Treating Or Preparing A Nonaqueous Dispersion Or Emulsion Of A Solid Polymer Or Specified Intermediate Condensation Product Patents (Class 524/923)
  • Patent number: 4493914
    Abstract: Crosslinked, preferably acrylic, preferably melamine crosslinked, polymer particles formed by reactions comprising free radical addition polymerization of:(a) between about 0.5 and about 20 weight percent each of first and second monomers, each bearing functionality capable of crosslinking reaction with the other, wherein (i) either both additionally are ethylenically unsaturated monomers or (ii) the first monomer additionally is ethylenically unsaturated and the second monomer bears multiple crosslinking functionality and no ethylenic unsaturation; and(b) between about 60 and about 99 weight percent of at least one other monoethylenically unsaturated monomer;in the presence of (I) an organic liquid which is a solvent for the polymerizable monomers, but a non-solvent for the resultant polymer, and (II) polymeric dispersion stabilizer bearing, on the average, more than one long chain non-polar hydrocarbon molecules and at least one pendant vinyl unsaturation.
    Type: Grant
    Filed: February 23, 1983
    Date of Patent: January 15, 1985
    Assignee: Ford Motor Company
    Inventor: Mohinder S. Chattha
  • Patent number: 4474924
    Abstract: Polymerization slurries of elastomeric isoolefin homopolymers and copolymers, such as butyl rubber, in diluents such as methyl chloride are effectively stabilized against agglomeration of polymer particles through addition of minor proportions of an hydrogenated preformed copolymer stabilizer having both a lyophobic and a lyophilic portion. The chemical and structural nature of the lyophobic and lyophilic portions which comprise the copolymer stabilizer are significant in determining the extent and method of hydrogenation for production of the most effective stabilizer. Agglomeration of polymer products is effectively prevented, yielding a number of significant processing advantages. The process is especially adaptable to the production of isobutylene-isoprene butyl rubber.
    Type: Grant
    Filed: January 27, 1983
    Date of Patent: October 2, 1984
    Assignee: Exxon Research & Engineering Co.
    Inventors: Kenneth W. Powers, Hsien C. Wang
  • Patent number: 4463128
    Abstract: This invention relates to a reactive plastisol dispersion comprising(1) a polyvinyl acetal thermoplast in particle form;(2) a liquid plasticizer member of the group consisting of(a) at least one an ethylenically unsaturated monomer, oligomer or prepolymer of the formula: ##STR1## wherein R is H or CH.sub.3, R.sub.1 is an organic moiety and n is 1 or more,(b) at least one unsaturated polyester containing the group: ##STR2## wherein R.sub.2 and R.sub.3 are organic moieties, x is 0-20 and y is 1-20; and(c) a mixture of (a) and (b);and, optionally, either(3) a free radical thermal initiator or(4) a photoinitiator for crosslinking.The reactive plastisol dispersion when fluxed can be useful as a sealant or adhesive.
    Type: Grant
    Filed: May 9, 1983
    Date of Patent: July 31, 1984
    Assignee: W. R. Grace & Co.
    Inventor: Shiow C. Lin
  • Patent number: 4454260
    Abstract: Stable suspension of a water-soluble polymer comprising solid particles of this water-soluble polymer in a liquid hydrocarbon medium which also comprises a thickening agent selected from the alkali or alkaline-earth metal salts of fatty acids having 6-33 carbon atoms. The resultant suspensions are stable and dissolve easily when dispersed in water; they can be used in enhanced oil recovery. They may also contain minor proportions of water and/or of C.sub.1 -C.sub.12 monoalcohols or C.sub.2 -C.sub.12 diols.
    Type: Grant
    Filed: January 18, 1983
    Date of Patent: June 12, 1984
    Assignee: Institut Francais du Petrole
    Inventors: Francois Dawans, Daniel Binet, Norbert Kohler, Quang D. Vu
  • Patent number: 4451506
    Abstract: Disclosed is a side seam-coated welded can comprising a welded can body having a seam on the side face and a resin coating layer covering at least one surface side of the seam, wherein said coating layer comprises a thermosetting resin and a thermoplastic resin having a softening point of 50.degree. to 300.degree. C. as determined according to the ring and ball method, at a volume ratio ranging (A) from 95/5 to 25/75 or (B) from 20/80 to 1/99, and one of said two resins is present in the coating in the form of a continuous phase and at least a part of the other resin is present in the coating in the form of fine dispersed particles.This can is excellent in corrosion resistance and processability.
    Type: Grant
    Filed: September 24, 1982
    Date of Patent: May 29, 1984
    Assignee: Toyo Seikan Kaisha Ltd
    Inventors: Seishichi Kobayashi, Tatsuo Mori, Tetsuo Miyazawa, Kazuo Taira, Makoto Horiguchi, Susumu Takahashi
  • Patent number: 4435537
    Abstract: The subject invention relates to storage stable dispersions comprising certain aromatic polyesters dispersed in certain polyhydroxyl compounds and their process of preparation. The dispersions are useful for the preparation of polymers containing urethane and/or isocyanurate linkages.
    Type: Grant
    Filed: March 22, 1982
    Date of Patent: March 6, 1984
    Assignee: BASF Aktiengesellschaft
    Inventors: Peter Horn, Anton Hesse, Walter Heckmann, Ulrich Lebert, Alfred Guthmann, Matthias Marx
  • Patent number: 4427820
    Abstract: The production is described of a dispersion of polymer microparticles, which may optionally be crosslinked, by dispersion polymerisation in aliphatic hydrocarbon liquid under specified conditions of a monomer mixture which comprises up to 50% of styrene or a substituted derivative thereof and up to 50% by weight of a derivative of maleic acid or fumaric acid which is soluble in the hydrocarbon liquid at the polymerization temperature. The microparticles have a size in the range 100-400 nm and a high refractive index, and are suitable for incorporation in coating compositions which are based on a film-forming polymer, such as a thermosetting acrylic resin or an alkyd resin, containing a significant proportion of aromatic residues, and which are intended to be used either unpigmented or when containing only light-absorbing pigments.
    Type: Grant
    Filed: June 9, 1982
    Date of Patent: January 24, 1984
    Assignee: Imperial Chemical Industries PLC
    Inventors: Alan J. Backhouse, Stephen J. Thorne, Patrick A. Hunt
  • Patent number: 4410601
    Abstract: A process for producing a colloidal solution of a curable resin which comprises:blending (a) 5 to 90% by weight of a polyfunctional maleimide component and (b) 95 to 10% by weight of at least one thermosetting resin,heating them to form a composition, andblending the resulting composition with at least one low boiling point solvent having a boiling point of more than room temperature and less than 150.degree. C., in which the thermosetting resin is rich soluble, but the maleimide component is poor soluble, thereby forming a colloidal solution of a curable resin is disclosed. The colloidal solution is used as a coating, as an impregnating agent for a coil, or for preparing prepreg.
    Type: Grant
    Filed: December 21, 1981
    Date of Patent: October 18, 1983
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Morio Gaku, Nobuyuki Ikeguchi, Hidenori Kimbara
  • Patent number: 4393151
    Abstract: Stable suspension of a water-soluble polymer comprising solid particles of this water-soluble polymer in a liquid hydrocarbon medium which also comprises a thickening agent selected from the alkali or alkaline-earth metal salts of fatty acids having from 6-33 carbon atoms. The resultant suspensions are stable and dissolve easily when dispersed in water; they can be used in enhanced oil recovery.
    Type: Grant
    Filed: July 15, 1981
    Date of Patent: July 12, 1983
    Assignee: Institut Francais du Petrole
    Inventors: Francois Dawans, Daniel Binet, Norbert Kohler, Quang Dang Vu
  • Patent number: 4358560
    Abstract: Polymerization slurries of elastomeric isoolefin homopolymers and copolymers, such as butyl rubber, in diluents such as methyl chloride are effectively stabilized against agglomeration of polymer particles through addition of minor proportions of (i) a preformed copolymer stabilizer having both a lyophobic or lyophilic portion, or (ii) an in situ formed stabilizer from a functional lyophilic stabilizer precursor capable of copolymerizing or otherwise chemically bonding with the polymer product. Agglomeration of polymer products is effectively prevented, yielding a number of significant processing advantages. The process is especially adaptable to the production of isobutylene-isoprene butyl rubber.
    Type: Grant
    Filed: February 23, 1981
    Date of Patent: November 9, 1982
    Assignee: Exxon Research & Engineering Co.
    Inventors: Kenneth W. Powers, Ralph H. Schatz