Poly (di Organo Siloxane) Reactant Has At Least One Sio Other Than As Si-o Si, E.g., Si-o-c, Or Sioh Group, Etc. Patents (Class 524/863)
  • Patent number: 6555056
    Abstract: A method of preserving two or more separately packaged agents for forming a silicone composition which can be cured by mixing the separately packaged agents, which method can reduce the number of air bubbles contained in a cured product of the silicone composition and prevent a reduction in the strength of the cured product. The method of preserving the composition is characterized by keeping each packaged agent of the curable silicone composition under reduced pressure.
    Type: Grant
    Filed: December 1, 2000
    Date of Patent: April 29, 2003
    Assignee: Tokuyama Corporation
    Inventors: Hiroyuki Nakagawa, Toshio Kawaguchi, Yasuhiro Hosoi
  • Patent number: 6548574
    Abstract: An untreated filler and a high viscosity silicone polymer premix is charged into a compounding apparatus. Treating agent and additional silicone polymer are added to the premix and the premix, treating agent and additional silicone polymer are compounded to produce a heat vulcanizable filled silicone composition.
    Type: Grant
    Filed: December 21, 1999
    Date of Patent: April 15, 2003
    Assignee: General Electric Company
    Inventors: Devesh Mathur, Alan L. Tate
  • Patent number: 6528121
    Abstract: An aqueous treatment agent for wiping paper is capable of rendering tissue paper, toilet paper, and other types of wiping paper dry to the touch, highly smooth, nonsticky, and extremely soft while suppressing the slippery or wet feel thereof. The aqueous treatment agent comprises a water dispersion of a silicone rubber powder with an average particle diameter of 0.1 to 500 micrometers, a silicone oil, a surfactant, and water.
    Type: Grant
    Filed: April 6, 2001
    Date of Patent: March 4, 2003
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Isao Ona, Masaru Ozaki, Kazuo Kobayashi, Yoshitsugu Morita
  • Patent number: 6515043
    Abstract: An oligomer of the formula: [R3SiO½]m[O½Si(R2)O½]n[SiO{fraction (3/2)}R]o[SiO{fraction (4/2)}]p  (I) wherein each R is selected individually from the group consisting of R1, —OR2 and —OR3; each R1 is independently a substituted or unsubstituted hydrocarbon group; each R2 is a C1-C6 alkyl group or an acyl group; and each R3 is a independently an alkyl or alkenyl group having at least 8 carbon atoms; with the provisos that if R3 is alkenyl, there is no unsaturation within two carbon atoms adjacent to the oxygen atom of the —OR3 group; at least one R group is —OR3; at least one quarter of all R groups are —OR2 or —OR3; m=2 to 20; n=0 to 50; o=0 to 20; and p=0 to 10. The oligomer is a useful component of in insulation formulations for wire and cable used in underground locations.
    Type: Grant
    Filed: March 20, 2001
    Date of Patent: February 4, 2003
    Assignee: Crompton Corporation
    Inventors: Herbert B. Petty, Robert Pickwell
  • Patent number: 6471985
    Abstract: In one embodiment, the present invention relates to a method of treating a wound, involving applying to the wound a room temperature vulcanizing silicone composition comprising a crosslinkable polymer, a crosslinking agent, and a catalyst; permitting the room temperature vulcanizing silicon composition to cure thereby forming a membrane having a thickness from about 0.1 mm to about 5 mm; and removing the membrane from the wound after at least about 1 day.
    Type: Grant
    Filed: June 4, 1999
    Date of Patent: October 29, 2002
    Inventors: Bahman Guyuron, Michael Doliveck
  • Patent number: 6451440
    Abstract: A silicone sealant composition containing: (a) a moisture curable organopolysiloxane component, comprising a mixture or reaction product of (i) an organopolysiloxane polymer having hydrolyzable substituent groups and (ii) a polyfunctional silicon compound having two or more hydrolyzable substituent groups, (b) a filler and (c) a hydrocarbon fluid comprising, based on 100 parts by weight of the hydrocarbon fluid, greater than 40 parts by weight cyclic paraffinic hydrocarbons and less than 60 parts by weight noncyclic paraffinic hydrocarbons, exhibits improved tensile, elongation and adhesive properties.
    Type: Grant
    Filed: January 19, 2001
    Date of Patent: September 17, 2002
    Assignee: General Electric Company
    Inventors: Robert C. Atwood, Chiu-Sing Lin, Gary M. Lucas
  • Patent number: 6444745
    Abstract: A silicone composition containing a polyethersiloxane block copolymer network and a fluid within the network is useful as a component of various personal care compositions.
    Type: Grant
    Filed: June 12, 2000
    Date of Patent: September 3, 2002
    Assignee: General Electric Company
    Inventors: John A. Kilgour, Michael J. O'Brien, Atchara Chaiyawat
  • Patent number: 6436543
    Abstract: It is an object of the present invention to provide a high-gloss, heat-resistant paint composition that can form a paint film having high gloss, hiding power, heat resistance and adhesion, a method for manufacturing the same, a method for applying a high-gloss, heat-resistant paint, and a high-gloss, heat-resistant paint film. The heat-resistant paint composition is prepared by combining inorganic pigment powder having hiding power and a binder solution chiefly consisting of an alcoholic solution of polysilicon alcoxide; the binder solution containing an effective amount of aluminum ingredient; the composition contains 8˜50 wt. % of hydrophilic organic solvent having a boiling point of not less than 100° C. and not more than 220° C.; the average particle size of primary particles of the inorganic pigment powder dispersed in the binder solution being not more than 0.3 &mgr;m; and the solidified paint film obtained when the composition has been dried and baked contains not less than 60 vol.
    Type: Grant
    Filed: November 8, 2000
    Date of Patent: August 20, 2002
    Assignee: Institute of Technology Precision Electrical Discharge Work's
    Inventors: Yasuhiko Endo, Hisayuki Sakai, Tomio Sakai, Saburou Shimada
  • Patent number: 6433076
    Abstract: There is provided a low-staining agent which can outstandingly improve an anti-staining property and a property of preventing penetration of a staining substance when it is added to an aqueous paint, which does not affect a weather resistance and a water resistance of the paint, and which has an excellent compatibility with the aqueous paint. The present invention also relates to a low-staining aqueous paint composition to which said low-staining agent is added. The present invention relates to an aqueous paint low-staining agent which is a modified condensation product of alkoxysilane having at least one polyoxyalkylene group and an alkoxyl group, wherein a repetition unit of said polyoxyalkylene group has 1 to 4 carbon atoms, and said alkoxyl group has 1 to 4 carbon atoms. In particular, it is preferable that the polyoxyalkylene group is a polyoxyethylene group and the alkoxyl group is an ethoxy group.
    Type: Grant
    Filed: July 16, 1999
    Date of Patent: August 13, 2002
    Assignee: SK Kaken Co., Ltd.
    Inventors: Shigeto Kamimura, Hiroyoshi Ono, Yoshifumi Asada, Hisashi Suzuki
  • Publication number: 20020103304
    Abstract: The present invention provides a curable fluoroelastomer composition comprising:
    Type: Application
    Filed: November 29, 2001
    Publication date: August 1, 2002
    Applicant: 3M Innovative Properties Company
    Inventors: Klaus Hintzer, Robert E. Kolb, Peter J. Scott, Erik D. Hare, William D. Coggio
  • Patent number: 6423128
    Abstract: The invention pertains to a coating material on the basis of liquid crystalline polysiloxanes which is obtained via the co-condensation of mesogenous silanes and/or polysiloxanes, that are capable of being hydrolyzed, with sols.
    Type: Grant
    Filed: February 4, 1999
    Date of Patent: July 23, 2002
    Assignee: Fraunhofer-Gesellschaft zur Forderung der Angewandten Forschung E.V.
    Inventors: Sabine Amberg-Schwab, Manfred Hoffmann
  • Patent number: 6410640
    Abstract: A one-pack type curable resin composition having high adhesive strength to various substrates, good storage stability and excellent restoring properties is disclosed. The one-pack type curable resin composition contains an organic polymer (a) having at least one reactive silicon group per molecule, a compound (b) having reactive silicon group in its molecule, a non-phthalate plasticizer (c) having no phthalate structure in its molecule, and a stannous curing catalyst (d).
    Type: Grant
    Filed: March 29, 2000
    Date of Patent: June 25, 2002
    Assignee: Kaneka Corporation
    Inventors: Atsushi Fukunaga, Yoshiteru Masaoka, Hiroshi Ando, Fumio Kawakubo
  • Patent number: 6403711
    Abstract: A high elongation, low 100% modulus composition comprises a copolymer dispersed in a continuous phase polysiloxane. The copolymer is made from high amounts of at least a monomer which is capable of forming a low Tg polymer and relatively low amounts of at least a monomer which is capable of forming a high Tg polymer. The monomer forming the low Tg polymer can be an alkyl acrylate whereas the monomers forming the high Tg polymer can be a vinyl ester, an acrylonitrile or derivatives thereof, a vinyl substituted aromatic such as styrene, an alkyl methacrylate, and the like. The composition has good adhesion to substrates as well as good viscosity aging, and can be utilized in caulks or sealants.
    Type: Grant
    Filed: January 10, 2000
    Date of Patent: June 11, 2002
    Assignee: Noveon IP Holdings Corp.
    Inventors: Wei-Yeih Yang, Melvin Dale Beers, Ta-Min Feng
  • Patent number: 6395826
    Abstract: The present invention relates to mixtures prepared from (A) at least one linear, branched, or cyclic monomeric organosilane having at least two silicon atoms with hydrolyzable and/or condensation-crosslinking groups in which the silicon atoms are bonded to one another through at least one carbon atom in a linking unit, and (B) at least one boron- and/or aluminum-containing compound having the formula (I) RxM(OR′)3−x  (I)  wherein M is Al or B, x is 0, 1, or 2, R is C1-C6-alkyl, C6-C12-aryl, or (O)½, with the proviso that if R is (O)½, then the compound of the formula (I) is a chain when x is 1 and a cyclic or cage-form compound when x is 2, and each R′ is independently H, C1-C10-alkyl, or C6-C12-aryl. The invention further relates to hybrid materials prepared from such mixtures and to coatings produced therefrom.
    Type: Grant
    Filed: March 24, 1999
    Date of Patent: May 28, 2002
    Assignee: Bayer Aktiengesellschaft
    Inventors: Michael Mager, Steffen Hofacker
  • Patent number: 6395856
    Abstract: Oligomers of the formula: [R3SiO1/2]m[O1/2Si(R2)O1/2]n[SiO3/2R]o[SiO4/2]p  (I) wherein each R is selected individually from the group consisting of B, R1, —OR2, R3 and R4; B is an organosilyl functional group bridged to the Si atom of the siloxane oligomer backbone by an Si—C bond; each R1 is independently a saturated aliphatic hydrocarbon group of 1 to 16 carbon atoms; each R2 is independently a group as defined for R1, an aromatic hydrocarbon group or an acyl group; each R3 is independently a monovalent organic radical containing an aliphatically unsaturated hydrocarbon group and each R4 is a monovalent organic radical linked to the Si atom of the siloxane oligomer backbone by an Si—C bond, which does not include an aliphatically unsaturated hydrocarbon group and which has thereon one or more members of the group selected from aromatic hydrocarbon, ether, ester, carbamate, thioether, polysulfide, blocked mercaptan, amide, epoxy, cyano an
    Type: Grant
    Filed: December 2, 1999
    Date of Patent: May 28, 2002
    Assignee: Crompton Corporation
    Inventors: Herbert E. Petty, Robert Pickwell, Frederick D. Osterholtz, Shiu-Chin Huang Su
  • Patent number: 6395855
    Abstract: The present invention relates to mixtures containing bi-functionally terminated diorganopoly siloxanes aminosilane or oxime or alkoxy crosslinking agents, and optionally, filling materials, suitable additives, pigments, colorants, anti-oxidation pigments, anti-heat pigments, and light-protection pigments in addition to solvents and plasticizers. Said mixtures contain water and a catalyst in the form of an acidic or basic neutral salt as an accelerating cross-linking agent.
    Type: Grant
    Filed: August 31, 2000
    Date of Patent: May 28, 2002
    Assignee: Heidelberger Bauchemie GmbH
    Inventors: Werner Luft, Michael Futscher, Hermann Pahl
  • Patent number: 6323277
    Abstract: Oligomers of the formula: [R3SiO½]m[O½Si(R2)O½]n[SiO{fraction (3/2)}R]o[SiO{fraction (4/2)}]p  (I) wherein each R is selected individually from the group consisting of B, R1,—OR2, R3 and R4; B is an organosilyl functional group bridged to the Si atom of the siloxane oligomer backbone by an Si—C bond; each R1 is independently a saturated or aromatic hydrocarbon group of 1 to 16 carbon atoms; each R2 is independently a group as defined for R1 or an acyl group; and each R3 is independently a monovalent organic radical containing an aliphatically unsaturated hydrocarbon group and each R4 is a monovalent organic radical linked to the Si atom of the siloxane oligomer backbone by an Si—C bond, which does not include an aliphatically unsaturated hydrocarbon group and which has thereon one or more members of the group selected from ether, polyether, ester, polyester, carbamate, polyurethane, isocyanurate, thioether, polysulfide
    Type: Grant
    Filed: March 11, 1999
    Date of Patent: November 27, 2001
    Assignee: Witco Corporation
    Inventors: Herbert E. Petty, Robert Pickwell
  • Patent number: 6319982
    Abstract: Novel hindered alkoxy siloxane compounds and compositions containing hindered alkoxy siloxane compounds are provided. The compositions include a polymer/crosslinking system which is composed of a self crosslinking resin comprised of a silicone fluid modified with pendant or terminal silanes containing hindered alkoxy groups, or a silanol fluid and a crosslinking compound, of a mixture thereof. These components are first emulsified and then formulated into a latex sealant by blending with a separate emulsion of an appropriate catalyst. Crosslinking occurs upon drying of the emulsion.
    Type: Grant
    Filed: June 25, 1999
    Date of Patent: November 20, 2001
    Assignee: CK Witco Corporation
    Inventors: Misty Weiyu Huang, Bruce A. Waldman, Jeff A. Cooke
  • Patent number: 6313220
    Abstract: This invention relates to the preparation of an elastomer which contains a dispersion of a reinforcing system formed in situ within an elastomer host by the interaction of a telechelic hydroxy and/or alkoxy terminated polysiloxane and a reticulating agent having a moiety comprised of at least two alkoxy groups. The invention further includes a rubber composition of at least two elastomers wherein one of said elastomers is a pre-formed composite of elastomer and the in situ formed reinforcement system. A tire having a component of such rubber composition, particularly a tire tread, is specifically contemplated.
    Type: Grant
    Filed: March 3, 2000
    Date of Patent: November 6, 2001
    Inventors: Thierry Florent Edme Materne, Daniel Edward Bowen, III, Francois Kayser, Eric Sean Castner
  • Patent number: 6303678
    Abstract: Stable RTV-1-alkoxy compositions contain a tin catalyst and surfactants (S) which contain divalent polyether units of the general formula (I) —O—[(CR&agr;R&bgr;)u—O]v—  (I) in which R&agr; and R&bgr; are hydrogen or a monovalent C1-C10-hydrocarbon radical optionally substituted by hydroxyl, fluorine, chlorine, bromine, C1-C10-alkoxyalkyl or cyano groups, u is from 1 to 6 and v is from 3 to 100. The compositions are stable despite the presence of the tin catalyst and alkoxy-functional organosilicon compounds.
    Type: Grant
    Filed: March 14, 2000
    Date of Patent: October 16, 2001
    Assignee: Wacker-Chemie GmbH
    Inventors: Wolfgang Ziche, Norman Dorsch, Susanne Straussberger, Wolfgang Hechtl
  • Patent number: 6291546
    Abstract: A silicone composition for oral mucosa impression is disclosed, comprising: (A) 100 parts by weight of an organopolysiloxane having at least two aliphatic unsaturated hydrocarbons in one molecule and having a viscosity at 25° C. of 500˜1,500 cS; (B) from 0.1 to 20 parts by weight of an organohydrogen polysiloxane having at least three hydrogen atoms directly bonded to a silicon atom in one molecule; (C) from 10 to 500 ppm, based on the total amount of the components (A) and (B), of a silicone-soluble platinum compound; (D) from 1 to 20 parts by weight of a linear methylphenyl polysiloxane having a viscosity at 25° C. of 30 to 10,000 cS; (E) from 10 to 200 parts by weight of an inorganic filler; and (F) from 0.5 to 5 parts by weight of one or two or more surfactants selected from nonionic surfactants.
    Type: Grant
    Filed: May 7, 1999
    Date of Patent: September 18, 2001
    Assignee: GC Corporation
    Inventors: Hiroshi Kamohara, Makiko Takeo
  • Patent number: 6268440
    Abstract: A water-base resin has both excellent storage stability and excellent curability at room temperature, the water base resin being obtained by mixing a composite resin (C) and a polysiloxane (D), bringing about a condensation reaction partially between them if necessary, and thereafter dispersing or dissolving the resulting mixture or partially condensed product into a water-base medium, wherein the composite resin (C) comprises a polysiloxane segment (A) and a polymer segment (B), the polysiloxane segment (A) having at least one silicon atom selected from the group consisting of a silicon atom bearing at least one organic group having a total carbon number of at least 3 together with at least one hydrolyzable group and/or at least one hydroxyl group, a silicon atom bearing one hydrolyzable group or one hydroxyl group together with two groups selected from the group consisting of methyl groups and ethyl groups, and a silicon atom bearing at least one triorganosiloxy group together with at least one hydrolyzable
    Type: Grant
    Filed: January 29, 1999
    Date of Patent: July 31, 2001
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Shin-ichi Kudo, Hiroshi Kinoshita, Masataka Ooka
  • Patent number: 6235833
    Abstract: A water-repellent solution for forming a superior water-repellent film on a glass substrate is produced by subjecting a fluoroalkyl-group contained silane compound to a hydrolysis and a condensation polymerization. With this, at least dimers and trimers of the silane compound are produced. In case wherein the fluoroalkyl-group contained silane compound is of a type having the following general formula, satisfied performance of the formed water-repellent film is expected: CF3(CF2)m(CH2)2SiX3 wherein “m” is equal to or greater than 7 (seven) and “X” represents halogen, isocyanate-group or alkoxy-group, said alkoxy-group including methoxy-group [OCH3], ethoxy-group [OC2H5] or isopropoxy-group [OC3H5]. When the “m” is equal to or greater than 9 (nine), the performance of the film is much increased.
    Type: Grant
    Filed: February 12, 1999
    Date of Patent: May 22, 2001
    Assignee: Central Glass Company, Limited
    Inventors: Yoshinori Akamatsu, Shigeo Hamaguchi
  • Patent number: 6225403
    Abstract: The present invention relates to a method and composition for treating textile fibers or substrates, to thereby impart oil, water and soil repellency at substantially reduced add on levels of fluorine containing resins based on weight of the textile fiber or substrate so treated.
    Type: Grant
    Filed: February 3, 1999
    Date of Patent: May 1, 2001
    Inventor: Barry R. Knowlton
  • Patent number: 6218461
    Abstract: A silicone composition curing at room temperature by condensation, which is suitable especially as a dental molding composition. The silicone composition consists of the a) base paste containing a filler and polyorganosiloxane having hydroxy groups, b) and the activator component containing in addition to crosslinking agent and catalyst also a polyaddition product with alkoxysilyl groups in the molecule. The base paste and activator component can be mixed uniformly together and can be offered with special advantage in double cartridges.
    Type: Grant
    Filed: February 23, 1999
    Date of Patent: April 17, 2001
    Assignee: Heraeus Kulzer GmbH & Co. KG
    Inventors: Peter Schwabe, Michael Freckmann, Klaus-Dieter Nehren
  • Patent number: 6214930
    Abstract: In a process for preparing a one-package RTV organopolysiloxane composition comprising (A) an organopolysiloxane containing at least two Si—OH groups or hydrolyzable groups, (B) an organosilane having at least two hydrolyzable groups or a partial hydrolyzate thereof, and (C) an inorganic filler, components (A) and (B) are premixed in a substantially anhydrous state, and component (C) is then added to the premix. Despite the absence of sag-control agents, the composition in the uncured state has a sufficient viscosity for sag-control, ease of extrusion, and improved slump properties.
    Type: Grant
    Filed: January 27, 1999
    Date of Patent: April 10, 2001
    Assignee: Shin-Etsu Chemical Col, Ltd.
    Inventors: Masatoshi Miyake, Kazuyuki Suzuki, Mamoru Teshigawara, Tsuneo Kimura
  • Patent number: 6207783
    Abstract: An oligomer of the formula: [R3SiO1/2]m[O1/2Si(R2)O1/2]n[SiO3/2R]o[SiO4/2]p  (I) wherein each R is selected individually from the group consisting of R1, —OR2 and —OR3; each R1 is independently a substituted or unsubstituted hydrocarbon group; each R2 is a C1-C6 alkyl group or an acyl group; and each R3 is a independently an alkyl or alkenyl group having at least 8 carbon atoms; with the provisos that if R3 is alkenyl, there is no unsaturation within two carbon atoms adjacent to the oxygen atom of the —OR3 group; at least one R group is —OR3; at least one quarter of all R groups are —OR2 or —OR3; m=2 to 20; n=0 to 50; o=0 to 20; and p=0 to 10. The oligomer is a useful component of in insulation formulations for wire and cable used in underground locations.
    Type: Grant
    Filed: May 18, 1999
    Date of Patent: March 27, 2001
    Assignee: Crompton Corporation
    Inventors: Herbert E. Petty, Robert Pickwell
  • Patent number: 6183551
    Abstract: A curable resin composition containing (A) a saturated hydrocarbon polymer having at least one reactive silicon-containing group in a molecule, and (B) a hydrogenated oligomer of an &agr;-olefin, or a curable resin composition containing (A) a saturated hydrocarbon polymer having at least one reactive silicon-containing group in a molecule, (C) a saturated hydrocarbon oligomer, and (D) an ester plasticizer, both of which have good workability, in particular, at low temperature.
    Type: Grant
    Filed: October 31, 1997
    Date of Patent: February 6, 2001
    Assignee: Kaneka Corporation
    Inventors: Toshihiko Okamoto, Kazuo Hagiwara, Makoto Chiba, Masashi Sakaguchi, Junji Takase
  • Patent number: 6180249
    Abstract: A condensation curable coating composition comprises the following and any reaction product thereof: (A) a room temperature vulcanizable polyorganosiloxane composition; and (B) a marine foul release-enhancing proportion of at least one organic compatible silicone fluid free from silanol groups and being capable of blooming to the surface of a cured product of component A.
    Type: Grant
    Filed: September 8, 1998
    Date of Patent: January 30, 2001
    Assignee: General Electric Company
    Inventor: Judith Stein
  • Patent number: 6166121
    Abstract: A curable organopolysiloxane composition that can form a cured product that is strongly adhesive to substrates such as glasses, plastics, and metals and exhibits a very durable adhesion in which adhesiveness is maintained even under severe conditions such as immersion in hot water. The curable organopolysiloxane composition comprises from 1 to 75 weight % of a calcium carbonate powder whose surface has been treated with both (a) a rosin or a rosin derivative and (b) a fatty acid or a fatty acid derivative.
    Type: Grant
    Filed: April 23, 1999
    Date of Patent: December 26, 2000
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Wataru Nishiumi, Seiji Hori
  • Patent number: 6136917
    Abstract: The compositions of the present invention consist essentially of (I) a reaction product, (II) a nonaqueous liquid continuous phase, and (III) a moderately hydrophobic particulate stabilizing aid. Component (I) is prepared by heating a mixture of (i) a polyorganosiloxane fluid, (ii) a silicon compound, (iii) a finely divided filler and (iv) a catalytic amount of a compound for promoting the reaction of components (i) to (iii) at a temperature of 50.degree. C. to 300.degree. C. The compositions of the present invention can additionally contain (IV) at least one nonionic silicone surfactant, and (V) a nonreinforcing inorganic filler.
    Type: Grant
    Filed: July 22, 1993
    Date of Patent: October 24, 2000
    Assignee: Dow Corning Corporation
    Inventors: Steven Patrick Christiano, Gregory Gerald Bausch, Lauren Marie Tonge, Sharon Kay McCoy, Elizabeth Fiona Mallen, Roger Jeffery Jones, Athanasios Surutzidis, Andrew Albon Fisk
  • Patent number: 6121298
    Abstract: An antibacterial and mildewproofing organopolysiloxane composition comprising (A) an organopolysiloxane such as polydimethylsiloxane terminated with silanol groups or polydimethylsiloxane terminated with trimethylsiloxyl groups, (B) a hydrolyzable silane compound and/or a partial hydrolysis-condensation product thereof, (C) a triazolyl-group-containing compound such as tebuconazole and (D) an inorganic antibacterial agent comprising an inorganic substance comprising zeolite, apatite and/or silica and supporting or containing silver and/or silver ions.This composition is superior in antibacterial properties, mildew resistance and permanence of mildew resistance and also superior in weatherability such as heat resistance and ultraviolet light resistance, may cause less change in color, and is useful as a sealing medium.
    Type: Grant
    Filed: January 14, 1999
    Date of Patent: September 19, 2000
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Takafumi Sakamoto, Tokuo Sato
  • Patent number: 6121336
    Abstract: Polyurethane foams prepared using polysiloxane/polyoxyalkylene surfactants, preferably blended with a viscosity modifying agent, particularly in combination with particulate silica, especially silica aerogel, exhibit improved thermal insulating capacity, as measured by K-factor, and improved closed cell content, without increasing the density of the polyurethane foam.
    Type: Grant
    Filed: June 28, 1994
    Date of Patent: September 19, 2000
    Assignee: BASF Corporation
    Inventors: Michael O. Okoroafor, Alan E. Wang, Bulent E. Yoldas
  • Patent number: 6121373
    Abstract: Thickening can be obtained by adding a silicone latex to the water phase of a water-in-silicone emulsion, instead of adding the silicone latex to the silicone phase of the emulsion. The latex is used in a range of about 0.1-5.0% by weight. Thick emulsions are made by (i) separately preparing a silicone phase containing a silicone polyether and a cyclic siloxane; (ii) separately preparing an aqueous phase containing water and at least one active ingredient; (iii) adding the latex to the aqueous phase; and (iv) combining and mixing the phases.
    Type: Grant
    Filed: October 7, 1998
    Date of Patent: September 19, 2000
    Assignee: Dow Corning Corporation
    Inventor: Michael Stephen Starch
  • Patent number: 6107381
    Abstract: Anti-fouling coatings comprise a room temperature vulcanizable polyorganosiloxane composition and a polyorganosiloxane free from silanol groups and comprising at least one hydroxy- or alkoxy-terminated polyoxyalkylenealkyl radical. The latter is capable of blooming to the surface of the cured room temperature vulcanizable composition, thus inhibiting the deposition of marine life on the coated article.
    Type: Grant
    Filed: June 15, 1998
    Date of Patent: August 22, 2000
    Assignee: General Electric Company
    Inventors: Judith Stein, Timothy Brydon Burnell, James Anthony Cella
  • Patent number: 6090885
    Abstract: A silicone emulsion useful as a component in hair care compositions In a first aspect of the present invention, a silicone emulsion comprises the product of a base catalyzed reaction of an aqueous emulsion of a hydroxy end-stopped polyorganosiloxane and an aminofunctional silane according to the structural formula: ##STR1## wherein: R.sup.1 and R.sup.2 are each independently H, alkyl, or an aminoalkyl group according to the structural formula: ##STR2## and wherein: R.sup.4, R.sup.5 and R.sup.6 are each independently (C.sub.1 -C.sub.12)alkyl or (C.sub.2 -C.sub.8)alkoxy, provided that at least two of R.sup.4, R.sup.5 and R.sup.6 are each (C.sub.2 -C.sub.8)alkoxy;R.sup.7 and R.sup.8 are each H or alkyl; andR.sup.3 and R.sup.9 are each independently alkylene.
    Type: Grant
    Filed: October 6, 1998
    Date of Patent: July 18, 2000
    Assignee: General Electric Company
    Inventors: An-Li Kuo, Virginia Van Valkenburg Powell, Frank J. Traver
  • Patent number: 6040354
    Abstract: An impression composition which is based on an aziridine-free composition which can be vulcanized at room temperature, and which comprises wax is provided according to the invention. The wax increases the dimensional stability of the composition during mixing and curing. The invention furthermore provides a kit for the preparation of such compositions and a process for the preparation of the wax-containing components of these kits. The wax is dispersed throughout the composition and is prepared by shock-cooling. The wax forms a crystalline network.
    Type: Grant
    Filed: August 21, 1997
    Date of Patent: March 21, 2000
    Assignee: Ernst Muhlbauer KG
    Inventors: Heijo Hubner, Dierk Lubbers, Wolfgang Muhlbauer
  • Patent number: 6031026
    Abstract: In a first step, a crosslinkable organopolysiloxane oil (2) is mixed with an inorganic filler (3) in a flow jet mixer (1) to form a flowing silicone rubber compound. In a second step, the silicone rubber compound is fed into a tank (6) equipped at the bottom with a vacuum discharge pump (8) and maintained in vacuum where the compound is continuously deaerated, and a thixotropy controlling agent (10) is then added and mixed with the compound in a mixer (9). In a third step, a crosslinking agent (12) is added and mixed with the silicone rubber compound in a KRC kneader (11), and the compound is degassed in a mixer (13). The process continuously produces an RTV silicone rubber composition which is anti-sagging and improved in applicability on use.
    Type: Grant
    Filed: June 12, 1998
    Date of Patent: February 29, 2000
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Yuki Tateyama, Yoshiharu Konya, Takao Kanaya
  • Patent number: 6022923
    Abstract: A pneumatic tire having improved rolling resistance and wear resistance comprises a tread made from a rubber composition containing a partially hydrophobizated silica subjected to a surface treatment with an organosilicon compound so as to have specified hydrophobization ratio and apparent density.
    Type: Grant
    Filed: August 28, 1997
    Date of Patent: February 8, 2000
    Assignee: Bridgestone Corporation
    Inventors: Shunji Araki, Kazuhiro Yanagisawa
  • Patent number: 6022050
    Abstract: A release coating composition containing about 50 to about 75 wt. % of an epoxy functional silicone; about 8 to about 25 wt. % of a reactive solvent; about 5 to about 25 wt. % of a reactive diluent; about 6 to about 12 wt. % of a wax-treated silica powder; and, about 2 to about 4 wt. % of a photoinitiator is disclosed. The composition is useful in preparing a low-gloss release coating for use on linerless labels.
    Type: Grant
    Filed: September 2, 1998
    Date of Patent: February 8, 2000
    Assignee: Monarch Marking Systems, Inc.
    Inventor: James R. Kline
  • Patent number: 6020402
    Abstract: Silicone rubber compositions are disclosed including a silicone polymer and a silicon-treated carbon black. The silicon-treated carbon blacks include a silicon-containing compound that is distributed through at least a portion of the carbon black aggregate. The silicon-treated carbon black is incorporated within a silicone rubber composition as an alternative reinforcing and extending filler, imparting higher hardness to elastomers formed from the composition, when compared to silicone rubber compositions incorporating an untreated carbon black.
    Type: Grant
    Filed: September 15, 1995
    Date of Patent: February 1, 2000
    Assignee: Cabot Corporation
    Inventors: Joginder N. Anand, John E. Mills, Steven R. Reznek
  • Patent number: 6013740
    Abstract: Polysiloxane sheet or tube polymers having pendant siloxane groups are prepared by contacting sheet or tube silicates with halogen endblocked halosiloxanes represented by the formula: ##STR1## where X is chlorine, fluorine, bromine, or iodine; R1 to R7 are alkyl groups with 1-6 carbon atoms, aryl groups, alkaryl groups, or aralkyl groups; in which one of the groups R1, R4, and R5 can additionally represent X; and n has a value of 2 to about 20.
    Type: Grant
    Filed: August 27, 1998
    Date of Patent: January 11, 2000
    Assignees: Dow Corning Corporation, Virginia Institute and State University
    Inventors: Gary Thomas Burns, Timothy Chi-Shan Chao, Aref Ben Ahmed Jallouli, Dimitris Elias Katsoulis
  • Patent number: 6008290
    Abstract: A room temperature curable mildew resistant organopolysiloxane composition comprises (A) a hydroxyl or hydrolyzable group-containing organopolysiloxane, (B) a hydrolyzable organosilane such as methyltrimethoxysilane, methyltris(methylethylketoxime silane) or vinyltris(methylethylketoxime silane), a partially hydrolyzed product thereof or a mixture of the hydrolyzable organosilane with the partially hydrolyzed product thereof; and (C) a triazolyl group-containing compound such as 2-(4-chlorophenyl)ethyl-.alpha.-(1,1-dimethylethyl)-1H-1,2,4-triazole-1-yl -ethanol. Preferably, the component (B) does not contain aliphatic unsaturation in the molecule, and in this case, the component (B) free of aliphatic unsaturation is used in combination with (B') a hydrolyzable silane such as tetrakis(dimethylketoxime)silane, a partially hydrolyzed product thereof or a mixture of the hydrolyzable silane and the partially hydrolyzed product thereof.
    Type: Grant
    Filed: February 16, 1996
    Date of Patent: December 28, 1999
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Kei Miyoshi, Tokuo Sato, Yoshio Inoue
  • Patent number: 6004679
    Abstract: A multilayer laminate having improved peel strength and containing a first and third layer comprising various plastic, metal, or glass materials, and a second layer containing an addition-curable silicone composition curable to form an adhesive having good physical properties and improved peel adhesion properties, the second layer comprising (A) a vinyl-containing polydiorganosiloxane composition, (B) a hydrogen-terminated polysiloxane, preferably in an amount sufficient to provide an adhesion-promoting molar ratio of silicon-bonded hydrogen atoms in (B) to olefinically unsaturated radicals in (A); (C) a catalytic amount of a platinum-containing hydrosilation catalyst; (D) an effective amount of an adhesion promoter selected from the group consisting of (i) bis[3-(trimethoxysilyl)alkyl]-fumarates; (ii) bis[3-(trimethoxysilyl)alkyl]maleates; (iii) allyl-[3-(trimethoxysilyl)alkyl]maleates; (iv) allyl-[3-(trimethoxysilyl)alkyl]fumarates; and (v) N-[3-(trimethoxysilyl) alkyl]maleimides, wherein R.sup.2, R.sup.
    Type: Grant
    Filed: March 14, 1991
    Date of Patent: December 21, 1999
    Assignee: General Electric Company
    Inventors: Tyrone Duncan Mitchell, Stuart Robert Kerr, III, Mark Wayne Davis
  • Patent number: 5994456
    Abstract: A composition comprising (A) at least one mercapto-functional organosilicon compound having an average of a least two mercapto groups per molecule and (B) a cure initiator. The mercapto-functional organosilicon compound may include mercapto-functional organosilanes, mercapto-functional organosiloxanes, and mercapto-functional copolymers. The compositions of the present invention polymerize or cure to form compositions comprising reaction products of components (A) and (B). The cure initiator is a metal salt that produces a uniform cure throughout the composition, regardless of the amount of oxygen present. The cured products range in properties from soft gels to though elastomers to hard resins and are useful as molded articles, electrical encapsulants, and sealants.
    Type: Grant
    Filed: April 9, 1998
    Date of Patent: November 30, 1999
    Assignee: Dow Corning Corporation
    Inventors: Jerome Melvin Klosowski, Sarah Severson Snow
  • Patent number: 5990231
    Abstract: A one-component room temperature vulcanizable silicone rubber composition comprising (A) silanol end-terminated polyorganosiloxane base polymer, (B) organotriacyloxysilane cross-linker, (C) polysiloxane-polyether copolymer rheology modifier, and (D) particulate silica. The rheology modifying agent is particularly useful for adjusting the viscosity and plateau stress of the silicone rubber compositions.
    Type: Grant
    Filed: December 23, 1998
    Date of Patent: November 23, 1999
    Assignee: Dow Corning Corporation
    Inventors: Jon Vierling DeGroot, Jr., Carl Allen Fairbank
  • Patent number: 5985994
    Abstract: Aqueous dispersions organopolysiloxanes which are free of organic transition metal compounds and of organic compounds of the metals of the main groups III, IV and V. These dispersions can be produced using the following starting compounds:(A) organopolysiloxane containing condensation-capable groups;(B) an organosilicon compound of the formula{[(RO).sub.3 Si--R.sup.3 --].sub.e R.sup.2.sub.1-e }.sub.a Si(OR).sub.4-a(II),in whichR is identical or different and is a hydrogen atom or alkyl radical having 1 to 6 carbon atoms,R.sup.2 is identical or different and is an SiC-bonded hydrocarbon radical having 1 to 18 carbon atoms, optionally substituted with halogen atoms, ether groups, ester groups, epoxy groups, mercapto groups or (poly)glycol radicals comprised of oxyethylene units, oxypropylene units and mixtures thereofR.sup.3 is identical or different and is a divalent hydrocarbon radical,a is 0 or 1, ande is 0 or 1 where {[(RO).sub.3 Si--R.sup.3 --].sub.e R.sup.2.sub.1-e }.sub.
    Type: Grant
    Filed: November 10, 1997
    Date of Patent: November 16, 1999
    Assignee: Wacker-Chemie GmbH
    Inventors: Stefan Oberneder, Karl Braunsperger, Alfred Heinrich, Rudolf Braun, Herbert Soellradl
  • Patent number: 5952077
    Abstract: Surfactant compositions including end-capped hydrocarbyl polyalkoxylate and/or fatty acid polyalkoxylate and organopolysiloxane having one or more polyoxyalkylene side chains are good immediate and long term spreaders particularly on fibrous hydrophobic synthetic polymeric substrates such as spun-bonded, non-woven materials made e.g. form polyolefins, especially polypropylene, or PET. Particularly useful alkoxylates are of one of the formulae (Ia to Id): R.sup.1 O.(AO.sup.1).sub.n.R.sup.2 (Ia); R.sup.3.CO.sub.2.(AO.sup.1).sub.n.R.sup.2 (Ib); R.sup.14 O.?EO.sub.i.PO.sub.j !.R.sup.15 (Ic); or R.sup.14 O.(AO.sup.2).sub.k.(AO.sup.3).sub.l.(AO.sup.2).sub.m.R.sup.15 (Id), where the various substituents and indices have defined meanings and useful silicones include those of the formula (II): R.sup.4.sub.3 SiO.?R.sup.4.sub.2 SiO!.sub.x.{(R.sup.4 Si?(O.R.sup.5.(AO.sup.2).sub.m.R.sup.6 !O}.sub.y.SiR.sup.4.sub.3, where the various substituents and indices have defined meanings.
    Type: Grant
    Filed: August 26, 1997
    Date of Patent: September 14, 1999
    Assignee: Imperial Chemical Industries PLC
    Inventors: David John Booth, Martin Spencer Williams
  • Patent number: 5948853
    Abstract: One component room temperature vulcanizable silicone sealant compositions comprising both a specific cross linker, ethyltriacetoxysilane, and a specific extending filler, stearic acid treated calcium carbonate, exhibit an extended work life or tooling time.
    Type: Grant
    Filed: January 26, 1996
    Date of Patent: September 7, 1999
    Assignee: General Electric Company
    Inventors: Brian P. Bayly, Frederick R. DeCelle, Van W. Stuart
  • Patent number: 5939478
    Abstract: The viscosity of a solvent is modified by thickening the solvent with a silicone latex. A silicone latex having a plurality of crosslinked polysiloxane particles is first prepared by mixing the siloxane polymer, a surfactant, and water; emulsifying the mixture to a gel phase; diluting the emulsion with water; adding a cure package (i.e., a catalyst, a crosslinker, or both, or a self catalytic crosslinker); and then without removing the water from the latex and after the particles of siloxane polymer in the latex have been cured, mixing the latex and solvent to thicken the solvent, forming viscous liquids, gels, and pastes. Water in the latex thickened solvent composition can be stabilized by adding a silicone polyether during mixing of the latex and the solvent.
    Type: Grant
    Filed: November 13, 1997
    Date of Patent: August 17, 1999
    Assignee: Dow Corning Corporation
    Inventors: James Anderson Beck, Vicky Sue Cobb, Cassie Emelia Cuthbert, Eric Jude Joffre, Virginia Kay O'Neil, Burt Michael Wrolson