Abstract: Fire retardant plastic construction materials containing a fire retarding quantity of the oxidation product of certain asphalts.

Abstract: A composite material is provided comprising an elastomer, from about 0.1 wt % to about 15 wt. % of a layered mineral based on the weight of the total composition and from about 0.1 wt. % to about 15 wt. % of asphalt based on the weight of the total composition.

Abstract: A new stable liquid suspension of a non soluble particulate material, and a method of preparation of same are provided. Such compositions comprise at least one oil, one oil soluble resin and a non oil soluble particulate material mixed together In the appropriate quantities and conditions.

Abstract: Bitumen/polymer compositions with a broadened plasticity range are produced by stirring together a bitumen or bitumen mixture and a sulphur-cross-linkable elastomer as well as a sulphur-donating coupling agent at 100.degree.-230.degree. C. to give a cross-lined bitumen/polymer composition, stirring an acid or acid anhydride inorganic admixture into the composition at 100.degree.-230.degree. C., and maintaining the resulting reaction medium at 100.degree.-230.degree. C. while stirring for at least 20 minutes. Such bitumen/polymer compositions may be used directly or in dilute form to provide bituminous binders for road surfaces, coated materials and sealing coatings.

Abstract: A thermosetting asphalt composition includes a blend of an asphalt and an epoxy-functionalized polymer, the epoxy-functionalized polymer being present in an amount within the range of from about 4 to about 30 percent of the combination of asphalt and epoxy-functionalized polymer.

Abstract: A thermoplastic elastomer consisting essentially of a copolymer comprising a mixture of ethylene; one or more alpha-olefins having 3 to 12 carbon atoms; and, optionally, a diene, said copolymer being in an uncrosslinked state and having a crystallinity in the range of about 2 to about 40 percent by weight based on the weight of the copolymer wherein about 15 to about 85 percent by weight of the crystallinity melts at a temperature above 80.degree. C.; about 15 to about 85 percent by weight of the crystallinity melts at a temperature below 80.degree. C.; and the crystalline melting temperatures differ by at least about 30.degree. C.

Abstract: A bituminous mixture having improved physical properties is obtained by adding to a bitumen a polyphosphoric acid (I) containing phosphorus, calculated as P.sub.2 O.sub.5, in amount from 80% to 87% by weight, and a polymer composition (II) comprising (A) a propylene homopolymer or copolymer, (B) optionally an ethylene copolymer fraction insoluble in xylene at ambient temperature and (C) a copolymer fraction soluble in xylene at ambient temperature.

Abstract: A paving asphalt concrete composition consists essentially of an oil-impregnated vulcanized rubber crumb and an asphalt-aggregate mixture, in which the oil-impregnated vulcanized rubber crumb consist of 99-60% by weight of vulcanized rubber crumb and 1-40% by weight of an extending oil. This paving asphalt concrete composition is suitable for pavement of motorways, sidewalks, runways, taxiways, parking lots and the like.

Abstract: The present invention provides for a method of making storage stable road paving binders by blending a minor amount of a polymer having at least one diene monomer with a major amount of asphalt containing at least 0.3% by weight of total nitrogen at an elevated temperature such that the components are sufficiently fluid to blend; treating the asphalt-polymer blend using not more than 250 meq of a sulfonating agent per 100 g of asphalt-polymer blend to introduce the corresponding acid functionality into the blend; maintaining the sulfonated asphalt-polymer blend at a sufficiently elevated temperature and stripping the sulfonated blend with sufficient chemically unreactive gas to remove a major fraction of the acid functionality introduced by sulfonation. The invention also provides for the compositions made by the process. These are useful as binders in road paving applications.

Abstract: A flame retardant asphalt material useful for the processing and formation of a roofing membrane includes from about 40 to about 50 parts by weight of asphalt; from about 10 to about 20 parts by weight of a copolymer; from 0 to about 5 parts by weight of polypropylene homopolymer having at least about 45 percent by weight of crystallinity; from about 10 to about 40 parts by weight of a functional filler having a decomposition temperature above the processing temperature of the material; from about 0 to about 15 parts by weight of a non-functional filler; and, from about 0.5 to about 10 parts by weight of an intumescent material.

Abstract: Disclosed are compositions of a two-phase mixture of a structural bitumen component and a thermoplastic polymer derived predominantly of ethylene and at least one other non-cyclic alpha-olefin, wherein the polymer has a crystallinity of less than 18% and a solubility distribution index value of less than 28.degree. C. Also disclosed is a method for producing such compositions. Such compositions are particularly useful as road paving and construction materials.

Abstract: Blended polymer compositions are disclosed comprising an admixture of (a) a copolymer of ethylene and an alphaolefin and (b) an amorphous polypropylene, and/or amorphous polyolefin, or mixtures thereof.

Abstract: The invention relates to a method for improving the properties of bitumen, asphalt, or a similar material by adding to it a thermoplastic or a thermoelastomer, the solubility and compatibility of the thermoplastic or thermoelastomer being improved by a third component, which is wood resin, turpentine resin, a derivative of these, tall oil, tall-oil pitch, or a constituent or mixture of these. The obtained composition of bitumen, asphalt or a similar material can be used as a binding agent in road pavement materials.

Abstract: An asphalt material, useful for forming a membrane, comprises a mixture of from about 47 to about 74 parts by weight of asphalt, from about 7 to about 15 parts by weight of styrene-butadiene-styrene block copolymer, from about 15 to about 25 parts by weight of a filler component, and from about 1 to about 5 parts by weight of polypropylene homopolymer. A method for preparing a modified-asphalt material comprises the steps of forming a mixture by admixing from about 47 to about 74 parts by weight of asphalt; from about 7 to about 15 parts by weight of a styrene-butadiene-styrene block copolymer; from about 15 to about 25 parts by weight of a filler; and from about 1 to about 5 parts by weight of a polypropylene homopolymer; wherein the polypropylene homopolymer inhibits high temperature crosslinking of the styrene-butadiene-styrene block copolymer.

Abstract: This bitumen-polymer composition contains:a) at least one bitumen,b) at least one polymer having hydrocarbon chains with mobile hydrogens, said polymer being grafted and crosslinked in situ in said bitumen through a complex of at least one organic silicon compound, said complex being formed from a primary constituent and a secondary constituent, the latter being the organic silicon compound.

Abstract: Blended polymer compositions are disclosed comprising an admixture of (a) a copolymer of ethylene and an alphaolefin and (b) an amorphous polypropylene, and/or amorphous polyolefin, or mixtures thereof.

Abstract: This invention relates to a composition and method for improving the storage stability of an asphalt that contains a higher molecular weight polymer having a number average molecular weight of at least about 10,000 which comprises adding a storage stable improving amount of a polymerized alpha-olefin prepared from an alpha-olefin of the formula ##STR1## where R is C.sub.6 to C.sub.50 alkyl, R.sup.1 is hydrogen or C.sub.6 to C.sub.50 alkyl, wherein the polymerized alpha-olefin has a number average molecular weight of from about 500 to 5,000 and is characterized in that it has a congealing and melting point which is essentially no higher than the congealing and melting point of the alpha-olefin from which it is prepared.

Abstract: A mixture containing bitumen and a polymer composition, characterized in that the polymer composition comprises:A) 10-40 parts by weight of an isotactic propylene homopolymer, or a random copolymer of propylene with ethylene and/or a C.sub.4 -C.sub.10 .alpha.-olefin;B) 0-20 parts by weight of a copolymer fraction containing ethylene, which is insoluble in xylene at ambient temperature;C) 50-80 parts by weight of a copolymer fraction of ethylene with propylene and/or C.sub.4 -C.sub.10 .alpha.-olefin, said copolymer fraction being soluble in xylene at ambient temperature and having an intrinsic viscosity greater than 1.5 and up to 2.2 dl/g and having 20 to 45 wt. % ethylene.

Abstract: Disclosed in this invention are novel road paving binder compositions and the method of making same. The compositions are made by combining an asphalt that contains sulfonate or sulfonic acid groups, a polymer preferably of butyl rubbers, styrene-butadiene linear diblock polymer, styrene-butadiene-styrene linear or radial triblock polymer and EPDM that has been sulfonated, and mixtures thereof, and a basic neutralizing agent that contains cations having a valence from +1 to +3. The amounts of each are effective to allow formation of one continuous phase or two interdispersed phases that do not segregate on standing at elevated temperatures associated with road paving. The amount of polymer is an amount less than 7 wt. % of total polymer-asphalt composition that is sufficient to produce an asphaltic composition having a viscosity at 135.degree. C. in the range of from about 150 cPs to about 2000 cPs or from about 3000 cPs to about 8000 cPs.

Abstract: Disclosed in this invention are novel road paving asphaltic compositions having improved viscoelastic properties and storage stability and unexpected phase compatibility. They contain neutralized mixtures of oxidized asphalt and an acid functionalized polymer, which polymer is selected from the group consisting of sulfonated EPDM, sulfonated styrene-butadiene, and acrylic acid terpolymers, in an amount that is sufficient to result in an asphaltic composition having a softening point greater about 55.degree. C. and a viscosity in the range from about 150 cPs to 2000 cPs or from about 3000 cPs to about 8000 cPs at 135.degree. C. and effective to allow the formation of one continuous phase or two interdispersed phases that do not segregate on standing at elevated temperatures. The basic neutralizing agent used in these compositions contain cations having a valence of from +1 to +3, preferably +2. The invention also relates to the products produced by the process and method of making the compositions.

Abstract: An asphalt composition for use in road pavements is disclosed which comprises chiefly of an asphalt of natural or petroleum origin, a thermoplastic elastomer and/or a styrene-butadiene rubber and a low molecular weight polypropylene. These components are premixed or plant-mixed to form a reformed asphalt which is mixed with an aggregate to provide a paving material having increased compression strength, increased low temperature viscosity and decreased high temperature viscosity.

Abstract: Composition of waterproofing membrane suitable for being applied by means of hot bitumen both on a new covering and on a previous waterproofing layer based on blown bitumen, which is characterized in that it comprises 50 to 80% by weight of distilled bitumen, 8 to 20% by weight of amorphous ethylene-propylene and/or ethylene-propylene-butene 1 copolymer, and 5 to 15% by weight of amorphous polypropylene homopolymer, and optionally up to 40% by weight of a filler and/or up to 1% by weight of an antioxidant.

Abstract: A bituminous composition comprising a bituminous component, a polymer which comprises at least one block of a conjugated diolefin and at least one block of an acrylic monomer such as an alkyl methacrylate and from 0.001 parts to 1 part by weight of a polyfunctional amine having at least two amino groups. An acid or anhydride functionalized conjugated diene block copolymer may be used in place of the acrylic monomer polymer.

Abstract: A moisture-curable, substantially solvent-free and anhydrous blend of a bituminous material such as asphalt and a liquid prepolymer is disclosed, which blend when cured, results in an elastomer having excellent adhesion to surfaces exposed outdoors. The stability of the blend derives from asphalt being microdispersed in a dispersed phase within a continuous phase of the liquid prepolymer so that particles of asphalt are in the size range from 0.5 .mu.m to 100 .mu.m. The asphalt is treated to react all functional groups it may have because they may react with a functional group of the liquid prepolymer. The prepolymer is a polyurethane, a terpolymer of ethylene-propylene-diene, or a silicone. The microdispersion is stably maintained by a compatibilizer having opposed substantially polar and non-polar terminal portions, present in an amount in the range from 0.01 to 5 parts per 100 parts of the blend. The compatibilizer is chosen from (A) an ester of a C.sub.2 -C.sub.

Abstract: A bitumen/polymer component of the type consisting of a hydrocarbon matrix is provided in which a sulphur-crosslinked elastomer is distributed homogeneously in a quantity such that it presents 5% to 20% by weight of the bitumen/polymer component. The component exhibits a penetration, determined according to NF standard T 66004, and a ball-and-ring softening temperature, determined according to NF standard T 66008, such that the Pfeiffer number, which links these quantities, assumes values greater than 5 in the case of the bitumen/polymer component.

Abstract: An asphalt blend used for paving is described. The blend contains polyethylene which has been modified by shearing action in the presence of an O-containing gas (such as oxygen or ozone). The blend has improved viscosity at high temperatures and reduced stiffness at low temperatures. A paving mix prepared using the asphalt blend has an improved Marshall Test Value (ASTM DI559), indicating that the paving mix should have a reduced tendency to become rutted under the load of traffic.

Abstract: An asphalt pavement material comprising an aggregate mixture of asphalt, gravel, sand and a pelletized composite of recycled rubber and thermoplastic material. The pelletized composite has a uniform size, smaller than the gravel and larger than the sand and is configured to fit within interstitial voids between the gravel. Sufficient pelletized composite is added to the asphalt pavement and mineral aggregate mixture (replacing mineral aggregate of comparable size) to substantially fill void spaces between the gravel.

Abstract: This invention relates to polymeric compositions comprising unhydrogenated or substantially unhydrogenated sulfonated copolymers of (poly)styrene and a (poly)conjugated diene, e.g., (poly)butadiene or (poly)isoprene, preferably (poly)butadiene containing less than about 1.0 wt. %, preferably less than about 0.8 wt. % sulfur, preferably from about 0.2 to about 0.7, more preferably from about 0.22 to about 0.6 wt. % sulfur, as well as base-neutralized products thereof. The invention includes the polymeric compositions produced by the process of sulfonating unhydrogenated copolymers of (poly)styrene and a conjugated diene, e.g., (poly)butadiene or (poly)isoprene, preferably (poly)butadiene, which process optionally includes base neutralizing the sulfonated copolymer. This invention further relates to the process for making these novel copolymers comprising combining an unhydrogenated or substantially unhydrogenated copolymer of (poly)styrene and a conjugated diene, e.g.

Abstract: Paving binders, especially hot mix paving mixtures, having excellent storage stability, reduced binder runoff, and high temperature viscosity are formed by adding a copolymer of ethylene with an alkyl acrylate or vinyl acetate and a neutralized sulfonated polymer to the asphalt. Preferably, the alkyl acrylate is methyl acrylate and the neutralized sulfonated polymer is a terpolymer of ethylene, propylene, and a diene monomer.

Abstract: A bituminous binder emulsion is provided and is formed from a dispersion of an organic phase consisting of a bituminous binder in an aqueous phase incorporating an emulsifying system made up of one or more emulsifying agents, a water-soluble thickener and optionally, a pH regulating agent. The thickener which may be used to control the viscosity of the emulsion incorporates at least 40% scleroglucan by weight. The emulsion obtained may be used for road building applications, water-proofing in civil engineering or construction works, or for industrial purposes.

Abstract: A process for preparing bituminous mixtures with added thermoplastic polymer is described, the mixtures having storage stability and improved general properties.The process consists of treating the bitumen-polymer mixtures with an unsaturated dicarboxylic aliphatic acid or with the relative anhydride.

Abstract: Paving composition comprising a blend of specified bitumen and high vinyl butadiene, substantially free of added sulphur or peroxide, with elastic recovery greater than 50%.

Abstract: A composition for producing a water-proof sheet comprising 100 weight parts of a linear ethylene-alpha-olefin copolymer having a density equal to or less than 0.910 g/ml, and 10-200 weight parts of asphalt. Water proof sheets produced from the composition are also included in the invention.In a preferred mode, the composition also includes an organic peroxide.

Abstract: A process for the production of a binder modified with thermoplastic synthetic material and a modified binder for building materials, especially road construction type materials are provided, in which for the formation of the binder, molten bitumen together with a thermoplastic material mixture, preferably an olefin polymer, are subjected to a homogenization treatment. The mixture containing bitumen and the thermoplastic material is rapidly accelerated followed by rapid braking. By this acceleration there is supplied to the mixture containing the bitumen and a thermoplastic material, in the form of kinetic energy, an amount of energy corresponding to the difference between the treatment temperature and the disintegration temperature of the thermoplastic material to form readily reacting molecular fragments of the thermoplastic material.

Abstract: Polymer-modified bituminous compositions containing 0.5 to 20% by weight of polymer components, where 20 to 100% by weight of the polymer added is polyalkyl(meth)acrylate, which in synthesized from 50 to 99.8% by weight from C.sub.6 to C.sub.28 alkyl(meth)acrylates, 0.2 to 20% by weight from polymerizable carboxylic acids and/or sulfonic acids and 0 to 49.8% by weight from one or more other polymerizable, in particular nitrogen-containing compounds. Through the addition of reactive metal compounds, bituminous mixtures with improved elastic recovery, for example ranging from >50% to about 90%, with low temperature flexibility and high thermal stability are obtained.

Abstract: A bitumen/polymer composition is provided exhibiting an adhesiveness which is retained on storage at elevated temperatures. Also provided is a process for the preparation of such a composition and to the application of this composition to the production of coatings and in particular of road surface dressings, asphalt mixes or seal coatings.

Abstract: A thermoplastic resin composition comprising a thermoplastic resin (A) and a hydrogen donative material or Component (B) added in an amount of 0.01-40 weight parts per 100 weight parts resin (A), the hydrogen donative material having a transfer of hydrogen or at least 0.1 (hydrogen atoms/molecules anthracene). The composition further incorporates metal salts of aliphatic acid and/or hydrotalcites and a selected class of oxidation inhibitors.

Abstract: This invention relates to a composition and method for improving the storage stability of acid treated polymer modified asphalts. More specifically, the storage stability of an asphalt which contains greater than 1.0 wt. % polymer can be improved by adding a branched, rather than a non-branched, polymer to an asphalt which has previously been reacted with an inorganic acid. The storage stable acid treated branched polymer modified asphalt thus produced is particularly well suited for use as a binder in paving materials and as a coating or saturant for roofing shingles.

Abstract: Polymer compositions in the form of spheroidal particles with average diameter between 0.5 and 7 mm, comprising:A) 10-50 parts by weight of homopolymer of propylene with an isotactic index greater than 90 and an intrinsic viscosity from 0.5 to 1.5 dl/g;B) 50-90 parts by weight of propylene-ethylene copolymer containing 15-45% by weight of ethylene and having an intrinsic viscosity between 0.5 and 1.5 dl/g. The compositions are suitable for the modification of bitumens.

Abstract: This invention relates to a composition and method for improving the storage stability of polymer modified asphalts. More specifically, the storage stability of an asphalt which contains greater than 1.0 wt. % polymer can be improved by adding the polymer to an asphalt which has previously been reacted with an inorganic acid. The storage stable acid treated polymer modified asphalt thus produced is particularly well suited for use as a binder in paving materials and as a coating or saturant for roofing shingles.

Abstract: A composition for producing a water-proof sheet comprising 100 weight parts of a linear ethylene-alpha-olefin copolymer having a density equal to or less than 0.910 g/ml, and 10-200 weight parts of asphalt. Water proof sheets produced from the composition are also included in the invention.In a preferred mode, the composition also includes an organic peroxide.

Abstract: Asphalt cement compositions are disclosed which utilize petroleum asphalt, natural asphalt, a reactive oil and an elastomer. These compositions produce a superior asphalt cement that can give low viscosity during application followed by high viscosity, toughness and tenacity after curing on the highway.

Abstract: Properties and cold applicability of asphalt elastomer compositions are substantially improved by utilizing cyclohexanone therein as a co-solvent.

Abstract: Process for the production of a binder modified with synthetic material for building materials, especially street-building material, in which for the formation of the binder, molten bitumen together with a thermoplast or a thermoplast mixture, preferably an olefin polymer, is subjected to a homogenization treatment. To the mixture containing the bitumen and a thermoplast or a thermoplast mixture, there is supplied in the form of kinetic energy an amount of energy corresponding to the difference between the treatment temperature and the disintegration temperature of the thermoplast or thermoplast mixture to form readily reacting molecular fragments of the thermoplast or thermoplast mixture. Preferably, the mixture containing bitumen and the thermoplast or a thermoplast mixture is driven through a narrow gap between two mixing tools standing opposite to one another and rotating relatively to one another.

Abstract: A homogeneous composition for road surfacing contains a bitumen for road use and a quantity of a mixture of thermoplastic organic polymers of up to 20 parts by weight per 100 parts by weight of the bitumen, said mixture containing not less than 40% and up to 70% by weight of one or more polyolefins, the remaining percentage consisting essentially of polyvinylchloride, polyethylene terephthalate and polystyrene.This mixture of thermoplastic polymers can be obtained by recovering and recycling the plastics material contained in solid urban refuse or in industrial waste.

Abstract: Bitumen-polyolefin compositions, e.g. for use as binders in paving compositions, are stabilized by an emulsifier system comprising a polyethylene wax terminally functionalized with acidic groups and having a polymeric main chain structure which is compatible with the polyolefin of the dispersed phase of the binder. In a preferred embodiment, the emulsifier system also includes an inorganic metal compound which will react chemically with the terminal functional groups of the polyethylene wax. Especially preferred is maleated polyethylene wax (as the polyethylene wax) and ferric oxide (as the inorganic metal compound). The emulsifier system forms a sheath of inorganic material around the dispersed polyolefin droplets, to stabilize them and to hinder their floatation to the surface of the binder composition.

Abstract: A bituminous composition comprising a blend of bitumen, a polyolefin and a thermoplastic elastomer containing at least two polymer blocks wherein one of said polymer blocks is a crystalline polymer block and one of said polymer blocks is an amorphous polymer block is provided.The bituminous compositions of the invention have excellent low temperature flexibility and high temperature creep resistance properties and are particularly useful as a roof coating or waterproofing material or a road paving material.

Abstract: A composition useful as a pavement material comprising a mixture of asphalt and a polymer of an .alpha.-olefin, or an interpolymer of an .alpha.-olefin, and at least one copolymer selected from the group consisting of an .alpha.,.beta.-unsaturated carboxylic acid, a monomer of an .alpha.,.beta.-unsaturated carboxylic acid, a vinyl ester of alkanoic acid, and carbon monoxide.

Abstract: An adhesive composition for roofing such as shingles is disclosed which is composed of a hard asphaltic bitumen fraction having a penetration number at 77.degree. F. of from 0 to 30 dmm and a softening point of from about 150.degree. to 220.degree. F. and an elastomeric composition composed of a thermoplastic elastomer and a plasticizer wherein the overall adhesive composition has a penetration number of from 30 to 100 dmm at 130.degree. F. and a softening point of 140.degree. to 230.degree. F. The inventive composition is self-sealing and exhibits excellent squash resistance, low temperature properties and resistance to blowoff. The composition can be used with shingles as well as other types of roofing coverings.

Abstract: A bituminous composition comprising: (a) a bitumen, (b) a block copolymer of at least one conjugated diolefin and at least one vinyl aromatic hydrocarbon, and (c) a thermoplastic or low crystallinity polymer.