. Johnson, Kwok-tuen Tse
  • Patent number: 5637643
    Abstract: The present invention intends to provide a polycarbonate resin composition which can inhibit the deterioration of the resin, can stably afford molded articles having a high stiffness and a good appearance, and is desirable as a material of exterior automotive trims and the like.The polycarbonate resin composition which comprises 30 to 89% by weight of a polycarbonate resin (A), 10 to 50% by weight of an aromatic polyester resin (B), 0 to 50% by weight of a rubbery elastomer (C) and 1 to 30% by weight of a surface-treated talc, mica or a mixture thereof (D). If necessary, a phosphite antioxidant (E) is blended with a mixture of these components (A), (B), (C) and (D) in an amount of 0.01 to 5 parts by weight to 100 parts by weight of the mixture. The exterior automotive trims can be obtained by molding this polycarbonate resin composition.
    Type: Grant
    Filed: October 23, 1995
    Date of Patent: June 10, 1997
    Assignee: Idemitsu Petrochemical Co., Ltd.
    Inventors: Takashi Umeda, Teruhiko Nakazato
  • Patent number: 5612398
    Abstract: The present invention provides polycarbonates stabilized against .gamma.-radiation and their use for the production of medical equipment.
    Type: Grant
    Filed: January 12, 1995
    Date of Patent: March 18, 1997
    Assignee: Bayer AG
    Inventors: Gerhard Fennhoff, Ralf Hufen, Klaus Kircher, Wolfgang Ebert
  • Patent number: 5583174
    Abstract: Mixtures ofA) 75 to 99.5 wt. % of a high molecular weight, thermoplastic, aromatic polycarbonate with a molecular weight M.sub.w (weight average) of at least 10,000 which contains bifunctional carbonate structural units of the formula (I), ##STR1## in which R.sup.1 and R.sup.2, independently of each other, represent hydrogen, halogen, preferably chlorine or bromine, or a C.sub.1 -C.sub.8 -alkyl, C.sub.5 -C.sub.6 -cycloalkyl, C.sub.6 -C.sub.10 -aryl, preferably phenyl, or C.sub.7 -C.sub.12 -aralkyl, preferably phenyl-C.sub.1 -C.sub.4 -alkyl, in particular a benzyl group,m is an integer from 4 to 7, preferably 4 or 5,R.sup.3 and R.sup.4 can be selected separately for each X and, independently of each other, represent hydrogen or a C.sub.1 -C.sub.6 -alkyl group andX represents carbon,with the proviso that R.sup.3 and R.sup.4 simultaneously represent an alkyl group on at least one X atom.B) 0.5 to 15 wt.
    Type: Grant
    Filed: August 11, 1995
    Date of Patent: December 10, 1996
    Assignee: Bayer AG
    Inventors: Burkhard Kohler, Peter Bier
  • Patent number: 5550176
    Abstract: A room temperature setting carbonaceous cement comprising a solid carbonaceous material, a catalyst, a liquid carbonizable component, and copper particles, which when treated with the catalyst will provide a carbon yield of at least 40% for the liquid component at an elevated baking temperature and possess increased flexural strength at elevated temperatures and reduced electrical resistance.
    Type: Grant
    Filed: March 23, 1995
    Date of Patent: August 27, 1996
    Assignee: UCAR Carbon Technology Corporation
    Inventors: Irwin C. Lewis, Terrence A. Pirro, Ronald A. Greinke, Richard I. Bretz, Dennis J. Kampe
  • Patent number: 5548015
    Abstract: The invention is directed to a stable phenolic dispersion of hydrophilic phenolic resin polymer using polyvinyl alcohol as protective colloid. Incorporation of a small proportion of an etherified bisphenol-A resin into an aqueous solution of a phenolic resin and a protective colloid (e.g., polyvinyl alcohol) forms a stable dispersion with low volatile organics content.
    Type: Grant
    Filed: January 25, 1995
    Date of Patent: August 20, 1996
    Assignee: Georgia-Pacific Resins, Inc.
    Inventors: Ken A. Bourlier, Peggy S. Mulrenin
  • Patent number: 5532324
    Abstract: A copolymeric polycarbonate containing repeating constituent units having formula [I] below and repeating constituent units having formula [II] below in a molar ratio of from 98:2 to 40:60. ##STR1## The above-described copolymeric polycarbonates have excellent resistance to chemicals, heat resistance and flame retardancy without compromising the impact resistance and good hues intrinsic to polycarbonates.
    Type: Grant
    Filed: October 12, 1995
    Date of Patent: July 2, 1996
    Inventors: Takeshi Sakashita, Tomoaki Shimoda, Kotaro Kishimura
  • Patent number: 5532314
    Abstract: A stable aqueous adhesive composition based on a combination of a normally water-immiscible organo-functional silane and a phenolic resole wherein the silane is dispersed in a stabilized aqueous dispersion of a phenolic resole.
    Type: Grant
    Filed: May 3, 1995
    Date of Patent: July 2, 1996
    Assignee: Lord Corporation
    Inventor: Frederick H. Sexsmith
  • Patent number: 5502153
    Abstract: Object: The present invention was conceived in light of the above-described prior art. The object of this invention is to provide a method for preparing optical-grade polycarbonate compositions, which method is able to prepare with good productivity optical-grade polycarbonate compositions that have not only excellent clarity and water resistance, but also excellent retention stability such as heat stability and hue stability when molten and a low content of inclusions and impurities, and that undergo little heat deterioration.Constitution: The method for preparing optical-grade polycarbonate compositions according to this invention, which method comprises the melt-polycondensation of an aromatic dihydroxy compound and a diester carbonate in the presence of a catalyst, followed by the addition of additives B! while the polycarbonate A! obtained as the reaction product is in a molten state, and mixing.
    Type: Grant
    Filed: October 24, 1994
    Date of Patent: March 26, 1996
    Assignee: GE Plastics Japan Ltd.
    Inventors: Takeshi Sakashita, Tomoaki Shimoda, Kimiyoshi Miura, Kenichi Tominari, Akio Kanezawa
  • Patent number: 5470902
    Abstract: A resin composition containing 100 parts by weight of a mixture containing 20 to 70% by weight of a polyphenylene ether which is modified with an unsaturated carboxylic acid compound having an ethylenic double bond and a carboxyl group or an acid anhydride group in a molecule and 30 to 80% by weight of a polyamide which contains 100 parts by weight of 6,6-nylon and 10 to 100 parts by weight of 6-nylon, 0.1 to 3 parts by weight of a metal salt of montanic acid, and optionally 5 to 70 parts by weight of polypropylene per 100 parts by weight of the modified polyphenylene ether in the mixture, which composition is suitable for the production of automobile relay boxes.
    Type: Grant
    Filed: October 19, 1993
    Date of Patent: November 28, 1995
    Assignee: Sumitomo Wiring Systems, Ltd.
    Inventors: Yoshinobu Kubo, Masamitsu Chishima
  • Patent number: 5459226
    Abstract: The present invention is directed to a method for effecting the redistribution of polycarbonate and polycarbonate blends utilizing a tetraorganophosphonium carboxylate salt.
    Type: Grant
    Filed: July 27, 1994
    Date of Patent: October 17, 1995
    Assignee: General Electric Company
    Inventors: Joseph A. King, Jr., Patrick J. McCloskey, David M. Dardaris
  • Patent number: 5430076
    Abstract: A glass fiber strand for reinforcing a thermoplastic resin, consisting essentially of a strand of glass filaments having a sizing agent applied thereto and bundled, and an auxiliary resin capable of forming a polymer alloy with a main thermoplastic resin to be reinforced, coated on the surface of the strand.
    Type: Grant
    Filed: January 26, 1993
    Date of Patent: July 4, 1995
    Assignee: Asahi Fiber Glass Company Limited
    Inventors: Mitsuhiro Matsumoto, Akira Kitsunezuka, Hiroki Sato, Shigeharu Arai
  • Patent number: 5427998
    Abstract: A polycarbonate resin solution for forming a thermal-sublimating dye-receiving layer film, comprising a random copolycarbonate resin dissolved in an organic solvent, the resin having a structural unit represented by following formula (1) and a structural formula represented by following formula (2) or (3), the molar ratio of the structural unit represented by formula (1) to the structural unit represented by formula (2) or (3) being from 35/65 to 65/35, and having a number average molecular weight of from 5,000 to 50,000. ##STR1## wherein R.sup.1 to R.sup.12 each represents a hydrogen atom, a halogen atom, or an alkyl group having from 1 to 4 carbon atoms and in formula (1), A represents a straight chain, branched, or cyclic alkylidene group having from 1 to 10 carbon atoms, an aryl-substituted alkylidene group, an arylene group, or a sulfonyl group.
    Type: Grant
    Filed: June 20, 1994
    Date of Patent: June 27, 1995
    Assignee: Mitsubishi Gas Chemical Co., Ltd.
    Inventors: Toshikazu Umemura, Satoshi Kanayama
  • Patent number: 5420192
    Abstract: A resin composition containing 99-50 parts by weight of (A), a copolymeric polycarbonate having the constituent units described by formulas (1) and (2), hereinbelow, and in which the constituent unit in formula (2) accounts for 2-90 mole percent of the constituent units (1) and (2) and 1-50 parts by weight of (B) glass fiber having a mean fiber diameter of less than 10 .mu.m. ##STR1## where each R.sup.4 and R.sup.5 is independently a halogen atom or a monovalent hydrocarbon radical; B is --(R.sup.1 --)C(--R.sup.2)-- where each R.sup.1 and R.sup.2 is independently a hydrogen atom or a monovalent hydrocarbon radical, --C(.dbd.R.sup.3)-- where R.sup.3 is a divalent hydrocarbon radical, --O--, --S--, --SO--, or --SO.sub.2 --; R.sup.6 is a hydrocarbon radical with 1-10 carbon atoms, a halide thereof, or a halogen atom; and each p, q, and n is independently an integer ranging from 0 to 4.
    Type: Grant
    Filed: October 5, 1994
    Date of Patent: May 30, 1995
    Assignee: General Electric Company
    Inventors: Kenichi Ishiwa, Hideyuki Itoi
  • Patent number: 5391690
    Abstract: A process for producing a (co)polycarbonate or a (co)polyestercarbonate having a high molecular weight and excellent hue, heat stability and mechanical properties by reacting a dihydroxyl compound with a diester of carbonic acid and/or a diester of dicarbonic acid in the presence of a transesterification catalyst, wherein at least part of the reaction process is conducted in the presence of a specified organic phosphorus compound, or, in the presence of a specified organic phosphorus compound and a hindered phenol compound. A (co)polycarbonate or (co)polyester-carbonate composition having excellent hue, heat stability and mechanical properties, comprising a (co)polycarbonate and/or a (co)polyestercarbonate and, a specified organic phosphorus compound, or, a specified organic phosphorus compound and a hindered phenol compound.
    Type: Grant
    Filed: June 2, 1993
    Date of Patent: February 21, 1995
    Assignee: Daicel Chemical Industries,Ltd.
    Inventors: Tatsuya Kanno, Tsutomu Yamato, Yasuhiro Oshino, Yutaka Fukuda, Yoshihiro Iguchi, Takaaki Kuwana, Toshihiro Matsumoto
  • Patent number: 5391691
    Abstract: A process for producing an aromatic polycarbonate with improved heat resistance comprising melt polycondensing an aromatic diol compound and a carbonic acid diester compound in the presence of an interesterification catalyst and in the co-presence of an organosilicon compound.
    Type: Grant
    Filed: October 22, 1993
    Date of Patent: February 21, 1995
    Assignee: Mitsubishi Petrochemical Co., Ltd.
    Inventors: Masuzo Yokoyama, Kazuhide Takakura, Junji Takano
  • Patent number: 5389713
    Abstract: Polycarbonate resin compositions methods for their preparation are disclosed. The disclosed compositions are comprised of polycarbonate resins and .alpha.-olefin oligomers and exhibit good mold release and thermal stability while experiencing little discoloration or molecular weight reduction during molding.
    Type: Grant
    Filed: March 3, 1993
    Date of Patent: February 14, 1995
    Assignee: GE Plastics Japan
    Inventors: Kenichi Ishiwa, Hideyuki Itoi
  • Patent number: 5387628
    Abstract: A process for producing a (co)polycarbonate or a (co)polyestercarbonate having a high molecular weight and excellent hue, heat stability and mechanical properties by reacting a dihydroxyl compound with a diester of carbonic acid and/or a diester of dicarbonic acid in the presence of a transesterification catalyst, wherein at least part of the reaction process is conducted in the presence of a specified organic phosphorus compound, or, in the presence of a specified organic phosphorus compound and a hindered phenol compound. A (co)polycarbonate or (co)polyester-carbonate composition having excellent hue, heat stability and mechanical properties, comprising a (co)polycarbonate and/or a (co)polyestercarbonate and, a specified organic phosphorus compound, or, a specified organic phosphorus compound and a hindered phenol compound.
    Type: Grant
    Filed: September 9, 1993
    Date of Patent: February 7, 1995
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Tatsuya Kanno, Tsutomu Yamato, Yasuhiro Oshino, Yutaka Fukuda, Yoshihiro Iguchi, Takaaki Kuwana, Toshihiro Matsumoto
  • Patent number: 5364926
    Abstract: Object: The present invention was conceived in light of the above-described prior art. The object of this invention is to provide a method for preparing optical-grade polycarbonate compositions, which method is able to prepare with good productivity optical-grade polycarbonate compositions that have not only excellent clarity and water resistance, but also excellent retention stability such as heat stability and hue stability when molten and a low content of inclusions and impurities, and that undergo little heat deterioration.Constitution: The method for preparing optical-grade polycarbonate compositions according to this invention, which method comprises the melt-polycondensation of an aromatic dihydroxy compound and a diester carbonate in the presence of a catalyst, followed by the addition of additives [B] while the polycarbonate [A] obtained as the reaction product is in a molten state, and mixing.
    Type: Grant
    Filed: March 1, 1993
    Date of Patent: November 15, 1994
    Assignee: GE Plastics, Japan, Ltd. (GEP)
    Inventors: Takeshi Sakashita, Tomoaki Shimoda, Kimiyoshi Miura, Kenichi Tominari, Akio Kanezawa
  • Patent number: 5362783
    Abstract: A stabilizer composition containsa) a phosphine of the general formulaPR.sup.1 R.sup.2 R.sup.3 (I)wherein R.sup.1, R.sup.2 and R.sup.3 independently from each other represent an alkyl, cycloalkyl, aryl or alkyl-aryl group or an aryl group which is substituted at the aromatic ring with one or more halogens and/or one or more alkyl, hydroxy or alkoxy groups andb) a hindered phenol.The stabilizer composition is useful for stabilizing thermoplastic polymers against discoloration. Optionally an organic light diffuser mixed with the thermoplastic polymer. The stabilizer composition is particularly useful for stabilizing polycarbonate compositions.
    Type: Grant
    Filed: June 8, 1993
    Date of Patent: November 8, 1994
    Assignee: The Dow Chemical Company
    Inventors: Juergen Eiffler, Robin J. Lee
  • Patent number: 5357027
    Abstract: Disclosed is a novel polycarbonate which has(1) a repeating unit (I) represented by the general formula: ##STR1## and a repeating unit (II) represented by the formula: ##STR2## (all the symbols are as defined in the claims); (2) a trihalogenophenoxy group as the end group thereof; and (3) a viscosity average molecular weight of 10,000 to 50,000, and 1 to 10 mol % of the repeating unit (I) in the main chain.The polycarbonate is excellent in all of flame retardance, impact resistance, and a thermostability at molding. Accordingly, the polycarbonate of the present invention is extensively and effectively used as various industrial materials such as home electric appliances, office automation devices, construction materials and the like.
    Type: Grant
    Filed: September 30, 1992
    Date of Patent: October 18, 1994
    Assignee: Idemitsu Petrochemical Co., Ltd.
    Inventor: Takashi Komatsu
  • Patent number: 5344874
    Abstract: A process for producing a condensed resin dispersion, which comprises subjecting an aldehyde and a compound condensable with the aldehyde, or their precondensate, to a condensation reaction in a dispersion medium consisting essentially of water and/or an organic solvent, to precipitate fine condensed resin particles which hardly settle in said dispersion medium, and then replacing the water and/or the organic solvent by an active hydrogen-containing compound having at least two active hydrogen-containing groups reactive with isocyanate groups.
    Type: Grant
    Filed: July 8, 1991
    Date of Patent: September 6, 1994
    Assignee: Asahi Glass Company Ltd.
    Inventors: Takao Doi, Noriko Itaya, Masami Yamashita, Nobuaki Kunii
  • Patent number: 5326799
    Abstract: A polymeric composition having aromatic polycarbonate or aromatic polycarbonate like properties which process at significantly lower temperatures than aromatic polycarbonate in admixture with an additive which is incompatible with an aromatic polycarbonate at standard processing temperature.
    Type: Grant
    Filed: March 31, 1993
    Date of Patent: July 5, 1994
    Assignee: General Electric Company
    Inventors: Luca P. Fontana, Kenneth F. Miller, Edgar E. Bostick
  • Patent number: 5322874
    Abstract: Disclosed is an electroconductive resin composition comprising 100 parts by weight of a polyphenylene ether, 1 to 50 parts by weight of a diamide compound and 5 to 35 parts by weight of a carbon black having a dibutyl phthalate absorption of 70 ml/100 mg or more. This composition is excellent in electroconductivity, processability and heat resistance.
    Type: Grant
    Filed: November 23, 1992
    Date of Patent: June 21, 1994
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Takeshi Fujii, Manabu Ishikawa
  • Patent number: 5306801
    Abstract: The present invention relates to a polycarbonate production method. More specifically, it relates to a polycarbonate production method that is capable of preparing polycarbonates which have excellent residence stability such as hue stability and heat stability at the time of molding, and which have particularly outstanding water resistance.
    Type: Grant
    Filed: June 24, 1992
    Date of Patent: April 26, 1994
    Assignee: GE Plastics Japan, Ltd.
    Inventors: Takeshi Sakashita, Tomoaki Shimoda
  • Patent number: 5286834
    Abstract: A copolymeric polycarbonate containing repeating constituent units having formula [I] below and repeating constituent units having formula [II] below in a molar ratio of from 98:2 to 40:60. ##STR1## The above-described copolymeric polycarbonates have excellent resistance to chemicals, heat resistance and flame retardancy without compromising the impact resistance and good hues intrinsic to polycarbonates.
    Type: Grant
    Filed: September 14, 1992
    Date of Patent: February 15, 1994
    Assignee: GE Plastics Japan, Ltd.
    Inventors: Takeshi Sakashita, Tomoaki Shimoda, Kotaro Kishimura
  • Patent number: 5278254
    Abstract: A liquid crystalline polyester resin composition containing (A) a polyphenylene ether which is modified with at least one amine selected from the group consisting of primary amines and secondary amines; (B) a liquid crystalline polyester; and optionally (C) at least one oil selected from the group consisting of white oil and phenyl ether type oils, which composition has improved moldability and provides a molded article having improved weld strength while maintaining good heat resistance and mechanical properties of the liquid crystalline polyester.
    Type: Grant
    Filed: November 10, 1992
    Date of Patent: January 11, 1994
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Motonobu Furuta, Takanari Yamaguchi, Ichiki Murase
  • Patent number: 5278279
    Abstract: A process for producing a (co)polycarbonate or a (co)polyestercarbonate having a high molecular weight and excellent hue, heat stability and mechanical properties by reacting a dihydroxyl compound with a diester of carbonic acid and/or a diester of dicarbonic acid in the presence of a transesterification catalyst, wherein at least part of the reaction process is conducted in the presence of a specified organic phosphorus compound, or, in the presence of a specified organic phosphorus compound and a hindered phenol compound. A (co)polycarbonate or (co)polyester-carbonate composition having excellent hue, heat stability and mechanical properties, comprising a (co)polycarbonate and/or a (co)polyestercarbonate and, a specified organic phosphorus compound, or, a specified organic phosphorus compound and a hindered phenol compound.
    Type: Grant
    Filed: August 31, 1992
    Date of Patent: January 11, 1994
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Tatsuya Kanno, Tsutomu Yamato, Yasuhiro Oshino, Yutaka Fukuda, Yoshihiro Iguchi, Takaaki Kuwana, Toshihiro Matsumoto
  • Patent number: 5273685
    Abstract: A thermoplastic resin composition comprising (a) 100 parts by weight of thermoplastic copolycarbonate comprising 0.1 to 50% by weight of structural unit of the following general formula (1) and 99.9 to 50% by weight of structural unit of the following general formula (2): ##STR1## and (b) 0.1 to 30 parts by weight of electroconductive carbon black can produce a molding product having good mechanical properties and surface smoothness with good moldability.
    Type: Grant
    Filed: February 21, 1992
    Date of Patent: December 28, 1993
    Assignee: Mitsubishi Gas Chemical Co., Inc.
    Inventors: Toshiaki Takata, Tadami Kinugawa, Hideo Otaki
  • Patent number: 5258442
    Abstract: There is disclosed a polyphenylene sulfide resin composition which comprises: (a) 100 parts by weight of a polyphenylene sulfide resin; and (b) from about 0.1 to about 10 parts by weight of finely divided calcium carbonate having a mean particle size of less than about 0.5 .mu.m and a BET surface area of greater than about 15 m.sup.2 /g. The resin composition is improved in that it exhibits no or little corrosive action on metals and that it shows excellent mechanical strength.
    Type: Grant
    Filed: September 10, 1992
    Date of Patent: November 2, 1993
    Assignees: Tosoh Corporation, Toso Susteel Co., Ltd.
    Inventors: Toshikazu Kato, Yasuhisa Ogita, Kensuke Ogawara
  • Patent number: 5256728
    Abstract: Pigmented polycarbonate compositions which are substantially stable with respect to molecular weight and melt viscosity are prepared by blending a redistributed polycarbonate with titanium dioxide free from polysiloxane coatings (i.e., "unpacified" titanium dioxide).
    Type: Grant
    Filed: November 23, 1992
    Date of Patent: October 26, 1993
    Assignee: General Electric Company
    Inventors: David M. Dardaris, Gary R. Faler, Patrick J. McCloskey
  • Patent number: 5250655
    Abstract: An aromatic polycarbonate of improved color value and high molecular weight is obtained by the addition of phosphorous acid and/or a phosphorous ester to the melt polycondensation reaction medium containing aromatic diol, carbonate diester and a metal-containing compound as ester interchange catalyst during the polycondensation reaction
    Type: Grant
    Filed: August 24, 1992
    Date of Patent: October 5, 1993
    Assignee: Mitsubishi Petrochemical Company, Ltd.
    Inventors: Masuzo Yokoyama, Junji Takano, Kazuhide Takakura
  • Patent number: 5244999
    Abstract: A diamine or bismaleimide of the general formula I ##STR1## in which R.sub.1 and R.sub.2 denote an H atom or together denote the group --OC--CH.dbd.CH--CO--, Y.sub.1 and Y.sub.2 independently of one another denote O or S and Het denotes a thiazole, a thiadiazole or a 1-methyltriazole ring. The diamines and bismaleimides are used for the preparation of polyimides which are if appropriate reinforced with fibers and if appropriate incompletely hardened.
    Type: Grant
    Filed: September 30, 1992
    Date of Patent: September 14, 1993
    Assignee: Petrochemie Danubia Gesellschaft m.b.H.
    Inventor: Heinz Horacek
  • Patent number: 5242973
    Abstract: A polycarbonate resin composition comprising(a) 100 parts by weight of a polycarbonate comprising(1) a repeating unit (I) represented by the following formula: ##STR1## and a repeating unit (II) represented by the following formula: ##STR2## wherein X.sup.1 to X.sup.4 are each a halogen atom and (2) a trihalogenophenoxy group as the end group thereof, the polycarbonate having viscosity average molecular weight of 10,000 to 50,000, and 1 to 10 mol % of the repeating unit (I) in the main chain and(b) 0.01 to 0.2 part by weight of an alkali metal salt or an alkaline earth metal salt of an organosulfonic acid. The polycarbonate composition is excellent in all of flame retardance, impact resistance, and a thermostability at molding. Accordingly, the polycarbonate resin composition is extensively and effectively used industrially in home electric appliances, office automation devices, construction materials and the like.
    Type: Grant
    Filed: November 16, 1992
    Date of Patent: September 7, 1993
    Assignee: Idemitsu Petrochemical Co., Ltd.
    Inventor: Takashi Komatsu
  • Patent number: 5240986
    Abstract: The present invention relates to a polycarbonate resin composition comprising:100 parts by weight of a polycarbonate resin;(A) 0.05 to 1 part by weight of long chain aliphatic alcohol represented by the general formula: C.sub.n H.sub.2n+1 OH wherein n is 25 or more; and(B) 0 to 0.001 part by weight as phosphorus atom of at least one phosphorus compound selected from the group consisting of phosphorous acid and phosphorous acid estersThe composition of the present invention is excellent in heat resistance and hydrolytic resistance, and further has good mold releasing properties.
    Type: Grant
    Filed: August 23, 1990
    Date of Patent: August 31, 1993
    Assignee: Idemitsu Petrochemical Co., Ltd.
    Inventor: Kazunari Ohtsubo
  • Patent number: 5238985
    Abstract: The invention relates to thermoplastic compositions containing an effective internal lubricating amount of a branched guerbet alcohol derived ester having the formula ##STR1## wherein R is hydrogen, --CO--alkyl or --CO--alkenyl; each R' is independently alkyl or alkenyl, said alkyl or alkenyl radicals having from 5 to 25 carbon atoms; each R" is independently hydrogen, methyl or ethyl; m and n are each integers having a value of from 0 to 150; p is an integer having a value of from 4 to 12 and s is an integer having a value of from 2 to 36. The invention also relates to the molded or extruded product of said thermoplastic composition.
    Type: Grant
    Filed: May 2, 1990
    Date of Patent: August 24, 1993
    Assignee: Rhone-Poulenc Surfactants and Specialties, L.P.
    Inventor: Anthony J. O'Lenick, Jr.
  • Patent number: 5221709
    Abstract: This invention relates to a sealing composition for a mineral insulated electric cable termination. The sealing composition includes an inert filler such as silica flour, a low vapor pressure organic material such as a polyphenyl ether and an aerosil. This composition has improved slump resistance at high temperatures with little run out and no tendency to crack at 250.degree. C.
    Type: Grant
    Filed: October 8, 1991
    Date of Patent: June 22, 1993
    Assignee: Associated Electrical Industries Limited
    Inventors: Brian A. Irving, Robert J. W. Powell
  • Patent number: 5212255
    Abstract: Functionalized polyphenylene ethers made with graftable orthoester moieties, preferably the orthoester is 4-acryloyloxymethyl-2-methoxy-2-methyl-1,3-dioxolane monomer. The preferred method for grafting orthoester functionality onto polyphenylene ethers is by melt grafting. Once formed, these Polyphenylene ether graft orthoesters (PPE-g-OE) are useful as compatibilizers in blends of PPE with polyesters.
    Type: Grant
    Filed: April 3, 1992
    Date of Patent: May 18, 1993
    Assignee: General Electric Company
    Inventors: Farid F. Khouri, Robert J. Halley, John B. Yates, III
  • Patent number: 5212214
    Abstract: The present invention provides an inventive arylene sulfide coating composition which exhibits enhanced hardness, inertness, abrasion-resistance, and durability. The, inventive composition comprises an arylene sulfide polymer resin and a ceramic microsphere filler. The inventive coating composition can be applied to a substrate in order to improve the degradation resistance of the substrate and provide an article of manufacture well suited for use in high temperature, abrasive, and/or corrosive environments.
    Type: Grant
    Filed: May 7, 1991
    Date of Patent: May 18, 1993
    Assignee: Phillips Petroleum Company
    Inventor: Lyle R. Kallenbach
  • Patent number: 5206286
    Abstract: A stable aqueous polymer emulsion contains an aqueous continuous phase, a dispersed polymeric phase which comprises an acrylic polymer and a polyhydroxyl functional, non-ionic surfactant having a repeating polymer unit in the backbone and containing from 3 to 31 hydroxyl groups wherein the hydroxyl groups on the repeating polymer unit are separated by 4 or more carbon atoms and the surfactant is substantially free of oxyethylene units.
    Type: Grant
    Filed: July 11, 1991
    Date of Patent: April 27, 1993
    Assignee: PPG Industries, Inc.
    Inventors: Shanti Swarup, Gregory J. McCollum, Charles M. Kania
  • Patent number: 5204395
    Abstract: Flame retardant polyphenylene ether compositions are provided which utilize a silicone fluid treated filler, such as a clay or fumed titanium oxide treated with a polydiorganosiloxane fluid.
    Type: Grant
    Filed: December 11, 1991
    Date of Patent: April 20, 1993
    Assignee: General Electric Company
    Inventor: John H. Lupinski
  • Patent number: 5187208
    Abstract: A thermoplastic polycarbonate molding composition resistant to gamma-radiation is disclosed. The composition incorporates about 0.05 to 5.0 percent by weight of and end-capped poly(alkyl oxide) conforming to ##STR1## where hal denotes bromine or chlorine, n is about 10 to 40 and x is 1 to 5.The composition was found to be resistant to the yellowing which characterized polycarbonate compositions upon exposure to gamma radiation. The composition of the invention not only has low initial color change upon exposure but also a small change in yellowness after long term storing.
    Type: Grant
    Filed: November 6, 1991
    Date of Patent: February 16, 1993
    Assignee: Miles Inc.
    Inventor: Randall A. Rodenhouse
  • Patent number: 5164435
    Abstract: A stabilized thermoplastic resin composition is provided which comprises the following components (i), (ii) and (iii):(i) 100 parts by weight, based on the total amount of the following (A), (B) and (C), of a mixture comprising (A) about 10-100% by weight of a polyphenylene ether, (B) 0-about 90% by weight of an alkenyl aromatic resin, and (C) 0-about 90% by weight of a crystalline thermoplastic resin, total amount of (A) and (B) being at least about 15% by weight of the total amount of (A), (B) and (C),(ii) 1-50 parts by weight of an alkenyl aromatic elastomer (non-hydrogenated), and(iii) a stabilizer comprising (D) 0.01-5 parts by weight of a sulfur compound and (E) 0.01-5 parts by weight of at least one phenol compound.
    Type: Grant
    Filed: September 19, 1991
    Date of Patent: November 17, 1992
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Hiroomi Abe, Kenji Nagaoka, Yasuro Suzuki, Takashi Sanada
  • Patent number: 5162428
    Abstract: A phenolic resin composition comprising (a) 30-55% by weight of an alkylbenzene-modified novolac type phenolic resin, (b) 30-55% by weight of a novolac type phenolic resin and (c) 15-30% by weight of a dimethylene ether resole type phenolic resin, and a phenolic resin molding material comprising said composition.
    Type: Grant
    Filed: August 21, 1990
    Date of Patent: November 10, 1992
    Assignee: Sumitomo Bakelite Company Limited
    Inventors: Ken Katoh, Keiji Ooi
  • Patent number: RE34228
    Abstract: Modified benzylic ether resole resins and process for their preparation. The resins are prepared by treating a phenol with a molar excess of aldehyde in the presence of a divalent metal ion catalyst at a pH below 7 followed by further reaction at a pH above 8 in the presence of an alkaline catalyst. Alkaline solutions of the resins are used as foundry binders in an ester cure process.
    Type: Grant
    Filed: March 2, 1992
    Date of Patent: April 20, 1993
    Assignee: Acme Resin Corp.
    Inventors: David R. Armbruster, Merlyn C. Pasion