Abstract: The present invention provides a method for preparing an asphalt and thermoplastic elastomer composition. The process comprises heating an asphalt cut in a stirred tank to a temperature sufficient to allow the stirring of the asphalt in the tank. A thermoplastic elastomer or rubber is added to the asphalt while continuing to stir the asphalt. The mixture is stirred at a speed and for a period of time sufficient to increase the distribution of the elastomer into the asphalt. The stirring speed is reduced and the temperature is increased to add crosslinking agents to the tank. Stirring is continued for a period of time sufficient to improve the distribution of the crosslinking agent dispersion in the asphalt. Crosslinking agents include compositions of mercaptobenzothiazole, zinc oxide and elemental sulfur; compositions of mercaptobenzothiazole, zinc oxide, and mixed polythiomorpholine; and compositions of zinc 2-mercaptobenzothiazole and dithiodimorpholine.

Abstract: A modified asphalt composition is provided comprising at least one plastomer, at least one elastomer, and asphalt. More specifically, a modified asphalt composition is provided comprising an oxidized polyethylene, a styrene-butadiene-styrene block copolymer, and asphalt. A hot mix asphalt composition is also provided comprising the modified asphalt composition and aggregate. Processes for producing the modified asphalt composition and the hot mix asphalt composition is also provided as well as articles produced from these inventive compositions.

Abstract: The present invention discloses methods of making improved rubber modified asphalt cement compositions, and compositions made by the method, where the compositions are useful in paving, roofing, coating and other sealing applications. In one aspect, the method comprises combining asphalt, RVPR (or a blended mixture of asphalt and RVPR) and at least one dodecyl or tridecylbenzene sulfonic acid (SA), which can be linear (LAS) or branched (BAS), in the presence of moderate heat. After heating the resultant RMAC mixture exhibits at least one of the following: (1) an increase in softening point, (2) an increase in hardness, or (3) improved recovery from deformation. In another aspect, the invention teaches addition of at least one SA to previously manufactured RMAC to accomplish at least one of the following: (1) an increase in softening point, (2) an increase in hardness, or (3) improved recovery from deformation.

Abstract: Supported catalyst composition for polymerization of olefins comprising: (i) a titanium compound, a magnesium compound and at least one electron donor compound; (ii) a chlorine containing polymer support; and (iii) a cocatalyst comprising at least one aluminum compound, wherein the magnesium loading on the final catalyst is between about 0.20 and 6% by weight.

Abstract: The present invention provides a bitumen composition including: —(i) from 0.1 to 25% wt of an elastomer, (ii) from 0.1 to 40% wt of a solvent, (iii) from 30 to 99% wt of a bitumen, (iv) from 0.1 to 30% wt of a lithium salt of a C10–C40 fatty acid or hydroxy fatty acid, and optionally (v) from 0 to 70% wt of a filler, all weights based on total bitumen composition, wherein the solvent is of general formula (I), wherein R1 represents a hydrogen atom or a hydrocarbyl group having from 1 to 6 carbon atoms, R2 represents a hydrocarbyl group having from 1 to 6 carbon atoms, and the sum of the carbon atoms in R1 and R2 is from 5 to 7; a process of preparing said bitumen composition and the use of the composition as a cold-applicable adhesive.

Abstract: The present invention relates to compositions and methods for providing an improved means of modifying asphalt with a polymer. More particularly, this invention provides a solvent system that permits addition of the polymer as a liquid that is preferred over solids addition and handling. The solvent system includes a polymerizable monomer solvent and a rubber or elastomeric polymer.

Abstract: A composition and a method for protection of constructions and structures from chemical action and destructive environmental effects. The main components of the composition are a polymerizing monomer, inert mineral filler, and chemical additives for improvement of chemical and physical properties. The method includes preliminary energetic activation of 5% by weight of the whole composition mass, adding the activated part of the composition to its main mass, and application of the composition to the surface of material chosen from the group including concrete, asphalt concrete, metal, and wood to obtain the required surface protection.

Abstract: A method of selecting an asphalt binder for use in constructing a high modulus layer of bituminous pavement is provided. This method includes measuring the complex shear modulus of one or more binders at a temperature of not more than about 30° C., measuring the creep stiffness of one or more binders at a temperature near the lowest in-service temperature at the depth of the layer at which the bituminous pavement is being placed, and selecting an asphalt binder for the high modulus layer using the complex shear modulus and creep stiffness measurements. A further aspect of the present invention is a method of formulating an asphalt binder that has a desirable complex shear modulus and creep stiffness for use in making the high modulus layer. This method of formulation includes mixing a stiff asphalt binder and a soft asphalt binder together to form a binder having a complex shear modulus of at least about 2 MPa at 30° C.

Abstract: It has been discovered that certain nitrogen-containing thiols other than mercaptobenzothiazole (MBT) perform equivalently as accelerators in preparing asphalt polymer compositions. Typically, the crosslinker in these compositions is sulfur. Nitrogen-containing thiols containing at least one functional group —N?(SH)— have been found to be useful alternate accelerators along with activators such as zinc oxides. Particular nitrogen-containing thiols include, but are not necessarily limited to, 2-mercaptobenzoxazole (MBO), 2-mercapto-5-methyl-1,3,4-thiadiazole (MMTD), and combinations thereof.

Abstract: Disclosed is a bituminous composition that comprises a bituminous component (A), an elastomer component (B), preferably a block copolymer of a conjugated diene and a monovinylaromatic hydrocarbon, and an additive (C), wherein the additive is a compound of the general formula Ar—R—Ar??(I) wherein each “Ar” independently is a benzene ring or fused aromatic ring system of 6 to 20 carbon atoms, substituted by at least one hydroxyl group, and “R” is an optionally substituted divalent radical comprising 6 to 20 atoms in the backbone and at least one amide and/or ester group in the backbone. These compositions are disclosed to be particularly useful in the preparing and repair of roofing.

Abstract: The present invention provides a dispersing agent that facilitates the delivery of a cross-linking agent to polymer modified asphalt. The present invention further includes a composition comprising a liquid hydrocarbon, the dispersant and cross-linking agent, and methods of preparing the composition and of preparing cross-linked polymer modified asphalt composition.

Abstract: The present invention provides an asphalt additive comprising a tire rubber powder and a petroleum resin. This asphalt additive is used in preparation of a reformed asphalt and paving material, which is effective in reduction of noise from traffic, minimization of crevice from contraction of road in winter and plastic deformation of road in summer, prevention of traffic accidents due to slippery road when raining, and prevention of water curtain and splash. Further, the road structure employing the present invention is helpful for protection of water resource. Moreover, the present invention provides an asphalt composition (echophalt) using the asphalt additive, and a method for preparation of the asphalt composition and its application.

Abstract: Non thixotropic, aqueous emulsions prepared from rubber modified asphalt cement (RMAC). The RMAC is prepared by a method whereby recycled tire rubber is liquified or otherwise consumed by or incorporated into asphalt such that no more than 2% by weight of solid particulate rubber remains. The RMAC may be emulsified in an aqueous or partially aqueous emulsification solution using a one-step or multi-step emulsification process. These aqueous RMAC emulsions are useable in many applications including paving, seal coat, roofing and slurry seal applications.

Abstract: A modified asphalt and method for making the same is characterized by the addition of a partitioning agent to a polymer modifier material such as synthetic rubber to prevent reagglomeration of the rubber. The partitioning agent reduces the time required to disperse the modifier material in asphalt to be modified and also reduces the viscosity of the modified asphalt so that the modified asphalt is easier to handle.

Abstract: Provided is a vulcanizing agent for vulcanizing bitumen, which vulcanizing agent comprises a sulphur agent and a binder, wherein the vulcanizing agent is in the form of pellets. Further provided is a process for producing a surfacing composition, which process comprises contacting bitumen with an elastomer and the vulcanizing agent of the present invention.

Abstract: Compositions produced by forming a homogenous mass consisting of a bitumen matrix wherein a cross-linked and/or functionalized elastomer produced in situ from a precursor elastomer is dispersed in a uniform manner and makes up 0.5-30% of the weight of the bitumen matrix. The bitumen matrix is created by associating 95%-20 wt. % non oxidized bitumen having a penetrability of 20-900 and 5-80 wt. % oxidized bitumen having a penetrability of 10-90. The compositions can be used as bitumen binders in the production of coverings.

Abstract: We have found a novel spray-on adhesive composition made from components including a high melt index polymer and a high melt tackifier that interact to produce a composition that can form a low odor, light color, non-tacky, hot melt adhesive material that can be used in disposable article manufacture. The adhesive is thermally stable at hot melt application conditions, is low in cost, is easily applied and produces high quality disposable articles.

Abstract: The present invention provides an improved polymer additive which may be used to increase the high temperature viscosity of an asphalt, without deleteriously affecting the low-temperature viscosity of the asphalt. The polymer additive may also be used to improve the stiffness of certain asphalts. The polymer additive is produced from readily available polymer blends by a thermal process. The invention additionally provides an improved polymer modified asphalt. In its preferred embodiments, the invention also provides an environmentally acceptable method for recycle of post consumer carpet and bottles.

Abstract: A polymer modified asphalt is characterized by the addition of a carrier material such as mineral oil. The carrier material is mixed with an activator material and then added to a hot mixture of polymer and asphalt. The activator assists the polymer material in linking with the asphalt while the carrier prevents the formation of gel or lumps within the asphalt. The modified asphalt retains its rheological and solubility characteristics.

Abstract: The present invention relates to elastomeric compositions and methods including compositions and methods involving the use of aromatic alcohols. The present invention further relates to elastomeric compositions that can include ground reclaimed elastomeric particles. Compositions of the present invention are usable in numerous elastomeric applications including interior and exterior vehicle parts, roofing, asphalt, and any other applications that employ an elastomer as an ingredient thereof, particularly those utilizing rubber or a similar elastomer. The present invention further is directed to asphalt compositions and their methods of manufacture and use.

Abstract: A method for producing a thermoplastic filler for eliminating surface damage to concrete or asphalt surface is disclosed which includes mixing stone chips, sand, a powdered material and a bituminous binding agent to a homogenous mixture which is in constant motion at a temperature of between about 180° C.-2400° C., with a coolant being added subsequently to the mixture in a rapid manner thereby converting the mixture into a non-cohesive granulate of small pellets due to the high surface tension of the various constituents, and wherein the granulate can be heated to convert it to a free-flowing or spreadable filler having strong adhesive properties.

Abstract: The present invention provides a method for preparing an asphalt and thermoplastic elastomer composition. The process comprises heating an asphalt cut in a stirred tank to a temperature sufficient to allow the stirring of the asphalt in the tank. A thermoplastic elastomer or rubber is added to the asphalt while continuing to stir the asphalt. The mixture is stirred at a speed and for a period of time sufficient to increase the distribution of the elastomer into the asphalt. The stirring speed is reduced and the temperature is increased to add crosslinking agents to the tank. Stirring is continued for a period of time sufficient to improve the distribution of the crosslinking agent dispersion in the asphalt. Crosslinking agents include compositions of mercaptobenzothiazole, zinc oxide and elemental sulfur; compositions of mercaptobenzothiazole, zinc oxide, and mixed polythiomorpholine; and compositions of zinc 2-mercaptobenzothiazole and dithiodimorpholine.

Abstract: The invention comprises polymers which have been functionalized so as to be able to chemically react with polyamines to form adducts containing at least one or more groups consisting of amino, amido, imino, imido, or imidazloyl. Furthermore, the invention teaches processes to prepare these adducts by solution, melt or in-situ methods. A further embodiment of the invention pertains to the use of polyolefin plastomers or elastomers, elastomeric polyethylene-polypropylene, compositions or interpolymers of styrene-&agr; olefins, which have been chemically modified so that they react with polyamines to confer to asphalt significantly improved desired chemical and physical properties.

Abstract: An adhesive composition which requires no applied heat to effect curing and which produces a strong bond between a polymeric capping membrane suitably employed in roofing or siding and a roofing or siding base or substrate which composition essentially comprises a homogeneous 60 to 75% solids mixture of (a) between about 0.5 and about 15 wt. % of a thermosetting styrene/isoprene/styrene block polymer containing up to 90% styrene; (b) between about 13 and about 30 wt. % aromatic hydrocarbon solvent containing from about 5 to about 20 wt. % aliphatic hydrocarbon; (c) between about 20 and about 70 wt. % non-blown asphalt optionally containing a minor amount of blown asphalt; (d) between about 1 and about 10 wt. % metal silicate and (e) between about 0.1 and about 5 wt. % of a C6 to C16 alkoxyalkyl amine substituted ester of a C2 to C12 carboxylic acid as a surfactant. The invention also relates to the method of preparing and using the above adhesive composition.

Abstract: This invention is based upon the discovery that a polydiene rubber that is comprised of repeat units that are derived from a conjugated diene monomer and sulfur can be used to improved the force ductility, elastic recovery, toughness and tenacity of asphalt cement. The polydiene rubber that is comprised of repeat units that are derived from a conjugated diene monomer and sulfur also exhibits excellent compatibility with asphalt. The repeat units in the polydiene rubber that are derived from sulfur are in the backbone of the polymer. These repeat units that are derived from sulfur typically contain from 2 to 8 sulfur atoms (—Sn—). The subject invention more specifically relates to a modified asphalt cement which is comprised of (i) from about 90 weight percent to about 99 weight percent asphalt; (ii) from about 1 weight percent to about 10 weight percent of a polydiene rubber that is comprised of repeat units that are derived from a conjugated diene monomer and sulfur.

Abstract: This invention is based upon the discovery that a polydiene rubber that is comprised of repeat units that are derived from a conjugated diene monomer and sulfur can be used to improved the force ductility, elastic recovery, toughness and tenacity of asphalt cement. The polydiene rubber that is comprised of repeat units that are derived from a conjugated diene monomer and sulfur also exhibits excellent compatibility with asphalt. The repeat units in the polydiene rubber that are derived from sulfur are in the backbone of the polymer. These repeat units that are derived from sulfur typically contain from 2 to 8 sulfur atoms (—Sn—). The subject invention more specifically relates to a modified asphalt cement which is comprised of (i) from about 90 weight percent to about 99 weight percent asphalt; (ii) from about 1 weight percent to about 10 weight percent of a polydiene rubber that is comprised of repeat units that are derived from a conjugated diene monomer and sulfur.

Abstract: The present invention relates to a novel aromatic polysulfide and an asphalt composition containing the same, and more particularly, to a novel aromatic polysufide having repeating units of the following formula (I), an asphalt composition, an asphalt paving composition, an adhesion promoter and an UV absorber containing the same: The asphalt paving composition of this invention exhibits excellent adhesiveness to aggregate component and better water resistance, and renders the temperature susceptibility less sensitive, thereby greatly improving durability.

Abstract: A process is provided for crosslinking polymer modified asphalt compositions using a combination of a crosslink initiator, crosslink co-agent and crosslinkable polymer, to provide a process that is more reliable and more reproducible and that gives products that have a combination of properties that are superior to conventional sulfur crosslinked compositions.

Abstract: This invention is based upon the discovery that a polydiene rubber that is comprised of repeat units that are derived from a conjugated diene monomer and sulfur can be used to improved the force ductility, elastic recovery, toughness and tenacity of asphalt cement. The polydiene rubber that is comprised of repeat units that are derived from a conjugated diene monomer and sulfur also exhibits excellent compatibility with asphalt. The repeat units in the polydiene rubber that are derived from sulfur are in the backbone of the polymer. These repeat units that are derived from sulfur typically contain from 2 to 8 sulfur atoms (—Sn—). The subject invention more specifically relates to a modified asphalt cement which is comprised of (i) from about 90 weight percent to about 99 weight percent asphalt; (ii) from about 1 weight percent to about 10 weight percent of a polydiene rubber that is comprised of repeat units that are derived from a conjugated diene monomer and sulfur.

Abstract: This invention is based upon the discovery that a polydiene rubber that is comprised of repeat units that are derived from a conjugated diene monomer and sulfur can be used to improved the force ductility, elastic recovery, toughness and tenacity of asphalt cement. The polydiene rubber that is comprised of repeat units that are derived from a conjugated diene monomer and sulfur also exhibits excellent compatibility with asphalt. The repeat units in the polydiene rubber that are derived from sulfur are in the backbone of the polymer. These repeat units that are derived from sulfur typically contain from 2 to 8 sulfur atoms (—Sn—). The subject invention more specifically relates to a modified asphalt cement which is comprised of (i) from about 90 weight percent to about 99 weight percent asphalt; (ii) from about 1 weight percent to about 10 weight percent of a polydiene rubber that is comprised of repeat units that are derived from a conjugated diene monomer and sulfur.

Abstract: The present invention is a method of producing substantially dry water insoluble polymers from poly alkyl esters of vinylic monomers for use in a method for the clarification of red mud-containing liquors generated in the Bayer process for the recovery of alumina from bauxite ore. The polymers can be either homopolymers, copolymers or terpolymers. Preferably, the dried emulsion polymers are high molecular weight polymers of poly(methyl acrylate), poly(methyl acrylate/acrylic acid), poly(vinyl acetate/acrylic acid/methyl acrylate), poly(t-butyl methacrylate/acrylic acid/methyl acrylate) and poly(t-butyl acrylate/acrylic acid/methyl acrylate).

Abstract: This invention relates to a roofing or siding membrane comprising a non-woven mat coated with an asphaltic composition containing, in addition to 35-75 wt. % bitumen, a mixture of isotactic and amorphous propylene polymers and between about 0.08 and about 15 wt. % of a functionalized, olefin polymer to provide a non-staining membrane of high tensile strength, low polyolefin content with respect to asphalt, improved compatibility between asphalt and non-functionalized polymers and reduced light end asphalt and polymer exudates. The invention also relates to a method for preparing the membrane.

Abstract: Roofing membranes are provided with both high stiffness at high temperature (greater than 110 ° C.) and good flexibility at low temperature (less than −20 ° C.). Bituminous compositions may be more effectively used in such membranes at lower elastomer concentration than currently practiced, using conventional cross-linking reagents to prepare the modified bituminous compositions with a range of viscosities that are readily processed as compared with conventional non-cross-linked systems.

Abstract: The invention relates to a hydraulic fracturing fluid comprising an aqueous liquid, and a block copolymer containing at least one water-soluble block and one hydrophobic block and being particularly suited for use in high temperature ranges, greater than 180° C.

Abstract: This invention is based upon the discovery that a polydiene rubber that is comprised of repeat units that are derived from a conjugated diene monomer and sulfur can be used to improved the force ductility, elastic recovery, toughness and tenacity of asphalt cement. The polydiene rubber that is comprised of repeat units that are derived from a conjugated diene monomer and sulfur also exhibits excellent compatibility with asphalt. The repeat units in the polydiene rubber that are derived from sulfur are in the backbone of the polymer. These repeat units that are derived from sulfur typically contain from 2 to 8 sulfur atoms (—Sn—). The subject invention more specifically relates to a modified asphalt cement which is comprised of (i) from about 90 weight percent to about 99 weight percent asphalt; (ii) from about 1 weight percent to about 10 weight percent of a polydiene rubber that is comprised of repeat units that are derived from a conjugated diene monomer and sulfur.

Abstract: A new composition is formed by combining a reduced waste rubber, a heavy paraffin and a reduced waste thermoplastic, and then further reducing the resulting material while holding it at an elevated temperature. In preferred embodiments the rubber and thermoplastic are pre-processed by reduction to mesh sizes of about 0.25 inch and 0.5 inch respectively, and the paraffin is pre-processed by being fluidizing to have a viscosity of at most about 1.0 Centipoise. It is also contemplated that the rubber and paraffin can be advantageously combined with each other prior to inclusion of the thermoplastic, with the paraffin/rubber combination being heated to a temperature of about 220° F. to about 250° F. for about 3 minutes. It is still further contemplated that the combination of rubber, paraffin and thermoplastic can be heated to between about 360° F. and about 500° F.

Abstract: Elastomeric polyurethane interpenetrating network compositions are disclosed which are preferably developed by in situ reaction of polyols with different isocyanates and polyisocyanates in a bituminous material, such as, asphalt, coal tar, polymer modified asphalt, oxidized, and unoxidized asphalt. The composition is preferably formed at a temperature between 200° F. and 350° F. The reaction kinetics can be accelerated by including catalysts and curing agents. Bituminous polyurethane interpenetrating network elastomers are suitable for a wide variety of applications including but not limited to roofing, new construction, and wall and foundation waterproofing applications.

Abstract: A rubber-modified asphalt composition is provided. The asphalt composition includes asphalt, a rubber including at least high vinyl poly(conjugated diene), and at least one phenolic curing resin. The high vinyl poly(conjugated diene) has a vinyl content of at least 35%. The use of phenolic curing agents results in improvements to the softening point of the present asphalt composition while also improving toughness and tenacity.

Abstract: The invention concerns a silicone composition cross-linkable by hydrosilylation into adhesive gel and absorber, characterized in that it comprises:(I) at least a polyorganosiloxane POS (I); (II) at least a polyorganosiloxane POS (II); (III) at least an adhesive promoter (III); (IV) hollow organic microspheres ; (V) optionally at least a polyorganosiloxane POS (V) particularly useful as diluent of POS (I); (VI) an effective amount of hydrosilylation catalyst, preferably of the platinous type.

Abstract: A rubber-modified asphalt composition is provided. The rubber includes at least a polydiene and may further include vinyl-substituted aromatic hydrocarbon monomer contributed units. The rubber is cured by a bismaleimide. The present composition demonstrates improvements in the softening point of the asphalt composition.

Abstract: The present invention provides a method for preparing an asphalt and thermoplastic elastomer composition. The process comprises heating an asphalt cut in a stirred tank to a temperature sufficient to allow the stirring of the asphalt in the tank. A thermoplastic elastomer or rubber is added to the asphalt while continuing to stir the asphalt. The mixture is stirred at a speed and for a period of time sufficient to increase the distribution of the elastomer into the asphalt. The stirring speed is reduced and the temperature is increased to add crosslinking agents to the tank. Stirring is continued for a period of time sufficient to improve the distribution of the crosslinking agent dispersion in the asphalt. Crosslinking agents comprise zinc 2-mercaptobenzothiole and elemental sulfur in a ratio of zinc 2-mercaptobenzothiazole to sulfur of 2.0/1.0. Useful concentrates are possible using this method while avoiding gel formation.

Abstract: A moisture-crosslinkable polyolefin material, comprising a silane-grafted polyolefin blend, and coatings or insulations, including heat-shrinkable coatings and insulations, prepared therefrom. The coating material is formed by a process comprising: (a) reacting a pre-blended mixture of polyolefin and polypropylene, or higher polyolefin, resins and optional compatibilizing agent, with an appropriate silane and silane-grafting initiator to produce a silane-modified polyolefin blend composition; (b) forming the coating or insulating material by melt processing the composition produced in step (a) with a silanol condensation catalyst; and (c) crosslinking the formed coating or insulating material by exposing it to moisture, preferably at an elevated temperature.

Abstract: A polymer modified asphalt which includes asphalt, a polymer, an aldehyde or a melamine resin, and an element chosen from a group consisting of Group VI-A of Periodic Table, such as sulphur.

Abstract: A method for manufacturing modified asphalt is characterized by adding a dispersion agent such as furfural or vegetable oil to a modifier material and then mixing the modifier material with asphalt. The dispersion agent facilitates dispersion of the modifier through the asphalt to form a homogeneous mixture. A first activator is added to the mixture to produce a devulcanized and stabilized asphalt material having improved rheological, separation and solubility characteristics. A micro activator is also added to the mixture to improve the ductility of the modified asphalt. The modifier material comprises granular crumb rubber or polymer.

Abstract: The present invention provides a method for preparing an asphalt and thermoplastic elastomer composition. The process comprises preparing a crosslinking elastomer concentrate that is added to a heated asphalt cut in a stirred tank and then aged to improve SHRP high temperature grading. The crosslinking elastomer concentrate is prepared by adding thermoplastic elastomer and crosslinking agents to a suitable carrier oil, preferably an aromatic oil such as Hydrolene H series. This concentrate is maintained at a temperature that promotes association between the crosslinking agents and the elastomer for a time sufficient for association to substantially complete. In one embodiment, the associating time is in excess of 2 hours up to 24 hours. The asphalt is heated to a temperature sufficient to allow the stirring of the asphalt in the tank. The crosslinking thermoplastic elastomer concentrate is added to the asphalt while continuing to stir the asphalt.

Abstract: Polymer modified bituminous compositions which are stable against phase separation are provided at greater levels of incorporation of elastomeric polymer having a conjugated diene structure, such as styrene-butadiene rubbers, and/or cross-linking agent, specifically sulfur, by incremental addition of elastomeric polymer and/or cross-linking agent into the bitumen at elevated temperatures of about 150° to about 220° C.

Abstract: The present invention relates to novel polymer modified asphalt polyphosphoric and superphosphoric acid treated binder compositions having enhanced high service temperature performance properties and the method of making them and to road paving asphalts containing them.

Abstract: A process for the preparation of an asphalt and polymer composition in which a minor amount of polymer component is subjected to a crosslinking. An asphalt base material is heated in a mixing chamber at a temperature sufficient to melt the asphalt and allow stirring of the asphalt within the chamber. A thermoplastic elastomer is added to the chamber in an amount not greater than 12 wt. %. While the asphalt elastomer formulation is stirred, a crosslinking agent is added in an amount effective to crosslink the thermoplastic elastomer. The crosslinking agent formulation comprises at least two components. One component is a thiopolymer incorporating organic sulfur prepared by the reaction of 6-tertiary butyl cresol and sulfur dichloride which reacts to produce a reaction product comprising 4,4-thiobis(6-tertiary butyl-m-cresol) and the thiopolymer, followed by subsequent separation of the 4,4-thiobis(6-tertiary-butyl-m-cresol) from the thiopolymer product.

Abstract: A bitumen emulsion comprising bituminous binder, emulsifier, and water. The bituminous binder comprises bitumen and an oxidised wax, and optionally one or more polymers. The incorporation of the oxidised wax into the bituminous binder provides modified bitumen with both a high softening point and a low enough viscosity to allow it to be emulsified. The emulsion may be used as a tack coat in applying a waterproofing layer to a roof base. The emulsion may be made using a static mixing emulsion process.

Abstract: The invention concerns the continuous production of asphalts modified by the addition of polymers and reacted with sulfur. The binders produced by said methods can contain very high amounts of polymers, also combined with secondary materials such as: rubber, various plastics, and waste lubricants. This type of binder, which cannot be obtained by discontinuous batch technology, is produced by the continuous mixing of several asphalt components through a static mixer. Said binders provide very high-performance asphalts and agents for regenerating old asphalts contained in waste road materials, in the process of hot recycling of coated materials. They are also used for producing novel emulsions of highly modified binders, with multiple applications and in particular for cold recycling. This novel method, by regenerating old asphalt contained in waste coated materials, represents a means for waste conversion and for limiting the use of asphalt and road-surfacing aggregates.